4/13/2020 Commercial Lithium Production and Mining of Lithium

COMMODITIES METALS

An Overview of Commercial Lithium

Production

ARTICLE TABLE OF CONTENTS EXPAND +

BY TERENCE BELL
Updated January 24, 2020

Most lithium is commercially produced from either the extraction of lithium-containing salts
from underground brine reservoirs or the mining of lithium-containing rock, such as
spodumene. Lithium production from clay sources is expected to become commercially
viable, though perhaps not until 2022.

Lithium is a metal commonly used in batteries like the rechargeable ones found in laptops,
cellphones, and electric cars as well as in ceramics and glass. It is the lightest metal on Earth
and is soft enough to be cut with a knife when in its elemental form.

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Processing From Brine

Much of the lithium produced today is extracted from brine reservoirs called salars that are
located in high-elevation areas of Bolivia, Argentina, and Chile. In order to extract lithium from
brines, the salt-rich waters must first be pumped to the surface into a series of large
evaporation ponds where solar evaporation occurs over a number of months.

Potassium is often first harvested from early ponds, while later ponds have increasingly high
concentrations of lithium. Economical lithium-source brines normally contain anywhere from
a few hundred parts per million (ppm) of lithium to upwards of 7,000 ppm.

When the lithium chloride in the evaporation ponds reaches an optimum concentration, the
solution is pumped to a recovery plant where extraction and filtering remove any unwanted
boron or magnesium. It is then treated with sodium carbonate (soda ash), thereby
precipitating lithium carbonate. The lithium carbonate is then filtered and dried. Excess
residual brines are pumped back into the salar.

Lithium carbonate is a stable white powder that is a key intermediary in the lithium market
because it can be converted into specific industrial salts and chemicals—or processed into
pure lithium metal.

Processing From Minerals
In contrast to salar brine sources, extraction of lithium from spodumene, lepidolite, petalite,
amblygonite, and eucryptite requires a wide range of processes. Because of the amount of
energy consumption and materials required, lithium production from mining is a much more

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costly process than brine extraction, even though these minerals have a higher lithium
content than the saltwater.

Of the five minerals, spodumene is the most commonly used for lithium production. After it is
mined, spodumene is heated to 2012 degrees Fahrenheit and then cooled to 149 degrees. It's
then crushed and roasted again, this time with concentrated sulfuric acid. [1] Ultimately,
sodium carbonate, or soda ash, is added, and the resulting lithium carbonate is crystallized,
heated, filtered, and dried.

Processing From Clay 
Several companies are exploring the extraction of lithium from clay in Nevada, including
American Lithium and Noram Ventures. The companies are testing di erent production
methods, including sulfuric acid leaching.

Turning Lithium Into Metal

Converting lithium into metal is done in an electrolytic cell using lithium chloride. The lithium
chloride is mixed with potassium chloride in a ratio of 55% to 45% in order to produce a
molten eutectic electrolyte. Potassium chloride is added to increase the conductivity of the
lithium while lowering the fusion temperature.

When fused and electrolyzed at about 840 degrees Farhenheit, chlorine gas is liberated while
molten lithium rises to the surface, collecting in cast-iron enclosures. The pure lithium
produced is wrapped in para n wax to prevent oxidization. The conversion ratio of lithium
carbonate to lithium metal is about 5.3 to 1.

Global Lithium Production

The top five countries for lithium production in 2018 were Australia, Chile, China, Argentina,
and Zimbabwe. Australia produced 51,000 metric tons of lithium that year, the latest for
which figures are available. Total global production, excluding the U.S., amounted to 70,000
metric tons.

The companies that produce the most lithium are Albemarle, Sociedad Quimica y Minera de
Chile, and FMC.

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