Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

1. PRODUCT AND COMPANY IDENTIFICATION

Identification of the
substance/preparation Isononanol
CAS-No 3452-97-9

Use of the Substance Intermediate.

/Preparation

Supplier OXEA Corporation

1505 West LBJ Freeway, Suite 400
Dallas, TX 75234
USA

Product Information Product Stewardship

FAX: +49 (0)208 693 2053
email: [email protected]

Emergency telephone number in USA, call 800 424 9300

outside USA, call 703 527 3887, collect calls accepted

2. HAZARDS IDENTIFICATION
Emergency Overview
Product Description
Physical state liquid
Colour colourless
Odour alcoholic

Statements of hazard Caution***

Combustible liquid and vapour
Vapour/air-mixtures are explosive at intense warming
May cause eye/skin irritation
Toxic to aquatic organisms***

OSHA Regulatory Status This material is hazardous as defined by the American OSHA Hazard
Communication Standard (29CFR 1910.1200).

Potential Health Effects

Principle Routes of Exposure Inhalation, Eye contact, Skin contact, Ingestion.

Inhalation Components of the product may be absorbed into the body by inhalation.
Eye contact May cause eye irritation.***

___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
1 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________
Skin contact May cause skin irritation. Components of the product may be absorbed into the
body through the skin.
Ingestion Components of the product may be absorbed into the body by ingestion.
Main symptoms cough, nausea, gastrointestinal discomfort, vomiting.

Target Organ Effects Lung irritation

Liver effects
Kidney disorders***

Environmental properties Toxic to aquatic organisms

3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No Concentration (%) OSHA status
3,5,5-Trimethylhexan-1-ol 3452-97-9 > 97,5 hazardous

4. FIRST AID MEASURES

General advice
Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.

Inhalation
Keep at rest. Aerate with fresh air. When symptoms persist or in all cases of doubt seek medical advice.

Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses.
Immediate medical attention is required.

Skin
Wash off immediately with plenty of water for at least 15 minutes. When symptoms persist or in all cases of doubt
seek medical advice.

Ingestion
Call a physician immediately. Do not induce vomiting without medical advice.

Main symptoms
cough, nausea, gastrointestinal discomfort, vomiting.

Special hazard
Lung irritation, Liver effects, Kidney disorders.***

Notes to physician
Treat symptomatically. If ingested, irrigate the stomach using activated charcoal.

5. FIRE-FIGHTING MEASURES
OSHA Flammability classification
Combustible liquid Class III A
___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
2 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

Suitable extinguishing media

alcohol-resistant foam. dry chemical. carbon dioxide (CO2). water spray.

Extinguishing media which must not be used for safety reasons

Do not use a solid water stream as it may scatter and spread fire.

Special exposure hazards arising from the substance or preparation itself, its combustion products, or
released gases
Under conditions giving incomplete combustion, hazardous gases produced may consist of:
carbon monoxide (CO)
carbon dioxide (CO2)
Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapours are heavier than air and may spread along floors
Vapour/air-mixtures are explosive at intense warming

Special protective equipment for fire-fighters

Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full
fire-fighting turn out gear.

Precautions for fire-fighting

Cool containers / tanks with water spray. Water run-off can cause environmental damage. Dike and collect water used
to fight fire. Keep people away from and upwind of fire.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak.
Ensure adequate ventilation, especially in confined areas. Keep away from heat and sources of ignition.
For emergency responders: Personal protection see section 8.

Environmental precautions
Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment
(biological treatment plant). Water runoff can cause environmental damage.

Methods for containment

Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.

Methods for cleaning up

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. If liquid has been spilt in large
quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take necessary
action to avoid static electricity discharge (which might cause ignition of organic vapours).

7. HANDLING AND STORAGE

Handling
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Provide sufficient air exchange and/or exhaust in work rooms.
___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
3 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

Advice on protection against fire and explosion

Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge (which
might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be available.
Ground and bond containers when transferring material. Vapour/air-mixtures are explosive at intense warming.

Storage
Technical measures/Storage conditions
Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care.

Advice on common storage

Incompatible products:
strong acids
strong oxidizing agents

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits United States of America
No exposure limits established.

Occupational exposure controls

Engineering measures
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local
ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts) should
be used in mechanical ventilation systems.

Personal protective equipment

General industrial hygiene practice

Avoid contact with skin, eyes and clothing. Do not breathe dust or mist. Ensure that eyewash stations and safety
showers are close to the workstation location.

Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks
and immediately after handling the product.

Respiratory protection
Respirator with filter for organic vapour. Use the indicated respiratory protection if the occupational exposure limit is
exceeded and/or in case of product release (dust). Equipment should conform to NIOSH.

Hand protection
Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on the
situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with
this chemical, material selection should be based on protection for all chemicals present.
Suitable material nitrile rubber

Suitable material polyvinylchloride / nitrile rubber

___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
4 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash to
the face.

Skin and body protection

Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.

Environmental exposure controls

Use product only in closed system. If leakage can not be prevented, the substance needs to be suck off at the
emersion point, if possible without danger. Observe the exposure limits, clean exhaust air if needed. If recycling is not
practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of leakage into
the atmosphere, or of entry into waterways, soil or drains.***

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid
Colour colourless
Odour alcoholic
Molecular weight 144,26
Molecular formula C9 H20 O

Flash point 169 °F (76 °C)

Method ISO 2719***
Autoignition temperature 725 °F (385 °C)
Method EU A.15***
Melting point/range -112 °F (-80 °C) (Pour point)
Boiling point/range 380 °F (193,5 °C) @ 1 atm (101,3 kPa)

Vapour pressure
Values Values Values @ °C @ °F
[hPa] [kPa] [atm]
2 0,2 0,002 20 68
68 6,8 0,068 50 122
Density
Values [g/cm³] @ °C @ °F Method
0,8264 20 68 DIN 51757

Viscosity 14,19 mPa*s @ 68 °F (20 °C)

Method dynamic OECD 114***
Water solubility 0,4 g/l @ 68 °F (20 °C) OECD 105
log Pow 3,7 (measured) OECD 117
Vapour density 5,0 (Air = 1) @ 20 °C (68 °F)
Surface tension 38,0 mN/m (0,36 g/l @ 20°C), OECD 115

10. STABILITY AND REACTIVITY

Stability
Stable under recommended storage conditions.
___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
5 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

Conditions to avoid
Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.

Materials to avoid
strong acids, strong oxidizing agents.

Hazardous decomposition products

No decomposition if used as directed.

11. TOXICOLOGICAL INFORMATION

Principle Routes of Exposure Inhalation, Eye contact, Skin contact, Ingestion

Acute toxicity
3,5,5-Trimethylhexan-1-ol (3452-97-9)
Routes of Exposure Endpoint Values Species Method
Oral LD50 > 2000 mg/kg rat, male/female OECD 401
Oral*** LD50 2300 mg/kg rat, male/female*** OECD 401***
Dermal*** LD50*** 2307 mg/kg*** rabbit OECD 402***

Irritation and corrosion

3,5,5-Trimethylhexan-1-ol (3452-97-9)
Target Organ Effects Species Result Method
Skin rabbit Moderate skin OECD 404 4h
irritation
Eyes rabbit Moderate eye OECD 405
irritation

Sensitization
3,5,5-Trimethylhexan-1-ol (3452-97-9)
Target Organ Effects Species Evaluation Method
Skin*** Human experience*** not sensitizing*** OECD 406***

Subacute, subchronic and prolonged toxicity

3,5,5-Trimethylhexan-1-ol (3452-97-9)
Type Dose Species Method
14 days NOAEL: 12 mg/kg/d rat, male/female*** OECD 422 Oral
14 days LOAEL: 60 mg/kg/d rat, male/female*** OECD 422 Oral

Carcinogenicity, Mutagenicity, Reproductive toxicity

3,5,5-Trimethylhexan-1-ol (3452-97-9)
Type Dose Species Evaluation Method
Reproductive toxicity NOAEL 300 rat, parental, male OECD 422, Oral
mg/kg/d
Reproductive toxicity NOAEL 60 rat, parental, OECD 422, Oral
mg/kg/d female

___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
6 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________
Reproductive toxicity NOAEL 12 rat, 1. Generation, OECD 422, Oral
mg/kg/d male/female
Mutagenicity Salmonella negative OECD 471 In vitro study
typhimurium (Ames)
Mutagenicity Escherichia coli negative OECD 472 In vitro study***
Mutagenicity V79 cells, negative OECD 473 In vitro study
Chinese hamster (Chromosomal
Aberration)
Developmental NOAEL 12 rat*** OECD 422*** Maternal toxicity,
Toxicity*** mg/kg/d*** Embryotoxicity***
Developmental NOAEL 12 rat*** OECD 422*** Fetal toxicity***
Toxicity*** mg/kg/d***
Developmental NOAEL 300 rat*** OECD 422*** Teratogenicity***
Toxicity*** mg/kg/d***

3,5,5-Trimethylhexan-1-ol, CAS: 3452-97-9

Main symptoms
cough, nausea, gastrointestinal discomfort, vomiting.
Target Organ Systemic Toxicant - Repeated exposure
Liver effects, Kidney disorders.***
Other adverse effects
Components of the product may be absorbed into the body by inhalation, ingestion and through the skin.
Note
Handle in accordance with good industrial hygiene and safety practice.

12. ECOLOGICAL INFORMATION

Acute aquatic toxicity
3,5,5-Trimethylhexan-1-ol (3452-97-9)
Species Exposure time Dose Method
Oryzias latipes (Medaka) 96h LC50: 27,7 mg/l OECD 203
Daphnia magna (Water flea) 48h LC50: 6,77 mg/l OECD 202
Scenedesmus capricornutum 72h EC50: > 33,3 mg/l OECD 201
(fresh water algae)*** (Biomass)***
Scenedesmus capricornutum 72h NOEC: 4,7 mg/l OECD 201
(fresh water algae)*** (Biomass)***

Long term toxicity

3,5,5-Trimethylhexan-1-ol (3452-97-9)
Type Species Dose Method
Mortality Daphnia magna LC50: > 3,87 mg/l OECD 202 21 d
(Water flea)
Reproductive toxicity Daphnia magna EC50: 2,09 mg/l OECD 202 21 d
(Water flea)
Mortality Oryzias latipes LC50: > 17 mg/l*** OECD 204
(Medaka)
Mortality*** Oryzias latipes NOEC: 1,28 mg/l*** OECD 204***
(Medaka)***
___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
7 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

3,5,5-Trimethylhexan-1-ol, CAS: 3452-97-9

Biodegradation
3,67 % (28*** d), activated sludge, Not readily biodegradable, OECD 301 C.***
Bioaccumulative potential
100 µg/l BCF: 3,9 - 8,1
Note
Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS

Product Information
Disposal required in compliance with all waste management related state and local regulations. The choice of the
appropriate method of disposal depends on the product composition by the time of disposal as well as the local
statutes and possibilities for disposal.

Uncleaned empty packaging

Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for
reuse.

14. TRANSPORT INFORMATION

ICAO/IATA Not restricted

IMDG Not restricted

IBC-Code
Product name Nonyl alcohol
Ship type 2
Pollution category Y

D.O.T. (49CFR)
UN/ID No NA 1993
Proper shipping name Combustible liquid, n.o.s.
Hazard Inducer (Isononanol)
Class 3
Packing group III
Emergency Response Guide 128
Remarks Only regulated if over 119 gallons

TDG (Transport of Dangerous Not restricted

Goods) Canada

15. REGULATORY INFORMATION

OSHA Regulatory Status
This material is hazardous as defined by the American OSHA Hazard Communication Standard (29CFR 1910.1200).

___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
8 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________
Federal and State Regulations
Components of the product are listed in the quoted regulations. For details please refer to the regulations directly.
This list is not exhaustive, please check for other applicable regulations.

Federal Regulations
This product is listed on the TSCA inventory

State Regulations

3,5,5-Trimethylhexan-1-ol, CAS: 3452-97-9

PA RTK List***

International Inventories

3,5,5-Trimethylhexan-1-ol, CAS: 3452-97-9

AICS (AU)***
DSL (CA)***
IECSC (CN)***
EC-No. 2223767 (EU)***
ENCS (2)-217 (JP)***
ISHL (2)-217 (JP)***
KECI KE-34566 (KR)***
PICCS (PH)***
TSCA (US)***
NZIoC (NZ)***

16. OTHER INFORMATION

Revision Date 17-Sep-2012
Issuing date 17-Sep-2012

Training advice
For effective first-aid, special training / education is needed.

Hazard Rating Systems

NFPA (National Fire Protection Association)

Health Hazard 2
Fire Hazard 2
Reactivity 0
HMIS (Hazardous Material Information System)
Health Hazard 2***
Flammability 2
Physical Hazard 0

Sources of key data used to compile the datasheet

Information contained in this safety data sheet is based on Oxea owned data and public sources deemed valid or
acceptable. The absence of data elements required by ANSI or 2001/58/EC indicates, that no data meeting these
requirements is available.
___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
9 / 10 USA (A-US)
Material Safety Data Sheet

10320 Revision Date 17-Sep-2012

Isononanol Revision Number 2 .00
___________________________________________________________________________________________

Further information for the safety data sheet

Observe national and local legal requirements. Changes against the previous version are marked by ***.
The annex is not required because the substance is registered as an intermediate under REACh.***

Disclaimer
For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not
suggest or guarantee that any hazards listed herein are the only ones which exist. Oxea makes no warranty of any
kind, express or implied, concerning the safe use of this material in your process or in combination with other
substances. User has the sole responsibility to determine the suitability of the materials for any use and the manner of
use contemplated. User must meet all applicable safety and health standards.

___________________________________________________________________________________________
Emergency telephone number in USA, call 800 424 9300; outside USA, call USA 703 527 3887, collect calls accepted
10 / 10 USA (A-US)