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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
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SDS # : 086288
ASB 1292

Date of the previous version: 2017-02-10 Revision Date: 2017-11-20 Version 3

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product name ASB 1292

Substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses H2S scavenger additive,

, Additive for crude oil and heavy fuel oil.

1.3. Details of the supplier of the safety data sheet

Supplier A - TOTAL UK LIMITED

183 Eversholt St, Kings Cross
London, NW1 1BU
UNITED KINGDOM
Tel: +44 (0)20 7339 8000
Fax: +44 (0)20 7339 8033

B - TOTAL ADDITIFS ET CARBURANTS SPECIAUX

Place du Bassin
69700 Givors
FRANCE
Tel: +33 (0) 4 72 49 27 00
Fax: +33 (0) 4 78 07 92 49

For further information, please contact:

Contact Point A - HSE

B - service HSE
E-mail Address A - [email protected]

B - [email protected]

1.4. Emergency telephone number

Emergency telephone: +44 1235 239670

UK: National Poisons Information Service (NPIS): NHS on 111 or a doctor

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

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REGULATION (EC) No 1272/2008

For the full text of the H-Statements mentioned in this Section, see Section 2.2.

Classification
Acute oral toxicity - Category 4 - (H302)
Acute inhalation toxicity - dust/mist - Category 4 - (H332)
Skin corrosion/irritation - Category 1 Subcategory C - (H314)

2.2. Label elements

Labelled according to REGULATION (EC) No 1272/2008

Contains 3,3'-methylenebis[5-methyloxazolidine]

EC-No 266-235-8

Hazard pictograms

Signal word
DANGER

Hazard Statements
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H332 - Harmful if inhaled

Precautionary statements
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTRE/doctor
P331 - Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTRE/doctor

2.3. Other hazards

Physical-Chemical Properties Contaminated surfaces will be extremely slippery.

Environmental properties Should not be released into the environment.

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Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substance

3.2. Mixture

Hazardous components
Chemical Name EC-No REACH CAS-No Weight % Classification (Reg. 1272/2008)
Registration
Number
3,3'-methylenebis[5-methylo 266-235-8 - 66204-44-2 90 - 100 Skin Corr. 1C (H314)
xazolidine] Acute Tox. 4 (H302)
Acute Tox. 4 (H332)

For the full text of the H-Statements mentioned in this Section, see Section 16.

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR

EMERGENCY MEDICAL CARE. Show this safety data sheet to the doctor in attendance.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Consult a physician.

Skin contact For severe burns, immediate medical attention is required. Wash off immediately with soap
and plenty of water while removing all contaminated clothes and shoes. Wash
contaminated clothing before reuse.

Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Inhalation of high concentrations of vapour or aerosols may cause irritation of the upper
respiratory tract. If not breathing, give artificial respiration. Consult a physician.

Ingestion Clean mouth with water. Do not induce vomiting without medical advice. Never give
anything by mouth to an unconscious person. If symptoms persist, call a physician.

Protection of first-aiders Wear self-contained breathing apparatus and protective suit. Use personal protective
equipment.

4.2. Most important symptoms and effects, both acute and delayed

Eye contact Causes serious eye damage.

Skin contact Causes skin burns.

Inhalation Harmful by inhalation.

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Ingestion Harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media Water spray, fog or regular foam. Dry chemical. Foam. Carbon dioxide (CO 2). Cool
containers / tanks with water spray.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special hazard Thermal decomposition can lead to release of irritating gases and vapours. Incomplete
combustion and thermolysis may produce gases of varying toxicity such as carbon
monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly
dangerous if inhaled in confined spaces or at high concentration.

5.3. Precautions for fire-fighters

Special protective equipment for In case of a large fire or in confined or poorly ventilated spaces, wear full fire resistant
fire-fighters protective clothing and self-contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.

Other information Cool down any tanks and surfaces exposed to fire by spraying abundantly with water. Use
water to cool tanks and parts exposed to the thermal flux not caught up in the flames. Do
not allow run-off from fire fighting to enter drains or water courses. Fire residues and
contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information The feasibility of any actions should always be assessed and advised, if possible, by a
trained, competent person in charge of managing the emergency.
If required, notify relevant authorities according to all applicable regulations.
Evacuate non-essential personnel. For personal protection see section 8.
Stop or contain leak at the source, if safe to do so. Cut off the electric power supply if this
operation causes no sparks in the area containing vapours from the product. Stay upwind.
In case of large spillages, alert occupants in downwind areas. ELIMINATE all ignition
sources (no smoking, flares, sparks or flames in immediate area). In case of important
spillages: risk of fire or explosion . Cover discharges with foam in order to reduce the risks
of ignition. Vapours are heavier than air and may spread near ground level to sources of
ignition.

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Advice for non-emergency Do not touch or walk through spilled material. Evacuate personnel to safe areas. For
personnel personal protection see section 8. ELIMINATE all ignition sources (no smoking, flares,
sparks or flames in immediate area).

Advice for emergency responders Take all appropriate steps to avoid fire, explosion and inhalation hazards to the rescuers
including the use of breathing apparatus. Work gloves (preferably gauntlets) providing
adequate chemical resistance. Antistatic non-skid safety shoes or boots.

6.2. Environmental precautions

General Information Do not allow material to contaminate ground water system. Local authorities should be
advised if significant spillages cannot be contained. The product should not be allowed to
enter drains, water courses or the soil.
Prevention of fire and explosion. A vapour suppressing foam may be used to reduce
vapours. Most vapours are heavier than air. They will spread along ground and collect in
low or confined areas (sewers, basements, tanks). Beware of vapours accumulating to form
explosive concentrations. Vapours can accumulate in low areas. In case of spill in river,
suspend the use of the water downstream to the spillpoint.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Dam up. Ground and bond containers when transferring material. Keep in suitable, closed
containers for disposal.
Contain spillage, and then collect with non-combustable absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

6.4. Reference to other sections

Personal protective equipment See Section 8 for more detail.

Waste treatment See section 13.

Other information recommended measures are based on the most likely spillage scenarios for this material.
However, local conditions (wind, air temperature, wave/current direction and speed) may
significantly influence the choice of appropriate actions.
For this reason, local experts should be consulted when necessary.
Local regulations may also prescribe or limit actions to be taken.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling Loading / Unloading temperature between 10 °C / 25 °C.

Handle in accordance with good industrial hygiene and safety practise. Use only in area
provided with appropriate exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment. NEVER ATTEMPT TO PRIME THE CONTAINER SIPHON
BY SUCKING WITH THE MOUTH. Avoid contact with skin, eyes and clothing. Prevent the
formation of vapors, mists and aerosols. Take precautionary measures against static
electricity. Ensure that all relevant regulations regarding explosive atmospheres, and
handling and storage facilities of flammable products, are followed. The inspection, cleaning
and maintenance of storage containers require the application of strict procedures and must

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be entrusted to qualified personnel (internal or external). Ensure adequate ventilation. Do
not smoke. Avoid breathing vapours or mists. Always wear a self-contained breathing
apparatus or full-face airline respirator when using this chemical. Never pierce, drill, grind,
cut, saw or weld any empty container. Do not use compressed air for filling, discharging, or
handling operations. For personal protection see section 8.

Technical measures Ensure adequate ventilation.

WHILE MOVING THE PRODUCT:. To avoid ignition of vapours by static electricity
discharge, all metal parts of the equipment must be grounded.
Take all necessary precautions to prevent water from entering the containers, tanks,
transfer lines etc...

Prevention of fire and explosion Keep away from open flames, hot surfaces and sources of ignition. Design installations
(machinery and equipment) to prevent burning product from spreading (tanks, retention
systems, interceptors (traps) in drainage systems). OPERATE ONLY ON COLD AND
DEGASSED TANKS IN VENTILATED PREMISES (TO AVOID RISK OF EXPLOSION). Do
not use compressed air for filling, discharging or handling. Empty containers may contain
flammable or explosive vapours. Do not allow splash loading and ensure that the product is
poured slowly, particularly at the beginning of the operation.

Hygiene measures Wear personal protective equipment. When using, do not eat, drink or smoke.
Provide regular cleaning of equipment, work area and clothing. Avoid contact with skin,
eyes and clothing. Wash hands before breaks and immediately after handling the product.
Keep away from food, drink and animal feeding stuffs. Regular cleaning of equipment, work
area and clothing is recommended. Ensure the application of strict rules of hygiene by the
personnel exposed to the risk of contact with the product.
Use personal protective equipment as required. Avoid breathing vapours, mist or gas. IF
ON SKIN: Wash skin with soap and water.
Remove contaminated clothing and shoes. Gloves must be periodically inspected and
changed in case of wear, perforations or contaminations.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep at temperatures between 10 and 25 °C.

conditions

Materials to avoid Strong acids. Strong bases. Strong oxidising agents. Strong reducing agents.

Packaging material Stainless steel. High density polyethylene (HDPE). Glass.

7.3. Specific use(s)

Specific use(s) Must not be used for cleaning processes. Restricted to professional users.

Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parametres

Exposure limits Components with workplace control parametres

Legend See section 16

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8.2. Exposure controls

Occupational Exposure Controls

Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.

Personal protective equipment

General Information These recommendations apply to the product as supplied. If the product is used in mixtures,
it is recommended that you contact the appropriate protective equipment suppliers.
Protective engineering solutions should be implemented and in use before personal
protective equipment is considered.

Respiratory protection For rescue and maintenance work in storage tanks use self-contained breathing apparatus.
. In the case of vapour formation use a respirator with filter model AB.

Eye protection If splashes are likely to occur, wear:. Safety glasses with side-shields. EN 166.

Skin and body protection Impermeable gloves. impervious clothing. Boots. Long sleeved clothing. Chemical resistant
apron. Antistatic boots. Wear suitable protective clothing. Protective shoes or boots.

Hand protection Please observe the instructions regarding permeability and breakthrough time which are
provided by the supplier of the gloves. Also take into consideration the specific local
conditions under which the product is used, such as the danger of cuts, abrasion, and the
contact time. If used in solution, or mixed with other substances, and under conditions
which differ from EN 374, contact the supplier of the EC approved gloves. Impermeable
gloves. Nitrile rubber.

Repeated or prolonged exposure

Glove material Glove thickness Break through time Remarks
butyl-rubber 0.70mm >480

In case of contact through splashing:

Glove material Glove thickness Break through time Remarks
Nitrile rubber 0.11mm

Environmental exposure controls

General Information Do not allow material to contaminate ground water system.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Colour colourless
Physical state @20°C liquid
Odour ammoniacal
Odour Threshold No information available

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Property Values Remarks Method
pH 10 @ 20 °C
Melting point/range Not applicable

Boiling point/boiling range No information available

Flash point > 100 °C ISO 2719

> 212 °F ISO 2719
Evapouration rate > 1 Not applicable
Flammability Limits in Air No information available

Vapour pressure < 100 hPa EN 13016-1

Vapour density Not applicable
Relative density 1.04 - 1.06
Density 1049 - 1069 kg/m3 @ 15 °C ISO 12185
Water solubility No information available
Solubility in other solvents No information available
logPow Not applicable
Autoignition temperature No information available

Decomposition temperature No information available

Viscosity, kinematic No information available
Explosive properties Not explosive
Oxidising properties Not applicable
Possibility of hazardous reactions None under normal processing

9.2. Other information

Freezing point No information available

Pour point < -30 °C ASTM D97

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

General Information No information available.

10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Heat, flames and sparks. Take precautionary measures against static discharges. Heating
in air.

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10.5. Incompatible materials

Materials to avoid Strong acids. Strong bases. Strong oxidising agents. Strong reducing agents.

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products None under normal use. Incomplete combustion and thermolysis may produce gases of
varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes
and soot.
formaldehyde.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity Local effects Product Information

Skin contact . Causes skin burns.

Eye contact . Causes serious eye damage.

Inhalation . Harmful by inhalation.

Ingestion . Harmful if swallowed.

Acute toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

3,3'-methylenebis[5-methyloxazolidine] LD50 900 mg/kg (Rat) LC50 (4h) 2 mg/l (Rat - Dust/mist
- OECD 436)
Sensitisation

Sensitisation None known.

Specific effects

Carcinogenicity No known effect based on information supplied.

Mutagenicity The current toxicological knowledge allows to not classify the product as a mutagen.
Reproductive toxicity None known.

Repeated dose toxicity

Subchronic Toxicity No information available.

Target Organ Effects (STOT)

Target Organ Effects (STOT) No information available.

Specific target organ toxicity - No information available.

repeated exposure

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Other information

Neurological effects No information available.

Other adverse effects No information available.

Other information No information available.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Not classified.

Acute aquatic toxicity - Product Information

No information available.

Acute aquatic toxicity - Component Information

Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic microorganisms
invertebrates.
3,3'-methylenebis[5-methylo EC50 (72h) 5.7 mg/l EC50 (48h) 37.9 mg/l LC50 (96h) 57.7 mg/l
xazolidine] (Desmodesmus (Daphnia magna) (Brachydanio rerio)
66204-44-2 subspicatus)

Chronic aquatic toxicity - Product Information

No information available.

Chronic aquatic toxicity - Component Information

.

Effects on terrestrial organisms

No information available.

12.2. Persistence and Degradability

General Information
Readily biodegradable.

12.3. Bioaccumulative potential

Product Information No information available.

logPow Not applicable

Component Information .
Chemical Name log Pow
3,3'-methylenebis[5-methyloxazolidine] - 66204-44-2 -0.3

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12.4. Mobility in soil

Soil No information available.

Air No information available.

Water No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment This preparation contains no substance considered to be persistent, bioaccumulating nor
toxic (PBT).

12.6. Other adverse effects

General Information No information available.

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues / unused Should not be released into the environment. Dispose of in accordance with the European
products Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated packageing Empty containers may contain flammable or explosive vapours. Do not burn, or use a
cutting torch on, the empty drum. Empty containers should be taken to an approved waste
handling site for recycling or disposal.

EWC Waste Disposal No According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used.

Section 14: TRANSPORT INFORMATION

ADR/RID
UN/ID No UN2735
Hazard Class 8
Packing group III
ADR/RID-Labels 8
Classification Code C7
Special Provisions 274
Tunnel restriction code (E)
ADR Hazard Id (Kemmler 80
Number)
Description UN2735, AMINES, LIQUID, CORROSIVE, N.O.S.
(3,3'-methylenebis[5-methyloxazolidine]), 8, III
Excepted Quantity E1
Limited quantity 5L

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IMDG/IMO
UN/ID No UN2735
Proper shipping name Amines, liquid, corrosive, n.o.s.
Hazard Class 8
Packing group III
Marine pollutant NP
EmS F-A, S-B
Description UN2735, Amines, liquid, corrosive, n.o.s. (3,3'-methylenebis[5-methyloxazolidine]), 8, III
Special Provisions 223, 274
Excepted Quantity E1
Limited quantity 5L

ICAO/IATA
UN/ID No UN2735
Hazard Class 8
Proper shipping name Amines, liquid, corrosive, n.o.s.
Packing group III
ERG Code 8L
Special Provisions A3, A803
Description UN2735, Amines, liquid, corrosive, n.o.s. (3,3'-methylenebis[5-methyloxazolidine]), 8, III
Excepted Quantity E1
Limited quantity 1L

ADN
UN/ID No UN2735
Hazard Class 8
Hazard Labels 8
Packing group III
Classification Code C7
Special Provisions 274
Description UN2735, AMINES, LIQUID, CORROSIVE, N.O.S.
(3,3'-methylenebis[5-methyloxazolidine]), 8, III
Excepted Quantity E1
Limited quantity 5L

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

European Union

REACH
This mixture contains only ingredients which have been registered according to Regulation (EC) No. 1907/2006 (REACH)

Other regulations
DIRECTIVE 2010/75/EU on industrial emissions
Directive 2004/37/EC of the European Parliament and of the Council of 29 April 2004 on the protection of workers from the risks
related to exposure to carcinogens or mutagens at work

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International Inventories All the substances contained in this product are listed or exempted from listing in the
following inventories:
Europe (EINECS/ELINCS/NLP)
U.S.A. (TSCA)
Canada (DSL/NDSL)
Australia (AICS)
China (IECSC)
Korea (KECL)
Philippines (PICCS)
New Zealand (NZIoC)
Taiwan (TCSI)

Further information

No information available

15.2. Chemical Safety Assessment

Chemical Safety Assessment No information available

15.3. National regulatory information

The United Kingdom

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Section 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3

H314 - Causes severe skin burns and eye damage
H302 - Harmful if swallowed
H332 - Harmful if inhaled

Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists
bw = body weight
bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LL = Lethal Loading
NIOSH = National Institute of Occupational Safety and Health

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NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
OECD = Organization for Economic Co-operation and Development
OSHA = Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
dw = dry weight
fw = fresh water
mw = marine water
or = occasional release

Legend Section 8

TWA: Time Weight Average

STEL: Short Time Exposure Limit

+ Sensitiser * Skin designation

** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction

Revision Date: 2017-11-20

Revision Note (M)SDS sections updated. 1. 3. 9. 8. 15. 16.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
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This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

End of Safety Data Sheet

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