Nautical Fragrance 175413 - MSDS

MATERIAL SAFETY DATA SHEET
--------------------------
NAUTICAL FRAGRANCE 175413 Page 1(4)
Date: 7 October 2005
MSDS Revision: 03 Date created: 11/08/05
1.Identification of the substance/preparation and company

---------------------------------------------------------
Product name : NAUTICAL FRAGRANCE 175413
Company name : Gracefruit.com
Company address : 146 Glasgow Road
Longcroft
Stirlingshire
FK4 1QL
Emergency phone : 01324 411587
2.Composition/information on ingredients
----------------------------------------
Chemical : Composition: multicomponent mixture of natural and/or
identification synthetic raw materials.
CAS number : Not applicable, product is a mixture.
EINECS number : Not applicable, product is a mixture.
Contains CAS/EINECS Hazard Symbols Conc%

1-(1,2,3,4,5,6,7,8-OCTAHYDRO-2,3,8,8-TET 54464-57-2 N; R 51/53 10.0
RAMETHYL-2-NAPHTHYL)ETHAN-1-ONE /259-174-3
1-(5,6,7,8-TETRAHYDRO-3,5,5,6,8,8-HEXAME 21145-77-7 Xn-N; R 22-50/53 10.6
THYL-2-NAPHTHYL)ETHAN-1-ONE /244-240-6
ALPHA-ISOMETHYL IONONE 127-51-5 -; R 52/53 1.8
/204-846-3
BENZYL BENZENE 101-81-5 N; R 50/53 0.1
/202-978-6
(L) BUTYLPHENYL METHYLPROPIONAL 80-54-6 Xn; R 22-43 3.5
/201-289-8
(L) CARVONE 6485-40-1 Xn; R 22-43 1.2
/229-352-5
CITRONELLOL 106-22-9 Xi-N; R 38-43-51/53 0.3
/203-375-0
(L) COUMARIN 91-64-5 Xn; R 22-43 2.0
/202-086-7
HEXAHYDROHEXAMETHYL CYCLOPENTABENZOPYRAN 1222-05-5 N; R 50/53 8.8
/214-946-9
(L) HYDROXYISOHEXYL 3-CYCLOHEXENE CARBOX 31906-04-4 Xi; R 43 2.0
ALDEHYDE /250-863-4
(L) Ingredient must be disclosed on a label (normal disclosure)

(S) Ingredient must be disclosed on a label as a sensitiser
("Contains_. May cause an allergic reaction.")
Ingredients with prefix L or S are for label disclosure in accordance with

The Chemicals (Hazard Information and Packaging for Supply) Regulations NOT
for the ingredient list applicable to Cosmetic & Detergent legislation
--------------------------
3.Hazards identification
------------------------
General : When undiluted and not properly handled, can be irritating
to the skin and eyes and upon excessive inhalation.
Combustible material that can sustain fire.
Hazard symbol : Xi, Irritant.
: N, Dangerous for the environment.
Risk phrases : R43, May cause sensitisation by skin contact.
: R51/53, Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Environment : When spilled, can contaminate soil, ground and surface
water.
4.First-aid measures
--------------------
Inhalation : Upon excessive inhalation, remove from exposure site to
fresh air, keep at rest, and obtain medical attention.
Eye exposure : Flush immediately with water for at least 15 minutes.
Contact physician if symptoms persist.
Skin exposure : Remove contaminated clothes. Wash thoroughly with soap and
water. Contact physician if irritation persists.
Ingestion : Rinse mouth with water and obtain medical attention.
Others : Take Risk and Safety phrases (section 15) into
consideration.
5.Fire-fighting measures
------------------------
Extinguishing : Carbon dioxide, dry chemical, foam.
media Do not use a direct water-jet on burning material.
6.Accidental release measures

-----------------------------
Personal : Avoid excessive inhalation and contact with skin and eyes.
precautions A self-contained breathing apparatus is recommended in
case of a major spill.
Spillage : Remove ignition sources. Provide adequate ventilation.
Avoid excessive inhalation of vapours. Gross spillage
should be contained immediately by use of sand or inert
powder and disposed of according to local regulations.
Environmental : Keep away from drains, surface and ground water, and soil.
precautions
--------------------------
7.Handling and storage

----------------------
Handling : Apply according to good manufacturing and industrial
hygiene practices with proper ventilation. Do not drink,
eat or smoke while handling. Respect good personal
hygiene.
Storage : Store in a cool, dry and ventilated area away from heat
sources and protected from light in tightly closed
original containers. Avoid plastic and uncoated metal
containers. Keep air contact to a minimum.
Fire : Keep away from ignition sources and naked flame.
protection
8.Exposure controls/personal protection

---------------------------------------
Respiratory : Avoid excessive inhalation of concentrated vapours.
protection
Eye protection : Wear safety glasses.
Skin protection : Avoid skin contact. Use chemically resistant gloves as
needed.
9.Physical and chemical properties

----------------------------------
Appearance : Clear pale yellow to pale brown liquid
Flash point : 87 degC (CC)
10.Stability and reactivity

---------------------------
Reactivity : Presents no significant reactivity hazard, by itself or in
contact with water. Avoid contact with strong acids,
alkali or oxidising agents.
Decomposition : Carbon monoxide and unidentified organic compounds may be
formed during combustion.
11.Toxicological information
----------------------------
Based on the ingredients in this composition and their concentrations, this
product is according to the conventional method of EEC directive 88/379/EEC
classified as:
May cause sensitisation by skin contact.
12.Ecological information
-------------------------
General : This material is unlikely to accumulate in the environment
and environmental problems under normal use conditions are
unexpected.
--------------------------
13.Disposal considerations
--------------------------
Dispose of according to local regulations.
Avoid disposing into drainage systems and into the environment.
14.Transport information
------------------------
Class Pack Group Sub risk UN no IMDG page
Road (CDGRR) : not restricted.
Air (IATA) : not restricted.
Sea (IMDG) : not restricted.
15.Regulatory information
-------------------------
Classification Packaging / Labelling (Directive 1999/45/EC)
Hazard symbol : Xi, Irritant.
: N, Dangerous for the environment.
Contains BUTYLPHENYL METHYLPROPIONAL, CARVONE, COUMARIN, HYDROXYISOHEXYL 3-
CYCLOHEXENE CARBOXALDEHYDE.
Risk phrases : R43, May cause sensitisation by skin contact.
: R51/53, Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety phrases : S24, Avoid contact with the skin.
: S37, Wear suitable gloves.
: S61, Avoid release to the environment. Refer to special
instructions/safety data sheet.
16.Other information
--------------------
Conc % Limits (*) : XiR43=28.57% NR51/53=12.19% R52/53=1.22% R53=79.18%
IFRA=71.429% IFRANS=714.286%
IFRANS = Alternative maximum usage in IFRA Non-Skin applications.

(*) These are the maximum percent concentrations that this material can be
used in a non-hazardous product without the indicated risk being applicable
to that product.
The information in this leaflet is to the best of our knowledge true and
accurate but all data, instructions, recommendations and/or suggestions are
made without guarantee.
In addition to the concentration limits applicable to the Dangerous Substance

and Dangerous Preparations Directives any IFRA limits provided are general
skin and non skin product concentrations. For limits against specific product
categories please contact gracefruit.com.

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MATERIAL SAFETY DATA SHEET

1.Identification of the substance/preparation and company

Emergency phone : 01324 411587

Contains CAS/EINECS Hazard Symbols Conc%

(L) Ingredient must be disclosed on a label (normal disclosure)

Ingredients with prefix L or S are for label disclosure in accordance with

6.Accidental release measures

7.Handling and storage

8.Exposure controls/personal protection

9.Physical and chemical properties

10.Stability and reactivity

IFRANS = Alternative maximum usage in IFRA Non-Skin applications.

In addition to the concentration limits applicable to the Dangerous Substance

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