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    Tutorial VIII Ix

    Uploaded by

    Zaid Mansuri
    This document contains 6 problems related to vapor-liquid equilibrium: 1. Design a distillation column to separate 1-chlorobutane and chlorobenzene, and obtain pressure-composition-temperature data for the non-ideal system at 50°C. 2. Calculate activity coefficients and vapor pressure for an ethanol/toluene mixture given experimental vapor-liquid equilibrium data. 3. Determine if ethanol/benzene forms an azeotrope at 90°C, and if so calculate the composition and pressure. 4. Determine if a binary system exhibits an azeotrope given overall composition, activity coefficients, and vapor pressures. 5. Determine if

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    Tutorial VIII Ix

    Uploaded by

    Zaid Mansuri
    70 views1 page
    This document contains 6 problems related to vapor-liquid equilibrium: 1. Design a distillation column to separate 1-chlorobutane and chlorobenzene, and obtain pressure-composition-temperature data for the non-ideal system at 50°C. 2. Calculate activity coefficients and vapor pressure for an ethanol/toluene mixture given experimental vapor-liquid equilibrium data. 3. Determine if ethanol/benzene forms an azeotrope at 90°C, and if so calculate the composition and pressure. 4. Determine if a binary system exhibits an azeotrope given overall composition, activity coefficients, and vapor pressures. 5. Determine if

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    This document contains 6 problems related to vapor-liquid equilibrium: 1. Design a distillation column to separate 1-chlorobutane and chlorobenzene, and obtain pressure-composition-temperature data for the non-ideal system at 50°C. 2. Calculate activity coefficients and vapor pressure for an ethanol/toluene mixture given experimental vapor-liquid equilibrium data. 3. Determine if ethanol/benzene forms an azeotrope at 90°C, and if so calculate the composition and pressure. 4. Determine if a binary system exhibits an azeotrope given overall composition, activity coefficients, and vapor pressures. 5. Determine if

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    70 views1 page

    Tutorial VIII Ix

    Uploaded by

    Zaid Mansuri
    This document contains 6 problems related to vapor-liquid equilibrium: 1. Design a distillation column to separate 1-chlorobutane and chlorobenzene, and obtain pressure-composition-temperature data for the non-ideal system at 50°C. 2. Calculate activity coefficients and vapor pressure for an ethanol/toluene mixture given experimental vapor-liquid equilibrium data. 3. Determine if ethanol/benzene forms an azeotrope at 90°C, and if so calculate the composition and pressure. 4. Determine if a binary system exhibits an azeotrope given overall composition, activity coefficients, and vapor pressures. 5. Determine if

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 1

    Tutorial VIII-IX

    1. We need to design a distillation column for separating 1-chlorobutane (1) and


    chlorobenzene (2). Vapor Pressure of the pure species are given by the Antoine’s
    equation:

    2826 . 26
    ln Psat
    1 =13 .96−
    T +224 . 10
    3295 .12
    ln Psat
    2 =13 .9926−
    T +217 .55 Pisat’s in kPa and T in C

    For the design purpose we need p-x-y data for the above system. Obtain p-x-y table at
    50C (minimum 7 data points). It is known that the system is non ideal in nature and
    activity coefficients are given by, ln γ 1= A x 22 and ln γ 2= A x 21, with A=1.23.

    2. An experimental determination of a VLE state for the ethanol/toluene system gave the
    following results: standard Vapor Pressure at 45C, ethanol = 173 mm Hg, toluene =
    75.4 mm Hg, x1 = 0.3; y1 = 0.634; PT = 183 mm Hg. Calculate (i) the liquid phase
    activity coefficients (ii) What pressure would be exerted by the mixture having liquid
    composition 0.5 at 45C ?

    3. Check weather the following system will form an azeotrope or not ? Ethanol
    (1)/Benzene (2) at T=900 C . Given that 1n1 = 1.66X22. If yes , find the azeotropc
    composition and pressure.

    4. A binary system of species 1 and 2 consists of vapor and liquid phases in equilibrium
    at temp. T. The overall mole fraction of species 1 in the system is Z 1 = 0.65. At temp.
    T, (a) 1n 1 = 0.67 X22 and 1n 2 = 0.67 X12 (b) P1sat = 32.27 kPa and P2sat = 73.14 kPa.
    Assuming system follows modified Raoult’s law. Show whether or not the system
    exhibits an azeotrope. If yes , find the azeotropc composition and pressure.

    5. Check whether the system ethyle ethanoate(1)/n-heptane(2) at 343.15 K forms


    2 2
    azeotrope or not ? Given that for this system,(i) ln γ 1 =0 .95 x 2 and ln γ 2 =0 . 95 x 1 (ii)
    P1sat=79.80 kPa and P2sat=40.50 kPa.

    6. Water (1)/ hydrazine (2) system forms an azeotrope containing 58.5% (mole)
    hydrazine at 393 K and 101.3 kPa. The vapor pressure of hydrazine at 393 K is
    124.76 kPa. With this much information determine equilibrium vapor composition for
    a liquid solution containing 20% (mol) hydrazine. The ratio of vapor pressure of water
    to that of hydrazine is 1.6 and may be assumed to remain constant in the temperature
    range involved. It is also given that, normal boiling points of water is 100C and that
    2
    of hydrazine is 114C. Assume that the system is well represented by ln γ 1 =Ax 2 .

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