Msds Peroxide Reagent 1023636

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Material Safety Data Sheet

according to 91/155/EEC

H2O2-Reagent–03 Revision: 05-09-2005


2005

1. Product and Company Identification

Product Identification: H2O2- Reagent - Part No.: 1023636

Company Identification: ProMinent Dosiertechnik GmbH


69123 Heidelberg, Im Schuhmachergewann 5-11
REG- No.: HRB 1350 / Heidelberg -Germany-
Tel: +49 (0)6221 842-0

2 Composition / Information on Ingredients

Contains: - Titanylsulfate (TiOSO4) CAS No 13825-74-6 <10 %


- Sulfuric Acid (H2SO4 ) CAS No 7664-93-9 < 25 %
in aqueous solution.

Hazardous ingredients for health: contains > 15 % Sulfuric Acid


Symbol: C ( corrosive) R-phrase: 35

3 . Hazards Identification of the Product

R 35: Causes severe burns

4 . First aid measures

after skin contact: Rinse with running water and soap. Skin care.
Remove contaminated clothes.
after eye contact: Immediately flush eyes with copious amounts of running water
(at least for 10 minutes) see an oculist.
After ingestion: Drink plenty of water. Avoid vomiting. Immediately see a physician.

5 . Fire-fighting measures

Suitable extinguishing media: are to be fit in with the environment


Extinguishing media which must not be used for safety reasons: not applicable
Special exposure hazards: not flammable.

6. Accidental release measures

Personal Precautions: Avoid contact with skin and eyes.


Environmental precautions: Do not allow to flow into drainage system.
Methods of cleaning up / of removing: dilute with plenty of water, then neutralize with
alcaline solutions, lime (CaCO3), soda (Na2CO3) or sodium bicarbonate (NaHCO3).

7 . Handling and storage

Handling: The product is to be handled with the usual care and caution for chemicals.
Storage: Keep original container tightly sealed.

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Material Safety Data Sheet
according to 91/155/EEC

H2O2-Reagent–03- Revision: 05-09-2005

8. Exposure / personal protection

Components with specific control parameters:


Sulfuric Acid: 1 mg/m³ peak limit: -1- (TRGS 900)
Eye protection: necessary
Hand protection: necessary

9. Physical and chemical properties:

physical state: liquid


colour: colourless
odour: odourless
pH-value: approx. 0 (undiluted at 20 °C)
cold sensitivity: under -5 °C
flash point: not applicable
vapour pressure: (aqueous solution)
relative density: approx. 1.2 kg/l (20 °C)
solubility: miscible in water (20 °C)

10. Stability and Reactivity

Conditions to avoid: no decomposition if used according to specifications


Materials to avoid: reaction with lyes: heat generated
reaction with metals: hydrogen released
Hazardous decomposition products: none known

11. Toxicological Information

Quantitative data regarding the toxicology of the product are not known.
Titanylsulfate LD50 : not available
Sulfuric Acid LD50 : 2140 mg/kg (oral, rat)
After skin contact: severe burns with formation of scabs.
After eye contact: burns, corneal lesions
After swallowing: severe pain (risk of perforation), nausea, vomiting

12. Ecological Information

Degradability: not pertinent, inorganic product


Aquatic toxicity: Harmful due to pH shift.
In case of discharging the acidic product into the sewerage system, the treated waste
water should have a pH-value according to local discharge regulations.

13. Disposal Considerations

In consultation with the responsible local authority, must be subjected to special


treatment: neutralisation. In case of chemical collecting actions of the authorities,
small containers can be handed over together with this safety data sheet.

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Material Safety Data Sheet
according to 91/155/EEC

H2O2-Reagent–03 Revision: 05-09-2005


2005

14. Transport Information

The product is a hazardous material according to the transport norms:


GGVS/ADR/GGVE/RID : class 8/1b
IMDG-Code : 8/II UN 2796
ICAO/IATA : 8 UN 2796 PAX 809 CAO 813

15. Regulations

Classification and labelling according to the norm for hazardous materials


annex II No 1, dated on Nov. 1st 1993:
Symbols of danger: C Corrosive
R-phrases: R 35: Causes severe burns
S-phrases: S 26-30-36/37/39-45

In case of contact with eyes, rinse immediately with plenty of


water and seek medical advise. Never add water to this product.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible.
National Prescriptions: water pollution class (WGK): 1

16. Other Information

This information is based on our current level of knowledge and relates to the product
in the state in which it is delivered. It is intended to describe our products from the
point of view of safety requirements and is not intended to guarantee any particular
properties.
Since ProMinent cannot anticipate or control the conditions under which this product may be
used, each user must, before using this product, assess and control the risks arising from
their use of this product.

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