Scribd Logo
Upload

Welcome to Scribd!

  • 76 views

    Lab 3 - CSTR 40L

    Uploaded by

    nur athilah
    The document presents the results of an experiment investigating the effect of residence time in a continuous stirred-tank reactor (CSTR). Tables show conductivity measurements at different solution mixtures and conversions at various residence times. Figures 1 and 2 plot the data, with Figure 1 showing a linear relationship between conductivity and conversion, and Figure 2 showing increasing conversion with decreasing residence time. Sample calculations are provided to determine rate constants and the rate of reaction based on experimental data collected at one residence time.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Lab 3 - CSTR 40L

    Uploaded by

    nur athilah
    76 views8 pages
    The document presents the results of an experiment investigating the effect of residence time in a continuous stirred-tank reactor (CSTR). Tables show conductivity measurements at different solution mixtures and conversions at various residence times. Figures 1 and 2 plot the data, with Figure 1 showing a linear relationship between conductivity and conversion, and Figure 2 showing increasing conversion with decreasing residence time. Sample calculations are provided to determine rate constants and the rate of reaction based on experimental data collected at one residence time.

    Original Description:

    lol

    Original Title

    LAB 3 - CSTR 40L

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document presents the results of an experiment investigating the effect of residence time in a continuous stirred-tank reactor (CSTR). Tables show conductivity measurements at different solution mixtures and conversions at various residence times. Figures 1 and 2 plot the data, with Figure 1 showing a linear relationship between conductivity and conversion, and Figure 2 showing increasing conversion with decreasing residence time. Sample calculations are provided to determine rate constants and the rate of reaction based on experimental data collected at one residence time.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    76 views8 pages

    Lab 3 - CSTR 40L

    Uploaded by

    nur athilah
    The document presents the results of an experiment investigating the effect of residence time in a continuous stirred-tank reactor (CSTR). Tables show conductivity measurements at different solution mixtures and conversions at various residence times. Figures 1 and 2 plot the data, with Figure 1 showing a linear relationship between conductivity and conversion, and Figure 2 showing increasing conversion with decreasing residence time. Sample calculations are provided to determine rate constants and the rate of reaction based on experimental data collected at one residence time.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 8

    7.

    0 RESULT

    Preparation of calibration curve.

    Table 1: Results of Conductivity in experiment.


    Conversion Solution Mixtures (mL) Concentration Conductivity
    (%) 0.1M NaOH 0.1M Et/Ac H2O NaOH(M) (mS/cm)
    0 100 - 100 0.0500 13.50
    25 75 25 100 0.0375 10.04
    50 50 50 100 0.0250 5.89
    75 25 75 100 0.0125 2.37
    100 - 100 100 0.0000 0.07

    16

    14

    y = -0.1381x + 13.28
    12
    R² = 0.9917
    10
    Conductivity (mS/cm)

    0
    0 20 40 60 80 100 120
    -2
    Conversion (%)

    Figure 1: Conductivity (mS/cm) against conversion (%)


    Effect of residence time of the reaction in CSTR

    Reactor volume = 10 L
    Concentration of NaOH in feed vessel = 0.1 M
    Concentration of Et(Ac) in feed vessel =0.1 M

    Table 2: Results of the Effect of Residence Time of the reaction in a CSTR.


    Temperature 27.7 28.1 28.3 28.5 28.6
    (oC)
    Flow rate NaOH 0.10 0.15 0.20 0.25 0.30
    (L/min)

    Flow rate Et (Ac) 0.10 0.15 0.20 0.25 0.30


    (L/min)

    Total flow rate of 0.20 0.30 0.40 0.50 0.60


    solution, F0 (L/min)

    Conductivity 2.86 2.83 2.82 2.80 2.79


    (s/cm)
    Volume of NaOH 29.7 29.8 30.0 32.0 30.2
    titrated, V1(mL)

    Residence Time, τ 50.00 33.33 25.00 20.00 16.67


    (min)

    Volume of unreacted 11.88 11.92 12.00 12.00 12.08


    quenching HCL,
    V2 (mL)
    Volume of HCL -1.88 -1.92 -2.00 -2.00 -2.08
    reacted with NaOH,
    V3 (mL)
    Conversion, X (%) 118.8 119.2 120.0 120.0 120.8
    Rate Constant, 13.44 19.4 24.0 30.0 33.50
    k (M-1s-1)
    Rate of reaction, -rA 0.00119 0.00179 0.00240 0.00300 0.00362
    (M/s)
    121

    120.5
    Conversion of NaOH (%)

    120

    119.5

    119

    118.5

    118
    0 10 20 30 40 50 60
    Residence Time, τ (min)

    Figure 2: Conversion of NaOH (%) vs Residence Time, τ (min)


    8.0 SAMPLE CALCULATION

    When both flow rate of solution is 0.10 L/min:

    Volume of sample, 50 mL Concentration of HCl in 0.25 mol/L


    Vs standard solution, CHCl,s
    Concentration of NaOH in 0.1 M Volume of NaOH 29.7 mL
    the feed vessel, CNaOH,f titrated, V1
    Volume of HCl for 10 mL Concentration of NaOH 0.1 mol/L
    quenching, VHCl,s used for titration, CNaOH,s

    Calculate:

    i. Concentration of NaOH entering the reactor, CNaOH,0

    CNaOH,0 = (1/2) CNaOH,s


    = (1/2) 0.1 mol/L
    = 0.05 mol/L

    ii. Volume of unreacted quenching HCl, V2

    V2 = (CNaOH,s / CHCl,s) × V1
    = (0.1/0.25) × 29.7
    = 11.88 mL

    iii. Volume of HCl reacted with NaOH in sample, V3

    V3 = VHCl,s – V2

    = 10 – 11.88

    = - 1.88 mL
    iv. Moles of HCl reacted with NaOH in sample, n1

    n1 = (CHCl,s × V3) / 1000

    = (0.25 × [-1.88])/1000

    = - 0.00047 mol

    Moles of unreacted NaOH in sample, n2= n1 = - 0.00047 mol

    v. Concentration of unreacted NaOH in the reactor, CNaOH

    CNaOH = n2/Vs × 1000

    −0.00047
    = × 1000
    50

    = - 0.0094

    vi. Conversion of NaOH in the reactor, X

    𝐶𝑁𝑎𝑂𝐻
    X = (1 - ) × 100%
    𝐶𝑁𝑎𝑂𝐻,0

    (−0.0094)
    = (1 - ) × 100%
    0.05
    = 118.8 %

    vii. Residence time, τ

    τ = VCSTR / F0

    = 10 L / (0.10 + 0.10) L/min

    = 50 min
    viii. Rate constant, k

    𝐶𝑁𝑎𝑂𝐻,0 − 𝐶
    𝑁𝑎𝑂𝐻
    k = 𝜏𝐶
    𝑁𝑎𝑂𝐻2

    0.05−(−0.0094)
    = 2
    50 (−0.0094)

    = 13.44 M-1s-1

    ix. Rate of reaction, -rA

    -rA = kCA2
    = 13.44 (- 0.0094)2
    = 0.00119
    13.0 APPENDIX
    SOLTEQ – QVF Continuous Stirred Tank
    50 mL sample was collected
    Reactor (CSTR) Model: BP143

    3 drops of phenolphthalein mix with sample. Titration process using 0.1M NaOH.

    Titration result

    You might also like