Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

Safety Data Sheet
According to Regulation (EC) No 1907/2006
R7
Revision: 2015-07-12 Version: 05.1
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name: R7
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses:
For professional use only.
AISE-P301 - General purpose cleaner. Manual process
AISE-P302 - General purpose cleaner. Spray and wipe manual process
Uses advised against: Uses other than those identified are not recommended
1.3 Details of the supplier of the safety data sheet

Diversey Europe Operations BV, Maarssenbroeksedijk 2, 3542DN Utrecht, The Netherlands
Contact details
Diversey Ltd
Weston Favell Centre, Northampton NN3 8PD, United Kingdom
Tel: 01604 405311, Fax: 01604 406809
Regulatory Email: [email protected]
1.4 Emergency telephone number

For medical or environmental emergency only:
call 0800 052 0185
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
The product has been classified and labelled in accordance with Regulation (EC) No 1272/2008.
Eye Irrit. 2 (H319)
Classification in accordance with Directive 1999/45/EC and corresponding national legislation

Indication of danger
Xi - Irritant
Risk phrases:
R36 - Irritating to eyes.
2.2 Label elements
Signal word: Warning.
Contains EUH208: 1,2-benzisothiazol-3(2H)-one (Benzisothiazolinone)
Hazard statements:
H319 - Causes serious eye irritation.
EUH208 - May produce an allergic reaction.
2.3 Other hazards

No other hazards known. The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No 1907/2006, Annex
XIII.
Page 1 / 11
SAFETY DATA SHEET
R7
SECTION 3: Composition/information on ingredients

3.2 Mixtures
Ingredient(s) EC number CAS number REACH number Classification Classification Notes Weight
(1999/45/EC) percent
sodium 285-600-2 85117-50-6 [1] Acute Tox. 4 (H302) Xn;R22 3-10
alkylbenzenesulphonate Skin Irrit. 2 (H315) Xi;R38-41
Eye Dam. 1 (H318)
sodium carbonate 207-838-8 497-19-8 01-2119485498-19 Eye Irrit. 2 (H319) Xi;R36 3-10
alkyl alcohol ethoxylate Polymer* 68131-39-5 [4] Eye Dam. 1 (H318) Xi;R41 1-3
Aquatic Acute 1 (H400) N;R50
Aquatic Chronic 2
(H411)
1,2-benzisothiazol-3(2H)-one 220-120-9 2634-33-5 No data available Acute Tox. 4 (H302) T;R23 0.01-0.1
Skin Irrit. 2 (H315) Xn;R22
Eye Dam. 1 (H318) Xi;R38-41-43
Skin Sens. 1 (H317) N;R50
Aquatic Acute 1 (H400)
* Polymer.
For the full text of the R, H and EUH phrases mentioned in this Section, see Section 16.
Workplace exposure limit(s), if available, are listed in subsection 8.1.
[1] Exempted: ionic mixture. See Regulation (EC) No 1907/2006, Annex V, paragraph 3 and 4. This salt is potentially present, based on calculation, and included
for classification and labelling purposes only. Each starting material of the ionic mixture is registered, as required.
[2] Exempted: included in Annex IV of Regulation (EC) No 1907/2006.
[3] Exempted: Annex V of Regulation (EC) No 1907/2006.
[4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006.
SECTION 4: First aid measures

4.1 Description of first aid measures
Inhalation Get medical attention or advice if you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water. If skin irritation occurs: Get medical advice
or attention.
Eye contact: Immediately rinse eyes cautiously with lukewarm water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If irritation occurs and persists, get medical attention.
Ingestion: Immediately drink 1 glass of water. Get medical attention or advice if you feel unwell.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: No known effects or symptoms in normal use.
Eye contact: Causes severe irritation.
Ingestion: No known effects or symptoms in normal use.
4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture

No special hazards known.
5.3 Advice for firefighters

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
No special measures required.
6.2 Environmental precautions

Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water.
6.3 Methods and material for containment and cleaning up

Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).
6.4 Reference to other sections

For personal protective equipment see subsection 8.2. For disposal considerations see section 13.
Page 2 / 11
SAFETY DATA SHEET
R7
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.
Measures required to protect the environment:

For environmental exposure controls see subsection 8.2.
Advices on general occupational hygiene:

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Sealed Air. Wash hands before breaks and at the end of workday. Wash face, hands and any exposed skin
thoroughly after handling. Take off immediately all contaminated clothing. Use personal protective equipment as required. Use only with
adequate ventilation.
7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local and national regulations. Keep only in original container. Store in a closed container.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.
7.3 Specific end use(s)

No specific advice for end use available.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Workplace exposure limits
Air limit values, if available:
Biological limit values, if available:
Recommended monitoring procedures, if available:
Additional exposure limits under the conditions of use, if available:
DNEL/DMEL and PNEC values

Human exposure
DNEL oral exposure - Consumer (mg/kg bw)
Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
sodium alkylbenzenesulphonate No data available No data available No data available No data available
sodium carbonate - - - -
alkyl alcohol ethoxylate No data available No data available No data available No data available
1,2-benzisothiazol-3(2H)-one No data available No data available No data available No data available
DNEL dermal exposure - Worker

effects effects (mg/kg bw) effects effects (mg/kg bw)
sodium carbonate No data available - No data available -
DNEL dermal exposure - Consumer

effects effects (mg/kg bw) effects effects (mg/kg bw)
sodium carbonate No data available - No data available -
DNEL inhalatory exposure - Worker (mg/m3)

sodium carbonate - - 10 -
DNEL inhalatory exposure - Consumer (mg/m3)

sodium carbonate 10 - - -
Page 3 / 11
SAFETY DATA SHEET
R7
Environmental exposure
Environmental exposure - PNEC
Ingredient(s) Surface water, fresh Surface water, marine Intermittent (mg/l) Sewage treatment
(mg/l) (mg/l) plant (mg/l)
Environmental exposure - PNEC, continued

Ingredient(s) Sediment, freshwater Sediment, marine Soil (mg/kg) Air (mg/m3)
(mg/kg) (mg/kg)
8.2 Exposure controls
The following information applies for the uses indicated in subsection 1.2.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.
Recommended safety measures for handling the undiluted product:
Appropriate engineering controls: Use only in well ventilated areas.

Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.
Personal protective equipment

Eye / face protection: Safety glasses are not normally required. However, their use is recommended in those cases
where splashes may occur when handling the product.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: Respiratory protection is not normally required. However, inhalation of vapour, spray, gas or
aerosols should be avoided.
Environmental exposure controls: No special requirements under normal use conditions.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Information in this section refers to the product, unless it is specifically stated that substance data is listed
Method / remark
Physical State: Liquid
Colour: Milky, White
Odour: Slightly perfumed
Odour threshold: Not applicable
pH: ≈ 11 ( neat)
Melting point/freezing point (°C): Not determined
Initial boiling point and boiling range (°C): Not determined
Substance data, boiling point

Ingredient(s) Value Method Atmospheric pressure
(°C) (hPa)
sodium alkylbenzenesulphonate No data available
sodium carbonate 1600 Method not given 1013
alkyl alcohol ethoxylate No data available
1,2-benzisothiazol-3(2H)-one No data available
Method / remark
Flash point (°C): Not applicable.
Sustained combustion: Not applicable.
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability limit (%): Not determined
Substance data, flammability or explosive limits, if available:
Method / remark
Vapour pressure: Not determined
Substance data, vapour pressure
Page 4 / 11
SAFETY DATA SHEET
R7
Ingredient(s) Value Method Temperature

(Pa) (°C)
sodium carbonate Negligible
Method / remark
Vapour density: Not determined
Relative density: 1.20 g/cm³ (20 °C)
Solubility in / Miscibility with Water: Fully miscible
Substance data, solubility in water

Ingredient(s) Value Method Temperature
(g/l) (°C)
sodium carbonate 210-215 Method not given 20
Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.3
Method / remark
Autoignition temperature: Not determined
Decomposition temperature: Not applicable.
Viscosity: ≈ 600 mPa. s(20° C)
Explosive properties: Not explosive.
Oxidising properties: Not oxidising
9.2 Other information

Surface tension (N/m): Not determined
Corrosion to metals: Not corrosive
Substance data, dissociation constant, if available:
SECTION 10: Stability and reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability

Stable under normal storage and use conditions.
10.3 Possibility of hazardous reactions

No hazardous reactions known under normal storage and use conditions.
10.4 Conditions to avoid

None known under normal storage and use conditions.
10.5 Incompatible materials

Reacts with acids.
10.6 Hazardous decomposition products

None known under normal storage and use conditions.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Mixture data:
Relevant calculated ATE(s):

ATE - Oral (mg/kg): >2000
Eye irritation and corrosivity

Result: Eye irritant 2 Method: Weight of evidence
Substance data, where relevant and available, are listed below.
Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
sodium alkylbenzenesulphonate No data
Page 5 / 11
SAFETY DATA SHEET
R7
available
sodium carbonate LD 50 2800 Rat Method not given -
alkyl alcohol ethoxylate No data
available
1,2-benzisothiazol-3(2H)-one No data
available
Acute dermal toxicity

(mg/kg) time (h)
available
sodium carbonate LD 50 > 2000 Rabbit Method not given -
available
available
Acute inhalative toxicity

(mg/l) time (h)
available
sodium carbonate LC 50 2.3 (dust) Rat OECD 403 (EU B.2) 2
available
available
Irritation and corrosivity

Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
sodium carbonate Not irritant Rabbit Method not given
Eye irritation and corrosivity

sodium carbonate Irritant Rabbit Method not given
Respiratory tract irritation and corrosivity

sodium carbonate No data available
Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
sodium carbonate Not sensitising Method not given -
Sensitisation by inhalation
sodium carbonate No data available -
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
sodium alkylbenzenesulphonate No data available No data available
sodium carbonate No data available No data available
alkyl alcohol ethoxylate No data available No data available
1,2-benzisothiazol-3(2H)-one No data available Page 6 / 11 No data available
SAFETY DATA SHEET
R7
Carcinogenicity
Ingredient(s) Effect
sodium carbonate No evidence for carcinogenicity, weight-of-evidence
Toxicity for reproduction

Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
sodium No data
alkylbenzenesulphonat available
e
sodium carbonate No data
available
available
1,2-benzisothiazol-3(2H No data
)-one available
Repeated dose toxicity

Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
available
sodium carbonate No data -
available
available
available
Sub-chronic dermal toxicity

available
available
available
available
Sub-chronic inhalation toxicity

available
available
available
available
Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
sodium No data
alkylbenzenesulphonat available
e
available
available
1,2-benzisothiazol-3(2H No data
)-one available
STOT-single exposure
Ingredient(s) Affected organ(s)
STOT-repeated exposure
Ingredient(s) Affected organ(s)
Page 7 / 11
SAFETY DATA SHEET
R7

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density
of the product.
Potential adverse health effects and symptoms

Effects and symptoms related to the product, if any, are listed in subsection 4.2.
SECTION 12: Ecological information

12.1 Toxicity
No data is available on the mixture.
Substance data, where relevant and available, are listed below
Aquatic short-term toxicity

Aquatic short-term toxicity - fish
(mg/l) time (h)
available
sodium carbonate LC 50 300 Lepomis Method not given 96
macrochirus
available
available
Aquatic short-term toxicity - crustacea

(mg/l) time (h)
available
sodium carbonate EC 50 265 Daphnia Method not given 96
magna Straus
available
available
Aquatic short-term toxicity - algae

(mg/l) time (h)
available
available
available
available
Aquatic short-term toxicity - marine species

(mg/l) time (days)
available
available
available
available
Impact on sewage plants - toxicity to bacteria

Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
available
available
available
available
Aquatic long-term toxicity

Page 8 / 11
SAFETY DATA SHEET
R7
Aquatic long-term toxicity - fish

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
available
available
available
available
Aquatic long-term toxicity - crustacea

(mg/l) time
available
available
available
available
Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
(mg/kg dw time (days)
sediment)
available
available
available
available
Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
soil)
available
Terrestrial toxicity - plants, if available:

soil)
available
Terrestrial toxicity - birds, if available:

time (days)
available
Terrestrial toxicity - beneficial insects, if available:

soil)
available
Terrestrial toxicity - soil bacteria, if available:

soil)
available
12.2 Persistence and degradability

Abiotic degradation
Abiotic degradation - photodegradation in air, if available:
Abiotic degradation - hydrolysis, if available:

Ingredient(s) Half-life time in Method Evaluation Remark
fresh water
sodium carbonate No data available Rapidly hydrolysible
Abiotic degradation - other processes, if available:
Page 9 / 11
SAFETY DATA SHEET
R7
Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
sodium carbonate Not applicable (inorganic
substance)
Ready biodegradability - anaerobic and marine conditions, if available:
Degradation in relevant environmental compartments, if available:
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.
648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be
made available to them, at their direct request or at the request of a detergent manufacturer.
12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
sodium carbonate No data available No bioaccumulation expected
Bioconcentration factor (BCF)

Ingredient(s) Value Species Method Evaluation Remark
sodium No data available
alkylbenzenesulphonat
e
sodium carbonate No data available No bioaccumulation expected
1,2-benzisothiazol-3(2H No data available
)-one
12.4 Mobility in soil

Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
sodium carbonate No data available Potential for mobility in soil,
soluble in water
12.5 Results of PBT and vPvB assessment

Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.
12.6 Other adverse effects

No other adverse effects known.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.
European Waste Catalogue: 20 01 29* - detergents containing dangerous substances.
Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.
SECTION 14: Transport information
ADR, RID, ADN, IMO/IMDG, ICAO/IATA

14.1 UN number: Non-dangerous goods
14.2 UN proper shipping name: Non-dangerous goods
14.3 Transport hazard class(es): Non-dangerous goods
Class: -
14.4 Packing group: Non-dangerous goods
Page 10 / 11
SAFETY DATA SHEET
R7
14.5 Environmental hazards: Non-dangerous goods

14.6 Special precautions for user: Non-dangerous goods
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers.
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorisations or restrictions (Regulation (EC) No 1907/2006, Title VII respectively Title VIII): Not applicable.
Ingredients according to EC Detergents Regulation 648/2004

anionic surfactants 5 - 15%
non-ionic surfactants, soap < 5%
perfumes, Benzisothiazolinone, Hexyl Cinnamal, Limonene, Butylphenyl Methylpropional
15.2 Chemical safety assessment

A chemical safety assessment has not been carried out on the mixture
SECTION 16: Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract
SDS code: MSDS4973 Version: 05.1 Revision: 2015-07-12
Reason for revision:

This data sheet contains changes from the previous version in section(s):, 1
Classification procedure
The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No
1272/2008. If for certain classifications data on the mixture is available or for example bridging principles or weight of evidence can be used for
classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section 9 for physical chemical properties, section 11
for toxicological information and section 12 for ecological information.
Full text of the R, H and EUH phrases mentioned in section 3:

•H302-Harmf ul i
fswal l
owed.
•H315-Caus ess k i
nirri
tation.
•H317-Mayc aus eanal lergics ki
nr eact
ion.
•H318-Caus ess eriousey edamage.
•H319-Caus ess eriousey ei r
ri
tat
ion.
•H400-Verytox ictoaquat icli
fe.
•H411-Toxi
ct oaquat icli
fewi t
hlongl ast
ingef
fect
s.
•R22-Harmful ifswal l
owed.
•R36-Ir
ri
tat
ingt oey es .
•R38-Ir
ri
tat
ingt os kin.
•R41-Riskofs eriousdamaget oey es.
•R43-Mayc aus es ens i
ti
s ationbys k i
ncontact
.
•R50-Verytox i
ct oaquat icor ganisms .
Abbreviations and acronyms:

•AISE-TheinternationalAs soci
ationforSoaps,Deter
gentsandMaint
enancePr
oduct
s
•DNEL-DerivedNoEf f
ec tLimit
•EUH-CLPSpec i
fi
chaz ar ds t
atement
•PBT-Persi
stent,Bioac cumul at
iveandTox ic
•PNEC-Predic t
edNoEf fec tConc ent
rati
on
•REACHnumber-REACHr egistr
ati
onnumber ,wi
thoutsuppl
i
erspeci
fi
cpar
t
•vPvB-ver
yPer s i
stentandver yBioaccumulat
ive
•ATE-AcuteTox ici
tyEs t
imat e
End of Safety Data Sheet
Page 11 / 11

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Safety Data Sheet

According to Regulation (EC) No 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

SECTION 2: Hazards identification

Eye Irrit. 2 (H319)

Classification in accordance with Directive 1999/45/EC and corresponding national legislation

2.2 Label elements

Signal word: Warning.

Contains EUH208: 1,2-benzisothiazol-3(2H)-one (Benzisothiazolinone)

2.3 Other hazards

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

Measures required to protect the environment:

Advices on general occupational hygiene:

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

Air limit values, if available:

Biological limit values, if available:

Recommended monitoring procedures, if available:

Additional exposure limits under the conditions of use, if available:

DNEL/DMEL and PNEC values

DNEL dermal exposure - Worker

DNEL dermal exposure - Consumer

DNEL inhalatory exposure - Worker (mg/m3)

DNEL inhalatory exposure - Consumer (mg/m3)

1,2-benzisothiazol-3(2H)-one No data available No data available No data available No data available

Environmental exposure - PNEC, continued

8.2 Exposure controls

Recommended safety measures for handling the undiluted product:

Appropriate engineering controls: Use only in well ventilated areas.

Personal protective equipment

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties

Substance data, boiling point

Substance data, flammability or explosive limits, if available:

Substance data, vapour pressure

Ingredient(s) Value Method Temperature

Substance data, solubility in water

9.2 Other information

Substance data, dissociation constant, if available:

SECTION 10: Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information