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UA008883 – Workbook for GCE students – Moles, Formulae and Equations 115
Edexcel Advanced GCE in Chemistry (9080)
Edexcel Advanced GCE in Chemistry (Nuffield) (9086) – Issue 3 – October 2004
116 UA008883 – Workbook for GCE students – Moles, Formulae and Equations
Exercise 1
1 18 21 11 41 159.5
2 44 22 164 42 161.4
3 17 23 74 43 170
4 46 24 136 44 53.5
5 28 25 208 45 132
6 64 26 1335 46 117.0
7 80 27 213 47 122.5
8 81 28 342 48 166.0
9 98 29 152 49 74.5
10 63 30 127 50 69.0
11 58.5 31 162.5 51 249.5
12 85 32 400 52 278
13 106 33 223 53 964
14 40 34 239 54 248
15 142 35 685 55 126
16 158 36 331 56 246
17 194 37 278 57 2635
18 100 38 303 58 60
19 166 39 99.0 59 58
20 195 40 134.5 60 122
Exercise 2
1 NaCl 21 BaSO4 41 PbCO3 61 PCl3

2 NaOH 22 AlCl3 42 PbO 62 PCl5
3 Na2CO3 23 Al2O3 43 PbO2 63 P2O3
4 Na2SO4 24 Al(OH)3 44 PbCl2 64 P2O5
5 NO3PO4 25 Al2(SO4)3 45 PbCl4 65 H3PO4
6 KCl 26 CuSO4 46 PbS 66 H2SO4
7 KBr 27 CuO 47 SnCl2 67 HNO3
8 KI 28 CuCl2 48 SnCl4 68 HCl
9 KHCO3 29 Cu(NO3)2 49 FeSO4 69 CCl4
10 KNO2 30 Cu2O 50 FeCl2 70 SiCl4
11 MgCl2 31 CuCl 51 Fe2(SO4)3 71 SiO2
12 Mg(NO3)2 32 Zn(NO3)2 52 FeCl3 72 SO2
13 Mg(OH)2 33 ZnCO3 53 Fe(OH)3 73 SO3
14 MgO 34 ZnO 54 Fe(OH)2 74 H2S
15 MgCO3 35 AgCl 55 NH4Cl 75 Cl2O
16 CaO 36 AgBr 56 (NH4)2CO3 76 NO2
17 CaCl2 37 AgI 57 NH4OH 77 NO
18 CaSO4 38 AgNO3 58 NH4NO3 78 CO2
19 CaCO3 39 Ag2O 59 (NH4)2SO4 79 CO
20 BaCl2 40 Pb(NO3)2 60 (NH4)3PO4 80 HOH/H2O
Exercise 3
1 Water 31 Iron(III) chloride

2 Carbon dioxide 32 Iron(III) sulphate
3 Ammonia 33 Lead(II) oxide
4 Oxygen 34 Lead(IV) oxide
5 Hydrogen 35 Lead(II) nitrate
6 Sulphur dioxide (or IV oxide) 36 Lead(II) chloride
7 Sulphur trioxide (or VI oxide) 37 Lead (II) sulphate
8 Hydrogen chloride 38 Copper(II) nitrate
9 Hydrogen iodide 39 Copper(I) chloride
10 Hydrogen fluoride 40 Copper(II) chloride
11 Methane 41 Copper(II) sulphate
12 Hydrogen sulphide 42 Zinc chloride
13 Hydrogen bromide 43 Silver nitrate
14 Sulphuric acid 44 Ammonium chloride
15 Nitric acid 45 Ammonium sulphate
16 Sodium chloride 46 Ammonium vanadate(V)
17 Sodium nitrate 47 Potassium chlorate(V)
18 Sodium carbonate 48 Potassium iodate
19 Sodium hydroxide 49 Sodium chlorate(I)
20 Sodium sulphate 50 Sodium nitrite
21 Calcium chloride 51 Ethane
22 Calcium nitrate 52 Butane
23 Calcium hydroxide 53 Octane
24 Calcium sulphate 54 Ammonium carbonate
25 Barium chloride 55 Potassium manganate(VII)
26 Aluminium chloride 56 Potassium chromate(VI)
27 Aluminium nitrate 57 Potassium hydrogencarbonate
28 Aluminium sulphate 58 Potassium iodide
29 Iron(II) sulphate 59 Cobalt(II) nitrate
30 Iron(II)chloride 60 Potassium astatide
Exercise 4a
1 0.50 26 0.10
2 2.0 27 0.10
3 0.10 28 0.0085
4 5.0 29 0.26
5 20 30 0.104
6 0.010 31 0.20
7 1.0 32 0.082
8 0.22 33 0.050
9 0.0010 34 1.34
10 0.050 35 0.025
11 0.33 36 0.204
12 0.25 37 0.071
13 0.021 38 0.010
14 0.020 39 0.050
15 0.125 40 0.254
16 0.020 41 0.0125
17 0.167 42 0.152
18 1.0 43 0.10
19 0.046 44 0.053
20 0.020 45 0.0043
21 0.0010 46 0.036
22 0.25 47 0.266
23 0.02 48 0.024
24 0.0025 49 0.025
25 0.20 50 1.574
Exercise 4b
1 36 g 26 14.95 g
2 132 g 27 76.2 g
3 47.6 g 28 10.03 g
4 23 g 29 17.82 g
5 33.6 g 30 145.2 g
6 40.96 g 31 2.925 g
7 240 g 32 12.25 g
8 81 g 33 21.4 g
9 1.152 g 34 745 g
10 9.45 g 35 0.069 g
11 26.3 g 36 49.9 g
12 59.5 g 37 27.8 g
13 11.66 g 38 4.82 g
14 80.0 g 39 9.92 g
15 127.8 g 40 302.4 g
16 7.9 g 41 756.5 g
17 34.92 g 42 39.53 g
18 90 g 43 10.2 g
19 249 g 44 11.6 g
20 23.4 g 45 9.76 g
21 12.2 g 46 4.34 g
22 672.4 g 47 9.59 g
23 0.296 g 48 41.0 g
24 13.6 g 49 304 g
25 43.68 g 50 1397 g
Exercise 4c
1 24000 cm3 11 134.4 cm3

2 2400 cm3 12 216 cm3
3 12000 cm3 13 960 cm3
4 48000 cm3 14 2952 cm3
5 2880 cm3 15 55.2 cm3
6 81600 cm3 16 192000 cm3
7 2640 cm3 17 0.24 cm3
8 96 cm3 18 144000 cm3
9 240000 cm3 19 182.4 cm3
10 10800 cm3 20 72000 cm3
Exercise 4d
1 0.0083 mol 11 0.0292 mol

2 0.0208 mol 12 0.2333 mol
3 0.0416 mol 13 0.0917 mol
4 0.0533 mol 14 0.0088 mol
5 0.0098 mol 15 0.0333 mol
6 0.0094 mol 16 0.0033 mol
7 0.0106 mol 17 0.000080 mol
8 0.0033 mol 18 0.8333 mol
9 0.0833 mol 19 0.0175 mol
10 0.10 mol 20 0.0375 mol
Exercise 4e
1 0.367 g 11 0.875 g
2 0.354 g 12 10.27 g
3 1.166 g 13 2.38 g
4 5.333 g 14 0.263 g
5 0.78 g 15 1.217 g
6 0.763 g 16 0.270 g
7 0.757 g 17 0.011 g
8 0.233 g 18 38.33 g
9 0.167 g 19 0.683 g
10 3.20 g 20 1.05 g
Exercise 4f
1 1091 cm3 11 56000 cm3

2 7059 cm3 12 30545 cm3
3 8571 cm3 13 20308 cm3
4 7500 cm3 14 16000 cm3
5 702 cm3 15 5260 cm3
6 670 cm3 16 2370 cm3
7 3380 cm3 17 375 cm3
8 30000 cm3 18 12000 cm3
9 2400000 cm3 19 26526 cm3
10 180000 cm3 20 77143 cm3
Exercise 4g
1 160 11 34
2 64 12 17
3 80 13 38
4 71 14 28
5 2.0 15 44
6 28 16 32
7 30 17 211
8 58 18 36.5
9 32 19 81
10 28 20 128
Exercise 5
Section (a)
1 CaCO3 4 N2H4S2O8
2 Na2SO4 5 P4O10
3 Na2S2O3 6 C2H4O2 - CH3COOH
4 PbO 7 C4H10
5 Pb3O4 8 Fe2O3
6 H3PO3 9 H2S2O8
7 H2SO3 10 C6H6
8 CH4 Section (c)
9 C3H8 1 PbO
10 HO (giving H2O2) 2 KO2
11 H4N2O3 (NH4NO3) 3 C2H2
12 FeSO11H14 (FeSO4 - 7H2O) 4 AlCl3
Section (b) 5 CH4
1 C2H4 6 yes
2 C3H6 7 CuSO4 5H2O
3 P2I4 8 PCl5, PCl3, Cl2
Exercise 6a
1 2H2 + O2 → 2H2O
2 BaCl2 + 2NaOH → Ba(OH)2 + 2NaCl
3 H2SO4 + 2KOH → K2SO4 + 2H2O
4 K2CO3 + 2HCl → 2KCl + H2O + CO2
5 CaCO3 + 2HNO3 → Ca(NO3)2 + H2O + CO2
6 Ca + 2H2O → Ca(OH)2 + H2
7 Pb(NO3)2 + 2NaI → PbI2 + 2NaNO3
8 Al2(SO4)3 + 6NaOH → 2Al(OH)3 + 3Na2SO4
9 Al(OH)3 + NaOH → NaAlO2 + 2H2O
10 2Pb(NO3)2 → 2PbO + 4NO2 O2
11 2FeSO4 → Fe2O3 + SO2 SO3
12 NH4NO3 → N2O + 2H2O
13 2NaNO3 → 2NaNO2 + O2
14 CH4 + 2O2 → CO2 + 2H2O
15 2C4H10 + 13O2 → 8CO2 + 10H2O
16 PCl3 + 3H2O → H3PO3 + 3HCl
17 8HNO3 + 3Cu → 3Cu(NO3)2 + 3NO + 4H2O
18 4HNO3 + Cu → Cu(NO3)2 + 2NO2 + 2H2O
19 H3PO4 + NaOH → NaH2PO4 + H2O
20 H3PO4 + 3NaOH → Na3PO4 + 3H2O
21 H3PO4 + 2NaOH → Na2HPO4 + 2H2O
22 6NaOH + 3Cl2 → NaClO3 + 5NaCl + 3H2O
23 N2 + 3H2 → 2NH3
24 2NaBr + H2SO4 → Na2SO4 + HBr
25 2HBr + H2SO4 → 2H2O + SO2 + Br2
26 3C2H5OH + PCl3 → 3C2H5Cl + H3PO3
27 Fe3O4 + 4H2 → 3Fe + 4H2O
28 Fe2O3 + 3CO → 2Fe + 3CO2
29 C2H5OH + CH3CO2H → CH3CO2C2H5 + H2O
30 2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 8H2O + 5 Cl2
Exercise 6b
1 Hydrogen is not H but H2, which gives

2Na(s) + 2H2O(aq) → 2NaOH(aq) + H2(g)
2 Since the valency of lead is 2 not 1 lead nitrate is not PbNO3 but Pb(NO3)2 and also lead
chloride is PbCl2
Pb(NO3)2(aq) + 2NaCl(aq) → PbCl2(s) + 2NaNO3(aq)
3 Calcium hydroxide is Ca(OH)2

Ca(OH)2(aq) + 2HCl(aq) → CaCl2(aq) + 2H2O(l)
4 This does not balance.
C2H4(g) + 3O2(g) → 2CO2(g) + H2O(l)
5 A magnesium compound cannot give a calcium compound!
6 Ozone O3 is not produced by heating a nitrate O2 is.
2Cu(NO3)2(s) → 2CuO(s) + 4NO2(g) + O2(g)
7 This reaction does not take place and so no equation can be written.
8 Aluminium has a valency of 3 not 2 as in this equation.
AlCl3(s) + 3KOH(aq) → Al(OH)3(s) + 3KCl(aq)
9 Sodium has a valency of 1 not 2 as in this equation

Na2CO3(s) + 2HCl(aq) → 2NaCl(aq) + H2O(l) + CO2(g)
10 Silver chloride is not soluble in water. Thus the AgCl needs a (s) symbol
Exercise 6c
1 Zn(s) + CuSO4(aq) → Cu(s) + ZnSO4(aq)
2 Ca(OH)2(s) + 2NH4Cl(s) → CaCl2(s) + H2O(g) + NH3(g)
3 2Pb(NO3)2(s) → 2PbO(s) + 4NO2(g) + O2(g)
4 SiCl4(l) + 2H2O(l) → SiO2(s) + HCl(g)
5 Ca(HCO3)2(aq) → CaCO3(s) + H2O(l) + CO2(g)
6 2C8H18(g) + 25O2(g) → 16CO2(g) + 8H2O(l)
7 6NaOH(aq) + 3Cl2(g) → NaClO3(aq) + 5NaCl(aq) + 3H2O(l)
6NaOH(aq) + 3Br2(g) → NaBrO3(aq) + 5NaBr(aq) + 3H2O(l)
6NaOH(aq) + 3I2(g) → NaIO3(aq) + 5NaI(aq) + 3H2O(l)
8 2M(s) + 2H2O(l) → 2MOH(aq) + H2(g)
Where M = Li, Na, K, Rb or Cs
9 SnCl2(aq) + 2HgCl2(aq) → 2HgCl (s) + SnCl4(aq)
10 9H2SO4 + 8KI → 4I2 + H2S + 8KHSO4 + 4H2O
Exercise 7
1 AlCl3 + 3AgNO3 → Al(NO3)3 + 3AgCl
2 K2CrO4 + Pb(NO3)2 → PbCrO4 + 2KNO3
3 2AgNO3 → 2Ag + 2NO2 + O2
4 i) 1 mole
ii) 2 moles
iii)
H3PO4 + NaOH → NaH2PO4 + H2O
H3PO4 + 2NaOH → Na2HPO4 + 2H2O
iv) 75 cm3
5 x=3
6 x=5
CuSO4.5H2O → CuSO4 + 5H2O
7 4NH3 + 5O2 → 4NO + 6H2O
8 C3H8 + 5O2 → 3CO2 + 4H2O
9 It is
10 FeSO4.7H2O → Fe2O3 + SO2 + SO3 + 14H2O
Exercise 8
1 11.2 g
2 21.6 g
3 0.682 g of ethanoic acid and 0.523 g of ethanol
4 143 tonnes
5 14.5 g
6 8.0 g of sodium hydroxide, 9.75 g of copper hydroxide
7 12000 cm3
8 54. 7 g of calcium nitrate, 8.0 dm3 of carbon dioxide
9 6 dm3 total (4.8 dm3 of nitrogen dioxide and 1.2 dm3 of oxygen)
10 Mg + H2SO4 + 7H2O → Mg SO4.7H2O + H2

41.0 g
11 31.9 g
12 324.3 g
13 5.11 g of ethanol, 2.67 dm3 of carbon dioxide
14 (i) 12.30 g of zinc hydroxide

(ii) 9.12 g of aluminium hydroxide
(iii) 9.67 g of magnesium hydroxide
15 0.600 dm3
16 0.100 g
17 2.94 g of sodium chloride, 1.065 g of sodium chlorate(v)
18 4.15 x 106 dm3 of nitrogen, 12.5 x 106 dm3 of hydrogen
19 63 tonnes of nitric acid, 4.8 x 107 dm3 of oxygen
20 2198 g of calcium carbonate, 4.395 dm3 of 10M HCl
Exercise 9
Section (a)
1 20cm3 O2 10cm3 CO2 20cm3 H2O (g)
2 30cm3 O2 20cm3 CO2 20cm3 H2O (g)
3 25cm3 O2 20cm3 CO2 10cm3 H2O (g)
4 125cm3 O2 80cm3 CO2 90cm3 H2O (g)
5 30cm3 H2 20cm3 NH3
Section (b)
1 500cm3 O2 (2NO + O2 →2NO2)
2 375cm3 air (2SO2 + O2 →2SO3)
3 2500cm3 NH3 needed 5
/4 x 2500 = 3125cm3 O2 → 15625cm3 air
4 6.5 x 24000cm3 = 156m3
5 24000cm3
6 Final volume = 20cm3 (10cm3 CO2 + 10 cm3 unused O2)
7 Final volume = 77.5cm3 (40cm3 CO2 + 37.5cm3 used O2)
8 This time the CH4 is in excess. We must assume that CO2 is produced
(not CO or C)!
Final volume = 60 cm3 (30 cm3 CO2 + 30 cm3 CH4)
9 N2 + 3H2 2NH3 →
10 cm3 30 cm3 20 cm3
+ 30 cm3excess
20 cm3 NH3 produced + 30 cm3 excess H2
10 2 H2 + O2 → 2H2O
10 cm3 5 cm3
+ 5 cm3 excess
Final volume = 5 cm3 (all excess O2)
Exercise 10
1 Pb2+ (aq) + 2OH– (aq) → Pb(OH)2(s)
2 Al3+(aq) + 3OH–(aq) → Al(OH)3(s)
3 Al(OH)3(s) + OH–(aq) → AlO2–(aq) + 2H2O (l)
4 Cl2(g) + 6OH–(aq) → ClO3–(aq) + 5Cl–(aq) + 3H2O(l)
5 2S2O32–(aq) + I2(s) → S4O62–(aq) + 2I–(aq)
6 Cu2+ (aq) + 2OH–(aq) → Cu(OH)2(s)
7 CO32–(s) + 2H+(aq) → H2O(l) + CO2(g)
8 Zn(s) + 2H+(aq) → Zn2+(aq) + H2(g)
9 Zn(s) + Pb2+ (aq) → Pb(s) + Zn2+(aq)
10 H+(aq) + OH– (aq) → H2O(l)
11 Mg(s) + 2H+(aq) → Mg2+(aq) + H2(g)
12 CO32–(s) + 2H+(aq) → H2O(l) + CO2(g)
13 CuO(s) + 2H+(aq) → Cu2+(aq) + H2O(l)
14 Ba2+(aq) + SO42–(aq) → BaSO4(s)
15 Ag+(aq) + Cl–(aq) → AgCl(s)
16 Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s)
17–20 20H+(aq) + OH–(aq) → H2O(l)
In every case the reaction is the same
634rp271004LT\PD\A LEVEL TEACHERS HANDBOOK\UA008883 GCE CHEM MOLES WKBK ISS3.DOC.1-150/5
Exercise 11a
1 0.025 moles 19 0.079 g
2 0.025 moles 20 0.828 g
3 0.0625 21 0.1 mol dm–3
4 0.005 moles 22 1.0 mol dm–3
5 0.025 moles 23 0.03 mol dm–3
6 0.025 moles 24 0.1 mol dm–3
7 0.0125moles 25 0.03 mol dm–3
8 0.01 moles 26 0.04 mol dm–3
9 0.00125 moles 27 0.40 mol dm–3
10 0.005 moles 28 0.40 mol dm–3
11 0.9125 g 29 0.152 mol dm–3
12 1.463 g 30 0.0102 mol dm–3
13 2 g 31 0.01 mol dm–3
14 1.70 g 32 0.2 mol dm–3
15 5.2 g 33 0.02 mol dm–3
16 0.98 g 34 0.005 mol dm–3
17 0.08 g 35 0.417 mol dm–3
18 0.97 g
Exercise 11b
1 0.168 mol dm–3 16 3.0
2 0.136 mol dm–3 17 0.02 mol dm–3
3 0.118 mol dm–3 18 50 cm3
4 1.0 mol dm–3 19 50 cm3
5 0.12 mol dm–3 20 25 cm3
6 0.040 mol dm–3 21 0.359 g
7 0.0080 mol dm–3 22 1.0 g
–3
8 0.010 mol dm 23 240 cm3
9 0.10 mol dm–3 24 0.12 g Mg
120 cm3 H2
10 0.40 mol dm–3 25 480 cm3
11 0.050 mol dm–3
12 0.167 mol dm–3
13 2.26 g dm–3
14 0.099 mol dm–3
15 1.755 g dm–3
Further copies of this publication are available from
Edexcel Publications, Adamsway, Mansfield, Notts, NG18 4FN
Telephone 01623 467467

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Email: [email protected]
Order Code UA008883 October 2004
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1 NaCl 21 BaSO4 41 PbCO3 61 PCl3

1 Water 31 Iron(III) chloride

1 24000 cm3 11 134.4 cm3

1 0.0083 mol 11 0.0292 mol

1 1091 cm3 11 56000 cm3

2 BaCl2 + 2NaOH → Ba(OH)2 + 2NaCl

3 H2SO4 + 2KOH → K2SO4 + 2H2O

4 K2CO3 + 2HCl → 2KCl + H2O + CO2

5 CaCO3 + 2HNO3 → Ca(NO3)2 + H2O + CO2

7 Pb(NO3)2 + 2NaI → PbI2 + 2NaNO3

8 Al2(SO4)3 + 6NaOH → 2Al(OH)3 + 3Na2SO4

9 Al(OH)3 + NaOH → NaAlO2 + 2H2O

10 2Pb(NO3)2 → 2PbO + 4NO2 O2

11 2FeSO4 → Fe2O3 + SO2 SO3

12 NH4NO3 → N2O + 2H2O

14 CH4 + 2O2 → CO2 + 2H2O

15 2C4H10 + 13O2 → 8CO2 + 10H2O

16 PCl3 + 3H2O → H3PO3 + 3HCl

17 8HNO3 + 3Cu → 3Cu(NO3)2 + 3NO + 4H2O

18 4HNO3 + Cu → Cu(NO3)2 + 2NO2 + 2H2O

19 H3PO4 + NaOH → NaH2PO4 + H2O

20 H3PO4 + 3NaOH → Na3PO4 + 3H2O

21 H3PO4 + 2NaOH → Na2HPO4 + 2H2O

22 6NaOH + 3Cl2 → NaClO3 + 5NaCl + 3H2O

24 2NaBr + H2SO4 → Na2SO4 + HBr

25 2HBr + H2SO4 → 2H2O + SO2 + Br2

26 3C2H5OH + PCl3 → 3C2H5Cl + H3PO3

27 Fe3O4 + 4H2 → 3Fe + 4H2O

29 C2H5OH + CH3CO2H → CH3CO2C2H5 + H2O

30 2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 8H2O + 5 Cl2

1 Hydrogen is not H but H2, which gives

3 Calcium hydroxide is Ca(OH)2

4 This does not balance.

C2H4(g) + 3O2(g) → 2CO2(g) + H2O(l)

5 A magnesium compound cannot give a calcium compound!

6 Ozone O3 is not produced by heating a nitrate O2 is.

2Cu(NO3)2(s) → 2CuO(s) + 4NO2(g) + O2(g)

8 Aluminium has a valency of 3 not 2 as in this equation.

AlCl3(s) + 3KOH(aq) → Al(OH)3(s) + 3KCl(aq)

9 Sodium has a valency of 1 not 2 as in this equation

1 Zn(s) + CuSO4(aq) → Cu(s) + ZnSO4(aq)

2 Ca(OH)2(s) + 2NH4Cl(s) → CaCl2(s) + H2O(g) + NH3(g)

3 2Pb(NO3)2(s) → 2PbO(s) + 4NO2(g) + O2(g)

4 SiCl4(l) + 2H2O(l) → SiO2(s) + HCl(g)

5 Ca(HCO3)2(aq) → CaCO3(s) + H2O(l) + CO2(g)

6 2C8H18(g) + 25O2(g) → 16CO2(g) + 8H2O(l)

7 6NaOH(aq) + 3Cl2(g) → NaClO3(aq) + 5NaCl(aq) + 3H2O(l)

6NaOH(aq) + 3Br2(g) → NaBrO3(aq) + 5NaBr(aq) + 3H2O(l)

6NaOH(aq) + 3I2(g) → NaIO3(aq) + 5NaI(aq) + 3H2O(l)

8 2M(s) + 2H2O(l) → 2MOH(aq) + H2(g)

Where M = Li, Na, K, Rb or Cs

9 SnCl2(aq) + 2HgCl2(aq) → 2HgCl (s) + SnCl4(aq)

10 9H2SO4 + 8KI → 4I2 + H2S + 8KHSO4 + 4H2O

1 AlCl3 + 3AgNO3 → Al(NO3)3 + 3AgCl

2 K2CrO4 + Pb(NO3)2 → PbCrO4 + 2KNO3

3 2AgNO3 → 2Ag + 2NO2 + O2

H3PO4 + NaOH → NaH2PO4 + H2O

H3PO4 + 2NaOH → Na2HPO4 + 2H2O

CuSO4.5H2O → CuSO4 + 5H2O