Chem Module 3 Worksheets

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® KEEP IT SIMPLE SCIENCE

keep it simple science Chemistry Module 3
Reactive Chemistry
WORKSHEETS
Worksheet 1 Predicting Reactions & Writing Equations
Practice Problems Student Name...........................................
From each description, predict the outcome by: 4. Combustion
Gaseous butane (C4H10) burns in air to form carbon
a) writing a chemical equation in words. dioxide & water vapour.
b) writing a balanced equation in symbols, including
the state of each species. a)
1. Synthesis b)
In the industrial production of sulfuric acid there are
3 reactions in sequence. Firstly, solid sulfur is
burned in air to form sulfur dioxide gas. 5. Precipitation
a) If solutions of potassium sulfide & barium nitrate are
mixed, a precipitate of barium sulfide forms. Another
product remains in solution.
b)
a)
Next, the sulfur dioxide is reacted with more oxygen

to form sulfur trioxide gas. b)
a)
6. Acid-base
When mixed in the correct proportions, solutions of
b) nitric acid & calcium hydroxide will neutralise each
other.
Finally, the sulfur trioxide is reacted with liquid a)

water to form a solution of sulfuric acid.
a)
b)
b) 7. Acid-carbonate
If sulfuric acid solution is poured onto solid lithium
carbonate, the mixture bubbles furiously. At the end
2. Decomposition of the reaction, a colourless solution remains.
If iron (III) carbonate is heated, it decomposes into
iron (III) oxide plus carbon dioxide. a)
a)
b)
b)
8. You figure it out!
The gas ammonia can be manufactured directly
3. Decomposition from its gaseous elements.
The iron oxide formed in Q2 is mixed with powdered a)
charcoal (carbon) & heated in a blast furnace. This
forms elemental iron (as a liquid due to the heat) &
carbon dioxide. b)
a)
9. Solid sodium sulfide reacts with oxygen to form 2
oxide compounds; 1 solid, 1 gas.
b) a)
b)
Chem Mod.3 “Reactive Chem.” Worksheets page 1 Usage & copying is permitted according
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® Worksheet 2 Metal Reactions

keep it simple science Student Name......................................
1. Write a balanced, symbol equation for the 3. All the following equations are Metal + Acid
reaction of each of the following metals with reactions. Fill in all blank spaces, then re-write in
oxygen. symbols and balance.
a) Lead (assume lead(IV) ion forms)
a) Zinc + Sulfuric acid ................. +.....................
b) Iron (Assume iron(III) ion)
b) Calcium + Hydrochloric ................. +.................

c) Lithium acid
2. Write a word equation AND a balanced, symbol

equation to describe the reaction of:
a) calcium metal with water (reacts spontaneously at c).................. +...................... Hydrogen + Barium
room temperature) nitrate
b) Tin metal with water (heated in steam) (Assume d).................... + .................... Hydrogen + iron(II)
tin(II)) chloride
Worksheet 3 Metal Displacement Reactions

For each combination, firstly use the “Activity Student Name......................................
Series” to decide whether or not a reaction would
occur. If not, write “no reaction”. 3. Aluminium metal placed in a solution of Cu2+
If a reaction would occur: ions.
a) write half-equations for the change occurring to

each species. Label each half-reaction as “oxidn.”
or “reduction”
b) write a balanced, net ionic equation for the 4. Copper metal placed in a solution of Ag+ ions.
overall reaction.
1. Magnesium metal placed in a solution of

Pb2+ ions.
5. Iron metal placed in a solution of Ba2+ ions.
2. Lead metal placed in a solution of Mg2+ ions. 6. Calcium metal placed in a solution of
Sn2+ ions.
® Worksheet 4 Activity Series

keep it simple science Fill in the blanks Student Name......................................
When a metal reacts with oxygen it forms an All these reactions involve the transfer of
a)......................... compound. m)......................... In the case of the Metal + Acid
reaction, the metal atoms always n).........................
Some metals will also react with water, forming electron(s) while a pair of o)............................ ions
b)..................................... gas and a gain 2 electrons (which they share in a
c)...................................... compound. p)......................... bond) and form a q)......................
Most metals will react with acids, forming molecule with formula r)...........
d)......................... gas & an ionic compound,
generally called a “e).....................” “Oxidation” is the technical term for s).....................
.................... The opposite is “t).................................”
In all these reactions the various metals react at In the Metal + Acid reaction, the metal is always
f)............................... rates, showing an order of u).............................................. while
chemical g).............................. From these reactions v).............................. ions are always
and others, the “Activity Series” has been w)..................................................
determined.
The “x)........................... Energy” of an element is
Metals such as h)...................... and ............................. defined as the energy required to y)...............
are the most active. These are the elements located ............................. from atoms in the z).................
in the i)....................... columns of the Periodic Table. state. The very active metals are like that because
they have very aa).................... (high/low) values for
Some metals such as j)....................... and this. Metals further down the series do not react as
......................... have very low activity, and often do vigorously because their values are
not react at all. Other common metals like ab)...........................................
k).................................. and .................................... are
in the middle of the series. They will react, but
generally do so l).......................................
Worksheet 5 Test-Style Questions

Multiple Choice Student Name......................................
1. A metal which reacts readily and vigorously with 5. (6 marks)
oxygen, water and dilute acids would probably: Write a balanced symbol equation for the reaction of:
A. have a high value for 1st ionisation energy. a) magnesium with hydrochloric acid.
B. be from the “Transition” block of the Periodic Table.
C. have a very low 1st ionisation energy. b) calcium with water (reacts at room temperature).
D. be located at extreme right of the Periodic Table.
c) potassium with oxygen.
2. If nickel reacted with sulfuric acid, the products of the
reaction would be:
A. hydrogen gas and nickel sulfate 6. (4 marks)
B. carbon dioxide gas and nickel sulfate. When barium metal reacts with an acid there is an
C. nickel sulfide and hydrogen gas. exchange of electrons such that hydrogen gas and
D. sulfur dioxide gas and nickel hydroxide. barium ions are formed. Write 2 “half-equations” to show
clearly the species gaining, and the species losing,
3. During the reaction in Q5, the basic underlying change electrons.
occurring is:
A. the breaking covalent bonds.
B. the transfer of electron(s) from one species to another.
C. chemical changes in “spectator ions”.
D. physical dissolving of metal in the acid. 7. (4 marks)
Longer Response Questions

a) Write an equation (including states) for the ionisation of
magnesium which might be used to determine the
Mark values shown are suggestions only, and are to give “1st ionisation energy” for this element.
you an idea of how detailed an answer is appropriate.
Answer on reverse if insufficient space.
b) Describe how the Activity Series of Metals is related to
4. (5 marks) the values of 1st Ionisation Energy.
Give an outline of an experiment you have done to
investigate the relative chemical activity of some metals.
Include the observation(s) you made to assess metal
activity, and state the conclusion(s) reached.
®
Worksheet 6 REDOX half-equations
keep it simple science
Answer in the spaces provided. Student Name......................................
(on reverse, if insufficient room)
e) 2HCl(aq) + Fe(s) FeCl2(aq) + H2(s)
1. For each of the following reactions, write
separate half-equations (including electrons) for
the oxidation & the reduction. (In some cases, this
may require elimination of “spectator ions”.)
2.
a) Cu(NO3)2(aq)+ Mg(s) Mg(NO3)2(aq + Cu(s) Define “oxidation” and “reduction” and outline the
role of electron transfer in a REDOX reaction.
b) I2(aq) + Zn(s) ZnI2(aq)
3.
Combine these half-equations to form a balanced
net ionic equation.
c) H2SO4(aq) + Ca(s) CaSO4(aq) + H2(g) a) Zn(s) Zn2+(aq) + 2e-
Fe3+(aq) + e- Fe2+(aq)
d) 3Br2(aq) + 2Al(s) 2AlBr3(aq) b) O2(g) + 4H+(aq) + 4e- 2H2O(l)

Mg(s) Mg2+(aq) + 2e-
Worksheet 7 REDOX & Galvanic Cells

Fill in the blanks Student Name......................................
The “a).......................... Series” of Metals contols
what happens when a metal reacts with the The 2 half-cells must be connected by a conducting
b).................... of another metal in solution. If the circuit so that r).......................... can flow from the
metal is c)............................... the Series, it will s)......................... to the t).............................
d)................................. the lower-activity ion from the
solution. In this process, the atoms of the higher- Half-cells must also be connected by a
activity metal e)......................... electrons, and “u)....................... Bridge” to allow v).............. to
become ions in the solution. The process of losing diffuse between half-cells, so that the total
electrons is called “f)................................” w).................... .......................... remains balanced.
Meanwhile, the ions of the less-active metal The voltage (or x)..........................................) of a cell
g)...................... electrons and form atoms, which can be determined from a table of
form a solid precipitate. The process of gaining “y)................................... Potentials”. Each half-
electrons is called h).............................................. reaction has been measured (under z)......................
conditions) against a “reference half-cell”. The
Neither process can occur alone; each can only reference used is the aa)........................
happen with the other, so the entire reaction is ........................... half-reaction which has been given
called i)............................ - ............................. or a value of ab).................... volts, and all other half-
simply “j).....................” cells measured against it.
Although oxidation and reduction must occur For Galvanic Cells, when combining any 2 half-
together, they can be separated as long as equations from the table, the one ac)..........................
k)............................. can flow from the site of the table must always by written as an
l)........................... to the site of m).......................... ad)................................., and its Eo value
through a wire. This is the basis of all electrical ae).................................. You can then af)....................
n).......................... and .................................... the 2 Eo values to get the total cell ag)......................
under standard conditions.
A typical electric cell consists of 2
o).................................... In one, called the A Galvanic Cell is one which has a ah).......................
p)................................, oxidation occurs, while cell EMF and will run ai).................................. when
reduction occurs in the q)............................. half-cell. connected.
® Worksheet 8 Galvanic Cells

keep it simple science Answer in the spaces provided. Student Name......................................
(on reverse, if insufficient room)
For each cell diagram or description, below: 4. An inert graphite electrode is in contact with an
a) Write half-equations for each half-cell. Label each acid (contains H+) in a stream of H2(g).
as “Anode reaction” or “Cathode reaction”
This is connected to a Zn /Zn2+ half-cell.
b) Find the cell EMF under standard conditions.
c) Write an overall, balanced, net ionic equation for

the cell
V
1.
Mg Cu
Mg2+ Cu2+
5. The same H+/H2 half cell is connected to one

containing a graphite electrode in a solution
containing Cl- ions, and dissolved Cl2(aq)
2. One half cell comprises an iron electrode in a

solution of Fe2+ ions. The other has a magnesium
electrode in Mg2+
6. (C) I-(aq)|I2 || O2, H+|H2O (C)

3. Ca|Ca2+ || Cu2+|Cu
® Worksheet 9 Test-Style Questions Section 3

Multiple Choice 5. (cont)
1. c) Sketch a galvanic cell which could be set up (using
If each of the following metals were placed into a solution simple laboratory equipment and appropriate chemicals)
of copper(II) sulfate, which one would NOT react? which would use the same reactions described in part
A. silver B. zinc (a) & (b). Label the “anode”, “cathode” and “salt bridge”
C. iron D. magnesium and show the direction of electron flow in the external
circuit.
2. V
In the cell shown:
A. electrons would flow
towards the Mg half-cell.
B. zinc ions would be
oxidized. Mg Zn
C. positive ions would
flow out of the Mg
half-cell. d) Determine the value of the cell voltage under standard
D. the zinc half-cell conditions.
is the anode.
Mg2+ Zn2+
6. (6 marks)
3. Solid copper metal reacts with a solution containing
The Galvanic Cell shown in Q2 uses a metal and ions of molecular chlorine (Cl2(aq)) to form chloride ions and
the same metal in each half-cell. If you built a series of copper(II) ions, both in solution.
similar cells, but used different metal combinations in a) Write a balanced equation (including states) for the
each case, which of the following would give the highest reaction described.
cell voltage? (Assuming all other variables were kept the
same.)
A. iron & zinc B. copper & silver
C. copper & magnesium D. magnesium & zinc b) State the “oxidation number” for each species in the
equation, and hence state which species has been
4. oxidized and which has been reduced.
In the following equation, which species has undergone
reduction?
Cl2(aq) + 2Br-(aq) Br2(aq) + 2Cl-(aq) c) Write half-equations for the reaction, and calculate the
cell voltage which would be produced if this reaction
A. Cl2(aq) B. Br-(aq) was used in a Galvanic cell under standard conditions.
C. Br2(aq) D. Cl-(aq)

Mark values shown are suggestions only, and are to give you an idea of
how detailed an answer is appropriate.
Answer on reverse if insufficient space. 7. ( marks)
A galvanic cell is set up in which both half-cells
5. (10 marks) contain inert graphite electrodes. In one half-cell,
a) Write a net ionic equation for the reaction which the electrode dips into an acid solution (H+ ions)
occurs when a piece of magnesium metal is dropped and has oxygen gas bubbling around it.
into a solution of lead(II) nitrate. The other half-cell contains a mixture of molecular
I2(aq) and I-(aq) ions.
a) Write the anode half-equation.

b) Write 2 separate “half-equations” for the reaction, and
label each as either “oxidation” or “reduction”.
b) Write the cathode half-equation.
c) Write the balanced, net equation. (no spectators)
d) Determine the cell EMF (under standard conditions)
® Worksheet 10 Rate of Reaction

keep it simple science Fill in the blanks Student Name......................................
The rate of a combustion reaction depends If solid substances are involved, then
on the reactant molecules reaction rate can be increased by
a)................................... with each other. increasing the u)............................................
In a slow combustion, such as the burning of the solid, such as by
of b)......................................, the reaction v)..............................................
only occurs at the surface where
c).......................... can reach the fuel. In a A “catalyst” is a substance which
gas stove or bunsen burner the fuel and w)........................... the rate of a reaction,
air are mixed before d).............................. without x).............................. or
The rate of reaction is limited only by the ................................. by the reaction. In
flow of e).................... & ...................... to the living things, all chemical reactions are
burner nozzle. controlled by catalytic proteins called
y).........................................
If a fuel-air mixture is allowed to build up,
a spark or flame can result in an Catalysts speed up a reaction by reducing
f)................................... Any combustible the z).......................................................
gas or even g)...................... can become an This means that, at any given temperature,
explosive mixture if allowed to mix with air. there are more reactant molecules with
This has important h)........................... enough aa).......................... to commence
implications for workplaces which produce the reaction, so the ab).................................
dust or fibres, such as i)..........................., increases.
........................., etc. (examples)
Some catalysts work by ac)..........................
According to the “j)................................. reactant molecules to their surface in such
Theory of Matter”, all substances contain a way that collisions become more
particles which are constantly ad)................................. Chemical bonds
k).............................. Adding heat energy may also be placed under ae).......................
causes the particles to l)............................ which makes it more likely that they can
....................... Temperature is a measure of be af)......................... to begin the reaction.
the average m)............................................... This type of catalyst is common in
of the particles. industry, such as the use of
ag)............................. catalyst in the
An increase in temperature causes all production of ammonia, and the use of the
chemical reactions to n)................................. clay mineral ah)................................. in the
This is because the particles will move “ai).......................... Cracking” in petroleum
o).............................., and the chances of refining.
p)................................. increases. Also, the
reactant molecules are more likely to have Other catalysts work by providing an
the necessary q)......................................... aj)..................................................... pathway
energy at higher temperatures. from reactants to products. In these cases,
the catalyst actually takes part in the
Higher r)............................ also increases reactions, but is ak).......................................
reaction rates by making it more likely that unchanged at the end.
s).................................. will occur. In gases,
the t).................................... of the gas is
equivalent to the concentration.
® Worksheet 11 Test-Style Questions, section 4

Multiple Choice 5. (4 marks)
1. In the upper atmosphere is a region called the
The risk of an explosive combustion is increased “ozone layer” where the gas ozone (O3) protects
by: the Earth by absorbing dangerous U.V. radiation
A. increasing the particle size of solid fuels. from the Sun. Certain human-made chemicals can
B. decreasing the collision rate of reactant release single chlorine atoms which react with
molecules. ozone as follows:
C. storing liquid fuel in larger tanks or drums. Cl(g) + O3(g) ClO(g) + O2(g)
D. allowing build-up of dust or fibres in the air.
Then the ClO(g) reacts with the occasional single
2. oxygen atoms which occur at this altitude:
The rate of a chemical reaction could NOT be ClO(g) + O(g) Cl(g) + O2(g)
increased by
A. increasing the temperature. The overall reaction is: O3(g) + O(g) 2O2(g)
B. reducing the pressure of a reactant gas.
C. adding a catalyst. The result is the destruction of ozone. This allows
D. increasing the concentration of a reactant more dangerous U.V. radiation to penetrate to the
solution. surface of the Earth.
3. a) In what sense can the chlorine atom (Cl(g)) be

Catalysts can speed up a chemical reaction by: considered as a “catalyst” in the overall reaction?
A. decreasing the activation energy.
B. increasing the activation energy.
C. causing reactant particles to move faster.
D. cause different products to form, via different
pathways.
b) Explain the “mechanism” of this catalytic action.
Mark values shown are suggestions only, and are to give you an idea of
how detailed an answer is appropriate.
Answer on reverse if insufficient space.
4. (5 marks)
During your study of this topic you have carried
out a “hands-on” practical exercise to observe the
effect of certain factors on the rate of a chemical
reaction. 6. ( marks)
a) Outline the “Collision Theory” of reaction rates.
Describe the experiment you did to investigate the
effect of either temperature or concentration on
reaction rate. Include:
a) a brief outline of the method used.
b) What effect on reaction rate would each of the

following changes cause and why?
b) description of exactly what observation or i) lowering the temperature.
measurement was used to get a result.
ii) increasing the gas pressure, in a reaction

involving gases.
c) what general conclusion was reached.
iii) increasing the surface area of a solid reactant.
® Answer Section
Worksheet 1 Worksheet 2 (cont)

1. 3.
a) sulfur + oxygen sulfur dioxide a) hydrogen + zinc sulfate
b) S(s) + O2(g) SO2(g) Zn + H2SO4 H2 + ZnSO4
a) sulfur dioxide + oxygen sulfur trioxide b) hydrogen + calcium chloride

b) 2SO2(g) + 3O2(g) 2SO3(g) Ca + 2HCl H2 + CaCl2
a) sulfur trioxide + water hydrogen sulfate c) Barium + nitric acid

b) SO3(g) + H2O(l) H2SO4(aq) Ba + 2HNO3 H2 + Ba(NO3)2
2. d) Iron + hydrochloric acid

a) iron(III) carbonate iron(III) oxide + carbon Fe + 2HCl H2 + FeCl2
dioxide
b) Fe2(CO3)3(s) Fe2O3(s) + 3CO2(g)
Worksheet 3
3. 1. OX: Mg(s) Mg2+(aq) + 2e-
a) iron(III) oxide + carbon iron + carbon RED: Pb2+(aq) + 2e- Pb(s)
dioxide
b) 2Fe2O3(s) + 3C(s) 4Fe(l) + 3CO2(g) Mg(s) + Pb2+(aq) Mg2+(aq) + Pb(s)
4. 2. no reaction
a) butane + oxygen water + carbon dioxide
b) 2C4H10(g) + 13O2(g) 10H2O(g) + 8CO2(g) 3. OX: Al(s) Al3+(aq) + 3e-
RED: Cu2+(aq) + 2e- Cu(s)
5.
a) potassium + barium barium + potassium 2Al(s) + 3Cu2+(aq) 2Al2+(aq) + 3Cu(s)
sulfide nitrate sulfide nitrate
b) K2S(aq) + Ba(NO3)2(aq) BaS(s) + 2KNO3(aq) 4. OX: Cu(s) Cu2+(aq) + 2e-
RED: Ag+(aq) + e- Ag(s)
6.
a) nitric + calcium water + calcium Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s)
acid hydroxide nitrate
b) 2HNO3(aq) + Ca(OH)2(aq) 2H2O(l) Ca(NO3)2(aq) 5. no reaction
7. 6. OX: Ca(s) Ca2+(aq) + 2e-

a) sulfuric + lithium carbon + water + lithium RED: Sn2+(aq) + 2e- Sn(s)
acid carbonate dioxide sulfate
b) H2SO4(aq)+ Li2CO3(s) CO2(g) + H2O(l) + Li2SO4(aq) Ca(s) + Sn2+(aq) Ca2+(aq) + Sn(s)
8.
a) nitrogen + hydrogen ammonia Worksheet 4
b) N2(g) + 3H2(g) 2NH3(g)
a) oxide b) hydrogen
9. c) metal oxide d) hydrogen
a) sodium + oxygen sodium + sulfur e) salt
sulfide oxide dioxide f) different g) activity
b) Na2S(s) + O2(g) Na2O(s) + SO2(g) h) potassium and sodium i) left
j) copper and gold k) iron and tin/lead/zinc
l) slowly m) electrons
Worksheet 2 n) lose o) hydrogen
1. p) covalent q) hydrogen
a) Pb + O2 PbO2 r) H2 s) loss of electrons
t) reduction u) oxidized
b) 2Fe + 3O2 2Fe2O3 v) hydrogen w) reduced
x) ionisation y) remove one electron
c) 4Li + O2 2Li2O z) gas aa) low
ab) higher
2.
a) calcium + water hydrogen + calcium
hydroxide
Ca + 2H2O H2 + Ca(OH)2
b) Tin + water hydrogen + tin(II) oxide

Sn + H2O H2 + SnO
® Answer Section
Worksheet 7
Worksheet 5 a) Activity b) ions
c) higher up d) displace
1. C 2. A 3. B e) lose f) oxidation
g) gain h) reduction
4. (example answer) i) oxidation-reduction j) Redox
Small pieces of metal were added to dilute acid in test k) electrons l) oxidation
tubes. (To keep expt. fair, the acid must be same m) reduction n) cells & batteries
strength, and metal pieces same size.) o) half-cells p) anode
Observe the rate of gas production to assess reactivity. q) cathode r) electrons
Conclusion: order of activity: Mg > Zn > Fe > Pb > Cu s) anode t) cathode
u) Salt v) ions
5. w) electric charge x) EMF
a) Mg + 2HCl H2 + MgCl2 y) Standard Electrode z) standard
aa) hydrogen ions hydrogen gas
b) Ca + 2H2O H2 + Ca(OH)2 ab) zero ac) higher up
ad) oxidation ae) reversed in sign
c) 4K + O2 2K2O af) add ag) voltage/ EMF
ah) positive ai) spontaneously
6.
Ba Ba2+ + 2e-
2H+ + 2e- H2
(Barium lost, hydrogen ions gained)
Worksheet 8
1. Eo
a) Anode: Mg(s) 2+
Mg (aq) + 2e - +2.36 V
7.
a) Mg(g) Mg+(g) + e- Cathode: Cu2+(aq) + 2e- Cu(s) +0.34 V
b) +2.36 + 0.34 = 2.70 V
b) The lower the ist Ionisation Energy the more active c) Mg(s) + Cu2+(aq) Mg2+(aq) + Cu(s)
the metal, because the metal readily loses electron(s) to
enter a reaction.
2.
a) Anode: Mg(s) Mg2+(aq) + 2e- +2.36 V
Worksheet 6 2+
Cathode: Fe (aq) + 2e- Fe(s) - 0.44 V
1. b) +2.36 -0.44 = 1.92 V
a) OX: Mg Mg2+ + 2e- c) Mg(s) + Fe2+(aq) Mg2+(aq) + Fe(s)
RED: Cu + 2e-
2+ Cu
b)
3.
OX: Zn Zn2+ + 2e-
RED: I2 + 2e- 2I- a) Anode: Ca(s) Ca2+(aq) + 2e- +2.87 V
2+
Cathode: Cu (aq) + 2e- Cu(s) +0.34 V
c)
OX: Ca Ca2+ + 2e- b) +2.87 + 0.34 = 3.21 V
RED: 2H + 2e-
+ H2 c) Ca(s) + Cu2+(aq) Ca2+(aq) + Cu(s)
d)
OX: Al Al3+ + 3e-
RED: Br2 + 2e- 2Br- 4.
e) a) Anode: Zn(s) Zn2+(aq) + 2e- +0.76 V
OX: Fe Fe2+ + 2e- Cathode: 2H+(aq) + 2e- H2(g) +0.00 V
RED: 2H + 2e-
+ H2 b) +0.76 + 0.00 = 0.76 V
c) Zn(s) + 2H+(aq) Zn2+(aq) + H2(g)
2.
Oxidation is the loss of electrons. Reduction is the gain
of electrons. Both processes must occur together, with 5.
electrons being transferred from one species to the a) Anode: H2(g) 2H+(aq) + 2e- +0.00 V
other. Cathode: Cl2(aq) + 2e- 2Cl-(aq) +1.40 V
b) +0.76 + 0.00 = 1.40 V
3.
c) H2(g) + Cl2(aq) 2H+(aq) + 2Cl-(aq)
a) Zn(s) + 2Fe3+(aq) Zn2+(aq) + 2Fe2+(aq)
b) O2(g) + 4H+(aq) + 2Mg(s) 2H2O(l) + 2Mg2+(aq) 6.

a) Anode: 2I-(aq) I2(aq) + 2e- -0.62 V
Cathode: O2(g) + 4H (aq) + 4e-
+ 2H2O(l) +1.40 V
b) +1.40 - 0.62 = 0.78 V
c) 4I-(aq)+ O2(g) + 4H+(aq) 2I2(aq) + 2H2O(l)
®
Answer Section
Worksheet 9 Worksheet 11
1. A 2. C 3. C 4. A 1. D 2. B 3. A
5. 4.
a) Mg(s) + Pb2+ Mg2+ + Pb(s) Effect of temperature.
(aq) (aq) a) Method outline:
b) Oxidation: Mg(s) Mg2+(aq) + 2e- • set up 3 identical test tubes of acid; one in an ice bath,
Reduction: Pb2+(aq) + 2e- Pb(s) one at room temp., one in hot water bath.
c) • Identical pieces of magnesium were dropped into each,
in turn.
e- V b) The time taken for the Mg to disappear was measured.
d) Cell EMF The faster the reaction, the shorter this time was.
Mg Salt bridge Pb
= +2.36 -0.13 c) Reaction rate increases at higher temperatures.
= 2.23 V
5.
a) It is a catalyst in that it is involved in a series of
reactions, but it is “regenerated” at the end, and can be
used over and over. It is not consumed or permanently
changed by the reactions.
Mg2+ Pb2+ b) The catalyst provides an alternative chemical pathway
to achieve the same overall reaction. The alternative
ANODE CATHODE pathway has a lower activation energy, so the reaction
6. occurs at a higher rate.
a) Cu(s) + Cl2(aq) 2Cl-(aq) + Cu2+(aq)
b) 0 0 -1 +2 6.
Oxidation numbers below each species. a) The theory proposes that for any chemical reaction to
Copper has been oxidized, chloride ions reduced. occur, the reactants must firstly collide with sufficient
c) Eo energy to begin the reaction. It follows that reaction rates
Cu(s) Cu2+(aq)+ 2e- -0.34 V will be affected by anything which changes the
Cl2(aq) + 2e- 2Cl-(aq) +1.40 V probability of collisions and/or the energy involved.
Cell EMF = 1.06 V
b) i) Reduce reaction rate, because at lower temperature
7. the reactant particles will move more slowly, collide less
often & have less energy.
a) 2I-(aq) I2(aq) + 2e-
b) O2(g) + 4H (aq) + 4e-
+ 2H2O(l) ii) Increase reaction rate, because higher pressure forces
c) 4I-(aq)+ O2(g) + 4H+(aq) 2I2(aq) + 2H2O(l) the molecules closer together and increases the
d) +1.40 - 0.62 = 0.78 V frequency of collisions.
Worksheet 10 iii) Increase the reaction rate, because solid reactants

only come in contact with the other reactants (collisions!)
a) colliding b) a large piece of wood at their surface. Greater surface area allows more
c) oxygen d) ignition collisions to occur per unit of time.
e) fuel & oxygen f) explosion
g) dust h) safety
i) wheat, cotton, coal j) Kinetic
k) moving l) move faster
m) kinetic energy n) proceed faster
o) faster p) collision
q) activation r) concentration
s) collisions t) pressure
u) surface area
v) breaking it into smaller/finer particles
w) increases
x) being consumed or changed
y) enzymes z) activation energy
aa) energy ab) reaction rate
ac) adsorbing ad) likely/frequent
ae) strain af) broken
ag) iron ah) zeolite
ai) Catalytic aj) alternative chemical
ak) regenerated

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KISS Resources for NSW Syllabuses & Australian Curriculum

® KEEP IT SIMPLE SCIENCE

Next, the sulfur dioxide is reacted with more oxygen

Finally, the sulfur trioxide is reacted with liquid a)

® Worksheet 2 Metal Reactions

b) Calcium + Hydrochloric ................. +.................

2. Write a word equation AND a balanced, symbol

Worksheet 3 Metal Displacement Reactions

a) write half-equations for the change occurring to

1. Magnesium metal placed in a solution of

5. Iron metal placed in a solution of Ba2+ ions.

® Worksheet 4 Activity Series

Worksheet 5 Test-Style Questions

Longer Response Questions

b) I2(aq) + Zn(s) ZnI2(aq)

d) 3Br2(aq) + 2Al(s) 2AlBr3(aq) b) O2(g) + 4H+(aq) + 4e- 2H2O(l)

Worksheet 7 REDOX & Galvanic Cells

® Worksheet 8 Galvanic Cells

c) Write an overall, balanced, net ionic equation for

5. The same H+/H2 half cell is connected to one

2. One half cell comprises an iron electrode in a

6. (C) I-(aq)|I2 || O2, H+|H2O (C)

® Worksheet 9 Test-Style Questions Section 3

Longer Response Questions

a) Write the anode half-equation.

c) Write the balanced, net equation. (no spectators)

d) Determine the cell EMF (under standard conditions)

® Worksheet 10 Rate of Reaction

® Worksheet 11 Test-Style Questions, section 4

3. a) In what sense can the chlorine atom (Cl(g)) be

b) What effect on reaction rate would each of the

ii) increasing the gas pressure, in a reaction

c) what general conclusion was reached.

iii) increasing the surface area of a solid reactant.

Worksheet 1 Worksheet 2 (cont)

a) sulfur dioxide + oxygen sulfur trioxide b) hydrogen + calcium chloride

a) sulfur trioxide + water hydrogen sulfate c) Barium + nitric acid

2. d) Iron + hydrochloric acid

7. 6. OX: Ca(s) Ca2+(aq) + 2e-

b) Tin + water hydrogen + tin(II) oxide

b) O2(g) + 4H+(aq) + 2Mg(s) 2H2O(l) + 2Mg2+(aq) 6.

Worksheet 10 iii) Increase the reaction rate, because solid reactants

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