Ex Orbe Medicvs OrbeNMAT 2022

1. The density of water is 1.0 g/cm3 . Which of shown above. What is the value of △HC
the following substances will float in water? given the information in equations A and B?
a. Density of gold = 19.3 g/cm3 a. -57.1 kJ
b. Density of silver = 10.5 g/cm3 b. -90.3 kJ
c. Density of milk = 1.0 g/cm3 c. -223.7 kJ
d. Density of ice = 0.92 g/cm3 d. -373.3 kJ

2. When a paper is crumpled, what physical 7. Using the valence-shell electron-pair repulsion
property is altered? theory, which of the following diagrams
a. Density represents the molecular shape of carbon
b. Shape dioxide?
c. Mass
d. State

3. Hikers light a campfire at night to keep

themselves warm. Lighting the campfire is an
______.
a. exothermic reaction which absorbs heat
b. exothermic reaction which releases heat
c. endothermic reaction which absorbs heat
d. endothermic reaction which releases heat

4. The molecular formula of caffeine is

C8H10N4O2 . What is its empirical formula? (H
= 1 g/mol, O = 16 g/mol, C = 12 g/mol, N = 14
g/mol)
a. CHNO B
b. C2H2N2O2
c. C4H5N2O 8. Which of the following is NOT true of Group II
d. C16H20N804 elements: Be, Mg, Ca, Sr, Ba, and Ra?
a. Be is the most active metal among them.
5. Which of the following represents a chemical b. Ra has the lowest ionization potential.
change? c. Ca is bigger than Mg.
a. Boiling water to form steam d. They have relatively low
b. Heating lead until it melts electronegativities.
c. Burning a piece of wood
d. Breaking of glass 9. The solubility of KClO3 at 60°C is 25 g per 100
g of water. If at 60°C, 15 g of the salt is
6. dissolved in 50 g of water, then the solution
A: CO(g) + ½ O2(g) → CO2(g) △HA = -283 kJ must be _____.
B: N2(g) + O2(g) → 2NO(g) △HB = 180.6 kJ a. unsaturated
C: CO2(g) + NO(g) → CO2(g) + ½ N2(g) △HC = ? b. saturated
c. supersaturated
Two gaseous pollutants that form in auto d. diluted and unsaturated
exhaust are CO and NO. An environmental
chemist is studying ways to convert them to 10. A volume of 1.1 liters of O2 was collected
less harmful gases through equation C inside a balloon at 295 K and 13.6 psi. The
next day, the surrounding conditions were
 Ex Orbe Medicvs OrbeNMAT 2022

observed to be 32°C and 0.98 atm. What is Which statement concerning this solution is
the volume of the gas inside the balloon? (1 FALSE?
atm = 14.7 psi) a. The solution is considered supersaturated
a. 0.107 liters since no additional orange powder will
b. 1.070 liters dissolve.
c. 10.7 liters b. The solution is considered saturated since
d. 107.0 liters not all of the orange powder dissolved.
c. The solubility of the orange powder in
11. water has been exceeded.
d. In order to get the additional orange
Element Electronegativity
powder to dissolve, the student can add
K 0.8 more water.
Cl 3.0
H 2.1 15.
O 3.5 2H2 + O2 → 2H2O
C 2.5
N 3.0
The reaction of hydrogen and oxygen gas to
produce water is shown above. Suppose 10.0
Based on the table shown above, in which of grams of hydrogen are mixed with 32.0 grams
the following compounds is the bonding ionic? of oxygen, what is the limiting reagent and
a. KCl how many excess grams of the other is left at
b. NH3 the end of the reaction? (Molar masses: H2 -
c. CH4 2.0 g/mol; O2 = 32.0 g/mol)
d. H2O
a. Limiting reagent = hydrogen;
12. Fifty-four grams of a certain metal at 98°C Excess = 16.0 grams of oxygen
was placed in 80 mL of water at 297 K. b. Limiting reagent = hydrogen;
Assuming no heat is lost to the surroundings, Excess = 2.0 grams of oxygen
what is the temperature of the water and the c. Limiting reagent = oxygen;
metal? (Specific heat of the metal = 0.085 Excess = 6.0 grams of oxygen
cal/g*C°) d. Limiting reagent = oxygen;
a. 280°C Excess = 8.0 grams of oxygen
b. 35°C
c. 28°C 16. Which of the following groups of compounds
d. 25°C are arranged from the strongest to weakest
intermolecular force?
13. What is the molecular weight of an unknown a. F2 → HCl → H2O2
gas if 200 mL of this gas diffuses through an b. F2 → H2O2 → HCl
apparatus in 180 seconds while 250 mL of c. HCl → F2 → H2O2
NO2 under the same conditions diffuses d. H2O2 → HCl → F2
through the same apparatus in 170 seconds?
a. 8.97 g/mole 17.
b. 60.88 g/mole
c. 80.52 g/mole
d. 805.20 g/mole
What type of nuclear reaction is shown above?
14. A student mixes three tablespoons of orane a. Nuclear fusion
powder in a glass of water at room b. Nuclear fission
temperature, and observes that much, but not c. Neutron emission
all, of the orange powder has dissolved. d. Scintillation
 Ex Orbe Medicvs OrbeNMAT 2022

18. Which of the following states that no two Given the above quantum numbers, what is
electrons in an atom can have the same set of the maximum number of electrons in the
quantum numbers? atom?
a. Hund’s rule a. 1
b. Madelung’s rule b. 3
c. Pauli exclusion principle c. 10
d. Heisenberg uncertainty principle d. 14

19. In which of the following sets of conditions will 25. When a chemist pours hot water with coffee
a real gas behave like an ideal gas? extract in an ice bath, some of the coffee
a. Low pressure, low temperature crystallizes. What kind of solution is formed?
b. High pressure, low temperature a. Unsaturated
c. Low pressure, high temperature b. Saturated
d. High pressure, high temperature c. Supersaturated
d. Diluted
20. A person has 6.0 qt of blood containing 95 mg
of glucose per 100 mL. How much glucose is 26.
there in this person’s total blood supply?
a. 5400 g
b. 5.4 g
c. 540 g
d. 570 g An aqueous solution of NH3 is in equilibrium.
Suppose a gram of NH4Cl is added to the
21. How many pi electrons are there in solution, and it is allowed to come to a new
naphthalene? equilibrium as shown above. What will happen
a. 9 to the pH as a result of the addition of NH4CL?
b. 10 a. It will go up.
c. 11 b. It will go down.
d. 14 c. It will not be affected.
d. It cannot be determined.
22. Which of the following correctly lists the five
atoms in order of increasing atomic size? 27. In a gravimetric analysis, the substance
(Atomic numbers: F = 9, K = 19, Ge = 32, Br = weighed is PbO2. If the substance sought is
35, Rb = 37) Pb3O4, which is the correct gravimetric factor?
a. F, K, Ge, Br, Rb a. 3PbO2/Pb3O4
b. F, Ge, Br, K, Rb b. Pb3O4/3PbO2
c. F, Br, Ge, K, Rb c. 2PbO2/Pb3O4
d. F, K, Br, Ge, Rb d. Pb3O4/2PbO2

23. If 8.0 moles of potassium superoxide reacts 28.

with 5.0 moles of water, how many moles will
remain unreacted? H2SO4(aq) + 2NaOH(aq) → 2H2O(l) + Na2SO2(aq)
a. 1.0 mole KO2
b. 3.0 moles KO2 Titration reveals that 8.33 mL of 3 M sulfuric
c. 1.0 mole H2O acid is required to neutralize the sodium
d. 3.0 moles H2O hydroxide in 25 mL of NaOH solution as
shown in the chemical reaction above. What
24. is the molarity of the NaOH solution?
a. 2.5 M
b. 2.0 M
c. 1.5 M
 Ex Orbe Medicvs OrbeNMAT 2022

d. 1.0 M A colorless hydrogen gas is mixed with purple

iodine vapor in a sealed flask. The chemical
29. Which of the following types of titration is best reaction produced a colorless hydrogen iodide
used in determining the total hardness of as shown in the equation above, What can be
water? done to temperature, concentration, and
a. Complexometric titration pressure of any of the chemicals in the
b. Zeta potential titration mixture to increase the formation of purple
c. Acid-base titration vapor?
d. Redox titration a. Decrease temperature and H2
concentration, same pressure
30. Which of the following pairs of compounds b. Decrease temperature and I2
can act as a buffer solution? concentration, same pressure
I. HF and NaF c. Increase temperature and I2
II. HNO3 and KNO3 concentration, decrease pressure
III. NH3 and NH4Cl d. Increase the temperature, HI
a. II only concentration, and pressure
b. I and II only
c. I and III only 34. Which of the following equations shows that
d. I, II, and III water is acting as a conjugate base?
a. NH3 + H2O ⇌ NH4+ + OH-
31. A high school laboratory’s waste container is b. H2SO4 + H2O ⇌ H3O+ + HSO4-
used to dispose of aqueous solutions of c. H2PO4- + H3O+ ⇌ H3PO4 + H2O
sodium nitrate, potassium sulfate, d. H2PO4- + OH- ⇌ HPO42- + H2O
hydrochloric acid, and tin (II) chloride. Which
of the following equations represents the most 35. In a reaction between copper metal and
likely net redox reaction predicted to occur aqueous iron (III) chloride, Fe3+ is reduced to
inside the waste container? Fe2+ while Cu is oxidized to Cu2+. What is the
a. Sn2+(aq) + 2NO-3(aq) + 4H+(aq) → 2NO(g) mass of Cu required to react with 50 mL of 1
+ 2H2O(l) + Sn4+(aq) mol/L FeCl 3?
b. So2-4(aq) + 4H+(aq) + 2Cl-(aq) → a. 0.5 grams
H2SO3(aq) + H2O(l)+Cl2(g) b. 1.6 grams
c. 2H+(aq) + 2K+(aq) → H2(g) + K(s) c. 2.1 grams
d. Cl2(g) + Sn2+(aq) → Cl-(aq) + Sn(s) d. 3.2 grams

32. 36.
2NaI + Pb(NO3)2 → PbI2 + 2NaNO3 Co(H2O)63+(aq) + 6NH3(aq) → Co(NH3)63+(aq) +
6H2O(l)
If 4.61 grams of PbI2 was isolated from the
reaction of Pb(NO3)2 and NaI, what will be the Which of the following is the Lewis acid and acts
calculated amount of Nal that reacted with as a reactant in the equation shown above?
PbI2? (Molar mass: PbI2 = 330 grams/mol; NaI a. Co3+
= 150 grams/mol) b. H2O
a. 1.50 grams c. NH3
b. 3.00 grams d. Co(H2O)63+
c. 4.61 grams
d. 9.22 grams 37. Which of the following is a primary alcohol?
a. 2-Propanol
33. b. 3-Bromo-2-pentanol
H2(g) + I2(g) ⇌ 2HI(g) △H = +52kJ c. Ethanol
d. 4-Ethyl-3-hexanol
 Ex Orbe Medicvs OrbeNMAT 2022

38. Using a catalyst, two gaseous hydrocarbons,

X and Y, were produced from heating hexane,
C6H14. The gases were individually tested with
aqueous bromine. For X, aqueous bromine
became colorless, while for Y, the
reddish-brown color of aqueous bromine was
retained. Which of the following best
describes the identity of the two
hydrocarbons?
a. X = alkane, Y = alkene
b. X = alkene, Y = alkane What is the classification of the carbon
c. Both X and Y contain the same number of atom that is bonded to the -OH group in
carbon atoms. methanol as shown above?
d. Both X and Y contain the same number of a. Primary
hydrogen atoms. b. Secondary
c. Tertiary
39. d. Quaternary
C5H12 + Br2 → C5H11Br + HBr
42. Which of the following properties of
What is the hybridization between carbon and hydrocarbons increase(s) as the number of
hydrogen in the organic compound molecule of carbon atoms in the hydrocarbon chain
the product of the reaction shown above? increases?
a. sp I. Density
b. sp2 II. Boiling point
c. sp3 III. Melting point
d. sp3d a. I only
b. II only
40. Which of the following statements are true c. III only
about electrophilic aromatic substitution d. I, II, and III
reactions?
I. It is the most common reaction of 43.
aromatic compounds.
II. It uses both addition-elimination and
elimination-addition mechanisms.
III. It occurs when an electrophilic reagent
reacts with a nucleophilic aromatic ring.
IV. It occurs when a nucleophilic reagent
reacts with an electrophilic aromatic ring.
a. I and II only How many sp2 hybridized carbon(s) is(are)
b. I and III only present in the compound shown above?
c. II and III only a. 1
d. II and IV only b. 2
c. 3
41. d. none

44.
 Ex Orbe Medicvs OrbeNMAT 2022

I. Using iron, potassium, and aluminum to

catalyze the reaction of hydrogen with
nitrogen to yield ammonia at 500 degC
II. Using hydrochloric acid in catalyzing the
reaction of ethyl acetate with water to
form acetic acid
What is the name of the benzene III. Using platinum to catalyze the reaction
derivative shown above? of carbon monoxide with oxygen to form
a. Styrene carbon dioxide
b. Toluene
c. Ethylbenzene a. I only
d. Benzaldehyde b. II only
c. I and III only
45. d. II and III only

49. Which of the following characteristics is

common to all lipids?
a. They contain long chains of C-H bonds.
b. They have a glycerol backbone.
c. They are insoluble in water.
d. All of these

50.
The molecular structures of three aromatic I. Silk fibroin extracted from silkworms
compounds labeled X, Y, and Z, are shown in II. Keratin in hair, feathers, and nails
the diagram above. Which of the following III. Collagen in tendons and bone matrix
shows the increasing order of acidity of the Which above structure of protein is present in the
substances X, Y, and Z? above fibrous materials?
a. Y < X < Z A. Primary
b. Y < Z < X B. Secondary
c. X < Z < Y C. Tertiary
d. Z < X < Y D. Quaternary

46. How many hybrid orbitals are present in a

water molecule?
a. 1
b. 2
c. 3
d. 4

47. Which of the following processes describes

the formation of glycogen from excess
glucose in the blood?
a. Ketogenesis
b. Lipogenesis
c. Glycogenesis
d. Gluconeogenesis

48. Which of the following scenarios will allow a

heterogenous catalysis to occur?