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    Solution Mix Tures

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    Tengku Ashraf
    The document presents results from experiments investigating the conversion of sodium hydroxide (NaOH) during a reaction with ethyl acetate. Calibration curves were prepared relating conductivity to NaOH concentration. Manual back titrations showed average NaOH consumption of 24.3 mL. Five experiments were conducted varying flow rates and calculating residence times and conversions. The calculations determine the NaOH concentration entering the reactor, unreacted HCl volume, moles of reacted HCl, concentration and conversion of NaOH in the reactor, and rate constant.

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    Solution Mix Tures

    Uploaded by

    Tengku Ashraf
    25 views6 pages
    The document presents results from experiments investigating the conversion of sodium hydroxide (NaOH) during a reaction with ethyl acetate. Calibration curves were prepared relating conductivity to NaOH concentration. Manual back titrations showed average NaOH consumption of 24.3 mL. Five experiments were conducted varying flow rates and calculating residence times and conversions. The calculations determine the NaOH concentration entering the reactor, unreacted HCl volume, moles of reacted HCl, concentration and conversion of NaOH in the reactor, and rate constant.

    Original Description:

    GG

    Original Title

    Results l3

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    The document presents results from experiments investigating the conversion of sodium hydroxide (NaOH) during a reaction with ethyl acetate. Calibration curves were prepared relating conductivity to NaOH concentration. Manual back titrations showed average NaOH consumption of 24.3 mL. Five experiments were conducted varying flow rates and calculating residence times and conversions. The calculations determine the NaOH concentration entering the reactor, unreacted HCl volume, moles of reacted HCl, concentration and conversion of NaOH in the reactor, and rate constant.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    25 views6 pages

    Solution Mix Tures

    Uploaded by

    Tengku Ashraf
    The document presents results from experiments investigating the conversion of sodium hydroxide (NaOH) during a reaction with ethyl acetate. Calibration curves were prepared relating conductivity to NaOH concentration. Manual back titrations showed average NaOH consumption of 24.3 mL. Five experiments were conducted varying flow rates and calculating residence times and conversions. The calculations determine the NaOH concentration entering the reactor, unreacted HCl volume, moles of reacted HCl, concentration and conversion of NaOH in the reactor, and rate constant.

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    of 6

    RESULTS

    Table 7.1: Preparation of calibration curves:

    Solution MixSolution Mixturestures Concentration Conductivity


    Conversion 0.1 M NaOH 0.1 M Et (Ac) H2O of NaOH (M) (mS/cm)
    0% 100 mL - 100 mL 0.0500 23.6000
    25 % 75 mL 25 mL 100 mL 0.0375 14.9000
    50 % 50 mL 50 mL 100 mL 0.0250 9.2100
    75 % 25 mL 75 mL 100 mL 0.0125 4.2000
    100 % - 100 mL 100 mL 0.0000 0.0654

    Graph 7 1: Conductivity versus conversion


    Table 7.2: Back titration for manual conversion determination

    Sample Vol. Of NaOH (mL)


    1 24.5
    2 22.6
    3 24.4
    4 24.7
    5 24.8

    Table 7.3: Table of experiment 1


     Reactor volume = 10 L
     Concentration of NaOH in feed vessel = 0.1 M
     Concentration of Et(Ac) in feed vessel = 0.1 M

    Total
    Flow Flow flow rate Exit
    Residence
    rate of rate of of Conductivity concentration Conversion
    No time, 𝜏
    NaOH Et(Ac) solutions, (mS/cm) of NaOH X (%)
    (min)
    (l/min) (l/min) F0 CNaOH (M)
    (ml/min)
    1 0.10 0.10 0.2 50.00 2.59 0.0010 98.0
    2 0.15 0.15 0.3 33.33 2.59 0.0018 96.4
    3 0.20 0.20 0.4 25.00 2.60 0.0012 97.6
    4 0.25 0.25 0.5 20.00 2.61 0.0006 98.8
    5 0.30 0.30 0.6 16.67 2.61 0.0004 99.2

    Graph 7.2: residence time versus convension.


    Calculations

    Volume of sample, Vs = 50 mL
    Concentration of NaOH in the feed vessel, CNaOH,f = 0.1 mol/L
    Volume of HCL for quenching, VHCl,s = 10 mL
    Concentration of HCl in standard solution, CHCls = 0.25 mol/L
    Volume of titrated NaOH, V1 = 28.5 mL
    Concentration of NaOH used for titration, CNaOHs = 0.1 mol/L

    F0 = 0.1+0.1 = 0.2 L/min

    Concentration of NaOH that entering the reactor, CNaOH0.


    1
    𝐶𝑁𝑎𝑂𝐻𝑜 = 𝐶
    2 𝑁𝑎𝑂𝐻𝑓
    1
    = (0.1)
    2
    𝑚𝑜𝑙
    = 0.05
    𝐿
    Volume of unreacted quenching HCl,V2
    𝑉2 = (𝐶𝑁𝑎𝑂𝐻𝑠 / 𝐶𝐻𝐶𝑙𝑠 ) 𝑥 𝑉1
    0.1
    = 𝑥 24.5
    0.25
    = 11.4𝑚𝐿
    Volume of HCl reacted with NaOH in sample, V3
    𝑉3 = 𝑉𝐻𝐶𝑙𝑠 – 𝑉2
    = 10 – 9.8
    = 0.2
    Moles of HCl reacted with NaOH in sample, n1
    (𝐶𝐻𝐶𝑙𝑠 𝑥 𝑉3 )
    𝑛1 =
    1000
    0.25 𝑥 0.2
    =
    1000
    = 0.00005 𝑚𝑜𝑙
    Moles of unreacted NaOH in sample, n2
    𝑛2 = 𝑛1
    = 0.00005 𝑚𝑜𝑙
    Concentration of unreacted NaOH in the reactor, CNaOH
    𝑛2
    𝐶𝑁𝑎𝑂𝐻 = 𝑥 1000
    𝑉𝑠
    0.00005
    = 𝑥 1000
    50
    = 0.001 mol/L
    Conversion of NaOH in the reactor, X
    𝐶𝑁𝑎𝑂𝐻
    𝑋 = (1 − ) 𝑥 100%
    𝐶𝑁𝑎𝑂𝐻𝑜
    0.001
    = (1 – ) 𝑥 100%
    0.05
    = 98.0 %
    Residence time, τ
    𝑉𝐶𝑆𝑇𝑅
    𝜏 =
    𝐹𝑜
    10
    =
    0.20
    = 50 𝑚𝑖𝑛
    Reaction rate constant, k
    ( 𝐶𝐴𝑜 – 𝐶𝐴)
    𝑘=
    𝜏𝐶𝐴 2
    = ( 0.05 – 0.001)
    (50 𝑥 0.0012 )
    = 980 𝑀−1 𝑚𝑖𝑛−1
    Rate of reaction, -rA

    −𝑟𝐴 = 𝑘𝐶𝐴 2
    = 980 𝑥 0.0062
    𝑚𝑜𝑙
    = 9.8 𝑥 10−4
    𝐿. 𝑚𝑖𝑛

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