Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and Supplier

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Safety Data Sheet

Cream R7 (5L)
Revision: 2015-06-14 Version: 01.0

SECTION 1: Identification of the substance/mixture and supplier


1.1 Product identifier
Product name: Cream R7 (5L)

1.2 Recommended use and restrictions on use


Identified uses:
Cream cleanser
Restrictions of use:
Uses other than those identified are not recommended

1.3 Details of the supplier


Diversey Australia Pty. Limited
29 Chifley St, Smithfield, NSW, 2164, Australia
Telephone: (02) 9757 0300
Fax: (02) 9725 5767
Email: [email protected]
Website: http://www.diversey.com

1.4 Emergency telephone number


Call 1800 033 111 (24hrs)

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classified as hazardous according to Safe Work Australia criteria.

Serious eye irritation, Category 2

2.2 Label elements

Signal word: Warning

Hazard statements:
H319 - Causes serious eye irritation.

Prevention statement(s):
P264 - Wash face, hands and any exposed skin thoroughly after handling.

Response statement(s):
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.

2.3 Other hazards

SECTION 3: Composition/information on ingredients


3.1 Substances / Mixtures

Ingredient(s) CAS number EC number Classification Weight percent

sodium dodecylbenzenesulphonate 25155-30-0 246-680-4 Acute Tox. 4 (H302) 3-10


Skin Irrit. 2 (H315)
Eye Dam. 1 (H318)

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SAFETY DATA SHEET
Cream R7 (5L)

sodium carbonate 497-19-8 207-838-8 Eye Irrit. 2 (H319) 1-3


Alcohol ethoxylates 68131-39-5 500-195-7 Acute Tox. 4 (H302) 1-3
Eye Dam. 1 (H318)
3-butoxypropan-2-ol 5131-66-8 225-878-4 Flam. Liq. 3 (H226) 1-3
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)

Non-hazardous ingredients are the remainder and add up to 100%.

Workplace exposure limit(s), if available, are listed in subsection 8.1.


For the full text of the H and AUH phrases mentioned in this Section, see Section 16.

SECTION 4: First aid measures


4.1 Description of first aid measures
Inhalation Get medical attention or advice if you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water. If skin irritation occurs: Get medical advice
or attention.
Eye contact: Immediately rinse eyes cautiously with lukewarm water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If irritation occurs and persists, get medical attention.
Ingestion: Immediately drink 1 glass of water. Get medical attention or advice if you feel unwell.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.
First aid facilities: Eyewash facilities should be considered in a workplace where necessary.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: No known effects or symptoms in normal use.
Eye contact: Causes severe irritation.
Ingestion: No known effects or symptoms in normal use.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

Poison Information Center: Call 13 11 26 (Australia Wide).

SECTION 5: Firefighting measures


5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

5.2 Special hazards arising from the substance or mixture


No special hazards known.

5.3 Advice for firefighters


As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

5.4 Hazchem code


None allocated

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
No special measures required.

6.2 Environmental precautions


Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water.

6.3 Methods and material for containment and cleaning up


Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).

6.4 Reference to other sections


For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.

Measures required to protect the environment:


For environmental exposure controls see subsection 8.2.

Advices on general occupational hygiene:


Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with

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SAFETY DATA SHEET
Cream R7 (5L)

other products unless adviced by Sealed Air. Wash hands before breaks and at the end of workday. Wash face, hands and any exposed skin
thoroughly after handling. Take off immediately all contaminated clothing. Use personal protective equipment as required. Avoid contact with
eyes. Use only with adequate ventilation.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local and national regulations. Keep only in original container. Store in a closed container.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.

7.3 Specific end use(s)


No specific advice for end use available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Workplace exposure limits

Air limit values, if available:

Biological limit values, if available:

8.2 Exposure controls

The following information applies for the uses indicated in subsection 1.2.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Appropriate engineering controls: No special requirements under normal use conditions.


Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.

Personal protective equipment


Eye / face protection: Safety glasses are not normally required. However, their use is recommended in those cases
where splashes may occur when handling the product.
Hand protection: No special requirements under normal use conditions.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties

Method / remark
Physical State: Liquid
Colour: Opaque, White
Odour: Product specific
Odour threshold: Not applicable
pH: ≈ 11 ( neat)
Melting point/freezing point (°C): Not determined
Initial boiling point and boiling range (°C): Not determined
Flash point (°C): Not applicable.
Sustained combustion: Not determined
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability limit (%): Not determined
Vapour pressure: Not determined
Vapour density: Not determined
Relative density: 1.20 g/cm³ (20 °C)
Solubility in / Miscibility with Water: Fully miscible
Autoignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: Not determined
Explosive properties: Not explosive.
Oxidising properties: Not oxidising

9.2 Other information


Surface tension (N/m): Not determined
Corrosion to metals: Not corrosive

SECTION 10: Stability and reactivity


10.1 Reactivity

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SAFETY DATA SHEET
Cream R7 (5L)

No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability


Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions


No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid


None known under normal storage and use conditions.

10.5 Incompatible materials


Reacts with acids.

10.6 Hazardous decomposition products


None known under normal storage and use conditions.

SECTION 11: Toxicological information


11.1 Information on toxicological effects

Mixture data:

Relevant calculated ATE(s):


ATE - Oral (mg/kg): >2000

Skin irritation and corrosivity


Result: Not corrosive or irritant Method: Weight of evidence
Eye irritation and corrosivity
Result: Eye irritant 2 Method: Weight of evidence

Substance data, where relevant and available, are listed below.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate LD 50 2800 Rat Method not given -
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol LD 50 3300 Rat Method not given

Acute dermal toxicity


Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate LD 50 > 2000 Rabbit Method not given -
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol LD 50 > 2000 Rat Method not given

Acute inhalative toxicity


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate LC 50 2.3 (dust) Rat OECD 403 (EU B.2) 2
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Irritation and corrosivity


Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
sodium dodecylbenzenesulphonate No data available
sodium carbonate Not irritant Rabbit Method not given
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Eye irritation and corrosivity

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SAFETY DATA SHEET
Cream R7 (5L)

Ingredient(s) Result Species Method Exposure time


sodium dodecylbenzenesulphonate No data available
sodium carbonate Irritant Rabbit Method not given
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Respiratory tract irritation and corrosivity


Ingredient(s) Result Species Method Exposure time
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
sodium dodecylbenzenesulphonate No data available
sodium carbonate Not sensitising Method not given -
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available -
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)


Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
sodium dodecylbenzenesulphonate No data available No data available
sodium carbonate No data available No data available
Alcohol ethoxylates No data available No data available
3-butoxypropan-2-ol No data available No data available

Carcinogenicity
Ingredient(s) Effect
sodium dodecylbenzenesulphonate No data available
sodium carbonate No evidence for carcinogenicity, weight-of-evidence
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Toxicity for reproduction


Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
sodium No data
dodecylbenzenesulpho available
nate
sodium carbonate No data
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Repeated dose toxicity


Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data -
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Sub-chronic dermal toxicity


Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data5 / 10
Page -
SAFETY DATA SHEET
Cream R7 (5L)

available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Sub-chronic inhalation toxicity


Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data -
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
sodium No data
dodecylbenzenesulpho available
nate
sodium carbonate No data
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

STOT-single exposure
Ingredient(s) Affected organ(s)
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

STOT-repeated exposure
Ingredient(s) Affected organ(s)
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density
of the product.

Potential adverse health effects and symptoms


Effects and symptoms related to the product, if any, are listed in subsection 4.2.

SECTION 12: Ecological information


12.1 Toxicity

No data is available on the mixture.

Substance data, where relevant and available, are listed below

Aquatic short-term toxicity


Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate LC 50 300 Lepomis Method not given 96
macrochirus
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol LC 50 560 - 1000 Fish Method not given 96

Aquatic short-term toxicity - crustacea


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate EC 50 265 Daphnia Method not given 96
magna Straus

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SAFETY DATA SHEET
Cream R7 (5L)

Alcohol ethoxylates No data


available
3-butoxypropan-2-ol LC 50 > 1000 Daphnia Method not given 48

Aquatic short-term toxicity - algae


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data -
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data -
available

Aquatic short-term toxicity - marine species


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data -
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data -
available

Impact on sewage plants - toxicity to bacteria


Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol EC 50 > 1000 Bacteria Method not given

Aquatic long-term toxicity


Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Aquatic long-term toxicity - crustacea


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data
available

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
sodium dodecylbenzenesulphonate No data
available
sodium carbonate No data -
available
Alcohol ethoxylates No data
available
3-butoxypropan-2-ol No data -
available

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
sodium carbonate No data -
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SAFETY DATA SHEET
Cream R7 (5L)

available
3-butoxypropan-2-ol No data -
available

Terrestrial toxicity - plants, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
sodium carbonate No data -
available
3-butoxypropan-2-ol No data -
available

Terrestrial toxicity - birds, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
time (days)
sodium carbonate No data -
available
3-butoxypropan-2-ol No data -
available

Terrestrial toxicity - beneficial insects, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
sodium carbonate No data -
available
3-butoxypropan-2-ol No data -
available

Terrestrial toxicity - soil bacteria, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
sodium carbonate No data -
available
3-butoxypropan-2-ol No data -
available

12.2 Persistence and degradability


Abiotic degradation
Abiotic degradation - photodegradation in air, if available:

Abiotic degradation - hydrolysis, if available:


Ingredient(s) Half-life time in Method Evaluation Remark
fresh water
sodium carbonate No data available Rapidly hydrolysible

Abiotic degradation - other processes, if available:

Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
sodium dodecylbenzenesulphonate No data available
sodium carbonate Not applicable (inorganic
substance)
Alcohol ethoxylates No data available
3-butoxypropan-2-ol Method not given Readily biodegradable

Ready biodegradability - anaerobic and marine conditions, if available:

Degradation in relevant environmental compartments, if available:

12.3 Bioaccumulative potential


Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available No bioaccumulation expected
Alcohol ethoxylates No data available
3-butoxypropan-2-ol 0.98 Method not given Low potential for bioaccumulation

Bioconcentration factor (BCF)


Ingredient(s) Value Species Method Evaluation Remark
sodium No data available
dodecylbenzenesulpho
nate
sodium carbonate No data available No bioaccumulation expected
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available Page 8 / 10
SAFETY DATA SHEET
Cream R7 (5L)

12.4 Mobility in soil


Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
sodium dodecylbenzenesulphonate No data available
sodium carbonate No data available Potential for mobility in soil,
soluble in water
Alcohol ethoxylates No data available
3-butoxypropan-2-ol No data available Potential for mobility in soil,
soluble in water

12.5 Other adverse effects


No other adverse effects known.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.

Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.

SECTION 14: Transport information

ADG, IMO/IMDG, ICAO/IATA


14.1 UN number: Non-dangerous goods
14.2 UN proper shipping name: Non-dangerous goods
14.3 Transport hazard class(es): Non-dangerous goods
Class: -
14.4 Packing group: Non-dangerous goods
14.5 Environmental hazards: Non-dangerous goods
14.6 Special precautions for user: Non-dangerous goods
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers.

Hazchem code: None allocated

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard
for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Classification Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals.

Inventory listing(s) AICS (Australian Inventory of Chemical Substances): All components are listed on AICS, or are
exempt

SECTION 16: Other information


The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

SDS code: MS31000092 Version: 01.0 Revision: 2015-06-14

Full text of the H phrases mentioned in section 3:


•H226-Fl
ammabl eli
qui
dandvapour .
•H302-Harmful
ifswall
owed.
•H315-Causesskini
rri
tati
on.
•H318-Causesseri
ousey edamage.
•H319-Causesseri
ousey eirr
it
ati
on.
•H400-Veryt
oxictoaquaticl
if
e.
•H412-Harmful
toaquat i
cli
fewithl
ongl
ast
ingef
fect
s.
Additional information:
Respirators: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment
must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable

Page 9 / 10
SAFETY DATA SHEET
Cream R7 (5L)

when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is
necessary.

Work practices - solvents: Organic solvents may present both a health and flammability hazard. It is recommended that engineering controls
should be adopted to reduce exposure where practicable (for example, if using indoors, ensure explosion proof extraction ventilation is
available). Flammable or combustible liquids with explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The
control of undesirable static electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for control procedures.

Personal protective equipment guidelines: The recommendation for protective equipment contained within this report is provided as a guide
only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering
controls should be considered before final selection of personal protective equipment is made.

Health effects from exposure: It should be noted that the effects from exposure to this product will depend on several factors including:
frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given
that it is impractical to prepare a Safety Data Sheet which would encompass all possible scenarios, it is anticipated that users will assess the
risks and apply control methods where appropriate.

Abbreviations and acronyms:


•ATE-Acut
eTox i
cit
yEs ti
mate
•LC50-Let
halConcentrat
ion,50% /MedianLethalConcent
rat
ion
•LD50-Let
halDose,50% /Medi anLet
hal dose
•STOT-RE-Specif
ictar
getorgantoxi
cit
y( r
epeatedexposur
e)
•STOT-SE-Specif
i
ct ar
getorgantoxi
ci
ty(singl
eex posur
e)
•ECNo.-EuropeanCommuni t
yNumber

End of Safety Data Sheet

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