Ridoline C 72 MSDS-P

Henkel Surface Technologies
Material Safety Data Sheet according to 91/155/EEC - ISO

11014-1
Classification and labelling according to GefStoffV.
Ridoline C 72
1. Identification of the product and of the company
---------------------------------------------------
Identification of the product:

Ridoline C 72
Company/undertaking identification:
HENKEL KGaA, D-40191 Duesseldorf
Tel.: ++49 (0) 211-797-0
2. Composition/information on ingredients
-----------------------------------------
cleaning agent
Declaration according recommendation 89/542/EEC:
more than 30 %: phosphates, 5 - 15 %: nonionic surfactants,
Further ingredients: sodium hydroxide,organic salt
Declaration of ingredients:
30-50% sodium hydroxide
Symbol: C
R-Phrases: 35
<5 % fatty alcohole;EO-PO
Symbol: Xi;N
R-Phrases: 36-50/53
<5 % fatty alcohole;ethoxylated
Symbol: Xi;N
R-Phrases: 36-50
3. Hazards identification of the product

----------------------------------------
R 35: Causes severe burns
4. First aid measures

---------------------
after inhalation:
Remove to fresh air.
Intensive inhalation: remove to fresh air, give oxygen, seek medical advice in hospital.
after skin contact:

Rinse with running water and soap. Skin care. Remove contaminated clothes.
after eye contact:
Immediately flush eyes with copious amounts of running water (for 10 minutes), put on a
bandage with sterile gauze, see an oculist.
after ingestion:
Drink plenty of water, immediate medical advice necessary.
5. Fire-fighting measures
-------------------------
Cool endangered containers with water spray jet.
Suitable extinguishing media:

not applicable
Extinguishing media which must not be used for safety reasons:

not applicable
Special exposure hazards arising from the product itself,

from combustion products or from resulting gases:
not flammable
Can be released in case of fire CO, CO2.
Special protective equipment for firefighters:

Put on breathing apparatus.
6. Accidental release measures

------------------------------
Personal precautions:
Avoid contact with skin and eyes.
Avoid dust formation.
Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
Methods of cleaning up/of removing:

Remove mechanically
wash away residue with plenty of water;
7. Handling and storage

-----------------------
Handling:
When diluting, always stir the product into standing water.
Avoid dust formation. Vacuum.
Storage:
store in a dry place;
keep container tightly sealed;
Do not store together with strong acids.
Storage Class: VCI-storage class: 8 (BRD)

8. Exposure controls / personal protection
------------------------------------------
Information on the system design:

Thorough dedusting.
Components with specific control parameters:

sodium hydroxide
CAS-Nr.: 1310-73-2
MAK: ppm (2 mg/m3)
Personal protection:
keep away from food, beverages and animal feed;
Respiratory protection: dust mask when dust is generated
Hand protection: suitable protective gloves
Eye protection: protective goggles
9. Physical and chemical properties

-----------------------------------
Physical state: powder

Colour: white -
pH: (at 10g/l H2O) (20'C) 12,8
Flash point: not applicable
Relative density: 900 kg/m3
10. Stability and reactivity

----------------------------
Conditions to avoid:
No decomposition if used according to specifications
Materials to avoid:
Reacts with acids: heat released
Reacts with water: generation of heat
Hazardous decomposition products:

none if used for intended purpose
In fire CO,CO2 may be generated
11. Toxicological information

-----------------------------
Skin contact:
The product causes corrosion on skin and mucous membranes.
12. Ecological information

--------------------------
Persistence and degradability:

Degradability:
This product contains surfactants which are 90 % biodegradable by reference to the
German regulation June 4, 1986.
In case of discharge of acidic or alkaline products into the sewerage system the pH must be
in the range of 6-10 since higher or lower pH values may damage the sewerage system or impair
biological sewage treatment plants. Local discharge statutes have to be observed.
13. Disposal considerations

---------------------------
special waste disposal with the approval of the responsible local authority;
Waste key number according to (LAGA) (Lçnderarbeitsgemeinschaft
Abfall)(Germany): 51310 (Zuordnung)
14. Transport information

-------------------------
Transport over land ADR/RID:

Class: 8 Number/Letter: 41b
1st numbering of tanks panel: 80
2nd numbering of tanks panel: 1823
Designation of goods:
1823 Natriumhydroxid, fest Gemisch
Transport over inland waterways ADN/ADNR:

Class: 8 Number/Letter: 41b
Category:
Designation of goods:
Natriumhydroxid, fest Gemisch
Transport over sea IMDG:

Class: 8 UN-Nr.: 1823 PG: II
EmS: 8-06
MFAG: 705
Proper shipping name:
Sodium hydroxide, solid, mixture
Transport by air ICAO/IATA:

Class: 8 UN/ID-Nr.: 1823 PG: II
Proper shipping name:
Sodium hydroxide, solid, mixture
15. Regulatory information

--------------------------
Classification and labelling according to GefStoffV:
Symbols of danger:
C Corrosive
Ingredients:
sodium hydroxide
R-phrases:
R 35: Cause severe burns
S-phrases:
S 22: Do not breathe dust
S 26: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice
S 37/39: Wear suitable gloves and eye/face protection
S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible)
National prescriptions:
WGK = 2. Classification according to Annex 2 of the ÜV erwaltungs-Vorschrift

assergefçhrdende StoffeÜ vom 18. April 1996.
Note the German BG-Chemie data sheet Çtzende Stoffe!
16. Other information

---------------------
This information is based on our current level of knowledge and relates to the product in the
state in which it is delivered. It is intended to describe our products from the point of view of
safety requirements and is not intended to guarantee any particular properties.

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Henkel Surface Technologies

Material Safety Data Sheet according to 91/155/EEC - ISO

Identification of the product:

3. Hazards identification of the product

R 35: Causes severe burns

4. First aid measures

after skin contact:

Cool endangered containers with water spray jet.

Suitable extinguishing media:

Extinguishing media which must not be used for safety reasons:

Special exposure hazards arising from the product itself,

Special protective equipment for firefighters:

6. Accidental release measures

Methods of cleaning up/of removing:

7. Handling and storage

Do not store together with strong acids.

Storage Class: VCI-storage class: 8 (BRD)

Information on the system design:

Components with specific control parameters:

9. Physical and chemical properties

Physical state: powder

10. Stability and reactivity

Hazardous decomposition products:

11. Toxicological information

12. Ecological information

Persistence and degradability:

13. Disposal considerations

14. Transport information

Transport over land ADR/RID:

Transport over inland waterways ADN/ADNR:

Transport over sea IMDG:

Transport by air ICAO/IATA:

15. Regulatory information

Classification and labelling according to GefStoffV:

WGK = 2. Classification according to Annex 2 of the ÜV erwaltungs-Vorschrift

Note the German BG-Chemie data sheet Çtzende Stoffe!

16. Other information

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