8 3FormulasIonicComp

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Writing Formulas: Ionic Compounds Name ________________

Chem Worksheet 8-3


Ionic compounds are composed of a positive ion and a negative ion bonded together in a specific
proportion. For example, magnesium chloride is made of one magnesium ion (Mg2+) and two chloride
ions (Cl1–). These two ions are combined in a ratio that creates a neutral compound (MgCl2). The 2+
charge on the magnesium ion is balanced by the two negative charges from the chloride ions. All ionic
compounds follow this rule: the charge from the positive ions must be equal to the charge from the
negative ions.
In a compound of aluminum ion (Al3+) and nitrate ion (NO31–) there must be three nitrate ions. So,
the formula for this compound is Al(NO3)3. Recall that nitrate is a polyatomic ion, so this combination
of atoms remains intact when writing a chemical formula. Also notice that the proper way to designate
more than one polyatomic ion involves the use of parenthesis.
An easy technique for creating a neutral combination of two charged ions is called the criss-cross
technique. When writing a formula for an ionic compound the charges from each ion are simply
switched to become the subscript values written to designate the number of atoms present in a
compound. See the example below. Common Polyatomic Ions
NH4+ Ammonium
OH1– Hydroxide
The Criss-Cross Technique CN1– Cyanide
NO31– Nitrate
ClO31– Chlorate
Write the chemical formula for calcium phosphide. C2H3O21– Acetate
SO42– Sulfate
CO32– Carbonate
Ca2+ P3– Ca3P2 PO43– Phosphate
HCO31– Bicarbonate
HSO41– Bisulfate

Write the chemical formulas for the following ionic compounds. Remember all ionic compounds
must be neutral.
Formula Name Formula Name
1. Potassium oxide 13. Magnesium bicarbonate
2. Sodium sulfide 14. Zinc hydroxide
3. Ammonium chloride 15. Potassium phosphate
4. Calcium nitrate 16. Aluminum acetate
5. Iron (II) bromide 17. Mercury (II) chloride
6. Chromium (III) hydroxide 18. Strontium sulfate
7. Copper (II) sulfate 19. Silver sulfide
8. Aluminum iodide 20. Iron (II) phosphate
9. Ammonium carbonate 21. Calcium nitride
10. Lithium bisulfate 22. Lead (IV) oxide
11. Manganese (III) oxide 23. Copper (I) carbonate
12. Tin (IV) chlorate 24. Ammonium acetate
© John Erickson, 2006 WS8-3WritingFormulasIonic

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