SAFETY DATA SHEET

Creation Date 01-Sep-2009 Revision Date 14-Dec-2020 Revision Number 18

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product Description: Isopropanol

Cat No. : 149320000; 149320010; 149320025; 149320050; 149320100; 149320250
Synonyms 2-Propanol; IPA; Isopropyl alcohol; Propan-2-ol; Isopropanol
CAS-No 67-63-0
EC-No. 200-661-7
Molecular Formula C3 H8 O
Reach Registration Number 01-2119457558-25

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Laboratory chemicals.

Sector of use SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites
Product category PC21 - Laboratory chemicals
Process categories PROC15 - Use as a laboratory reagent
Environmental release category ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)
Uses advised against No Information available

1.3. Details of the supplier of the safety data sheet

Company UK entity/business name

Fisher Scientific UK
Bishop Meadow Road, Loughborough,
Leicestershire LE11 5RG, United Kingdom

EU entity/business name
Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium

E-mail address [email protected]

1.4. Emergency telephone number

For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

CLP Classification - Regulation (EC) No 1272/2008

Physical hazards

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Flammable liquids Category 2 (H225)

Health hazards

Serious Eye Damage/Eye Irritation Category 2 (H319)

Specific target organ toxicity - (single exposure) Category 3 (H336)

Environmental hazards
Based on available data, the classification criteria are not met

Full text of Hazard Statements: see section 16

2.2. Label elements

Signal Word Danger

Hazard Statements
H225 - Highly flammable liquid and vapor
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness

Precautionary Statements
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 - Ground and bond container and receiving equipment
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing

2.3. Other hazards

Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB)

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances

Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No

1272/2008
Isopropyl alcohol 67-63-0 200-661-7 >95 Flam. Liq. 2 (H225)
Eye Irrit. 2 (H319)
STOT SE 3 (H336)

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Reach Registration Number 01-2119457558-25

Full text of Hazard Statements: see section 16

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if
symptoms occur.

Ingestion Do NOT induce vomiting. Get medical attention.

Inhalation Remove to fresh air. Get medical attention. If not breathing, give artificial respiration.

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination.

4.2. Most important symptoms and effects, both acute and delayed

Difficulty in breathing. May cause central nervous system depression: Inhalation of high
vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea
and vomiting

4.3. Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically. Symptoms may be delayed.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media

CO 2, dry chemical, dry sand, alcohol-resistant foam. Water mist may be used to cool closed containers.

Extinguishing media which must not be used for safety reasons

Do not use water jetstream. Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.
Containers may explode when heated.

Hazardous Combustion Products

Carbon monoxide (CO), Carbon dioxide (CO2), peroxides.

5.3. Advice for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

SECTION 6: ACCIDENTAL RELEASE MEASURES

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6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective equipment as required. Remove all sources of ignition. Take precautionary measures against static
discharges. Avoid contact with skin, eyes or clothing.

6.2. Environmental precautions

Should not be released into the environment. See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Take
precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. Keep in suitable, closed
containers for disposal.

6.4. Reference to other sections

Refer to protective measures listed in Sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Wear personal protective equipment/face protection. Keep away from open flames, hot surfaces and sources of ignition. Use
spark-proof tools and explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static
discharges. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. To avoid ignition of vapors by static
electricity discharge, all metal parts of the equipment must be grounded.

Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before
re-use. Wash hands before breaks and after work.

7.2. Conditions for safe storage, including any incompatibilities

Keep away from heat, sparks and flame. Flammables area. Keep container tightly closed in a dry and well-ventilated place.

Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Class 3
(Germany)

7.3. Specific end use(s)

Use in laboratories

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure limits
List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. IRE - 2018 Code of Practice for the Chemical
Agents Regulations, Schedule 1. Published by the Health and Safety Authority

Component The United Kingdom European Union Ireland

Isopropyl alcohol STEL: 500 ppm 15 min TWA: 200 ppm 8 hr.
STEL: 1250 mg/m3 15 min STEL: 400 ppm 15 min
TWA: 400 ppm 8 hr Skin
TWA: 999 mg/m3 8 hr

Biological limit values

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List source(s):

Monitoring methods
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of
exposure to chemical and biological agents.
MDHS70 General methods for sampling airborne gases and vapours
MDHS 88 Volatile organic compounds in air. Laboratory method using diffusive samplers, solvent desorption and gas
chromatography
MDHS 96 Volatile organic compounds in air - Laboratory method using pumped solid sorbent tubes, solvent desorption and gas
chromatography

Derived No Effect Level (DNEL) See table for values

Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects
(systemic) (local) (systemic)
Oral
Dermal 888 mg/kg
Inhalation 500 mg/m3

Predicted No Effect Concentration According to our experience and to the information provided to us, the product does not
(PNEC) have any harmful effects if it is used and handled as specified. See values below.

Fresh water 140.9 mg/l

Fresh water sediment 552 mg/kg
Marine water 140.9 mg/l
Water Intermittent 140.9 mg/l
Food chain 160 mg/kg
Microorganisms in sewage 2251 mg/l
treatment
Soil (Agriculture) 28 mg/kg

8.2. Exposure controls

Engineering Measures
Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof
electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas.
Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or
equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to
control hazardous materials at source

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments

Butyl rubber > 480 minutes 0.5 mm EN 374 Permeation rate < 0.9 µg/cm2/min
Nitrile rubber > 360 - 480 minutes 0.35 - 0.55 mm As tested under EN374-3 Determination of
Resistance to Permeation by Chemicals
Viton (R) > 480 minutes 0.4 mm
Neoprene < 40 minutes 0.7 mm
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure

Inspect gloves before use.

Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.
sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion.

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Remove gloves with care avoiding skin contamination.

Respiratory Protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.
To protect the wearer, respiratory protective equipment must be the correct fit and be used
and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced
Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to
EN14387

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure
limits are exceeded or if irritation or other symptoms are experienced.
Recommended half mask:- Valve filtering: EN405; Half mask: EN140; plus filter, EN 141
When RPE is used a face piece Fit Test should be conducted

Environmental exposure controls No information available.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical State Liquid

Appearance Colorless
Odor Alcohol-like
Odor Threshold No data available
Melting Point/Range -89.5 °C / -129.1 °F
Softening Point No data available
Boiling Point/Range 81 - 83 °C / 177.8 - 181.4 °F @ 760 mmHg
Flammability (liquid) Highly flammable On basis of test data
Flammability (solid,gas) Not applicable Liquid
Explosion Limits Lower 2 Vol%
Upper 12 Vol%
Flash Point 12 °C / 53.6 °F Method - Abel Closed Cup (BS 2000 Part 170, IP
170, AS/NZS 2106)
Autoignition Temperature 425 - °C / 797 - °F ASTM E-659
Decomposition Temperature No data available
pH 7 1% aq. sol
Viscosity 2.27 mPa.s at 20 °C
Water Solubility Miscible
Solubility in other solvents No information available
Partition Coefficient (n-octanol/water)
Component log Pow
Isopropyl alcohol 0.05
Vapor Pressure 43 mmHg @ 20 °C
Density / Specific Gravity 0.785 ASTM D-4052
Bulk Density Not applicable Liquid
Vapor Density 2.1 @ 20 °C / 68 °F (Air = 1.0)
Particle characteristics Not applicable (liquid)

9.2. Other information

Molecular Formula C3 H8 O
Molecular Weight 60.1
VOC Content(%) 100% (Organic Carbon (by mass) = 59.9 %) (EC/1999/13)
Explosive Properties Not explosive explosive air/vapour mixtures possible Vapors may form explosive mixtures
with air
Evaporation Rate 1.7 - ASTM D 3539 (Butyl acetate = 1.0)
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Thermal conductivity 0.137 W/m °C at 20 °C / 68 °F
Refractive index 1.377 at 20 °C / 68 °F (ASTM D-1218)
Surface tension 22.7 mN/m at 20 °C / 68 °F
Coefficient of expansion 0.0009 / °C
Specific heat capacity 3 kJ/kg °C at 20 °C / 68 °F
Dielectric constant 18.6 at 20 °C / 68 °F
Heat of vapourisation 665 J/g

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
None known, based on information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

10.4. Conditions to avoid

Heat, flames and sparks. Keep away from open flames, hot surfaces and sources of
ignition.

10.5. Incompatible materials

Strong oxidizing agents. Acids. Halogens. Acid anhydrides.

10.6. Hazardous decomposition products

Carbon monoxide (CO). Carbon dioxide (CO2). peroxides.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Product Information

(a) acute toxicity;

Oral Based on available data, the classification criteria are not met
Dermal Based on available data, the classification criteria are not met
Inhalation Based on available data, the classification criteria are not met

Component LD50 Oral LD50 Dermal LC50 Inhalation

Isopropyl alcohol 5045 mg/kg ( Rat ) 12800 mg/kg ( Rat ) 72.6 mg/L ( Rat ) 4 h
3600 mg/kg ( Mouse )

(b) skin corrosion/irritation; Based on available data, the classification criteria are not met

(c) serious eye damage/irritation; Category 2

(d) respiratory or skin sensitization;

Respiratory Based on available data, the classification criteria are not met
Skin Based on available data, the classification criteria are not met

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(e) germ cell mutagenicity; Based on available data, the classification criteria are not met

(f) carcinogenicity; Based on available data, the classification criteria are not met
There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; Based on available data, the classification criteria are not met

(h) STOT-single exposure; Category 3

Results / Target organs Central nervous system (CNS).

(i) STOT-repeated exposure; Based on available data, the classification criteria are not met

Target Organs None known.

(j) aspiration hazard; Based on available data, the classification criteria are not met

Symptoms / effects,both acute and May cause central nervous system depression. Inhalation of high vapor concentrations may
delayed cause symptoms like headache, dizziness, tiredness, nausea and vomiting.

11.2. Information on other hazards

Endocrine Disrupting Properties Assess endocrine disrupting properties for human health. This product does not contain any
known or suspected endocrine disruptors.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
Ecotoxicity effects . Do not empty into drains.

Component Freshwater Fish Water Flea Freshwater Algae

Isopropyl alcohol LC50: = 9640 mg/L, 96h 13299 mg/L EC50 = 48 h EC50: > 1000 mg/L, 96h
flow-through (Pimephales 9714 mg/L EC50 = 24 h (Desmodesmus subspicatus)
promelas) EC50: > 1000 mg/L, 72h
LC50: > 1400000 µg/L, 96h (Desmodesmus subspicatus)
(Lepomis macrochirus)
LC50: = 11130 mg/L, 96h static
(Pimephales promelas)
LC50: = 10000000 µg/L, 96h
(Daphnia)

Component Microtox M-Factor

Isopropyl alcohol = 35390 mg/L EC50 Photobacterium phosphoreum
5 min

12.2. Persistence and degradability Expected to be biodegradable

Persistence Persistence is unlikely, based on information available.

12.3. Bioaccumulative potential Bioaccumulation is unlikely

Component log Pow Bioconcentration factor (BCF)

Isopropyl alcohol 0.05 No data available
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12.4. Mobility in soil The product contains volatile organic compounds (VOC) which will evaporate easily from all
surfaces Will likely be mobile in the environment due to its volatility. Disperses rapidly in
air
Surface tension 22.7 mN/m at 20 °C / 68 °F

12.5. Results of PBT and vPvB Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent
assessment and very bioaccumulative (vPvB).

12.6. Endocrine disrupting

properties
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant This product does not contain any known or suspected substance
Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives
Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and
empty container away from heat and sources of ignition.

European Waste Catalogue (EWC) According to the European Waste Catalog, Waste Codes are not product specific, but
application specific.
Other Information Waste codes should be assigned by the user based on the application for which the product
was used. Do not flush to sewer. Can be landfilled or incinerated, when in compliance with
local regulations.

SECTION 14: TRANSPORT INFORMATION

IMDG/IMO

14.1. UN number UN1219

14.2. UN proper shipping name Isopropanol (Isopropyl alcohol)
14.3. Transport hazard class(es) 3
14.4. Packing group II

ADR

14.1. UN number UN1219

14.2. UN proper shipping name Isopropanol (Isopropyl alcohol)
14.3. Transport hazard class(es) 3
14.4. Packing group II

IATA

14.1. UN number UN1219

14.2. UN proper shipping name Isopropanol
14.3. Transport hazard class(es) 3
14.4. Packing group II

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14.5. Environmental hazards No hazards identified

14.6. Special precautions for user No special precautions required

14.7. Maritime transport in bulk Not applicable, packaged goods

according to IMO instruments

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

International Inventories
X = listed, Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), China (IECSC), Japan (ENCS), Australia
(AICS), Korea (ECL).

Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS IECSC AICS KECL
Isopropyl alcohol 200-661-7 - X X - X X X X KE-2936
3

Regulation (EC) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and
import of dangerous chemicals
Not applicable

National Regulations

WGK Classification See table for values

Component Germany - Water Classification (VwVwS) Germany - TA-Luft Class

Isopropyl alcohol WGK1

Component France - INRS (Tables of occupational diseases)

Isopropyl alcohol Tableaux des maladies professionnelles (TMP) - RG 84
UK - Take note of Control of Substances Hazardous to Health Regulations (COSHH) 2002 and 2005 Amendment

15.2. Chemical safety assessment

A Chemical Safety Assessment/Report (CSA/CSR) has been conducted by the manufacturer/importer

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3

H225 - Highly flammable liquid and vapor
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness

Legend

CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b)
Inventory
EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic
Substances/EU List of Notified Chemical Substances Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances
IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

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WEL - Workplace Exposure Limit TWA - Time Weighted Average
ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer
DNEL - Derived No Effect Level Predicted No Effect Concentration (PNEC)
RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50%
LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50%
NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water
PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ADR - European Agreement Concerning the International Carriage of ICAO/IATA - International Civil Aviation Organization/International Air
Dangerous Goods by Road Transport Association
IMO/IMDG - International Maritime Organization/International Maritime MARPOL - International Convention for the Prevention of Pollution from
Dangerous Goods Code Ships
OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate
BCF - Bioconcentration factor VOC (volatile organic compound)
Key literature references and sources for data
https://echa.europa.eu/information-on-chemicals
Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Training Advice
Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and
hygiene.
Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit
and standards.
First aid for chemical exposure, including the use of eye wash and safety showers.
Fire prevention and fighting, identifying hazards and risks, static electricity, explosive atmospheres posed by vapours and dusts.

Creation Date 01-Sep-2009

Revision Date 14-Dec-2020
Revision Summary Update to CLP Format.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
COMMISSION REGULATION (EU) 2020/878 amending Annex II to Regulation (EC) No
1907/2006
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of Safety Data Sheet

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