Sulfur dioxide

Safety Data Sheet P-4655

This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

SECTION: 1. Product and company identification

1.1. Product identifier
Product form : Substance
Name : Sulfur dioxide
CAS No : 7446-09-5
Formula : SO2
Other means of identification : Sulfur Oxide, Sulfurous acid anhydride, Sulfur oxide, Sulfurous anhydride, Sulfurous oxide,
Refigerant gas R764
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial use. Use as directed.
1.3. Details of the supplier of the safety data sheet
Praxair, Inc.
10 Riverview Drive
Danbury, CT 06810-6268 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
1.4. Emergency telephone number
Emergency number : Onsite Emergency: 1-800-645-4633

CHEMTREC, 24hr/day 7days/week

— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887
(collect calls accepted, Contract 17729)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
GHS-US classification
Liquefied gas H280
Acute Tox. 3 (Inhalation:gas) H331
Skin Corr. 1B H314
Eye Dam. 1 H318

2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS04 GHS05 GHS06

Signal word (GHS-US) : DANGER
Hazard statements (GHS-US) : H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H331 - TOXIC IF INHALED
CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT
Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing gas
P262 - Do not get in eyes, on skin, or on clothing
P271+P403 - Use and store only outdoors or in a well-ventilated place
P280+P284 - Wear protective gloves, protective clothing, eye protection, respiratory protection,
and/or face protection
P405 - Store locked up
P501 - Dispose of contents/container in accordance with container Supplier/owner instructions

EN (English US) SDS ID: P-4655 1/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

CGA-PG05 - Use a back flow preventive device in the piping

CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and
rated for cylinder pressure
CGA-PG12 - Do not open valve until connected to equipment prepared for use
CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug
CGA-PG06 - Close valve after each use and when empty
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance
Name Product identifier %
Sulfur dioxide (CAS No) 7446-09-5 100
(Main constituent)

3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing,
give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a
physician.
First-aid measures after skin contact : In case of contact, immediately flush affected areas with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Call a physician. Wash clothing before
reuse. Discard contaminated shoes.
First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Exposure to concentrations above the TLV of 2 ppm may irritate the eyes, nose, throat, and
sinuses, resulting in choking, coughing, and sometimes bronchoconstriction.

Concentrations of 50-100 ppm are considered dangerous.

Exposures of 400-500 ppm are immediately life-threatening.

Exposure to high concentrations may result in pulmonary edema and paralysis.

.

4.3. Indication of any immediate medical attention and special treatment needed
Obtain medical assistance.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.

EN (English US) SDS ID: P-4655 2/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

5.3. Advice for firefighters

Firefighting instructions : DANGER! Toxic, corrosive, liquefied gas.

Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.
Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : DANGER: Toxic. Corrosive. Wear a self-contained breathing apparatus and appropriate
personal protective equipment (PPE). (gas tight, chemical-protective) Evacuate personnel to a
safe area. Approach suspected leak area with caution. Remove all sources of ignition. Toxic,
corrosive vapor can spread from spill. Ventilate area or move container to a well-ventilated
area. Before entering the area, especially a confined area, check the atmosphere with an
appropriate device.

6.1.1. For non-emergency personnel

No additional information available
6.1.2. For emergency responders
No additional information available
6.2. Environmental precautions
Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Contact supplier for any special requirements.
6.3. Methods and material for containment and cleaning up
No additional information available
6.4. Reference to other sections
See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
Safe use of the product : Do not breathe gas/vapors. Use only with adequate ventilation or respiratory protection. Do
not get liquid or vapor in eyes, on skin, or on clothing. Have safety showers and eyewash
fountains immediately available.

EN (English US) SDS ID: P-4655 3/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only where
temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from
falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand.
Store full and empty containers separately. Use a first-in, first-out inventory system to prevent
storing full containers for long periods

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in the
piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with
adequate ventilation. If a leak occurs, close the container valve and blow down the system in a
safe and environmentally correct manner in compliance with all international, federal/national,
state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
7.3. Specific end use(s)
None.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Sulfur dioxide (7446-09-5)
ACGIH ACGIH TLV-STEL (ppm) 0.25 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 13 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 5 ppm
USA IDLH US IDLH (ppm) 100 ppm

8.2. Exposure controls

Appropriate engineering controls : Use only in a closed system. A corrosion-resistant, forced-draft fume hood is preferred. LOCAL
EXHAUST: A corrosion-resistant system is acceptable.

In semiconductor process gas and other suitable applications, Praxair recommends the use of
engineering controls such as gas cabinet enclosures, automatic gas panels (used to purge
systems on cylider changeout), excess-flow valves throughout the gas distribution system,
double containment for the distribution system, and continuous gas monitors.

Eye protection : Provide readily accessible eye wash stations and safety showers. Wear safety glasses when
handling cylinders; vapor-proof goggles and a face shield during cylinder changeout or
whenever contact with product is possible. Select eye protection in accordance with OSHA 29
CFR 1910.133.
Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where
needed. Wear appropriate chemical gloves during cylinder changeout or wherever contact with
product is possible. Select per OSHA 29 CFR 1910.132, 1910.136, and 1910.138.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure. For
emergencies or instances with unknown exposure levels, use a self-contained breathing
apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Colorless, non-flammable gas.
Molecular mass : 64 g/mol
Color : Colorless.
EN (English US) SDS ID: P-4655 4/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

Odor : Pungent. choking

Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -75.5 °C
Freezing point : No data available
Boiling point : -10 °C
Flash point : Not applicable.
Critical temperature : 157.6 °C
Auto-ignition temperature : Not applicable.
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 330 kPa
Critical pressure : 7884 kPa
Relative vapor density at 20 °C : No data available
Relative density : 1.5
Density : 1.39 g/cm³ (at 20 °C)
Relative gas density : 2.3
Solubility : Water: Completely soluble.
Log Pow : Not applicable for inorganic gases.
Log Kow : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.
Explosive properties : Not applicable.
Oxidizing properties : None.
Explosion limits : Non flammable.
9.2. Other information
Gas group : Liquefied gas
Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground
level

SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
None.
10.4. Conditions to avoid
Avoid moisture in installation systems.
10.5. Incompatible materials
Moisture. Fluorine. Chlorine trifluoride. Chlorates. Sodium Carbide. Aluminum. (powdered). Zinc and
its alloys. Manganese. Alkali metals. Metal nitrates. Rubidium carbide. Metal oxides. metal
acetylides. Metal hydrides, flammable, n.o.s. Stannous oxide. Sodium. Acrolein (propenal).
10.6. Hazardous decomposition products
None known.

EN (English US) SDS ID: P-4655 5/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Inhalation:gas: TOXIC IF INHALED.

Sulfur dioxide ( \f )7446-09-5
LC50 inhalation rat (ppm) 1260 ppm/4h
ATE US (gases) 1260.000 ppmV/4h

Skin corrosion/irritation : CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.

Serious eye damage/irritation : CAUSES SERIOUS EYE DAMAGE.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Sulfur dioxide (7446-09-5)
IARC group 3 - Not classifiable
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : Exposure to concentrations above the TLV of 2 ppm may irritate the eyes, nose, throat, and
sinuses, resulting in choking, coughing, and sometimes bronchoconstriction.

Concentrations of 50-100 ppm are considered dangerous.

Exposures of 400-500 ppm are immediately life-threatening.

Exposure to high concentrations may result in pulmonary edema and paralysis.

.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No known ecological damage caused by this product.

12.2. Persistence and degradability

Sulfur dioxide (7446-09-5)
Persistence and degradability Not applicable for inorganic gases.

12.3. Bioaccumulative potential

Sulfur dioxide (7446-09-5)
BCF fish 1 (no bioaccumulation expected)
Log Pow Not applicable for inorganic gases.
Log Kow Not applicable.
Bioaccumulative potential No data available.

12.4. Mobility in soil

Sulfur dioxide (7446-09-5)
Mobility in soil No data available.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.

EN (English US) SDS ID: P-4655 6/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

12.5. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.
Effect on ozone layer : None

Effect on the global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Do not attempt to dispose of residual or unused quantities. Return container to supplier.

SECTION 14: Transport information

In accordance with DOT
Transport document description : UN1079 Sulfur dioxide, 2.3
UN-No.(DOT) : UN1079
Proper Shipping Name (DOT) : Sulfur dioxide
Class (DOT) : 2.3 - Class 2.3 - Poisonous gas 49 CFR 173.115
Hazard labels (DOT) : Poison Gas
2.3 - Poison gas
8 - Corrosive

DOT Special Provisions (49 CFR 172.102) : 3 - This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone C
(see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the
provisions of this subchapter
B14 - Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated
with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more
than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per
square foot per degree Fahrenheit) temperature differential. Insulating materials must not
promote corrosion to steel when wet
T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the
applicable liquefied compressed gases are authorized to be transported in portable tanks in
accordance with the requirements of 173.313 of this subchapter
TP19 - The calculated wall thickness must be increased by 3 mm at the time of construction.
Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic
tests (every 2.5 years). The portable tank must not be used if the wall thickness is less than
that prescribed by the applicable T code in Column (7) of the Table for this material
Additional information
Emergency Response Guide (ERG) Number : 125

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea
UN-No. (IMDG) : 1079
Proper Shipping Name (IMDG) : SULPHUR DIOXIDE
Class (IMDG) : 2 - Gases
MFAG-No : 125

EN (English US) SDS ID: P-4655 7/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

Air transport
UN-No. (IATA) : 1079
Proper Shipping Name (IATA) : Sulphur dioxide
Class (IATA) : 2
Civil Aeronautics Law : Gases under pressure/Gases toxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations
Sulfur dioxide (7446-09-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

Listed on the United States SARA Section 302

SARA Section 302 Threshold Planning Quantity 500 lb
(TPQ)
SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard
Immediate (acute) health hazard
Sudden release of pressure hazard

15.2. International regulations

CANADA

Sulfur dioxide (7446-09-5)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Sulfur dioxide (7446-09-5)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

15.2.2. National regulations

Sulfur dioxide (7446-09-5)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)

15.3. US State regulations

Sulfur dioxide(7446-09-5)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental Yes
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

EN (English US) SDS ID: P-4655 8/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Sulfur dioxide
Safety Data Sheet P-4655
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 10/24/2016 Supersedes: 03/20/2015

SECTION 16: Other information

NFPA health hazard : 3 - Short exposure could cause serious temporary or

residual injury even though prompt medical attention was
given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.

HMIS III Rating

Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 0 Minimal Hazard
Physical : 2 Moderate Hazard

SDS US (GHS HazCom 2012) - Praxair

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

EN (English US) SDS ID: P-4655 9/9

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.