SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 1. IDENTIFICATION

Product name : Eastman(TM) 1,4-Diisopropylbenzene

Product code : 05231-00, E0523101, S0523101, S052310S, S0523102,

S05231H2, S0523105

Manufacturer or supplier's details

Company name of supplier : Eastman Chemical Company

Address : 200 South Wilcox Drive

Kingsport TN 37660-5280

Telephone : (423) 229-2000

Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

Recommended use of the chemical and restrictions on use

Recommended use : Chemical intermediate

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Flammable liquids : Category 4

Skin irritation : Category 2

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H227 Combustible liquid.

H315 Causes skin irritation.

Precautionary Statements :
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

P332 + P313 If skin irritation occurs: Get medical advice/ atten-

tion.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients
Chemical name CAS-No. Concentration (% w/w)
p-diisopropylbenzene 100-18-5 100

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.

Treat symptomatically.
If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes.
Wash contaminated clothing before re-use.
Get medical attention.
Thoroughly clean shoes before reuse.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : Seek medical advice.

Most important symptoms : Causes skin irritation.

and effects, both acute and Causes skin irritation.
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)

Dry chemical
Water spray

Unsuitable extinguishing : Water spray jet

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

media

Specific hazards during fire : Water may be ineffective.

fighting The product will float on water and can be reignited on surface
water.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Further information : Use water spray to cool unopened containers.

Special protective equipment : Wear an approved positive pressure self-contained breathing

for fire-fighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Local authorities should be advised if significant spillages
gency procedures cannot be contained.

Environmental precautions : Avoid release to the environment.

Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
After cleaning, flush away traces with water.
Eliminate all ignition sources if safe to do so.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : None known.

fire and explosion

Advice on safe handling : Avoid inhalation of vapor or mist.

Avoid contact with skin, eyes and clothing.
Ensure adequate ventilation.
Wash thoroughly after handling.
Keep away from fire (No Smoking).
Keep away from fire, sparks and heated surfaces.
Do not use sparking tools.

Conditions for safe storage : Keep container closed when not in use.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : Ensure adequate ventilation.

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Hand protection

Remarks : Wear suitable gloves.

Eye protection : Safety glasses

Protective measures : Remove respiratory and skin/eye protection only after vapors
have been cleared from the area.
Ensure that eye flushing systems and safety showers are
located close to the working place.
Use personal protective equipment as required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : colorless

Odor : aromatic

Odor Threshold : not determined

pH : not determined

Melting point/range : 1 °F / -17 °C

Boiling point/boiling range : 428 °F / 220 °C

Flash point : 163 °F / 73 °C

Method: Seta closed cup

Evaporation rate : not determined

Upper explosion limit / Upper : 5.3 %(V)

flammability limit

Lower explosion limit / Lower : 0.64 %(V)

flammability limit

Vapor pressure : 67 hPa (248 °F / 120 °C)

Relative vapor density : 5.6

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Relative density : 0.85 (73 °F / 23 °C)

Solubility(ies)
Water solubility : negligible

Partition coefficient: n- : log Pow: 5.71

octanol/water

Autoignition temperature : 790 °F / 421 °C

Method: ASTM E659

Decomposition temperature : Method: DTA

No exotherm to boiling

Viscosity
Viscosity, dynamic : not determined

Viscosity, kinematic : not determined

Explosive properties : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Stable

tions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Carbon dioxide (CO2)

products Carbon monoxide

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Ingredients:

p-diisopropylbenzene:
Acute oral toxicity : LD50 Oral (Rat): > 3,200 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: Not classified

Acute inhalation toxicity : LC50 (Rat): > 5.6 mg/l

Exposure time: 4 h
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: (highest concentration tested)
Read-across from a similar material

Acute dermal toxicity : LD50 Dermal (Guinea pig): > 17,120 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks : Causes skin irritation.

Ingredients:

p-diisopropylbenzene:
Species : Guinea pig
Exposure time : 24 h
Result : Skin irritation

Serious eye damage/eye irritation

Not classified based on available information.
Product:
Remarks : No data available

Ingredients:

p-diisopropylbenzene:
Species : Rabbit
Result : very slight

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Ingredients:

p-diisopropylbenzene:
Test Type : Skin Sensitization
Species : Guinea pig
Result : none

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
Not classified based on available information.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Information on likely routes of exposure

Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: Causes skin irritation.

Eye contact : Remarks: None known.

Ingestion : Remarks: None known.

Further information

Product:
Remarks : None known.

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:

p-diisopropylbenzene:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 0.91 mg/l
Exposure time: 96 h
Remarks: Read-across from a similar material

LC50 (Oryzias latipes (Orange-red killifish)): 0.707 mg/l

Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.392 mg/l
aquatic invertebrates Exposure time: 48 h
Remarks: Read-across from a similar material

Toxicity to algae : ErC50 (Selenastrum capricornutum (green algae)): 2.7 mg/l

Exposure time: 72 h
Remarks: Read-across from a similar material

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.063 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Remarks: Read-across from a similar material

Persistence and degradability

Ingredients:

p-diisopropylbenzene:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 0 %
Exposure time: 21 d

Chemical Oxygen Demand : 780 mg/g

(COD)

Bioaccumulative potential

Ingredients:

p-diisopropylbenzene:
Bioaccumulation : Bioconcentration factor (BCF): 503

Mobility in soil
No data available
Other adverse effects
No data available

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
UN/ID/NA number : NA 1993
Proper shipping name : Combustible liquid, n.o.s.
(p-diisopropylbenzene)
Class : CBL
Packing group : III
Labels : None
ERG Code : 128
Marine pollutant : no
Remarks : Above applies only to containers over 119 gallons or 450
liters. Not regulated if shipped in packages less than or equal
to 119 gallons (450 liters).

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Fire Hazard

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

Acute Health Hazard

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer,
birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TCSI : On the inventory, or in compliance with the inventory

TSCA : On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH / 2
2 FLAMMABILITY
Instability

2
Health

2 0
PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
Special hazard. cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -

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SAFETY DATA SHEET

Eastman(TM) 1,4-Diisopropylbenzene

Version Revision Date: SDS Number: Date of last issue: 09/12/2018

2.2 12/04/2018 150000000035 Date of first issue: 09/06/2016
PRD SDSUS / Z8 / 0001

United Nations Recommendations on the Trans port of Dangerous Goods ; vP vB - Very Persistent
and Very Bioaccumulative

Revision Date : 12/04/2018

The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

US / Z8

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