Code No: R05211802 R05 Set No.

2
II B.Tech I Semester Examinations,December 2011
THERMODYNAMICS AND KINETICS
Metallurgy And Material Technology
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
?????

1. (a) Define the following :

i. Heat
ii. Work
iii. Internal Energy.
iv. Heat capacity.
(b) State and explain the first law of thermodynamics and its applications. [8+8]

2. (a) Explain the practical importance of Classiuus - Clapeyron equation.

(b) List the assumptions made in deriving the integrated form of the clausius
clapeyron equation. [16]

3. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]

4. (a) Draw a potential energy diagram for an uncatalyzed reaction. Compare it with
a potential energy diagram for a catalyzed reaction. In each case indicate ∆H
for the activated complex.
(b) Discuss the various methods available for determining the order of reaction.
[16]

5. Explain the following

(a) Tabular method of recording thermodynamic data

(b) Application of third law of thermodynamics
(c) Various methods to obtain ∆S O for a reaction. [16]

6. (a) Explain how does second law of thermodynamic lead to concept of entropy.
(b) A lump of copper having a mass of 5 KG at a temperature of 540 C is dropped in
a well insulated bucket containing 50 Kg of water at a temperature of 200C.If
the specific heats of copper &water are 0.418KJ/Kg 0 C and 4.4 KJ/Kg 0 C
respectively, calculate the change in entropy of the water and copper and
calculate the total entropy change resulting from the process. [16]

7. (a) State whether the following statements are true or false and justify your answer
in brief.

1
Code No: R05211802 R05 Set No. 2
i. Internal energy of a gas does not depend upon its pressure and tempera-
ture.
ii. If f is negative , a reaction will definitely will be spontaneous .
(b) The properties of a closed system undergoes change following the relation PV
=4 and P isin bar and V in metre cube . Calculate the work done, when P
increases from 2.5 bar to 8 bar. [8+8]

8. (a) state the third law of thermodynamics and explain how it rationalize the
thermo chemical data [6]
(b) What is the meaning of thermodynamically possible process [5]
(c) What are the important deductions of third law of thermodynamics [5]

?????

2
Code No: R05211802 R05 Set No. 4
II B.Tech I Semester Examinations,December 2011
THERMODYNAMICS AND KINETICS
Metallurgy And Material Technology
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
?????

1. (a) Define the following :

i. Heat
ii. Work
iii. Internal Energy.
iv. Heat capacity.
(b) State and explain the first law of thermodynamics and its applications. [8+8]

2. (a) State whether the following statements are true or false and justify your answer
in brief.
i. Internal energy of a gas does not depend upon its pressure and tempera-
ture.
ii. If f is negative , a reaction will definitely will be spontaneous .
(b) The properties of a closed system undergoes change following the relation PV
=4 and P isin bar and V in metre cube . Calculate the work done, when P
increases from 2.5 bar to 8 bar. [8+8]

3. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]

4. (a) Explain how does second law of thermodynamic lead to concept of entropy.
(b) A lump of copper having a mass of 5 KG at a temperature of 540 C is dropped in
a well insulated bucket containing 50 Kg of water at a temperature of 200C.If
the specific heats of copper &water are 0.418KJ/Kg 0 C and 4.4 KJ/Kg 0 C
respectively, calculate the change in entropy of the water and copper and
calculate the total entropy change resulting from the process. [16]

5. Explain the following

(a) Tabular method of recording thermodynamic data

(b) Application of third law of thermodynamics
(c) Various methods to obtain ∆S O for a reaction. [16]

6. (a) state the third law of thermodynamics and explain how it rationalize the
thermo chemical data [6]

3
Code No: R05211802 R05 Set No. 4
(b) What is the meaning of thermodynamically possible process [5]
(c) What are the important deductions of third law of thermodynamics [5]

7. (a) Explain the practical importance of Classiuus - Clapeyron equation.

(b) List the assumptions made in deriving the integrated form of the clausius
clapeyron equation. [16]

8. (a) Draw a potential energy diagram for an uncatalyzed reaction. Compare it with
a potential energy diagram for a catalyzed reaction. In each case indicate ∆H
for the activated complex.
(b) Discuss the various methods available for determining the order of reaction.
[16]

?????

4
Code No: R05211802 R05 Set No. 1
II B.Tech I Semester Examinations,December 2011
THERMODYNAMICS AND KINETICS
Metallurgy And Material Technology
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
?????

1. (a) state the third law of thermodynamics and explain how it rationalize the
thermo chemical data [6]
(b) What is the meaning of thermodynamically possible process [5]
(c) What are the important deductions of third law of thermodynamics [5]

2. (a) Define the following :

i. Heat
ii. Work
iii. Internal Energy.
iv. Heat capacity.
(b) State and explain the first law of thermodynamics and its applications. [8+8]

3. (a) State whether the following statements are true or false and justify your answer
in brief.
i. Internal energy of a gas does not depend upon its pressure and tempera-
ture.
ii. If f is negative , a reaction will definitely will be spontaneous .
(b) The properties of a closed system undergoes change following the relation PV
=4 and P isin bar and V in metre cube . Calculate the work done, when P
increases from 2.5 bar to 8 bar. [8+8]

4. (a) Explain the practical importance of Classiuus - Clapeyron equation.

(b) List the assumptions made in deriving the integrated form of the clausius
clapeyron equation. [16]

5. Explain the following

(a) Tabular method of recording thermodynamic data

(b) Application of third law of thermodynamics
(c) Various methods to obtain ∆S O for a reaction. [16]

6. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]

5
Code No: R05211802 R05 Set No. 1
7. (a) Explain how does second law of thermodynamic lead to concept of entropy.
(b) A lump of copper having a mass of 5 KG at a temperature of 540 C is dropped in
a well insulated bucket containing 50 Kg of water at a temperature of 200C.If
the specific heats of copper &water are 0.418KJ/Kg 0 C and 4.4 KJ/Kg 0 C
respectively, calculate the change in entropy of the water and copper and
calculate the total entropy change resulting from the process. [16]

8. (a) Draw a potential energy diagram for an uncatalyzed reaction. Compare it with
a potential energy diagram for a catalyzed reaction. In each case indicate ∆H
for the activated complex.
(b) Discuss the various methods available for determining the order of reaction.
[16]

?????

6
Code No: R05211802 R05 Set No. 3
II B.Tech I Semester Examinations,December 2011
THERMODYNAMICS AND KINETICS
Metallurgy And Material Technology
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
?????

1. (a) Draw a potential energy diagram for an uncatalyzed reaction. Compare it with
a potential energy diagram for a catalyzed reaction. In each case indicate ∆H
for the activated complex.
(b) Discuss the various methods available for determining the order of reaction.
[16]

2. Explain the following

(a) Tabular method of recording thermodynamic data

(b) Application of third law of thermodynamics
(c) Various methods to obtain ∆S O for a reaction. [16]

3. (a) Explain the practical importance of Classiuus - Clapeyron equation.

(b) List the assumptions made in deriving the integrated form of the clausius
clapeyron equation. [16]

4. (a) Define the following :

i. Heat
ii. Work
iii. Internal Energy.
iv. Heat capacity.
(b) State and explain the first law of thermodynamics and its applications. [8+8]

5. (a) state the third law of thermodynamics and explain how it rationalize the
thermo chemical data [6]
(b) What is the meaning of thermodynamically possible process [5]
(c) What are the important deductions of third law of thermodynamics [5]

6. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]

7. (a) Explain how does second law of thermodynamic lead to concept of entropy.

7
Code No: R05211802 R05 Set No. 3
(b) A lump of copper having a mass of 5 KG at a temperature of 540 C is dropped in
a well insulated bucket containing 50 Kg of water at a temperature of 200C.If
the specific heats of copper &water are 0.418KJ/Kg 0 C and 4.4 KJ/Kg 0 C
respectively, calculate the change in entropy of the water and copper and
calculate the total entropy change resulting from the process. [16]

8. (a) State whether the following statements are true or false and justify your answer
in brief.
i. Internal energy of a gas does not depend upon its pressure and tempera-
ture.
ii. If f is negative , a reaction will definitely will be spontaneous .
(b) The properties of a closed system undergoes change following the relation PV
=4 and P isin bar and V in metre cube . Calculate the work done, when P
increases from 2.5 bar to 8 bar. [8+8]

?????