Gen Chem

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1. An ideal gas can be liquefied, because a. enthalpy b.

Gibb’s energy

a. its molecular size is very small. c. Internal energy d. entropy


b. its critical temp. is more than 0℃.
c. forces operative between its molecules are negligible. 9. Atomic ______ of an element is a whole number.
d. it gets solidified directly without becoming liquid.
a. volume b. number
2. Gases diffuse faster compared to liquids because of the c. weight d. radius
reason that the liquid molecules
10. The change in energy when an electron is accepted by
a. are held together by stronger intermolecular bonds. a gaseous atom to form an anion.
b. move faster.
c. have no definite shape. a. activation energy b. electronegativity
d. are heavier.
c. electron affinity d. ionization energy
3. Which of the ff. is not a colligative property?
11. Which of the ff. molecules/compounds is formed by
a. Osmotic pressure b. Depression of freezing pt. covalent bonds?

c. Lowering of vapor pressure d. none a. ZnS b. LiF

c. MgO d. BeCl2

4. The vapor pressure of liquids (similar nature) at any 12. Avogadro’s number is the number of molecules in one
specified temperature _______ with increasing molecular _______ of a gas.
weight.
a. kilogram b. litre
a. decreases
b. increases c. gm. Mole d. gram
c. unchanged 13. The quantity of heat required to evaporate 1 kg of a
d. increases linearly
saturated liquid is called
5. Mass number of an atom is the sum of the numbers of a a. latent heat b. sensible heat
a. protons and electrons c. specific heat d. 1 kcal
b. neutrons and electrons
c. neutrons and protons 14. A vapor whose partial pressure is less than its
d. both b and c equilibrium vapor pressure is called the _______ vapor.

6. In osmosis through a semi – permeable membrane, a. superheated b. dry gaseous


diffusion of the
c. saturated d. superheated
a. solvent is from high concentration to low concentration
b. solvent is from low concentration to high concentration 15. At higher temperatures, molal heat capacities for most
c. solute takes place of the gases (at const. pressure) _______ with increase in
c. none temperature.

a. increases b. decreases
7. Real gases approach ideal behavior at
c. varies linearly d. does not vary
a. high pressure & high temperature
16. Normality of a solution does not change with the
b. high pressure & low temperature
c. low pressure & high temperature increase in the
d. low pressure & low temperature a. temperature b. solute concentration
8. During a phase change process like sublimation, c. pressure d. dilution of the solution
vaporization, melting, etc., the specific _______ does not
change.
17. A reaction with a calculated yield of 9.23 g produced 23. For the balanced equation shown below, if the
7.89 g of product. What is the percent yield for this reaction of 20.7 grams of CaCO3 produces 6.81 grams of
reaction? CaO, what is the percent yield?

a. 85.5 % b. 90.5% c. 80% d.95% CaCO3=>CaO+CO2

18. 5.96 g of ammonia react completely according to the a. 58.7% b.58.9% c. 60% d.68.9%
following reaction:
24. For the balanced equation shown below, if the
NH3(g) + CO2(g) CN2OH4(s) + H2O(I) reaction of 91.3 grams of C3H6 produces a 81.3% yield,
how many grams of CO2 would be produced?
What is the theoretical yield of urea (CN2OH4) for this C3H6+O2=>CO2+H2O
reaction?
a. 230 g b. 232 g c. 233 g d. 244 g
a. 11 g b. 12.5 g c. 11.5 g d. 10.5 g
25. For the balanced equation shown below, if the
19. 9.87 g of ammonia react completely according to the reaction of 0.112 grams of H2 produces 0.745 grams of
following reaction: H2O, what is the percent yield?
NH3(g) + CO2(g) CN2OH4(s) + H2O(I) Fe3O4+H2=>Fe+H2O
If 13.74 g of urea (CN2OH4 ) are produced, what is the a. 60% b.80% c.74% d.76%
percent yield for this reaction?
26. For the balanced equation shown below, if the
a. 76 % b. 77% c. 78% d. 79% reaction of 77.0 grams of CaCN2 produces 27.1 grams of
20. 85.4 g of chlorine (70.91 g/mol) reacts completely NH3, what is the percent yield?
according to the following reaction: CaCN2+H2O=>CaCO3+NH3
P4(s) + Cl2(g) PCl3(I) a. 81% b. 82% c. 83% d. 84%
If 104 g of phosphorus trichloride is produced, what is
27. Determine the [OH-] concentrations of a solution that
the percent yield for this reaction?
has a pH = 7.40.
a. 90.5 % b. 91.5% c.94.5% d. 95.5%
a. 2.51x10-7 M b. 2.81x10-8 M
21. 15.4 g of methanol (CH3OH) reacts completely
c. 2.51x10-9 M d. 2.81x10-7 M
according to the following reaction:

CH3OH (g) CH2O (g) + H2 (g)


28. Determine the pH of aqueous solutions having the
If 12.35 g of formaldehyde is produced, what is the
following ion concentrations: [OH-] = 1.00 x 1O-6M
percent yield for this reaction?
a. 5 b. 6 c. 7 d. 8
a. 80% b.85% c.90% d. 95%
29. Determine the pH of solutions having the following
22. For the balanced equation shown below, if the
H+ ion concentrations: [H+] = 1.00 x 1O-2M
reaction of 40.8 grams of C6H6O3 produces a 39.0%
a. 2 b. 4 c. 6 d. 8
yield, how many grams of H2O would be produced?

C6H6O3 + O2 => CO2 + H2O

a. 7.83 g b. 6.83 g c. 5.83 g d. 8.63g


30. A lab technician determines the boiling point elevation
of an aqueous solution of a nonvolatile, nonelectrolyte to
be 1.12°C. Determine the solution's molality. 39. Acetylene gas, C2H2, is used in welding, produces an
extremely hot flame when it burns in pure oxygen
a. 3.19 m b. 2.19 m c. 1.19 m d. 4.19 m according to the following reaction.

31. Determine the freezing point of a O.029m aqueous C2H2(g) + O2(g)  CO2(g) + H2O(g)
solution of sodium chloride (NaCl).
How many moles of water (H2O) are produced when
NaCI(s) – Na+ (aq) + CI- (aq) 25.0 grams of C2H2 burns completely?

a. -0.11 b. 0.11 c. 0.20 d. -0.20 a. 0.96 b. 0.90 c. 0.86 d.0.80

32. Determine the new boiling point of a 2.75m solution 40. Laughing gas (nitrous oxide, N2O) is sometimes used
of NaOH in water. as an anesthetic in dentistry.

a. 102.8 b. 122 c. 132.8 d. 112.8

33. Determine the molarity of a dilute solution made by NH4NO3(s)  N2O(g) + H2O(l)
starting with 20.0 mL of a 3.50M stock solution and
diluting it to 100.0 mL. How many moles of NH4NO3 are required to produce
33.0g of N2O?
a. 0.80 b. 0.90 c.0.70 d. 0.50
a. 0.849 g b. 0.749g c. 0.549 g d. 0.649g
34. Determine the volume, in mL, of a 3.00M KI stock
solution needed to make 0.300 L of a 1.25M KI solution.

a. 135 b. 115 c. 145 d. 125

35. A bleach solution of NaOCI has a concentration


ofO.128M. Determine the mass of NaOCI in the solution if
its volume is 1.00 L.

a. 9.53 g b. 9.63 g c. 10.70 g d. 10.53 g

36. What is the percent by mass ofNaHC03 in a solution


containing 20.0g NaHC03 dissolved in 600.0 mL of water?

a. 4.22% b. 3.22% c. 8.22% d. 5.22%

37.

Mg(s) + 2HCl(aq)  MgCl2(aq) + H2(g)

What is the mass in grams of H2 gas when 4.0 moles of


HCl is added to the reaction?

a. 2 g b. 4 g c. 6g d. 8g

38. Acetylene gas (C2H2) is produced as a result of the


following reaction.

CaC2(s) + 2H2O(l)  C2H2(g) + Ca(OH)2(aq)

If 3.20 moles of CaC2 are consumed in this reaction, how


many grams of H2O are needed?

a. 111 g b. 113 g c. 114 g d. 115g

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