MSDS SF6

Sulfur hexafluoride
Safety Data Sheet P-4657

This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979 Revision date: 11/23/2016 Supersedes: 01/28/2015
SECTION: 1. Product and company identification

1.1. Product identifier
Product form : Substance
Name : Sulfur hexafluoride
CAS No : 2551-62-4
Formula : SF6
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial use. Use as directed.
1.3. Details of the supplier of the safety data sheet
Praxair, Inc.
10 Riverview Drive
Danbury, CT 06810-6268 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
1.4. Emergency telephone number
Emergency number : Onsite Emergency: 1-800-645-4633
CHEMTREC, 24hr/day 7days/week

— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887
(collect calls accepted, Contract 17729)
SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
GHS-US classification
Liquefied gas H280
2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :
GHS04
Signal word (GHS-US) : WARNING
Hazard statements (GHS-US) : H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
CGA-HG01 - MAY CAUSE FROSTBITE
Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood
P262 - Do not get in eyes, on skin, or on clothing
P271+P403 - Use and store only outdoors or in a well-ventilated place
CGA-PG05 - Use a back flow preventive device in the piping
CGA-PG06 - Close valve after each use and when empty
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)
2.3. Other hazards

Other hazards not contributing to the : Asphyxiant in high concentrations
classification
Contact with liquid may cause cold burns/frostbite.
2.4. Unknown acute toxicity (GHS US)
No data available
EN (English US) SDS ID: P-4657 1/9
This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
Sulfur hexafluoride
SECTION 3: Composition/Information on ingredients

3.1. Substance
Name : Sulfur hexafluoride
CAS No : 2551-62-4
Name Product identifier %
Sulfur hexafluoride (CAS No) 2551-62-4 99.5 - 100
3.2. Mixture
Not applicable
SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
First-aid measures after skin contact : In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain
medical assistance. The liquid may cause frostbite. For exposure to liquid, immediately warm
frostbite area with warm water not to exceed 105°F (41°C). Water temperature should be
tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring
and sensation have returned to the affected area. In case of massive exposure, remove
clothing while showering with warm water. Seek medical evaluation and treatment as soon as
possible.
First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
None.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
5.2. Special hazards arising from the substance or mixture
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.
Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.
Special protective equipment for fire fighters : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self
Contained Breathing Apparatus) for fire fighters.
Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas containers to rupture. Cool endangered containers with water spray jet
from a protected position. Prevent water used in emergency cases from entering sewers and
drainage systems
Stop flow of product if safe to do so
Use water spray or fog to knock down fire fumes if possible.
Sulfur hexafluoride
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate area. Ensure adequate air ventilation. Prevent from entering sewers, basements and
workpits, or any place where its accumulation can be dangerous. Monitor concentration of
released product. Try to stop release.
6.1.1. For non-emergency personnel

6.1.2. For emergency responders
6.2. Environmental precautions
Try to stop release. Prevent waste from contaminating the surrounding environment. Prevent soil
and water pollution. Dispose of contents/container in accordance with
local/regional/national/international regulations. Contact supplier for any special requirements.
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
See also sections 8 and 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only where
temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from
falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand.
Store full and empty containers separately. Use a first-in, first-out inventory system to prevent
storing full containers for long periods
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in the
piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with
adequate ventilation. If a leak occurs, close the container valve and blow down the system in a
safe and environmentally correct manner in compliance with all international, federal/national,
state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
7.3. Specific end use(s)
None.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Sulfur hexafluoride (2551-62-4)
ACGIH ACGIH TLV-TWA (ppm) 1000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 6000 mg/m³
Sulfur hexafluoride

USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm

ACGIH ACGIH TLV-TWA (ppm) 1000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 6000 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm
8.2. Exposure controls

Appropriate engineering controls : Oxygen detectors should be used when asphyxiating gases may be released. Consider work
permit system e.g. for maintenance activities. Systems under pressure should be regularly
checked for leakages. Provide adequate general and local exhaust ventilation. Ensure
exposure is below occupational exposure limits (where available).
Hand protection : Wear working gloves when handling gas containers.
Eye protection : Wear safety glasses with side shields or goggles when transfilling or breaking transfer
connections. Wear safety glasses with side shields.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure. For
emergencies or instances with unknown exposure levels, use a self-contained breathing
apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.
Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
specific methods for waste gas treatment.
Other information : Wear safety shoes while handling containers. Wear leather safety gloves and safety shoes
when handling cylinders.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Colorless gas.
Molecular mass : 146 g/mol
Color : Colorless.
Odor : Irritating choking
Odor threshold : No data available
pH : Not applicable.
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -50.8 °C
Freezing point : No data available
Boiling point : -63.8 °C
Flash point : Not applicable.
Critical temperature : 45.5 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 23.07 bar (334.6 psia) (@20°C)
Critical pressure : 37.6 bar (545.3 psia)
Relative vapor density at 20 °C : No data available
Relative density : 1.4
Relative density of saturated gas/air mixture : 5.04
Sulfur hexafluoride
Density : 0.0061 g/cm³ (at 20 °C)

Relative gas density : 5
Solubility : Water: 41 mg/l
Log Pow : 1.68
Log Kow : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.
Explosive properties : Not applicable.
Oxidizing properties : None.
Explosion limits : Non flammable.
9.2. Other information
Sublimation point : -63.9 °C
Gas group : Liquefied gas
Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground
level
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
May occur.
10.4. Conditions to avoid
Avoid temperature above 800°C (1472°F).
10.5. Incompatible materials
Explodes violently in contact with disilane.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be
produced. Thermal decomposition may produce : Fluorides. Sulfur dioxide.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified

pH: Not applicable.
Serious eye damage/irritation : Not classified
pH: Not applicable.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Sulfur hexafluoride
SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No ecological damage caused by this product.
12.2. Persistence and degradability

Persistence and degradability Not applicable for inorganic gases.
Persistence and degradability Not applicable for inorganic gases.
12.3. Bioaccumulative potential
Log Pow 1.68
Log Kow Not applicable.
Bioaccumulative potential No data available.
Log Pow 1.68
Bioaccumulative potential No data available.
12.4. Mobility in soil
Mobility in soil No data available.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
12.5. Other adverse effects

Effect on ozone layer : None
Global warming potential [CO2=1] : 22200
Effect on the global warming : Contains Fluorinated greenhouse gases covered by the Kyoto protocol
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste treatment methods : Do not discharge into any place where its accumulation could be dangerous. Avoid discharge
to atmosphere.
Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international
regulations. Contact supplier for any special requirements.
SECTION 14: Transport information

In accordance with DOT
Transport document description : UN1080 Sulfur hexafluoride, 2.2
UN-No.(DOT) : UN1080
Proper Shipping Name (DOT) : Sulfur hexafluoride
Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Hazard labels (DOT) : 2.2 - Non-flammable gas
Additional information
Emergency Response Guide (ERG) Number : 126
Other information : No supplementary information available.
Sulfur hexafluoride
Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
UN-No. (IMDG) : 1080
Proper Shipping Name (IMDG) : SULPHUR HEXAFLUORIDE
Class (IMDG) : 2 - Gases
MFAG-No : 126
Air transport
UN-No. (IATA) : 1080
Proper Shipping Name (IATA) : Sulphur hexafluoride
Class (IATA) : 2
Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure
SECTION 15: Regulatory information

15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Sudden release of pressure hazard
15.2. International regulations

CANADA

Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
15.2.2. National regulations

Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
15.3. US State regulations

Sulfur hexafluoride(2551-62-4)
U.S. - California - Proposition 65 - Carcinogens List No
Sulfur hexafluoride
Sulfur hexafluoride(2551-62-4)
U.S. - California - Proposition 65 - Developmental No
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

U.S. - California - U.S. - California - U.S. - California - U.S. - California - Non-significant risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male
Female
No No No No

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product
Praxair asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information
The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe
that the information contained herein is current as of the date of this Safety Data Sheet. Since
the use of this information and the conditions of use are not within the control of Praxair, Inc, it
is the user's obligation to determine the conditions of safe use of the product
Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your Praxair sales representative, local distributor, or supplier, or download from
www.praxair.com. If you have questions regarding Praxair SDSs, would like the document
number and date of the latest SDS, or would like the names of the Praxair suppliers in your
area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247;
Address: Praxair Call Center, Praxair, Inc, P.O. Box 44, Tonawanda, NY 14151-0044)
PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair
Technology, Inc. in the United States and/or other countries.
Sulfur hexafluoride
NFPA health hazard : 2 - Intense or continued exposure could cause temporary

incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS III Rating

Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard
Physical : 2 Moderate Hazard
SDS US (GHS HazCom 2012) - Praxair
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

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Sulfur hexafluoride

Safety Data Sheet P-4657

SECTION: 1. Product and company identification

CHEMTREC, 24hr/day 7days/week

SECTION 2: Hazard identification

2.2. Label elements

2.3. Other hazards

EN (English US) SDS ID: P-4657 1/9

SECTION 3: Composition/Information on ingredients

SECTION 4: First aid measures

SECTION 5: Firefighting measures

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

EN (English US) SDS ID: P-4657 2/9

SECTION 6: Accidental release measures

6.1.1. For non-emergency personnel

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

EN (English US) SDS ID: P-4657 3/9

Sulfur hexafluoride (2551-62-4)

Sulfur hexafluoride (2551-62-4)

8.2. Exposure controls

SECTION 9: Physical and chemical properties

EN (English US) SDS ID: P-4657 4/9

Density : 0.0061 g/cm³ (at 20 °C)

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

EN (English US) SDS ID: P-4657 5/9

SECTION 12: Ecological information

12.2. Persistence and degradability

12.5. Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport information

Other information : No supplementary information available.

EN (English US) SDS ID: P-4657 6/9

SECTION 15: Regulatory information

15.2. International regulations

Sulfur hexafluoride (2551-62-4)

Sulfur hexafluoride (2551-62-4)

15.2.2. National regulations

15.3. US State regulations

EN (English US) SDS ID: P-4657 7/9

Sulfur hexafluoride (2551-62-4)

Sulfur hexafluoride (2551-62-4)

SECTION 16: Other information

EN (English US) SDS ID: P-4657 8/9

NFPA health hazard : 2 - Intense or continued exposure could cause temporary

HMIS III Rating

SDS US (GHS HazCom 2012) - Praxair

EN (English US) SDS ID: P-4657 9/9

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