Minerology and Petrology-2
Minerology and Petrology-2
Minerology and Petrology-2
Crystallography is the experimental science of the arrangement of atoms in solids. It derives from
the Greek words crystallon means cold drop or frozen drop and grapho means write with its meaning
extending to all solids with some degree of transparency.
A crystal is any solid material in which the component atoms are arranged in a definite pattern and
whose surface regularity reflects its internal symmetry. A crystal consists of matter that is formed of an
ordered three dimensional arrangement of atoms, molecules or ions. This can be imagined as the stacking
of bricks in a wall (resembling to a two dimensional ordered arrangement of bricks).
A unit-cell is the smallest building block of a crystal and it is the smallest unit of volume that
permits identical cells to be stacked together to fill all space. By repeating the pattern of the unit cell over
and over in all directions, the entire crystal lattice can be constructed.
I. Symmetry Operation
a) Rotational Symmetry
b) Mirror Symmetry
A mirror symmetry operation is an imaginary operation that can be performed to reproduce an object. The
operation is done by imagining that you cut the object in half,
then place a mirror next to one of the halves of the object along
the cut. If the reflection in the mirror reproduces the other half
of the object, then the object is said to have mirror symmetry.
c) Center of
Symmetry
d) Rotoinversion
In turn these symmetry classes, because some of them show similarities among each other, are divided
among the different crystal systems. There are six crystal system.
The three crystallographic axes are all equal in length and intersect at right
angles to each other.
A = B = C a=b=c=90°
Cube is one of the easiest to recognize and many minerals display it with little
modification: pyrite, fluorite, perovskite, or halite cubes.
A = B ≠ C a=b=c=90°
Four axes! Three of the axes fall in the same plane and intersect at the axial
cross at 120°. These 3 axes, labeled A1, A2, and A3, are the same length.
The fourth axis, c, may be longer or shorter than the A axes set. The c axis
also passes through the intersection of the A axes set at right angle to the
plane formed by the A set.
Three axes, all at right angles, all three have different length.
A ≠ B ≠ C a=b=c=90°
a≠b≠c
Bravais Lattices
By means of unit cells we managed to reduce all possible crystal structures to a relatively small
numbers of basic unit cell geometries. Lattice points are theoretical points arranged periodically in 3-D
space, rather than actual atoms. The limited number of possibilities, referred to as Bravais lattice. The
French scientist August Bravais, demonstrated in 1850 that only these 14 types of unit cells are compatible
with the orderly arrangements of atoms found in crystals.
The material that was displaced into the mantle during formation of the iron core contained
abundant oxygen, silica, magnesium, iron, aluminum. During formation of the crust, other compounds, in
particular feldspars and quartz were common reaction products. Instead, they show very specific
geometric arrangements. These compounds that make up the crust and mantle are commonly known to us
as minerals. Minerals are naturally occurring chemical compounds or elements found in the earth's crust
and are the building blocks of rocks. Rocks may contain only a single mineral, but usually they contain a
mixture of many minerals.
a) Quartz - Silicon dioxide, or quartz, is the most common mineral in the earth's
crust.
d) Mica var. Biotite - Some granites, schists, and gneisses contain this iron-bearing
potassium aluminum silicate.
I. IGNEOUS ROCKS
Igneous rocks were once lava or magma, that is, a molten collection of minerals. The rate at which a
lava or magma cools and solidifies influences rock texture, making it fine, medium or coarse grained.
a. Pumice - A light colored volcanic rock of rhyolite composition; the texture results from bubbles
formed by escaping gasses.
b. Obsidian - Very rapid cooling caused this volcanic rock to have its glassy appearance.
c. Basalt - This dark-colored, extrusive rock occurs as large flows, dikes, and sills.
d. Rhyolite - Quartz and microcline are the major components of rhyolite.
e. Andesite - The feldspar phenocrysts present in this light-colored, extrusive rock is the result of
relatively slowly cooling lava at shallow depths.
f. Granite - Feldspars and quartz made up the majority of this intrusive rock.
II. METAMORPHIC ROCKS
Metamorphic rocks are rocks that have been changed (metamorphosed), by heat, pressure, and/or
hydrothermal solutions. All three rock types can be metamorphosed.
a. Mica Schist - This rock is highly metamorphosed shale. All schists exhibit schistose structure; the
generally parallel alignment of micaceous minerals.
b. Slate - The low-grade metamorphism of shale results in slate.
c. Quartzite - The "parent rock" of quartzite is quartz sandstone.
d. Gneiss - All gneisses exhibit gneissic structure that is, alternating layers of granular minerals and
micaceous minerals.
e. Garnet Schist - Shale that undergoes complete recrystallization due to metamorphism often
contains high-pressure minerals such as garnet or andalusite.
f. Marble - This rock results when lime stones or certain dolomites are metamorphosed.
Clastic sedimentary rocks are formed from layers of sediment (fragments of older, weathered rock)
exposed to pressure. Other sedimentary rocks are of organic or chemical origin.
a. Sandstone - Quartz grains cemented together by silica, calcite or other cementing minerals make
up this clastic, sedimentary rock.
b. Shale - Shale is the most abundant of all the sedimentary rocks. It is usually finely bedded and is
composed of silt and/or clay size particles.
c. Arkose - This clastic, sedimentary rock is made up primarily of quartz and microcline, with
lesser amounts of other minerals.
d. Conglomerate - Rounded pebbles cemented together with finer material make up this clastic,
sedimentary rock.
e. Breccia - is composed of re-consolidated angular fragments of gravel and/or sand size particles.
f. Limestone - This sedimentary rock is made up primarily of calcite. Some lime stones are
chemical in origin, while other is clastic.
A mineral is defined in part by a specific chemical composition. In theory, therefore, it is always easy
to identify a mineral. In reality, however, even if you are looking at rocks on Earth, determining the exact
chemical composition of a substance involves significant time preparing the sample and sophisticated
laboratory equipment (and often significant money).
The most common minerals in Earth's crust can often be identified in the field using basic physical
properties such as color, shape, and hardness. The context of a mineral is important, too – some minerals
can form under the same conditions, so you are likely to find them in the same rock, while others form
under very different conditions and will never occur in the same rock.
a) Color
The most obvious property of a mineral, its color, is unfortunately also the least
diagnostic.
b) Crystal form
The external shape of a mineral crystal (or its crystal form) is determined largely by its internal
atomic structure, which means that this property can be highly diagnostic. Specifically, the form of
a crystal is defined by the angular relationships between crystal faces (recall Steno's Law of
Interfacial Angles as discussed in our Minerals I module).
c) Hardness
The hardness of a mineral can be tested in several ways. Most commonly, minerals are compared
to an object of known hardness using a scratch test – if a nail, for example, can scratch a crystal,
then the nail is harder than that mineral. In the early 1800s, Friedrich Mohs, an Austrian
mineralogist, developed a relative hardness scale based on the scratch test. He assigned integer
numbers to each mineral, where 1 is the softest and 10 is the hardest.
d) Luster
Luster of a mineral is the way that it reflects light. This may seem like a difficult distinction to make,
but picture the difference between the way light reflects off a glass window and the way it reflects
off of a shiny chrome car bumper.
e) Density
The density of minerals varies widely from about 1.01 g/cm3 to about 17.5 g/cm3. The density of
water is 1 g/cm3, pure iron has a density of 7.6 g/cm3, pure gold, 17.65 g/cm3. Minerals, therefore,
occupy the range of densities between water and pure gold. Measuring the density of a specific
mineral requires time-consuming techniques, and most geologists have developed a more intuitive
sense for what is "normal" density, what is unusually heavy for its size, and what is unusually light.
Most minerals contain inherent weaknesses within their atomic structures, a plane along which
the bond strength is lower than the surrounding bonds. When hit with a hammer or otherwise
broken, a mineral will tend to break along that plane of pre-existing weakness. This type of
breakage is called cleavage, and the quality of the cleavage varies with the strength of the bonds.
Some minerals don't have any planes of weakness in their atomic structure. These minerals don't
have any cleavage, and instead they fracture.
I. Coal
Coal is a fossil fuel and is the altered remains of prehistoric vegetation that originally accumulated in
swamps and peat bogs. The energy we get from coal today comes from the energy that plants absorbed
from the sun millions of years ago.
Petroleum was formed by the decomposition of plants and animals buried deep under the sea,
millions of year ago.
Due to high temperature and pressure, action of bacteria, and in the absence of air, the dead
remains of the plants and animals were gradually converted into petroleum.
Petroleum is also term that includes both oil and natural gas.
Occurrence of petroleum
Petroleum Gas: petroleum gas is used as a fuel in homes and industry, sometimes in the form of
Liquefied Petroleum Gas (LPG).
Petrol: it is used as a fuel in light vehicles such as motorcycles, cars and etc…
Kerosene: is used as fuel in wick stoves and pressure stoves to cook foods, is also used for lighting
purposes.
Diesel: is used as fuel in heavy vehicles such as buses, tractors, trucks, etc..
Bitumen: is used for road surfacing. It is also used for water proofing the roofs of buildings.
PETROLOGY
CLASSIFICATION OF ROCKS
I. Igneous Rock
Rocks are formed when magma (or molten rocks) cool down, and become solid. High temperatures
inside the crust of the Earth cause rocks to melt, and this substance is known
as magma. Magma is the molten material that erupts during a volcano.
This substance cools down slowly, and causes mineralization to take place.
Gradually, the size of the minerals increases until they are large enough to be
visible to the naked eye. Igneous rocks are mostly formed beneath the Earth’s
surface
Rocks are formed over millions of years when sediments (tiny pieces
of rocks and animal skeletons) are pressed together at the bottom
of seas and rivers. Examples include sandstone, coal and chalk.
Some sedimentary rocks contain fossils (bones or shells of living
things that were buried long ago and have turned to stone).
Igneous rocks form when magma (molten rock) cools and crystallizes, either at volcanoes on the
surface of the Earth or while the melted rock is still inside the crust. It can have many different
compositions, depending on the magma they cool from. They can also look different based on their cooling
conditions.
1. Extrusive Rocks/ Volcanic Rocks-are formed on the surface of the Earth from lava, which is
magma that has emerged from underground. The rate of cooling of the magma is rapid, and crystal
growth is inhibited. -are characteristically fine-grained.
2. Intrusive Rocks/ Plutonic Rocks - are formed from magma that cools and solidifies within the
crust of the planet. The rate of cooling of the magma is slow, allowing large crystals to grow and
are characteristically coarse-grained.
light-coloured.
Texture -phaneritic(medium to
coarse grained).
Uses -can be used as aggregate, fill etc. in the
construction
and roading industries (often not ideal for
concrete aggregate
because of high silica content
2. SYENITE
group - plutonic.
Color - variable but typically
light coloured.
Texture-phaneritic(medium
to coarse grained).
Uses - dimension stone for building facings, foyers
etc (often preferred to granite due to its better fire-
resistant qualities)
3. DIORITE
it is commonly speckled black and white, it is often
referred to as "salt and pepper" rock
Group - plutonic.
Colour - typically speckled
black and white.
Texture -phaneritic(medium
to coarse grained).
4. BASALT
Many moon rocks brought back by Apollo astronauts are of basaltic composition
Group -volcanic.
Colour- dark grey to black.
Texture-aphanitic
(can be porphyritic).
Sedimentary rocks are formed on the earth’s surface under normal surface temperature and pressures.
They result from the accumulation of the products of weathering of other rocks and organic materials. The
processes of transforming loose fragmented rocks into a compact solid cohesive mass is called lithification.
This process is also known as consolidation, and the resultant rock is said to be consolidated. Sandstone is
a consolidated rock, while sand is an example of an unconsolidated rock.
a) RIVERS
A river usually flows across rocks that may be soft and friable due to weathering process. Fragments
of the loose rocks usually break away and are carried by the river.
b) EROSION
This type of erosion often occurs around coasts where waves pick up rock fragments and smash them
against cliffs or other structures.
c) GLACIAL EROSION
Unlike the rivers, rock fragments carried within the ice do not become rounded. When the ice melts,
these abraded and transported materials are carried away by the melt water. Glacial deposits are poorly
sorted, because melting ice deposits material of all sizes together.
d) WIND EROSION
Wind erosion acts like rivers in that they pick up very small particles and roll the slightly larger ones
along the ground. Wind-blown sediments are usually well sorted because after the storm the wind speed
gradually reduces leading to the deposition of sediments in decreasing order of size.
Sediment transport is the movement of organic and inorganic particles by water . In general, the
greater the flow, the more sediment that will be conveyed. Transported sediment may include mineral
matter, chemicals and pollutants, and organic material.
a) Bedload
The portion of sediment transport that rolls, slides or bounces along the bottom of a
waterway. It occurs when the force of the water flow is strong enough to overcome the weight
and cohesion of the sediment. While the particles are pushed along, they typically do not move
as fast as the water around them, as the flow rate is not great enough to fully suspend them.
b) Suspended Load
Any particles found in the water column, whether the water is flowing or not. The
suspended load, on the other hand, is the amount of sediment carried downstream within the
water column by the water flow . Suspended loads require moving water, as the water flow
creates small upward currents (turbulence) that keep the particles above the bed.
c) Wash Load
The wash load is a subset of the suspended load. This load is comprised of the finest
suspended sediment (typically less than 0.00195 mm in diameter). The wash load is differentiated
from the suspended load because it will not settle to the bottom of a waterway during a low or no
flow period1.
• Grain size of sediment – this is the diameter in mm of the particles i.e. the grains that make up
the rock. This can vary from less than 1 mm to 100 mm or more.
• Sorting of the rock – in sedimentary rocks all the grains of the rock may not be of the same
size. The more or nearly they are of the same size, the better is the sorting.
• Rounding - as the rock fragments are being transported, they collide with other fragments and
become less angular i.e. more rounded.
I. Diagenesis
II. Lithification
Lithification may occur at the time a sediment is deposited or later. Cementation is one of the main
processes involved, particularly for sandstones and conglomerates. In addition, reactions take place
within a sediment between various minerals and between minerals and the fluids trapped in the pores.
• Compaction - as more sediment is being deposited, there is an increase of weight or pressure that
usually expels much of the connate water and forces the rock grains to come much closer together.
As the grains are forced against each other, their outer surfaces usually dissolve and re-crystallize
thus welding the grains together.
• Re-crystallization – this includes pressure solution as described, percolating water can also
dissolve material from one area and re-deposit it elsewhere or alternatively water can introduce
substance into the sediments which then crystallize
• Cementation – Deposition of substances from aqueous solutions usually occurs in the voids or
other spaces between the grains.
2. Chemical sediments – formed dominantly by chemical processes and more so from direct
precipitation of compounds from solutions.
3. Organic sediments – formed from organic debris such as mollusks, shells, plant debris etc.
CLASTIC ROCKS
Clastic sedimentary rocks are formed from the products of the mechanical breakup of other rocks.
The clastic rocks are most often named and classified on the basis of the average grain size of the particles
that form the rock.
Rudites
Breccia - Similar size as conglomerates but most of the clasts fragments are angular.
Arenites
Sandstone – usually consists of sand-sized sediment particles of quartz grains but also with other
minor components such as carbonate cement.
Greywacke – It is a poorly sorted sandstone usually dark in colour, containing rock fragments as
well as quartz.
Arkose – sandstone with at least 25% of the mineral composition being feldspar and the rest is
mainly quartz.
Calcarenite – This is a rock with sand sized grains but dominantly of carbonate composition.
Lutites
These are fine grained sedimentary rocks (0.05-0.005) and include the following:
Siltstone – silt sized particles which are slightly coarser than clay.
Mudstone – it has clay-sized particles which usually are too small to be seen by the naked eye and
which consist mainly of quartz and clay minerals.
Shale – is made up of finer-grained sediments whose grains cannot be seen with the naked eye. Its
grains are similar to mudstone but it is usually fissile rock i.e. it splits easily into thin sheets.
1. Contact metamorphism – a rocks intruded by hot magma that "bakes" the surrounding rock.
2. Regional metamorphism – (dynamothermal metamorphism) large-scale deformation in rocks that are
subjected to higher pressure and temperatures from burial and/or during "mountain building" processes.
a. AGENTS OF METHAMORPHISM
Heat is the most important agent since it provides the energy to drive the chemical changes that result in
recrystallization of minerals in the rock. Two primary ways that heat is an metamorphic agent:
• During contact metamorphism, the intense heat of an intruded magma may "bake" the adjacent
rock.
• During regional metamorphism, rocks near the surface of the Earth may be thrust downward and
buried where they are subjected to increased temperatures and stresses.
TEXTURE COMPOSITION
•Foliated •Metamorphic Grade
•Slightly foliated •Index Minerals
•Non-foliated •Overall Mineral
Quartzite – is a hard, non-foliated metamorphic rock which was originally pure quartz sandstone.
Sandstone is converted into quartzite through heating and pressure usually related to tectonic
compression with orogenic belts.
Marble – is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite
or dolomite. Marble is typically not-foliated, although there are exceptions. In geology, the term “marble”
refers to metamorphoses limestone, but it is used in stonemasonry more broadly encompasses
unmetamorphosed limestone.
Slate – a fine-grained, foliated, homogenous metamorphic rock derived from an original shale-type
sedimentary rock composed of clay or volcanic ash through low-grade regional metamorphism. It is the
finest grained foliated metamorphic rock.
Gneiss – is a common and widely distributed type of metamorphic rock. Gneiss is formed by high
temperature and high-pressure metamorphic processes acting on formations composed of igneous or
sedimentary rocks. Orthogneiss is gneiss derived from igneous rock while Paragneiss derived from
sedimentary rock.
Why Study Metamorphic Rocks?
• Studies of metamorphic rocks provide insights into the physical and chemical changes that take place
deep within Earth. The presence of index minerals in metamorphic rocks allows geologists to assess the
temperatures and pressures the parent rock encountered.
• Knowledge of metamorphic processes and rocks is valuable, because metamorphic minerals and rocks
have economic value. For example, slate and marble are building materials, garnets are used as gemstones
and abrasives, talc is used in cosmetics, paints, and lubricants, and asbestos is used for insulation and
fireproofing.
References
Structure Determination by X-ray Crystallography, M.F.C. Ladd & R.A. Palmer, 3rd Edition, Plenum
Press, NY. Retrived on February 06, 2020 from https://www.cif.iastate.edu/acide/xrd-
tutorial/crystallography#Q2
Online Resources
https://pressbooks-dev.oer.hawaii.edu/chemistry/chapter/lattice-structures-in-crystalline-solids/
https://www3.nd.edu/~amoukasi/CBE30361/Lecture__crystallography_A.pdf
https://www.tulane.edu/~sanelson/eens211/introsymmetry.htm
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