Scribd Logo
Upload

Welcome to Scribd!

  • 869 views

    Lab Report CHM361

    Uploaded by

    Nurin Izzati Zulkifli
    This document contains the results of experiments analyzing the coordination compound potassium tris(oxalato)ferrate(III) trihydrate, K3[Fe(C2O4)3].3H2O. A group of 3 students synthesized the compound and determined its percentage of ligands. They obtained an 81.3% yield and used titration with potassium permanganate to find that the compound contains 25.40 mL of ligands on average per 0.2 grams of sample.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Lab Report CHM361

    Uploaded by

    Nurin Izzati Zulkifli
    869 views6 pages
    This document contains the results of experiments analyzing the coordination compound potassium tris(oxalato)ferrate(III) trihydrate, K3[Fe(C2O4)3].3H2O. A group of 3 students synthesized the compound and determined its percentage of ligands. They obtained an 81.3% yield and used titration with potassium permanganate to find that the compound contains 25.40 mL of ligands on average per 0.2 grams of sample.

    Original Title

    Lab Report CHM361.docx

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document contains the results of experiments analyzing the coordination compound potassium tris(oxalato)ferrate(III) trihydrate, K3[Fe(C2O4)3].3H2O. A group of 3 students synthesized the compound and determined its percentage of ligands. They obtained an 81.3% yield and used titration with potassium permanganate to find that the compound contains 25.40 mL of ligands on average per 0.2 grams of sample.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    869 views6 pages

    Lab Report CHM361

    Uploaded by

    Nurin Izzati Zulkifli
    This document contains the results of experiments analyzing the coordination compound potassium tris(oxalato)ferrate(III) trihydrate, K3[Fe(C2O4)3].3H2O. A group of 3 students synthesized the compound and determined its percentage of ligands. They obtained an 81.3% yield and used titration with potassium permanganate to find that the compound contains 25.40 mL of ligands on average per 0.2 grams of sample.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 6
    At a glance
    Powered by AI
    The document discusses the synthesis and analysis of the coordination compound K3[Fe(C2O4)3].3H2O.

    Three experiments were conducted: 1) Predicting molecular shape and polarity using VSEPR theory, 2) Synthesis of K3[Fe(C2O4)3].3H2O, and 3) Determination of the percentage of ligands in K3[Fe(C2O4)3].3H2O.

    The percentage yield of K3[Fe(C2O4)3].3H2O was determined to be 81.3% based on actual and theoretical yield calculations.

    OCTOBER 2020 - FEBRUARY 2021

    Universiti Teknologi MARA


    Cawangan Pahang

    CHM361
    Inorganic Chemistry

    ANALYSIS OF COORDINATION COMPOUND


    K3[Fe(C2O4)3].3H2O

    Group Members :

    No
    Name Student ID
    .
    1 NURIN IZZATI BINTI MOHD ZULKIFLI 2018213768
    2 NURUL AINA ZULAIKHA BINTI ARBAIN 2018280422
    3 NURUL AQILLAH BINTI ZOLKEFLE 2018410938

    Group : AS1205F

    Lecturer’s Name : DR. NORSHAHIDATUL AKMAR BINTI MOHD SHOHAIMI

    Date Submitted : JANUARY 2021


    OCTOBER 2020 - FEBRUARY 2021

    CRITERIA FULL OBTAINED

    Procedure 2%

    Results / Data / Observation (Data Sheet) 2%

    Data Analysis / Justification / Validation 4%

    Question 2%

    Discussion 2%

    Conclusion 1%

    Format 2%

    Data Sheet EXP 1 & EXP 2 5%

    Total 20%
    OCTOBER 2020 - FEBRUARY 2021

    EXPERIMENT 1
    Predicting Molecular Shape and Polarity Using VSEPR Theory

    RESULT
    OCTOBER 2020 - FEBRUARY 2021

    EXPERIMENT 2
    Synthesis of Potassium Tris(oxalato)ferrate (Iii) Trihydrate, K3[Fe(C2O4)3].3H2O

    RESULT

    Mass of ferrous ammonium sulphate, Fe(NH4)2(SO4)2.6H2O 4.0044 g

    Mass of filter paper 0.4688 g


    Mass of filter paper + crystals of potassium tris(oxalato)ferrate
    4.5403 g
    (III) trihydrate, K3[Fe(C2O4)3].3H2O

    CALCULATION

    Chemical equations involved,


    (1) Fe(NH4)2(SO4)2.6H2O (aq) + H2C2O4 (aq) → FeC2O4 (s) + H2SO4 (aq) + (NH4)2SO4 (aq) + 6H2O (l)
    (2) Fe3+ + 3OH- → Fe(OH)3 (s)
    (3) 3K2C2O4 (aq) + 2Fe(OH)3 (s) + 3H2C2O4 (aq) → 2K3[Fe(C2O4)3].3H2O (aq) + 3H2O (l)

    1) Mass of Fe(NH4)2(SO4)2.6H2O
    Mass of Fe ( NH4 ) 2 ( SO4 ) 2 .6 H 2 O = 4.0044 g

    2) Moles of Fe(NH4)2(SO4)2.6H2O
    4.0044 g
    Moles of Fe ( NH 4 )2 ( SO4 )2 .6 H 2 O = = 0.0102 mol
    392.13 g mol-1

    3) Actual yield of K3[Fe(C2O4)3].3H2O (mass)

    Actual yield of K3 [ Fe ( C2 O 4 )3 ] .3 H 2 O = 4.5403 g - 0.4688 g = 4.0715 g

    4) Theoretical yield of K3[Fe(C2O4)3].3H2O (moles)


    Fe(OH)3,

    1 mole of Fe ( NH 4 ) 2 ( SO 4 ) 2 .6 H2 O : 1 mole of Fe ( OH )3

    Moles of Fe (OH)3 = 0.0102 mo l


    OCTOBER 2020 - FEBRUARY 2021

    H2C2O4,
    10 g 1000 mL
    Concentration of H2 C2 O 4 = × = 100 g / L
    100 mL 1 L
    100 gL
    Molarity of H2 C2 O 4 = = 1.11 mol L-1
    90.03 gmol
    Moles of H 2 C2 O 4 = 1.11 mol L-1 × 0.015 L = 0.0167 mol

    K2C2O4,

    Moles of K2 C2 O 4 = 1 mol L-1 × 0.015 L = 0.015 mol

    Fe(OH)3 was the limiting reagent.

    2 moles of Fe( OH)3 : 2 moles of K 3 [ Fe ( C2 O4 )3 ] .3 H2 O

    0.0102 mol of Fe(OH) 3 : 0.0102 mol of K 3 [ Fe ( C2 O 4 )3 ] .3 H 2 O

    Moles of K3 [ Fe ( C2 O4 )3 ] .3 H2 O = 0.0102 mol

    5) Theoretical yield of K3[Fe(C2O4)3].3H2O (mass)

    Theoretical yield of K 3 [ Fe ( C2 O4 )3 ] .3 H2 O = 0.0102 mol × 491.24 g mol-1


    = 5.011 g

    6) Percent yield of K3[Fe(C2O4)3].3H2O


    Actual yield
    Percent yield of K 3 [ Fe ( C2 O 4 )3 ] .3 H 2 O = × 100
    Theoretical yield
    4.0715 g
    = × 100 = 81.3 %
    5.011 g
    OCTOBER 2020 - FEBRUARY 2021

    EXPERIMENT 3
    Determination of the Percentage of Ligands in K3[Fe(C2O4)3].3H2O

    RESULT

    A. Standardization of Potassium Permanganate Solution

    Rough Accurate titrations


    estimation 1 2
    Final burette reading (mL) 22.20 43.30 21.20
    Initial burette reading (mL) 0.30 22.20 0.10
    Vol. of KMnO4 used (mL) 21.90 21.10 21.10
    Mean vol. of KMnO4 used (mL) 21.10

    B. Determination of the Percentage of Ligands in K3[Fe(C2O4)3].3H2O

    Rough Accurate titrations


    estimation 1 2
    Mass of K3[Fe(C2O4)3].3H2O (g) 0.2013 0.2006 0.2008
    Final burette reading (mL) 25.80 28.40 30.40
    Initial burette reading (mL) 1.50 3.00 5.00
    Vol. of KMnO4 used (mL) 24.30 25.40 25.40
    Mean vol. of KMnO4 used (mL) 25.40

    You might also like