SK027 / CHAPTER 1 : THERMOCHEMISTRY / amalkebajikan01

Enthalpy Stoichiometry

1. How much heat will be transferred when 5.81g of graphite reacts with excess H2 according to the following
equation? Is the reaction endothermic or exothermic? ____________________
6C+ 3H2 C6H6 Ho = 49.03kJ
Ans: 3.95 kJ

2. How much heat will be released when 1.48g of chlorine reacts with excess phosphorous according to the
following equation? Is the reaction endothermic or exothermic? ____________________
2P + 5Cl2 2PCl5 Ho = -866kJ
Ans: -3.62 kJ

3. How much heat will be released when 4.77g of ethanol (C2H5OH) reacts with excess O2 according to the
following equation? Is the reaction endothermic or exothermic? ____________________
C2H5OH + 3O2 2CO2 + 3H2O Ho = -791.4kJ
Ans: -81.9 kJ

4. What is the change in enthalpy when 11.8g of iron reacts with excess O2 according to the following
equation? Is the reaction endothermic or exothermic? ____________________
3Fe + 2O2 Fe3O4 Ho = -1120.48kJ
Ans: -78.9 kJ

5. How much heat will be transferred when 14.9g of ammonia reacts with excess O2 according to the
following equation? Is the reaction endothermic or exothermic? ____________________
4NH3 + 5O2 4NO + 6H2O Ho = -1170kJ
Ans: -256 kJ
SK027 / CHAPTER 1 : THERMOCHEMISTRY / amalkebajikan02

Standard Reaction Enthalpy H = H products - H reactants

1. The molar enthalpy of formation for liquid benzene is +49.08 kJ. Write the thermochemical equation for
this enthalpy.

2.Calculatethestandardreactionenthalpyforthephotosynthesisreaction,
o
6CO2(g)+6H2O(l)C6H12O6(s)+6O2(g)Hrxn =?kJ Ans:2801.3kJ

Substance Ho .
C6H12O6(l) -1274.5 kJ/mol
O2(g) 0 kJ/mol
CO2(g) -393.5 kJ/mol
H2O(l) -285.8 kJ/mol

3. Calculate the standard reaction enthalpy for the combustion of benzene, C6H6(l).
Ans:3267.48kJ
Substance H o
.
C6H6(l) +49.08 kJ/mol
O2(g) 0 kJ/mol
CO2(g) -393.5 kJ/mol
H2O(l) -285.8 kJ/mol

4. According to the following data, calculate the H of the combustion of methane.

Substance H(kJ/mol) Ans: -802.25 kJ
CH4(g) -74.90
O2(g) 0
CO2(g) -393.51
H2O(g) -241.82

5. The molar enthalpy of formation value for ammonia gas is -45.9kJ. What is the H for the decomposition
of 2 moles of NH3?
Ans: +91.8 kJ

6. The Hof value for liquid water is -285.8 kJ. What is the H for the decomposition of 10.0 g of liquid
water?
Ans: +159 kJ
 CALORIMETRY WORKSHEET
(Chemistry IB)

1) A 1.5 kg hot rock was dropped into 2.5dm3 of 250C water. The water temperature rose to 390C.
Calculate the E per kilogram lost by the rock to the water.

2) Calculate the H (in kilograms) that must be released for 5.7kg of water to be cooled from 730C to
250C.

3) Calculate the amount of heat energy needed to vaporize 625g of water at 1000C. The molar heat of
vaporization is 40.6kJmol-1.

4) A test tube containing 10.1g of molten wax was put into 155cm3 of water at 180C. The temperature
rose to 210C. Calculate the molar heat of fusion of the wax, assuming the formula of the wax is
C14H30.

5) Calculate the amount of heat needed to raise the temperature of 175g of mercury from 250C to 850C.
Specific heat capacity of Hg is 0.14Jg-1C-1.

6) CCl4 has a density of 1.5g/cm3 and a specific heat capacity of 0.84J0C-1g-1. Calculate the heat energy
(in kJ) required to heat 2.5dm3 of CCl4 from 150C to 320C.

7) When 1105J of heat is added to 36.5g of ethyl alcohol, the temperature increases by 12.30C. Calculate
the molar heat capacity of ethyl alcohol.

8) When 285J of heat is added to 33.6g of hexane, the temperature rises from 250C to 28.740C. Calculate
the molar heat capacity of hexane.

9) Liquid Na is being considered as an engine coolant. How many grams of Na are needed to absorb
1.0MJ of heat if the temperature of Na is not to increase more than 100C? (CNa = 30.8JK-1mol-1).

Answers:
1)
1.0 x 105 Jkg-1
2)
1.1 x 106J
3)
1.41 x 103kJ
4)
3.85 x 105J mol-1
5)
1.47 x 103J
6)
54 kJ
7)
113Jmol-1C-1
8)
195Jmol-1C-1
9)
7.5 x 104g Na
Mrs. Meer Name_____________________________ #_____
Honors Chemistry Date______________________ Period_________

Chapter 16: Review Problems

1. A serving of Campbells chicken soup has 80. Calories per serving. How many joules per serving is this?
Ans: 330,000 J

2. An 18.7 g sample of platinum metal increases in temperature by 2.3oC when 5.7 J of heat are added. What is the specific heat of
platinum? Ans: 0.13 J/goC

3. A 21.0 g sample of water is cooled from 34.0oC to 28.0oC. How many joules of heat were removed from the water?
Ans: 530 J

4. 10.0g of ice at -5.0oC is heated until it becomes water at 5.0oC. Approximately how much heat did this take?
Ans: 3600 J

5. Benzene has a boiling point of 80.1oC and a freezing point of 5.5oC. A 10.0g sample of benzene at 25.0oC is heated until its
boiling point. This takes 959 J of heat. What is the specific heat of benzene?
Ans: 1.74 J/goC

6. 10.0g of ice at -10.0oC is added to water at 50.0oC. The final temperature of the system was 35.0oC. How many mL of water was
present in the beginning of the process? Ans: 79.7 mL

7. How much heat is transferred when 0.5113 g of ammonia reacts with excess of oxygen according to the following equation?
4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) + 905.4 kJ Ans: -6.792 kJ

8. How much heat will be absorbed if 27.1g of I2 reacts with excess hydrogen according to the following equation?
H2 + I2 2HI H = +26.5 kJ Ans: +2.83 kJ

9. The molar enthalpy of formation for liquid benzene is +49.08 kJ. Write the thermochemical equation for this.

10. According to the following data, calculate the H of the combustion of methane.
H(kJ/mol) Ans: -802.25 kJ
CH4(g) -74.90
O2(g) 0
CO2(g) -393.51
H2O(g) -241.82

11. David has performed a calorimetry experiment to determine H for the dissociation of CuSO4(s). He placed 0.800g of
CuSO4(s) in a calorimeter with 43.0g of water at an initial temperature of 18.3oC. As the CuSO4(s) dissolved in the water, the
temperature rose to 20.2oC. According to Davids data, what is the enthalpy of solution for copper (II) sulfate?
CuSO4(s) Cu+2(aq) + SO4-2(aq) H = ? Ans: -68 kJ

12. Maggie performed a calorimetry experiment to determine H for the solvation of potassium permanganate. Her calorimeter
contained 50.0 g of water at an initial temperature of 17.4oC. After adding 1.10g of KMnO4, the temperature fell to 16.0oC. What
value of H can Maggie obtain from her data? Ans: +42 kJ
KMnO4(s) K+(aq) + MnO4-(aq) H = ?
13. The molar enthalpy of formation value for ammonia gas is -45.9kJ. What is the H for the decomposition of 2 moles of NH3?
Ans: +91.8 kJ
14. The Hof value for liquid water is -285.8 kJ. What is the H for the decomposition of 10.0 g of liquid water?
Ans: +159 kJ
15. From the following enthalpy changes,
2TiCl4(l) + 2CO2 (g) 2TiO2(s) + 2CCl4(g) H = +310. kJ #9 Ans: 6C(s) + 3H2(g) + 49.08 kJ C6H6(l)
TiCl4(l) + 2Mg(s) Ti(s) + 2MgCl2(s) H = -478 kJ
calculate the H for the following reaction:
TiO2(s) + CCl4(g) + 2Mg(s) Ti(s) + CO2(g) + 2MgCl2(g) Ans: H = -633 kJ

Chapter 16: Review Problems

Answers
1000 cal 4.184 J
1. 80. Cal x x = 330,000 J (sig figs)
1 Cal 1 cal

H = mcT
5.7 J = (18.7g)c(2.3 O C)
2.
J
c = 0.13 O
g C

H = mcT
J
3. H = (21.0g)(4.184 O
)(6.0 O C)
g C
H = 530J

H = mcTice + K f m + mcTwater
J J J J
4. H = (10.0g)(2.06 O
)(5.0 O C) + (333 )(10.0g) + (10.0g)(4.184 O )(5.0 O C) = m(4.184 O )(15.0 O C)
g C g g C g C
H = 3600 J
H = mcT
959J = (10.0g)c(55.1 O C)
5.
J
c = 1.74 O
g C

H ice = H water
mcTice + K f m + mcTwater = mcTwater
6. J J J J
(10.0g)(2.06 )(10.0 O C) + (333 )(10.0g) + (10.0g)(4.184 O )(35.0 O C) = m(4.184 O )(15.0 O C)
O
g C g g C g C
m = 79.7 g which = 79.7 mL for water.
1 mol NH 3 -905.4 kJ
7. 0.5113g NH 3 x x = -6.792 kJ (exothermic)
17.04 g NH 3 4 mol NH3

1 mol I 2 +26.5 kJ
8. 27.1 g I 2 x x = +2.83 kJ
253.80 g I 2 1 mol I 2
9. 6C(s) + 3H2(g) + 49.08 kJ C6H6(l) The DH is on the left because it is endothermic. The benzene is on
the right because it is the molar enthalpy of FORMATION. The benzene is one mole because it is the
MOLAR enthalpy of formation. The reactants are pure elements because the molar enthalpy of formation
requires the formation of the substance to be from elements in their standard states.

10. 1st: Write the balanced equation for the combustion of methane.
CH4 + 2O2 CO2 + 2H2O
2nd: Use the equation - H = H products - H reactants
H=[(1mol)(393.51kJ/mol)+(2mol)(241.82kJ/mol)][(1mol)(74.90kJ/mol)+(2mol)(0kJ/mol)]
H=802.25kJ

11. Hsolutionprocess=Hwater(heatlossequalsheatgain)
H= mcT(Iamcalculatingthisforwater,butcancallittheenthalpyoftheexperiment)
H=(43.0g)(4.184J/goC)(1.9oC)
H=341.8328J(dontroundyet)ThisistheHfortheexperimentthatyoudid(dissolved0.800g).
ThisisnottheHforonemoleofCuSO4dissolving.Nowweneedtofinditpermole.

Convert0.800gtomoles:
1 mol CuSO 4
0.800 g CuSO 4 x = 0.0050122173 mol CuSO 4 (dont round yet)
159.61 g CuSO 4

Now you can find the HforonemolebydividingyourHbyyourmoles:

341.8328 J
= 68199.91651 J = 68kJ
0.0050122173 mol
The final answer is negative (-68kJ) because it is exothermic. The temperature of the solution went up.
12. Hsolutionprocess=Hwater(heatlossequalsheatgain)
H= mcT(Iamcalculatingthisforwater,butcancallittheenthalpyoftheexperiment)
H=(50.0g)(4.184J/goC)(1.4oC)
H=292.88J(dontroundyet)ThisistheHfortheexperimentthatyoudid(dissolved1.10g).
ThisisnottheHforonemoleofKMnO4dissolving.Nowweneedtofinditpermole.

Convert1.10gtomoles:
1 mol KMnO 4
1.10 g KMnO 4 x = 0.0069602632 mol KMnO 4 (dont round yet)
158.04 g KMnO 4

Now you can find the HforonemolebydividingyourHbyyourmoles:

292.88 J
= 42078.86836 J = 42kJ
0.0069602632 mol
The final answer is positive (+42 kJ) because it is endothermic. The temperature of the solution went down.
1 3
13. N 2 + H 2 NH 3 H f = -45.9 kJ
o

2 2

For two moles, you would reverse the equation to make it the decomposition of NH3 and then double it to
make it two moles. H = +91.8 kJ

1
14. O 2 + H 2 H 2 O H of = -285.8 kJ
2
 1 mol +285.8 kJ
10.0g H 2 O x x = +159kJ It is positive because it is for the decomposition of water
18.02g H 2O 1 mol H 2 O
when the above equation was for the formation, the opposite.

15. Another Hesss Law Problem.

Mrs. Meer Name____________________________#_____

Honors Chemistry Date_________________ Period______

Hesss Law
Germain Henri Hess (1802 - 1850) is known for his thermochemical studies. Hess's
Law states that the heat evolved or absorbed in a chemical process is the same
whether the process takes place in one or in several steps.

1. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for N2O4(g) 2NO2(g) Ans: 58.2 kJ

N2(g) + O2(g) NO2(g) Ho = 33.9 kJ

N2(g) + 2O2(g) N2O4(g) Ho = 9.6 kJ

2. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for N2(g) + 3H2(g) 2NH3(g) Ans: -114.8 kJ

2NO2(g) + 7H2(g) 2NH3(g) + 4H2O(l) Ho = 142.5 kJ

2NO2(g) N2(g) + 2O2(g) Ho = 82.5 kJ

H2O(l) H2(g) + O2(g) Ho = -43.7 kJ

3. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for CH3COOH(l) 2C(s) + 2H2(g) + O2(g) Ans: 1956 kJ
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ho = 3484 kJ

C(s) + O2(g) CO2(g) Ho = -1576 kJ

2H2(g) + O2(g) 2H2O(l) Ho = -2288 kJ

4. Calculate the enthalpy of reaction for the combustion of nitrogen monoxide gas, NO, to form nitrogen
dioxide gas, as given in the following thermochemical equation. Ans: H = -57.09 kJ
o

NO(g) + O2(g) NO2(g)

Ans: H c = -2219.9 kJ
o
5. Calculate the molar enthalpy of combustion of propane gas, C3H8.
( H f for C3H 8 = -103.8 kJ/mol ) (Use the H f for liquid water.)
o o

Ans: H c = -5544.1 kJ
o
6. Calculate the molar enthalpy of combustion of liquid octane, C8H18.
( H f for C8 H18 = -219.9 kJ/mol ) (Use the H f for water vapor.)
o o
Mrs. Meer Name____________________________#_____
Honors Chemistry Date_________________ Period______

Hesss Law
Germain Henri Hess (1802 - 1850) is known for his thermochemical studies. Hess's
Law states that the heat evolved or absorbed in a chemical process is the same
whether the process takes place in one or in several steps.

1. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for N2O4(g) 2NO2(g) Ans: 58.2 kJ

N2(g) + 2O2(g) 2NO2(g) Ho = 67.8 kJ (DOUBLE)

N2(g) + O2(g) NO2(g) Ho = 33.9 kJ

N2O4(g) N2(g) + 2O2(g) Ho = -9.6 kJ (REVERSE)

N2(g) + 2O2(g) N2O4(g) Ho = 9.6 kJ

N2O4(g) 2NO2(g) Ho = 58.2 kJ

2. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for N2(g) + 3H2(g) 2NH3(g) Ans: -114.8 kJ

2NO2(g) + 7H2(g) 2NH3(g) + 4H2O(l) Ho = 142.5 kJ (KEEP AS IS)

N2(g) + 2O2(g) 2NO2(g) Ho = -82.5 kJ (REVERSE)

2NO2(g) N2(g) + 2O2(g) Ho = 82.5 kJ

4H2O(l) 4H2(g) + 2 O2(g) Ho = -174.8 kJ (MULTIPLY BY 4)

H2O(l) H2(g) + O2(g) Ho = -43.7 kJ

N2(g) + 3H2(g) 2NH3(g) Ho = -114.8 kJ

3. Use the thermochemical equations shown below to determine

the enthalpy for the reaction for CH3COOH(l) 2C(s) + 2H2(g) + O2(g) Ans: 1956 kJ
CH3COOH(l) + 2O2(g) 2CO2(g) + 2H2O(l) Ho = -3484 kJ (REVERSE)
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ho = 3484 kJ

2CO2(g) 2C(s) + 2O2(g) Ho = +3152 kJ (REVERSE & DOUBLE)

C(s) + O2(g) CO2(g) Ho = -1576 kJ

2H2O(l) 2H2(g) + O2(g) Ho = +2288 kJ (REVERSE)

2H2(g) + O2(g) 2H2O(l) Ho = -2288 kJ

CH3COOH(l) 2C(s) + 2H2(g) + O2(g) Ho = 1956 kJ

Use Table A-14 For Problems 4-6.
4. Calculate the enthalpy of reaction for the combustion of nitrogen monoxide gas, NO, to form nitrogen
dioxide gas, as given in the following thermochemical equation. Ans: H = -57.09 kJ
o

NO(g) + O2(g) NO2(g)

1st: Write the molar enthalpy of formation equations for all compounds in the final equation (NO &
NO2). These equations are listed below in blue.

NO(g) N2(g) + O2(g) Ho = -90.29 kJ

N2(g) + O2(g) NO(g) H of = +90.29 kJ

N2(g) + O2(g) NO2(g) H of = +33.2 kJ (Keep)

2nd: Manipulate the equations to get them to add up to your final equation (changes to the above
equations are made in red.)

Ans: H c = -2219.9 kJ
o
5. Calculate the molar enthalpy of combustion of propane gas, C3H8.
( H f for C3H 8 = -103.8 kJ/mol ) (Use the H f for liquid water.)
o o

1st: Write the combustion reaction for propane.

C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(l) Ho = ? (This is what you are trying to determine.)

2nd: Write the molar enthalpy of formation equations for all compounds in the final equation (C3H8, CO2,
and H2O). These equations are listed below in red.
C3H8 3C + 4H2 Ho = +103.8 kJ
3C + 4H2 C3H8 H of = -103.8 kJ
3C + 3O2 3CO2 Ho = -1180.5 kJ
C + O2 CO2 H of = -393.5 kJ
4H2 + 2 O2 4H2O Ho = -1143.2 kJ
o
H2 + O2 H2O H f = -285.8 kJ

3rd: Manipulate the equations to get them to add up to your final equation (changes to the above
equations are made in green.)

Ans: H c = -5544.1 kJ
o
6. Calculate the molar enthalpy of combustion of liquid octane, C8H18.
( H f for C8 H18 = -219.9 kJ/mol ) (Use the H f for water vapor.)
o o
1st: Write the combustion reaction for octane.
C8H18(g) + 12.5 O2(g) 8CO2(g) + 9H2O(l) Ho = ? (This is what you are trying to determine.)

2nd: Write the molar enthalpy of formation equations for all compounds in the final equation (C3H8, CO2,
and H2O). These equations are listed below in red.
C8H18 8C + 9H2 Ho = +219.9 kJ
8C + 9H2 C8H18 H of = -219.9 kJ
8C + 8O2 8CO2 Ho = -3148 kJ
C + O2 CO2 H of = -393.5 kJ
9H2 + 9 O2 9H2O Ho = -2572.2 kJ
o
H2 + O2 H2O H f = -285.8 kJ

3rd: Manipulate the equations to get them to add up to your final equation (changes to the above
equations are made in green.)

HESSS LAW PROBLEMS

(Chemistry IB)

1) Calculate Ho for the formation of 1 mol of strontium carbonate (the material that gives the red color in
fireworks) from its elements.

Sr (s) C(graphite) 3
2 O2 (g) SrCO3 (s)
The information available is
(1) Sr (s) 1
2 O2 (g) SrO (s) H -592 kJ
(2) SrO (s) CO2 (g) SrCO3 (s) H -234 kJ
(3) C(graphite) O2 (g) CO2 (g) H -394 kJ

2) The combination of coal and steam produces a mixture called coal gas, which can be used as a fuel or as a
starting material for other reactions. If we assume coal can be represented by graphite, the equation for
the production of coal gas is:

2 C (s) 2 H2O (g) CH4 (g) CO2(g)

Determine the standard enthalpy change for this reaction from the following
standard enthalpies of reaction :
(1) C(s) H2O (g) CO (g) H2 (g) H 131.3 kJ
(2) CO (g) H2O (g) CO2 (g) H2 (g) H - 41.2 kJ
(3) CH4 (g) H2O (g) 3 H2 (g) CO (g) H 206.1 kJ

3) One reaction involved in the conversion of iron ore to the metal is:

FeO (s) CO (g) Fe (s) CO2 (g)

Calculate the standard enthalpy change for this reaction from these reactions
of iron oxides with CO :
(1) 3 Fe2O3 (s) CO (g) 2 Fe3O4 (s) CO2 (g) H - 47 kJ
(2) Fe2O3 (s) 3 CO (g) 2 Fe (s) 3 CO2 (g) H - 25 kJ
(3) Fe3O4 (s) CO (g) 3 FeO (s) CO2 (g) H 19 kJ

4) Find the H for the reaction below, given the following steps and subsequent H values:
N2H4(l) + H2(g) 2NH3(g)
 N2H4(l) + CH4O(l) CH2O(g) + N2(g) + 3H2 (g) H = -37 kJ
N2(g) + 3H2(g) 2NH 3(g) H = -46 kJ
CH4O(l) CH2O(g) + H 2(g) H = -65 kJ

5) Find the H for the reaction below, given the following steps and subsequent H values:
H2SO4(l) SO3(g) + H2O(g)

H2S(g) + 2O2(g) H2SO4(l) H = -235.5 kJ

H2S(g) + 2O2(g) SO 3(g) + H2O(l) H = -207 kJ
H2O(l) H2O(g) H = 44 kJ

6) Find the H for the reaction below, given the following steps and subsequent H values:
H2(g) + Cl2(g) HCl(g)

COCl2(g) + H2O(l) CH2Cl2(l) + O2(g) H = 47.5 kJ

2HCl(g) + O2(g) H 2 O(l) + Cl2(g) H = 105 kJ
CH2Cl2(l) + H2(g) + 3/2 O 2(g) COCl2(g) + 2H 2O(l) H = -402.5 kJ

7) Find the H for the reaction below, given the following steps and subsequent H values:
C2H2(g) + 5/2O2(g) 2CO2(g) + H2O(g)

C2H6(g) C2H 2(g) + 2H2(g) H = 283.5 kJ

H2(g) + 1/2O2(g) H2O(g) H = -213.7 kJ
2CO2(g) + 3H2O(g) C2H6(g) + 7/2O2(g) H = 849 kJ

8) Find the H for the reaction below, given the following steps and subsequent H values:
HCl(g) + NaNO2(s) HNO2(l) + NaCl(s)

2NaCl(s) + H2O(l) 2HCl(g) + Na2O(s) H = 507 kJ

NO(g) + NO2(g) + Na2O(s) 2NaNO2(s) H = -427 kJ
NO(g) + NO2(g) N2O(g) + O2(g) H = -43 kJ
2HNO2(l) N2O(g) + O2(g) + H 2O(l) H = 34 kJ

9) Find the H for the reaction below, given the following steps and subsequent H values:
Zn(s) + 1/8S8(s) + 2O2(g) ZnSO4(s)

Zn(s) + 1/8S8(s) ZnS(s) H = -183.92 kJ

2ZnS(s) + 3O2(g) 2ZnO(s) + 2SO2(g) H = -927.54 kJ
2SO2(g) + O2(g) 2SO3(g) H = -196.04 kJ
ZnO(s) + SO3(g) ZnSO4 (s) H = -230.32 kJ

10) Calculate the Hformation and give the overall reaction of CS2 from its elements, given the steps involved are
as follows:

C(s) + O2 (g) CO2 (g) H = -393.5kJ

S(s) + O2 (g) SO2 (g) H = -296kJ
CS2 (l) + 3 O2 (g) CO2 (g) H = -1072kJ

Answers:

1. 1220 kJ 4) -18kJ 7) -705kJ

2. + 15.3 kJ 5) 72kJ 8) -78kJ
3. 14 kJ 6) -230kJ 9) -976.03kJ
 10) 86.5kJ (Overall Rxn: C (s) + 2 S (s) CS2 (l))

Mrs. Meer Name____________________________#_____

Honors Chemistry Date_________________ Period______

More Hesss Law

1. The H f of FeCl 2 (s) = -399.4 kJ. FeCl3(s) forms when 1 mole of FeCl2 reacts with mole of Cl2(g). The
o

enthalpy change of that reaction (Ho) is -57.7 kJ. What is the H f of FeCl3 (s)?
o

Ans: -457.1 kJ

2. Use the thermochemical equations shown below to determine the molar enthalpy of combustion for
methane. Ans: -890.36 kJ

C(s) + 2H2(g) CH4(g) Ho = -74.81 kJ

H2O(l) H2(g) + O2(g) Ho = 285.83 kJ

3C(s) + 3O2(g) 3CO2(g) Ho = -1180.53 kJ

3. Use the thermochemical equations shown below to determine the enthalpy of the reaction of iodine and
hydrogen to produce hydrogen iodide. I2(s) + H2(g) 2HI(g) Ans: 51.8 kJ
Ans: -890.36 kJ

I2(g) I2(s) Ho = -124.8 kJ

3I2(g) + 3H2(g) 6HI(g) Ho = -219.0 kJ

4. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2H2O(l) 2H2(g) + O2(g) Ans: 2288 kJ
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ho = 3484 kJ

CO2(g) C(graphite) + O2(g) Ho = 1576 kJ

CH3COOH(l) 2C(graphite) + 2H2(g) + O2(g) Ho = 1956 kJ

5. Under ordinary conditions, carbon does not react with hydrogen to any appreciable extent. However, the
enthalpy change for the reaction C(s) + 2H2(g) CH4(g), can be determined by carrying out the following
series of related reactions and measuring their enthalpy changes. Calculate the enthalpy change for this
reaction. Ans: -74.8 kJ

C(s) + O2(g) CO2(g) Ho = -393.51 kJ

H2(g) + O2(g) H2O(l) Ho = -285.83 kJ

CH4(g) + 2O2(g) CO2(g) + 2H2O(l) Ho = -890.37 kJ

6. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ans: 3484 kJ

C(graphite) + O2(g) CO2(g) Ho = -1576 kJ

2H2O(l) 2H2(g) + O2(g) Ho = 2288 kJ

2C(graphite) + 2H2(g) + O2(g) CH3COOH(l) Ho = -1956 kJ

7. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
3Fe2O3(s) 2Fe3O4(s) + O2(g) Ans: 465 kJ

3Fe2O3(s) 6Fe(s) + 4 O2(g) Ho = 4933 kJ

6Fe(s) + 4O2(g) 2Fe3O4(s) Ho = -4468 kJ

8. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
cis-C4H8(g) + 6O2(g) 4CO2(g) + 4H2O(g) Ans: -675.7 kJ

trans-C4H8(g) + 6O2(g) 4CO2(g) + 4H2O(g) Ho = -676.7 kJ

cis-C4H8(g) trans-C4H8(g) Ho = 1.0 kJ

9. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
H2O(l) H2(g) + O2(g) Ans: 143.0 kJ

C(s) + O2(g) CO2(g) Ho = -196.7 kJ

C2H6(g) 2C(s) + 3H2(g) Ho = 42.3 kJ

C2H6(g) + 3 O2(g) 2CO2(g) + 3H2O(l) Ho = -780.2 kJ

Mrs. Meer Name____________________________#_____
Honors Chemistry Date_________________ Period______

More Hesss Law

1. The H f of FeCl 2 (s) = -399.4 kJ. FeCl3(s) forms when 1 mole of FeCl2 reacts with mole of Cl2(g). The
o

enthalpy change of that reaction (Ho) is -57.7 kJ. What is the H f of FeCl3 (s)?
o

Ans: -457.1 kJ
Fe(s) + Cl2(g) FeCl2(s) H = -399.4 kJ
o
f
Nothing needs changed for either of these
FeCl2(s) + Cl2 FeCl3(s) Ho = -57.7 kJ equations once they are written. They
add up to the final equation, therefore, so
____________________________________________ do the Hs.
Fe(s) + 3/2 Cl2(g) FeCl3(s) H f = -457.1 kJ
o

2. Use the thermochemical equations shown below to determine the molar enthalpy of combustion for
methane. Ans: -890.36 kJ

C(s) + 2H2(g) CH4(g) Ho = -74.81 kJ

CH4(g) C(s) + 2H2(g) Ho = +74.81 kJ
H2O(l) H2(g) + O2(g) Ho = 285.83 kJ
2H2(g) + O2(g) 2H2O(l) Ho = -571.66 kJ
3C(s) + 3O2(g) 3CO2(g) Ho = -1180.53 kJ
C(s) + O2(g) CO2(g) Ho = -393.51 kJ
_______________________________________________________
CH4(g) + 2O2(g) CO2(g) + 2H2O(l) H c = -890.36 kJ
o

3. Use the thermochemical equations shown below to determine the enthalpy of the reaction of iodine and
hydrogen to produce hydrogen iodide. I2(s) + H2(g) 2HI(g) Ans: 51.8 kJ
Ans: -890.36 kJ

I2(g) I2(s) Ho = -124.8 kJ

 I2(s) I2(g) Ho = +124.8 kJ
3I2(g) + 3H2(g) 6HI(g) Ho = -219.0 kJ
I2(g) + H2(g) HI(g) Ho = -73.0 kJ

4. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2H2O(l) 2H2(g) + O2(g) Ans: 2288 kJ

2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ho = 3484 kJ

CO2(g) C(graphite) + O2(g) Ho = 1576 kJ

2C(graphite) + 2O2(g) 2CO2(g) Ho = -3152 kJ

CH3COOH(l) 2C(graphite) + 2H2(g) + O2(g) Ho = 1956 kJ

5. Under ordinary conditions, carbon does not react with hydrogen to any appreciable extent. However, the
enthalpy change for the reaction C(s) + 2H2(g) CH4(g), can be determined by carrying out the following
series of related reactions and measuring their enthalpy changes. Calculate the enthalpy change for this
reaction. Ans: -74.8 kJ

C(s) + O2(g) CO2(g) Ho = -393.51 kJ

H2(g) + O2(g) H2O(l) Ho = -285.83 kJ

2H2(g) + O2(g) 2H2O(l) Ho = -571.66 kJ

CH4(g) + 2O2(g) CO2(g) + 2H2O(l) Ho = -890.37 kJ

CO2(g) + 2H2O(l) CH4(g) + 2O2(g)Ho = +890.37 kJ

6. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
2CO2(g) + 2H2O(l) CH3COOH(l) + 2O2(g) Ans: 3484 kJ

C(graphite) + O2(g) CO2(g) Ho = -1576 kJ

2CO2(g) 2C(graphite) + 2O2(g) Ho = +3152 kJ
2H2O(l) 2H2(g) + O2(g) Ho = 2288 kJ

2C(graphite) + 2H2(g) + O2(g) CH3COOH(l) Ho = -1956 kJ

7. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
3Fe2O3(s) 2Fe3O4(s) + O2(g) Ans: 465 kJ

3Fe2O3(s) 6Fe(s) + 4 O2(g) Ho = 4933 kJ

6Fe(s) + 4O2(g) 2Fe3O4(s) Ho = -4468 kJ

Do nothing to either of these equations. They are fine the way they are.
8. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
cis-C4H8(g) + 6O2(g) 4CO2(g) + 4H2O(g) Ans: -675.7 kJ

trans-C4H8(g) + 6O2(g) 4CO2(g) + 4H2O(g) Ho = -676.7 kJ

cis-C4H8(g) trans-C4H8(g) Ho = 1.0 kJ

Do nothing to either of these equations. They are fine the way they are.

9. Use the thermochemical equations shown below to determine the enthalpy for the reaction:
H2O(l) H2(g) + O2(g) Ans: 143.0 kJ

C(s) + O2(g) CO2(g) Ho = -196.7 kJ

2C(s) + 2O2(g) 2CO2(g) Ho = -393.4 kJ

C2H6(g) 2C(s) + 3H2(g) Ho = 42.3 kJ

C2H6(g) + 3 O2(g) 2CO2(g) + 3H2O(l) Ho = -780.2 kJ

2CO2(g) + 3H2O(l) C2H6(g) + 3 O2(g) Ho = +780.2 kJ

**Tip** The last equation is miserable to try to divide by 3, so instead, multiply the desired (original)
equation by 3 and then when you are all done, divide your answer by 3.
3H2O(l) 3H2(g) + 3/2O2(g)