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SAFETY DATA SHEET

CREOLIN ECO
Commission Regulation (EU) No 2015/830 of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CREOLIN ECO

Product number CREOLIN ECO

Container size 1L, 5L, 25L, 200L

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Detergent.

1.3. Details of the supplier of the safety data sheet

Supplier COVENTRY CHEMICALS LTD
WOODHAMS RD
SISKIN DRIVE
COVENTRY
CV3 4FX
Tel: +44 (0) 02476639739
Fax: +44 (0) 02476639717
Email: [email protected]

Contact person For content of safety data sheet:, [email protected], [email protected]

1.4. Emergency telephone number

Emergency telephone +44 (0) 1865407333 (Strictly for emergencies only: incidents involving damage to human
health and/or the environment)

National emergency telephone In case of a medical emergency following exposure to a chemical call NHS Direct in England
number or Wales 0845 46 47 or NHS 24 in Scotland 08454 24 24 24

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318

Environmental hazards Not Classified

2.2. Label elements

Pictogram

Signal word Danger

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Hazard statements EUH208 Contains ALPHA-METHYLCINNAMALDEHYDE. May produce an allergic reaction.

H315 Causes skin irritation.
H318 Causes serious eye damage.

Precautionary statements P102 Keep out of reach of children.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container in accordance with local regulations.

Contains QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C12-16-ALKYLDIMETHYL,

CHLORIDES, TETRASODIUM ETHYLENE DIAMINE TETRAACETATE

Detergent labelling < 5% disinfectants, < 5% EDTA and salts thereof, < 5% perfumes, < 5% phosphates

Supplementary precautionary P264 Wash contaminated skin thoroughly after handling.

statements P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C12- 1-5%

16-ALKYLDIMETHYL, CHLORIDES
CAS number: 68424-85-1 EC number: 270-325-2
M factor (Acute) = 1

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 C;R34 Xn;R21/22 N;R50
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400

TETRASODIUM ETHYLENE DIAMINE TETRAACETATE 1-5%

CAS number: 64-02-8 EC number: 200-573-9 REACH registration number: 01-
2119486762-27-XXXX

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 Xn;R22 Xi;R41
Acute Tox. 4 - H332
Eye Dam. 1 - H318

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ALPHA-METHYLCINNAMALDEHYDE <1%
CAS number: 101-39-3 EC number: 202-938-8

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Sens. 1 - H317 R43.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Provide eyewash station.

Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical
attention if any discomfort continues.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse
mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Rinse immediately with plenty of water. Remove contaminated clothing. Get medical attention
if irritation persists after washing.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention if symptoms are severe
or persist after washing. Show this Safety Data Sheet to the medical personnel.

4.2. Most important symptoms and effects, both acute and delayed
General information Provide eyewash station.

Skin contact Prolonged contact may cause redness, irritation and dry skin.

Eye contact The product is irritating to eyes and skin. Prolonged or repeated exposure may cause the
following adverse effects: Irritation and redness, followed by blurred vision. Corneal damage.
Risk of serious damage to eyes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.
Foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Toxic gases or vapours.

5.3. Advice for firefighters

Protective actions during Control run-off water by containing and keeping it out of sewers and watercourses.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

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Personal precautions For personal protection, see Section 8. Treat the spilled material according to the instructions
in the clean-up section. Take care as floors and other surfaces may become slippery.

6.2. Environmental precautions

Environmental precautions Collect and dispose of spillage as indicated in Section 13. Do not discharge into drains or
watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if safe to do so. Absorb in vermiculite, dry sand or earth and place into containers.
Flush contaminated area with plenty of water. Avoid the spillage or runoff entering drains,
sewers or watercourses.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Provide adequate ventilation. Avoid spilling. Avoid contact with skin and eyes. Wear protective
clothing as described in Section 8 of this safety data sheet. Avoid breathing vapour/spray. Do
not mix with other household chemical products. Do not mix with acid.

Advice on general Good personal hygiene procedures should be implemented. Do not eat, drink or smoke when
occupational hygiene using this product. Wash skin thoroughly after handling. Take off contaminated clothing and
wash it before reuse. Use appropriate hand lotion to prevent defatting and cracking of skin.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Store at room
temperature. Keep out of the reach of children. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

TETRASODIUM ETHYLENE DIAMINE TETRAACETATE (CAS: 64-02-8)

DNEL General population - Oral; Long term systemic effects: 25 mg/kg/day

General population - Inhalation; Long term local effects: 0.6 mg/m³
General population - Inhalation; Short term local effects: 1.2 mg/m³
Workers - Inhalation; Long term local effects: 1.5 mg/m³
Workers - Inhalation; Short term local effects: 3 mg/m³

PNEC - Fresh water; 2.2 mg/l

- marine water; 0.22 mg/l
- Intermittent release; 1.2 mg/l
- STP; 43 mg/l
- Soil; 0.72 mg/kg

8.2. Exposure controls

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Protective equipment

Appropriate engineering Provide adequate ventilation.

controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Unless the assessment indicates a higher degree of protection is
required, the following protection should be worn: Tight-fitting safety glasses. Personal
protective equipment for eye and face protection should comply with European Standard
EN166.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. It is recommended that gloves are made
of the following material: Polyvinyl chloride (PVC). Rubber (natural, latex). Neoprene. Nitrile
rubber. Polyethylene. To protect hands from chemicals, gloves should comply with European
Standard EN374.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact. Use appropriate
protection hand lotion to prevent defatting and cracking of skin.

Hygiene measures When using do not eat, drink or smoke. Good personal hygiene procedures should be
implemented. Wash hands and any other contaminated areas of the body with soap and
water before leaving the work site. Use appropriate skin cream to prevent drying of skin.

Respiratory protection Respiratory protection not required.

Environmental exposure Avoid releasing into the environment.

controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Dark brown.

Odour Phenolic.

pH pH (concentrated solution): 11.00

Relative density ~ 1.020

Solubility(ies) Soluble in water.

Explosive under the influence Not considered to be explosive.

of a flame

Comments Information given is applicable to the product as supplied.

9.2. Other information

Other information Not relevant.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

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Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Not applicable.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid exposure to high temperatures or direct sunlight.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects No information available.

Acute toxicity - oral

Notes (oral LD₅₀) Calculation method.

ATE oral (mg/kg) 9,471.89

Acute toxicity - dermal

Notes (dermal LD₅₀) Calculation method.

ATE dermal (mg/kg) 41,600.0

Acute toxicity - inhalation

ATE inhalation (dusts/mists 207.0
mg/l)

Skin corrosion/irritation
Skin corrosion/irritation Irritating to skin. Calculation method.

Serious eye damage/irritation

Serious eye damage/irritation Causes serious eye damage. Calculation method.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

General information This product has low toxicity.

Ingestion May cause irritation. Symptoms following overexposure may include the following: Stomach
pain. Nausea, vomiting. Diarrhoea.

Skin contact Skin irritation should not occur when used as recommended. Prolonged or repeated exposure
may cause the following adverse effects: Irritation. Redness. Dryness and/or cracking. Mild
dermatitis, allergic skin rash.

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Eye contact Irritating to eyes. May cause serious eye damage. Severe irritation, burning, tearing and
blurred vision. Corneal damage.

Toxicological information on ingredients.

QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C12-16-ALKYLDIMETHYL, CHLORIDES

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 397.5

mg/kg)

Species Rat

ATE oral (mg/kg) 397.5

Acute toxicity - dermal

ATE dermal (mg/kg) 1,560.0

SECTION 12: Ecological information

Ecotoxicity There are no data on the ecotoxicity of this product. Not regarded as dangerous for the
environment.

12.1. Toxicity
Toxicity The product contains a substance which is harmful to aquatic organisms.

Ecological information on ingredients.

QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C12-16-ALKYLDIMETHYL, CHLORIDES

Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - fish LC₅₀, 96 hours: 0.85 – 1.2 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 0.02 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic LC₅₀, 96 hours: 0.06 mg/l, Algae

plants

12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product. The surfactant(s) contained in this
product complies(comply) with the biodegradability criteria as laid down in Regulation (EC)
No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to them at their direct
request, or at the request of a detergent manufacturer.

Ecological information on ingredients.

QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C12-16-ALKYLDIMETHYL, CHLORIDES

Persistence and The substance is readily biodegradable.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

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12.4. Mobility in soil

Mobility The product is water-soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Do not discharge into drains or watercourses or onto the ground.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Reuse or recycle products wherever possible.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).

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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 453/2010 of 20 May 2010.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative
occupational exposure limit values in implementation of Council Directive 98/24/EC on the
protection of the health and safety of workers from the risks related to chemical agents at
work (as amended).
Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list
of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and
Directive 91/689/EEC on hazardous waste with amendments.
Commission Regulation (EU) No 2015/830 of 28 May 2015.

Guidance Workplace Exposure Limits EH40.

ECHA Guidance on the Application of the CLP Criteria.
ECHA Guidance on the compilation of safety data sheets.
COSHH Essentials.
Technical Guidance WM2: Hazardous Waste.

15.2. Chemical safety assessment

No information available.

SECTION 16: Other information

Abbreviations and acronyms DNEL: Derived No Effect Level.

used in the safety data sheet PBT: Persistent, Bioaccumulative and Toxic substance.
PNEC: Predicted No Effect Concentration.
MARPOL 73/78: International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978.

Revision comments New revision number applied to comply with Commission Regulation (EU) No 2015/830 Of
28 May 2015’ NOTE: Lines within the margin indicate significant changes from the previous
revision.

Revision date 14/12/2018

Revision 1

SDS number 21961

Hazard statements in full H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
EUH208 Contains ALPHA-METHYLCINNAMALDEHYDE. May produce an allergic reaction.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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