Sika Post Fix - (A-B) - E

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SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

SECTION 1. IDENTIFICATION

Product name : Sika® Post Fix Part A

Manufacturer or supplier's details


Company name : Sika Canada Inc.
601, avenue Delmar
Pointe-Claire, QC H9R 4A9
Canada
www.sika.ca

Telephone : (514) 697-2610 / 1 (800) 933-7452

Telefax : (514) 694-2792

Health and Safety Services’s : [email protected]


e-mail address

Emergency telephone : CANUTEC (collect) (613) 996-6666 (24 hours)

Recommended use of the chemical and restrictions on use


For further information, refer to product data sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4

Acute toxicity (Oral) : Category 4

GHS label elements


Hazard pictograms :

Signal Word : Warning

Hazard Statements : H227 Combustible liquid.


H302 Harmful if swallowed.

Precautionary Statements : Prevention:


P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ eye protection/ face protection.

1/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/doctor if you feel unwell. Rinse mouth.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 Store in a well-ventilated place.
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

Supplemental information
If product is in liquid or paste form, physical or health hazards listed related to dust are not con-
sidered significant. However, product may contain substances that could be potential hazards if
caused to become airborne due to grinding, sanding or other abrasive processes.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous ingredients
Chemical name CAS-No. Concentration (% w/w)
Propane-1,2-diol, propoxylated 25322-69-4 >= 20 - < 25

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.

If inhaled : Move to fresh air.


Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Remove contact lenses.


Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : No known significant effects or hazards.

2/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

and effects, both acute and Gastrointestinal discomfort


delayed See Section 11 for more detailed information on health effects
and symptoms.
Harmful if swallowed.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)

Unsuitable extinguishing : Water


media

Further information : Collect contaminated fire extinguishing water separately. This


must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.


tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.


fire and explosion

Advice on safe handling : Do not breathe vapors or spray mist.


Avoid exceeding the given occupational exposure limits (see
section 8).
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products.

3/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

Conditions for safe storage : Store in original container.


Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.
Protect from frost.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Contains no substances with occupational exposure limit values.
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits.

Personal protective equipment


Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.

The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection

Remarks : Chemical-resistant, impervious gloves complying with an


approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should


be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.


Wash hands before breaks and immediately after handling
the product.
Remove respiratory and skin/eye protection only after vapors
have been cleared from the area.

4/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

Remove contaminated clothing and protective equipment


before entering eating areas.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : green

Odor : mild

Odor Threshold : No data available

pH : not determined

Melting point/range / Freezing : No data available


point

Boiling point/boiling range : No data available

Flash point : ca. 86 °C (187 °F)


Method: closed cup

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : 0.01 hpa (0.01 mmHg)

Relative vapor density : No data available

Density : 1.018 g/ml (23 °C (73 °F) ())

Solubility(ies)
Water solubility : completely miscible

Partition coefficient: n- : No data available


octanol/water

Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s (40 °C)

Explosive properties : No data available

5/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.


tions

Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : Water


Alcohol
Amines
Acids and bases

No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if swallowed.
Product:
Acute oral toxicity : Acute toxicity estimate: 1,591 mg/kg
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg


Method: Calculation method

Skin corrosion/irritation
Not classified based on available information.
Serious eye damage/eye irritation
Not classified based on available information.
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
IARC Not applicable

NTP Not applicable

6/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not empty into drains; dispose of this material and its con-
mation tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste han-


dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

Domestic regulation
TDG (road/train)
Not dangerous goods
International Regulations

7/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

IATA-DGR
Not dangerous goods
IMDG-Code
Not dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Canadian lists
No substances are subject to a Significant New Activity Notification.

SECTION 16. OTHER INFORMATION

Revision Date : 05/19/2017


Prepared by : R & D of Sika Canada Inc.
Notice to Reader:
The information contained in this Material Safety Data Sheet applies only to the actual Sika Can-
ada product identified and described herein. This information is not intended to address, nor does
it address the use or application of the identified Sika product in combination with any other mate-
rial, product or process. All of the information set forth herein is based on technical data regarding
the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of
any Sika product, the user must always read and follow the warnings and instructions on the
product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY


ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY
PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sika.ca or 514-697-2610.
Full text of other abbreviations
ADR Accord européen relatif au transport international des marchandises
Dangereuses par Route
CAS Chemical Abstracts Service
DNEL Derived no-effect level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Code for Dangerous Goods
LD50 Median lethal dosis (the amount of a material, given all at once, which
causes the death of 50% (one half) of a group of test animals)
LC50 Median lethal concentration (concentrations of the chemical in air that
kills 50% of the test animals during the observation period)
MARPOL International Convention for the Prevention of Pollution from Ships, 1973

8/9
SAFETY DATA SHEET

Sika® Post Fix Part A

Version Revision Date: SDS Number:


1.4 05/19/2017 100000004613

as modified by the Protocol of 1978


OEL Occupational Exposure Limit
PBT Persistent, bioaccumulative and toxic
PNEC Predicted no effect concentration
REACH Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a
European Chemicals Agency
SVHC Substances of Very High Concern
vPvB Very persistent and very bioaccumulative

CA / Z8

9/9
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

SECTION 1. IDENTIFICATION

Product name : Sika® Post Fix Part B

Manufacturer or supplier's details


Company name : Sika Canada Inc.
601, avenue Delmar
Pointe-Claire, QC H9R 4A9
Canada
www.sika.ca

Telephone : (514) 697-2610 / 1 (800) 933-7452

Telefax : (514) 694-2792

Health and Safety Services’s : [email protected]


e-mail address

Emergency telephone : CANUTEC (collect) (613) 996-6666 (24 hours)

Recommended use of the chemical and restrictions on use


For further information, refer to product data sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Acute toxicity (Inhalation) : Category 4

Skin irritation : Category 2

Eye irritation : Category 2B

Respiratory sensitization : Category 1

Skin sensitization : Category 1

Specific target organ system- : Category 3 (Respiratory system)


ic toxicity - single exposure

Specific target organ system- : Category 2


ic toxicity - repeated expo-
sure (Inhalation)

GHS label elements

1 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H315 + H320 Causes skin and eye irritation.


H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing diffi-
culties if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or re-
peated exposure if inhaled.

Precautionary Statements : Prevention:


P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves.
P284 In case of inadequate ventilation wear respiratory protec-
tion.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P342 + P311 If experiencing respiratory symptoms: Call a
POISON CENTER/doctor.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

Supplemental information

2 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

If product is in liquid or paste form, physical or health hazards listed related to dust are not con-
sidered significant. However, product may contain substances that could be potential hazards if
caused to become airborne due to grinding, sanding or other abrasive processes.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous ingredients
Chemical name CAS-No. Concentration (% w/w)
4,4'-methylenediphenyl diisocyanate 101-68-8 >= 40 - < 50
Diphenylmethanediisocyanate, isomeres and 9016-87-9 >= 35 - < 45
homologues
o-(p-isocyanatobenzyl)phenyl isocyanate (MDI) 5873-54-1 >= 20 - < 25

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.

If inhaled : Move to fresh air.


Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Remove contact lenses.


Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : irritant effects


and effects, both acute and sensitizing effects
delayed Asthmatic appearance
Cough
Respiratory disorder
Allergic reactions
Headache
See Section 11 for more detailed information on health effects
and symptoms.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause respiratory irritation.

3 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

May cause damage to organs through prolonged or repeated


exposure if inhaled.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This


must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.


tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.


fire and explosion

Advice on safe handling : Avoid formation of aerosol.


Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.

4 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

Follow standard hygiene measures when handling chemical


products.

Conditions for safe storage : Store in original container.


Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.
Protect from frost.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters


Ingredients CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
4,4'-methylenediphenyl diiso- 101-68-8 TWA 0.005 ppm CA BC OEL
cyanate
C 0.01 ppm CA BC OEL
TWA 0.005 ppm CA ON OEL
C 0.02 ppm CA ON OEL
TWA 0.005 ppm CA AB OEL
0.05 mg/m3
TWAEV 0.005 ppm CA QC OEL
0.051 mg/m3
TWA 0.005 ppm ACGIH
Diphenylmethanediisocyanate, 9016-87-9 TWA 0.005 ppm CA AB OEL
isomeres and homologues 0.07 mg/m3
TWA 0.005 ppm CA BC OEL
C 0.01 ppm CA BC OEL
o-(p-isocyanatobenzyl)phenyl 5873-54-1 TWA 0.005 ppm CA ON OEL
isocyanate (MDI)
C 0.02 ppm CA ON OEL
TWA 0.005 ppm CA ON OEL
C 0.02 ppm CA ON OEL
TWA 0.005 ppm CA AB OEL
0.05 mg/m3
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.

Personal protective equipment


Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.

5 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection

Remarks : Chemical-resistant, impervious gloves complying with an


approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should


be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.


Wash hands before breaks and immediately after handling
the product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : brown

Odor : mild

Odor Threshold : No data available

pH : not determined

Melting point/range / Freezing : No data available


point

Boiling point/boiling range : No data available

Flash point : > 110 °C (230 °F)

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

6 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

Vapor pressure : No data available

Relative vapor density : No data available

Density : 1.240 g/ml (23 °C (73 °F) ())

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : No data available


octanol/water

Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s (40 °C)

Explosive properties : No data available

Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.


tions

Conditions to avoid : No data available

Incompatible materials : Isocyanates

No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if inhaled.
Product:
Acute inhalation toxicity : Acute toxicity estimate: 1.5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

7 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

Ingredients:
4,4'-methylenediphenyl diisocyanate:
Acute inhalation toxicity : Acute toxicity estimate: 1.5 mg/l
Test atmosphere: dust/mist
Method: Expert judgment

Diphenylmethanediisocyanate, isomeres and homologues:


Acute oral toxicity : LD50 Oral (Rat): > 10,000 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: 1.5 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgment

Acute dermal toxicity : LD50 Dermal (Rabbit): > 9,400 mg/kg

Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes eye irritation.
Respiratory or skin sensitization
Skin sensitization: May cause an allergic skin reaction.
Respiratory sensitization: May cause allergy or asthma symptoms or breathing difficulties if in-
haled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
IARC Not applicable

NTP Not applicable

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
May cause respiratory irritation.
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available

8 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

Persistence and degradability


No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not empty into drains; dispose of this material and its con-
mation tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste han-


dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

Domestic regulation
TDG (road/train)
Not dangerous goods
International Regulations
IATA-DGR
Not dangerous goods
IMDG-Code
Not dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Canadian lists
No substances are subject to a Significant New Activity Notification.

9 / 10
SAFETY DATA SHEET

Sika® Post Fix Part B

Version Revision Date: SDS Number:


1.6 05/19/2017 100000004158

SECTION 16. OTHER INFORMATION

Revision Date : 05/19/2017


Prepared by : R & D of Sika Canada Inc.
Notice to Reader:
The information contained in this Material Safety Data Sheet applies only to the actual Sika Can-
ada product identified and described herein. This information is not intended to address, nor does
it address the use or application of the identified Sika product in combination with any other mate-
rial, product or process. All of the information set forth herein is based on technical data regarding
the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of
any Sika product, the user must always read and follow the warnings and instructions on the
product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY


ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY
PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sika.ca or 514-697-2610.
Full text of other abbreviations
ADR Accord européen relatif au transport international des marchandises
Dangereuses par Route
CAS Chemical Abstracts Service
DNEL Derived no-effect level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Code for Dangerous Goods
LD50 Median lethal dosis (the amount of a material, given all at once, which
causes the death of 50% (one half) of a group of test animals)
LC50 Median lethal concentration (concentrations of the chemical in air that
kills 50% of the test animals during the observation period)
MARPOL International Convention for the Prevention of Pollution from Ships, 1973
as modified by the Protocol of 1978
OEL Occupational Exposure Limit
PBT Persistent, bioaccumulative and toxic
PNEC Predicted no effect concentration
REACH Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a
European Chemicals Agency
SVHC Substances of Very High Concern
vPvB Very persistent and very bioaccumulative

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