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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
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SDS # : 31521
CERAN WR 2

Date of the previous version: not applicable Revision Date: 2013-04-30 Version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name CERAN WR 2

Number H52
Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Lubricating grease.

1.3. Details of the supplier of the safety data sheet

Supplier TOTAL UK LIMITED

40 Clarendon Road
Watford. Hertfordshire. WD17 1TQ
UNITED KINGDOM
Tel: +44 (0)1923 427700
Fax: +44 (0)1923 427701

For further information, please contact:

Contact Point Specific Product Related Info : 01977 636200

E-mail Address [email protected]

1.4. Emergency telephone number

+33 1 49 00 00 49 (24h/24, 7d/7)

Total UK - 01923 427700
NHS Direct: 0845 46 47 / Textphone: 0845 606 46 47

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

REGULATION (EC) No 1272/2008

For the full text of the H-Statements mentioned in this Section, see Section 2.2.

Classification

DIRECTIVE 67/548/EEC or 1999/45/EC

For the full text of the R-phrases mentioned in this Section, see Section 16.

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Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC.
Symbol(s)
Not Classified

2.2. Label elements

Labelled according to Not classified/No labelling required

R-phrase(s)
None

S-phrase(s)
None

2.3. Other hazards

Physical-Chemical Properties Contaminated surfaces will be extremely slippery.

Environmental properties Should not be released into the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixture

Chemical Name EC-No REACH CAS-No Weight % Classification (Dir. GHS Classification
Registration 67/548)
Number
Benzenesulfonic acid, 271-529-4 no data available 68584-23-6 <5 Xi;R36 Eye Irrit. 2 (H319)
C10-16-alkyl derivs., calcium
salts
Sulfonic acids, petroleum, 263-093-9 no data available 61789-86-4 <2.5 Xi;R36 Eye Irrit. 2 (H319)
calcium salt
Benzenesulfonic acid, 274-263-7 no data available 70024-69-0 <2.5 Xi;R36 Eye Irrit. 2 (H319)
mono-C16-24-alkyl derivs.,
calcium salts

Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346

For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1. Description of first aid measures

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General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR

EMERGENCY MEDICAL CARE.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids.

Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water. Wash
contaminated clothing before reuse.
High pressure jets may cause skin damage. Take victim immediately to hospital.

Inhalation Move to fresh air.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or poison control centre immediately.

4.2. Most important symptoms and effects, both acute and delayed

Eye contact Not classified.

Skin contact Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.

Inhalation Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory
system.

Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

4.3. Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.

5.3. Precautions for fire-fighters

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Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters

Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.

6.2. Environmental precautions

General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained.

6.3. Methods and materials for containment and cleaning up

Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustable absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Collect free product with suitable mechanical
means. Keep in suitable, closed containers for disposal.

6.4. Reference to other sections

Personal protective equipment See Section 8 for more detail.

Waste treatment See section 13.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes
and clothing.

Prevention of fire and explosion Take precautionary measures against static discharges. Ground/bond containers, tanks
and transfer/receiving equipment.

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Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product. Do
not use abrasives, solvents or fuels. Do not dry hands with rags that have been
contaminated with product. Do not put product contaminated rags into workwear pockets.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
conditions container tightly closed. Preferably keep in the original container. Otherwise, reproduce all
the statutory information from the labels onto the new container. Do not remove the hazard
labels of the containers (even if they are empty). Design the installations in order to avoid
accidental emissions of product (due to seal breakage, for example) onto hot casings or
electrical contacts. Protect from frost, heat and sunlight. Protect from moisture.

Materials to avoid Strong oxidising agents.

7.3. Specific use(s)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parametres

Exposure limits oil mist : 10mg/m3, for 15 minutes

oil mist : 5mg/m3, for 8 hours

Legend See section 16

DNEL Worker (Industrial/Professional)

Chemical Name Short term, systemic Short term, local effects Long term, systemic Long term, local effects
effects effects
Benzenesulfonic acid, 3.33 mg/kg bw/day
C10-16-alkyl derivs., (dermal)
calcium salts 0.66 mg/m³ (inhalation)
68584-23-6
DNEL Consumer
Chemical Name Short term, systemic Short term, local effects Long term, systemic Long term, local effects
effects effects
Benzenesulfonic acid, 1.667 mg/kg bw/day
C10-16-alkyl derivs., (dermal)
calcium salts 0.33 mg/m³ (inhalation
68584-23-6 0.8333 mg/kg bw/day
(oral)
Predicted No Effect Concentration
(PNEC)

Chemical Name Water Sediment Soil Air STP Oral

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Benzenesulfonic 1 mg/l fw 723500000 868700000 100 mg/l 16.667 mg/kg
acid, C10-16-alkyl 1 mg/l mw mg/kg dw fw mg/kg dw food
derivs., calcium 10 mg/l or 723500000
salts mg/kg dw mw
68584-23-6
8.2. Exposure controls

Occupational Exposure Controls

Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.

Personal protective equipment

General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.

Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with combination
filter for vapour/particulate (EN 14387). The use of breathing apparatus must comply strictly
with the manufacturer's instructions and the regulations governing their choices and uses.

Eye protection If splashes are likely to occur, wear:. Safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.

Hand protection Hydrocarbon-proof gloves: Fluorinated rubber, Nitrile rubber. Please observe the
instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion. If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of
the EC approved gloves.

Environmental exposure controls

General Information The product should not be allowed to enter drains, water courses or the soil.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Colour beige
Physical state @20°C solid
Odour characteristic

Property Values Remarks Method

pH not applicable

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Boiling point/boiling range not applicable

Flash point > 200 °C

> 392 °F .
Evapouration rate No information available
Flammability Limits in Air No information available
Vapour pressure No information available
Vapour density No information available
Density ~ 900 kg/m3 @ 20 °C
Water solubility Insoluble
Solubility in other solvents No information available
logPow No information available
Autoignition Temperature > 250 °C ASTM E659
> 482 °F ASTM E659
Viscosity, kinematic No information available
Explosive properties Not explosive
Oxidising Properties not applicable
Possibility of hazardous reactions not applicable

9.2. Other information

10. STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions None under normal processing.

10.4. Conditions to Avoid

Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products None under normal use. Incomplete combustion and thermolysis may produce gases of
varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes
and soot.

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11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity Local effects Product Information

Skin contact . Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.

Eye contact . Not classified.

Inhalation . Not classified. Inhalation of vapours in high concentration may cause irritation of
respiratory system.

Ingestion . Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

Acute toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Benzenesulfonic acid, C10-16-alkyl derivs., > 5000 mg/kg (Rat - OECD 401) > 5000 mg/kg bw (rabbit - OECD > 1.9 mg/l (Rat - aerosol-OECD
calcium salts 402) 403)
Sulfonic acids, petroleum, calcium salt > 5000 mg/kg ( Rat ) > 4000 mg/kg ( Rabbit )
Sensitisation

Sensitisation Not classified as a sensitizer.

Specific effects

Carcinogenicity This product is not classified carcinogenic.

Mutagenicity This product is not classified as mutagenic.
Reproductive toxicity This product does not present any known or suspected reproductive hazards.
Repeated Dose Toxicity

Subchronic Toxicity No information available.

Target Organ Effects (STOT)

Target Organ Effects (STOT) No information available.

Other information

Other adverse effects Characteristic skin lesions (oil blisters) may develop following prolonged and repeated
exposures (contact with contaminated clothing).

12. ECOLOGICAL INFORMATION

12.1. Toxicity

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Not classified.

Acute aquatic toxicity - Product Information

No information available.

Acute aquatic toxicity - Component Information

Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic microorganisms
invertebrates.
Benzenesulfonic acid, EL50 (72h) >1000 mg/l EL50 (48h) > 1000 mg/l LL50(96h) > 10000 mg/l
C10-16-alkyl derivs., calcium Pseudokirchneriella daphnia magna Cyprinodon variegatus
salts subcapitata (OECD 203)
68584-23-6
Sulfonic acids, petroleum, EC50 (48h) > 100 mg/l LC50 (96h) > 10000 mg/l
calcium salt Daphnia magna (OECD 202) Cyprinodon variegatus
61789-86-4 (OECD 203)

Chr onicaquat i
ct oxicity •Pr
oductI
nfor
mat
ion
No information available.

Chronic aquatic toxicity - Component Information

No information available.

Effects on terrestrial organisms

No information available.

12.2. Persistence and Degradability

General Information
No information available.

12.3. Bioaccumulative potential

Product Information No information available.

logPow No information available

Component Information .
12.4. Mobility in soil

Soil Given its physical and chemical characteristics, the product has no soil mobility.

Air Loss by evaporation is limited.

Water The product is insoluble and floats on water.

12.5. Results of PBT and vPvB assessment

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PBT and vPvB assessment No information available.

12.6. Other adverse effects

General Information No information available.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues / unused Should not be released into the environment. Dispose of in accordance with the European
products Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.

EWC Waste Disposal No The following Waste Codes are only suggestions:. 12 01 12. According to the European
Waste Catalogue, Waste Codes are not product specific, but application specific. Waste
codes should be assigned by the user based on the application for which the product was
used.

14. TRANSPORT INFORMATION

ADR/RID not regulated

IMDG/IMO not regulated

ICAO/IATA not regulated

ADN not regulated

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

European Union

International Inventories

EINECS/ELINCS -

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TSCA -
DSL -
ENCS -
IECSC -
KECL -
PICCS -
AICS -
NZIoC -
Legend
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

Further information

15.2. Chemical Safety Assessment

Chemical Safety Assessment No information available

15.3. National regulatory information

The United Kingdom

•Av
oidex
ceedi
ngoccupat
ional
expos
urel
i
mit
s(seesect
ion8)
.

Ireland

•Av
oidex
ceedi
ngoccupat
ional
expos
urel
i
mit
s(seesect
ion8)
.

16. OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3

R36 - Irritating to eyes

Full text of H-Statements referred to under sections 2 and 3

H319 - Causes serious eye irritation

Abbreviations, acronyms

Legend Section 8

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+ Sensitiser * Skin designation
** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction

Revision Date: 2013-04-30

Revision Note *** Indicates updated section.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
_____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

End of Safety Data Sheet

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