ENVIRONMENTAL ISSUES IN THE PROCESSING AND

EXTRACTION OF NON-FERROUS METALS

AMITAVABANDOPADHYAY
Email [email protected]
PREAMBLE
The non-ferrous metals industry is a key sector in the Indian economy as it meets the requirements
of a wide range of key industries including engineering, electrical and electronics, infrastructure,
automobile and automobile components, packaging etc. The Indian non-ferrous metals industry
comprises of the primary and secondary downstream segments. Primary producers are those
players who process the mined ore to obtain the primary metal. This metal is commercially
available in the form of rods, ingots, cathodes, wires etc., Secondary producers are those players
who manufacture value added products like foils, extrusions, dry batteries, castings etc., either
by procuring the metal from the primary producers or from scrap.
The domestic industry is characterized by the presence of only a few players in the primary
segment. However, in the secondary and downstream segments there are many players both
in the organized and in the unorganized sectors. There are significant reserves of non-ferrous
metal ores in India. India is rich in bauxite (aluminium ore) and has grades of zinc, lead and
copper reserves. Copper, lead and zinc are also imported as scrap or concentrates to be processed
by secondary/custom smelters.
The non-ferrous metals industry in India is growing strongly aided by the privatisation process
started in early 2000. By 2020, it is expected that the industry, comprising aluminium, copper,
lead and zinc sectors, will be completely privatised, and India will grow to become a global
player in the non-ferrous metals industry.
Aluminium
India has nearly 10 per cent of the world's bauxite reserves and a growing aluminium sector
that leverages this. Demand in the domestic market is expected to grow by 8-10 per cent in
2005-06. By 2020, India is expected to have an installed aluminium capacity of 1.7 to 2 million
tones per annum. The primary market for aluminium in India is the power sector, which
consumes about 35 per cent of the domestic production. This is in contrast to the global market,
where the bulk of aluminium is consumed by the construction and packaging sectors. The
ongoing reforms in the power sector as well as focus on improving power infrastructure is
expected to further boost the aluminium sector in India.
Copper
Copper is a key sector impacting the Indian economy. Copper has a number of applications
across several sectors such as telecom, power, construction, transportation, handicrafts,
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engineering, and consumer durables. The Indian industry has an installed capacity - about
477,500 tonnes per annum in 2003-04 - that is greater than the domestic market - about 290,000
tonnes - leading to a surplus situation. This is an advantage that can be leveraged for boosting
exports, especially since the Asian region has a deficit of around 2.6 million tonnes. Nearly 40
per cent of copper production in India is currently exported.
The industry currently has three major players - Sterlite, Hindalco and Hindustan Copper Ltd.
(HCL), which together account for nearly 80 per cent of the total copper production in the
country. Other players include around 1000 small-scale industries (SSIs), which are primarily
involved in converting scrap into ingots. While HCL is the only primary producer, which
mines and refines copper, Hindalco and Sterlite are secondary producers, who process
indigenous and/or imported copper concentrate to produce end products like copper bars,
rods and wires.
The performance of the copper industry is highly dependent on the performance of and demand
for products like power and telecommunication cables, transformers, generators, radiators
and other ancillary components. Hence, its growth is closely linked to the country's economic
and industrial growth. India has been growing at a steady and sustained compounded average
growth rate of 5.6 per cent for the past 20 years. This is expected to improve further to a level
of around 8 per cent in the future. The outlook for the copper industry in India is therefore
positive.
Zinc
With the privatisation of the largest zinc producer, Hindustan Zinc Ltd, sold to the Sterlite
group in April 2002, the Indian zinc industry is completely under the private sector and is in
the midst of expansion. At present the smelting capacity for primary zinc in India is 260,000
tonnes per annum, as against a domestic demand of about 350,000 tonnes per annum. Over
the next 5 to 6 years, demand is expected to grow at about 12 -15 percent annually, as against
a global average of 5 per cent. Domestic production capacity, however, is also expected to
increase to attain self-sufficiency by 2010.
The main consumer for zinc in the domestic market is the steel industry - over 70 per cent of
zinc is used for galvanising. Other sources of demand for zinc include die-casting, guard rails
for highways and imported-substituted zinc alloys. The steel industry has bright prospects
with demand drivers being the construction industry and exports. With continued infrastructure
development such as roads, irrigation, construction, oil & gas, ports etc, there is a rising demand
for steel, thus providing significant opportunities for zinc in India.
Lead
Lead is a very corrosion-resistant, dense, ductile, and malleable blue-gray metal that has been
used for at least 5,000 years. Early uses of lead included building materials, pigments for
glazing ceramics, and pipes for transporting water. Today's major use of lead is in lead-acid
storage batteries. The electrical systems of vehicles, ships, and aircraft depend on such batteries
for startup, and, in some cases, batteries provide the actual motive power. It is also for
soundproofing in office buildings, schools, and hotels. It is widely used in hospitals to block
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X-ray and gamma radiation and is employed to shield against nuclear radiation both in
permanent installations and when nuclear material is being transported.
DOMESTIC SCENARIO
-

Lead production equalled approximately 82,000 tonnes in 2004, mostly from secondary
sources.

The main constraint in lead production in the country is the lack of lead ore reserves,
which necessitates large-scale imports and recycling.

Lead demand in India was estimated at 150,000 tonnes for 2004. Due to huge gap in
demand-supply, India imported nearly about 50% of its domestic demand.

The major suppliers for the imports were China, the Republic of Korea and Australia:
54%, 15% and 10% respectively.

The domestic industry is characterized by the presence of only a few players in the
primary segment. The primary lead industry in India is divided between the following
main players: Binani Industries Limited and Sterlite Industries (India) Ltd. (Hndustan
Zinc Ltd.). Due to increasing use of lead in domestic market both players are expanding
their smelting capacities for lead.

WORLD SCENARIO
-

USA, Japan, China, EU and India are the major consumers of Lead
Supply is controlled by Australia and China.

Lead in the global market is traded as soft lead, animated lead, lead alloys and copperbase scrap.

However, each of the above industry creates significant amount of environmental pollution
through emission in air and water as well as pollution caused by solid wastes. Since technologies
for metal extraction is constantly improving, newer clean technologies are likely to improve
the environmental performance of these industries.
ENVIRONMENTAL ISSUES IN NON-FERROUS PROCESSING
As a part of the materials cycle, ores and fossil fuels are extracted from the earth, processed,
and converted into metals, chemicals, and other processed materials. Wastes are generated by
the mining, mineral processing, metallurgical and chemical industries at an estimated annual
rate of over 2 billion tons. The accumulated solid wastes at both active and inactive mining
sites approach 30 billion tons. These wastes include gases, dusts, sludge or solutions, ashes,
and a variety of solid materials such as overburden, waste rocks, tailings, and slag that must
be disposed of at low cost with a minimum of environmental degradation. A large volume of
the wastes is normally disposed of at locations close to either the mining sites or processing
plants. A significant amount of tailings is disposed of in impoundments, which range in size
from a few acres to large ponds covering thousands of acres. Mining also leads to significant
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pollution of water resources around the mines and beneficiation plant sites. Man-made tailing
ponds and dams are amongst the largest structures constructed by man. They may contain as
much as 100 million tons of slurries. There are about 3500 such dams. The main effects of
mining and beneficiation on the surrounding water bodies are listed below:
-

Suspended solids and sediment from runoff and processing operations,

Acids from various processes,

Acid mine drainage (AMD) during and after operation,

Heavy metals leached from waste and tailings,

Sulphate, thiosulphate, polythionate etc. from acid drainage,

Mercury from processes or from ores,

Arsenic from oxidised mine waters,

Cyanide from leaching processes and

Oil and fuels from ancillary operations.

Even though the waste disposal issues from mining and mineral processing are not dealt with
stringency in today's context, the situation is changing fast and precautions must be taken to
both minimise and control waste disposal. Hence, the mineral or metal constituents in wastes,
whether of little or no economic value, must be amended for their environmental impact [1,21
In the non-ferrous processing sector, major environmental issues includes: fluoride emissions,
use of spent pot-lining (SPL) from the aluminium electrolytic pots, sulphur dioxide pollution,
waste water processing from sulphide smelting and recovery of lead from battery scrap. Drastic
modification of the Hall Heroult technology through the substitution of carbon electrodes and
adaptation of multi-polar cells would bring in significant improvement in the environment
performance of the aluminium production process. These would result in achieving a high
productivity, no generation of spent pot linings, reduction in carbon monoxide and green
house gases emission such as fluorocarbons and CO2. In the lead production area, the QSL
process has emerged as a serious challenger to the old pollution prone blast furnace process.
This high intensity single step process has the potential to be adapted for producing even
copper and nickel. In copper area, the Isasmelt process has been established as a high intensity
process with good environmental performance. M/s Sterlite Copper is operating a Isasmelt
reactor which is doing very well for the last few years.
MAJOR ENVIRONMENTAL PROBLEMS IN ALUMINIUM INDUSTRY
Red Mud Disposal
Red mud is an alkaline waste containing oxides of iron, silicon, titanium and water soluble
soda. It is stored in specially constructed leach proof ponds. Prior to 1985, most of the alumina
refineries in the world used to store red mud in slurry form. Indal was the first Indian alumina
refinery to adopt dry mud stacking. In this process the mud is stacked in cake form and by this
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practice the life of ponds has increased from 5 to 25 years. In addition to this, water and
caustic soda are also recovered and recycled into the process.[3] Investigators throughout the
world have developed many processes for recovery of metals from red mud. However, they
have not been successful techno-economically and have not been commercialised.
Emission of Perfluorocarbon and Hydrofluoric Acid
During aluminium production several perfluorocarbons (PFC) gases are evolved. These are
not generated during normal smelting conditions. They are only produced during brief upset
conditions that can be related to anode effect. These conditions occur when the level of the
dissolved alumina in the cell drops too low and the cryolytic bath itself begins to undergo
electrolysis. The main gases are CF4 and C2F6 but also other PFC gases such as C3F6 and C3F8
may be formed in minor quantities. Apart from PFC's, HF gas is also formed from two principal
sources. One of them is during the reaction occurring in the bath between A1F3 and moisture.
The other is hydrolysis of NaA1F4 vapour present above the bath surface. Excess emission of
HF is due to the chemical process occurring in the filter dust, involving particulate fluoride
compounds originating in the electrolytic bath and moisture present in the pot gas.
PFC Reduction
Research efforts have been continuing on the better understanding of process parameters related
to PFC generation as well as their reduction. Restructuring new and improved gas cleaning
equipment and continuous improvements in the smelter operation have contributed to
considerable reduction of the fluoride emissions from aluminium smelter. Today's smelters
use two types of electrode technologies: Soderberg and Prebaked.
(1)

Soderberg technology uses a continuous anode which is delivered to the cell (pot) in the
form of a paste and which bakes in the cell itself. The Soderberg technology has two
variants based upon how the electricity is introduced to the cell, namely Vertical Stud
Soderberg (VSS) and Horizontal Stud Soderberg (VSS)

(2)

Prebaked technology uses a multiple anode in each cell which are prebaked in a separate
facility and attached to rods that suspend the anode in the cell. New anodes are exchanged
for spent anodes. Prebaked technology has two variants referring to how alumina is
added, namely Centre Worked (CWPB) and Side Worked (SWPB).

The newest primary smelters use the centre worked prebake technology. This technology
provides use of multiple point feeders and other computerised controls for precise alumina
feeding. A key feature of CWPB plants is the closed circuit nature of the process. Fugitive
emissions from these cells are very low which is less than 2% of generated emissions.
The balance of the emission is collected inside the cell itself and carried away to a very
efficient scrubbing system. US aluminium industry achieved 46% reduction of PFC's from
1990 to 1998 through technical improvements such as reduction of frequency and also to
some extent the duration of the anode effect in pot line cells. Significant progress has also
been made in improving environmental performance through these technological
developments (Table - 1). [4}
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Table-1 CF4 Emission from Aluminium Smelter using Soderberg and

Prebake Technology
Technology type

kilograms CF4 per tonne of aluminium produced

1990

1997

CWPB

0.36

0.15

VSS

0.70

0.45

SWPB

1.88

1.34

HSS

0.36

0.46

Disposal/Use of Spent Potling/Black Mud

The cathode lining of electrolytic cells gets degenerated after a life of around 2000 days due to
adsorption of fluoride bearing materials. World over, this material is disposed in secured
landfills as it is highly toxic. Some aluminium plants in India recovers cryolite from this
waste material and recycles it back to the electrolyte cell. Black mud generated during cryolite
recovery is sold to cement plants as a fuel-cum-mineraliser.
Disposal/Use of Wet Scrubber Sludge
Aluminium electrolytic cells emit fluoride fumes. These are collected in a wet scrubber and
then neutralised with lime to produce a solid waste called "Scrubber sludge". This waste is
also disposed in secured landfills as it contains toxic fluoride chemicals. A process has been
developed to convert this hazardous waste into a product that can act as a flux in alloy steel
refining.
MAJOR ENVIRONMENTAL PROBLEMS IN COPPER INDUSTRY
Even though copper is least harmful amongst the non-ferrous metals, copper based industries
do generate a lot of industrial wastes which can contaminate the environment. Copper mining,
smelting and refining activities are associated with generation of large quantities of overburden
and mine tailings, sediments from concentrator effluents, acidic fumes and smoke from smelters,
effluent from refinery tank house etc., all from a single industrial complex. Major smelter
refinery complexes are usually set up close to mine sites, which are generally away from
urban centres. However, some of the new copper smelter refinery units based on imported
concentrates are, however, located closer to the end use markets and hence thickly populated
areas. The increased awareness of pollution problem has forced some of the units to change
the location of the new plants. Moreover, the new plants do have adequate provisions for
pollution mitigation integrated into the plant and machinery. [5]
The downstream processing and fabrication industries on the other hand are mostly located in
and around major industrial or metropolitan centres and hence deserve greater attention.
Capacity of each processing or fabrication unit is much smaller compared to a smelter and the
quantum of pollutants generated is also much lower. Moreover, majority of the units in the
unorganised sector are not fully aware of the adverse effects of environmental pollution and
the means of their control. This coupled with the apathy of the larger units add to the magnitude
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of the problem. Some of the important sources of pollution from metal processing and
fabrication units include:
Flue gases from fuel fired melting or preheating furnaces
Furnace fumes with volatile metallic and other contaminants
Liquid effluents from pickling, electroplating, etching, chemical and electro-polishing,
anti-tarnishing treatments, etc.
Solid wastes such as slag, scales, ashes, dross, slimes, floor dust, effluent sludge etc.
It may be noted that most of these wastes not only contribute to environmental pollution but
also affect the yield, productivity and even quality. It may be of interest to note that nearly
50% of the surface tarnishing problem of processed semis and fabricated components are
caused by many of the atmospheric pollutants. Moreover, generation of copper bearing wastes
mean loss of metal value and generation of waste effects yield and productivity, besides its
adverse influence on production economics.
FUTURE ROADMAP FOR NON-FERROUS PROCESSING
A broad R&D road map for improving environmental performance of non-ferrous metals
sector in India is summarized below. For convenience it is divided into four sections: Energy
targets, process development, metal unit recycling and environmental issues.
(a)

Energy Targets : Opportunities for energy savings involve the applications of technology
to measure, control and improve processes. Some will produce near net shape products
to maximize yield; others will make products with optimum as-processed microstructure
and properties to avoid traditional post processing heat treatments. Other opportunities
will relate to the capture and re-use of the energy lost in current processes. Some
opportunities, related primarily to cost and the environment, involve the production and
recycling of metal units. A comprehensive R&D programme should be taken up to reduce
energy consumption in this sector which in turn will significantly reduce environmental
pollution.

(b)

Process Development : Research priorities and technical barriers to success should be

identified for each of major minerals and metallurgical processes. Where appropriate,
targets and timelines for critical technologies should be established. Technical
developments are needed to create a furnace design that will maximize the use of energy
inputs, optimize productivity, and allow flexibility in charge materials and fuels.

(c)

Metal Recycling : Increased recycling of by-product wastes requires significant advances

in technology and presents one of the largest opportunities for further metal recovery.
Current technologies offer limited ability to use fine materials in large quantities.
However, more R&D work is needed to develop agglomerates with the required strength
and properties. Although uses for low-metal bearing wastes, such as slag, are well
developed, they represent most of the metal units lost in the product life cycle.
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(d) Environmental Issues: Despite significant progress, metals-related environmental issues

will continue to be the focus of policy debates, legislation, and regulation. Further
improvements in pollution prevention technologies are needed for metallurgical plants
to reduce costs, improve profitability, and facilitate compliance with changing
government regulations. Increased priority should be given for the development of cleaner
technologies.
CONCLUDING REMARKS
In the non-ferrous metal extraction industry in India, there have been significant improvements
in the technological front to achieve better means of processing both from a cost and an
environmental viewpoint. However, during the next decade the non-ferrous sector should put
more emphasis on development and use of cleaner technologies as well as implementing process
integration and optimisation measures in the existing plants. The full benefits of pollution
mitigation should be recognised by the resource developers and investors in the interest of the
community, as well as for the long-term benefits of the industry. Many experts now believe
that industrial participation should be on the basis of encouragement of open debate with
transparency achieved through exchanging the knowledge and views of all parties that have
an interest in the industrial development of our country.
REFERENCES
(1)

Mehrotra, S. P. and Bandopadhyay A., In Proc. Int. Sym. Proc. Chem. Min. Met. Industries
wastes (POCMIW-2003), Bhubaneswar, India, August 27-29, 2003, 147-155,

(2)

Bandopadhyay, A., In Monograph on 'Min. Proc. Engg.', Eds. V. N. Misra, G. D. Yadav,

and K. S. Rao, Indian Institute of Chemical Engineers, Kolkata, 2003.

(3)

Parbat, R. N., In Proc. Nat. Sem. Environ. Waste Manag. Non-ferrous Metallurgical
industries (EWM-1998), Jamshedpur, India, January 29-30, 1998, 3-10.

(4)

Gorai, B., Jana R. K. and Premchand, Proc. Nat. Sem. Cleaner technologies for
metallurgical industries (EWM-2002), Jamshedpur, India, January 24-25, 2002, 129138.

(5)

Vishwanathan, M., Proc. Nat. Sem. Environ. Waste management Non-ferrous

Metallurgical industries (EWM-1998), Jamshedpur, India, January 29-30, 1998, 67-78.

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