Revision date: 05/01/2018 Revision: 9

SAFETY DATA SHEET

GPC8

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name GPC8

Product number R051 EV

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses General Glutaraldehyde and Quaternary Ammonium Disinfectant for animal hygiene.

1.3. Details of the supplier of the safety data sheet

Supplier
Evans Vanodine International
Brierley Road
Walton Summit
Preston. UK. PR5 8AH
Tel: 01772 322 200
Fax: 01772 626 000
[email protected]

1.4. Emergency telephone number

Emergency telephone New Safety Data Sheets - 8.30am to 4.45pm - 01772 322 200 - Mon to Fri. (Also available
24/7 from our website www.evansvanodine.co.uk) Technical Advice - 8.30am to 4.45pm -
01772 318 818 - Mon to Fri

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 2 - H330 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Resp.
Sens. 1 - H334 Skin Sens. 1 - H317

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 3 - H412

2.2. Label elements

Pictogram

Signal word Danger

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Hazard statements H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P102 Keep out of reach of children.

P261 Avoid breathing vapour/ spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P270 Do not eat, drink or smoke when using this product.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P315 Get immediate medical advice/ attention.
P501 Dispose of contents/ container in accordance with local regulations.

Contains GLUTARAL

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

GLUTARAL 10-15%
CAS number: 111-30-8 EC number: 203-856-5
M factor (Acute) = 1
Spec Conc Limits :- Skin Corr. 1B (H314)>=10 %, Skin Irrit. 2 (H315) >=0.5 % <10%, Eye Dam. 1 (H318)>=2 % < 10%, Eye
Irrit. 2 (H319) >=0.5 % <2%, STOT SE 3 (H335) >=0.5%, Skin Sens. 1 (H317) >=0.5%

Classification
Acute Tox. 3 - H301
Acute Tox. 2 - H330
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335
Aquatic Acute 1 - H400
Aquatic Chronic 2 - H411

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C12-15 ALCOHOL ETHOXYLATE (7EO) 5-10%

CAS number: 68131-39-5
M factor (Acute) = 1

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318
Aquatic Acute 1 - H400

DIDECYL DIMETHYL AMMONIUM CHLORIDE 3-5%

CAS number: 7173-51-5 EC number: 230-525-2
M factor (Acute) = 10

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 2 - H411

PROPAN-2-OL 1-3%
CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01-
2119457558-25-xxxx

Classification
Flam. Liq. 2 - H225
Eye Irrit. 2 - H319
STOT SE 3 - H336

PHOSPHORIC ACID 0.1-1%

CAS number: 7664-38-2 EC number: 231-633-2
Spec Conc Limits :- Skin Corr. 1B (H314) ≥ 25%, Skin Irrit. 2 (H315) >10% <25%, Eye Irrit. 2 (H319) >10%

Classification
Skin Corr. 1B - H314
Eye Dam. 1 - H318

METHANOL 0.1-1%
CAS number: 67-56-1 EC number: 200-659-6
Spec Conc Limits :- STOT SE 1 (H370) >=10%, STOT SE 2 (H371) >3% <10%

Classification
Flam. Liq. 2 - H225
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370

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The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments Please note that the % Range values quoted above are given for guidance in assessment of
hazard & should not be interpreted as specifications.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Keep affected person warm and at rest. Get
medical attention immediately.

Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Give plenty of water to drink. Get
medical attention immediately.

Skin contact Wash with plenty of water. Get medical attention promptly if symptoms occur after washing.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Get medical attention immediately. Continue to rinse.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Irritation of nose, throat and airway. Coughing, chest tightness, feeling of chest pressure.

Ingestion May cause stomach pain or vomiting. May cause chemical burns in mouth and throat.

Skin contact Burning pain and severe corrosive skin damage. May cause serious chemical burns to the
skin.

Eye contact Severe irritation, burning and tearing. Prolonged contact causes serious eye and tissue
damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Thermal decomposition or combustion products may include the following substances: Toxic
gases or vapours.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing, gloves, eye and face protection. Wear respiratory protection. For
personal protection, see Section 8.

6.2. Environmental precautions

Environmental precautions Avoid release to the environment. Spillages or uncontrolled discharges into watercourses
must be reported immediately to the Environmental Agency or other appropriate regulatory
body.

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6.3. Methods and material for containment and cleaning up

Methods for cleaning up Small Spillages: Flush away spillage with plenty of water. Large Spillages: Contain and
absorb spillage with sand, earth or other non-combustible material. Collect and place in
suitable waste disposal containers and seal securely.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Wear Respiratory protection compliant with EN 141 (A2 B2 E2 K2 Hg-p3). Wear protective
clothing, gloves, eye and face protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep only in the original container in a cool, well-ventilated place. Store away from the
following materials: Oxidising materials. (eg Hypochlorite / Bleach)

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

Usage description See Product Information Sheet & Label for detailed use of this product.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
GLUTARAL
Long-term exposure limit (8-hour TWA): WEL 0.05 ppm 0.2 mg/m³
Short-term exposure limit (15-minute): WEL 0.05 ppm 0.2 mg/m³
Sen
PROPAN-2-OL
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³
Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
PHOSPHORIC ACID
Long-term exposure limit (8-hour TWA): WEL 1 mg/m³
Short-term exposure limit (15-minute): WEL 2 mg/m³
METHANOL
Long-term exposure limit (8-hour TWA): WEL 200 ppm 266 mg/m³
Short-term exposure limit (15-minute): WEL 250 ppm 333 mg/m³
Sk
WEL = Workplace Exposure Limit
Sen = Capable of causing occupational asthma.
Sk = Can be absorbed through skin.

8.2. Exposure controls

Protective equipment

Appropriate engineering This product must not be handled in a confined space without adequate ventilation.
controls

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Eye/face protection The following protection should be worn: Chemical splash goggles or face shield.

Hand protection Wear protective gloves. Polyvinyl chloride (PVC).

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Respiratory protection Wear Respiratory protection compliant with EN 141 (A2 B2 E2 K2 Hg-p3).

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Clear. Orange. Red.

Odour Characteristic. Pungent. Glutaraldehyde.

pH pH (concentrated solution): 1.70

Melting point -2°C

Initial boiling point and range 101°C @ 760 mm Hg

Flash point Boils without flashing.

Relative density 1.035 @ 20°C

Solubility(ies) Soluble in water.

9.2. Other information

Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Reacts with alkalis and generates heat.

10.2. Chemical stability

Stability No particular stability concerns.

10.3. Possibility of hazardous reactions

Possibility of hazardous See sections 10.1,10.4 & 10.5
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat. >30°C

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition When heated, vapours/gases hazardous to health may be formed.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

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Toxicological effects We have not carried out any animal testing for this product. Any ATE figures quoted below are
from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate)
Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer.

Acute toxicity - oral

Notes (oral LD₅₀) Classification criteria has been met – Product is classified as Harmful if Swallowed.

ATE oral (mg/kg) 610.65

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

ATE dermal (mg/kg) 160,282.34

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Fatal if inhaled.

ATE inhalation (gases ppm) 784.99

ATE inhalation (vapours mg/l) 3.92

ATE inhalation (dusts/mists 0.39

mg/l)

SECTION 12: Ecological Information

Ecotoxicity The product contains a substance which is very toxic to aquatic organisms. Harmful to aquatic
life with long lasting effects. The product may affect the acidity (pH) of water which may have
hazardous effects on aquatic organisms.

12.1. Toxicity
Toxicity We have not carried out any Aquatic testing, therefore we have no Aquatic Toxicity Data
specifically for this product. The Aquatic Toxicity Data, where provided by the raw material
manufacturer for ingredients with aquatic toxicity, can be made available on request. Very
toxic to aquatic organisms.

12.2. Persistence and degradability

Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents.

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil

Mobility Not known.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

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Disposal methods Discharge used solutions to drain. Small amounts (less than 5 Litres) of unwanted product
may be flushed with water to sewer. Larger volumes must be sent for disposal as special
waste. Rinse out empty container with water and consign to normal waste.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3265

UN No. (IMDG) 3265

UN No. (ICAO) 3265

14.2. UN proper shipping name

Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (glutaraldehyde)
(ADR/RID)

Proper shipping name (IMDG) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (glutaraldehyde)

Proper shipping name (ICAO) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (glutaraldehyde)

14.3. Transport hazard class(es)

ADR/RID class Class 8: Corrosive substances.

ADR/RID label 8

IMDG class Class 8: Corrosive substances.

ICAO class/division Class 8: Corrosive substances.

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-B

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not relevant. for a packaged product.
Annex II of MARPOL 73/78
and the IBC Code

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Safety Data Sheet prepared in accordance with REACH Commission Regulation (EU) No
2015/830 (which amends Regulation (EC) No 453/2010 & 1907/2006).
The product is as classified under GHS/CLP- Regulation (EC) No 1272/2008 classification,
labelling & packaging of substances & mixtures.
Ingredients are listed with classification under GHS/CLP - Regulation (EC) No 1272/2008
classification, labelling & packaging of substances & mixtures.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out as not applicable as this product is a mixture.

SECTION 16: Other information

Abbreviations and acronyms PBT: Persistent, Bioaccumulative and Toxic substance.

used in the safety data sheet vPvB: Very Persistent and Very Bioaccumulative.
ATE: Acute Toxicity Estimate.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
IMDG: International Maritime Dangerous Goods.
ICAO-TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
GHS: Globally Harmonized System.
Spec Conc Limits = Specific Concentration Limits.

Classification abbreviations Acute Tox. = Acute toxicity

and acronyms Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Eye Dam. = Serious eye damage
Eye Irrit. = Eye irritation
Eye Irrit. = Eye irritation
Resp. Sens. = Respiratory sensitisation
Skin Corr. = Skin corrosion
Skin Irrit. = Skin irritation
Skin Sens. = Skin sensitisation
STOT SE = Specific target organ toxicity-single exposure

Key literature references and Material Safety Data Sheet, Miscellaneous manufacturers. CLP Class - Table 3.1 List of
sources for data harmonised classification and labeling of hazardous substances. ECHA - C&L Inventory
database.

Classification procedures Calculation Method.

according to Regulation (EC)
1272/2008

Revision comments Change in product classification due to the change in classification of a raw material.
(Changes made to sections 2,3 & 16)

Revision date 05/01/2018

Revision 9

SDS status The Hazard Statements listed below in this Section No 16 relate to the Raw Materials
(Ingredients) in the Product (as listed in Section 3) and NOT the product itself. For the Hazard
Statements relating to this Product see Section 2.

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Hazard statements in full H225 Highly flammable liquid and vapour.

H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H370 Causes damage to organs .
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

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