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    P ω= dB PT BP H dT dB PT U dT dB P S BP G: - r - = T sat r

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    Dhwani Shah
    This document summarizes several equations of state and thermodynamic property relations: 1) It presents the virial equation of state and defines parameters for modeling vapor pressure. 2) It shows the van der Waals and Redlich-Kwong equations of state and gives expressions for calculating internal energy, enthalpy, and other properties. 3) It lists the fundamental thermodynamic relations for changes in internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy in terms of temperature, pressure, and volume changes.

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    P ω= dB PT BP H dT dB PT U dT dB P S BP G: - r - = T sat r

    Uploaded by

    Dhwani Shah
    27 views1 page
    This document summarizes several equations of state and thermodynamic property relations: 1) It presents the virial equation of state and defines parameters for modeling vapor pressure. 2) It shows the van der Waals and Redlich-Kwong equations of state and gives expressions for calculating internal energy, enthalpy, and other properties. 3) It lists the fundamental thermodynamic relations for changes in internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy in terms of temperature, pressure, and volume changes.

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    Formulae of chemical engg thermodynamics

    Original Title

    CHE201 New

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    This document summarizes several equations of state and thermodynamic property relations: 1) It presents the virial equation of state and defines parameters for modeling vapor pressure. 2) It shows the van der Waals and Redlich-Kwong equations of state and gives expressions for calculating internal energy, enthalpy, and other properties. 3) It lists the fundamental thermodynamic relations for changes in internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy in terms of temperature, pressure, and volume changes.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    27 views1 page

    P ω= dB PT BP H dT dB PT U dT dB P S BP G: - r - = T sat r

    Uploaded by

    Dhwani Shah
    This document summarizes several equations of state and thermodynamic property relations: 1) It presents the virial equation of state and defines parameters for modeling vapor pressure. 2) It shows the van der Waals and Redlich-Kwong equations of state and gives expressions for calculating internal energy, enthalpy, and other properties. 3) It lists the fundamental thermodynamic relations for changes in internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy in terms of temperature, pressure, and volume changes.

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    © All Rights Reserved
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    of 1

    CHE201 Chemical Engineering Thermodynamics, IIT (BHU)

    Virial Equation of State


    0.422 0.172
    B0 = 0.083 − 1.6
    B1 = 0.139 − 4.2 ω= − 1 − log10 Prsat
    Tr Tr Tr = 0 .7

    dB dB dB
    H R = BP − PT , U R = − PT , S R = −P , G R = BP .
    dT dT dT

    van der Waals Equation of State


    RT a 27R 2Tc2 RT
    P= − 2 a= b= c
    V −b V 64Pc 8Pc
     RT  2 a ab
    V 3 − b + V + V − =0
     P  P P
    a bRT 2a P(V − b ) G R RT b 2a
    UR =− , HR = − , S R = R ln , = ln + − .
    V V −b V RT RT P(V − b ) V − b RTV

    Redlich-Kwong Equation of State


    RT a 0.42748R 2Tc2.5 0.08664RTc
    P= − 1 a= b=
    V − b T 2V (V + b ) Pc Pc
    RT 2  2 bRT a  ab
    V3 − V − b + − V − =0
    P  P TP TP
     V   V 
    H R = (Z − 1)RT +
    3a 3a
    UR = ln , ln ,
    2b T V+b 2b T V+b
    P (V − b ) a V
    S R = R ln + ln ,
    RT 2bT 3/ 2
    V +b
    GR b RT a  1 1 V 
    = + ln − 1.5 
    − ln .
    RT V − b P(V − b ) RT  V + b b V + b 

    Thermodynamic Property Relations


    dU = TdS − PdV dH = TdS + VdP
    dA = −SdT − PdV dG = VdP − SdT
      P     V  
    dU = CV dT + T   − P  dV dH = C P dT + V − T    dP
      T V    T  P 
     S  C  S  C
      = P   = V
     T  P T  T V T
    P
      2V   2P 
    V
    C P = C − T   2
    0
     dP C V = C + T   2  dV
    0

    0  T   T  V
    P V
    P
    1  V  1  V  TV 2
    =   KT = −   C P − CV =
    V  T  P V  P  T KT
    dM dM
    M1 = M + x 2 M2 = M - x1
    dx 1 dx 1

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