The Essentials of Continuous Evaporation
The Essentials of Continuous Evaporation
The Essentials of Continuous Evaporation
The Essentials of
Continuous Evaporation
Bryan W. Hackett, P.E. Evaporation is a standard thermally driven
kW Engineering
unit operation. Learn three methods to
improve evaporator efficiency.
E
vaporation is a unit operation that separates a liquid the product of evaporation is a concentrated liquid, not a
from solids by means of heat transfer via vaporization solid. Evaporation can be used as the initial step in produc-
or boiling. The purpose of evaporation is to concen- ing a dried product if the liquid concentrate then undergoes
trate a solution of a nonvolatile solute (i.e., solids) and a a drying process such as spray drying. The combination of
solvent (i.e., liquid), which is typically water. Evaporating a evaporation and spray drying is often used to make pow-
portion of the solvent concentrates the solute into a more- dered products, such as powdered milk. This combination of
viscous liquid product. Evaporation is regularly used in the processes is economically attractive because high-efficiency
food processing, chemical, kraft paper, and pharmaceutical evaporation is significantly less costly than drying and other
industries to produce liquid concentrates. methods of removing water (1). Evaporation also produces a
Evaporation differs from dehydration and drying in that higher concentration of solids than other methods of concen-
tration (Figure 1) (2).
Reverse Osmosis
Evaporation differs from distillation in that the con-
centrated solution, rather than the condensed evaporate, is
Ultrafiltration
typically the valuable product. A common exception is the
evaporation of solutions with a high mineral content, where
Freeze Concentration the vapor is condensed as the product and the concentrated
brine is discarded. This process is commonly referred to
Evaporation as water distillation, although the process is more akin to a
thermally driven liquid-solids separation operation.
Scraped Surface Evaporation Evaporation may be carried out as a batch or continuous
process. This article focuses on evaporation as a continuous
Drying process, in which the feed and product streams are continu-
ous and their concentrations remain constant.
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
Solids Content The basics
All evaporators are comprised of two sections: a heating
p Figure 1. Evaporation as a method of concentration can produce solids
contents that range from 0% to as much as 92% with scraped surface section (called a steam chest) and a vapor/liquid separation
evaporators (used in select applications). section. These sections can be located within a single vessel
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(body), or the heating section may be external to the vessel
that houses the vapor/liquid separation section. Evaporator Condenser
Steam
MF = MP + MV (1)
MS = MC (2)
Condensate
The energy balance assumes that no work is performed
on the system (W = 0) and heat loss is negligible (Q = 0). In
p Figure 3. An energy balance for this evaporator assumes no work is
real applications, heat loss is typically estimated to be 2% of
performed on the system and heat loss is zero. To get a closer approxima-
the vapor energy input to each effect (2). Latent heat from tion of the evaporator rating, however, the heat loss is estimated to be 2%
saturated steam drives the evaporation of water, and depend- of the vapor energy input to each effect.
Copyright © 2018 American Institute of Chemical Engineers (AIChE) CEP May 2018 www.aiche.org/cep 25
Back to Basics
ing on the initial feed temperature, may also be used to raise In theory, the evaporation of 1 kg of water requires
the temperature to boiling. slightly more than 1 kg of steam, since the latent heat of
The product concentration, where xF and xP are the mass vaporization decreases as pressure increases (3). As the
fractions of the respective streams, can be calculated from: steam’s latent heat is transferred to the feed, some of the
heat raises the initial feed temperature to the boiling point
MFxF = MPxP (4) and the remaining latent heat evaporates water. Thus, the
steam economy will always be less than one. Depend-
Steam economy ing on the initial feed temperature and system losses, the
Another way to measure and compare the performance steam economy of a single-effect evaporator typically is
of evaporators is to consider the amount of water evaporated 0.75–0.95 kg water/kg steam (4).
per amount of steam consumed. This metric is called the Improving steam economy. Consider the example of
steam economy (SE) and is commonly expressed as the ratio the single-effect evaporator (Figure 3). For heat transfer to
of water evaporated to steam consumed. occur, the temperature of the saturated steam must be higher
than the boiling temperature of the feed. If the latent heat of
MV1 MV2 MV3
the water vapor leaving the evaporator can be reused, the
steam economy can be increased. But, because heat transfer
MF1
82°C 68°C 57°C requires a temperature gradient, the latent heat of the water
vapor can only be transferred to a lower-temperature fluid.
MS1 The two primary means of improving the steam econ-
omy of an evaporator both involve manipulating temperature
1st 2nd 3rd
Effect Effect Effect via pressure change.
Multiple-effect evaporators
If the water vapor from the first effect of a multiple-
effect evaporator can be introduced into the steam chest
of a second effect operating at a lower boiling point, the
latent heat in the water vapor can be reused. Lowering
MP1 MP2 MP3
MC1 MC2 MC3 the vapor pressure of the second effect relative to the first
p Figure 4. The steam economy of an evaporator can be improved by effect lowers the boiling point of the second effect. This
adding more effects. The first effect has the highest boiling temperature, arrangement of reusing vapor latent heat is called multiple-
while the last effect has the lowest. Each successive effect uses the vapor effect evaporation.
from the previous effect as a heat source.
Figure 4 shows the mass flows in a three-effect evapo-
Thermocompressor Vapor to rator. The vapor from the first effect (MV1) becomes the
Condenser
heating source for the second effect (MS2). This is possible
Steam
because the second effect’s boiling temperature has been
Feed
lowered to 68°C (at 29 kPa), which is less than the satu-
71°C 80°C 60°C
rated temperature of the first effect, 82°C (at 51.8 kPa). The
Steam
latent heat is reused again as MV2 becomes the heat source
of the third effect, where the boiling point temperature has
1st 2nd 3rd been lowered to 57°C (at 17.5 kPa). The steam economy of
Effect Effect Effect
multiple-effect evaporators can be estimated by (4):
SE = eN (5)
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ture and creates the temperature gradient necessary for latent of an evaporator with MVR — which is 5–10 times that of
heat reuse within the evaporator system. the three-effect evaporator.
Thermal vapor recompression (TVR) uses a steam ejec- Note that the steam economy of an evaporator is highly
tor to compress the vapor leaving the evaporator vessel. In dependent on the initial temperature of the feed as it enters
this application, the steam ejector is often called a thermo the evaporator system and the properties of the liquid being
compressor; its primary purpose is to compress vapor, but concentrated.
its secondary benefit is creating vacuum within the evapora- Feed that enters the first effect at a temperature above
tor vessel. As a thermocompressor, the ejector uses high- the boiling point first flashes some vapor before heat transfer
pressure steam (0.8–2.1 MPa) as the motive fluid to draw within the evaporator even begins. Thus, the steam economy
in the low-pressure vapor from the evaporator and produce will be higher than if the initial feed temperature was below
a combined vapor of suitable pressure and temperature for the boiling point, which would require heat transfer to the
evaporator heating. liquid before evaporation can occur.
Figure 5 illustrates one possible configuration of a three- Boiling point rise, also called boiling point elevation
effect evaporator with TVR. In this example, the thermo- (BPE), is the difference between a solution’s boiling point
compressor raises the saturation temperature of the vapor and the boiling point of pure water at the same pressure.
from 71°C to 88°C so it can be reused to heat the second Some solutions, especially as they become more concen-
effect operating at 80°C. trated, may require a large temperature gradient (16–27°C)
Steam ejectors are better suited to handling large to sufficiently transfer enough heat to reach boiling condi-
volumes of low-density vapor than mechanical vacuum tions. High temperature gradients limit the number of effects
pumps and are easier and cheaper to maintain. As a rule of that can be applied, thereby limiting the potential steam
thumb, TVR improves an evaporator’s steam economy by an economy increase of a system. Also, single-stage thermal
amount equivalent to the addition of another effect, but at a
much lower cost (5). Evaporator Startup/Makeup
Steam
Mechanical vapor recompression (MVR) uses a mechan- Body
Figure 6 shows a single-effect, vertical long-tube p Figure 6. Mechanical vapor recompression (MVR) improves steam
evaporator with MVR. An MVR evaporator requires steam economy by compressing low-pressure steam exiting the evaporator and
to bring the system up to boiling temperature during startup, recycling it as the heat source.
but requires very little steam once operating at steady state,
Table 1. Comparison of evaporator steam economies.
with only the work of the compressor adding energy to
the system. Type of Evaporator Steam Economy,
kg water/kg steam
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Back to Basics
and mechanical compressors are economically limited to pumped upward through the heat exchanger, the static head
compression ratios of about two, which produces a tempera- pressure suppresses vapor formation until the heated liquid
ture increase of 5–20°C (5). Thus, the potential to increase enters the vapor/liquid separator, where a portion flashes to
the steam economy by adding effects, TVR, and MVR may vapor. The centrifugal pump allows the residence time in the
be constrained by the thermal and rheological properties of heat exchanger to be controlled based on the heat-sensitivity
the liquid being concentrated. of the liquid being concentrated. This feature is important
when concentrating pulpy, viscous liquids, such as tomato
Evaporation in industry juice and mango juice.
Evaporation is used for subtlety different purposes and Plate-type evaporators operate similarly to long-tube ver-
with different results in each industry. In the food process- tical evaporators, but with the film flowing on plates rather
ing industry, food products are concentrated to increase their than tubes. Their advantages over tubular-type evaporators
shelf life, reduce volume and weight, reduce storage costs, include compact size that allows installation within buildings
reduce transportation costs, and increase value. and their ability to be disassembled for easier cleaning.
Concentration of fresh foods, such as fruit juices, is an
economic way to make use of perishable crops during peak Wrapping up
harvest periods (6). Fruit juice concentrates and tomato The primary means of increasing the steam economy of
paste are two examples of seasonal foods that evaporation an evaporator is to reuse the latent heat of the water vapor.
preserves for year-round consumption. Lower water activity, A multiple-effect evaporator uses the water vapor from one
which is a general indication of microbiological stability, effect as the heating medium for the next effect, which oper-
preserves concentrated foods. ates at a lower boiling point. The latent heat in water vapor
In the chemical and kraft paper industries, evaporation can also be reused by thermally or mechanically compress-
is often used to recover valuable, nonvolatile chemicals. ing the vapor to a higher pressure and temperature. These
For example, in the kraft pulping process, water is evapo- three methods of improving efficiency have their limits,
rated from spent cooking liquid (i.e., black liquor), which however, which are specific to the physical properties of the
concentrates the solids. The concentrated inorganic process liquid feed being evaporated. CEP
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