SP15 PDF

SPRING 2015
VOLUME LI
THE QUARTERLY JOURNAL OF THE GEMOLOGICAL INSTITUTE OF AMERICA
Vietnamese Blue Spinel

Chinese Tradition in Modern Jewelry Design
Moroccan Amethyst and Mozambique Ruby
2015 Tucson Gem Shows
Spring 2015
VOLUME 51, No. 1
EDITORIAL
1 Colored Gems, Chinese Jewelry Designers, and Colored Diamond Spectra
Duncan Pay
FEATURE ARTICLES
2 Blue Spinel from the Luc Yen District of Vietnam
Boris Chauviré, Benjamin Rondeau, Emmanuel Fritsch, Phillipe Ressigeac,
and Jean-Luc Devidal
pg. 3
Offers geological context and gemological characterization of this increasingly popular
vivid blue spinel from northeast Vietnam.
18 The Chinese Soul in Contemporary Jewelry Design

Andrew Lucas, Merilee Chapin, Moqing Lin, and Xiaodan Jia
Guided by their cultural heritage and powered by a rapidly growing domestic consumer
market, Chinese designers are exerting a powerful influence on the global stage.
pg. 20
NOTES AND NEW TECHNIQUES

32 Amethyst from Boudi, Morocco
Fabrizio Troilo, Abdelghani El Harfi, Salahaddine Mouaddib, Erica Bittarello,
and Emanuele Costa
An introduction to Moroccan amethyst, which features distinctive color zoning and
inclusions.
pg. 37
41 Visible Absorption Spectra of Colored Diamonds
James E. Shigley and Christopher M. Breeding
Features a foldout chart containing representative visible spectra and photos of the
major color categories of diamond.
FIELD REPORTS
44 Mozambique: A Ruby Discovery for the 21st Century
Merilee Chapin, Vincent Pardieu, and Andrew Lucas
Explores the geology, production, and yield of the world’s most important
pg. 86 commercially important ruby deposit.
REGULAR FEATURES
31 The Dr. Edward J. Gübelin Most Valuable Article Award
56 2015 Gems & Gemology Challenge
58 Lab Notes
Pink and reddish purple cobaltocalcite • Analysis of melee diamonds using FTIR spectroscopy • Irradiated color-
change diamonds • Diamond in diamond • Concerns over use of Tridacna shell in imitation pearls • Large natural
quahog pearl • HPHT synthetic melee in high-end jewelry piece • Large HPHT synthetic diamonds examined in
GIA’s Hong Kong lab • Synthetic moissanite melee in colored diamond bracelet
68 Gem News International

Tucson 2015: exceptional colored stones and gem artistry • New production of Brazilian copper-bearing tourmaline
and emerald • Oregon sunstone update • Pearl market updates • Conference reports • Amblygonite-montebrasite
carving • Moroccan amethyst • Dumortierite in rock crystal quartz • Jadeite with high albite • Moldavite study
• Iridescent scapolite • Composite quartz beads • CVD synthetic with unstable color centers • The Foldscope
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About the Cover

The lead article in this issue examines the geological and gemological characteristics of blue spinel from Luc Yen,
Vietnam. The centerpiece of the 18k yellow gold ring from the Love Doves collection is a 4.95 ct marquise-cut
spinel, framed on either side by doves with ruby eyes. Photo by Robert Weldon/GIA, courtesy of Loretta Castoro.
The gem-quality blue spinel octahedron associated with olivine in marble matrix was seen at a mine in the Luc
Yen district. Photo by Vincent Pardieu/GIA. Composite image by Kevin Schumacher.
Printing is by L+L Printers, Carlsbad, CA.
GIA World Headquarters The Robert Mouawad Campus 5345 Armada Drive Carlsbad, CA 92008 USA
© 2015 Gemological Institute of America All rights reserved. ISSN 0016-626X
Colored Gems, Chinese Jewelry Designers,
and Colored Diamond Spectra
Welcome to the first Gems & Gemology of 2015!
Spring is always an especially busy time, because our first issue comes hard on the heels of
the annual Tucson gem shows. This event always provides an illuminating window into the
world of colored gem supply and demand. Indeed, articles in this G&G provide a flavor of
that worldview, featuring Vietnamese blue spinel, Moroccan amethyst, ruby from
Mozambique, and a survey of contemporary Chinese jewelry designs featuring a wealth of
colored gemstones.
Our lead article, by French researcher Boris Chauviré and his coauthors, offers geological
context and a gemological characterization of the vivid blue spinel from Luc Yen, northern
Vietnam, which owes its remarkable color to traces of cobalt.
Next, GIA’s Andrew Lucas and Merilee Chapin partner with Chinese coauthors Moqing Lin and Xiaodan Jia
to survey the tremendous progress this country’s jewelry
designers have made in the last decade. Informed by “An illuminating window into the world
their civilization’s rich cultural roots and driven by the of colored gem supply and demand…”
power of a rapidly growing domestic consumer market,
the artistic prowess of Chinese designers is increasingly evident on the global stage.
Our third article, by a joint Moroccan-Italian team headed by lead author Fabrizio Troilo, provides an
introduction to amethysts from Boudi, Morocco. Their study outlines the geology, mining, and the internal
and external features of this attractive material.
Our fourth paper, by GIA’s Dr. Jim Shigley and Dr. Mike Breeding, bucks this issue’s colored-gem trend. Their
article provides a review of colored diamond spectra, including a foldout chart, which we trust many practicing
gemologists will find illuminating.
In addition, we’re delighted to present G&G’s third field report. GIA authors Merilee Chapin, Vincent
Pardieu, and Andrew Lucas report on the geology and mining practices at Mozambique’s Montepuez ruby
deposit, currently the world’s most important commercial source of ruby.
After these five feature articles, you’ll find our regular Lab Notes and Gem News sections. This issue contains
in-depth coverage of the February 2015 Tucson Gem and Mineral shows, along with reports on the recent
Gemstone Industry & Laboratory Conference (GILC) and the GIA-sponsored International Diamond
School for natural diamond researchers held late January in Brixen, Italy.
We’re also delighted to present the results of the 2014 Dr. Edward J. Gubelin Most Valuable Article Award.
Our sincere thanks to everyone who participated—we had an excellent response this year. Please see the results
on page 31. Also, please don’t forget to take the G&G Challenge, our annual multiple-choice quiz!
Finally, as many longtime contributors know, Stuart Overlin has been the editorial backbone of our journal for
a number of years. I’m very pleased to announce Stuart’s promotion to G&G’s managing editor. I’d also like to
thank former managing editor Justin Hunter for his contribution. Justin is moving to an important new role at
GIA.
We hope you enjoy this edition!
Duncan Pay | Editor-in-Chief | [email protected]
EDITORIAL GEMS & GEMOLOGY SPRING 2015 1

FEATURE ARTICLES
BLUE SPINEL FROM THE
LUC YEN DISTRICT OF VIETNAM
Boris Chauviré, Benjamin Rondeau, Emmanuel Fritsch, Phillipe Ressigeac, and Jean-Luc Devidal
The Luc Yen district of northern Vietnam is a very productive gem province and the leading source of
vivid blue spinel. This study characterizes the origin and gemological properties of these spinels, espe-
cially the cause of their unusually bright color, which is directly related to their value. Chemical and
spectroscopic analyses indicated that the blue color is due to cobalt (Co2+), with some iron contribution.
Petrographic examination identified the context of the gem’s formation, which appears to be linked to
intense metamorphism during successive orogenies. The carbonate platforms in the ancient Paleo-Tethys
Ocean were sandwiched and highly deformed during this orogeny, leading to marble and spinel for-
mation. The authors propose that the cobalt (and to a lesser extent the iron) necessary for the blue color
were transported by fluids during metamorphism of the sedimentary sequence.
B
lue spinels are mined in Sri Lanka, Tanzania, LOCATION AND ACCESS
Myanmar, Pakistan, and Vietnam (Shigley and The Luc Yen district is located in the Yen Bai
Stockton, 1984; Delaunay, 2008; Pardieu and province, in the north of Vietnam. Luc Yen’s capital
Hughes, 2008). Vietnam’s two major spinel deposits, of Yen The (22°6 ′ 38.84″ N, 104°45 ′57.80″ E) is a five-
Luc Yen and Quy Chau, were discovered at the end or six-hour drive from Hanoi on a 160 km expanse of
of the 1980s. The Luc Yen deposits have mostly been good road. All of the district’s blue spinel mining
mined since the 1990s (Pardieu and Hughes, 2008; sites lie within 20 km of Yen The. Several hours of
Senoble, 2010). This area, known for its gem-quality walking or biking are needed to access these mines.
ruby, red spinel, and sapphire (Webster, 1994;
Hauzenberger et al., 2003; Long et al., 2004; Senoble,
2010; Huong et al., 2012), has also been a notable pro-
ducer of vivid blue spinels since the 2000s (figure 1). In Brief
Bright, saturated blue gems are very popular, as evi- • Over the past two decades, Luc Yen, Vietnam has be-
denced by the classic appeal of sapphire and the more come a notable source for blue spinel.
recent trend of Paraíba tourmaline and bright blue • Vietnamese blue spinel may have resulted from the
apatite in the same color range. Therefore, the bright involvement of evaporitic rocks during post-collision
blue color of some spinels has increased the popular- metamorphism.
ity of this gem overall (Delaunay, 2008; Senoble, • Cobalt (Co2+) is the main chromophoric element in
2010). In this article, we investigate the gemological blue spinel, though iron (Fe2+) is also a factor.
characteristics of Vietnamese blue spinels and the ge-
ology of the deposits to gain a better understanding
of this gem source.
The blue spinel deposits are Bai Gou, May Trung, Bai
Son, Bah Linh Mot, Khe Khi, Kuoi Ngan, Khao Ka,
Lung Thin, Lung Day, Khin Khang, and Chuong Tran
See end of article for About the Authors and Acknowledgments.
GEMS & GEMOLOGY, Vol. 51, No. 1, pp. 2–17, (figure 2). Of these, only May Trung, Bai Son, and Bah
http://dx.doi.org/10.5741/GEMS.51.1.2. Linh Mot are primary deposits; the others are second-
© 2015 Gemological Institute of America ary placer deposits. Bai Son, reported by Senoble
2 BLUE SPINEL FROM LUC YEN, VIETNAM GEMS & GEMOLOGY SPRING 2015
Figure 1. The Luc Yen
district of Vietnam has
become a major source
of top-quality blue
spinel, including these
two rough crystals (45
and 70 ct) and the 5 ct
faceted stone. Photo by
J.B Senoble; © Senoble
& Bryl.
(2010), was no longer being mined as a primary de- the Indosinian orogeny, led to the collision of the
posit during our visit in February and March 2012. main shields (Yangtze and Indochina) during the
May Trung is divided into two sites located about Permo-Triassic at about 240–245 Ma (Kušnír, 2000;
150 meters from each other: a marble cliff that is Lepvrier et al., 2008; Huong et al., 2012). In the later
mined for red and lavender spinels, and a second site orogeny, the Himalayan collision during the Tertiary
that is mined for blue spinel from a vein in marble. period, the terrains were strongly reworked. These
terrains are primarily composed of metamorphic
GEOLOGY rocks, mainly medium-grade mica schist, marble,
The rich tectonic history of Southeast Asia is inher- and granulitic gneisses (Kušnír, 2000; Leloup et al.,
ited from several deformation episodes related to the 2001; Hauzenberger et al., 2003).
closure of the Paleo-Tethys Ocean and, later, to the Northern Vietnam has been studied extensively
Himalayan orogeny. The geology of northern Viet- to understand how a continental collision (in this
nam is dominated by metamorphic rocks inherited case, between India and Eurasia) induced crustal
from these two major orogenic events. The first one, wedges to extrude laterally into the surrounding
BLUE SPINEL FROM LUC YEN, VIETNAM GEMS & GEMOLOGY SPRING 2015 3
Yen The
Bai Gou/Chuong Tran
2 km
Figure 2. Most Viet-
namese blue spinel
Khin Khang
deposits are confined to
Luc Yen District May Trung a 30 km² area in the Luc
Khe Khi
Yen district of northern
Bah Linh Mot
Anh Pha Vietnam. The circles
Hanoi
LAOS represent placer deposits,
Kuoi Ngan
Lung Thin while diamonds indi-
cate primary deposits in
Bai Son
THAILAND Lung Day
marble.
Khao Ka
VIETNAM
Thac Ba Lake
Bangkok
CAMBODIA
Blue Spinel Deposit

Primary Secondary Major cities/towns Road
plates. (Tapponnier et al., 1982, 1990; Leloup et al., micaschist, and amphibolite. These metamorphic
1995, 2001; Jolivet et al., 2001; Anckiewicz et al., rocks are sometimes intruded by granitic and peg-
2007). During the Oligo-Miocene (from 35 to 17 Ma), matitic dykes (Leloup et al., 2001; Garnier et al.,
the Indo-Eurasian collision induced strong rock de- 2005, 2008). The marbles are mainly calcitic and in-
formation over all of Southeast Asia. The Indochi- terlayered with Al-, V-, and Cr-rich amphibolites.
nese block was extruded toward the southeast, and Blue spinel is found in a layer of marble more than
this induced the Red River Shear Zone, extending 500 meters thick. It occurs in discontinuous series of
from the Tibetan plateaus to the China Sea for more lenses, tens of millimeters thick and meter-sized in
than 1,000 km (Jolivet et al., 2001; Leloup et al., 2001; length, roughly following the regional foliation. These
Hauzenberger et al., 2003; Anckiewicz et al., 2007). marble lenses are remarkably rich in forsterite (mag-
The Yen Bai province is formed by two different ge- nesian olivine). The gem is often associated with cal-
ological units separated by a fault that is part of the cite, forsterite, pargasite (sodi-calcic amphibole),
Red River shear zone. To the northeast lies the Lo sulfides, and chlorites (magnesian chlorite and
Gam zone, and to the southwest the Day Nui Con clinochlore). Remarkably, blue spinel in these primary
Voi range (figure 3). deposits is not associated with ruby or red spinel.
All of Luc Yen’s gem deposits are located in the
Lo Gam zone (again, see figure 3). The structure of MINING
this unit results from the deformation of the Hi- The three primary deposits at May Trung (22°1′48.9″
malayan orogenesis superimposed on the preexisting N, 104°48′42.7″ E), Bai Son (21°59′47.3″ N, 104°40′9.9″
Indosinian structure (Garnier et al., 2002, 2005). The E), and Bah Linh Mot (22°1′23.7″ N, 104°48′42.8″ E)
Lo Gam formation consists of a sedimentary series are located on a mountain range composed of marble,
metamorphosed into marble, gneiss, calc-silicates, standing about 600 meters high. Each site is mined by
a handful of locals, mainly farmers trying to earn extra and sorted inside the cave and brought up to the sur-
income. The blue spinel is extracted from the marble face, where they are sorted under daylight. In second-
using hand tools (figure 4, top) and a jackhammer. ary deposits, blue spinel is found together with ruby,
Secondary deposits (figure 4, bottom left and bot- red spinel, sapphire, tourmaline, and occasionally gold.
tom right) yield most of the blue spinel production.
Some lie in the valley to the east of the spinel-rich PRODUCTION AND DISTRIBUTION
mountain range. These include Kuoi Ngan (22°0′7.8″ In secondary deposits, blue spinel is a by-product of
N, 104°50′41.1″ E); Khao Ka (21°59′6.5″ N, 104°50′52.5″ ruby and red spinel mining. Even so, some large
E); Lung Thin (22°0′12.8″ N, 104°49′31.5″ E); Lung Day parcels contain more than a thousand carats of mil-
(21°59′51.3″ N, 104°49′23.3″ E); and Khin Khang limeter-sized, very saturated blue spinel (see Pardieu,
(22°1′46.7″ N, 104°50′9.3″ E). Khe Khi (22°1′36.8″ N, 2012). Some dark grayish blue stones weighing ap-
104°48′41.2″ E) and Bai Gou (22°4′43.2″ N, 104°47′5.5″ proximately 5 ct have been faceted, but far fewer
E) are located in the mountain in a small secondary than ruby and red spinel.
basin. Miners use a water hose and a sluice to sort the Blue spinels from primary deposits are found in
gem-bearing gravels (figure 4, bottom left). Some sec- two different forms. Usually miners encounter them
ondary deposits are localized in karst caves inside mar- in “pockets” as centimeter-sized crystals, occasion-
ble (figure 4, bottom right). Heavy gravels are washed ally with a pleasing, well-defined octahedral shape
Figure 3. This geological map of Luc Yen shows two different geological formations: the Day Nui Con Voi Range in
the southwest and the Lo Gam zone in the northeast. The blue spinel deposits are located in the Lo Gam zone.
Adapted from Garnier (2003) and Long et al. (2004).
22 104º40 104º50 Day Nui Con Voi Range

10
to Lao Cai Cenozoic sediment
fault
Ngoi Chi & Nui Voi Formation : gneiss, schist
Tan Linh Minh Xuan with marble and amphilobite lense.
An Lac river
Khoan Thong
Tan Huong granite complex
road
Luc Yen Can an complex : gabbo, diorite
Bai Gou / Chuong Tran
Cong Quan Bao Ai complex : pyroxenite, homblendite
Lo Gam zone
Tan Lap
Quaternary sediments
May Trung Minh Tien Dai Thi Formation : quartz-mica-feldspath scist,

Truc Lau Khin Khang quartz-biotitsericite schist, quartite
Khe Khi
Phuc Loi Bah Linh Mot An Phu
Kuoi Ngan An Phu Formation :
Lung Thin
Trung Tam Bai Son Upper Proterozoic - Lower Cambrian : calcitic
22 marble. dolomitic marble with phlogopite-
Lung Day
00 graphite-margarite
Khao Ka
Quang Minh
Thac Ba Formation :
Upper Proterozoic - Lower Cambrian : micashist,
quartz-biotite or muscovite schist, gneiss,
Tan Nguyen migmatite, marble, quartzite
Nui Chua complex : olivine or pryoxene or

Bai Da Lan amphibole gabbro
Ngoi A Khe Nhan
Mong Son
Phia Bioc complex : biotite granite, pegmatite
Yen Thai and aplite
Khe Nhan
Phia Ma complex : hornblende-garnet to
pryoxene granosyenite
8 km Blue Spinel Deposit
Primary Secondary Ruby deposit
Figure 4. Gem-quality
blue spinels are ex-
tracted from primary
deposits by locals using
hand tools, as shown in
Bai Nua Doi (top). Sec-
ondary deposits are ex-
ploited in the valley
with a sluice box to sort
the minerals according
to their density (bottom
left). In the karstic envi-
ronment, caves trap the
gem-rich gravel (bottom
right). These special
secondary deposits are
also processed with
sluice boxes. Photos by
Boris Chauviré.
with some portion containing gem material, or as ag- from one deposit to the next. In the secondary Bai Gou
gregates of small octahedral crystals of varying qual- deposit, the crystals have a very dark blue color and
ity. These are broken down or cobbed by miners to often reach 10 ct. In Chuong Tran and Bai Son, the
extract a small amount of gem spinel. These gem spinel has a bright blue color (Senoble, 2010; Overton
blue spinel can reach 5 ct, but they are often frac- and Shen, 2011) and can reach 5 ct. Crystals from May
tured. Spinels are also found as millimeter-sized oc- Trung and Khe Khi have a very saturated cobalt blue
tahedra or twins in the marble. color but are quite small (rarely larger than 1 ct).
The blue spinel’s hue, tone, and saturation vary Millimeter-sized blue spinels from the primary
deposits are often kept in marble so that the whole All spinel samples were observed under a 6 W A-
piece can be carved. This is done directly at the min- Krüss Optronic 240 UV light, and we also tested their
ing site, and the carvings are taken down to the val- Chelsea filter reaction. Color was documented under
ley to be sold as decorative pieces. normalized daylight (D65) and a normalized incan-
descent light (A).
MATERIALS AND METHODS
Spectroscopic Measurements. UV-Vis-NIR absorp-
Sample Collection. In early 2012, two field trips were
tion spectra of each sample (window plates) were
organized to collect samples and map the main blue
taken with a Cary 5G Varian spectrophotometer in
spinel deposits within the Luc Yen district. The first
the 200–1500 nm range with a sampling interval of
expedition enabled us to visit most of the corundum
1 nm and a spectral bandwidth of 1 nm maximum
and spinel deposits and to understand the geology of
(sampling and spectral bandwidth were sometimes
this area. We also made contact with local merchants
reduced to 0.25 nm to obtain better resolution).
and miners for the second expedition just one month
Raman spectra were collected on gem samples using
later. On the second field trip, we visited only blue
both a Jobin-Yvon Labram with a 514 nm, 50 mW
spinel deposits and collected whole rock and gem-
laser excitation, and a Jobin-Yvon Spex Horiba
bearing samples. Most of the rock samples were col-
T64000 with a 647 nm, 50 mW laser excitation. The
lected at the mining site. Unfortunately, we did not
spectral range extended from 40 to 1500 cm–1 with a
observe gem samples at the mining sites. All gem
blue spinels for spectroscopic and gemological meas- two-second exposure.
urements were procured from several local mer-
Chemical Composition. LA-ICP-MS chemical analy-
chants in Yen The.
sis was conducted at Blaise Pascal University (Cler-
Materials. From the 55 carats of blue spinel we col- mont-Ferrand, France) using an Agilent 7500
lected from local merchants, six representative rough spectrometer with a Resonetics M-50E laser (193 nm
crystals were selected and prepared in parallel-win- ablation wavelength, 5 Hz frequency with an energy
dow plates for gemological and spectroscopic inves- between 10 and 12 J/cm2). For these analyses, four in-
tigation. The least included and fractured samples dentations (about 73 µm in diameter) were ablated on
were chosen for spectroscopic analysis. A polished each sample, and 27Al was used as the internal stan-
window was prepared on each one to facilitate gemo- dard. Data was processed with the GLITTER 4.4.2
logical and microscopic examination. One additional software. To complement these analyses, we used a
sample similar to SATBLU1 in color and saturation RIGAKU NEX CG energy-dispersive X-ray fluores-
(labeled SATBLUchem) was prepared as a polished cence (EDXRF) spectrometer operating at 25 kV and
section for laser ablation–inductively coupled 0.10 mA. The detection limit for the major elements
plasma–mass spectrometry (LA-ICP-MS) chemical (Al, Mg) is about 0.1 wt.%, and below 0.01 wt.% for
analysis. Four additional samples from a later field the minor elements. Each sample was measured for
trip by author EF were added to complete this study. 90 seconds.
These were also purchased from local merchants.
The spinels were divided into three different parcels Petrographic Examination. Thin sections of rocks
according to their color category (detailed in “Gemo- were observed with a standard Wild Makroscope
logical Characteristics” below). The sample names M420 petrographic microscope, and a JEOL JSL-5800
consisted of the color category (GREBLU, SKYBLU LV scanning electron microscope (SEM) operating at
and SATBLU) followed by a number; see table 1. 20 kV and 0.3 nA electron beam, with a 37° take-off
Moreover, 73 rock samples were collected in the field angle of the detector. Mineral compositions of the
from 11 different mining sites. From these, 19 thin samples and their inclusions were first determined
sections were prepared for petrographic examination. by energy-dispersive spectroscopy (EDS) using an
IMIX-PTS detector. This detector uses a high-resolu-
Methods. Gemological Properties. Specific gravity tion (115 eV) Ge crystal and an ultrathin polymer
was measured hydrostatically with a Mettler Toledo window, detecting elements ideally down to boron,
JB703-c/FACT (with a precision of 0.001 ct). Internal if it is a major component of the material. The cali-
features were observed with a standard gemological bration standards used were either pure elements or
microscope. Refractive index was measured with a simple compounds. The PGT software applies phi-
PФ-І refractometer with Rayner SVLS orange light. rho-z data correction for the effect of X-ray absorp-
TABLE 1. Characteristics of gem blue spinels from Luc Yen, Vietnam.
Samples SKYBLU1 SKYBLU2 SKYBLU3 SKYBLU4 GREBLU1 GREBLU2 GREBLU3 SATBLU1 SATBLU2 SATBLU3
Photo
(normalized
daylight)
Photo
(normalized
incandescent
light)
Weight (ct)1 2.076 0.91 0.24 0.18 4.076 2.538 2.863 0.28 0.23 0.09
Dimensions 10.8 x 5.2 7.6 x 4.6 3.8 x 2.7 2.9 x 2.4 14.9 x 7.1 9.8 x 5.4 9.7 x 5.5 2.8 x 1.1 3.9 x 2.7 3.1 x 1.9
(mm)2 x 4.3 x 2.7 x 1.5 x 0.5 x 4.1 x 2.8 x 3.1 x 2.1 x 1.4 x 1.4
Origin Khao Ka Khao Ka Unknown Unknown Bai Son Bai Son Bai Son Khe Khi Unknown Unknown
Refractive index 1.712 1.712 1.714 1.710 1.718 1.713 1.711 1.712 1.716 1.714
Specific gravity 3.583 3.584 3.594 3.596 3.578 3.598 3.583 3.410 3.673 3.645
Chelsea Pink- Pink- Red Red Pink- Pink Pink Red Red Red
reaction orange orange orange
1
For SKYBLU4 and SATBLU1, the weight is the sum of the weights of the pieces from the sample.
2
For SKYBLU4 and SATBLU1, the dimensions are an average of the measurements of each piece from the sample.
tion in the analyzed material, taking into account all phenomena, nowadays identified separately: classical
the matrix effects. Oxygen was calculated from the color change with lighting, and Usambara effect
spectrum, not based on stoichiometry. (change of color with thickness). We observed that
the color change is more pronounced in stones with
GEMOLOGICAL CHARACTERISTICS a more saturated color. While examining numerous
Visual Appearance. We separated the spinel samples parcels in Yen The, we observed that most of the
into three categories according to their color descrip- grayish blue spinel—and some of the very saturated
tions: blue material, contrary to our other observations—
did not show any color change.
• SATBLU samples: medium to medium dark Blue spinel from secondary deposits (except Khe
tone, strong to vivid saturation, and blue to vi- Khi) is rounded and can reach several tens of carats.
oletish blue hue In Khe Khi, blue spinels are found as millimeter-
• SKYBLU samples: medium light to very light sized octahedra.
tone, strong to very vivid saturation, and blue
hue Optical and Physical Properties. The samples’ refrac-
• GREBLU samples: medium light to light tone, tive index ranged from 1.711 to 1.718, and their spe-
grayish to slightly grayish saturation, and blue cific gravity was from 3.578 to 3.673. They were
to bluish violet hue isotropic, with no anomalous double refringence, and
inert under both short- and long-wave UV light. Under
All of the rough samples were slightly fractured the Chelsea filter, all the samples appeared pink to red
and contained very few inclusions. Color was homo- (see table 1 for details). We observed that the darker
geneous in each stone, and most showed a subtle the spinel, the redder the Chelsea filter reaction.
color change from blue under daylight-equivalent
normalized light (D65) to violetish blue under incan- Microscopic Characteristics. Conchoidal fractures and
descent light (see table 1). The authors avoid the “fingerprint” healed fractures were often present in
commonly used term “color shift” (Senoble, 2010), our samples (figure 5, left). Some showed elongated
which Manson and Stockton (1984) defined in gar- tubes, while others contained groups of parallel tubes.
nets while observing the combination of two color We observed birefringence in some of these tubes,
Figure 5. Blue spinels (here, GREBLU3) often show healed fractures (fingerprints, left), and some samples contain
irregular opaque black crystals associated with elongated tubes (center and right). Photos by Boris Chauviré; field
of view 1 mm (under daylight equivalent light on the left, plane-polarized light in the center, and cross-polarized
light on the right).
which suggested that they consisted of an anisotropic PETROGRAPHY AND CHEMISTRY OF HOST
solid phase (figure 5, middle and right). Black, opaque, ROCKS
irregular to hexagonal crystal inclusions less than 1 Minerals. The marble that hosts blue spinel is
mm, reminiscent of graphite, were also found in some mainly composed of calcite (sometimes magnesian)
samples (figure 5, middle and right). GREBLU1 was and dolomite. The major additional phases are
the only sample that had yellowish fractures covered olivine and pargasite (figure 6). Several accessory
by red crystals (probably ferric oxide hematite). phases were identified using the petrographic micro-
Figure 6. These views of thin sections from rocks bearing blue spinel (under plane-polarized light) show that blue
spinel is always associated with olivine (forsterite) and pargasite in calcite matrix. Clinochlore surrounds all main
minerals (left, field of view 1.5 mm). In the matrix, graphite and pyrrhothite are common accessory minerals
(right, field of view 0.5 mm). Cc = calcite, Clh = clinochlore, Gph = graphite, Ol = olivine, Pg = pargasite, Pyr =
pyrrhotite, Sp = spinel. Photomicrographs by Boris Chauviré.
Cc Pg
Pg
Gph
Pyr
Sp
CIh
OI
Cc Sp Dol
Pen Clh
OI
Pyr
Sp
Pg
Ap
Cc
A B C
Figure 7. An inclusion of apatite in pargasite exhibits intergrowth with calcite (slightly magnesian; left, magnifica-
tion 750×). In most cases, pyrrhotite inclusions have exsolutions of pentlandite, a sulfide with higher nickel con-
tent (center, magnified 1200×), which also contains cobalt. Using scanning electron microscopy with
backscattered electron imaging, sensitive to the atomic number, a petrographic thin section of marble-bearing
blue spinel shows that spinel and olivine are surrounded by clinochlore. The marble is composed of calcite and
dolomite (right, magnified 65×). Ap = apatite, Cc = calcite, Clh = clinochlore, Dol = dolomite, Ol = olivine, Pen =
pentlandite, Pg = pargasite, Pyr = pyrrhotite, Sp = spinel.
scope or EDS with SEM. These included titanite, ru- ite crystals, SEM imaging revealed inclusions of zircon
tile, zircon, graphite, apatite, several sulfide minerals and pargasite. Therefore, titanite probably represents a
(again, see figure 6), and phyllosilicates. The sulfides later stage of mineralization. Clinochlore crystals sur-
were mainly pyrrhotite (Fe1–xS; monoclinic) with round all the other minerals (figure 7c), meaning it
pentlandite exsolution lamellae ((Fe,Ni)9S8; cubic) probably crystallized later during a hydration phase,
and violarite (FeNi2S4; cubic). Raman spectroscopy and possibly during exhumation.
helped to distinguish between different phyllosili-
cates, mainly clinochlore and phlogopite. Humite CHEMICAL COMPOSITION
was not observed in the marble, although this min- Spinel. The composition of the three types of spinel
eral is associated with red or purple spinel, as well as crystals was measured in thin sections using EDS,
ruby (Hauzenberger et al., 2003; Garnier et al, 2008). and all rough samples were analyzed by EDXRF.
These analyses identified them as spinel sensu
Texture. The marble that hosts blue spinel has a gra- stricto (MgAl2O4). Table 2 presents LA-ICP-MS
noblastic texture, with millimeter to centimeter chemical analyses on representative samples of the
grain size. SEM imaging with a backscattered elec-
tron detector showed exsolution features between
calcite and dolomite, and intergrown apatite and cal- TABLE 2. Trace-element composition of three spinel
cite (figure 7a). Pentlandite lamellae in pyrrhotite samples, measured by LA-ICP-MS.
present two different morphologies. The first con- Element Detection
sists of parallel flat lamellae less than 500 nm thick, (ppma) Limit (ppma) SKYBLU1 GREBLU2 SATBLUchem
crossing some pyrrhotite crystals from end to end.
Li 4 2778 6030 2120
The second is lens-shaped, more than 1 µm thick and
Be 10 552 946 32
about 3 µm long, often associated with parallel flat
Ti 2 3 3 202
lamellae (figure 7b).
V 1 11 6 362
Paragenesis. Blue spinel is observed only in olivine-rich Cr 3 16 8 1111
lenses, associated with dolomite and calcite (figure 8). Mn 5 238 106 287
No blue spinel is observed in the marble when olivine Fe 20 11,009 9362 12,794
is absent. The spinel-rich lenses are elongated nearly Co 0.2 84 22 1236
parallel to the regional foliation: roughly 45° toward Ni 1 85 29 2514
the northeast. Spinel and pargasite show inclusions of Cu 1 4 4 4
apatite and sulfides similar in shape and composition
Zn 4 7242 4887 1047
for both host minerals. This suggests that apatite and
Ga 0.2 299 1088 234
sulfides preexisted spinel and pargasite. In some titan-
10 cm
Marble Pargasite Blue Spinel Olivine
5 mm
Figure 8. In Vietnam, primary blue spinel deposits appear as approximately lens-shaped bodies rich in olivine.
These lenses are hosted in marble, and pargasite is found throughout the surrounding marble. Photo and drawing
by Boris Chauviré.
three color categories. The main impurities detected part of the spectra, in the violet to blue region (400–
were Li, Fe, and Zn. Significant traces of Be, Ti, V, Cr, 500 nm) and in the red region (670–700 nm). We also
Mn, Ga, Ni, and Co were also detected. All analyzed observed several weak peaks between 300 and 500 nm
spinels had concentrations of Ga, Zn, and Li, consis- at about 371, 386, 418, 427, 455, 460, and 480 nm. The
tent with those observed only in natural blue spinel bands at 427 and 460 nm are not visible on the spectra
(Muhlmeister et al., 1993; Krzemnicki, 2008; Sae- that show the most intense main band between 500
seaw et al., 2009). All the samples presented nearly and 670 nm (samples SKYBLU2 and SATBLU1). Ad-
uniform concentration in iron and in copper: around ditionally, we noted a large, weak band centered at
10,000 ppma (equal to 1 atomic percent) and 4 ppma, about 440 nm only on the SKYBLU samples. For sam-
respectively. The other elements showed strong vari- ples GREBLU1 and SATBLU1, we also note an in-
ation among samples. Sample SATBLUchem (satu- creasing absorption from 450 nm toward the UV.
rated blue) was enriched in Ti, V, Cr, Mn, Co, and Ni
compared to the other samples. Samples SKYBLU1 Raman and Luminescence. The Raman spectra were
and GREBLU2 were enriched in Be and Zn compared typical of spinel, with weak peaks at 405, 665, and
to SATBLUchem. GREBLU2 is also enriched in Li 766 cm–1 (figure 10a; Fraas et al., 1973). The 405 cm–1
and Ga compared to the two others. peak was 9 cm–1 wide, evidence that the analyzed
spinels were natural and unheated (Krzemnicki,
Host Rocks. The chemical composition and charac- 2008; Saeseaw et al., 2009). However, this Raman sig-
teristics of associated minerals were also examined nal of spinel was overwhelmed by luminescence
with EDS analysis. Olivine is 99% pure forsterite with the two available excitation wavelengths (514
(Mg2SiO4). Pargasite is rich in titanium, sodium, and or 647 nm). The luminescence band was centered at
chlorine. Apatites are fluorapatites with up to 20% 107 cm–1 for the 647 nm excitation wavelength, cor-
chlorine in substitution of fluorine. In two thin sec- responding to a 650 nm emission (figure 10b). In this
tions, we analyzed one REE-rich unknown mineral case, the sample showed a strong red luminescence
and several molybdenum- and tungsten-rich un- (figure 10b, inset) consistent with a broad band emis-
known minerals. Cobalt was found in sulfides, as high sion centered at 650 nm. In addition, many weak
as 1.5 wt.% in pentlandite and 3.5 wt.% in violarite. peaks between 673 and 710 nm, grouped in apparent
triplets, were visible: 685, 687, and 689 nm; 696, 697,
SPECTROSCOPIC PROPERTIES OF BLUE SPINEL and 700 nm; and 704, 707, and 709 nm (figure 10b).
UV-Vis Absorption Spectra. All UV-visible spectra
showed a broad, intense absorption band between 500 DISCUSSION
and 670 nm composed of several narrower bands at Primary Geological Origin. Red and blue spinels are al-
about 545, 550, 560, 580, 590, and 625 nm (figure 9). ways found in marble (figure 11). Garnier et al. (2008)
Two transmission windows were seen in the visible proposed that this marble originated from an old car-
UV-VISIBLE SPECTRA
above 550°C for a CO2-rich system; Bucher and Frey,
SATBLU1
14.0
Band due to Co 2+ 1994; Janardhan et al., 2001; Proyer et al., 2008). Par-
12.0 Band due to Fe2+ gasite is ubiquitous in marble, also representing a
10.0
Band not allocated
high-temperature phase. Pargasite, olivine, and spinel
are nearly contemporaneous, and they may have
8.0
crystallized from the destabilization of diopside with
6.0 increasing pressure and temperature in a prograde re-
4.0 action (Proyer et al., 2008; Ferry et al., 2011).
2.0
We detected some fluorine and chlorine in apatite
and pargasite, and some sodium, lithium, and beryl-
0.0
ABSORPTION COEFFICIENT (cm –1)
2.5 SKYBLU2
Figure 10. The samples in this study displayed the

2.0
typical Raman signal for spinel (top), with a strong
1.5
continuum due to cobalt luminescence. But when the
concentration in cobalt was too high, luminescence
1.0
overwhelmed the signal for spinel. In some samples,
spectra acquired using a 647 nm excitation showed
0.5 additional luminescence peaks of chromium (the so-
called organ pipe spectrum, bottom). Under green
0 laser excitation (514 nm), the sample reacted with a
red luminescence (bottom photo).
0.9 GREBLU1
0.8
0.7
RAMAN SPECTRA
0.6
0.5
30.0
0.4 27.5
0.3 25.0
0.2 22.5
20.0
0.1
17.5
0
350 400 450 500 550 600 650 700 15.0 405
12.5
RAMAN INTENSITY (x1000 COUNTS)
WAVELENGTH (nm) 10.0 665

7.5
766
5.0
Figure 9. The UV-Visible spectra of typical blue 2.5 GREBLU2

0.0
spinels from Vietnam show a major composite ab- 100 200 300 400 500 600 700 800 900 1000 1100
sorption band between 500 and 650 nm, a large trans-
mission window in the blue to violet region, and a
smaller one in the red. The bands at 371, 386, 418, 40.0
455, 460, 480, 560, and 590 nm are due to Fe2+.The 35.0
685 nm
bands at 545, 550, 580, and 625 nm are due to Co2+. 687 nm
30.0
The band at 427 nm is not allocated. 673 nm
675 nm 689 nm
25.0 Co 2+ : 650 nm
697 nm
20.0 696 nm 700 nm 707 nm
bonate platform (considered Precambrian to Permo-Tri- 15.0
704 nm 709 nm
assic), which later metamorphosed. Graphite crystals
10.0
in these Vietnamese marbles likely derive from
metamorphism of organic matter (Giuliani et al., 5.0
SATBLU1
Cr 3+
2003; Garnier et al., 2008). As already mentioned, 0.0

50 150 250 350 450 550 650 750 850 950 1050 1150125013501450
blue spinels are always associated with olivine
(nearly pure forsterite). This paragenesis is typical of RAMAN SHIFT (cm–1)
the granulitic metamorphic facies (high temperature
Garnier et al. (2008) did not observe evidence of a
fluid circulating through the marble. They proposed
that aluminum and chromium originally sedimented
within the carbonate platform. These elements were
mobilized due to the presence of halogen elements
(fluorine and chlorine) from evaporitic rocks. We pro-
pose that the mobilization of Ni and Co happened
through the same process. Another hypothesis is that
Ni and Co were mobilized from amphibolitic rocks
interlayered in the marble (observed by Garnier et al.,
2006) via halogen-rich fluids. Fluids can be formed
by the metamorphism of clay minerals, evaporate,
and organic matter (Giuliani et al., 2003; Garnier et
al., 2008).
Proposed Geological History. The ancient Paleo-

Tethys Ocean (possibly Proterozoic to Permo-Trias-
sic) separated the China (Yangtze) and Indochina
cratons (now Vietnam, Laos, Cambodia, Thailand,
and Myanmar). In this ocean, a carbonaceous plat-
form developed by sedimentation. Tectonic move-
ments caused the closing of this ocean, and
evaporitic minerals were deposited. The two main
blocks (Yangtze and Indochina) subsequently col-
lided, and all the sedimentary and magmatic rocks
of the oceanic crust underwent intense deformation
and metamorphism. During the collision, the meta-
morphism of the mix of former carbonate platform
minerals and some detritic material (such as clays)
Figure 11. Blue spinel from Luc Yen in its marble host. deposited with it may have led to the formation of
Photo by Vincent Pardieu/GIA. diopside through the following reactions:
tremolite + calcite → diopside + dolomite

dolomite + quartz → diopside + carbon dioxide
lium in blue spinel. These elements are indications By increasing metamorphism, diopside destabi-
that evaporitic rocks played a role during metamor- lized into olivine, spinel, and clinohumite. The re-
phism (Proyer et al., 2008). Giuliani et al. (1993) and duction of evaporitic minerals such as sulfates
Garnier et al. (2005, 2008) also proposed this hypoth- formed chlorine- and fluorine-rich fluids. These flu-
esis from the study of fluid inclusions in gem ruby ids were involved in the mobilization of aluminum
from the Luc Yen area. and other elements such as chromium (Giuliani et
Different areas yielding ruby and red or blue spinel al., 2003; Garnier et al., 2008).
show distinct characteristics. Red spinel and rubies Some processes remain poorly understood. Why do
have a very similar paragenesis. Forsterite is only as- some areas show clinohumite with red spinel while
sociated with blue spinel, and clinohumite is only as- others show olivine and blue spinel? What is the main
sociated with red spinel. Clinohumite can also grow difference responsible for mobilizing more chromium
from diopside in a prograde reaction with dolomite (red spinel) or more cobalt (blue spinel) in the marble?
and water (Proyer et al., 2008). Ruby-bearing rocks are
very different from those containing blue spinel, as Origin of Blue Color and Color Change in Viet-
they underwent different metamorphic histories. Be- namese Blue Spinels. The main absorption band be-
cause of the intense tectonic activity in Luc Yen, it is tween 500 and 670 nm, the dominant origin of color
possible that two rocks with very different geological in these blue spinels, is composed of a series of bands
histories have been brought in contact. at approximately 545, 550, 560, 580, 590, and 625 nm
Figure 12. A gem mer-
chant examines a blue
spinel from the Luc
Yen district. Photo by
Vincent Pardieu/GIA.
(again, see figure 9). Bands at 545, 550, 580, and 625 had an absorption coefficient greater than 10 cm–1, and
nm are due to cobalt (Co2+) substituting for Mg2+ in the iron optical absorptions observed were weak. For
tetrahedral sites of the spinel structure (Wherry, the parcel classified as SKYBLU, iron and cobalt opti-
1929; Pappalardo et al., 1961; Shigley and Stockton, cal absorption seemed to have a similar importance in
1984; Kuleshov et al., 1993; Muhlmeister et al., 1993; the optical spectra, reaching a maximum of 2 cm–1 as
Delaunay et al., 2008; Duan et al., 2012; Bosi et al., compared to SATBLU samples. GREBLU samples had
2012; D’Ippolito et al., 2015). The remaining absorp- the most significant iron band, but the main absorp-
tion bands (at 371, 386, 418, 455, 460, 480, 560, and tion band only reached 0.5 cm–1. We also observed a
590 nm) are allocated to iron (Fe2+) in tetrahedral sites correlation between the cobalt absorption bands and
of the spinel structure (Gaffney, 1973; Dickson and the color saturation.
Smith, 1976; Muhlmeister et al., 1993; Delaunay et SATBLU2 had a Fe/Co value of approximately 10
al., 2008; D’Ippolito et al., 2015). A weak band ob- (table 2), and the SATBLU samples had the most sat-
served at 427 nm is not attributed but may be linked urated color (table 1). GREBLUE2, with a Fe/Co ratio
with other measurable elements such as Ni. Conse- of about 425 (table 2), had a visible gray hue compo-
quently, the spectra show transmission windows be- nent (table 1). For intermediate Fe/Co ratios of about
tween 300 and 500 nm and between 700 and 900 nm 130 (measured on SKYBLU1; see table 2), the spinel
that explain the blue color. As expected, the spectra had a sky-blue color (table 1). Moreover, sample
show that iron (Fe2+) and cobalt (Co2+) are the main GREBLU1, which had the grayest color, showed
chromophore elements. The other trace elements de- more significant bands due to Fe2+. We propose that
tected either do not give rise to absorption in the vis- the GREBLU samples are colored mainly by iron and
ible range or are much less efficient absorbers than the SATBLU samples by cobalt. The SKYBLU sam-
cobalt. Chromium, which is the main chromophore ples’ colors arise from both iron and cobalt absorp-
for red and pink spinel, makes a significant contribution. Hue differences are more significantly
tion to color if the concentration is above 1000 ppma. controlled by iron (with different species), while sat-
(Muhlmeister et al., 1993; T. Häger, pers. comm., uration is largely dictated by cobalt (D’Ippolito et al.,
2014). Cr concentration in SATBLU samples is bor- 2015).
derline, but the Co concentration is higher, too. The Using chemical and spectroscopic analysis from
contribution is considered negligible. eight of our samples, we calculated the molar absorp-
We observed that the SATBLU samples, which had tivity of cobalt in spinel (sensu stricto) for three ab-
the most saturated color, also had the most important sorption bands. At wavelengths of 545, 580, and 625
cobalt optical absorption. In addition, the main band nm, we took the apparent maximum of each band. We
determined a molar absorptivity of 530±29, 664 ±18, CONCLUSION
and 586±11 L·mol–1·cm–1, respectively. For the sake of We confirmed that the saturated “cobalt-blue” color
comparison, we calculated the molar absorptivity of of Vietnamese spinels (figures 12 and 13) is due pre-
iron in spinel (sensu stricto) for bands 371, 386, 480, dominantly to Co2+ substituting for Mg2+ in the tetra-
and 590 nm. These bands are attributed to ferrous iron hedral site of the spinel structure. For the most
(Fe2+) in the tetrahedral site. Our chemical analysis saturated blue spinel, cobalt is the main coloring
measured only the total iron content. Assuming all agent, even if iron is more abundant. Indeed, cobalt
iron was in the form Fe2+, we propose that the molar is a powerful coloring agent, with a molar absorptiv-
absorptivity of ferrous iron in the tetrahedral site had ity between 500 and 700 L·mol–1·cm–1 depending on
an order of magnitude of about 30 L·mol–1··cm–1 for wavelength, whereas iron (Fe2+ in the tetrahedral site)
each band. With this method, values of molar absorp- has a molar absorptivity of about 30 L·mol–1·cm–1.
tivity are not very accurate but provide a working as- The higher the iron/cobalt ratio is, the grayer the
sumption for our preliminary study. We recognize color. The red transmission window of these gems
that further investigation is needed to fully under- explains both their pink to red Chelsea filter reaction
stand the color in blue spinel. A Gaussian decompo- and their slight change of color from blue to “laven-
sition of spectra can improve the precision of these der” with a change of lighting environment. The red
values. Nevertheless, it is apparent that in spinel, luminescence is due to both Cr3+ and Co2+, and it may
Co2+ is approximately 20 times more efficient at ab- have a minor influence on the perceived color.
sorbing light, and thus creating color, than Fe2+ (con- This study offers clues to the definition of
sistent with D’Ippolito et al., 2015). “cobalt-blue” spinel. Cobalt is actually the main
Spectra have two transmission windows between chromophore, but the presence of iron is also signif-
350 and 500 nm (in the blue region) and between 670 icant. The term “cobalt-blue” can be clarified by fur-
and 900 nm (in the red region). This explains the pink ther investigations on the significance of each
to red reaction under the Chelsea filter and the color chromophore elements (iron and cobalt). These in-
change. Indeed, the Chelsea filter probes a transmis- vestigations can propose a limit on the ratio of
sion window in the red. The color change is also ex- iron/cobalt above which the term “cobalt-blue” can-
plained when the spectral composition of the not be used.
lighting environment is compared with the absorp- Spinels from Luc Yen contain few inclusions.
tion spectra of spinel, although this change is not ob- Fractures and fingerprints were the most common
served in every example. Compact fluorescent light inclusions found. Sometimes, we observed parallel
emits more in the blue region than in the red, and elongated tubes with black, irregular solid inclusions
therefore the spinel appears blue. Under incandes- associated.
cent light, which is richer in red, spinel displays a vi-
oletish blue color that is mostly blue with minor red.
Figure 13. Vietnam’s spinel production yielded this
Origin of Red Luminescence. Under laser excitation, 2.59 ct cobalt blue gem. Photo by Robert
our samples showed a strong red luminescence. In Weldon/GIA, courtesy of Palagems.com.
spectra acquired using a 647 nm excitation, we ob-
served several peaks (in groups of three) between 673
and 710 nm (at about 673, 675, 685, 687, 689, 696,
697, 700, 704, 707, and 709 nm; see figure 10b). These
peaks are known to be due to trivalent chromium
(Cr3+) substituting for aluminum in the octahedral
site (Burns et al., 1965; Wood et al., 1968; Skvortsova
et al., 2011). The broad band centered at 650 nm is
allocated to divalent cobalt in the tetrahedral site of
the spinel structure (Abritta and Blak, 1991;
Kuleshov et al., 1993). These luminescence behaviors
are consistent with our chemical analysis, as the
strongest luminescence was observed in the SATBLU
samples, which had higher concentrations of Cr3+
(1111 ppma) and Co2+ (1236 ppma).
From a geological standpoint, gem-quality blue form and evaporitic platform, was sandwiched be-
spinels are associated with intense metamorphism. tween the two continents. The collision led to the
Their marble host results from the metamorphism metamorphism of the evaporite rocks, in turn pro-
of an ancient carbonaceous platform. This platform ducing fluids mobilizing some elements, possibly in-
was located in the Paleo-Tethys Ocean, which sepa- cluding cobalt. Spinel grew in the marble during this
rated Indochina and China. During the convergence intense metamorphism. These processes of meta-
of these “paleo-continents,” the ocean closed off, ac- morphism and fluid interaction led to the crystalliza-
companied by the formation of evaporitic rocks. The tion of attractive blue spinels in the marble
ocean crust, associated with the carbonaceous plat- mountains of Luc Yen.
ABOUT THE AUTHORS preparation and progress of the expeditions. We thank Vincent’s
Mr. Chauviré ([email protected]) is a PhD student at contacts for acquiring blue spinel samples. We are grateful to Mr.
the Laboratoire de Planétologie et Géodynamique de Nantes, Chuãn, our guide, for his knowledge of the field and his logistical
France, and Dr. Rondeau is an assistant professor at the same support. We also thank Pham Van Long, director of the Center for
laboratory (CNRS Team 6112). Dr. Fritsch (CNRS Team 6502) is a Gem and Gold Research and Identification in Hanoi, for his logisti-
professor of physics at the University of Nantes, Institut des cal support and for exporting the samples collected. GIA’s labora-
Matériaux Jean Rouxel. Mr. Ressigeac is product manager for tory in Bangkok and its director, Kenneth Scarratt, provided
Montepuez Ruby Mining, Mozambique. Mr. Devidal is an engineer technical and logistical support. Jean-Pierre Lorand (LPGN-
specialist of ICP-MS-LA at the Laboratoire Magmas et Volcans, CNRS) generously shared his knowledge about sulfides. We
Clermont Ferrand, France. thank Alexandre Droux from the Laboratoire Français de Gem-
mologie for EDXRF measurements. We also thank Tobias Häger
ACKNOWLEDGMENTS of Johannes Gutenberg University in Mainz, Germany, for his help
We are grateful to Vincent Pardieu, senior manager of field gemol- with interpreting UV-Vis spectra. We also thank reviewers that
ogy at GIA’s Bangkok laboratory, for his valuable aid during the participated to improve this study.
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FEATURE ARTICLES
THE CHINESE SOUL IN

CONTEMPORARY JEWELRY DESIGN
Andrew Lucas, Merilee Chapin, Moqing Lin, and Xiaodan Jia
When the same gems and precious metals are used in jewelry, design is the element that ultimately dis-
tinguishes one piece from another. Real success is measured not only by the value of its materials but
also by the character and quality of the design and craftsmanship. Once considered a weak point of
China’s gem and jewelry industry, design has seen tremendous progress over the last decade. Benefiting
from the availability of more gem materials and the power of a rapidly growing consumer market, Chi-
nese designers now have the freedom to develop their design concepts and craftsmanship skills. De-
signers from mainland China, Hong Kong, and Taiwan share the bond of cultural identity and have
found ways to create jewelry that expresses the Chinese soul.
F
rom dangling hair ornaments to exquisite jade This lack of innovation caused a sense of stagna-
pendants and splendid crowns, jewelry has al- tion, which led some industry pioneers to find a new
ways served as personal adornment for the Chi- approach. Professional training and degree programs
nese people, from ordinary citizens to royal families
(figure 1). Throughout the civilization’s 5,000-year
Figure 1. In this replica of a Qing dynasty hairpin,
history, masters of jewelry design and manufacturing outlines of flowers, leaves, and other patterns were
have emerged continually, applying innovations created with very thin gold threads using the filigree
while developing their skills. technique. Kingfisher feathers mounted in the frame
China’s Cultural Revolution (1966–1976) fol- provide the bright blue color. Unlike dyes, the feath-
lowed more than a century of social and economic ers show natural color and shading as well as biologi-
upheaval that hindered almost every aspect of na- cal texture. Ruby cabochons are mounted as the
tional growth. During this period, jewelry came to center stones. Photo by Eric Welch, courtesy of
represent capitalism, and wearing it was considered Zhaoyi Xintiandi (Beijing) Jewelry Co., Ltd.
offensive. Designers and craftsmen avoided persecu-
tion by simply stopping their work.
In the last decades of the 20th century, the Chi-
nese gem and jewelry industry experienced a dra-
matic upswing. By the end of the 1990s, there were
about 20,000 jewelry businesses and some three mil-
lion people involved in the trade (Hsu et al., 2014).
The country’s jewelry markets became saturated
with similar products, many of low quality (J. Bai,
pers. comm., 2013).

GEMS & GEMOLOGY, Vol. 51, No. 1, pp. 18–30,
http://dx.doi.org/10.5741/GEMS.51.1.18.
© 2015 Gemological Institute of America
18 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

curately interpret their meanings (see figure 3, for ex-
ample). The spiritual message carried by a piece of
jewelry can be reflected by combining some Chinese
design elements, but this is not always the case. Sim-
ply using Chinese elements is not enough: The de-
signers must think in the Chinese way.
In 2010 China overtook Japan to become the
world’s second-largest economy, after the United
States. China is now also the second-largest jewelry
market and is projected to become the largest by
2020 (“Chinese jewelry firms…,” 2014). To cater to
the rapidly expanding market for luxury goods, the
Chinese began developing their own innovative jew-
elry designs.
Figure 2. This ring is from the “Jade That She
Wants” collection, designed by Hong Kong–based
Grace Lee, chief designer of Zhaoyi Jade House. The CHINESE DESIGN ELEMENTS
18K white gold ring features a transparent jadeite One recent jewelry trend is to incorporate Chinese
cabochon center stone and fancy sapphire accent elements such as dragons, the phoenix, bamboo, and
stones. Photo courtesy of Zhaoyi Xintiandi (Beijing) Chinese characters into their products. Many award-
Jewelry Co., Ltd. winning pieces from international design and gem-
in jewelry design have been offered since the early

1990s. Over the last 10 years, many leading universi- Figure 3. This fragrance locket ring was designed by
ties and art academies have formed their own jewelry Dickson Yewn. Ancient Chinese scholars and social
design and manufacturing departments to serve an elites often carried small lockets filled with fragrance
expanding market. Foremost among these are Ts- to freshen the air or even act as an insecticide. The
ring symbolizes the wearer’s virtue, which in turn can
inghua University, China University of Geosciences,
influence their peers. Although flowers and lockets
and China Central Academy of Fine Art. Jewelry are not considered traditional symbols of Chinese
competitions have been created to foster the develop- culture, this ring is a reminder of the important
ment of young talent. Many companies have invited virtues one should bear. Photo courtesy of Yewn.
designers from Hong Kong and overseas to bring their
skills to China and to train locals (figure 2). At the
same time, Chinese artists have begun going overseas
to the UK, the United States, Italy, and Germany to
study Western jewelry manufacturing.
It is widely believed by domestic consumers that
Chinese jewelry designs should capture the “Chinese
soul.” This concept is a reflection of the native cul-
ture, “a collective programming of the mind” that
distinguishes a group of people (Hofstede and Bond,
1988). Rather than being genetically transferred, cul-
tural inheritances can only be acquired by native ex-
perience. For thousands of years, the core values of
Chinese culture have not fundamentally changed.
The process begins at birth and continues throughout
a person’s life, as one gains a deeply rooted under-
standing of Chinese culture, including its distinct
traditions, philosophy, religions, and preferred mate-
rials. This understanding allows the native-born de-
signer to easily and naturally incorporate traditional
elements into jewelry for domestic audiences and ac-
CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 19

tional flower. One of his collections, “Lock of Good
Wishes,” is based on such traditions (figure 5). The
earliest known lock in China was uncovered from a
tomb dated 3000 BC. While the basic function of the
lock has not changed, the style, materials, and crafts-
manship have continued to evolve, and its meaning
as a decorative motif has broadened. As a symbol of
security, a lock also represents good health and
longevity in Chinese culture. Newborns are given
precious metal lock pendants to “lock” health and
happiness into their lives forever. This type of pen-
dant is still one of the most popular jewelry gifts for
babies in China.
Yewn’s jadeite and diamond “Wish Fulfilling”
ring features a traditional lattice window shank. Lat-
tice windows were a common sight in ancient Chi-
nese gardens, their delicate patterns inviting the
viewer to look through and enjoy the beautiful
scenery within. They originated in southern China,
home of the Classical Gardens of Suzhou. These pri-
vate gardens, a UNESCO World Heritage Site, date
from the 11th through 19th centuries. Their lattice
windows are among the most important elements,
framing the view with a mysterious veil (figure 6).
Figure 4. Hong Kong designer Dickson Yewn is de- Yewn borrowed this concept from the garden mas-
voted to creating jewelry inspired by Chinese tradi- ters, intending the ring to create a connection be-
tions. Photo courtesy of Yewn. tween the wearer’s mind and the outside world.
cutting competitions feature these elements (Chen, Figure 5. This diamond and emerald bracelet is
2014). While several Western designers have em- from Dickson Yewn’s “Lock of Good Wishes” collec-
braced traditional Chinese symbols, they sometimes tion. The four corners of the lock panel are deco-
rated with simplified bat patterns, which symbolize
do not apply or combine them properly, making
good luck and happiness in Chinese culture. The
them less meaningful. According to Hong Kong jew-
clasp is a realistic recreation of an ordinary gate
elry designer Dickson Yewn, “Jewelry is a new way lock from ancient China. The concept is typically
to interpret a culture that has been suppressed for used in baby jewelry to make the wearer feel
decades.” He believes China is a fundamental re- blessed throughout life, and Yewn has successfully
source for jewelry design and that after prolonged so- applied it to adult pieces. Photo courtesy of Yewn.
cial upheaval, it is time to recapture its glory.
Trained as a painter, Yewn has always been inter-
ested in Chinese culture and history (figure 4). Hav-
ing spent years in the West, he has a deep
appreciation for its culture but prefers to create jew-
elry that is distinctly Chinese rather than mixing
cultural designs (World Gold Council, 2014). He is
also engaged in reviving traditional Chinese jewelry
craftsmanship.
While many designers focus on generating new
concepts, Yewn digs deeply into native traditions and
fuses them with contemporary luxury. His common
themes include lattice patterns, paper cutting,
Manchurian motifs, and peonies—the Chinese na-

Figure 6. Left and top
right: The inspiration
for the “Wish Fulfill-
ing” ring worn by First
Lady Michelle Obama
came from the exqui-
site lattice windows
used in ancient Chi-
nese gardens. The lat-
tice patterns add
variety to the inner and
outer parts of the ring.
Photo courtesy of
Yewn. Bottom right: A
representative lattice
window in the Humble
Administrator’s Gar-
den in the Classical
Gardens of Suzhou.
The exquisite design
and craftsmanship of
this window lend ele-
gance to the view be-
hind it. Photo by
Wenrong Cao.
This ring was a favorite of First Lady Michelle edge and skills, but she felt they were not enough to
Obama, who wore it in 2011 when President Obama make her a successful master goldsmith and de-
hosted a banquet for Queen Elizabeth II and Prince signer. Over the next 40 years, she perfected her tech-
Philip. The ring caught the attention of many notable nique in a filigree inlay art factory, where she was
guests that evening (Adducci, 2011). trained by older-generation master goldsmiths. In
2008, filigree inlay art was designated the Intangible
TRADITIONAL CRAFTSMANSHIP Cultural Heritage of China, and Master Bai was
China has a long history of using gold and silver in named the official Representative Inheritor. Master
jewelry design, and gold still dominates the domes- Bai’s participation in promoting filigree inlay art ac-
tic jewelry market. Imperial artisans were once able
to spend considerable time on a piece of jewelry
commissioned by the emperor. Today very few can In Brief
afford to practice time-consuming traditional crafts- • After years of stagnation, Chinese jewelry design has
manship. Yet the rise of mainland China’s luxury undergone a renaissance, combining innovative tech-
market is changing this by encouraging the adoption niques with culturally relevant motifs.
of classic techniques. • Individual designers are able to develop unique pieces
One of these is filigree inlay art (figure 7). This based on exposure to both Western methods and tradi-
combines two crafting skills: The first is filigree, the tional Chinese craftsmanship.
use of gold or silver threads of different weights. The • The growth of the Chinese jewelry market has led to a
second is inlay work, which involves setting stones greater presence in the international industry, particu-
and carving or filing precious metals around them. larly in the luxury market.
The artist responsible for the revival of this tech-
nique is Master Jingyi Bai (figure 8).
Master Bai’s interest in both painting and pattern celerated in 2009, after she began designing for well-
serves as the basis for her design life. As an art school known Chinese jade jewelry brand, Zhaoyi. These
student of precious metals, she gained some knowl- two events took her career to new heights.

Figure 7. This is a replica of a Qing dynasty hairpin re- Figure 9. This pair of earrings is from an award-win-
covered from a tomb in Beijing. The two main pearl- ning filigree inlay jewelry suite by Master Bai. Thin
mounted patterns, composed of two layers of gold gold threads were bent to form springs, which were
threads, are called ruyi in Chinese and symbolize the rolled to form the individual cones. Craftsmen then
fulfillment of one’s wishes. Photo by Eric Welch, cour- joined the cones to shape each earring before mount-
tesy of Zhaoyi Xintiandi (Beijing) Jewelry Co., Ltd. ing the faceted jadeite. This filigree technique, known
as piling, gives the pieces a light, airy feel. Photo by
Eric Welch, courtesy of Zhaoyi Xintiandi (Beijing)
Master Bai has created many replicas of historic Jewelry Co., Ltd.
filigree inlay art pieces. Today, she works full-time
in her studio as Zhaoyi’s chief designer of filigree
inlay products (figure 9). Her jewelry is thoroughly manship. Her filigree inlay jewelry set “Royal Clas-
Chinese, from the materials to the themes and crafts- sic: Ripping Cloud” won Best Craft Inheritance
Award at the second National Jewelry Processing
Craft Competition in 2011.
Figure 8. Master Jingyi Bai is China’s official Repre-
sentative Inheritor of filigree inlay art. She works in
Master Bai’s design philosophy is that a piece must
her studio to create haute couture jewelry for high- succeed on its own in the market. To reach this goal,
end consumers. Photo courtesy of Zhaoyi Xintiandi she considers both the quality of the craftsmanship
(Beijing) Jewelry Co., Ltd. and the contemporary composition. She says the first
filigree inlay jewelry suite she designed and made for
Zhaoyi was purchased—unexpectedly—by a young
couple. For years, China’s younger generation, espe-
cially in large cities, considered high-purity gold jew-
elry somewhat out of fashion. This was largely due to
the lack of creative design. Today, young consumers
prefer innovative gold jewelry.
DEPICTIONS OF CHINESE PHILOSOPHIES

Chinese jewelry designers benefit from many sources
of inspiration. Poems, fairy tales, and paintings, for
instance, are full of generations-old Chinese philoso-
phies. Yue-Yo Wang (figure 10), a jewelry designer
from Taiwan, has devoted herself to traditional Chi-
nese jewelry design using such themes. She com-
bines Chinese knotting art with modern design and
manufacturing techniques to create her own pieces,
giving each of them its own story.

maline, and chalcedony (figure 13). These gems are
time-honored favorites of the Chinese people. Wang
believes that every gem has its own spirit, and she is
inspired to find it and express it through her jewelry.
Wang’s designs, with their balanced and harmo-
nious color and materials (figure 14), reflect the phi-
losophy laid out circa 500 BC in Zhong Yong,
translated as The Doctrine of the Mean. Zhong sym-
bolizes impartiality, while Yong represents perma-
nence. This classic text was one of the first books
composed by the disciples of Confucius and has been
a central tenet of the philosophy ever since. Intellec-
tuals practiced this philosophy in their daily lives,
while the ruling class applied it to management strat-
egy. After generations, Confucian philosophy became
the barcode of Chinese culture and remains so to this
day. This is reflected in art, symmetry patterns, and
motifs. The aesthetic standard the Chinese people
hold is also based on this philosophy. Chinese paint-
ing, calligraphy, and carving all reflect this standard,
which is exemplified by Wang’s jewelry.
Figure 11. This necklace by Yue-Yo Wang features a

knotted neckpiece and a rose quartz pendant
mounted in 18K gold. Photo courtesy of Wang Yue-Yo
Creative Jewelry Design.
Figure 10. Taiwanese designer Yue-Yo Wang, pictured

here, creates jewelry that expresses Chinese philoso-
phy and traditions. Photo courtesy of Wang Yue-Yo
Creative Jewelry Design.
In China, knotting art can be traced back to

around 1600 BC. Today the younger generation is em-
bracing this ancient art with renewed interest. Wang
began with knotted teapot covers and then developed
her product lines to include clothing and decorations.
She eventually realized that knotting art could be
combined with modern jewelry manufacturing meth-
ods (figure 11), and established Wang Yue-Yo Creative
Jewelry Design in Taipei about 20 years ago. The flag-
ship store opened in 2007 in Beijing. Since then her
company has greatly expanded its number of retail
outlets. In 2012 Wang formed the Taiwan Creative
Jewelry Design Association, hoping to attract design-
ers focused on artistry and a desire to spread Chinese
culture to the rest of the world (figure 12).
Wang’s designs feature traditional Chinese sym-
bols with elements of Chinese knotting art, such as
long tassels and thread patterns. Gem materials often
seen in her designs include opal, coral, jadeite, tour-

Figure 12. Yue-Yo Wang’s design and marketing style has
taken her jewelry into the world of high fashion. Photo
courtesy of Wang Yue-Yo Creative Jewelry Design.
INNOVATIVE DESIGN TECHNIQUES

Shirley Zhang, one of China’s leading designers (fig-
ure 15), has been in the industry since the 1990s. She Figure 14. Yue-Yo Wang used a combination of green
has created her own patented jewelry-making meth- jadeite and red coral in this necklace. The goldfish
symbolizes good fortune in Chinese culture, while a
pair of goldfish symbolizes everlasting marriage. The
Figure 13. Jadeite is one of China’s most treasured gem-
Chinese character between the two fish is a tradi-
stones. This ring by Yue-Yo Wang uses jadeite to por-
tional wedding symbol, while the boy and the lotus
tray the dragon and 18K gold for the phoenix. In
beneath them represent wishes for the family’s pros-
Chinese culture, the dragon and phoenix symbolize
perity. The immediate sense of perfect symmetry
man and woman, respectively. The dragon and phoenix
characterizes many of Wang’s designs. Photo courtesy
are seen rejoicing together in the sky, a scene that repre-
of Wang Yue-Yo Creative Jewelry Design.
sents the prosperity of a nation or a family. Photo cour-
tesy of Wang Yue-Yo Creative Jewelry Design.
ods while importing Western techniques. Zhang’s

small factory, Meiher Jewelry Styling Research Cen-
ter, performs every manufacturing step from design
to finished product. This allows Zhang to test and
develop new manufacturing processes.
These efforts proved worthwhile when Zhang’s
masterpiece, “Dancing on the Flowers” (figure 16),
won a special award at the 2012 National Gems &
Jewelry Technology Administrative Centre jewelry
design and manufacturing skills competition. The
suite, accented with bee and flower designs, in-
cludes a shoulder drape, a cuff bracelet, and a pair
of earrings. In Chinese culture, bees symbolize the
essential character trait of diligence. This design
competition was a salute to the accomplishments
of the Chinese gem and jewelry industry over the
previous 20 years, and Zhang used the bees to rep-
resent the industry’s diligent work. A variety of

links between the honeycomb cells, allowing the
piece to move freely and drape perfectly on the
wearer’s shoulder, giving the feeling of silk fabric
rather than gold. The wearer can also reshape the
piece by disconnecting and reattaching the links in
various combinations for versatility.
Another patented technique applied to this shoul-
der drape is the “honeycomb” setting of the colored
stones in the flowers, allowing more light to pass
through the stones. The color and setting are equally
attractive on both sides of the petals, resolving an
age-old design and setting challenge.
Zhang’s experience working overseas opened her
eyes to the Western jewelry industry and inspired her
to apply some of its methods. One example is her use
of plique-à-jour (figure 17). Developed in France and
Italy in the early 14th century, this technique differs
Figure 15. Independent jewelry designer Shirley from standard enameling in that the precious metal
Zhang’s creative philosophy rests on the belief that frames that contain the glass material have no back-
the piece must integrate craftsmanship and inspira- ing, allowing light to pass through. This creates the
tion. Photo courtesy of Shenzhen Meiher Jewelry, Ltd.
stunning effect of a miniature stained glass window
within a piece of jewelry. Plique-à-jour is commonly
applied to jewelry and pocket watches by Western
gemstones and setting techniques were applied. Of jewelers, including internationally known brands
these items, the shoulder drape is the most breath- such as Van Cleef & Arpels, Cartier, and Tiffany.
taking. It features patented “dumbbell” buckle Zhang and her team spent years researching and test-
Figure 16. Shirley

Zhang’s award-winning
jewelry suite “Dancing
on the Flowers” fea-
tures a total of 1,002
colored stones and
4,986 diamonds. Zhang
applied several of her
patented jewelry man-
ufacturing techniques
in its creation. Photo
courtesy of Shenzhen
Meiher Jewelry, Ltd.

Figure 17. This plique-à-jour pocket watch cover was
created by Shirley Zhang. Courtesy of Shenzhen Mei-
her Jewelry, Ltd.
ing this technique. Her company is now the only one

in mainland China that applies it to jewelry.
Zhang’s jewelry emphasizes the fine colors of the
gemstones, aiming for harmony. She also likes to co-
ordinate colors with different shapes or cultural
themes and to express her love of nature through her
designs. Her styles blend innovative craftsmanship
with oriental aesthetics, making use of unique com-
binations of materials and colors.
Figure 18. Jin Ren is also a jewelry design professor at
REAL JEWELRY AND REAL JOY China University of Geosciences in Beijing. Photo
In his 2011 book Luxurious Design: My Way of De- courtesy of RJ Jewelry Co.
signing Jewelry, Jin Ren (figure 18) shares the words
he lives by: “If you want a nicely designed ring, come
visit me.” If the whole luxury market is an ivory the time, he was a professor in the country’s only
tower, he believes that natural gemstone jewelry is gemological program. The turning point came in
the top of that tower and design is its structure and 1993, when a magazine invited him to write about
soul. The ring is one of the most common jewelry jewelry fashion trends. His reputation grew from
items but also the hardest to design, according to there, eventually providing a foundation for his own
Ren. He considers his work in ring design the major brand, RJ (Ren, 2011).
accomplishment of his career. One of the most fa- Along with his name, the RJ brand stands for “Real
mous jewelry designers in China, he is also a founder Jewelry and Real Joy.” He considers jewelry design a
of the School of Gemology at China University of matter of controlling shape, size, color, and dynamics,
Geosciences in Beijing and author of the first Chi- combined with a strong emphasis on culture (Ren,
nese jewelry design textbook. 2011). His designs combine traditional and contempo-
With a PhD in geology, Ren never expected that rary concepts, encompassing mechanical design tech-
one day he would co-host an haute couture show in niques and often reflecting a storyline that connects
Paris with world-class fashion designer Laurence Xu. one piece to another (figure 19).
When asked about his design education, Ren con- Ren and his friend Laurence Xu often get together
fesses that he barely had any. His career as a designer to discuss fashion trends and design ideas. Because
began purely by chance, starting just as the Chinese they share common interests, Xu invited Ren to be
gem and jewelry industry boomed in the 1990s. At the jewelry designer for his collection at Paris Haute

Figure 19. This suite with colorless, yellow, and black diamonds was inspired by snakeskin and its ability to be shed.
The earrings (left) depict the beginning of the shedding process, when the removal of old skin starts to expose the
new skin beneath it. The ring (center and right) represents the culmination, when the beautiful new skin is fully re-
vealed. Jin Ren considers this a metaphor for human beings, who must experience periodic transformations. Photos
courtesy of RJ Jewelry Co.
Couture in 2013. Xu’s majestic garments and Ren’s REVIVAL OF GOLD-JADE CULTURE
matched jewelry suites reflect their shared identity Jade-mounted gold jewelry has a long history in Chi-
and heritage (figure 20). nese culture, where gold represents splendor and jade
Ren says his themes come from outings with fam- symbolizes elegance. Chinese people use the relation-
ily and friends, where he is inspired by people, archi- ship between gold and jade to symbolize a happy mar-
tecture, movies, and ancient fairy tales (Ren, 2011). riage. For political and economic reasons, the market
His jewelry suite “Journey to the West” is based fairy for this type of jewelry was very limited for many
tale that is considered one of the four great master- years (“Revival of gold-jade culture…,” 2014). After
pieces of Chinese literature. Baroque pearls represent the jade-mounted 2008 Olympic medals were an-
the four main characters on their expedition to the nounced, the market sensed an opportunity to revive
West, including the famous Monkey King (figure 21). what is known as the gold-jade culture.
Their adventures are treasured childhood memories Shanghai jewelry designer Kaka Zhang’s interests
for almost every Chinese person. and talents encompass art, science, and business (fig-
Figure 20. This suite includes earrings and a

bangle inspired by the peacock, which is also
the theme of the gown. Carefully chosen tour-
maline, sapphire, topaz, tsavorite, and dia-
monds set in 18K white gold represent the
peacock’s feathers. Jin Ren designed the pieces
so that each feather moves freely. A 3 ct dia-
mond hidden under the bangle’s feathers can
be disconnected and worn separately. Photos
courtesy of RJ Jewelry Co.

Figure 21. Left: Jin Ren’s 2014 collection “Journey to the West” is based on the Chinese fairy tale of the same
name, as illustrated here. Right: Baroque pearls portray the master and his three disciples, capturing their essen-
tial qualities (clockwise from top left): Master Tang Sanzang’s mercy, the Monkey King’s boldness, Sha Wujing’s
honesty, and Zhu Bajie’s greed. Courtesy of microfoto (left) and RJ Jewelry Co. (right).
ure 22). She designs for the high-end, mid-range, and nese paintings (figure 23). She takes advantage of var-
commercial markets, using designs and jadeite qual- ious colors and patterns and is often inspired by the
ities to suit each market level. When she was three, jadeite carving itself. If its shape reminds her of
her father taught her painting. Her high school and something she has seen or heard—an old saying, a
university studies included science and technology poem, a scene, or a painting—she bases her design on
as well as gemology, leading her to a career in jewelry that theme (figures 24 and 25).
design and e-commerce. Jadeite is most often available as a carving whose
Ninety percent of Zhang’s business is on the In- beauty has been interpreted and revealed by the carver.
ternet, where she has a loyal and enthusiastic follow- The designer must consider the carving and envision
ing. She operates her design studio and website from the form or theme it will take. Although the gem can-
her home. Her jewelry is manufactured in Shenzhen, not be altered, the composition may be enhanced by
where skilled master jewelers turn her designs into precious metal craftsmanship and other elements to
finished pieces. express the theme in the designer’s inimitable style.
When Kaka Zhang purchased her first piece of Zhang believes that to achieve success, she must
jadeite jewelry as an adolescent, she never expected educate her customers about jewelry design, materi-
to become a designer in her own right. Along with als, and manufacturing. Her dream is to establish a
the highly desirable imperial jadeite, Zhang uses col- private jewelry club where she can create a relaxed
orless transparent jadeite, which has gained popular- environment and connect with each customer.
ity among young female consumers in the past
several years. THE FUTURE
Most of Kaka Zhang’s design inspirations come Over the past decade, Chinese jewelry designers have
from nature, also a major theme of traditional Chi- made great strides in matching the rapid growth of

Figure 22. Shanghai
jewelry designer Kaka
Zhang is devoted to re-
viving the gold-jade
culture. Photo courtesy
of Kaka’s Gem Eyes.
the domestic gem and jewelry market. Many are now Haute couture has a long history in China,
well-known internationally. As Chinese designers though it was once limited to the royal family and
continue to gain recognition, many more jewelry the highest social classes. The high-end design mar-
professionals will consider a future in design. ket has seen more progress than other market sec-
Native designers have come to understand that tors in the past decade. Now all top brands—and
they must take advantage of their common cultural even some independent designers and small-scale
background, drawing from the heritage of time-hon- stores—offer high-end custom design services. De-
ored craftsmanship and respect for the Chinese signers now focus more on catering to the main-
philosophical system. In the luxury market of the
future, uniqueness will surpass high value (Yang,
2014). Figure 24. This small jadeite carving reminded Kaka
Zhang of a fish. She designed a fishing pole and
breaking wave around that theme and called the
Figure 23. The hairpin was one of the most important piece “Fishing Fun.” One Chinese adage describes a
personal decorations for women of ancient China, famous intellectual fishing with no bait and the hook
and the butterfly is the traditional symbol of the loy- above the water. Rather than forcing things to hap-
alty of love. The dangling butterfly can be easily de- pen, the true intellectual “goes with the flow.” Many
tached and worn as a pendant. Photo courtesy of Chinese consider this the highest spiritual state.
Kaka’s Gem Eyes. Photo courtesy of Kaka’s Gem Eyes.

valued traditions. Leading jewelry enterprises are
improving commercial jewelry design, hopefully re-
sulting in more innovation in the near future. In
2013 and 2014, Rio Tinto launched a series of com-
mercial lines of its Argyle diamond jewelry in
China. Instead of marketing the diamonds them-
selves, Rio Tinto featured their commercial line de-
signers in promotions through multiple media
channels. The majority of them were young Chinese
designers.
Chinese designers, especially large brands, are
also making a global impact in the high-end jewelry
market. Two recent examples are Chow Tai Fook
Figure 25. Named “Beautiful Opera Singer,” this ring Jewellery Group’s purchase of the U.S. diamond
displays intricate metalwork resembling a style of hat
company Hearts on Fire and French luxury retailer
once worn by female Peking Opera singers. The
Kering’s acquisition of Chinese jewelry house
jadeite cabochon symbolizes the beauty of their faces
and the purity of their hearts. Photo courtesy of Qeelin. While Western brands have typically domi-
Kaka’s Gem Eyes. nated the market, Chinese brands have gained an in-
ternational foothold through their distinctive
design, cultural connotations, and fine craftsman-
stream commercial jewelry market by learning from ship. The influence of the “Chinese soul” goes both
the Western world while maintaining many of their ways.
ABOUT THE AUTHORS ACKNOWLEDGMENTS

Mr. Lucas is manager of field gemology and Ms. Chapin is The authors thank GIA for funding the trip to China. They are
managing editor for content strategy at GIA in Carlsbad, Califor- grateful for the assistance of Dickson Yewn, Shirley Zhang,
nia. Moqing Lin and Xiaodan Jia are gemologists at GIA’s Hong Jingyi Bai, Jin Ren, Yue-Yo Wang, and Kaka Zhang, who
Kong laboratory. agreed to be interviewed and provided their own photos as
well as jewelry pieces to photograph. Special thanks also go
to the designers’ assistants for facilitating this project.
REFERENCES
Adducci S. (2011) Contemporary Chinese jewelry. Departures, Chinese gem and jewelry industry. G&G, Vol. 50, No. 1, pp. 2–
http://www.departures.com/articles/contemporary-chinese- 29, http://dx.doi.org/10.5741/GEMS/50.1.2.
jewelry. Ren J. (2011) Luxurious Design: My Way of Designing Jewelry.
Chen W.H. (2014) Jewelry design contests. China Gems, Vol. 94, Zhejiang University Press [in Chinese].
pp. 24–29 [in Chinese]. Revival of gold-jade culture in the modern gem and jewelry indus-
Chinese jewelry firms design brighter future (2014) China Daily, try (2014) China Jeweler, http://biz.ifeng.com/zhubaowang/
October 3, http://europe.chinadaily.com.cn/epaper/2014-09/12/ zhubaohangye/tebiezhuanti/wdhjwzzhjzbzgf/detail_2014_06/09/
content_18587486.htm. 2400792_0.shtml [in Chinese].
Hofstede G., Bond M.H. (1988) The Confucius connection: From World Gold Council (2014) LoveGold meets Dickson Yewn. Love-
cultural roots to economic growth. Organizational Dynamics, Gold, http://www.lovegold.com/lovegold-meets/dickson-yewn.
Vol. 16, No. 4, pp. 5–21. Yang F. (2014) Haute couture of jewelry (in Chinese). China Gems,
Hsu T., Lucas A., Qiu Zh. L., Li M., Yu Q.Y. (2014) Exploring the Vol. 95, pp. 158–161.

First Place
SRI LANKA: EXPEDITION TO THE I SLAND OF J EWELS
SUMMER 2014
Andrew Lucas, Armil Sammoon, A.P. Jayarajah, Tao Hsu, and
Pedro Padua
Andrew Lucas is a field gemologist in GIA’s content strategy depart-
ment. He researches and documents the entire mine-to-market gem and
Andrew Lucas Armil Sammoon A.P. Jayarajah
jewelry industry for GIA education; he also presents seminars on col-
ored stones and diamonds. Armil Sammoon is the founder of the
Sapphire Capital Group and a member of the board of directors of the National Gem and Jewellery
Authority. A.P. Jayarajah is CEO of Wellawatta Nithyakalyani Jewellery and chairman of the Sri Lanka
Gem and Jewellery Association. Tao Hsu is the technical editor of Gems & Gemology and a contributor
to the Research and News section of GIA’s website. She received her doctorate in geology from the
University of Southern California. Pedro Padua is the senior video producer at GIA. He also contributes
to GIA website articles and educational course material. He received his master’s degree in communi-
cations from Loyola Marymount University. Pedro Padua
Second Place
EXPLORING THE CHINESE GEM AND J EWELRY
INDUSTRY
SPRING 2014
Tao Hsu, Andrew Lucas, Zhili Qiu, Mu Li, and
Qingyuan Yu
Tao Hsu and Andrew Lucas were profiled in the first-
place entry. Zhili Qiu is a professor in the earth science Tao Hsu Zhili Qiu Mu Li Qingyuan Yu
department of Sun Yat-sen University. Dr. Qiu received
his doctorate in geology from Zhejiang University and has been devoted to gemological research and
education since the early 1990s. Mu Li is the vice chairman of the Diamond Administration of China
(DAC). Qingyuan Yu is the colored stone director of a global mineral company in Guangdong, China.
Third Place
THREE-PHASE INCLUSIONS IN EMERALD AND THEIR IMPACT ON
ORIGIN DETERMINATION
SUMMER 2014
Sudarat Saeseaw, Vincent Pardieu, and Supharart Sangsawong
Sudarat Saeseaw is a senior manager of colored stones at GIA’s
Bangkok lab. She obtained a master’s degree in analytical chemistry
Sudarat Saeseaw Vincent Pardieu Supharart Sangsawong
from Mahidol University in Thailand. Vincent Pardieu is senior man-
ager of field gemology at GIA in Bangkok. He has led 64 successful
field expeditions to gemstone mining areas in order to collect samples for the GIA reference collection. Supharart
Sangsawong is a research scientist at GIA in Bangkok. He earned his doctorate in analytical chemistry from Mahidol
University.
Thank you to all the readers who voted. In additon to our winning authors, we
congratulate Richard Xu of Bakersfield, California, whose name was randomly drawn
from the entries to win a one-year subscription to G&G.
31OST VALUABLE
M Most Valuable
ARTICLE aArticle
WARD award GEMS
eMs & GeMoloGy
EMOLOGY 31
sprinG 2015
SPRING 2015
NOTES & NEW TECHNIQUES
AMETHYST FROM BOUDI, MOROCCO

Fabrizio Troilo, Abdelghani El Harfi, Salahaddine Mouaddib, Erica Bittarello, and Emanuele Costa
an off-road track to comply with environmental reg-

Amethysts from Boudi, Morocco, are character- ulations. This article focuses on the geological set-
ized by double terminations and hourglass- ting of the deposit and the gemological features of the
shaped color zoning. This study provides amethysts obtained from it.
information about the geology of the deposit, the
mining of the material, and its internal and exter- LOCATION AND ACCESS
nal features. Photos show the amethyst’s strong The village of Boudi (figure 2) is located in the arid
color zoning. Analysis of the needle-shaped min- Central Anti-Atlas mountain range, about 30 km
eral inclusions identified them as hematite, ori-
ented along the crystal’s growth direction.
Figure 1. The color zoning of amethyst from Boudi
often displays a characteristic hourglass shape. Photo
by Abdelghani El Harfi and Salahaddine Mouaddib.
F or 25 years, the Moroccan locality of Boudi in the

Tata province (part of the Guelmim-Es-Semara re-
gion) has yielded amethyst crystals that show double
termination and hourglass-shaped color zoning (fig-
ure 1). The deposit was discovered in 1990, and for
years the amethyst was extracted on a small scale by
local villagers using handheld tools. Only small
quantities were sold to tourists, and the low market
value limited production. The first foreign mineral
dealer to visit the location was Zee Haag in 2007.
These specimens debuted internationally at the 2009
Mineral & Gem show at Sainte-Marie-aux-Mines,
Europe’s second-largest mineral event. Since then,
dealers and collectors have visited the site, and the
deposit was featured in an extraLapis monograph on
amethyst (Praszkier and Rakovan, 2012).
In early 2012, the Geostone Group in Casablanca
obtained exclusive rights to the mine (an open
quarry, in accordance with Moroccan law). The com-
pany began production in early 2013, after building

32 NOTES & NEW TECHNIQUES GEMS & GEMOLOGY SPRING 2015

W 010° W 008° W 006° W 004° W 002°
M E D I T E R R A N E A N S E A
N 36°
Rif
A
T
A T L A N T I C O C E A N E
S
N 34°
Rabat
S E
A LA M
T
T A N
E A
Casablanca
S LE R
E D O
M ID
M
N
A
C
C
O
N 32°
R HIGH ATLAS
O Marrakesh Figure 2. This map
M shows the location of
the Boudi quarry (out-
lined in red), in the
Anti-Atlas mountain
range of Morocco. From
N 30° Faik (2005).
ANTI - ATLAS
OUGARTA
A L G E R I A
N 28° Continent
Orogens except Anti-Atlas system

T I N D O U F B A S I N
Paleozoic Cover of Anti-Atlas system
Basement inliners of Anti-Atlas system
Anti-Atlas Major Fault

REGUIBAT SHIELD
South Atlas Fault
northeast of the town of Tata. Boudi is accessed by fractured area crossed by hydrothermal veins. The
taking National Road 12 for 40 km, followed by a sin- host rock is siltstone-sandstone belonging to the Is-
uous 14 km road and a newly built off-road track for safen Formation of the Lower Cambrian, a schist for-
the final 4 km. The region is mountainous, with an mation composed of mudstone with marl and
altitude ranging from 1,400 to 1,800 m, and set in a sandstone intercalations in the upper zone, dolomitic
very arid and forbidding environment (figure 3). The limestones (with stromatolites) in the middle, and
mine is located 6 km east of the Tagragra Tata Pre- purplish red mudstones in the lower part, again with
cambrian basement, a kind of erosive depression on intercalations of stromatolitic limestones and dolo-
the crest of an anticline, similar to a tectonic win- stones, all of these in stratigraphic contact. In the
dow. Figure 4 shows a simplified geological map of simplified geological map, the Issafen Formation is
the region; amethysts are found in the Lower Cam- below the Schist-Limestone and Limestone series of
brian Issafen Formation (Faik et al., 2001; Faik, 2005). Lower Cambrian age, and thus is not visible (again,
see figure 4).
GEOLOGY AND MINERALOGY At Boudi, quartz is found either scattered in a silt-
The deposit is exposed along an eroded area on the sandstone matrix or within cavities of a complex
south side of an anticline formed by rock of Cam- fault and fractures system. Small openings are com-
brian age. It covers hundreds of square meters in a pletely filled with interlocking quartz crystals. In the
NOTES & NEW TECHNIQUES GEMS & GEMOLOGY SPRING 2015 33

Figure 3. The area near Boudi is arid and rich in geological features. Photo by Abdelghani El Harfi and
Salahaddine Mouaddib.
reddish mudstones, floating quartz specimens are al- and secondary. The authors hypothesize that the
ways found as single crystals without matrix, usually well-shaped quartz crystals originated in the faults
singly terminated but sometimes doubly. The and veins in the surrounding limestone, and then
amethyst clearly formed by hydrothermal deposi- eroded and redeposited in the residual mudstones.
tion, but the condition of the crystals suggests they
MINING
Conditions are challenging due to the location’s re-
In Brief moteness, the hot summer temperatures, and the
• Amethyst mined from Boudi, Morocco, features dis- lack of water and electrical power at the mine. Since
tinctive hourglass-shaped color zoning, double termi- the beginning of 2013, the open pit has been worked
nation, and red needle-shaped hematite inclusions. by an excavator and a loader that easily remove the
• These inclusions help to differentiate the formation fractured limestone and mudstone containing scat-
and the origin of the Boudi specimens. tered quartz crystals and fragments (figure 5). The
• Recent mechanized mining efforts have led to greater miners come from Boudi, Targuant, and other sur-
availability of gem-quality Boudi material, which rivals rounding villages, so the mine is an economic re-
“Siberian” amethyst in coloration. source for the area. Figure 6 shows a selection of the
production from the mine.
The quarried amethyst crystals vary in size, color,
and quality. Four-wheel-drive vehicles carry the pro-
were removed from the original site of crystallization duction to storage facilities. About 90% of the crys-
and subsequently encapsulated in the mudstones. tals are well formed and detach from the matrix as
The deposit could be regarded, then, as both primary individual crystals. High-pressure washing with a

SP Q Quaternary deposits
DLP
GLC “Grés terminaux” (Lower Cambrian)
N
SLC Schist-limestone (Lower Cambrian)
LLC Limestone (Lower Cambrian)
PLC PLC Pelite (Lower Cambrian)
SP Schist (Precambrian)
LLC DLP Dolomite-limestone (Proterozoic)
SLC
Fault
Extraction area
4 km
Q GLC
Figure 4. A simplified geologic map of the area hosting the amethyst quarry. The Issafen Formation lies below the
Limestone series of Lower Cambrian age and is not visible in the map. The red square indicates the mining area.
From Faik (2005).
brush and water gun removes the clays that cover the that characterizes the locality. Rhombohedral faces
crystals. Encrusted crystals are soaked for a short are well developed (figure 7). Euhedral crystals are
time in a mixture of diluted hydrochloric acid to dis- common, ranging from 1 to 10 cm in length and rarely
solve the residual limestone. up to 15 cm. The highest-quality material is in the 1–
5 cm range. The crystal faces are normally clean or
DESCRIPTION OF THE AMETHYST coated by carbonates and clay minerals.
Amethyst from Boudi displays a fairly typical mor- The color quality and distribution varies widely,
phology. The crystals have well-developed prism faces, from light purple to very deep purplish red, often
and in some cases they present the double termination showing sharp color concentration along the rhom-
Figure 5. The front of

the open quarry in
Boudi. Photo by Abdel-
ghani El Harfi and
Salahaddine Mouaddib.

Figure 6. The amethysts extracted from the piles are still
covered with matrix and carbonates. The well-shaped
crystals range from 2 to 5 cm in diameter. Photo by Ab-
delghani El Harfi and Salahaddine Mouaddib.
bohedral direction. The color concentration usually

resembles a core, beyond which the quartz becomes Figure 8. This suite of amethyst from Boudi, titled
colorless toward the surface. Abundant oriented, nee- “Purple Champagne,” received first place in the 2014
dle-like reddish inclusions are often found, mainly in AGTA Spectrum Awards, Pairs & Suites. Courtesy
of Ai Van Pham Gem & Gold Creations, Scottsdale,
Arizona.
Figure 7. This crystal from Boudi displays the classic
morphology of amethyst. Clearly visible is the habit
of the hexagonal prism and the two different rhombo-
the deeply colored stones. Color banding may also be
hedra (positive and negative). The hematite inclu-
sions, mainly oriented perpendicular to the surface of evident in the deeply colored core, mostly oriented
the prism, are clearly visible in the outer colorless parallel to the rhombohedral crystal faces.
portion. Photo by Abdelghani El Harfi and Sala- The purple coloration of amethyst is caused by
haddine Mouaddib. the presence of an interstitial Fe4+ color center in the
quartz (Rossman, 1994), combined with irradiation
from natural gamma-ray sources. Irradiation creates
color centers that absorb some light wavelengths and
produce the very attractive tone seen in this material.
The hourglass zoning distinctive of the Boudi mine
is created when the iron is incorporated preferen-
tially along the rhombohedral faces. During the
growth of the crystal, with the development of the
face, the purple sector assumes its typical form.
While most of the material produced is cabochon-
grade, a consistent percentage—maybe 20%—is suit-
able for faceting. Most of the rough shows color
zoning, which is often regarded as an unwanted fea-
ture but can be very attractive in the hands of skilled
and creative gem cutters. This was the case with an
award-winning suite recently cut from Boudi
amethyst (figure 8). Both cabochon- and facet-grade

20×–80× magnification. Inclusions were pho-
tographed with an Olympus BX41 microscope using
immersion techniques.
Chemical composition data were obtained with
semi-quantitative, non-destructive EDS microanalysis
for determination of major and minor elements. Micro-
Raman spectroscopy was used for mineral inclusion
identification purposes.
EDS data were acquired at Turin University’s De-
partment of Earth Science using a Cambridge Stere-
oscan 360 scanning electron microscope, equipped
with an Oxford Inca Energy 200 EDS for microanaly-
sis and a Pentafet detector and an ultrathin window
for the determination of elements with atomic num-
ber down to boron. All spectra were obtained at 15
kV accelerating voltage, 25 mm working distance,
and 1 µA probe current for 60 to 300 seconds. Pri-
Figure 9. This 22.5 ct faceted trilliant is from the
mary standardization was performed on SPI Supplies
Boudi quarries. Photo by Abdelghani El Harfi and
Salahaddine Mouaddib. and Polaron Equipment analytical standards. Daily
standardization was performed on a high-purity
metallic cobalt standard.
Unoriented micro-Raman spectra were obtained
material can display strong colors, and significant
at Turin University with a HoribaJobin Yvon LabRam
amounts of rough show a deep reddish purple color.
HRVIS apparatus, equipped with a motorized x-y
The best crystals exhibit purple flashes with a red
tinge. Faceting this deeply colored material can re- stage and an Olympus microscope. The backscat-
veal strong red overtones; these stones are known in tered Raman signal was collected with a 50× objec-
the trade as “Siberian” amethyst (Wise, 2005). Fine tive, and the Raman spectrum was obtained for a
stones larger than 20 carats are regularly faceted, but non-oriented position. The 632.8 nm line of a He-
most of the faceting material is in the 5–10 ct range. Ne laser was used as the excitation wavelength;
Cabochon-grade material up to 100 ct is common. To laser power was controlled by a series of density fil-
date, we have not seen heat treatment applied to ters. The minimum lateral and depth resolution was
amethyst from Boudi, which is rarely dark enough to set to a few µm. The system was calibrated using the
warrant it (Götze and Möckel, 2012; figure 9). 520.6 cm–1 Raman band of silicon before each exper-
imental session. The spectra were collected in 8 to
MATERIALS AND METHODS 10 acquisitions with single counting times ranging
between 40 and 120 seconds. Spectral manipulation
Gemological properties of 20 faceted amethysts sup-
plied by the Geostone Group were analyzed using such as baseline adjustment, smoothing, and nor-
standard gem testing instruments. The samples were malization were performed using the LabSpec 5 soft-
representative of the material produced from this lo- ware package (HoribaJobin Yvon, 2004 and 2005).
cality in both their color (light pinkish purple to dark For band component analysis, we used the Fityk
reddish purple) and size range (6.06–17.92 ct). software package (Wojdyr, 2010), which enabled us
Refractive indices and birefringence values were to select the type of fitting function and fix or vary
obtained with a standard refractometer and a near- specific parameters accordingly. The spectra were
monochromatic light source. Specific gravity was de- recorded for the 100–1300 cm–1 range using the Lab-
termined using a Mettler-Toledo hydrostatic meter. Spec 5 program.
Reactions to ultraviolet radiation were observed using
standard long-wave (365 nm) and short-wave (254 nm) RESULTS AND DISCUSSION
lamps. Visible absorption spectra were obtained with The refractive indices of the 20 amethyst samples
a Krüss prism spectroscope. Visual features were ob- from Boudi varied from 1.540 to 1.542 (o-ray) and
served using an SZM-2 zoom microscope from Gem- 1.549 to 1.552 (e-ray), with birefringence from 0.009
marum Lapidator with darkfield illumination at to 0.010. Pleochroism, observed with a calcite dichro-

Figure 10. This amethyst sample weighs 17.94 ct. Figure 11. Microscopic observation reveals the red
Clearly visible in the magnified inset is a veil consist- hematite inclusions. Photo by Emanuele Costa and
ing of one- and two-phase inclusions. Photo by Fabrizio Troilo, field of view 210 mm.
Emanuele Costa and Fabrizio Troilo.
scope, varied from weak to medium bluish purple to thetic amethyst, and their distribution and orientation
reddish purple. None of the samples showed any re- within the stone could help to identify their origin as
action to either short- or long-wave UV radiation. No the Boudi deposit. To the best of our knowledge, such
absorption spectra were observed using the Krüss inclusions have not been described in detail until now.
spectroscope.
Fluid inclusions with a veil-like pattern (figure 10)
were common in the amethyst samples from Boudi. Figure 12. A 9.14 ct faceted amethyst from Boudi dis-
Individual fluid inclusions sometimes showed a playing red hematite needle inclusions. Photo by
moderate negative crystal form. Some of these inclu- Emanuele Costa and Fabrizio Troilo.
sions had a two-phase character, with liquid and gas
components.
The red, elongated solid inclusions were also the
most interesting internal features and could be ob-
served in almost every specimen analyzed (figure 11).
The crystals’ near-colorless zones were permeated by
a series of fibrous red inclusions, approximately ori-
ented from the different crystal faces toward the col-
ored core, in which they gradually disappeared. The
orientation of the tiny fibers was not crystallographic,
but the general distribution of the fibers followed the
crystal growth direction (figures 12 and 13). The nee-
dles had different lengths, but their diameters were
quite consistent. Their microscopic appearance
showed a morphology that seemed less angular and
fragmented and more straight and continuous than
the hematite “beetle leg” inclusions (once believed to
be lepidocrocite) reported in the literature (Hyršl and
Niedermayr, 2003; Leon-Reina et al., 2011).
These inclusions distinguish the material from syn-

host quartz crystal) as well as iron, but it was impos-
sible to discriminate between various iron oxides and
hydroxides. Raman analysis (figure 14) showed a
close match between the obtained spectrum and
those of quartz (R040031) and hematite (R050333) in
the RRUFF database (Downs, 2006). Visible in detail
were the typical intense band of quartz around 467
cm–1 and weak broad bands at 132, 209, 359, and 811
cm–1. Additionally, the distinctive bands of hematite
inclusions were observed. The Raman spectrum
showed an intense band at around 299 cm–1, with a
weak shoulder at 302 cm–1; multiple bands at 231,
251, and 267 cm–1; medium-intensity bands at 413
and 619 cm–1; and weak peaks at 490 (a shoulder of
the most intense band of quartz), 664, 703, and 1160
cm–1.
Figure 13. This 14.30 ct sample, viewed in immer-

sion, clearly shows the distribution of the hematite CONCLUSIONS
inclusions, together with the uneven but distinct The Boudi quarry in the Anti-Atlas mountain range
zoning of the purple color. Photo by Emanuele Costa of Morocco was worked for more than 20 years in a
and Fabrizio Troilo. largely artisanal and sporadic manner. Since 2014,
mechanized mining has produced commercial quan-
The nature of the inclusions was confirmed by tities of amethyst for the jewelry industry. The de-
EDS and Raman analysis. The EDS spectra showed posit also yields amethyst with deep red tones that
only the presence of silicon and oxygen (from the rival the highly sought “Siberian” material (Wise,
Figure 14. This Raman spectrum clearly indicates the peaks of hematite in the quartz matrix.
RAMAN SPECTRUM
Quartz
15
INTENSITY (counts)
Hematite
10
Hematite
Hematite
5 Quartz
Hematite
Hematite Quartz
Quartz Hematite Quartz Hematite
200 400 600 800 1000 1200
–1
RAMAN SHIFT (cm )

2005). The color of the stones varies, but a consider- have distinctive red needle hematite inclusions, typ-
able quantity exhibits a deep purplish red color. ically observed in stones with deep color). Production
Moreover, singular internal features distinguish the is likely to expand, which means the gem market
material’s natural origin (about 50% of the stones could see more of this amethyst.
ABOUT THE AUTHORS ([email protected]) is researcher and professor in biominer-

Mr. Troilo is a geologist and graduate gemologist from the Istituto alogy and environmental geochemistry in the earth sciences de-
Gemmologico Italiano. He has published works about gemstone partment at Turin University.
mining abroad as well as gemstone deposits in the Alps. Dr. El
Harfi is professor of geodynamics in the geology department of ACKNOWLEDGMENTS
Ibn Zohr University in Agadir, Morocco. Mr. Mouaddib is CEO at The authors would like to thank the reviewers for their helpful and
Geostone Group in Casablanca, Morocco (www.moroccanfire. constructive observations and suggestions, and the Geostone
com). Dr. Bittarello is a PhD geologist graduate at Turin University Group for providing the samples used in this study.
in Italy and an expert in mineralogical analysis. Dr. Costa
REFERENCES
Anderson B.W., Jobbins E.A. (1990) Gem Testing. Butterworths, tion]. Version 5.64.15.
360 pp. Hyršl J., Niedermayr G. (2003) Magic World: Inclusions in Quartz.
Downs R.T. (2006) The RRUFF Project: an integrated study of the Bode Verlag, Haltern, Germany 240 pp.
chemistry, crystallography, Raman and infrared spectroscopy Leon-Reina L., Compana J.M., De la Torre A.G., Moreno R.,
of minerals. Program and Abstracts of the 19th General Meet- Ochando L.E., Aranda M.A.G. (2011) Powder diffraction analy-
ing of the International Mineralogical Association in Kobe, sis of gemstone inclusions. Powder Diffraction, Vol. 26, No. 1
Japan. O03-13. pp. 48–52, http://dx.doi.org/10.1154/1.3552672.
Faik F. (2005) Lithostratigraphie et structure de l’Anti-Atlas cen- Praszkier T., Rakovan J. (2012) Hourglass figures – Bou Oudi
tre-occidental : du rifting fini-protérozoïque a l’orogenèse her- amethyst. In H.A. Gilg, S. Liebetrau, G.A. Staebler, and T. Wil-
cynienne. Master’s thesis, Ibn Zohr University, Agadir, son, Eds., Amethyst: Uncommon Vintage, No. 16, Lithogra-
Morocco, 176 pp. phie, Ltd., Denver, Colorado, pp. 102–105.
Faik F., Belfoul M.A., Bouabdelli M., Hassenforder B. (2001) Les Rossman G.R. (1994) Colored varieties of the silica minerals. In
structures de la couverture Néoprotérozoïque terminal et P.J. Heaney, C.T. Prewitt, and G.V. Gibbs, Eds., Silica: Physical
Paléozoïque de la région de Tata, Anti-Atlas centre-occidental, Behavior, Geochemistry, and Materials Applications. Reviews
Maroc: Déformation polyphasée, ou interactions socle/couver- in Mineralogy, Vol. 29. Mineralogical Society of America. pp.
ture pendant l’orogenèse hercynienne? Journal of African Earth 433–468.
Sciences, Vol. 32, No. 4, pp. 765–776, http://dx.doi.org/10.1016/ Wise R.W. (2005) Secrets of the Gem Trade: The Connoisseur's
S0899-5362(02)00053-2. Guide to Precious Gemstones. Brunswick House Press, Lenox,
Gotze J., Mockel R (2012) Quartz: Deposits, Mineralogy and An- MA.
alytics. Springer, Berlin, 377 pp. Wojdyr M. (2010) Fityk: a general-purpose peak fitting program.
Horiba Jobin Yvon GmbH (2004, 2005) LabSpec [Software for Journal of Applied Crystallography, Vol. 43, No. 5, pp. 1126–
Raman spectroscopic data analysis, acquisition and manipula- 1128, http://dx.doi.org/10.1107/S0021889810030499.
For online access to all issues of GEMS & GEMOLOGY from 1934 to the present, visit:
gia.edu/gems-gemology

NOTES & NEW TECHNIQUES
VISIBLE ABSORPTION SPECTRA OF COLORED DIAMONDS

James E. Shigley and Christopher M. Breeding
tion) across a wide portion of the electromagnetic

Diamond color is usually the result of selective spectrum from the ultraviolet through the visible and
absorption of incident white light. The unab- into the infrared regions. There are, however, intrin-
sorbed portion of this light is transmitted through sic absorption features in the spectra of all actual di-
the diamond and is interpreted by the human vi- amonds. As discussed in our 2013 article, most
sion system as the perceived color. The spectro- diamonds also contain lattice defects which, in suf-
scope allows a gemologist to observe some of the ficient concentrations, can produce selective absorp-
more intense and narrower absorptions in the vis- tion of incident light. (In these instances, the lattice
ible spectrum of diamond as dark bands at spe- defects are often referred to as optical defects.) When
cific wavelengths. Yet the broader regions of white light strikes a polished diamond, some of the
absorption, which can be difficult to observe with light is reflected, while the rest enters the diamond
the spectroscope, often have a greater influence where it is refracted and dispersed based on wave-
on a diamond’s color. A chart has been prepared length. Some of the light energies (i.e., wavelengths)
to illustrate the visible spectra of various colored are absorbed by the defects, while the unabsorbed
diamonds as recorded at low (liquid-nitrogen) wavelengths are transmitted. When they exit the di-
temperatures with a spectrophotometer. The chart amond, these transmitted wavelengths in combina-
shows how similar diamond colors can result tion can create the sensation of color in the human
from different light absorption patterns. vision system (figure 1). Visible absorption spec-
troscopy is the analytical tool for understanding most
causes of diamond coloration.
At GIA’s laboratory, visible spectra of diamonds
I n 2013, the authors published a simple chart listing
the major optical defects that can occur at the
atomic lattice level in diamond (Shigley and Breed-
are recorded with a spectrophotometer. Since dia-
mond is optically isotropic, the same spectrum can
be recorded in any direction through the sample. The
ing, 2013). The chart presented some basic informa- faceted stone can be positioned in any orientation as
tion on those defects, including the ones responsible long as the light transmitted through it is sufficient
for the colors and ultraviolet fluorescence reactions to reach the instrument’s detector. The gem’s shape
of most diamonds. The brief article that accompa- and facet arrangement can make this a challenge,
nied the chart discussed the ongoing challenge pre- though. The best positions are those where the light
sented by the identification of natural, treated, and travels directly from the table facet to the culet, or
synthetic diamonds. It also discussed how spec- across the diamond through the opposing girdle
troscopy techniques, used to detect absorption and/or facets. The diamond is held in a cryogenic unit and
emission bands caused by those optical defects, play cooled to low temperatures with liquid nitrogen. Re-
a leading role in making this important determina- moving heat from the sample produces a less noisy
tion. GIA’s laboratory staff, which has the opportu- spectrum. Under these conditions, absorption fea-
nity to examine a large number of colored diamonds, tures that result from certain optical defects are
faces this identification challenge on a daily basis. stronger and sharper. Data collection conditions are
A theoretically pure and defect-free diamond selected to produce a spectrum that extends from
would be completely colorless, and a unique attrib- about 350 to 800 nanometers (nm).
ute would be its transparency (or lack of light absorp- Because of a polished diamond’s high refractive
index, light can be internally refracted a number of
times within it, so the total distance traveled cannot
be directly measured or calculated. This uncertainty
http://dx.doi.org/10.5741/GEMS.51.1.41. makes it difficult to relate the strength of the light ab-
© 2015 Gemological Institute of America sorption (as recorded by the spectrophotometer) to the

400 450 500 550 600 650 700
TRANSMISSION
ABSORPTION
400 450 500 550 600 650 700
WAVELENGTH (nm)
Figure 1. In most cases, transparent gemstones owe their color to selective absorption of light. In the case of a yel-
low diamond, the blue portions of the incident white light are absorbed by the diamond, while the remaining por-
tions in combination are transmitted to the eye and interpreted by our vision system as a yellow color. In the
spectroscope, this selective absorption is seen as a darkening toward the blue end of the spectrum (below 425 nm).
Recording the spectrum with a spectrophotometer produces a graph of wavelength (horizontal scale) versus ab-
sorption (vertical scale). Greater absorption is represented by the higher portions of the spectrum trace, and greater
transmission by the lower portions. Below 425 nm, the height of the spectrum trace increases. In the case of this
yellow diamond, superimposed on this increasing absorption are several sharp absorption bands or peaks on the
spectrum trace between 415 and 478 nm due to the N3 optical center. Gemologists often refer to this set of dark
bands as the “Cape” absorption lines characteristic of type Ia yellow diamonds.
path length of light traveled within the gemstone. Yet visible absorption spectra provide a tool to under-
this relationship can be estimated by comparing ab- stand most causes of diamond coloration.
sorption peak height to the heights of some intrinsic The accompanying chart contains representative
absorption features. This relationship also provides visible spectra and photos of the major color cate-
an indirect way of comparing the visible spectra of di- gories of diamond. The spectra are shown over the
amonds of different sizes and faceting styles. Because
of internal reflection and longer path lengths within
the polished diamond, the face-up saturation of the
color may appear stronger than the intensity of the
In Brief
absorption features (i.e., height of the absorption • While lattice defects and physical causes such as min-
bands) in the visible spectrum would suggest. eral inclusions may contribute to diamond coloration,
most color perception is due to the selective absorption
Natural diamonds occur in all colors of the spec-
of white light.
trum. A few colors, such as yellow and brown, are
• The accompanying reference chart details the effect
very common, but most are very rare. Nitrogen is the
of light absorption patterns, recorded with a spectro-
most widespread and abundant impurity element in photometer, on diamond color.
diamond. It can be present in several optical defects,
all of which produce absorption toward the blue end
of the spectrum. These factors help explain the
prevalence of yellow diamonds in nature. While the 400–750 nm wavelength range. Relative absorption
face-up appearance of colored diamonds is also influ- is shown on the vertical scale of each graph, with
enced by their size and the choice of faceting style, light absorption increasing higher on the scale (and,

conversely, light transmission increasing lower on since perceived color is a combination of the
the scale). Thus, the lower portion of each graph rep- wavelengths transmitted to the eye, different
resents the transmitted portion of the spectrum that absorption patterns can produce similar colors.
creates the material’s color sensation. The chart For example, type Ia and type Ib diamonds,
summarizes the major categories of colored dia- which have different visible spectra patterns,
monds; it is not intended as a detailed discussion of can both exhibit a yellow color (although the
diamond coloration. The graphs are grouped in color is usually more intense for the latter).
columns and ranked in descending order of fre- 4. Some diamond colors are the result of just one
quency. The colored diamonds included in the chart optical defect, while others result from more
were selected because their spectra (and color) are than one defect. For example, the chart indi-
principally the result of one main lattice defect. As cates that the GR1 defect can create a blue or a
discussed in our 2013 article, the cause of some de- green color. The defect alone produces a blue
fects is well understood, while others are not. We oc- color, but when there is also absorption toward
casionally encounter unusual colors in diamonds the blue end of the spectrum due to nitrogen
whose visible spectra do not correspond to any of the impurities, the resulting color is green.
categories shown on the chart. 5. Some diamond colors are simply the result of
The information presented on the chart suggests selective light absorption, while others stem
several observations: from a combination of light absorption and
light emission (or luminescence). For example,
1. In most cases, diamond colors result from dif-
certain greenish yellow diamonds are yellow
ferent absorption spectrum patterns, with each
due to absorption, while the green component
pattern originating from one or more optical
is due to luminescence.
defects. This can be seen for the different yel-
low diamonds shown in the first column. 6. Variations in the types of optical defects, and
in their relative concentrations, produce slight
2. Broad and intense spectral absorption features color variations among similar diamonds.
are more important in producing various colors
than sharp or weak bands. Conversely, sharp 7. Where a diamond photo is shown without an
absorption bands (such as the N3 observed at accompanying visible spectrum, the color is
415 nm, H4 at 496 nm, and H3 at 503 nm) that due to physical causes other than light absorp-
can be seen using the spectroscope are helpful tion—most often the presence of mineral inclu-
in gem identification. We used a spectropho- sions (e.g., numerous graphite inclusions
tometer to record the visible spectra, as it can causing black color in natural diamonds).
better capture broad absorption bands that are This chart is intended as a simple reference for
difficult or impossible to see with the eye those interested in understanding diamond col-
through a spectroscope. oration. While the visible spectra of diamonds are
3. Similar diamond colors can result from differ- often presented in the gemological literature, compi-
ent absorption spectra patterns. In other words, lations of spectra are rarely encountered.
REFERENCE
Shigley J.E., Breeding C.M. (2013) Optical defects in diamonds: A ABOUT THE AUTHORS
quick reference chart. G&G, Vol. 49, No. 2, pp. 107–111, Dr. Shigley is distinguished research fellow, and Dr. Breeding is a
http://dx.doi.org/10.5741/GEMS.49.2.107. research scientist, at the GIA Laboratory in Carlsbad, California.

CAUSES OF DIAMOND COLORATION
Yellow Green Blue/Gray/Violet Orange/Brown Red/Pink/Purple Other Colors
N3 and N2 Clouds of fine inclusions

“Cape” peaks (N3 and N2) General absorption H3 550 nm band 550 nm band
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
GR1 from boron impurities
(type IIb)
General absorption
from plastic deformation
400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750
WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm)
Nitrogen-vacancy defects Clouds of fine inclusions

H3 480 nm band
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
H3
GR1
H3 luminescence
400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750
WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm)
480 nm band
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
Hydrogen impurity defects
Hydrogen impurity defects
General absorption Example Visible Absorption Spectrum

from isolated nitrogen
impurities (type Ib)
400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750
WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) WAVELENGTH (nm) Absorption
ABSORBANCE (a.u.)
Clouds of fine inclusions Fractures filled with natural materials, usually iron oxide
General absorption
ABSORBANCE (a.u.)
ABSORBANCE (a.u.)
from isolated nitrogen

impurities (type Ib)
Nickel impurity defects
Transmission
400 450 500 550 600 650 700 750 400 450 500 550 600 650 700 750
WAVELENGTH (nm) WAVELENGTH (nm)
In most cases, transparent gemstones such as diamond with a spectrophotometer, and then depicting the spectrum
owe their coloration to selective absorption of light. With as a line on a graph. The peaks on the graph correspond 400 450 500 550 600 650 700 750
Hydrogen impurity defects a yellow diamond, the blue portions of the incident white to the dark lines or bands seen with the spectroscope.
ABSORBANCE (a.u.)
WAVELENGTH (nm)
light are absorbed by the diamond, while the remaining
portions are transmitted in combination to the eye and This chart illustrates representative visible spectra and
interpreted by our vision system as a yellow color. A photos of the major color categories of diamond. The
gemologist uses a spectroscope to detect this selective graphs are grouped in six columns and ranked in
absorption—the instrument separates light into its compo- descending order of occurrence. These colored diamonds
nent colors, and the portions of the spectrum that are were selected because their spectra (and colors) are prin-
absorbed as they pass through the gemstone appear as cipally the result of one main lattice defect (a disruption
400 450 500 550 600 650 700 750
dark lines or bands at particular wavelength locations. An of the atomic structure that causes selective light absorption This chart was published in conjunction with J.E. Shigley and C.M. Breeding, “Visible Absorption Spectra
WAVELENGTH (nm)
© 2015 Gemological Institute of America alternative method involves recording the absorption by the diamond). of Colored Diamonds,” Gems & Gemology, Vol. 51, No. 1, pp. 41-43.
FIELD REPORT
MOZAMBIQUE: A RUBY DISCOVERY FOR THE

21ST CENTURY
Merilee Chapin, Vincent Pardieu, and Andrew Lucas
T he Republic of Mozambique is located in south-

eastern Africa along the Indian Ocean. Separated
from Madagascar by the Mozambique Channel, it is Pemba
bordered by Tanzania to the north, South Africa to Montepuez
N
Namahumbire
the south, and Zimbabwe, Malawi, and Zambia to Namahaca
the east (figure 1).

0 150 mi
The country boasts rich resources of natural gas,
coal, titanium, and hydroelectric power. Agriculture 0 150 km
is also important to the economy and includes ex-

tensive production of cotton, cashew nuts, sugar- A F R I C A
cane, tea, manioc root, tapioca, fruits, potatoes, beef,
and poultry. Ruby mining is one of the newer eco-
nomic sectors, with major developments in the
northeastern part of the country in the mid to late
2000s. MOZAMBIQUE
The Montepuez ruby deposit was discovered in
May 2009 (Pardieu et al., 2009). Shortly thereafter, Maputo
thousands of miners, supported by foreign traders,

began to illegally work the area. This continued until
June 2011, with the formation of the Montepuez Figure 1. Mozambique, located in southeastern
Africa, is the world’s newest major ruby source. Its
Ruby Mining company (MRM), a partnership be-
ruby mines are concentrated in the country’s north-
tween Mozambique’s own Mwiriti Ltd. and the
eastern corner. Adapted from Hughes (2014).
multinational British gemstone mining company
Gemfields. MRM acquired a 25-year concession in
March 2012 and has expended considerable effort and
capital to improve the mine’s infrastructure, machin- MRM ruby deposit, as the entire inventory was the di-
ery, staffing, security, and public relations. rect result of the ongoing bulk sampling at Mon-
While the public is generally unaware of Mozam- tepuez. This bulk sampling will guide further
bique as a ruby source, the deposit near Montepuez is development of large-scale mine operations.
considered by the trade to be the world’s largest sup- The company employs about 400 people at the
plier. Gemfields’ first Mozambique ruby auction took mine, plus another 300 contractors. Along with ex-
place in Singapore in June 2014, marking a milestone perienced personnel imported from other countries,
for the global trade (figure 2). The US$33.5 million rev- the company also trains Mozambican locals, who
enue generated by the auction put the spotlight on the make up the vast majority of the workforce, to attain
high skill levels.
In September 2014, GIA researchers Tao Hsu, Vin-
See end of article for About the Authors and Acknowledgments. cent Pardieu, and Andrew Lucas visited the Mon-
Note: The full version of this article was originally published as Hsu et tepuez ruby deposit (figure 3). Hosted by MRM, the
al. (2014).
expedition’s purpose was to witness the evolution
http://dx.doi.org/10.5741/GEMS.51.1.44. and operation of this major deposit and to gather re-
© 2015 Gemological Institute of America search samples for study by GIA’s laboratory.
44 FIELD REPORT GEMS & GEMOLOGY SPRING 2015

Belt (figure 4). Both are “treasure-bearing” Neoprotero-
zoic (approximately 500–800 million years old) oro-
genic belts within the global Pan-African tectonic
framework. Several major geologic complexes are sep-
arated by major thrusts and shear zones. Complex
thermal and deformational events provided ideal tem-
perature and pressure for the formation of ruby, garnet,
and other minerals of economic importance.
The Montepuez ruby mine lies about 150 km
west of the beautiful coastal city of Pemba (again, see
figure 1). It is located within the wedge-shaped Mon-
tepuez Complex (Boyd et al., 2010). Its mineral as-
Figure 2. The large amount of ruby produced by MRM semblages indicate that the whole complex
allowed Gemfields to offer goods in a wide variety of underwent amphibolite-grade metamorphism, gen-
qualities at their 2014 Singapore auction. Photo by erally at a pressure of 0.4–1.1 GPa and a temperature
Andrew Lucas/GIA. of 550–750°C.
Ruby forms only within a very limited range of
pressure and temperature conditions, and only in the
AREA GEOLOGY presence of a sufficient supply of aluminum,
Northeastern Mozambique is located at a geologically chromium, and oxygen. Around Montepuez, ruby
critical junction between the north-south trending formation seems to have resulted mainly from a
Mozambique Belt and the east-west trending Zambezi metasomatic process, when fluid derived from the
Figure 3. The GIA team that visited the Montepuez ruby deposit in September 2014 consisted of (left to right) Tao
Hsu, Vincent Pardieu, and Andrew Lucas. Photo by Stanislas Detroyat.
FIELD REPORT GEMS & GEMOLOGY SPRING 2015 45

40° A F R I C A
N Palma
11° 11°
39°
MOZAMBIQUE
Mucda Figure 4. The Mon-

tepuez ruby deposit is
MAIN GEOLOGICAL UNITS at the geologically criti-
12° 12° IN NORTHEASTERN MOZAMBIQUE
cal location between
Marrupa Complex two large tectonic
Karoo Supergroup structures along two di-
Intrusions of Mesozoic to
Neoproterozoic age rections at right angles
Nampula Complex to each other. Adapted
Recent to Palaeogene from Boyd et al. (2010).
sediments
Pemba
13° 13° Meluco Complex
Montepuez Ruby Deposit Lalamo Complex

worked by
MRM Nairoto Complex
Xixano Complex
Montepuez Complex
Ocua Complex
39° 40°
parental magma interacted with the host rocks in a all scales, later cut by a number of shear zones trend-
low-silica environment. ing northeast to southwest.
The Montepuez operation consists of mostly sec- The MRM concession is located on one limb of a
ondary deposits, with only one primary deposit ex- fold with a subvertical axial plane striking east-west.
posed so far. The composition of the rocks in the At least four different deformation phases occurred in
Montepuez complex ranges from granitic to amphi- this area. The strong deformation history complicated
bolitic, while quartzite and marble can be found in- the rock units on all scales, making the exploration
side and outside the concession property. The rocks and prediction of the primary ore very complex.
are also strongly folded into tight isoclinal folds on The pit walls in Maninge Nice, where the only
Figure 5. Left: A clear contact between the topsoil and the ruby-containing amphibolite can be found on the walls
of the primary deposit pit. Photo by Andrew Lucas/GIA. Right: The top of the ruby-containing layer has been ex-
tensively weathered, and the rock is very fragile. Photo by Vincent Pardieu/GIA.

Current
channel
Paleo
channel
Ruby traps
Rub
Ruby traps
Figure 6. Left: River channel morphology changes constantly over time. Center: Rubies are trapped and concentrated
in certain areas along those channels. Right: Cross-sections of former river channels can be seen in the wall of pit 3.
Photo by Andrew Lucas/GIA.
primary deposit discovered so far is located, show an channels are quite recognizable and easy to work.
obvious contact zone between the topsoil and the MRM targets these as well as the richest paleochan-
weathered ruby-containing amphibolite, which is nels, where large reserves of fine rubies are buried.
very fragile and easily crumbled by hand (figure 5). Pit 3, the largest being worked by MRM, is lo-
Ruby is found in close association with white cated along one of the main paleochannels. On the
feldspar, mica, and dark green amphibole. Core wall of this pit, observers can see some superb cross-
drilling data indicate that the amphibolite extends sections of former river channels (figure 6, right).
about 30 meters below the surface and lies on top of Gravel size increases visibly from the edge to the bot-
the basement gneiss. The whole amphibolite unit tom of these “traps,” where gravity caused heavier
strikes roughly east-west. gravels to settle and concentrate at the bottom of a
Hundreds of millions of years of erosion have depression.
made the secondary ruby deposits in Montepuez far Larger gravels are better at slowing the water
easier to uncover and work than the primary de- speed. Since the specific gravity of ruby is relatively
posits. Rubies liberated from the host rock were high, it tends to settle along the bottom of a depres-
transported and concentrated by water and eventu- sion with other heavy minerals.
ally settled in the alluvial, colluvial, and eluvial de- Heavy mineral traps occur at different places
posits being worked today. along the river channel, wherever the water current
slows. The traps themselves work as natural jigs,
PALEOCHANNELS AND RUBY TRAPS usually leaving a higher concentration of ruby at the
Cycles of weathering and erosion are constantly bottom of the trap. These ruby “traffic jams” are
shaping the surface of the earth. Once the ruby-bear- ideal locations for gem hunters.
ing rock is weakened and broken down by physical Since there are numerous granitic rocks in the area,
and chemical weathering, it is ready for erosion. In the gravels are mainly quartz crystals and aggregates
Montepuez, rubies and other minerals liberated from of different sizes. Their shape and sharp corners indi-
the parent rocks were picked up and carried by water cate that they were not transported very far from their
and, due to their high specific gravity and hardness, source rocks. The focus of secondary deposit explo-
trapped and concentrated in certain locations along ration is to find old stream channels and better define
current or former river beds, above the weathered the distribution of this ruby-bearing gravel layer.
basement rocks.
River channel morphology has also changed con- THE MINE
stantly over time. Hundreds of millions of years ago, The MRM concession encompasses roughly 400
the stream channels were at different positions; square kilometers, with both primary and secondary
traces of their original flows are known by geologists deposits. Most of the bulk sampling takes place at the
as “paleochannels” (figure 6). secondary deposits, but sampling is planned for both
The concession has a well-developed drainage sys- types within the current fiscal year. The only area
tem. The local topography causes the water to flow with a primary deposit as well as secondary gravels is
generally from north to south. Present-day stream Maninge Nice, a local name given because of the

fractured and included stones were ground into sand
by weathering. In the secondary deposits, everything
above the gem-bearing gravel is overburden. MRM
samples the gravel down to bedrock, often using two
excavators—one to strip the overburden down to the
gravel and the other to load the gravel into trucks that
take it to the processing plant (figure 9).
The long-term bulk sampling strategy at the sec-
ondary pits is dictated mostly by the geology. MRM
opened several bulk sampling locations based on ex-
ploratory auger drilling and on small 50 × 50 meter
pits that all follow a single paleochannel. In one area,
the company plans to merge several pits at some
point, forming a massive operation along the pale-
ochannel. The paleochannel in this area is approxi-
Figure 7. This photo shows the bulk sampling pit in
Maninge Nice. The greenish layer is the weathered
mately 4.5 kilometers in length, and the width of the
ruby-bearing amphibolite, and the contact between pits varies from 50 to 150 meters. The large pit con-
the topsoil and the amphibolite is visible. Photo by necting them is about 2.5 kilometers long, and is ex-
Vincent Pardieu/GIA. pected to become longer. The end result will be a
massive colored gemstone pit-mining operation.
MRM conservatively predicts the removal of 1.7
“nice” stones that have come from there (figure 7). million tons of potentially gem-bearing gravel from
Another major bulk sampling area is Mugloto. Pit the pit along this paleochannel. This will involve the
3 is in an area of Mugloto called Mashamba, a local handling of 15 million tons of rock. At the time of
name for the maize once farmed on the site (figure our visit, MRM was using four excavators, and an-
8). Pit 5 is in an area called Mercado, which means other two were scheduled to arrive shortly. This will
“market” in Portuguese, as it was once an illegal allow more pits to be sampled simultaneously, the
miners’ market. doubling up of excavators in pits identified as crucial,
and the starting of new pits.
BULK SAMPLING METHODOLOGY As primary deposits go, the one at Maninge Nice
Secondary deposits host a concentration of fine stones. is relatively easy to sample. The host rock is soft,
They are fairly easy to sample because most of the weathered amphibolite, so removing it is not difficult
Figure 8. The main

bulk sampling pit in
the Mugloto area is the
most productive pit by
value. Photo by Stanis-
las Detroyat.

Figure 9. In the second-
ary deposit at pit 3, ex-
cavators and trucks
work together to strip
the overburden, load
the ruby-bearing gravel,
and transport it to the
washing plant. Photo by
Vincent Pardieu/GIA.
or destructive to the crystals. This type of weathered workers. From setting up the machine to refilling the
rock offers a tremendous advantage in keeping costs borehole, it takes about an hour to finish one spot. The
down and production high. Still, future sampling at goal is to finish eight to nine drill holes each day. The
the MRM concession will likely involve the extrac- sites are cleaned and prepared before the drilling starts.
tion of more primary rock at greater depths, increas-
ing the challenge.
Figure 10. Workers remove the soil and gravel that
FURTHER EXPLORATION come up with the auger and then dump the material
into a container for further processing. Photo by An-
The current bulk sampling and resource analysis drew Lucas/GIA.
stage is scheduled to be completed in 2016, which
should give a clearer picture of the potential produc-
tion figures and life of the mine.
Primary and secondary deposits require different
drilling methods and strategies. The goal of second-
ary deposit exploration is to better define the distri-
bution of the ruby-bearing gravel layer in the
concession. Contours of the gravel layer will be con-
structed from this, as well as data on the concentra-
tion of rubies.
Auger drilling, a method not typically seen by GIA
researchers, is used to explore the secondary deposits.
The auger consists of a rotating helical screw driven
into the ground. The screw blade is shaped to lift
earth up from the borehole. As earth is pulled out of
the hole, workers remove the loose gravel from be-
tween the drill blades (figure 10). This is different
from core drilling, which removes solid or fragmented
cores from hard rock. Auger drilling is considered an
efficient way to explore soft unconsolidated material
or weak weathered rocks.
Gemfields’ geologists have divided the target area
into blocks and plan to drill boreholes in 100-meter
grids. The drill bits and other equipment are hauled
by truck to drilling sites. Every exploration team is
composed of a geologist, a technician, and four or five

sites with strong potential. Sampling the topsoil also
gives the geologists a good idea how much waste
they will need to remove before reaching the ore-
containing gravel layer.
To obtain a representative sample, each meter of
earth removed from the drill bit above the ruby-
bearing gravel layer is thoroughly mixed, and then
50–100 grams of sample are taken for geochemical
analysis to quantify certain elements. The results
will guide further exploration and evaluation.
At the gravel layer, the drill removes 10–20 kilo-
Figure 11. The soil and the gravel are sampled at grams of ruby-bearing gravel, which is bagged and
every meter until the drill strikes bedrock. The ma- transported back to the washing plant and the sorting
chine will continue another meter or two to finish the house for processing to get a rough estimate of ruby
sampling. Photo by Andrew Lucas/GIA. concentration (figure 12). The top one to two meters
of basement rock are also washed to minimize the
risk of losing rubies. The leftovers from all samples
From ground level, the drill removes one meter are carefully stored for future reference. The process
of earth with every sampling until it hits the base- is completed by refilling the drill hole in an environ-
ment rock, where it will continue removing two to mentally responsible manner.
three meters of rock before it stops (figure 11). The Ultimately, understanding the geology of the pri-
average depth of the drill holes is about eight me- mary deposit is the key to sustaining a profitable
ters, and the team’s goal is to finish about 70–80 mine. Geologists use geophysical tools to locate the
meters of drilling each day. MRM runs two shifts host rock, targeting related amphibolite and mag-
per day. matic intrusions.
Drilling results will indicate the depth and thick- Different mineral assemblages in rocks give off
ness of the ruby-bearing gravel layer at each location. distinct magnetic signatures that can be displayed by
After thousands of drillings are done, a contour map a detailed magnetic scan. The results are used to
will be constructed to show the depth and thickness model the distribution of certain rock types. Amphi-
of the area’s gravel bed. Prior to our visit, auger bolite usually gives a high magnetic anomaly that is
drilling had already helped delineate the aforemen- easily distinguished from other rocks in the area. A
tioned 2.5 km paleochannel, as well as many other high-resolution magnetic survey helps geologists
form a map pinpointing the location of the amphibo-
Figure 12. These bags of gravel layers will be transported lite. Next, a radiometric survey on uranium, tho-
to the washing plant and then to the sorting house. This rium, and potassium is performed to detect the
will give a reasonable estimation of ruby concentration. alkaline magmatic intrusions in the area. Further ex-
Photo by Andrew Lucas/GIA. ploration plans are based on these results.
The current exploration of the primary deposit in-
volves extensive core drilling around the exposed
Maninge Nice area (figure 13). The goal is to better
define the distribution of ruby-bearing amphibolite
below the surface. Each drilling extends about 50 me-
ters deep and takes one week to finish, at an average
rate of 10 meters per day. Drill bits coated with syn-
thetic diamond are used to sample the rock at every
meter. Drill sites are positioned every 100 meters un-
less more lithological variation is observed, in which
case the distance is shortened to 50 meters.
Through extensive core drilling, the geologists
have made some important underground discoveries.
Each core starts with the loose topsoil, which is
bagged. The ruby-bearing amphibolite is usually

Figure 14. Ruby is contained in the amphibolite,
which is not weathered and very hard to break. Photo
by Andrew Lucas/GIA.
The actual recovery of ruby in the secondary de-

posits is more difficult to predict. The amount of
ruby per ton can vary dramatically, and so can the
quality of the rubies recovered. For example, the re-
covery rate in Mugloto pit 3 is relatively low: 0.60–1
gram per ton of ore processed. Yet the pit yields high-
quality ruby, making it economically advantageous
to sample, even with the low recovery rate. This pit
also produces some large rough crystals of 6–8 grams.
Figure 13. The setup of the core-drilling instrument. For comparison, Maninge Nice has a higher recovery
Water from a tank next to the working platform is rate of 20–35 grams per ton, but generally produces
run the whole time to cool the drill bit. Photo by An- much lower-value material.
drew Lucas/GIA. Overall, the recovery rate for the primary deposit
is around 162 carats per ton, while the secondary de-
posits produce 31 carats per ton. The figure for the
found at a depth of 10–30 meters, gradually becoming secondary deposits includes only processed gravels
granitic gneiss, the basement rock in the area (figure and not the amount of overburden topsoil moved.
14). The exploration team drills down into the base-
ment rock as well to see if the amphibolite repeats. WASHING AND SORTING
Sometimes they discover a secondary ruby-bearing The Montepuez processing plant (figure 15) is organ-
gravel bed above the primary deposit. ized into four major areas: (1) dry screening; (2) dis-
In addition to the amphibolite, which contains integration with a log washer, where the removal of
various concentrations of rubies, two marble bodies waste particles begins; (3) wet screening; and (4) siz-
north of Maninge Nice have been defined. No rubies ing and concentration. In an auxiliary section, water
were found in the marbles, however. A detailed re- is held in a reservoir and cleaned for use in washing.
port on the primary deposit will be submitted to The washing process uses two screening systems
MRM in 2016. and two jig systems, both of which separate the ma-
terial by size (figure 16). The jigs have a batch system
PRODUCTION where any overflow from the first upper-level jig is
As part of its bulk sampling operation, MRM has retrieved by the lower-level jig. The 150 tons washed
handled around 1.8 million tons of rock at Mon- per hour deliver concentrated gravel containing var-
tepuez, recovering approximately 8 million carats of ious amounts of corundum rough.
ruby and sapphire of various colors. The company Suction hoses pull the gravels from the jigs into
hopes to double its capacity to 3.6 million tons of canisters. Then the gravels are poured into bags and
rock in 2015 and eventually increase that figure to taken to the sorting house. The concentrated gem
10 million tons of rock a year. gravels are loaded into the back portion of a sorting

Figure 15. After the gravel passes through a grating, Figure 17. The first step of sorting is to separate ruby
conveyor belts carry it through the washing stages and garnet from the washed gravel. Sorters do not
until the ruby is finally trapped by the sluices. Photo touch the gravels with their hands. Instead, they
by Vincent Pardieu/GIA. wear rubber gloves attached to cloth sleeves. Photo
by Andrew Lucas/GIA.
box, a rectangular case with an angled glass window and the corundum crystals are cleaned and sorted.
for viewing. This is the beginning of the process of The rough is divided into dark and light tones, repre-
separating ruby from the gravels and garnets. senting ruby and pink sapphire, respectively. The ru-
To reduce the possibility of theft, the sorters never bies are then classified into four further categories:
actually touch the rubies. They wear sleeves with rub- premium, facet-grade, translucent to opaque, and
ber gloves attached (figure 17). They drop the retrieved basic corundum.
stones into two holes, one for garnets and the other The grading of the premium ruby rough is done in
for corundum. The sorters base the identification on an adjacent room, first by color and then clarity. White
visual appearance, especially crystal morphology. tables provide the background, while windows just in
Next, a senior staff member and a member of the front of the graders provide ample daylight for color
security team unlock the box holding the gemstones, grading. The Gemfields ruby grading system is based
on the rough’s size, color, shape, and clarity (figure 18).
Figure 16. Two sluices, or jigs, are used for different-sized
gravel. The heavier material is trapped in the grooves of PRELIMINARY GEMOLOGY
the jig, while other material goes into the piles in front. Rubies from Montepuez are very important to the
Photo by Vincent Pardieu/GIA. trade because of the large quantities and the wide
range of qualities and sizes produced. Their colors
bridge the gap between those from the classic sources
of Burma (highly fluorescent, with low iron content)
and Thailand/Cambodia (weakly fluorescent, with
high iron content).
Rubies owe their red color to chromium, but their
color is modified by the presence of iron, which re-
duces the chromium-caused fluorescence. An interest-
ing aspect of rubies from the amphibole-related deposit
near Montepuez is their iron content, which ranges
from nearly as low as Burmese marble-type rubies to
as high as rubies found in basalt-related deposits along
the Thai-Cambodian border. This means they have the
potential to suit a range of different markets.
A small but significant percentage of the material
has a combination of color and clarity that requires no

from Maninge Nice looks purplish red to red. Rough
rubies from other areas tend to be darker and more
brownish or orange. They generally have higher iron
content—similar to Thai/Cambodia rubies—than the
samples from Maninge Nice.
Rough rubies from Montepuez are mostly tabular.
Specimens from the primary deposit are usually more
euhedral, but also more fractured, and contain amphi-
bole and mica inclusions (figure 19, left). Rough from
the secondary deposit is generally more tumbled,
more transparent, and less included (figure 19, right).
While there are some exceptionally large stones
over 100 ct, most of the unheated faceted rubies from
Montepuez are under 3 ct. Faceted stones over 10 ct
were seen at the Bangkok and Hong Kong shows in
September 2013. With their even coloration, high
Figure 18. Top-grade ruby rough from Montepuez. transparency, and good luster, unheated rubies from
Photo by Vincent Pardieu/GIA.
Montepuez are very suitable for calibrated cuts.
heat treatment. Others lack transparency due to fis- COLLECTING REFERENCE SAMPLES
sures or the presence of inclusions. Heat treatment GIA’s Bangkok lab has been collecting reference sam-
transforms this lower-quality material so it can find a ples and mining information from sources since
market within the jewelry industry. Lead-glass filling 2008. A study of the gemological characteristics of
is used for heavily fractured stones, while more tradi- 131 ruby samples from Mozambique was completed
tional heat treatment (with or without borax-like ad- by the laboratory and published by Pardieu et al.
ditives) is performed on less-fractured stones with a (2013). Studies of inclusions and chemical composi-
milky or silk-like appearance (Pardieu et al., 2010). tion are in progress, and the results will be presented
Overall, treated products are much more readily avail- in future articles. The team’s current main focus is
able than unheated material (Scarratt, 2012). to collect and study ruby, sapphire, and emerald ref-
Each of Montepuez’s bulk sampling areas yields ru- erence samples following GIA protocols.
bies with slightly different appearances. The material At Maninge Nice, the team was allowed to search
Figure 19. Left: Rough rubies from the primary deposit at Maninge Nice have sharp edges and corners. Their color
is brighter because they contain less iron than other deposits in this area. Right: Classic secondary-deposit rubies
from the Mugloto area. Most are tumbled and clean from millions of years of weathering and erosion by the rivers.
The darker color is caused by their higher iron content. Photos by Vincent Pardieu/GIA.

Figure 20. Expedition
guest Stanislas De-
troyat and Vincent Par-
dieu collect samples on
the ground at Maninge
Nice under the supervi-
sion of Gemfields secu-
rity guards. Photo by
Andrew Lucas/GIA.
the ground under the supervision of company security because they are “type A” samples. This means they
guards (figure 20). The host amphibolite was highly were obtained directly from the rock by the gemolo-
weathered, making it very easy to extract the rubies gists themselves. Samples that are collected by the
from the host rock. Using rock hammers, the team col- miners but not under the direct supervision of GIA
lected a fair number of high-quality samples that met researchers are classified as “type C” samples. These
the requirements for lab preparation and analysis. valuable reference samples will be important addi-
The specimens collected are especially valuable tions to the GIA reference sample database.
REFERENCES
Boyd R., Nordgulen Ø., Thomas R.J., Bingen B., Bjerkgård T., (2009) Expedition report to the ruby mining sites in northern
Grenne T., Henderson I., Melezhik V.A., Often M., Sandstad J.S., Mozambique (Niassa and Cabo Delgado provinces).
Solli A., Tveten E., Viola G., Key R.M., Smith R.A., Gonzalez http://www.gia.edu/gia-news-research-NR121709
E., Hollick L.J., Jacobs J., Jamal D., Motuza G., Bauer W., Daudi Pardieu V., Sturman N., Saeseaw S., Du Toit G., Thirangoon K.
E., Feitio P., Manhica V., Moniz A., Rosse D. (2010) The geology (2010) FAPFH/GFF treated ruby from Mozambique: A prelimi-
and geochemistry of the East African Orogen in northeastern nary report. http://www.giathai.net/pdf/Flux_heated_and_glass
Mozambique. South African Journal of Geology, Vol. 113, No. _filled_rubies_from_Mozambique.pdf
1, pp. 87–129, http://dx.doi.org/10.2113/gssajg.113.1.87. Pardieu V., Sangsawong S., Muyal J., Chauviré B., Massi L., Stur-
Hsu T., Lucas A., Pardieu V. (2014) Mozambique: A ruby discovery man N. (2013) Rubies from the Montepuez area. GIA News
for the 21st century. GIA Research & News, www.gia.edu/ from Research, http://www.gia.edu/gia-rubies-from-mon-
gia-news-research-mozambique-expedition-ruby-discovery- tepuez-area.
new-millennium. Scarratt K. (2012) A discussion on ruby-glass composites & their
Hughes R. (2014) Ruby & Sapphire: A Collector’s Guide. Gem and potential impact on the nomenclature in use for fracture-filled
Jewelry Institute of Thailand, Bangkok. or clarity enhanced stones in general. http://www.giathai.net/
Pardieu V., Jacquat S., Senoble J., Bryl L.-P., Hughes R., Smith M. pdf/Ruby-Glass_Composites.pdf.
ABOUT THE AUTHORS ACKNOWLEDGMENTS

Merilee Chapin is managing editor of content strategy at GIA in The authors gratefully acknowledge the assistance provided by
Carlsbad. Vincent Pardieu is senior manager of field gemology at Gemfields and MRM personnel, including Ian Harebottle, CEO;
GIA in Bangkok, and Andrew Lucas is manager of field gemology Adrian Banks, product director; Ashim Roy, head of geology and
for content strategy at GIA in Carlsbad. exploration; Raime Raimundo Pachinuapa, executive director;
Sanjay Kumar, project manager; Philippe Ressigeac, assistant
product manager; Mohun Raman, head of security; and Angus
Barthram, logistics manager.

RESEARCH AND NEWS
Visit G&G online to explore free multimedia content. Scan the QR codes
with your smartphone or tablet, or enter the links below.
Brazil: Explore Brazil’s emerald and tourmaline mines and follow

the production of the gems step by step. Exclusive videos and
slideshows highlight the fascinating discoveries.
www.gia.edu/gia-news-research-an-overview-of-2014-gia-brazil-
expedition
Zambian Emeralds: Documents the mining and gemological

characteristics of emeralds from Kagem, the world’s largest
emerald mine.
www.gia.edu/gia-news-research-kagem-emerald-mine-zambia
LA Museum of Natural History: A rare behind-the-scenes look at

the outstanding gem and mineral specimens in LA’s Natural
History Museum, featuring insight from the museum’s curators.
www.gia.edu/gia-news-research-natural-history-museum-los-
angeles-county
Botswana's Scintillating Moment: Discover more about

Botswana’s strategies and challenges as it develops a thriving
diamond and jewelry industry.
www.gia.edu/gems-gemology/summer-2014-weldon-botswana-
scintillating-moment
Gemological Field Expeditions: GIA’s Andy Lucas and Vincent

Pardieu discuss the challenges and rewards of gemology
fieldwork. Contains slideshows from local mines and markets.
www.gia.edu/gia-news-research-behind-scenes-gemological-
field-expedition
Chinese Gem and Jewelry Industry: The authors explore the

development, impact, and future of China’s domestic and
international gemstone and jewelry market. Includes artisan video
interviews, on-site slideshows, and a Chinese language PDF.
www.gia.edu/gems-gemology/spring-2014-lucas-chinese-gem-
industry
The following 25 questions are from the Spring, Summer, Fall, and
Winter 2014 issues of GEMS & GEMOLOGY. Refer to the articles in those
issues to find the single best answer for each question.
Mark your choice on the response card provided in this issue or visit
gia.edu/gems-gemology to take the Challenge online. Entries must be
received no later than Monday, August 3, 2015. All entries will be
acknowledged with an e-mail, so please remember to include your
name and e-mail address (and write clearly).
Score 75% or better, and you will receive a certificate of completion

(PDF file). Earn a perfect score, and your name also will be listed in
the Fall 2015 issue of GEMS & GEMOLOGY.
1. Which city is the world’s largest D. Weight retention is more of a A. It may contain an extra FTIR
center for diamond sorting, concern with natural mate- absorption band around 1140
valuing, and selling? rial. cm–1.
A. Shanghai, China B. Its composition (stoichiometry)
B. Mumbai, India 4. Which of the following is a valid is ideal.
C. Antwerp, Belgium GIA diamond color grade? C. It does not contain water.
D. Gaborone, Botswana A. Fancy Intense red. D. It is most likely a synthetic.
B. Fancy Vivid purplish pink.
2. What happens if the c-axis is C. Fancy Vivid purplish red. 8. All of the following statements
parallel to the table facet of a D. Fancy Deep Vivid purplish are true of “Jedi” spinels except
strongly pleochroic stone? pink. ___________.
A. No pleochroism can be ob- A. there are other sources be-
served through the table. 5. In 2013, China was the world’s sides the Namya deposit in
B. A “bow tie” may be observed. largest consumer of ___________. Myanmar
C. For a biaxial stone, all three A. jadeite and platinum B. they have no dark tone
colors can be observed B. gold and diamonds C. they are sometimes found in
through the table, whereas C. diamonds and jadeite matrix
only two colors can be ob- D. jadeite, platinum, diamonds, D. they have lower iron content
served for a uniaxial stone. and gold on average than Mogok spinel
D. Only the ordinary ray is ob-
6. What determines the final color 9. The top three diamond producers
served.
of treated amber? are:
3. Why do natural blue sapphire A. Presence of bubbles. A. Rio Tinto, Alrosa, BHP
and Verneuil synthetic blue B. Pressure during treatment. B. De Beers, Alrosa, Rio Tinto
sapphire often display differences C. Presence of liquid inclusions. C. Rio Tinto, Alrosa, De Beers
in pleochroism? D. Atmosphere during heating. D. Dominion Resources, Rio
A. The table facets are often ori- Tinto, De Beers
7. What can be said about an
ented differently.
emerald that contains a 10. The green and orange-red
B. The blue color is caused by
significant amount of alkali metal phosphorescence displayed by
different trace impurities.
impurities? natural and untreated type IIb
C. Verneuil material does not
display pleochroism. blue diamonds when exposed to
56 G&G CHALLENGE GEMS & GEMOLOGY SPRING 2015

short-wave UV can potentially be A. they are commonly non- 22. All of the following statements are
attributed to ___________. nacreous true of high-pressure high-temper-
A. the recombination of donor- B. they tend to craze ature (HPHT) synthetic diamonds
acceptor pairs and possibly C. they are used as nuclei in cul- except ___________________.
plastic deformation tured pearls A. near-colorless type IIa mate-
B. their origin in the Cullinan D. they are mainly found in the rial is grown by using higher-
mine Arabian (Persian) Gulf purity solvents, catalysts, and
C. high levels of nitrogen carbon sources
D. the presence of boron 17. Pink to red diamonds are cut to B. they are produced via belt,
___________. BARS, cubic, or toroid presses
11. Which diamond mine is the A. maximize color and clarity C. most colorless material to
world’s richest as of 2014? B. retain as much weight as pos- date has been grown for non-
A. Argyle sible jewelry purposes
B. Jwaneng C. maximize color grade and D. yellow is the most common
C. Orapa weight color for jewelry use
D. Diavik D. ensure a better clarity grade
than I 23. What is required of the observa-
12. With the emergence of rough tion lighting to see the greenish
diamond tender sales, small 18. What is true about nephrite from blue color of blue amber?
manufacturers ___________. Hechi, China? A. Only sunlight allows the ob-
A. now face rough shortages A. Colors include white, green, servation of this phenomenon.
B. have seen stability in the black, purple, and gray. B. Any light source will reveal
supply of rough B. Only secondary material dis- the blue color.
C. have experienced overall plays dendrites. C. It must have an ultraviolet
industry profits C. Band- and dendrite-free mate- component.
D. have seen increased selection rial is the most prized. D. It must cover the full visible
and availability of rough D. The specific gravity of this range.
material is unusually low.
13. Most gemstones from Sri Lanka 24. What inclusion feature is report-
are found in ______. 19. When comparing high karatage edly unique about Zambian
A. pegmatites gold jewelry from Sri Lanka and emeralds from the Kafubu area?
B. skarns India, which is true of Sri Lankan A. Some multiphase inclusions
C. alluvial deposits jewelry? contain crystals visible only
D. eluvial deposits A. It contains more copper. with cross-polarized light.
B. It is more yellow. B. Kafubu is the only source of
14. Which type of treated amber can C. It is manufactured exclusively emeralds containing solid in-
be produced by two different with traditional methods. clusions with no associated
methods? D. Weddings are a more signifi- liquid or gas inclusions.
A. Beeswax amber cant source of business. C. Of all Zambian emeralds,
B. Golden flower amber they had inclusions most sim-
C. Red flower amber 20. In China, which metal do brides
ilar to those of Colombian
D. Sun spark amber generally prefer for wedding rings?
emeralds.
A. 22–24K gold
15. Which of these statements about D. The most common inclusions
B. Platinum
beaded pearls is true? were three-phase, containing
C. 18K gold
two or more colorless crystals.
A. Nacre deposition requires a D. Silver
solid surface. 25. Which is not a regular character-
B. The bead determines the size 21. The actual boron content in a
istic of HPHT synthetic
and shape of the pearl. blue diamond is ___________ its
diamonds?
C. Their density is consistent calculated value from FTIR
A. Patterned color zoning.
from specimen to specimen. absorption spectroscopy.
B. Inclusions that are attracted to
D. The bead is not always in di- A. equal to or greater than
a strong magnet.
rect contact with the nacre. B. equal to or less than
C. Strong fluorescence to short-
C. generally equal to
16. All the following statements are wave UV illumination.
D. None of the above.
true of “pen pearls” except ______. D. Presence of trace levels of Si.
G&G CHALLENGE GEMS & GEMOLOGY SPRING 2015 57

Editors
Thomas M. Moses | Shane F. McClure
Pink and Reddish Purple

COBALTOCALCITE
Cobaltocalcite is a pink to purple va-
riety of calcite. The mineral is popular
as a collector’s item because of its
striking purplish pink color, which is
caused, as the name suggests, by the
presence of cobalt. Cobalt occurs in
calcite in octahedral coordination as
Co2+ (E. Fritsch and G.R. Rossman,
“An update on color in gems. Part 1:
Introduction and colors caused by dis-
persed metal ions,” Fall 1987 G&G,
pp.126–139).
Recently, GIA’s laboratory in
Bangkok examined the botryoidal pur-
plish pink and rough reddish purple
cobaltocalcite specimens shown in fig- Figure 1. The pink and reddish purple cobaltocalcite specimens (246.3 and
ure 1. Gemological properties were ob- 361.0 g, respectively) are shown with some of the wafers cut from them.
tained from both, and we also prepared
several polished wafers for advanced
testing. long-wave UV and weak pink to purple specimen, while the purplish
Standard gemological testing of short-wave. Magnification revealed pink one contained pronounced irreg-
these translucent stones revealed white particulate flakes of a fibrous ular fibrous inclusions forming a mo-
strong double refraction with an RI of nature forming bands in the reddish saic pattern in areas (figure 2).
1.49–1.66 (as expected for a carbonate
material) and an SG of approximately
2.70. The reddish purple cobaltocal- Figure 2. Left: The reddish purple cobaltocalcite showed a banded struc-
cite exhibited a very weak purplish ture formed by white particles with a fibrous appearance. Field of view
pink reaction to long-wave UV radia- 4.1 mm. Right: Irregular bands of fibrous inclusions in the pink stone
tion and an inert reaction to short- formed a mosaic pattern. Fiber-optic illumination, field of view 4.1 mm.
wave UV. The purplish pink stone had
a moderate orangy pink reaction to
Editors’ note: All items were written by staff

members of GIA laboratories.
GEMS & GEMOLOGY, Vol. 51, No. 1, pp. 58–67.
58 LAB NOTES GEMS & GEMOLOGY SPRING 2015

UV-VIS-NIR SPECTRA
7
treated or synthetic diamonds being
mixed in with natural melee goods
6 (those weighing less than 0.20 ct). Re-
543 cently, GIA’s laboratory has seen a
ABSORPTION COEFFICIENT (cm–1)
surge in notably small faceted melee

5
Reddish Purple diamonds submitted for identification.
Pink In melee sizes less than 0.01 ct, a stan-
4 dard Fourier-transform infrared (FTIR)
spectrometer provides a less stable en-
vironment for analysis and produces
3
431
an indistinct spectrum. Diamonds
smaller than 0.01 ct prove challenging
2 for other screening devices as well.
Meanwhile, there is heightened pres-
sure to identify both loose and
1
mounted melee diamonds in the labo-
ratory quickly and reliably so that each
0 stone can be analyzed. In late 2014,
300 400 500 600 700 800 900 1000 GIA developed a new protocol to use
WAVELENGTH (nm) an FTIR microscope to focus on melee
diamonds as small as 0.00054 ct (figure
Figure 3. UV-Vis-NIR spectra in the 300–1000 nm region showed broad 4) to produce high-quality spectra suit-
absorption bands at approximately 431 and 543 nm in the reddish purple able for diamond typing.
cobaltocalcite, and a weak broad band at 543 nm in the pink stone. Inset: Operating the FTIR microscope in
The reddish purple and pink stones’ CIE L*a*b* color coordinates (71, 47, reflection mode allows for fine-tuned
24 and 96, 3, 4, respectively) are reproduced from their UV-visible spectra. aligning of the beam within a sample,
improving the detail of the infrared
spectra. Once a faceted round brilliant
The UV-Vis-NIR spectrum of the Mn. Manganese can cause pink to pur- melee is stationed on a slide, the mi-
reddish purple cobaltocalcite wafer ple color in appropriate concentra- croscope beam can be focused either
(figure 3) showed a dominant absorptions, so its contribution to the through the pavilion (if the melee is
tion band at 543 nm and a small peak purplish pink color in this material table-down) or through the table at an
at 431 nm. The pink wafer only may require further analysis. angle to reflect off an inner pavilion
showed a weak absorption feature at Piradee Siritheerakul and facet (if the melee is resting on the
543 nm. Color calculations (see box A Supharart Sangsawong pavilion). Many of the samples were
in R. Lu, “Color origin of lavender so small that the position of the stone
jadeite: An alternative approach,” remained unknown until the micro-
Winter 2012 G&G, pp. 273–283) were DIAMOND scope was focused. Nevertheless,
consistent with the respective reddish Analysis of Melee Diamonds Using spectral quality was independent of
purple and purplish pink color of the FTIR Spectroscopy stone position.
two specimens (figure 3, inset). The jewelry industry has expressed in- All 70 melee examined were nat-
Elemental analysis was performed creasing concern over the possibility of ural round brilliants, the smallest a
using laser ablation–inductively cou-
pled plasma–mass spectrometry (LA-
ICP-MS). Besides the main constituent Figure 4. This 0.00054 ct colorless round brilliant was submitted for iden-
calcium, both the reddish purple and tification as a natural or synthetic diamond. Despite the specimen’s small
the purplish pink cobaltocalcites size, an FTIR microscope can focus a beam through the facets to capture a
showed significant amounts of Co at high-quality infrared spectrum.
5673 and 730 ppmw, respectively. The
reddish purple sample’s higher concen-
tration is consistent with a higher Co
level produces a more saturated color.
The concentration of Co is consistent
with the intensity of the 543 nm ab-
sorption bands in the visible region of
both samples. The purplish pink cobal- Gem Instruments Units = .1mm
tocalcite also showed 8719 ppmw of
LAB NOTES GEMS & GEMOLOGY SPRING 2015 59

FTIR SPECTRUM
A chameleon diamond is an un-
likely candidate for artificial irradia-
tion treatment to enhance the stone’s
green or blue bodycolor. It is likely that
this property was not known or under-
stood before the irradiation process. A
permanent color change may occur if
these treated chameleon stones are
heated for a prolonged period, so it is
ABSORBANCE
important to exercise caution during

testing. Because the diamonds’ original
colors are unknown, they were issued
reports stating that they had been arti-
ficially irradiated to enhance their
color.
Sally Chan, Jessie Yixin Zhou,
and Paul Johnson
6000 5000 4000 3000 2000 1000 Diamond in Diamond

WAVENUMBER (cm–1)
The New York laboratory recently
examined a 1.69 ct Fancy black round
Figure 5. This infrared spectrum of the 0.00054 ct diamond in figure 4, ob- brilliant diamond (figure 8). The type
tained using an FTIR microscope, shows the detail that can be captured Ia diamond contained an abundance
from very small melee sizes. of tiny cloud inclusions and strong
hydrogen-related absorptions, both
common features for this type of dia-
0.00054 ct colorless sample identified thermochromic properties of these di- mond. We observed numerous etch
as a type Ia diamond (figure 5). A few amonds (D.J. Content, Ed., A Green channels with brown radiation stain-
screening devices for treatment and Diamond: A Study of Chameleonism, ing, also normal features for dia-
synthetics have been introduced for W.S. Maney & Son, Leeds, England, monds of this type and color. But we
diamonds over 0.01 ct. The FTIR mi- 1995, 42 pp.). also observed a sizable octahedral
croscope has proved very effective in Recently the New York laboratory crystal inclusion that broke the sur-
analyzing melee smaller than this examined two chameleon diamonds, face of a pavilion facet (figure 9, left).
size, either loose or mounted. a 0.35 ct Fancy Deep yellow-green The surface-breaking area was ap-
The knowledge that GIA can type marquise and a 0.27 ct Fancy Deep proximately 150 × 250 microns ac-
such small stones and determine their grayish yellowish green marquise (fig- cording to the Raman microscopic
origin, either loose or mounted, apart ure 6). Spectroscopic analysis and
from being an impressive test of FTIR gemological observations confirmed
microscopy, will increase consumer that these were typical chameleon di- Figure 6. These two chameleon
confidence in these remarkable melee amonds. After excitation with short- diamonds (0.35 and 0.27 ct)
diamonds. wave UV light, both exhibited a were color-treated with artifi-
strong blue to yellow phosphores- cial irradiation.
Rachel Sheppard, Tom Moses, and
Wuyi Wang cence often seen in natural
chameleon diamonds. Their UV-Vis
absorption spectra showed a broad
Artificially Irradiated Color-Change band at about 480 nm, as expected for
Diamonds this type of diamond. But the spectra
Diamonds that exhibit a temporary also displayed a peak at 741 nm (figure
color change, commonly referred to as 7), known as GR1 (general radiation
“chameleon” diamonds, are rare in na- damage), that can contribute to a
ture. Their color changes with gentle green color in diamonds. Because this
heating, or when they are left in dark- radiation-related feature is not found
ness for a period of time. The change in untreated natural chameleon dia-
from a dark greenish to a lighter yellow monds, we concluded that both
hue upon gentle heating is due to the stones had been artificially irradiated.

UV-VIS SPECTRA
ABSORBANCE
480 band
GR1
Figure 8. This 1.69 ct Fancy black

round brilliant diamond con-
tained an octahedral diamond
crystal.
450 500 550 600 650 700 750
WAVELENGTH (nm)
at approximately 1580 cm–1 was not
Figure 7. The UV-Vis spectra for the two chameleon diamonds show a observed in either. Raman mapping
broad absorption peak around 480 nm and an atypical GR1 feature at 741 showed that the full width at half-
nm. maximum (FWHM) of the inclusion’s
1332 cm–1 peak was different from
that of the host diamond (figure 9,
image. The actual dimensions of the crystal, and Raman analysis easily center). In the map, each colored pixel
entire included crystal could not be identified it as diamond. Both the host represents the FWHM value of the
determined. diamond and inclusion show sharp 1332 cm–1 Raman peak. The colored
The exposed crystal inclusion had 1332 cm–1 Raman bands, indicating pixels of the inclusion were decidedly
the morphology of a natural diamond high crystallinity. The graphite peak different from those of the host dia-
Figure 9. Left: This photomicrograph reveals natural etch channels with brown radiation staining, as well as an oc-
tahedral crystal inclusion (the inset shows the surface-breaking outline). Center: The Raman map of the 1332 cm–1
FWHM clearly outlines the surface break of the octahedral diamond inclusion. The inset in the left-side image rep-
resents the Raman mapping area. The image was taken in a grid pattern measuring FWHM of the diamond Raman
peak at 1332 cm–1. More than 300 Raman spectra collected at multiple points on the grid were translated into this
map by the software. Each colored pixel represents the FWHM value, and similar FWHM values will be shown in
similar colors. Noticeably different colors outlining the inclusion indicate that it is not part of the host diamond
and that it formed in a different geological environment. Right: DiamondView imaging shows that the diamond
inclusion was captured during the second phase of growth.
50 µm

mond, confirming that it formed in a
different geological environment. We
also observed differences between the
photoluminescence (PL) spectra of the
inclusion and the host diamond, evi-
dence that the diamond inclusion
formed in a different environment
and was later incorporated as a proto-
genetic inclusion. This also suggests
that this diamond may have traveled
from its original formation environ-
ment to another geological environ-
ment after crystallization. Figure 10. Left: This white shell bead (10.08 mm) was visible after the
A DiamondView image shows coating was removed from one of the imitation pearls. Right: A subtle
the diamond crystal to have been flame structure was observed on the surface of the shell bead; magnified
captured in a second growth phase of 40×.
the host diamond crystal (figure 9,
right). This is the first documented
case of a diamond crystal inclusion such as Tridacna gigas, are more vul- are commonly harvested from their
with a different origin than that of nerable than others, such as Tridacna natural habitats or aquaculture farms
the host diamond. squamosa or Tridacna maxima. These for food (Center for Tropical and Sub-
large saltwater clams can have heavy tropical Aquaculture Publication No.
Paul Johnson and Kyaw Soe Moe
shells fluted with multiple folds (figure 114, University of Hawaii), and their
11) and colorful mantles. Their natural shells are fashioned into beads or or-
habitats lie in the warm marine waters naments that are prized by some cul-
PEARLS of the Indo-Pacific, a fragile region that tures. Despite their protection under
has been heavily impacted by human CITES, these shell products are readily
Conservation Concerns over Use
activities. available on the Internet and often
of Tridacna Shell in Imitation These beautiful marine animals very inexpensive (figure 12). Imitation
Pearls
Last year the New York laboratory re-
ported on the use of shell as a pearl Figure 11. These three shells of Tridacna species are part of the collection
imitation (Summer 2014 Lab Notes, at GIA’s Bangkok laboratory. The two largest measure approximately 33 ×
pp. 153–154) and the improper 20 cm each. The two larger shells were found empty by Thai divers, while
nomenclature applied by those mar- the smaller shell was donated to the Bangkok lab several years ago and
keting it. We decided to delve deeper comes from an unknown source.
and investigate the nature of the shell
beads used in such imitation pearls
following correspondence with Dr.
Henry A. Hänni, who previously re-
ported on this issue (see Summer
2004 Gem News International, p. 178,
and references within).
After removing the outer coating
on one of the imitation pearls by im-
mersing it in acetone, we observed a
banded white bead (figure 10, left).
Magnification revealed fine and subtle
flame structures (figure 10, right), indi-
cating the bead was most likely fash-
ioned from the shell of a Tridacna
(giant clam) species.
All species of the Tridacnidae fam-
ily are currently listed in Appendix II
of the Convention on International
Trade in Endangered Species of Wild
Fauna and Flora (CITES). Some species,

Figure 13. This northern quahog
pearl exhibited a fine color and
shape.
Figure 12. Tridacna shell beads of various sizes (4.5 to 10.5 mm) are read-
ily available from various commercial sites. The carved beads shown on
the left are marketed as “Tibetan prayer beads.” well as 1130 and 1520 cm–1 peaks re-
lated to a mixture of polyenic (poly-
acetylenic) compounds, the natural
shell “pearls” fashioned from these natural non-nacreous/porcelaneous pigments responsible for its purple
endangered and protected mollusks do pearls. Raman spectroscopy using color, as previously observed in sim-
not offer any obvious advantages over 514 nm laser excitation (figure 14) ilar pearls (Winter 2008 GNI, pp.
common freshwater mussel shells, showed characteristic aragonite 374–375). The characteristic natural
and it is extremely difficult to identify peaks at 702, 706, and 1086 cm–1, as purple color and non-nacreous porce-
the exact Tridacna species or whether
the mollusks were farmed or har-
vested from the wild. We urge manu- Figure 14. The quahog pearl’s Raman spectrum showed the typical arago-
facturers to stop using Tridacna shell nite peaks seen in most pearls, together with 1130 and 1520 cm–1 peaks re-
beads when producing imitation lated to a natural coloring compound.
pearls.
Jessie Yixin Zhou and RAMAN SPECTRUM
35000
Chunhui Zhou
1520
30000
1130
Large Natural Quahog Pearl
A notable purple non-nacreous pearl 25000
(figure 13) recently submitted to GIA’s
New York laboratory measured 13.69 1086
× 11.80 mm and weighed 16.64 ct. It
COUNTS
20000
was immediately recognizable as an

outstanding specimen due to its clean
15000
surface, which possessed an attractive
sheen reminiscent of fine porcelain. It
had good symmetry, featuring a near- 10000
round button shape with a perfect 702 706
dome top and a rounded base, and a

richly saturated and well-distributed 5000
mid-purple color.
Real-time microradiography re- 200 400 600 800 1000 1200 1400 1600 1800 2000
vealed a tight internal structure, a WAVENUMBER (cm–1)
common characteristic of certain

sizes is of particular concern. This is
due in part to the expense of examin-
ing melee relative to their value.
While GIA can reliably identify syn-
thetic melee, this requires individual
analysis of each stone, preferably be-
fore mounting. In a complicated piece
with hundreds of melee, this can be
prohibitively expensive or time-con-
suming. The same is true for melee
parcels. A synthetic diamond mixed
into a packet may not be identified
until later, deceiving dealers, jewelers,
and consumers and potentially caus-
ing damage to the trade.
Recently, a pendant with 118
mounted stones was submitted to
GIA’s New York laboratory for color
Figure 15. This quahog shell from the eastern coast of the United States
origin analysis of each individual
has a naturally attached pearl.
melee (figure 16). The pendant con-
sisted of a central pear-shaped stone
surrounded by three consecutive rows
laneous appearance indicated a pearl SYNTHETIC DIAMOND of round brilliant melee. Of the 118
from the bivalve mollusk Mercenaria stones, 58 were fancy yellow, includ-
HPHT Synthetic Diamond Melee
mercenaria (belonging to the Veneri- ing the center stone, and 60 were col-
in High-Quality Jewelry Piece orless. Using a Fourier-transform
dae family), also referred to as the
Advances in the laboratory growth of infrared (FTIR) microscope in reflec-
“northern quahog.”
diamonds have led to an increase in tion mode allowed detailed focusing of
Quahogs are native to the At-
the number of synthetic diamonds the infrared beam on the mounted
lantic shores of North America from
seen at GIA. The existence of high- stones, including those that were par-
Canada to Georgia, especially on the
quality synthetic diamonds in melee tially obscured. Analysis was carried
coast of the New England states, and
can also be found along California’s
Pacific coast. They can produce non-
Figure 16. A photo and a detailed illustration of the melee-set pendant
nacreous porcelain-like pearls, and
show the location of all 118 samples. The single HPHT synthetic melee is
their shells typically exhibit an un-
highlighted in both images.
even white and purple interior color
(figure 15). Quahog pearls may occur
in a variety of colors ranging from
white to brown and from faint pink-
ish purple to dark purple. Like other
natural pearls, quahog pearls are
rarely spherical. Button shapes with
flat bases are most often encountered.
Natural northern quahog pearls
are often submitted to GIA labs. Most
are below 10 carats with a flat-based
button shape, usually with a dark or
light purple color, and tales of their
accidental discovery while eating
clams are not uncommon. This qua-
hog pearl’s large size, clean surface,
fabulous luster, near-round shape, and
evenly distributed rich color combine
to make it an exceptionally fine and
rare example of its type.
Joyce Wing Yan Ho

Figure 17. Left and center: DiamondView fluorescence images of the 0.00431 carat type Ib diamond show clear
cuboctahedral HPHT synthetic growth sectors. Right: The sample’s strong phosphorescence is atypical for a dia-
mond of this type and color.
out on a Thermo Nicolet iN10 FTIR 452, 465, and 478 nm. This spectrum synthetic diamonds,” Winter 1995
microscope, which determined the di- is known as the “Cape series,” and G&G, pp. 256–264; J.E. Shigley et al.,
amond type classification of each such goods are commonly referred to “Gemological properties of near-col-
melee stone from its mid-IR absorp- as “Cape yellow.” orless synthetic diamonds,” Spring
tion spectra (C.M. Breeding and J. E. Two colorless stones were classi- 1997 G&G, pp. 42–53). The 0.00431
Shigley, “The ‘type’ classification sys- fied as type IaB, showing only pure B- ct yellow stone was removed from its
tem of diamonds and its importance in aggregate absorption; the remaining mounting for more comprehensive
gemology,” Summer 2009 G&G, pp. colorless stone was type IIa, meaning examination with the DiamondView
96–111). One melee was identified as it did not show IR absorption from (figure 17). Its cuboctahedral synthetic
an HPHT-grown (high-pressure, high- any nitrogen-related impurities. Fi- growth sectors were clearly seen from
temperature) synthetic diamond, based nally, a partially obscured yellow both the table and pavilion, confirm-
on its infrared spectrum as well as its stone near the bottom of the piece ing its HPHT synthetic origin.
color, fluorescence pattern, and phos- was type Ib, showing absorption due Although this could have been an
phorescence behavior. This 0.00431 ct to isolated nitrogen impurities, and isolated event, it underscores the need
melee was removed from the setting characterized by features at 1130 and for caution when buying melee parcels
to confirm its origin as HPHT-syn- 1344 cm–1. Isolated nitrogen centers or mounted pieces from unfamiliar
thetic. The rest were confirmed as also produce a broad absorption fea- sources. Nevertheless, it is important
natural diamonds. ture in the UV-visible range (approxi- to note that such stones can be un-
Of the 118 melee, 114 were classi- mately 270 nm), resulting in a equivocally identified as lab-grown.
fied as type IaA or type IaAB. These coloration often described as “Canary Colorless and near-colorless (D–N) un-
were characterized by absorption yellow.” Type Ib diamonds are very mounted diamonds larger than 0.01 ct
from aggregated nitrogen centers, rare, representing only 0.1% of all nat- can be tested using commercially
where A-centers (nitrogen pairs) and ural diamonds (R. Tappert and M.C. available testing equipment such as
B-centers (four nitrogen atoms sym- Tappert, Diamonds in Nature, the GIA DiamondCheck. Meanwhile,
metrically surrounding a vacant lat- Springer, Berlin, 2011). Conversely, colored diamonds, smaller stones, and
tice site) absorb infrared light at 1282 this diamond type is common in yel- mounted jewelry need to be tested by
and 1174 cm–1, respectively. These low synthetic diamonds. Due to the a reputable gemological laboratory. In-
spectra revealed sufficient A-center absence of A-centers, these four sam- creased industry awareness, combined
concentrations, eliminating the pos- ples required further testing. with diamond testing, may deter the
sibility of HPHT treatment, which Photoluminescence spectroscopy spread of undisclosed synthetics, ulti-
would have deaggregated the centers confirmed that the type IaB and IIa mately benefiting both sellers and
into isolated nitrogen atoms (A.T. stones were natural in origin. However, buyers of polished diamond goods.
Collins, “The colour of diamond and the type Ib stone (marked in figure 16) Rachel Sheppard, Ulrika D’Haenens-
how it may be changed,” Journal of was further examined with Diamond- Johansson, Kyaw Soe Moe,
Gemmology, Vol. 27, No. 6, 2001, pp. View imaging, which showed that it Tom Moses, and Wuyi Wang
341–359). Since A- and B-center ab- exhibited strong yellow-green fluores-
sorptions occur solely in the infrared cence under deep ultraviolet illumi-
range, their presence does not produce nation (wavelength <230 nm) and
color. Instead, the yellow color ob- indicated growth sector patterns typ- Large HPHT-Grown Synthetic
served in 57 of these type IaA/IaAB ical of HPHT synthetic diamonds, as Diamonds Examined in GIA’s
stones resulted from absorption from well as strong blue phosphorescence Hong Kong Laboratory
the N3 defect at 415 nm (a complex of inconsistent with natural yellow type Over the last decade, the jewelry in-
three nitrogen atoms surrounding a Ib diamonds (J.E. Shigley et al., “A dustry has seen rapid improvement in
vacancy) and associated peaks at 453, chart for the separation of natural and the quality of synthetic diamond

736.6/736.9 nm from the silicon-va-
cancy defect, and an 882.7/884.4 nm
doublet from the well-known Ni-re-
lated defect. Very weak emissions
from nitrogen-vacancy centers at
575.0 and 637.0 nm were detected
only in the K-color sample. Besides
metallic inclusions, another impor-
tant identification feature of HPHT
synthetics is fluorescence. Typical flu-
orescence patterns showing multiple-
sector growth were observed in both
samples.
These two diamonds were dis-
Figure 18. These two large synthetic diamonds were produced using
closed as HPHT synthetic when sub-
HPHT growth methods by the Russian firm New Diamond Technology.
mitted for examination. Tested using
The 4.30 ct specimen on the left has D color and SI1 clarity. On the right
the GIA DiamondCheck device, both
is a 5.11 ct sample with K color and I1 clarity.
were referred for further testing.
Gemological observations and spec-
troscopic features confirmed they
grown by the CVD (chemical vapor short-wave UV, a medium to strong were HPHT synthetics.
deposition) method. Colorless and green-yellow fluorescence was ob- Examination of these improved
near-colorless CVD synthetics with served. Both showed strong yellow- HPHT synthetic diamonds, the largest
sizes up to 3.04 ct, with I color and SI1 green phosphorescence lasting more synthetic diamonds produced by any
clarity, have been reported. GIA’s Hong than 20 seconds. One noteworthy fea- method that GIA has examined so far,
Kong laboratory recently examined ture was the absence of pinpoint in- demonstrated significant progress in
two large synthetic diamonds created clusions, which are common in this growth technology. In addition to
using the HPHT (high-pressure, high- HPHT synthetic diamonds and often their use as gem materials, crystals of
temperature) method that demon- distributed throughout the crystal. this size have many potential indus-
strated parallel progress in the two Absorption spectra in the infrared trial applications.
growth technologies. These samples, region demonstrated these were type
shown in figure 18, were produced in II diamonds, with no absorption band Ping Yu Poon, Shun Yan Wong, and
Russia by New Diamond Technology. detected in the one-phonon region Carmen Lo
The first was a 4.30 ct cushion (approximately 1350–1000 cm–1)
shape with D color and a clarity grade where nitrogen impurities occur. A
of SI1, based on three small clusters of very weak 2800 cm–1 band was attrib- SYNTHETIC MOISSANITE Melee
metallic inclusions. The other was a uted to trace substitutional boron. A in a Colored Diamond Bracelet
5.11 ct cut-cornered rectangular mod- higher boron concentration was A colored diamond bracelet submit-
ified brilliant. It had K color and a recorded in the D-color synthetic dia- ted to the New York laboratory for
clarity grade of I1, the result of a few mond (7 ± 1 ppb, compared to 1.2 ± 0.2 identification (figure 19) contained
metallic inclusions and two small ppb). Photoluminescence spectra col- 162 round brilliants ranging from 0.05
fractures in the girdle area. Neither lected at liquid-nitrogen temperature to 0.20 ct, with a color range from
one showed reaction to long-wave UV with varying laser excitations re- near-colorless to fancy yellow and
radiation. When they were exposed to vealed an emission doublet at brownish yellow. Melee-size dia-
Figure 19. This fancy-color melee diamond bracelet contained two synthetic moissanites.

RAMAN SPECTRUM
facet junctions, a key identification
789
30000 feature for synthetic moissanites (K.
Nassau et al., “Synthetic moissanite:
25000 A new diamond substitute,” Winter
1997 G&G, pp. 260–275). Further
20000 testing with Raman spectroscopy
confirmed this identification with
COUNTS
15000 three peaks at 768, 789, and 966 cm–1

966 (figure 20).
10000
768
FTIR spectroscopy performed on
the other referred near-colorless and
5000 colored melee identified them as nat-
ural. One melee was found to be type
0 IaB, while the others were type IaA.
This analysis showed that melee-
1800 1600 1400 1200 1000 800 600 400 200
sized diamond imitations are being
WAVENUMBER (cm–1)
mixed with natural diamond parcels
and set into fine jewelry without
Figure 20. Raman spectroscopy confirmed the identification of two color- proper disclosure. Therefore, proper
less round brilliants as synthetic moissanite with peaks at 768, 789, and identification by a gemological labo-
966 cm–1. ratory is an essential tool to maintain-
ing the integrity of the industry.
monds below 0.20 ct are usually not cided to conduct a full analysis on the Jessie Yixin Zhou
screened for synthetics and imita- mounted round brilliants in this
tions, and melee set into fine jewelry bracelet.
are very seldom tested due to limita- Testing was first performed on the
tions from the mounting. But because 60 near-colorless round brilliants with PHOTO CREDITS:
of recent concerns over fine diamond the DTC DiamondSure. Several sam- Nuttapol Kitdee—1, 11; Jonathan Muyal—
jewelry set with melee-size synthetics ples were referred and sent for further 2; Jian Xin (Jae) Liao—4, 6, 8, 13, 16 (left);
and imitations (see H. Kitawaki et al., testing using Raman spectroscopy. Of Paul Johnson—9 (left and right); Kyaw Soe
Moe—9 (center); Jessie Yixin Zhou—10,
“Identification of melee-size syn- these, two round brilliants were sus-
19; Sood Oil (Judy) Chia—12, 19; Robert
thetic yellow diamonds in jewelry,” pected as imitation. Close examina-
Weldon—15; Martha Altobelli—17; Ming Yin
Fall 2008 G&G, pp. 202–213; Winter tion under the optical microscope Poon—18.
2014 Lab Notes, pp. 293–294), we de- revealed obvious doubling on the
For online access to all issues of GEMS & GEMOLOGY from 1934 to the present, visit:
gia.edu/gems-gemology

Contributing Editors
Emmanuel Fritsch, CNRS, Team 6502, Institut des Matériaux Jean
Rouxel (IMN), University of Nantes, France ([email protected])
Kenneth Scarratt, GIA, Bangkok ([email protected])
baroque shapes—were also everywhere. The freeform

TUCSON 2015 shapes of many opals also fit well with natural-shape
trends for jewelry, lending themselves to carved
flowers, animals, and abstract pieces.
Once again, buyers and sellers from all over the world con- • Designers were seeking out unusual colors for stan-
verged on a corner of the American Southwest for the an- dard gems: fancy-color sapphires, colored diamonds,
nual Tucson gem shows. Many broad trends continued tourmalines, spinel, garnets, zoisite, zircon, and
from 2014: Consuming markets are hungry for fine colored beryl (morganite was very much in demand).
gems, and demand still outstrips supply, causing prices for • Many vendors told us they left their “traditional” in-
some gems to reach new highs. As more buyers from Asia ventory items at home, as they can sell those at any
compete for new production of rough gemstones, the sec- time. The Tucson crowd demands the unusual (fig-
ondary market is becoming more important for domestic ure 3), so vendors brought nontraditional items and
dealers. Many recycled gems and jewelry pieces were re- were reportedly selling them at a good pace.
turning to the market through estate sales, or directly from • Even though red-brown “Marsala” was named the
owners lured by all-time high prices. Some sellers were Pantone color of the year for 2015, it did not appear
showing items that had been held in inventory for years or to be an overall favorite, with the most observed col-
even decades (figure 1). These included fine corundum, Im- ors being bright blues, greens, and pinks.
perial topaz, red spinel, and aquamarine. We noted that
• The largest crowds observed at the wholesale
many of these “recirculated” goods were exceptional gems,
shows were gathered at the booths selling nontra-
superior to newly mined production. Many vendors are un-
ditional gem materials such as cabochons, druzy,
able to source new production at prices their clientele are
tourmalinated and rutilated quartz (again, see fig-
prepared to pay.
Cultured pearls of every type were in high demand—es-
pecially from the Chinese market. The same was true of
Figure 1. Many sellers at Tucson were displaying very
rubellite and “watermelon” tourmaline, tsavorite, and
large, fine, or unusual gems that had been held in in-
spinel, especially red to pink material from Mahenge, Tan-
ventory for years. Photo by Duncan Pay/GIA; cour-
zania.
tesy of Noor Gems Japan Ltd.
Overall, we observed several clear trends:
• Many gem-quality stones were cut in nontraditional
shapes such as cabochons, fantasy cuts, carvings (fig-
ure 2), and even slices.
• Many jewelry pieces had an organic, natural feel.
Similarly, non-round pearls—particularly large
Editors’ note: Interested contributors should send information and illustra-

tions to Stuart Overlin at [email protected] or GIA, The Robert Mouawad
Campus, 5345 Armada Drive, Carlsbad, CA 92008.
GEMS & GEMOLOGY, VOL. 51, NO. 1, pp. 68–110,
68 GEM NEWS INTERNATIONAL GEMS & GEMOLOGY SPRING 2015

Figure 2. Rutilated quartz was a popular material at
the 2015 Tucson gem shows. These examples were
carved by German artist Alexander Kreis. Photo by
Eric Welch/GIA; courtesy of Sonja Kreis.
Figure 3. All throughout central Tucson and along the
Interstate 10 corridor, tents sprang up around hotels
and other venues to host buyers and sellers from all
ure 2), and crystal slices—material typically used over the globe. Photo by Duncan Pay/GIA.
in “craft” jewelry.
• Opal (figure 4) was prominent: There was an abun-
Alexander Wild (Wild & Petsch Lapidaries, Kirsch-
dance of Ethiopian hydrophane opal, Australian opal,
weiler, Germany) provided a broad-brush market update
Mexican fire opal, and material from the U.S. Recent
from his firm’s perspective. Rough prices for many gems
finds in Ethiopia have generated a buzz for all types,
continued on an upward trajectory, he reported. Just a few
according to several vendors.
years ago, fine-color, high-clarity rubellite tourmaline sold
Foot traffic at the main AGTA and GJX shows appeared at wholesale for $300 to $350 per carat. These numbers re-
down from 2014, but most merchants reported brisk sales, flected the asking price for superb quality, with perhaps
especially of very fine or unique items. In fact, many ven- just a few tiny inclusions. In 2015, prices for equivalent
dors mentioned that this was their best show in recent material are almost triple that figure.
years. Eric Braunwart of Columbia Gem House (Vancou- As in the previous year, sourcing rough gems remains
ver, Washington) said he had forgotten what a “good year a problem, although it is by no means impossible for es-
was like” until this show. tablished companies with good connections in source
Figure 4. Opals of all

kinds were prominent
at this year’s shows.
The freeform shapes of
these Mexican fire
opals lend themselves
to one-of-a-kind pieces.
Photo by Eric Welch;
courtesy of Opalos &
Artesanias Mexicanas.
GEM NEWS INTERNATIONAL GEMS & GEMOLOGY SPRING 2015 69

Figure 5. The Cruzeiro mine, the Miranda Group, and Figure 7. Fine Brazilian rubellite tourmaline at the
KGK work together to bring Brazil’s bicolor and rube- Miranda Group’s factory in Shenzhen—most of these
lite tourmaline to the market in China. The Cruzeiro cut stones are larger than 10 ct. The factory needs to
mine provides the rough to the Miranda Group, receive 100 kilos of rough per month to meet produc-
which cuts the material. Photo by Andrew Lucas; tion goals of 25,000 to 30,000 carats. KGK markets
courtesy of Miranda Group Co. Ltd. and sells the cut stones and also mounts them into
jewelry for sale, primarily in China. Photo by Andrew
Lucas; courtesy of Miranda Group Co. Ltd.
countries, such as Wild & Petsch. The company is able to
source quality rough, though prices are definitely higher
for many goods. Since mid-2014, prices for many other ficult, and most of his supply has been coming from Nige-
commodities such as oil and copper have fallen. But gem- ria. Brazilian rubellite is basically unavailable.
stone rough prices continue to rise, largely due to demand [Editor’s note: In a 2014 visit to Brazil’s Cruzeiro mine
from China. In Wild’s opinion, such high prices are unsus- in Minas Gerais State, a GIA team witnessed recovery of
tainable. He wondered how long this would continue, ask- large facet-grade rubellite crystals (figure 5), which were all
ing rhetorically, “Is this a gem bubble?” put aside for exclusive sale to a consortium—composed of
Asked what was in demand, he answered that it was the the Miranda Group and KGK—that fashions the material
gemstones Wild & Petsch is known for: fine tourmaline and at its own factory in Shenzhen, China, for the Chinese
beryl. With their African connections, they secured a nice market (figures 6 and 7). Only blue to green production was
production of Paraíba-type copper-bearing tourmaline from available for sale to local and export markets.]
Mozambique, along with good parcels of aquamarine. As a Adjusting to price fluctuations has always been part of
result, they were able to offer their clientele this material life for colored stone merchants, Wild conceded, but not
at what Wild considered very fair market prices. In contrast, sudden, successive increases to levels that are three, four,
supply of rubellite and pink tourmaline rough is quite dif- or five times higher than the market was previously accus-
tomed to (see www.gia.edu/gia-news-research-miranda-
journey-of-rubellite-tourmaline).
Figure 6. Rough tourmaline crystals are sliced or Wild offered the possibility that at some point a single
sawn by the Miranda Group in Hong Kong, then market will be satisfied—even one as large as China’s.
faceted and polished at their factory in Shenzhen. When that happens, suppliers will have to find other mar-
Photo by Andrew Lucas; courtesy of Miranda Group kets for these goods. Wild believes the North American
Co. Ltd. and European markets are more sophisticated in terms of
pricing—especially for cut goods—than China’s current
market. There is also the possibility that any political up-
heavals there could cause rough prices for certain gems to
go down sharply, he said. And that could spell trouble for
some miners who base their operations on today’s histori-
cally high rough gem prices.
Wild said business at the 2015 show had been better
than the year before. He reckoned business was a third
above 2014, with some big-ticket items—including a fine
aquamarine suite—spoken for prior to the show. He con-
firmed our impression that traffic was down slightly from
last year—possibly due to fewer Asian buyers or the winter
travel difficulties on the U.S. East Coast.
Wild intimated that many clients came with specific
requirements in mind, particularly aquamarine or Paraíba-

Figure 8. A group of Paraíba tourmalines from Brazil’s
Rio Grande do Norte state. From the top: a 6.28 ct
cushion, a 1.73 ct triangular brilliant, a 5.28 ct oval,
three smaller ovals totaling 3.50 carats, and a 0.97 ct
triangular brilliant. Photo by Robert Weldon/GIA;
courtesy of Brazil Paraíba mine.
type tourmaline, and selection was good for these gems at

this year’s show. He mentioned they had even sold a few
collectors’ pieces, including a beautiful large green step-cut
beryl that measured more than 200 ct. That was a surprise
to him, because such items have proven more difficult to
sell the last few years.
“Everyone is searching for good things,” Wild con-
cluded. “For the most part, we get what we need.” Asked
Figure 9. Discovered in early 2014, this spray of cop-
if the trend is still toward finer, more unique pieces, Wild
per-bearing tourmaline was a harbinger of new pro-
responded, “Absolutely. I think quality still comes first. A
duction at the MTB mine in Rio Grande do Norte.
lot of the trends from last year still apply, and we’re still
Photo by Duncan Pay/GIA.
waiting to see if there’s going to be any deflation in pricing
for some goods.”
Once again, G&G greatly appreciates the assistance of
the many friends who shared material and information The MTB mine is located at the northern edge of a ridge
with us this year, with special thanks to the American of low, rounded hills that curve to the south and west from
Gem Trade Association for providing photography studio Rio Grande do Norte toward the original copper-bearing
space during the AGTA show. Dr. Tao Hsu, Andy Lucas, tourmaline discoveries by Heitor Barbosa at Mina da
Donna Beaton, Pedro Padua, and Dr. Jennifer Stone-Sund- Batalha in the state of Paraíba. The geology is very similar
berg contributed to these reports. to the Batalha occurrences, except that the feldspars in the
MTB mine’s pegmatites are not decomposed.
New production of copper-bearing tourmaline from Rio These gems represent the first new production from the
Grande do Norte, Brazil. At the GJX show, Sebastian and mine in several years. At the time of GIA’s visit, the oper-
Ananda Ferreira (Brazil Paraíba mine, Parelhas, Brazil) ation was reprocessing ore from previous mining for melee-
showed us examples of new production from their MTB sized rough. This produces strongly colored precision-cut
mine, which a GIA team visited in April 2014. The seven gems, much in demand for the watch industry. When GIA
principal stones we saw were a 6.28 ct square cushion, a visited the mine, miners had recently extended the work-
1.73 ct triangular brilliant, a 5.28 ct oval, three small ovals ings downward and been rewarded with sprays of what ap-
totaling 3.50 carats, and a smaller 0.97 ct triangular bril- peared to be copper-bearing tourmaline in the wall rock
liant (figure 8). (figure 9).

mology, Vol. 20, Nos. 7–8, 1987, pp. 446–457). Since then,
the mine has expanded to include both open-pit and un-
derground operations with a highly sophisticated recovery
plant. Mining is supported by a comprehensive geological
survey program. To date, more than 15 km (9.3 miles) of
3.8 cm (1.5 inch) diameter cores have been drilled. Geolog-
ical surveys indicated that a 300-meter-thick schist layer—
with emerald potential—underlies much of the property,
including the recovery plant. Core sampling defined the
extent and depth of the emerald ore body and proved the
Figure 10. This exceptional 9.22 ct emerald is from viability of an underground mine at Belmont. Sampling the
Belmont’s underground mine. Photo by Robert Wel- underlying rocks also helped plan the mine’s mechanical
don/GIA; courtesy of the Belmont mine. structure by showing which layers would be capable of
supporting underground tunnels.
The underground mine is accessed via a 666-meter
ramp that allows removal of up to 30 to 40 truckloads of
The new production that furnished the cut gems seen
ore per day using large commercial trucks (figure 11). At
in figure 8 came a few weeks after the GIA team’s depar-
the time of our visit, approximately 10 to 15 truckloads per
ture. For more on the MTB mine, please see www.gia.edu/
day (about 200 tonnes) were being taken to the recovery
gia-news-research-an-overview-of-2014-gia-brazil-expedition.
plant. The underground workings deliver a ratio of one
Duncan Pay tonne of ore to one tonne of waste. Each tonne of ore yields
GIA, Carlsbad about two grams of rough emerald. On average, those two
grams of rough produce two carats of faceted emeralds. By
New production of Brazilian emerald from Minas Gerais. contrast, the ratio for the current open pit is only one tonne
At the GJX show, Marcello Ribeiro (Belmont Mine, Itabira, of ore per 11 tonnes mined. The rest is overburden or
Brazil) showed us production from Belmont’s underground waste. There is clearly the capacity for many more years
mine, including one especially fine 9.22 ct stone (figure 10). of productive mining at Belmont.
As a GIA team visited Belmont in April 2014, it was inter- During the same April 2014 trip, GIA field gemologists
esting to see the gems from this relatively new part of the visited the Montebello mine, near Nova Era. At this year’s
mining operation for sale at the show. GJX show, Sergio Martins (Stone World, São Paulo) showed
Originally the site of a cattle ranch, Belmont yielded its us new production from that mine (figure 12). These gems
first emeralds in 1978 (H.A. Hänni et al., “The emeralds of were in the 2–4 ct range, bright with strong color and good
the Belmont Mine, Minas Gerais, Brazil,” Journal of Gem- luster.
Figure 11. A full-size

truck navigates the
tunnels of Belmont’s
underground mine.
From the outset, the op-
erators determined this
would be a high-capac-
ity, ramp-style mine.
Photo by Duncan
Pay/GIA; courtesy of
the Belmont mine.

Figure 12. This array of gems in the 2–4 ct range from
the Montebello mine shows the bright, vivid appear-
ance of high-quality emeralds from Nova Era. Photo by
Robert Weldon/GIA; courtesy of the Montebello mine.
The Montebello mine is adjacent to the independent

miners’ village of Capoeirana, about 6 km (3.7 miles) from
Nova Era. Capoeirana is about 26.5 km (16.5 miles) east of
Itabira. Unlike the larger mechanized operation at Bel-
mont, the area around Capoeirana hosts a variety of small-
scale mining activities by these independent miners,
known as garimpeiros. The Montebello mine is perhaps
the largest, employing 15 of them.
Emeralds were first discovered near here in 1988 (D. Ep-
stein, “The Capoeirana emerald deposit near Nova Era,
Minas Gerais, Brazil,” Fall 1989 G&G, pp. 150–158;
www.gia.edu/gems-gemology/fall-1989-brazil-emeralds-
epstein). The exploration that led to a mining boom in
nearby Capoeirana was triggered by the discovery of
emerald at Belmont. Production has dwindled in Nova
Era, due in part to the 2008 global economic recession and
the greater depths—often more than 100 meters—re- Figure 13. At Montebello, the miners have sunk a new
quired to reach the emerald mineralization (A. Lucas, shaft to follow a promising vein of emerald-bearing
“Brazil’s emerald industry,” Spring 2012 G&G, pp. 73–77; schist to deeper levels in the mine. The base of the
www.gia.edu/gems-gemology/spring-2012-brazil-emerald- new shaft is 170 meters below the surface. Photo by
lucas). Emerald mineralization in the surrounding area Andy Lucas/GIA; courtesy of the Montebello mine.
appears to start in Nova Era and finish at the Belmont
mine. Between them is another—currently unworked—
mine, called Piteiras, which Martins used to operate.
added that Montebello’s stones appear to increase in size
Mining stopped there due to ownership disputes that the
and color with depth.
parties hope will be resolved shortly.
At Montebello, the main elevator shaft descends 130 Duncan Pay
meters. At the time of GIA’s visit, miners had sunk a new
vertical shaft about 40 meters below the level of the exist- Exceptional red spinels and fine aquamarine. At the GJX
ing main shaft (figure 13). It follows a new vein that dips show, Axel Henn (Henn GmbH, Idar-Oberstein, Germany)
steeply underground. Neighbors in an adjacent mine have showed a superbly colored 61.29 ct Tanzanian red spinel
already found a productive vein at about that level. When measuring 36.49 × 18.44 × 13.55 mm (figure 14), along with
the miners sunk their shaft, they located a seven-meter- two pear-shaped gems cut from similar rough. Red spinels
thick seam of soft black schist underlain by granite. Emer- of this size, color, and quality are exceptionally rare. Indeed,
alds occur in the boundary where the quartz meets the stones of such deep, rich color larger than 50 ct are almost
schist. The dark color of the schist and the presence of unheard of.
quartz are good indicators for emeralds and pale beryl crys- According to Henn, this gem was from a find of three
tals. From this new 40-meter shaft, they are driving a new exceptionally large spinel crystals (one larger than 50 kg)
horizontal tunnel out into the schist. The miners plan to recovered from a dried riverbed in the mid-2000s. Henn
expand the shaft and install a second elevator. The miners heard of the discovery through a local Tanzanian contact.

Figure 14. Superb Tanzanian red spinel marquise of
61.29 ct. Photo courtesy of Henn Gems.
Figure 15. Among the many fine aquamarines at Axel

Henn’s booth, the standout was this 450.08 ct square
The crystals needed to be hammered and trimmed, but step-cut gem. Photo by Duncan Pay/GIA; courtesy of
they still produced cuttable rough of significant size, in- Henn Gems.
cluding a suite of gems totaling 174.58 carats. In his opin-
ion, the 61.29 ct marquise is the finest of the lot.
This is likely the same discovery as the widely reported ample’s unusual square cushion shape, large size, color, and
2007 recovery of four giant spinel crystals weighing 52, 28, clarity make it a notable and rare gemstone.
20, and 5.7 kg from a zone in the Ipanko ruby and spinel After seeing the wealth and variety of gems on display
mining area known as the “Joel Box.” Reported as having at the Tucson gem shows, it might be easy to come away
a “vibrant orangy, pinkish red color,” the largest crystal with the impression that fine colored stones are not par-
was broken up for transportation away from the mining ticularly rare. Yet the truly magnificent stones are ex-
area. The outside portions of crystals had some superb cut- tremely rare and often have a memorable provenance. One
table material, but the cores were mostly lower quality. Al- such gem is the 18.21 ct triangular cut red spinel Bruce
though the eventual yield was said to be as low as 3%, the Bridges showed us at his AGTA booth (figure 17). Accord-
crystals had the potential to produce many thousands of ing to Bridges, this magnificent gem was cut in 2007 in
carats of cut gems, including significant pieces of over 50 Bangkok from rough recovered in one astounding find in
ct. The 61.29 ct marquise is likely part of this yield. Tanzania’s Ipanko mining area that yielded several giant
Henn also displayed a superb 450.08 ct rectangular (cor- spinel crystals, one of which weighed in at over 50 kg. A
ners-on) step-cut aquamarine (figure 15). This gem pos- number of other dealers at this year’s show, including Axel
sessed the coveted pure blue “Santa Maria” color, with no
hint of green or yellow (this name refers to a mine near
Santa Maria de Itabira in Minas Gerais, Brazil). The gem
was of stunning clarity—this cutting style is very revealing Figure 16. This spectacular 12.46 ct tsavorite recently
of any imperfections—and was fashioned from rough re- returned to Bruce Bridges’s inventory after being in a
covered in 1927. Henn said he purchased the rough from collector’s possession for many years. Photo by Robert
an “old gemstone family,” and it had been “kept in the Weldon/GIA; courtesy of Bridges Tsavorite.
basement” for generations.
Duncan Pay
Fine tsavorite and spinel. Bruce Bridges (Tsavorite USA

Inc., Tucson) said that fine stones often return to his in-
ventory after years in a collector’s possession. At the
AGTA show, he showcased a vivid, top-quality 12.46 ct
cushion-cut tsavorite fashioned some 15 years earlier,
which made its way back into the market in the last two
years (figure 16). As tsavorite rough has a high value, gems
are typically cut to maximize weight. Rough is typically
recovered as long, thin asymmetrical fragments that lend
themselves to pear, marquise, and trilliant shapes. This ex-

Figure 17. This 18.21 ct Tanzanian red spinel was Figure 18. This unheated 8.56 ct intense pink sapphire
fashioned from material recovered from one of four represents the very best of recent production from
enormous multi-kilogram crystals reputedly found in Madagascar. Photo by Robert Weldon/GIA; courtesy
the Ipanko ruby and spinel mining area near Ma- of B&B Fine Gems.
henge, Tanzania. Photo by Robert Weldon/GIA; cour-
tesy of Bridges Tsavorite.
recirculated stones: a graduated suite of 12 perfectly
matched Russian demantoid garnet round brilliants. Each
Henn, also displayed fine gems from this one extraordinary gem contained a classic “horsetail” inclusion. Weighing in
discovery. at 20 carats total, the suite took Bindra four years to com-
Donna Beaton plete. He described it as a special item, with the stones
GIA, New York from the secondary market selected and recut to perfectly
match the newer gems.
Fine corundum, demantoid garnet. At the AGTA show, For Bindra, Mozambique is the future of ruby produc-
Dave Bindra (B&B Fine Gems, Los Angeles) showed us tion. He illustrated this with three fine heated gems from
some exceptional corundum, especially fine untreated yel- the Montepuez deposit weighing 7.05, 7.92, and 9.35 ct (fig-
low and pink sapphires. ure 20). Although all three stones represented beautiful,
The first standout piece Bindra showed us was an 8.56 clean material, he considered the 7.92 ct gem the finest, due
ct unheated, intense pink sapphire of extremely high clarity to its superior brilliance and intense red hue. Due to the on-
from Madagascar. Under the lights of our photo studio, it going trade embargo with Myanmar, classic “Burmese”
showed an intense pink hue (figure 18). A gem of this quality ruby is unobtainable for U.S. dealers. Fine Mozambique ru-
might expect to realize a wholesale price in the region of bies like these in the 7–9 ct range are in high demand and
$10,000 to $15,000 per carat. Bindra noted that Madagascar exceptionally rare. Gems larger than 4 or 5 ct are increas-
is producing some superb fancy sapphire, including pink, vi- ingly hard to find, Bindra pointed out.
olet, and “padparadscha” colors.
Although this pink gem represented recent production,
Figure 19. This exceptional unheated 89.55 ct golden
Bindra explained that the secondary market has become an
sapphire from Sri Lanka is an example of a recircu-
extremely important source for many dealers now that com-
lated stone. Photo by Robert Weldon/GIA; courtesy of
petition for freshly mined goods is so intense, particularly
B&B Fine Gems.
from buyers serving Asian markets. These recirculated gems
coming back onto the market offer a way for dealers to pro-
cure stones that often surpass current production in size and
quality, or are simply unobtainable today. As an example,
Bindra cited an 89.55 ct unheated golden sapphire from Sri
Lanka (figure 19), remarking that he had not seen material
of this color emerge from the ground in Sri Lanka for more
than 10 years. Originally this gem was somewhat larger,
over 100 ct. Modern cutting reduced the weight slightly but
produced a dramatic improvement in color and brilliance.
Bindra described this gem’s appearance and stature as “world
class.” As such, it would likely command a wholesale price
in excess of $3,000 per carat.
Bindra next showed us a blend of new production and

Figure 20. Left to right:
These heated rubies
from Mozambique
weigh 7.05, 7.92, and
9.35 ct. Photos by
Robert Weldon/GIA;
courtesy of B&B Fine
Gems.
Unlike Myanmar, Mozambique does not carry the each gem weighing approximately 25 ct and measuring 19–
stigma of human rights abuses. The heat treatment of these 20 mm. The suite included aquamarine and an unheated
rubies is not an issue with consumers, either. As Bindra ex- purple copper-bearing tourmaline from Mozambique;
plained, the market for top natural unheated ruby has now rubellite, yellow beryl, green tourmaline, and Imperial
reached such rarified levels that buyers are very receptive to topaz from Brazil; peridot and kunzite from Pakistan; man-
high-quality heated rubies. (The current auction record is darin (spessartine) garnet from Nigeria; tanzanite from
held by an unheated 8.62 ct Graff ruby, of Burmese origin, Tanzania; green sphene from Sri Lanka; and “canary” tour-
which sold for $8,372,094—or $994,040 per carat—at a maline from Zambia (figure 21).
Sotheby’s Geneva auction in September 2014.) Purchasing
such expensive stones is a stretch even for the top 1% of
Figure 21. Constantin Wild displays a unique 290
consumers. By contrast, stones like the three Bindra showed
carat multicolored gem suite. Photo by Duncan
us wholesale in the region of $35,000 to $50,000 per carat.
Pay/GIA.
He said gems like these are “quite consumable” and can be
the centerpieces of wearable jewelry, meaning they will oc-
casionally be seen outside of safe deposit boxes.
Bindra faces the same issue as many other colored stone
dealers in Tucson: scarcity of new rough production due to
intense competition between the U.S. market and buyers
purchasing for Chinese consumers. This is the major driver
for dealers looking for alternative sources of gems such as
recirculated goods, he said.
The new wealth in China has created a different dy-
namic. For more than 50 years, American and European
consumers have been the main buyers of fine gemstones,
he explained. Now these established markets have compe-
tition, and Bindra and many of his colleagues in the busi-
ness supply gems to these competitors as well. Besides
China, other cultures—India, for instance—have a rich
jewelry heritage, and consuming gems is ingrained. This
trend is not going to change, so there will be more wealthy
consumers in emerging markets that desire colored gems,
and current producers will struggle to meet demand.
In terms of demand at the show, Bindra reported that
rubies and unheated sapphires were quite strong. There
was demand for anything rare and exotic, goods that the
average consumer would not find elsewhere. He also saw
renewed demand for emerald. In the past, he noted a “cer-
tain favoritism” toward Colombian emerald, but increased
supplies of quality gems from Zambia have made it a much
more popular source and established the “Zambian brand”
in people’s minds.
Duncan Pay
High-end colored gems. At GJX, Constantin Wild (W. Con-

stantin Wild & Co., Idar-Oberstein, Germany) showed us
a remarkable multicolored suite composed of 12 gems from
all over the world. The total weight was 290 carats, with

Figure 22. 26.18 ct and 19.83 ct “canary” tourmalines
from Zambia. Photos by Duncan Pay/GIA; courtesy
of Constantin Wild.
Wild specifically highlighted canary tourmaline (figure

22). He remarked that its intensity of color is reminiscent Figure 23. This superb 339.42 carat suite of 10 rubel-
of Paraíba tourmaline. Found intermittently in the 1980s lite tourmalines contains Brazilian gems with a
and marketed since the early 2000s, this typically yellow- Nigerian center stone. The gems in the suite range
green material is rich in manganese (up to 9.18 wt.% MnO). from 39.61 to 77.16 carats (center stone). Photo by
Wild had two significant oval-cut gems of 19.83 and 26.18 Duncan Pay/GIA; courtesy of Constantin Wild.
ct, both unheated. For more information on this unique
gem, see www.gia.edu/gems-gemology/winter-2007-yellow-
tourmaline-zambia-laurs. and treated blue topaz, along with more unusual arrange-
Another standout at Wild’s booth was a superb suite of ments: demantoid and “Mali” garnet with fire opal, or yel-
rubellite tourmaline totaling 339.42 carats (figure 23). Wild low beryl and mandarin garnet.
called it a suite “from two continents,” as it contained Another trend was the use of facet-grade rough for cabo-
both South American and African gems. The suite featured chons. These were often of large size and superb color. Of
a spectacular cushion-cut 77.16 ct Nigerian rubellite cen- particular note were a 104.83 ct tanzanite and a 140.95 ct
terpiece from new production, measuring 28.30 × 24.87 kunzite spodumene (figure 25).
mm, framed by nine perfectly matched Brazilian rubellites Duncan Pay
from previous inventory weighing 262.26 carats.
Besides his higher-end single gems and suites, Wild also Tsavorite garnet and Mahenge red spinel. At GJX, Daniel
displayed some mixed-color sets, which he described as Assaf (The Tsavorite Factory, New York City; figure 26) ex-
more “fashion-oriented” combinations (figure 24). In- plained the current market situation for tsavorite garnet,
tended as concepts for jewelry designers, they included Tanzanian red to pink spinel, and yellow danburite. Ac-
color combinations such as opal with pink tourmaline and cording to Assaf, the recent recession and the ensuing dis-
morganite beryl with red tourmaline, tanzanite, tsavorite, ruption in supply had less of an impact on his business
Figure 24. Constantin

Wild’s selection of
mixed-color sets for
jewelry designers in-
cluded some interest-
ing combinations.
Photo by Duncan
Constantin Wild.

garnet. It is usually recovered as a byproduct of tanzanite
mining. Every so often, he related, miners find a productive
pocket and buyers fly in within a couple of weeks.
According to Assaf, the stones on the tray in front of us
(figure 27) were from the latest small pocket and had been
in the ground just a few months earlier. After the initial
flurry of buying activity, Assaf said, it might be another
Figure 25. Left: A 140.83 ct tanzanite cabochon with year or two before a similar discovery. In the meantime,
superb color and clarity. Right: Kunzite is rarely seen the miners might bring buyers the occasional stone—at
in cabochon cuts. The color and clarity of this 140.95 much higher prices.
ct example make it noteworthy. Photos by Duncan In Assaf’s opinion, today’s tsavorite rough prices in
Pay/GIA; courtesy of Constantin Wild. Arusha are almost “out of control.” In effect, there is a dis-
connect between the Arusha prices and the prices in Tuc-
son, which will likely take several years to readjust.
than increasing demand from China. For him, current His company stops buying before the Tucson show be-
rough scarcity and high prices relate more to the growth in cause the clientele here will not pay the high asking prices.
the Chinese jewelry market, which 5 to 10 years ago was He cited an instance several weeks earlier in which buyers
a fraction of its size today. were offering him top-quality rough for approximately
Assaf explained that both tsavorite and spinel are rare $10,000 per stone, in sizes sufficient to cut 3 ct finished
stones, and even minor changes in the market might have gems. A stone cut from this rough would have a per-carat
a considerable impact. If just a fraction of one percent of price well above what the market at the Tucson show
Chinese consumers becomes interested in tsavorite, this would pay. Besides the high asking price, Assaf said there
has a measurable consequence for supply, especially if pro- is a significant element of risk in buying rough: “You never
duction in mining areas is static or even showing slight de- know what kind of unpleasant surprises you might find.”
clines. According to Assaf, the biggest tsavorite purchasers He pointed out that there are places in the world where
at the source in Arusha, Tanzania, are Sri Lankans buying such high prices are accepted—China and possibly parts of
for the Chinese domestic market. These buyers are pre- Europe—which is why the few fine rough tsavorites that
pared to pay very high prices for tsavorite rough. become available every month are snatched up. Assaf had
To illustrate the sporadic nature of current supply, Assaf just heard of a 7-gram piece of tsavorite—perhaps suitable
cited a bright, light-toned green grossular garnet. This ma- for a 10 ct finished gem—that sold for $200,000 in Arusha.
terial has become popular and is sold as “Merelani mint” Assaf showed us two examples of the finest tsavorite col-
Figure 26. Daniel and

Andre Assaf of the Tsa-
vorite Factory ex-
plained the current
market for tsavorite.
Photo by Duncan
Pay/GIA.

stone. If it is pale but still has a bluish component to the
green, he would classify it as a “mint” garnet.
We asked Assaf how recent Chinese demand has af-
fected tsavorite prices. He said that for sizes under 2 ct,
prices have increased as much as 30–40%. The impact has
been most dramatic in larger stones: For gems larger than
3 ct, prices have tripled. He felt that prices for large tsa-
vorites have gone up in relation to emerald and other gems
due to scarcity of supply and high demand.
To emphasize the point, Assaf chose a suite of three tsa-
vorite pear shapes totaling 37.79 carats (figure 28, right).
Each gem was above 10 ct and of the highest clarity, so they
constituted exceptionally rare material. Aside from these
standouts, Assaf admitted he had few stones of such size—
large stones are typically a Tsavorite Factory specialty—due
to the prohibitively high price of rough. He lamented that
with today’s stratospheric prices, he would have to pay
around $200,000 to obtain another 7-gram piece to cut an-
other 10 ct gem. And very few clients—likely none at this
show—would accept the resultant high per-carat prices for
the finished gem. That leaves two possibilities: Either the
prices will adjust in Arusha, or they will become accepted
in the U.S.
Assaf recounted that some of the same market factors
apply to red spinel. His company does not carry spinel from
Myanmar, focusing instead on Tanzanian material. This
year, he said, a specific color people were calling “Ma-
Figure 27. These light-toned Tanzanian grossular gar-
henge”—deep pink with a touch of orange, almost like a
nets—termed “Merelani mint”—were mined just a
padparadscha color—was in extremely high demand (figure
few months prior to the Tucson show. Photo by Dun-
29). Assaf had sold all of his “Mahenge” spinel but none of
can Pay/GIA; courtesy of Tsavorite Factory.
the other colors. While these lavenders, blues, and mauves
are quite beautiful and competitively priced at around 10%
ors. In his opinion, both are of equal merit (figure 28, left). of the pinks, the red to pink spinels are what his clients
Some clients love the deeper, darker color, while others pre- seek. Assaf also mentioned that buyers looking for some-
fer a brighter, lighter-toned green. In either case, he said, the thing unusual picked yellow danburite from Tanzania, and
most important consideration is to have a blue color com- that this gem had sold quite well for him at the show (Sum-
ponent rather than a yellow one. As long as the gem is not mer 2008 GNI, pp. 169–171).
overly dark, and has a bluish cast to the green, it is a quality Duncan Pay
Figure 28. Left: Some prefer tsavorite garnets with a brighter color, while others prefer a darker appearance. The
stone on the left weighs 9.50 ct. Right: This suite of three pear-shaped tsavorites totals 37.79 carats. The approxi-
mate asking price for such fine gems would be about $15,000 per carat. Photos by Duncan Pay/GIA; courtesy of
Tsavorite Factory.

Figure 29. An example of “Mahenge” spinel from Tan- Figure 30. Fashioned by lapidary Jean-Noel Soni, this
zania. This was one of the few examples left at Daniel 35.50 ct mixed-cut sunstone is reportedly from a
Assaf’s booth at the time of our interview. Photo by mine on Eagle Butte, in Oregon’s remote Harney
Duncan Pay/GIA; courtesy of Tsavorite Factory. Basin. Photo by Robert Weldon/GIA; courtesy of
Suncrystal Mining.
Oregon sunstone update. At the GJX Show, Nirinjan Khalsa the integrity of natural, untreated Oregon sunstone and pro-
(Suncrystal Mining, Lake and Harney Counties, Oregon) mote it to retailers and consumers as a rare and desirable
showed us a remarkable 35.50 ct rich orangy red Oregon “all-American” gemstone. Called the Oregon Sunstone
sunstone fashioned into a modern mixed-cut cushion by Miners Association (OSMA), the organization includes most
lapidary Jean-Noel Soni (Top Notch Faceting). This stone of the miners with working claims or mines in Lake and
(figure 30) resembled a fine ruby under the showcase lights Harney Counties (figure 32). OSMA also offers an associate
and was one of the most exquisite examples we had seen. membership for sellers of loose gems or jewelry. Anyone
At Khalsa’s request, we followed up with Soni after the purchasing sunstone from an OSMA member can be assured
show. He told us the original rough weighed 198.82 ct. As they are getting the natural, untreated Oregon product. The
is typical with Oregon sunstone, the rough contained spots intention is to expand the marketplace for this unique gem
of strong red or green color in the cores of otherwise yellow and maintain stability and consumer confidence in the
or near-colorless crystals. This crystal had two color spots, event of an influx of treated material from another source.
so he divided it, and this gem was the first of two he in- The association’s website is www.oregonsunstonema.com.
tended to cut. Rather than using CAD software to design At the AGTA show, John Woodmark (Desert Sun Min-
his gems’ faceting styles, Soni treats each rough as unique ing & Gems, Depoe Bay, Oregon) provided an update of his
and individual, cutting to maximize color and luster. He
explained that the pavilion had to be deep, due to sun-
stone’s relatively low RI (1.563–1.572). This produced a Figure 31. This 156.00 ct rough sunstone belongs to
63.00 ct preform, from which he faceted the 35.50 ct gem the Dust Devil mine’s Mark Shore and will likely be-
we saw. The asking price for this gem—reportedly from come a fine carving. Photo by Duncan Pay/GIA; cour-
one of the mines on Little Eagle Butte (in Harney Basin, tesy of Mark Shore.
near Plush, Oregon)—was in the region of $60,000.
Also at the GJX show, Don Buford and Mark Shore (Dust
Devil Mining, Plush, Oregon) gave an update on their oper-
ations. They said 2014 was a good year at Dust Devil. They
uncovered a former dried creek bed where the basalt was ex-
tensively decomposed, which has allowed easier recovery of
the sunstones. Buford hopes to have the mine’s optical sorter
operational for the 2015 mining season.
Shore showed us an exceptional 156.00 ct “water-
melon” sunstone from recent production (figure 31). The
stone has a red center surrounded by a greenish “rind.”
Shore has made arrangements to have it carved by Dalan
Hargrave, winner of multiple AGTA Spectrum Awards.
At the 22nd Street show, Terry Clarke, co-owner of the
Dust Devil mine, explained a recent initiative to maintain

Figure 33. This 2.77 ct “spinel red” sunstone, measur-
ing 10.5 × 8 mm, is from Oregon’s Ponderosa mine.
Photo by Robert Weldon/GIA; courtesy of Desert Sun
Mining & Gems.
cuts costing several thousands of dollars per piece. Accord-

ing to Woodmark, one buyer for a major TV jewelry retailer
at the Tucson shows said that Internet business was now
40% of the company’s total sales volume.
Woodmark estimated the total volume of fashioned
Oregon sunstone on the market in 2014 was approximately
70,000 carats. By his calculations, that would be sufficient
to supply one large U.S. retail jewelry chain with 10 carats
per store per month over the course of a year. If demand
Figure 32. Dust Devil Mining’s Terry Clarke holds a picks up in 2015, that volume will not meet the industry’s
flyer promoting the Oregon Sunstone Miners’ Associa- needs. Woodmark reported that business was up 25% on
tion. Photo by Duncan Pay/GIA; courtesy of Dust the previous year’s show, which was up one-third on the
Devil Mining. year before.
In the 2014 mining season, Woodmark employed up to
five pickers working the screens. He worked the mine for a
operations at the Ponderosa mine and summarized the cur- total of 20 days and produced almost 2,000 kg of rough in
rent market for his goods. He showed us a striking 2.77 ct all grades. Woodmark plans to work for 40 days in 2015 and
“spinel red” gem from recent production (figure 33). expects to recover 4,000 to 5,000 kg of rough. To start the
According to Woodmark, 2014 saw heightened interest upcoming mining season, Woodmark will bring in heavier
in Oregon sunstone. He received requests for rough from machinery and extend the pit back into the hillside. He will
clients in Australia and for finished stones from Brazil and also bring in a bulldozer with a ripper to tear up the pit floor
Europe (principally the UK and Germany). At this particu- and start moving downward, too. Late 2014 saw recovery
lar show, Woodmark said he had received many more in- of larger rough, some pieces up to 70 grams (figure 34). In
quiries from domestic jewelers for samples and addition, the pit’s “red zone,” with a higher proportion of
information, all following customer requests due to grow- red-cored rough (up to 20%), remained productive. Wood-
ing public awareness of the gem. He cited a TV shopping mark expected the trend of bigger, better stones to continue
channel’s recent promotion of production from the Sun- as the miners work deeper into the deposit. This is similar
stone Butte mine and the growing reach of his Internet to the situation at Sunstone Butte, he remarked.
business. For more information on the Sunstone Butte Anticipating higher demand, he also planned to cut
mine, see www.gia.edu/gia-news-research-butte-sunstone. more frequently in 2015. Rather than cutting two to three
Woodmark observed that Internet merchandising, often times per year, he will cut 2,000 to 4,000 kg per month
by TV jewelry shopping channels, has been transformative (new production plus stockpiled rough), depending on his
for low-volume, one-of-a-kind products like Oregon sun- needs. As 4,000 kg equates to approximately 2,000 carats
stone. Web marketing frees traditional TV merchandisers of finished stones, Woodmark expected his production to
from the production costs of on-air hosts and studios, and significantly increase market availability of Oregon sun-
allows the cost-effective presentation of a spectrum of Ore- stone in 2015.
gon sunstone from “bargain parcels” to unique designer Like all the Oregon sunstone mines, Ponderosa pro-

Figure 34. The 2014 season saw some larger rough sunstone from Ponderosa mine in the 20–70 gram range. As op-
erations go deeper, stone size seems to increase. Photo by Duncan Pay/GIA; courtesy of Desert Sun Mining &
Gems.
duces a substantial quantity of yellow and near-colorless like QVC are moving away from that concept, in essence
labradorite—material with little or no pink or red and no marketing the uniqueness of the gem rather than a unifor-
visible coppery reflections. One of the things Woodmark mity it can never provide. He cited a piece for which he sup-
has learned at this show is the importance of cutting style plied 3.0, 4.0, and 5.0 mm calibrated gems. One was a
and quality on a gem’s perceived value. He sold 2 kg of yel- top-quality red sunstone, and the others were paler pink. In
low rough to another vendor at the AGTA show—Ken Ivey this way, the manufacturer does not have to match the
(Ivey Gemstones, Prescott, Arizona)—and was astonished stones and can use larger volumes.
at the result. Duncan Pay
Ivey’s use of concave cutting styles (figure 35) presented
the feldspar’s bright yellow color far more effectively than
conventional cuts. With conventional cutting, Woodmark Figure 35. The concave cutting style used on these
struggled to get a few tens of dollars per carat for yellow Oregon feldspars accentuates their yellow color and
goods. With only a modest investment in extra cutting raises the market value of the material. Photo by
costs for concave faceting—perhaps twice the expendi- Duncan Pay/GIA; courtesy of Ivey Gemstones.
ture—the same material can sell for up to five times as
much. As the yellow rough sells for a couple hundred dol-
lars per kilogram, this is a potentially significant value ad-
dition in the finished product.
Another encouraging trend Woodmark sees is that de-
signers and jewelers are mixing calibrated sunstones of dif-
ferent shapes and colors in the same jewelry piece. The
casting is standardized, but because every combination is
unique there is no longer the need to match them. Volume
business with sunstone jewelry has always been hampered
by the perception that every stone in a piece has to match
and every piece must be uniform.
In Woodmark’s opinion, even home shopping channels

Figure 38. Marketed as “ginger” garnet, these four gar-
nets range from 8.33 to 35.54 ct. Photo by Robert Wel-
don/GIA; courtesy of Advanced Quality.
Mehraj Uddin exhibited two large topaz of exceptional

Figure 36. Noor Gems showcased afghanite from
pink to red color (6.38 and 12.08 ct). As with virtually all
Badakhshan Province, Afghanistan. Photo by Dun-
pink topaz, he acknowledged that these fine stones were
can Pay/GIA; courtesy of Noor Gems Japan Ltd.
heat treated. Debuting at Noor’s GJX booth was pinkish pur-
ple copper-bearing tourmaline from Mozambique (figure 37).
Large and unusual gems. The inventory of Noor Gems For some large and exceptional gemstones, such as a
Japan Ltd. at the GJX show was characterized by large and 254.50 ct peridot cabochon from Pakistan, Uddin admitted
unusual gems, including a fine selection of rare blue and they hold on to these stones for 10 or 20 years. The com-
pink gemstones: afghanite, hauynite, hemimorphite, and pany is reluctant to sell them because of the difficulty in
pezzottaite. Bright blue afghanite (figure 36), which the replacing such inventory. They will only sell when they
company has been selling for three years, was available in feel the market is high.
gem quality in the 0.3–1.5 ct range, priced at approximately Donna Beaton
$500–$700 per carat. It has been especially popular with
Noor’s Japanese clientele. Afghanite is a relatively soft Ginger garnet, “fancy” tanzanite. Kobi Sevdermish (Ad-
stone for jewelry, with a hardness 5.5 to 6, best suited for vanced Quality, Ramat Gan, Israel) showed us large fine
pendants and earrings. While near-colorless material can “ginger” garnets and discussed the cutting of natural-color
be found in Italy and Germany, the recent production of tanzanite crystals. The garnets are from a new find in Tan-
blue afghanite is from Badakhshan Province, Afghanistan. zania, discovered in late 2014. In large sizes, the stones
have a pleasing “open” pinkish orange or orangy red hue
(figure 38). By “open,” Sevdermish meant the tone is not
Figure 37. Another attraction at the Noor Gems booth
too dark, remaining lively and relatively bright even in
was pinkish purple copper-bearing tourmaline from
sizes above 30 ct. He noted that many red garnets cut in
Mozambique, which they labeled as “Paraíba.” Photo
large sizes have a tendency to become very dark, and this
by Duncan Pay/GIA; courtesy of Noor Gems.
material avoids that pitfall. If fashioned correctly, it
“pops.” Along with the virtues of lighter tones and rela-
tively large sizes, it possesses high clarity.
Supply has been limited—Sevdermish had only seen a
few parcels of larger rough suitable for cutting gems up to
40 ct—and some of this material was of lower clarity. Stan-
dard gemological testing revealed an RI of 1.74 and an SG
in the range of “Malaya” garnet (3.78–3.85).
As in 2014, Sevdermish reported that “natural-color”
tanzanite remained a very successful item for Advanced
Quality. He showed us a selection of unheated gems in a
range of subtle secondary colors (greens and pinks) behind
the predominant “typical” blue to purple tanzanite colors
(figure 39). Sales have been strong in Europe and particu-
larly Asia. According to Sevdermish, this is because no two

Figure 39. A selection of reportedly natural-color, un-
heated tanzanites ranging from 9.93 to 27.86 ct. Photo
by Duncan Pay/GIA; courtesy of Advanced Quality.
are exactly alike. To demonstrate, he showed us a large

suite of mixed fancy colors (figure 40).
He explained that rough of “odd” colors—unheated
pinks and greens—did turn up over the years, but in the
last year and a half, material from Block B of the tanzanite
mining area has provided some “magnificent” natural col-
ors: lavender, cognac or golden colors, and very rare pink
and yellow and green.
Sevdermish noted that buying suitable tanzanite rough
in these colors is a painstaking business, even though the Figure 40. Kobi Sevdermish of Advanced Color shows
company has cultivated connections in Africa that locate off natural-color tanzanite, including a remarkable
this material for them. Some purchases take time, he said, multicolor necklace of almost 170 carats total. Photo
and require him to extend buying trips to obtain a few spe- by Duncan Pay/GIA.
cial, unique pieces. He added that it takes persistence to
negotiate with miners and their representatives. And if no
other buyers outbid you, you succeed. Sevdermish said that pecially the rough for this “fancy-color” tanzanite, the re-
many of the stones at his booth were cut about a week and sults are less foreseeable. The rough for the 27.59 ct gem
a half earlier. promised a “kaleidoscope of colors” blending pink, yel-
Advanced Quality documents, through video recording low, and green, so Sevdermish expected to see an inter-
and photography, each rough piece as it goes through the play of colors inside the fashioned gem. Instead, he was
planning, sawing, and faceting process—in essence, the dismayed to find the gem was colorless. Fortunately, Sev-
mine-to-market story of each significant gem. In this way,
Sevdermish asserted the company can show—to the best
of its knowledge—the unheated nature of its gems to Figure 41. This 27.59 ct unheated, natural-color
clients. Many of the stones promoted as “unheated” in the zoisite or “fancy” tanzanite shows a subtle tint of lilac
market are actually the products of less-than-successful pink against a greenish yellow bodycolor. Photo by
heating, he explained. Robert Weldon/GIA; courtesy of Advanced Quality.
Just a couple of weeks earlier, he managed to obtain a
few large pieces of rough with unique light yellow colors,
one of which yielded a 27.59 ct antique cut (figure 41). The
gem came out predominantly greenish yellow, but with
flashes of lilac pink, which is what Sevdermish initially
expected from the rough. The company debated whether
to cut the original rough, as it was such a spectacular piece,
but ultimately decided to fashion it because the crystal was
not quite perfect enough to be a specimen.
Sevdermish described buying and cutting rough as a
lottery. Certain gems—some spinels or even regular tan-
zanite—are more or less predictable. But with others, es-

dermish reported, the hoped-for greenish yellow color re-
turned after the gem had “rested” for two days in its par-
cel paper.
Duncan Pay
Gem artistry in smaller sizes. At GJX, we caught up with

gem artist Alexander Kreis (Sonja Kreis Unique Jewelry,
Niederworresbach, Germany). It is a family business, with
his father buying the rough, his mother designing the jew-
elry, and Alexander cutting the gems. Kreis had placed
their best Oregon sunstone and their largest rutilated
quartz pieces prominently in the booth to achieve a “wow”
effect. Immediately beneath those signature pieces, Kreis
had positioned more accessible gems that customers could
use to make more affordable jewelry items. Although
smaller than his trademark pieces, these were invested
with the same precision and beauty. He produces pairs that
would be ideal for earrings or even men’s cufflinks. Kreis
spoke about three of these more accessible lines, involving
tourmaline, citrine, and blue topaz.
For Kreis, green and pink tourmaline symbolize the col-
ors of the rainforest, so their design evokes the vivid foliage
and blooms of that environment. The curves provide a
fluid elegance, and the cuts on the underside capture the
veins and structure of tropical leaves.
Among Kreis’s new product designs for this year are cit- Figure 42. Gemstone artist Alexander Kreis holds a
rines cut in a more angular style, with very detailed carv- sun carving, one of his new designs in citrine. Photo
ings on the back representing sunrays (figure 42). To Kreis, by Duncan Pay/GIA; courtesy of Sonja Kreis.
citrine’s color represents the heat of the sun, while the
carvings channel its intense slanted rays.
In striking contrast, another new design he called gem’s frosted sides. The design and the material combine
“frozen topaz” (figure 43) uses the icy hue of treated blue to produce an icy brilliance. As the wearer moves the gem,
topaz to evoke arctic waters. The carving in the center is Kreis said, it produces “a harmony of light points dancing
smoothly polished; the light rays, which are reflected from through the stone.”
the polished carving, produce pinpoints of light on the Duncan Pay
Figure 43. In these ex-

amples of “frozen
topaz,” the smooth
carvings contrast with
the frosted textures and
lend an icy brilliance to
the finished gems.
Photo by Duncan
Sonja Kreis.

Figure 44. This edge-on view of the “wheel of light”re- Figure 45. Seen end-on, the larger disk displays the
veals its construction. Photo by Duncan Pay/GIA; spectrum as concentric colors. Photo by Duncan
courtesy of Nature’s Geometry. Pay/GIA, courtesy of Nature’s Geometry.
Larger optic disks. At the 2014 GJX show, Brian Cook (Na- ous directions the disk was suffused with bands of rich
ture’s Geometry, Graton, California) showed us innovative green, electric blue, or royal blue color.
optical disks made of colorless quartz featuring a drilled According to Cook, this new product takes the color
tube containing pieces of brightly colored gem and mineral and amplifies it. There is a chamber within the quartz,
rough. The tube is subsequently sealed with clear quartz. which he polishes before inserting the colors he wants. Be-
When the disk is viewed face up, the insert’s reflections cause no faceting is involved, all the colors are blended to-
permeate the disk with bright color. gether. Cook said his passion for Paraíba tourmaline was
For this year’s show, Cook’s “wheel of light” design the starting point.
evolved into larger sizes with more intriguing reflective ef- Cook unwrapped a larger disk, approximately 8 cm
fects. Seen front-on, the new disks produced concentric (3.15 in.) in diameter. Viewed edge-on, the chamber’s pat-
colored reflections. The first we saw measured approxi- tern of colored rough gems and minerals was revealed (fig-
mately 4 cm (1.57 in.) in diameter and featured Brazilian ure 44). Cook had arranged a complete spectrum of
emerald, Paraíba tourmaline, and haüyne insets (haüyne is rainbow colors in sequence: ruby, spessartine garnet, a gold
a brittle sodium calcium sulfate that provides rich blues). nugget, Paraíba tourmaline, and haüyne (figure 45).
One innovative feature is that the viewer could see differ- Cook also showed us a smaller optic disk set in a hand-
ent colors depending on the viewing direction. From vari- made platinum pendant set with diamond and melee-size
Paraíba tourmaline from the Brazil Paraíba mine in Parel-
has, Rio Grande do Norte. This piece combined the un-
Figure 46. This unique 303 carat “Snow White” tour-
usual optic effects of the center, which featured more
maline suite was reportedly carved in Idar-Oberstein
Paraíba tourmaline and haüyne, with a conventional suite,
in the 1970s. Photo by Duncan Pay/GIA; courtesy Jan
which besides the pendant included a pair of earrings set
Goodman Co.
with similar optic disks.
Duncan Pay
Unusual carved tourmaline suite. Jan Goodman (Beverly

Hills, California), had an exquisite 303 carat suite of
carved, particolored tourmaline depicting Snow White and
the Seven Dwarfs (figure 46). In most depictions of the
dwarfs in a line, the lead figure is “Doc” carrying a lantern.
In this series, in a nod to the jewelry industry, the lead
dwarf is depicted carrying a beaded necklace. Goodman re-
calls that the set was carved in Idar-Oberstein in the 1970s
and came to him mounted in the presentation case. The
suite had been in his personal collection for more than 30
years. Goodman told us “demand and price are finally in
such a place as to justify parting” with it.
Donna Beaton

Figure 47. A carved agate and leaf pendant featuring Figure 48. A platinum pendant featuring 13 natural
diamond and tsavorite accents. Photo by Robert Wel- colored diamonds (6.31 carats total) with an 18K yel-
don/GIA; courtesy of Jeff Bilgore, LLC. low gold and platinum chain featuring 36 oval fancy
color diamonds (4.23 carats total). Photo by Robert
Weldon/GIA; courtesy of Jeff Bilgore, LLC.
Gemstones and jewelry inspired by nature. Jeff Bilgore has

18 AGTA Spectrum Awards to his credit in both the cut- Rare stones in demand. For Brad Wilson and John Brad-
ting and design categories. His booth in the AGTA Gem- shaw (Coast-to-Coast Rare Stones International, Kingston,
Fair featured two pieces that departed from the norm of Ontario), their inventory of corundum and other familiar
colored stones: an exquisitely carved leaf brooch of moss
agate, highlighted with diamonds (figure 47), and a plat-
inum pendant panel and chain featuring natural-color
Figure 49. A 5.69 ct Australian crystal opal is accom-
fancy diamonds that appeared to float within the frame
panied by an image of the aurora borealis on a tiny
(figure 48). The cut-corner rectangular panel, reminiscent
easel. Photo by Towfiq Ahmed; courtesy of Jeff Bil-
of a classic Cartier design, featured 11 natural colored di-
gore, LLC.
amonds (5.68 carats total, all with GIA reports confirming
Fancy, Fancy Vivid, or Fancy Intense hue), paired with a
chain featuring 36 additional oval fancy colored diamonds
(4.23 carats total).
After viewing the selection of carefully curated gem-
stones, one becomes aware of the entwined themes of art
and nature. Bilgore espouses the principle of biophilia, the
belief that humans intuitively respond positively to nature.
Rather than viewing gemstones as inanimate objects, Bil-
gore sees them as part of nature, and he displays many of
the gemstones and jewelry pieces with a tiny easel featur-
ing an associated image (figure 49). A 5.69 ct Australian
crystal opal, exhibiting play-of-color in all hues, was dis-
played with an image of the aurora borealis. Some of the
other images are Bilgore’s own photos, taken in his garden
or while hiking. In a further nod to nature, the design of
the colored diamond panel pendant was inspired by the
Golden Mean and the Fibonacci series, mathematical rela-
tionships often found in nature and incorporated into man-
made creations as diverse as music and architecture.
Donna Beaton

ple is tugtupite, a rosy-pink mineral, usually found in ag-
gregate form, that exhibits both interesting fluorescence
and tenebrescence. It sold out on the first day in previous
shows, according to Wilson, but in 2015 only a few had
sold by the third day.
Donna Beaton
Color-change garnets from Tanzania. At the Riverpark Inn

(Pueblo) show, Todd Wacks (Tucson Todd’s Gems, Tucson
and Vista, California) showed us interesting color-change
or color-shift garnets from Tanzania (figure 51). According
to Wacks, they were mined in Morogoro, Tanzania, back
in 1988, and documented the same year (see C.M. Stock-
Figure 50. Brightly colored sphalerite is one of the ton, “Pastel pyropes,” Summer 1988 G&G, pp. 104–106).
most popular “unusual” gems sold by Coast-to- The material resembled rhodolite rough and contained fine
Coast. Photo by Duncan Pay/GIA; courtesy of Coast- needle-like inclusions—most likely rutile.
to-Coast Rare Stones International. The gems were pinkish purple in daylight and showed
a color change from intense pink in warm incandescent
light to purple—almost like a fine amethyst—in cool LED
gemstones never makes the trip to Tucson. Instead, their light. Wacks said the larger stones display the most pro-
showcases are filled with rarities such as afghanite, bast- nounced color change. Very similar color change phenom-
naesite, beryllonite, clinohumite, celestite, hambergite, ena have been reported for other purple “pastel pyropes”
magnesite, montebrasite, pargasite, sphalerite, violane, and from Tanzania, Sri Lanka, and Madagascar.
zincite. These stones often are soft and near-colorless and The rough had been stuck in a safe deposit box for
have cleavage, making them less desirable for jewelry. But years, he said, because most potential buyers assumed it
for a collector or a designer looking for the unusual who was rhodolite, saw the inclusions, and lost interest. Wacks
understands how to work with such challenging stones in recently acquired the 2–4 kg of rough, cut a few pieces, and
jewelry, Coast-to-Coast at GJX is a worthwhile destination. discovered the color change. He has been promoting the
Some of the lesser-known stones available at Coast-to- gem since then.
Coast included datolite, cobaltocalcite, faceted aragonite, He sent samples to Dr. George Rossman (California In-
and tenebrescent scapolite. Fluorescent opal was a note- stitute of Technology, Pasadena), San Diego gemologist
worthy new find. Under ordinary interior lighting, this opal Kirk Feral, and GIA. According to Wacks, the gems are ap-
is near colorless to very pale yellow. It can fluoresce bright proximately 80% pyrope, 10% spessartine, and 10% al-
green in response to the small UV component in ordinary mandine, with an RI of 1.736. (This material will be the
daylight. Placed under an ultraviolet light or 405 nm laser, subject of a more detailed paper in the Summer 2015
the fluorescent effect is spectacular. G&G.)
With unfamiliar collectors’ stones, colorful varieties Sharing booth space with Wacks was colleague and jew-
usually sell best. Wilson’s more popular items for this show elry designer Mary van der Aa (vdAaco, Vista, California).
included sphene, sphalerite (figure 50), and apatite. He told She produces jewelry designs for many of the gems he cuts,
us that other stones rise and fall in popularity. One exam- including pastel pyropes and pink tourmalines from some
Figure 51. This 7.61 ct “pastel pyrope” shows a strong pink color in warm incandescent light and a strong purple in
cool LED light. Photos by Duncan Pay/GIA; courtesy of Tucson Todd’s Gems.

Figure 52. This hand-fabricated 14K rose gold and yel-
low gold pendant by Mary van der Aa features a 6 ct
“hot pink” tourmaline from the Stewart mine, cut by
Todd Wacks. Photo by Duncan Pay/GIA; courtesy of
vdAaco.
Figure 53. Top: This vibrant 2.08 ct oval pink sapphire
flanked by a pair of warm-hued spessartine garnets
totaling 3.41 carats strikes a tropical note. Bottom:
of the mines in San Diego County (figure 52). Her jewelry This bold pendant and earring suite features three
also features stones cut by renowned gem artist Meg Berry. marquise-shaped tanzanites totaling 6.73 carats, with
Duncan Pay modified trilliant rubellite tourmalines of 14.20
carats total. Photos courtesy of Stephen M. Avery.
Bold color combinations. For retailers and designers over-
whelmed by the endless rows of gemstones lined up in
trays, inspiration could be found at the booth of Stephen approximately 1.5 in the blue area, and a 1.46 spot reading
M. Avery (Lakewood, Colorado). Avery presented “state- in transparent areas. Specific gravity ranged from 2.36 to
ment”-sized gemstones in suites of bold color combina- 2.47. The fluorescence reaction to long-wave UV was weak
tions (figure 53). His company has mainly sourced African white in fractures and the transparent areas. Raman analy-
stones but is now traveling to Asia to add brightly colored sis confirmed that the blue material was chrysocolla, the
sapphire and spinel to its design palette. Avery, an expert transparent to whitish areas were quartz, and the transpar-
cutter as well as buyer, fashioned all the gemstones in his ent cryptocrystalline areas were chalcedony. Raman analy-
inventory. The combination of craftsmanship and creative sis also indicated the presence of a hardened glassy polymer
inspiration appeared to have paid off, as he reported the (polymethyl methacrylate). FTIR also confirmed the poly-
company’s best show ever. mer, corroborating the stabilization that Heher indicated
Donna Beaton
Figure 54. 52.96 ct and 19.16 ct chrysocolla in quartz,
Chrysocolla in quartz. The Rare Earth Mining Company obtained from Rare Earth Mining Company at the
(Trumbull, Connecticut) booth at the AGTA show dis- AGTA show. Photos by Jian Xin (Jae) Liao.
played a specialized inventory of unique and rare materials
available as finished gemstones, mineral specimens, and
fossils. Curt Heher, Rare Earth’s president of sales, reported
more than 300 companies placing orders in finished stones
alone: “We enjoyed our biggest Tucson show in 40 years.”
We obtained two cabochons of blue-spotted clear and
near-colorless quartz (figure 54) that were reminiscent of
“K2 stone” or “Raindrop azurite” seen in previous years
(Spring 2012 GNI, pp. 55–56). Heher’s father bought the
rough, which was crystallized around blue stalactites, at
auction in the 1980s. It remained in storage until recently.
The material was reportedly mined in Globe, Arizona, in
the 1970s.
Gemological examination of the 19.16 and 52.96 ct
cabochons revealed an RI of 1.54 to 1.55 in most areas, but

was needed to prevent crumbling or fracturing during the
cutting and polishing process. The treatment conclusion
on a GIA report would be “impregnated” or possibly “com-
posite” if the polymer occupied significant volume or sur-
face area.
Chrysocolla in quartz is not uncommon, but it is rare
to see such defined stalactites resulting in a distinct orbic-
ular pattern. This material often remains as mineral spec-
imens rather than being cut for jewelry purposes.
Donna Beaton and Akhil Sehgal
PEARLS
Cultured pearl market update. At the 2014 AGTA show,

Fran Mastoloni (Mastoloni Pearls, New York City) pro-
vided a market summary from his own business perspec-
tive. He emphasized surging demand in the Chinese
domestic market for all cultured pearl types, plus the
need to introduce innovative styles and pearl combina-
tions in contemporary jewelry. Since then, overall supply
of fine cultured pearls of every type has become even
more challenging.
This year, Mastoloni reported that Chinese demand for
Philippine golden cultured pearls continues unabated, and
the domestic market there is absorbing nearly all available Figure 56. Top-quality Australian South Sea baroque
production, effectively pricing them out of the North cultured pearls 15.5 × 19.0 mm and larger grace this
American market. Although never a high-turnover item in spectacular necklace. Photo by Duncan Pay/GIA;
the U.S., any such pearls sold in the American market will courtesy of Mastoloni Pearls.
likely come from suppliers’ existing inventory. And once
sold, they will not be replaceable given current market
prices. Mastoloni predicted an eventual downward correc-
tion, once the Asian market’s appetite for golden pearls is Exceptional pearls are particularly scarce. He was very con-
sated. cerned about pearl production over the next 10 years. Prior
Supply of quality Tahitian cultured pearls (figure 55) is to 2008, he said, Tahitian pearl farmers were very consci-
also becoming problematic. Mastoloni said the Tahitian entious about quality. Today, in Mastoloni’s words, “Farm-
government has ceased support of pearl farmers, with a re- ers are producing to turn over.”
sulting decline in colors, sizes, and overall product quality. [Editor’s note: On October 1, 2008, the Tahitian gov-
ernment abolished the pearl export tax, which had largely
supported the GIE Perles de Tahiti industry association.
Figure 55. Mastoloni described this fine 16.4–16.7 mm This removed the funding for the promotion of Tahitian
Tahitian cultured pearl with natural color and luster cultured pearls, leading to GIE Perles de Tahiti’s collapse
as his “new favorite pearl.” He added that top-quality in 2012. The 2008 global economic downturn drastically
examples like this are increasingly hard to find. Photo curtailed pearl sales and stressed many Tahitian pearl farm-
by Duncan Pay/GIA; courtesy of Mastoloni Pearls. ers (see A. Müller, “A brief analysis of the global seawater
cultured pearl industry,” European Gemmological Sympo-
sium, Bern, Switzerland, June 5, 2009, pp. 7–10). Since the
collapse of GIE Perles de Tahiti, producers have increas-
ingly looked to China as a promising export market, which
is also likely to affect availability for U.S. and European
markets.]
Mastoloni noted that white South Sea cultured pearls
remain the standard by which fine pearls are judged. Al-
though fine quality is still difficult to find, supply is good.
He showed us a spectacular Australian South Sea necklace
composed of white to pink 15.5 to 19 mm-plus baroque
pearls with excellent luster and unblemished surface (fig-
ure 56). Weighing in at an “extraordinary” 46.1 momme

Figure 57. Left: Long necklaces are in style. This “Wave” necklace features multicolored Tahitian cultured pearls
ranging from 7 to over 14 mm. Right: This close-up of the necklace shows its repeating color and size patterns in a
succession of “waves.” Photos by Duncan Pay/GIA; courtesy of Mastoloni Pearls.
(172.88 grams), this necklace took more than two years to Chinese freshwater pearl culturing, overall market sum-
complete. There is always the temptation to keep improv- mary. Also at the AGTA show, Jack Lynch (Sea Hunt Pearls,
ing a piece, to make it “bigger and better.” As an example, San Francisco) offered his perspective as a pearl entrepre-
he showed us a large baroque specimen that measured 23.3 neur (figure 58). Over the years he has introduced many
× 28.6 mm and weighed 4 momme (15 grams), with superb trends in cultured pearls and pearl culturing techniques to
luster, that he would like to make the centerpiece of the
necklace. Prices for baroque cultured pearls are stable with
moderate demand, he noted, but sourcing high-quality Figure 58. Jack Lynch of Sea Hunt Pearls displays
goods is somewhat difficult. strands of baroque bead-nucleated Chinese freshwa-
Mastoloni said fine akoya cultured pearls are also in ter cultured pearls at his AGTA booth. Photo by Dun-
high demand. Once again, he faces competition from Chi- can Pay/GIA.
nese buyers purchasing for their domestic market. Accord-
ing to Mastoloni, pearl farmers in China are no longer
concentrating on smaller round pearls. They are not pro-
ducing enough 5, 6, or 7 mm diameter goods in sufficient
quality, in either akoya or freshwater types, to satisfy de-
mand. The result is increased competition, with Chinese
buyers competing at the source in Japan for akoya. This de-
mand is driven by the emerging wealth of Chinese con-
sumers. Their purchasing power and the sheer quantity of
consumers in the Chinese domestic market is fueling un-
precedented demand. They are looking for better quality,
and fine Japanese akoya pearls meet that need.
In terms of trends, Mastoloni noted that “long is in.”
Double- and triple-length necklaces from 32 to more than
50 inches are very popular, he said. He has also noticed that
basic necklaces are making a comeback, and more retailers
are asking him to supply “regular” necklaces for their in-
ventory. Mastoloni showed us a double-length necklace
that made clever use of soft-colored round Tahitian cul-
tured pearls in a variety of sizes. He called it the “Wave”
necklace (figure 57). “Swells” graduating from 7 to over 14
mm form waves in repeating color patterns along the
length of this necklace (approximately 36 inches), creating
a layered look. The repeating size and color patterns lend
a sense of movement and drama.
Duncan Pay

stead of mollusk tissue. “Edison” is a backhanded tribute
to American inventor Thomas Edison.
Lynch noted that producers are continually hybridizing
the mussels used for cultivation, and that they remain very
tight-lipped about their methods. Without drilling, sawing,
or X-raying the pearls, it is difficult to fully understand the
processes or growth methods used.
He mentioned that some of the top producers in China
have become increasingly “bullish” about their products,
comparing them very favorably with the best South Sea
cultured pearls. Because the Chinese domestic market is
so strong, its consumers are prepared to pay higher prices
than consumers in countries like the U.S. The producers
are, in effect, pricing their products out of these markets.
According to Lynch, the message from these producers is
Figure 59. This spectacular strand of Chinese fresh-
that the traditional stature of their product vis-à-vis other
water cultured pearls is graduated from 15.4 to 19.3
pearl types must change. In the meantime, they will not
mm. Lynch described it as the best of four such
consider lowering their prices to satisfy traditional export
strands available when he purchased it from his sup-
markets in the U.S. and Europe.
plier. Photo by Duncan Pay/GIA; courtesy of Sea
We noticed he had a comprehensive selection of
Hunt Pearls.
baroque freshwater cultured pearls. Lynch said that while
there is moderate market demand for baroque pearls, much
of the production originates from cultivators striving for
the market, including soufflé pearls: large baroque Chinese
spherical pearls, because “that’s where the money is.” In
freshwater cultured pearls with fine luster, interesting col-
his opinion, much of the current Chinese production is
ors, and light heft (Spring 2010 GNI, pp. 61–63,
similar to “Kasumiga pearls” with textured skins that dis-
www.gia.edu/gems-gemology/spring-2010-gem-news-
play very strong orient over natural colors (figure 60).
international). Known as “ripple” pearls for their textured surface,
Lynch’s reputation for introducing new products and they are highly regarded for their prismatic effects, near-
styles leads to the same question at his Tucson booth every metallic luster, and organic shapes. As a strand wholesales
year: “What’s new in the pearl business?” Typically the for just a few hundred dollars, they present a “big look” for
question centers on freshwater cultured pearls from China. a modest outlay. For example, a very rough estimate on the
This year, he noted, the emphasis of Chinese pearl cultur-
ing innovation was on size. As evidence, Lynch showed us
a remarkable necklace composed of round freshwater cul-
tured pearls graduating from 15.4 to 19.3 mm (figure 59). Figure 60. These 16 × 13 mm bead-nucleated baroque
He had never seen a necklace of this size and quality, with Chinese freshwater cultured pearls have impressive
beautifully matched, top-quality round pearls. His supplier heft along with striking orient and warm natural col-
only had four available, and this necklace was the finest. ors. Photo by Duncan Pay/GIA; courtesy of Sea Hunt
Rather than producing baroque pearls, like the soufflé, Pearls.
the drive is now toward bead nucleation and large, spheri-
cal pearls. As producers initially sell by weight, there is a
financial imperative to produce bigger pearls.
Although producers are ultimately striving for quality,
quantity is still the most important factor. Lynch felt that
the goal of Chinese freshwater pearl culturing has always
been the production of “large white round pearls” and that
success to date has been limited, with extremely small vol-
umes of fine-quality product available. Certainly, Lynch
knows of no more than a handful of examples like the
necklace he showed us at his AGTA booth.
Lynch was uncertain which kind of nuclei or culturing
process is used for these larger spherical pearls, but he said
the results speak for themselves. He believed it might be
similar to the proprietary process used by Chinese producer
Grace Pearl for its “Edison” pearls. In this method, genet-
ically selected mussels are implanted using tiny beads in-

Figure 61. These
slightly larger, higher-
quality baroque cul-
tured pearls have
smoother skins than
those in figure 60. As a
consequence, they are
priced two to three
times higher. Natural-
color goods are in the
foreground, while the
white pearls have been
bleached for a more
uniform appearance.
Photo by Duncan
Sea Hunt Pearls.
15.4–19.3 mm round necklace shown in figure 59 would Although Lynch carries a wide stock of Chinese fresh-
be $10,000 per strand, whereas these baroque multicolor water pearls, most of his resources go into purchasing
necklaces cost just a few hundred dollars per strand. Tahitian, South Sea, and akoya cultured pearl products. All
Lynch’s higher-quality baroque Chinese freshwater in all, he said, supply of every top-quality cultured pearl
pearls are larger and have smoother skins (figure 61), so the type is very limited, and competition for available product
price rises accordingly. The next examples he showed us is very high. The increase in Chinese consumption has
cost two to three times more. According to Lynch, they are drastically affected supply for U.S. and European whole-
very fashion-forward and still represent a tremendous salers. Fortunately, Lynch told us with a sense of relief, he
value for the size. has been a “pearl hoarder” for many years, so he has a sig-
The higher-quality baroque strands Lynch showed us nificant inventory to draw upon.
were also bead nucleated, but the bead had been positioned Lynch suggested that the Chinese domestic market
more conventionally, in the gonad of the mollusk. This tech- does not know what the market value of many products
nique produces a different type of pearl, known in the trade might be elsewhere. The Chinese have a different mindset
as a “fireball” (D. Fiske and J. Shepherd, “Continuity and
change in Chinese freshwater pearl culture,” Summer 2007
G&G, pp. 138–145, www.gia.edu/gems-gemology/summer- Figure 62. These tissue-nucleated Chinese freshwater
2007-continuity-change-chinese-freshwater-pearl- cultured strands resemble fine akoya cultured pearls.
culture-fiske). Photo by Duncan Pay/GIA; courtesy of Sea Hunt
All the peach to pink colors in these strands are natural, Pearls.
Lynch told us. Bleaching produces the white product. Un-
like the soufflé pearls, which are typically hollow after
being drilled, these bead-nucleated pearls have impressive
heft. They sell very well, according to Lynch, and no two
necklaces are quite the same due to the uniqueness of
every pearl. As an aside, he told us that the weight of the
pearls he shipped to the show was around 489 pounds
(about 221 kg), much of that consisting of bead-nucleated
freshwater cultured pearls.
Next, he showed us some tissue-nucleated (non-
beaded) round freshwater cultured pearls (figure 62). These
5–6 mm spherical pearls were impressively uniform with
high luster and crisp reflections from smooth skins, mak-
ing them an excellent substitute for an akoya strand. Find-
ing this sort of quality is very difficult these days, Lynch
told us. These also cost a few hundred dollars per strand.

cally. Lynch’s perception is that spending habits have
changed as the middle class in the U.S. has shrunk. He
finds fewer consumers looking for $1,000 items. Instead,
he sees purchasers from a higher income bracket looking
for a $20,000 or $30,000 piece.
Lynch now sells far more round white South Sea and
Tahitian goods, along with fine single pearls and pairs (fig-
ure 63). The first piece he showed us was a superb, excep-
tionally large round South Sea cultured pearl of 18.2 mm
(figure 64). Lynch said he buys with designers in mind, as
items like this are far more affordable than a strand and
make excellent centerpieces for custom jewelry pieces.
The price for such a piece would be approximately $6,000,
whereas a necklace of this quality would cost many tens
Figure 63. Fine Tahitian and South Sea cultured pearl of thousands of dollars.
singles and pairs are in high demand with designers Finally, Lynch pulled out a uniquely shaped Tahitian
for one-of-a-kind custom jewelry pieces. Photo by baroque cultured pearl (figure 65). Its flattened shape would
Duncan Pay/GIA; courtesy of Sea Hunt Pearls. allow it to sit especially well as a pendant. At 19.7 mm, it
was large. Even though the pearl was very baroque, its
color was exceptional. This piece had the style and sub-
than consumers in the West, he told us, citing a fashion
stance to really make a statement at a reasonable price (a
example: “You’ll pay more for couture items in Shanghai
couple of thousand dollars).
than in Paris… If it’s expensive, it’s better.” Although
many commentators insist the Chinese economy is slow- Duncan Pay
ing down and no longer enjoying double-digit percentage
growth, Lynch said that the emergence of a large middle CONFERENCE REPORTS
class that wants all the trappings of wealth is driving up
the market prices for gems and pearls. He noted that the GILC 2015. The International Colored Gemstone Associ-
tChinese like to display their wealth, and jewelry is an ob- ation (ICA) sponsored the invitation-only GILC (Gemstone
vious way to do that. Industry & Laboratory Conference) on February 2, during
Asked what was selling this year, Lynch explained how the Tucson gem shows. Participants represented primarily
his business has changed. He used to sell more volume at gemological laboratories, educational institutions, gem-
the Tucson show, especially freshwater items wholesaling stone buyers and wholesalers, and retailers (figure 66).
for $300 to $600 apiece. Today he handles fewer transac- Shane McClure of GIA began with an update on the
tions, but the average transaction has increased dramati- activities of the Laboratory Manual Harmonization Com-
Figure 64. This superb spherical South Sea cultured Figure 65. This 19.7 mm Tahitian Sea cultured pearl
pearl measures 18.2 mm in diameter and weighs 8.25 weighs 2.45 momme (9.19 grams). It would make a
grams. Photo by Duncan Pay/GIA; courtesy of Sea fine centerpiece for an item of custom jewelry. Dun-
Hunt Pearls. can Pay/GIA; courtesy of Sea Hunt Pearls.

Figure 66. Laboratory
representatives at the
GILC in Tucson spoke
on a wide range of top-
ics related to colored
gems, including
nomenclature, treat-
ment, and clarity en-
hancement. Photo by
Duncan Pay/GIA.
mittee (LMHC). The LMHC establishes consistent nomen- process. He presented visual evidence that “dust” from the
clature among international lab reports but does not address emeralds, laps, or abrasive powders can enter fractures dur-
standardization of criteria and testing procedures. The coming cutting and polishing, and he was concerned that they
mittee consists of seven international gemological labora- might be interpreted as clarity enhancement residues. It
tories, whose representatives meet three times per year by emerged during the discussion that although the stones
teleconference or in person. Information sheets that are might not have been intentionally clarity enhanced, the
under development include hydrophane opal, along with lubricating oil used in the cutting process, or the wax or
“pigeon’s blood” and “royal blue” designations for corun- nail polish used on rough to seal the fractures from dust,
dum. Topics under discussion include light sources, tanzan- could be the source of the clarity enhancement being de-
ite/zoisite nomenclature, and the problem of stones being tected by gemological laboratories.
treated soon after a laboratory report is issued. In the open session forum, participants pointed out that
McClure also presented additional color designations confidence in lab reports was waning for two reasons: (1)
for ruby that will be featured on GIA reports. He noted that the inconsistency in country-of-origin and treatment de-
“pigeon’s blood” would designate vivid red color on rubies terminations, and (2) the increasing prevalence of stones
with high fluorescence and low iron content, as typified by being altered or treated after receiving a favorable report
high-quality Burmese rubies. “Scarlet” and “crimson” (for instance, the re-oiling of emeralds).
would be used for fine-colored iron-bearing rubies with low The issue of hydrophane opal was revisited, with a call
fluorescence, in the slightly orangy to slightly purplish for nomenclature and comments, and perhaps a standard-
ranges, respectively. “Deep red” will be used for rubies of ized method of assessing and communicating the degree of
darker tone. There appeared to be different opinions among absorption and its impact on durability and color stability.
the participants about the definition of pigeon’s blood, and While trade in elephant ivory is prohibited in the U.S.,
no clear agreement about the proposed new terms. This the trade in extinct mammoth ivory has been severely re-
provoked a lively discussion as to whether “romantic” ter- stricted in New York and New Jersey, and on eBay. Nomen-
minology belonged on lab reports, and whether the use of clature to distinguish the two types needs to be developed,
advantageous vocabulary was a move by some labs to gain along with awareness of treatments to disguise modern
market share. ivory as mammoth or antique to circumvent restrictions.
Chris Smith of AGL spoke on the detection of low- Another issue raised was the treatment of spinel, once
temperature heat treatment of corundum. Smith defined considered a gemstone that was not treated. Participants
“low temperature” as less than 1300°C, a treatment range confirmed the routine heating of spinel from Myanmar and
where rutile (including silk) would still remain intact. The Tanzania, as well as the colored (red) oiling of both spinel
treatment has a long history and is still used to improve and corundum in Mogok. While microscopic examination
the color of pink, red, yellow, and orangy corundum, typ- does little to detect heating, photoluminescence and
ically by removing purplish or bluish components. Char- Raman spectroscopy are useful.
acterization of non-rutile mineral inclusions and IR Donna Beaton
spectroscopy are keys to detecting the treatment.
Gabriel Angarita, ICA ambassador to Colombia and International Diamond School. In late January 2015, nearly
president of the Emerald Exporters Association, gave a 100 scientists (figure 67) gathered in the northern Italian
presentation on residues in emeralds caused by the cutting town of Brixen to attend the Second International Diamond

Figure 67. Attendees from countries including Australia, Botswana, Russia, Brazil, and the United States
learned the latest tools and techniques for diamond research at the Second International Diamond School.
Photo by Fabrizio Nestola.
School (IDS). The program, titled “The Nature of Diamonds niques have been remarkably successful, partly because of
and Their Use in Earth’s Study,” was designed so that atten- the solid scientific research behind them.
dees from varied educational and professional levels could Jeff Harris (University of Glasgow, UK) reviewed the
learn from leaders in the field of natural diamond research. characteristics of lithospheric diamonds based on his ex-
The school successfully blended student and professional perience as a De Beers research director and his access to
perspectives, as well as the cross-disciplinary nature of the an unparalleled proportion of run-of-mine diamonds. He
participants and speakers. Over four days, IDS attendees from showed how different pipes produce distinct diamond size
a wide range of backgrounds—including experimental re- ranges and morphologies. He covered the age relationships
searchers, petrologists, mineralogists, crystallographers, iso- between inclusions and host diamond, inclusion chem-
tope geochemists, and diamond industry experts—were istry, formation pressures and temperatures, fluid inclusion
treated to a wide scope of lectures and workshops. Presenta- chemistry, and the abundance of different carbon and ni-
tions provided insight into diamond exploration, advanced trogen isotopes in diamond.
research-level analysis, diamond morphology, inclusion Michael Walter (University of Bristol, UK) discussed
chemistry, and geologic occurrences. the super-deep carbon geodynamics of Earth’s mantle along
George H. Read (Shore Gold Inc., Vancouver) presented with information provided by analysis of lower-mantle flu-
a recent history of diamond exploration, culminating with ids found as inclusions in “superdeep” (sublithospheric) di-
his company’s new Canadian diamond mine: Star-Orion in amonds from Brazil’s Juina field. He explained how new
Saskatchewan, a $2.5 billion project. He provided context thinking over the past five to six years has provided a
on production history, sources, and trading centers. He out- model for diamond formation by subduction of carbonate-
lined future diamond mining projects in Botswana, bearing hydrated oceanic crust in the transition zone of the
Canada, Lesotho, and India, concluding that the small mantle at depths of 440 to 600 km.
number of viable projects might signify a shortfall in rough Paolo Nimis (University of Padua, Italy) discussed ther-
supply. The complexity and financial risks involved with mobarometry, a technique that uses mineral phase diagrams
bringing new diamond mines online was made evident. to discover the original formation conditions (pressure, tem-
Bruce Kjarsgaard (Geological Survey of Canada, Ot- perature, and therefore depth) of rocks in the mantle. He also
tawa) reviewed kimberlite eruptive models based on 1970s related the possibility of applying similar techniques to in-
and 1980s research in South Africa. He explained the revi- clusions in diamonds to help determine their formation con-
sion of these models after new kimberlite discoveries in ditions. His talk explored the accuracy and precision of the
the 2000s in Canada’s Slave craton. He defined kimberlite different thermobarometers and where future improve-
as a strongly homogenized and “mixed-up” hybrid rock, ments are likely to occur.
representing a blend of crystallization out of the magma Ross Angel (University of Padua) discussed elastic
with country rock, that is often highly variable from place barometry for inclusions in diamonds. This new field uses
to place. In a second presentation Kjarsgaard examined the Raman shift or X-ray diffraction (lattice distortion) to
major techniques used for exploration for diamondiferous measure decompression effects on the surrounding dia-
kimberlites, focusing on the Canadian experience and its mond crystal caused by inclusions formed at high pressure
applicability to glaciated shield areas such as Canada, Rus- to estimate pressure of diamond formation.
sia, the northern United States, and Finland. These tech- Fabrizio Nestola (University of Padua) explained the ad-

vanced X-ray diffraction methods used in their laboratory, diamonds. Much of this work is nanostructural in nature
which permit very rapid crystal orientation and data col- and requires removing exceptionally thin wafers of diamond
lection. This work has shown that some olivine inclusions by focused ion beam lithography, a technique borrowed from
cannot be syngenetic, as they share no preferred orienta- the electronics industry. Brenker dealt specifically with the
tion with the host diamond. idea that some of the inclusion minerals thought to have
Graham Pearson (University of Alberta, Canada) grown in the lower mantle (e.g., Mg perovskite and ferroper-
overviewed the petrology and geochemistry of cratonic iclase) might actually have formed at the shallower depths
mantle roots. He explained the effects of melt depletion of the mantle transition zone or even the upper mantle.
(removal of clinopyroxene and orthopyroxene) to produce Dan Frost (University of Bayreuth, Germany) presented
very magnesium-rich melts in the sub-continental mantle, on the experimental petrology of the mantle, using state-
which removes rhenium (Re) to “freeze in” the osmium of-the-art multi-anvil presses capable of achieving pres-
(Os) isotopic system to allow radiometric dating. This gives sures of 250,000 bar at 1,800°C. This work demonstrates
very different mean Re/Os model ages for “on-craton” the possibility that at certain temperatures and pressures,
(>2.5 billion years) and “off-craton” (<2.0 billion) mantle a system may exist where carbon dioxide (CO2) and
xenoliths (potential diamond host rocks) for the Kaapvaal methane (CH4) produce carbon (C) plus water (H2O). He
craton, which underlies southern Africa. presented this as a new model for diamond formation in
Steven Shirey (Carnegie Institution of Washington) re- the deep mantle.
viewed the topic of age-dating diamonds, beginning with Pierre Cartigny (Institut de Physique du Globe de Paris)
work in the 1980s using rare-earth element ratios in sili- showed how carbon and nitrogen isotopes are used to char-
cate mineral inclusions within the diamonds. He covered acterize the fluid sources and fractionations that can occur
rhenium/osmium dating techniques devised in the late with diamond growth. One of his long-standing conclu-
1990s and perfected in the 2000s, finishing with recent sions is that even though subduction of C and N can occur
Re/Os dating work on zoned diamonds from Yakutia, and is thought to be a major process for introducing fluids
which showed two-billion-year-old cores surrounded by into the mantle, the signatures of subduction are not as
younger rims of one billion years. clear as one would expect. The possible isotopic changes
that can occur between the diamond and its host fluid dur-
Oded Navon (Hebrew University of Jerusalem) pre-
ing diamond growth need much further study.
sented on silicic and low-magnesium carbonatitic fluids in
Andy Davy (Rio Tinto Plc., Bristol, UK) drew upon his
fibrous diamonds and their relationship to fluids in gem-
experience as a consulting geologist to discuss the role of en-
quality diamonds. He explained how new work on inclu-
gineers and natural diamond scientists in evaluating dia-
sions along the twin planes of otherwise gem-quality
mond deposits. His talk covered the exploration and
diamonds—macles—revealed fluids of very similar com-
evaluation of prospective deposits, improvements in recov-
positions. One can generalize from previous studies of fi-
ery methods to prevent diamond breakage, and assessing the
brous diamond that most diamonds form under similar
performance of deposits through time. He left the audience
growth conditions most of the time.
with a realistic picture of the complications in establishing
Thomas Deining (WITec Instruments Corp., Ulm, Ger- diamond grade, price, and hence the viability of any given
many) introduced WITec’s confocal Raman spectrometer diamond project. He further showed how exceedingly rare
system and described its ability to map three-dimensional good diamond-producing kimberlites are.
fields of features at very high resolution. This instrument The school was a fantastic opportunity for attendees to
is ideally suited to looking into diamond, and his talk set learn about diamond exploration, advanced research-level
the stage for the Raman workshops the following day. analysis, diamond morphology, inclusion chemistry, and ge-
Maya Kopylova (University of British Columbia) dis- ologic occurrences in a way that will inspire their future
cussed fluid inclusions and volatiles in monocrystalline, studies and career choices. GIA’s contribution directly bene-
octahedral diamonds, with a focus on nitrogen (N2) and car- fited these up-and-coming research scientists by reducing the
bon dioxide (CO2). She related this new work to previous attendance fees for the conference, permitting many students
studies on fibrous diamonds, showing it has wider rele- to attend who otherwise would have been unable to do so.
vance than previously thought. IDS was organized by Fabrizio Nestola, Graham Pear-
Wuyi Wang (GIA, New York) covered diamond treat- son, and Steven Shirey, under the auspices of the Diamonds
ment and synthesis. He introduced the various causes of and Mantle Geodynamics of Carbon (DMGC) consortium,
color in natural diamonds and explained how combinations part of the Deep Carbon Observatory (DCO). The school
of irradiation and high-pressure, high-temperature (HPHT) was sponsored by GIA, the DCO, the Italian Society of Min-
treatment might alter or remove color. He also reviewed im- eralogy and Petrology (SIMP), and the University of Padua.
provements in synthetic diamond size and quality due to The IDS website is at www.indimedea.eu/diamond_
advances in HPHT and chemical vapor deposition (CVD) school_2015.htm.
synthesis technology. Steven Shirey
Frank Brenker (Goethe University, Frankfurt) outlined Carnegie Institution of Washington
the latest findings on ultra-high pressure mineral phases in Washington, DC

REGULAR FEATURES
COLORED STONES AND ORGANIC MATERIALS
A remarkably large amblygonite-montebrasite carving.

Recently the Gem Testing Laboratory in Jaipur had an op-
portunity to examine an unusually large yellow, semi-
transparent to translucent carving (figure 68). This 1,871
g (9,355 ct) piece measuring approximately 18.50 × 15.10
× 7.30 cm was fashioned after Lord Mahavira, one of the
ancient Indian sages who established the tenets of Jain
Dharma. Initial observations suggested beryl due to the
color, medium heft, and cloudy liquid inclusions visible
to the unaided eye. Gemological testing ruled out that pos-
sibility, however. Spot RI was approximately 1.61, with a
small but distinct birefringence blink, while hydrostatic
specific gravity measured 3.00. The carving was inert to
UV radiation.
Examination with a hand loupe revealed reflective liq-
uid films (figure 69, left), fingerprints composed of phase
droplets, elongated phase/short tubes oriented in one di-
rection, aligned in planes intersecting at approximately
65/115° angles (figure 69, center). Also present were paral-
lel reflective films that appeared to be incipient cleavage Figure 68. This 1,871 g amblygonite-montebrasite
(figure 69, right). The overall inclusion pattern was typical carving (18.50 × 15.10 × 7.30 cm) is unusual for its
of gems found in pegmatitic bodies such as beryl, tourma- size and transparency. Photo by Gagan Choudhary.
line, and topaz.
The carving was identified as amblygonite-montebra-
site by Raman spectroscopy in the 200–2000 cm–1 region, Their Sources, Descriptions and Identification, 5th ed., rev.
which revealed distinct peaks at ~297, 425, 481, 600, 643, tby P.G. Read, Butterworth-Heinemann, Oxford, UK). The
797, 1011, 1058, 1107, and 1186 cm–1 (figure 70). Amblygo- amblygonite and montebrasite end members can be differ-
nite and montebrasite are both lithium phosphates with a entiated on the basis of peaks at ~600 and 1060 cm–1 and a
common chemical formula of (Li, Na)AlPO4(F, OH), form- peak at ~3370 cm–1. With an increasing percentage of fluo-
ing an isomorphous series between F-rich amblygonite and rine, the 600 cm–1 peak shifts from 599 to 604 cm–1 while
OH-rich montebrasite. The two minerals can be colorless, the 1060 cm–1 peak shifts from 1056 to 1066 cm–1 (B. Ron-
yellow, or green. High-quality crystals are prized by collec- deau et al, “A Raman investigation of the amblygonite-
tors but rarely seen in the gem trade (R. Webster, Gems: montebrasite series,” The Canadian Mineralogist, Vol. 44,
Figure 69. Examination of the carving with a hand loupe revealed reflective liquid films (left), elongated
phase/short tubes oriented in one direction and aligned in planes intersecting each other at approximately 65/115°
(center), and parallel reflective films that appeared to be incipient cleavage (right). Photos by Gagan Choudhary;
image width 25 mm.

R AMAN SPECTRUM
1011
1058
Figure 70. The carving’s
Raman spectrum
showed major peaks at
around 297, 425, 481,
600, 643, 797, 1011,
INTENSITY
1058, 1107, and 1186
643
cm–1. The peaks at ap-
297
proximately 600 and

1058 cm–1 suggest an
intermediate member
1107
425
600
1186
of the amblygonite-
797
481
montebrasite series.
200 400 600 800 1000 1200 1400 1600 1800 2000
–1
RAMAN SHIFT (cm )
No. 5, pp. 1109–1117). According to the RRUFF database, Amethyst from Morocco: An update. Most major sources
however, the peak for montebrasite is at 1047 cm–1 while of fine amethyst are located in Africa. Yet African
amblygonite’s is at 1060 cm–1. This is possibly due to dif- amethysts on the market, especially Zambian material,
ferent instrument settings. Although the ~3370 cm–1 peak tend to be dark and difficult to find in sizes larger than 10
was not studied here, the 600 and 1058 cm–1 peaks in this ct. Since the late 1980s, there have been additional discov-
carving suggested that it belongs to an intermediate state eries in Malawi, Tanzania, Namibia, Nigeria, and the Dem-
in the amblygonite-montebrasite series. ocratic Republic of Congo. The most recent African source
Amblygonite-montebrasite is known from many local- is Morocco (see Spring 2009 GNI, pp. 62–63), which has
ities, especially the United States and Brazil, but the client produced gem-quality amethyst with an appealing purple
did not know the source of the carving. A few faceted sam- color and sizes larger than 10 ct.
ples have been examined at this laboratory, but the carving GIA’s Bangkok laboratory recently examined several
documented here was exceptional for its large size and parcels of gem-quality Moroccan amethyst (figure 71) re-
transparency, despite its brittleness and tendency to crack. ceived from Tom Banker, a colored stone dealer. Gemolog-
Gagan Choudhary ([email protected]) ical properties obtained from the crystals and faceted stones
Gem Testing Laboratory, Jaipur, India were similar to those reported in the 2009 GNI entry.
Figure 71. These Moroc-

can amethyst crystals,
which weigh 2.87 and
6.24 grams, display an
attractive purple zoning
conforming to the
rhombohedral faces.
Photo by Nuttaphol
Kitdee.

ural vs. synthetic amethyst: An update,” Fall 2011 G&G,
pp. 196–201). Areas of dark, medium, and light purple zoning
had very similar FTIR patterns.
Amethyst owes its purple color to color centers associ-
ated with Fe2+ or Fe3+ impurities (A.J. Cohen, “New data on
the cause of smoky and amethystine color in quartz,” The
Mineralogical Record, Vol. 20, No. 5, 1989, pp. 365–367).
The UV-Vis-NIR absorption spectra showed bands in the
visible range at 545 nm caused by Fe4+ charge transfer
(E.H.M. Nunes, “Spectroscopic study of natural quartz
samples,” Radiation Physics and Chemistry, Vol. 90, 2013,
pp. 79–86; E. Neumann, “Mechanism of thermal conver-
sion of color and color centers by heat treatment of
amethyst,” Neues Jahrbuch für Mineralogie, Monatshefte,
Figure 72. A closer view of the amethyst shows alter- 1984, No. 6, pp. 272–282). The complexity of absorption
nating bands of darker and lighter purple color zon- bands in the ultraviolet region is related to the presence of
ing. Photo by Charuwan Khowpong; magnified 10×. Fe3+ in more than one environment in the α-quartz struc-
ture (F. Hassan and A.J. Cohen, “Biaxial color centers in
amethyst quartz,” American Mineralogist, Vol. 59, Nos.
7–8, 1974, pp. 709–718).
Common characteristic internal features were intense
Further chemical analysis using advanced techniques
color zoning conforming to the rhombohedral faces (figure
such as EDXRF and ICP-MS will be conducted to summarize
72), reddish brown needle-like hematite inclusions (figure
the characteristic chemical profile of the Moroccan material.
73, left), and fingerprints consisting of two- and three-phase
inclusions (figure 73, center). Dolomite and anhydrite in- Ratima Suthiyuth
clusions were also found (figure 73, right). GIA, Bangkok
A thin wafer with a thickness of 1.28 mm was prepared
for FTIR and UV-Vis-NIR spectroscopy. The wafer plane Dumortierite in rock crystal quartz. Dumortierite, which
was oriented parallel to the c-axis. The FTIR spectra were commonly occurs as a blue borosilicate mineral, is of
recorded using a Thermo Nicolet 6700 spectrometer with gemological interest when present in quartzite, making an
a resolution of 4 cm–1 and 200 scans, while the UV-Vis spec- attractive blue ornamental material. Recently examined
tra were collected using a Hitachi U-2910 spectrometer at by GIA’s Carlsbad laboratory were several examples of du-
1.5 nm slit width and 100 nm/min scan speed, integrated mortierite inclusions in rock crystal quartz (figure 74) pro-
with a polarizer accessory controlled by Thorlabs APT. vided by Luciana Barbosa (Asheville, North Carolina).
FTIR spectroscopy revealed typical features of amethyst. According to Mrs. Barbosa, the material is reported to be
The absorption peaks at 3585 and 3613 cm–1 were related to from the Brazilian state of Bahia, in the Serra do Espinhaço
vibrations caused by Al substitutions. The absorption shoul- Range near the Vaca Morta quarry.
der at 3595 cm–1 is common in natural quartz and rarely seen Much of the material examined by the authors showed
in synthetic quartz. The cause of this feature remains un- phantom planes and clusters of acicular needles with a vi-
known (S. Karampelas et al., “Infrared spectroscopy of nat- brant blue coloration (figure 75). Polarized light revealed
Figure 73. Microscopic examination of the Moroccan amethyst samples revealed reddish brown hematite (left),
two-phase inclusions (center), and dolomite crystals (right). Photomicrographs by Charuwan Khowpong; magni-
fied 50×, 5×, and 80×.

Figure 74. This group of
rock crystal quartz
from Brazil shows vi-
brant blue dumortierite
inclusions. The largest
rough crystal weighs
139.79 ct, and the
faceted stone weighs
15.47 ct. Photo by
Kevin Schumacher.
very strong blue to colorless pleochroism in the blue min- to look for any prominent differences that might explain
eral inclusions. Raman analysis confirmed the identity of the variance in observed color. The most significant differ-
the needles as dumortierite. Also observed in one sample ence was in the magnesium content, which was almost 10
were colorless acicular crystals on a phantom plane, which times higher in the colorless dumortierite inclusions (1070
were also identified by Raman as dumortierite (figure 76). ppma, compared to 127 ppma Mg in the blue dumortierite).
Blue color in dumortierite has previously been reported While more research is needed to fully understand the role
to be caused mainly by Fe2+-Ti4+ charge-transfer (see this higher magnesium content has on color, the authors
http://minerals.gps.caltech.edu/FILES/Visible/dumortierite/ speculate that the titanium preferentially charge-compen-
Index.htm). The chemical composition of the blue and col- sates with magnesium instead of iron. If there is not
orless dumortierite inclusions was analyzed by LA-ICP-MS enough excess titanium relative to magnesium, it may not
be possible for titanium to pair with divalent iron, and this
would prevent the formation of blue color.
Figure 75. Clusters of vibrant blue acicular du-
mortierite were observed in this rock crystal quartz.
Note that some dumortierite crystals are brownish
due to epigenetic mineral staining along the interface Figure 76. Unusual pale blue to colorless needles of
of the quartz host and the dumortierite inclusions. dumortierite were also observed in the rock crystal
Photomicrograph by Nathan Renfro; horizontal field quartz. Photomicrograph by Nathan Renfro; horizon-
of view 7.38 mm. tal field of view 2.24 mm.

These are the first examples of prismatic blue and col-
orless dumortierite inclusions in rock crystal quartz we
have encountered.
Nathan Renfro, Ziyin Sun, and John Koivula
GIA, Carlsbad
Jadeite with high albite content. With high prices and de-
mand from Chinese consumers for jadeite jade (or fei cui),
correctly identifying samples is a major challenge for gemo-
logical laboratories. Jadeite’s complex mineral composition
and its nature as a rock rather than a mineral further com-
plicate this problem. While jadeite is the main mineral in
jadeite jade, other pyroxene minerals such as kosmochlor, Figure 78. Two groups of minerals were observed on
omphacite, amphibole-group minerals, plagioclase (espe- the surface of this sample under brightfield illumina-
cially albite), and even some iron oxides may also be present. tion. One group is composed of the pale whitish sub-
Recently, the National Gold & Diamond Testing Center hedral to euhedral grains, the other of the creamy
(NGDTC) lab tested 29 bangles submitted as jadeite jade (fig- minerals in between. Photomicrograph by Li Jianjun;
ure 77). The results again raised the issue of nomenclature. magnified 30×.
The samples could be separated into two groups, one
group with finer texture and color (shown on the left in fig-
ure 77). Standard gemological tests were applied to all of samples were inert to UV, though six showed weak to
the samples, and the surface features were observed using moderate unevenly distributed bluish fluorescence. Under
a standard gemological microscope. The samples showed 30× magnification and brightfield illumination, two major
the characteristic 437 nm line with a handheld spectro- mineral groups with contrasting color, crystal shape, and
scope. Ten randomly chosen spot RI readings were recorded luster were revealed (figure 78).
on each bangle, and the results offered interesting insights. Transmission infrared spectra collected from the posi-
Two different readings of 1.52 and 1.66 were observed, in- tions that fluoresced weakly to moderately showed no
dicating the presence of two major components. The SG polymer-related features. To confirm the composition of
ranged from 2.99 to 3.34, while the referenced SG for the two major minerals, we collected micro-infrared re-
jadeite jade is 3.34 (+0.06–0.09). The low SG indicates a sig- flectance spectra from them (figure 79). The spectrum of
nificant amount of light minerals in these samples. An- the pale whitish mineral indicated jadeite, with the pres-
other observation was that the group of lesser luster and ence of the featured 1050 and 744 cm–1 bands in addition
color (shown on the right in figure 77) tended to have lower to the four bands between 400 and 600 cm–1. The IR spec-
SG than the higher-quality samples. Overall, most of the trum of the creamy mineral matched that of albite, with
the characteristic peak at 1040 cm–1 band assigned to the
Si-O stretching vibration in the SiO4 tetrahedral structure.
Figure 77. These 29 bangles were submitted to The multiple peaks in the 800–700 cm–1 region can also
NGDTC by a wholesaler as jadeite jade. The bangles help to distinguish albite from jadeite.
in the left column are slightly finer and of better The spot RI readings around 1.52 were consistent with
color. Photo by Li Jianjun. albite’s published RI of 1.528–1.542. The SG of albite is
2.60–2.65, considerably lower than that of jadeite. The
presence of albite as a major mineral component in this
material could account for the much lower SG in most of
the samples. Although albite is one of the common min-
erals in jadeite jade, the amount is usually very minor and
cannot be easily detected by standard gemological tests.
Because the lab could not destroy the samples, no quanti-
tative data were achieved.
Identifying these materials is not easy, especially when
the concentration of certain components cannot be quan-
titatively determined and there is no trade standard on the
boundaries for the different varieties. This study serves as
a reminder that in addition to the omphacite issue, the high
concentration of albite in some goods is a potential problem
facing laboratories. To better protect consumers, the
NGDTC recommends a clear statement regarding the pres-

IR SPECTRA
1050
744
REFLECTANCE
Jadeite
Figure 80. Glass in a silver brooch, hallmark from

677
1866. Private collection, photo by Jaroslav Hyršl.
800
Albite
set contained moldavites—a donation to the museum by

1400 1300 1200 1100 1000 900 800 700 600 500
Olga Havlova, the first wife of Vaclav Havel, the late Czech
author and statesman. All of the stones in the other four
WAVELENGTH (cm–1)
sets proved to be glass imitations. This means that glass
imitations have been around decades longer than previ-
Figure 79. IR reflectance spectra collected from the ously thought (figure 80).
two main minerals in the samples identified one as Fortunately, the identification of faceted moldavite is
jadeite and the other one as albite. simple. Besides their flow texture and abundant bubbles
(almost always much more abundant than in an artificial
glass), moldavites contain “wires” of lechatelierite, a high-
ence of albite on laboratory reports once the albite is iden-
temperature form of SiO2. Lechatelierite is very easy to see
tified by the standard gemological test especially according
with a loupe due to its lower RI.
to refractive index, even by the FTIR spectrometer.
The identification of moldavite with a natural-looking
Li Jianjun, Luo Yuanfei, Liu Xiaowei, Yu Xiaoyan, Li surface is much more difficult. Rumors of moldavite im-
Guihua, Fan Chengxing, and Ye Hong itations from China have been circulating among Czech
National Gold & Diamond Testing Center, dealers for many years, but only recently has the author
Jinan City, China been able to study some examples (see figure 81). Two
large moldavite imitations were seen in a high-end jew-
Moldavites: natural or fake? Tectites are members of a
large group of impact glasses, formed by the collision of a
meteorite on the Earth’s surface and the subsequent melt-
ing of surrounding rocks. The most famous tectites used Figure 81. Two moldavites from southern Bohemia,
as gemstones are moldavites from southern Bohemia in Czech Republic (top row) and two recent imitations
the Czech Republic. These were formed by a meteorite’s from China (bottom row). The natural specimen on
impact in the Ries crater in southern Germany 14.7 mil- the top right measures 44 mm across. Photo by
lion years ago, about 500 km from their occurrence (V. Jaroslav Hyršl.
Bouška, Moldavites: The Czech Tektites, Stylizace,
Prague, 1994). Moldavites are popular for their pleasant
green color, enigmatic origin, and interesting etched tex-
ture. They are used in jewelry, in either faceted or natural
form. The price of moldavite has risen in the last few
years, and as a logical consequence imitations have be-
come more widespread.
In fact, moldavite imitations are nothing new. Faceted
moldavites were very popular in Czech jewelry during the
second half of the 19th century, often with Czech garnets
(chrome pyropes) or small river pearls. Their use dimin-
ished in the beginning of the 20th century when imitations
made from green bottle glass began to appear. Neverthe-
less, the author’s recent study of five moldavite sets
(bracelet, brooch, and earrings) from the second half of the
19th century in the collection of the Museum of Decora-
tive Arts in Prague revealed an unexpected result. Only one

Figure 82. One of two huge moldavite fakes seen in
Hanoi. Photo by Jaroslav Hyršl.
elry shop in Hanoi during the 2013 International Gem-

mological Conference (figure 82). Their size was aston-
ishing, because very few real moldavites weigh more than
100 g. Their shape was also too perfect, making them easy
to recognize.
Chinese producers are now manufacturing small
stones weighing just a few grams that are very realistic.
The surface feature of natural moldavite is caused by nat-
ural etching, and an almost identical feature can be created Figure 83. Typical bubbles and inclusions of lechate-
artificially, likely in hydrofluoric acid. If the stone in ques- lierite in natural moldavite; image width 5 mm. Pho-
tion has a polished surface, the presence or lack of lechate- tomicrograph by Jaroslav Hyršl.
lierite “wires” (figure 83, top and bottom) is the best
diagnostic tool, along with refractive index (table 1). For
rough, immersion in water or especially oil with a similar author several years ago was not fluorescent, but its very
RI is very helpful to reveal lechatelierite. Imitation mol- high specific gravity of 3.60 immediately ruled out natural
davite also has a different density, UV-Vis absorption spec- moldavite.
trum (figure 84), and fluorescence (again, see table 1). The Jaroslav Hyršl ([email protected])
color of natural moldavites is caused by very low concen- Prague
tration of iron; all other tectites are more Fe-rich and
therefore black. Fluorescence is particularly helpful be- Iridescent scapolite. GIA’s Carlsbad laboratory recently ex-
cause it may be used on large mixed lots. Some imitations amined two cabochons from L. Allen Brown (All That Glit-
are not fluorescent, however. One imitation seen by the ters, Methuen, Massachusetts) that exhibited prominent
TABLE 1. Characteristics of natural and imitation moldavite.
19th-century
Moldavite Chinese imitations
glass imitations
Color Light green to brown Light green Light green

RI 1.490 (1.480–1.510) 1.520 1.545–1.580
Density 2.35 (2.27–2.46) 2.52–2.53 n.a.
Fluorescence Inert in UV Chalky in short-wave UV Inert in UV
Absorption spectrum Minimum at 550 nm Maxima at 460 and 640 n.a.

UV-VIS SPECTRA
4
3,6
3,2
2,8
2,4
ABSORBANCE
2 Figure 84. Absorption

spectra of natural mol-
1,6
davite (black and red
1,2 lines) and imitations
(green and blue lines).
0,8
0,4
Moldavite 9.92 ct
Moldavite 29.57 ct
0
Imitation a
Imitation b
-0,4
-0,8
300 400 500 600 700 800 900 1000
WAVELENGTH (nm)
iridescence in reflected light (figure 85). Standard gemological light, these exsolution stringers proved to be the source of
testing of the 7.30 and 32.22 ct specimens revealed a spot RI the iridescent colors (figure 86, right). Similar material has
of 1.55 and a hydrostatic specific gravity of 2.67. Fluorescence been reported to occur in India, by G. Choudhary (Spring
was inert to long- and short-wave UV light. The stones also 2013 GNI, pp. 58–59), but the identity of the phenomenon
showed a very weak reaction to a strong magnet. causing inclusions was not determined.
Under magnification, the most distinctive internal Raman spectroscopy confirmed that the stones were
characteristic was the presence of dark brown exsolution scapolite. To identify the color causing inclusions, the
stringers of a secondary mineral. Larger tabular dark brown smaller stone was selected for destructive testing. Win-
crystals were also observed (figure 86, left). Under reflected dows were polished to expose some of the inclusions to the
Figure 85. These two

scapolite cabochons
(7.30 and 30.22 ct) dis-
played prominent iri-
descence in reflected
light. Photo by Don
Mengason.

Figure 86. Dark brown exsolution stringers of magnetite (left), also viewed with oblique fiber-optic illumination
(right), were the source of iridescence in this scapolite. Photomicrographs by Nathan Renfro; field of view 4.37 mm.
surface of the stone. The exposed surface of the inclusion This scapolite with iridescence, also known in the trade as
showed a metallic luster (figure 87), which was identified rainbow scapolite, is a very interesting example of a phe-
as magnetite by Raman spectroscopy, and was explanatory nomenal gemstone.
of the magnetic reaction observed. Ziyin Sun, Nathan Renfro, and Aaron C. Palke
Laser ablation–inductively coupled plasma–mass spec- GIA, Carlsbad
trometry (LA-ICP-MS) analysis was used to further support
the identity of the inclusions. While the exposure of the in- Attractive composite quartz beads. The Gem Testing Lab-
clusions on the stone’s surface was too small for a clean oratory in Jaipur recently received a 145.70 carat string of
analysis without a contribution from the scapolite host, the attractive blue and golden brown spherical beads (figure 88)
results showed a significant increase in iron as the laser ab- measuring approximately 7.91–8.48 mm in diameter. The
lated through the brown inclusion and decreased afterward. beads were readily identified as artificial by their appear-
Scapolite occurs in a number of rock types as a product ance, which consisted of metallic golden brown veining
of regional metamorphism or metasomatism. The close as- and concentrations of blue color against a whiter body. Fur-
sociation of magnetite with scapolite has been noted before, ther tests were performed to identify the blue areas.
particularly in some skarn deposits and some hydrother-
The measured RI was approximately 1.54. The beads
mally altered volcanic formations (J.A. Naranjo et al., “Sub-
displayed a patchy chalky blue reaction to short-wave UV
volcanic contact metasomatism at El Laco Volcanic
Complex, Central Andes,” Andean Geology, Vol. 37, 2010,
pp. 110–120). Choudhary reported similar material, but the
inclusions that caused the iridescence were not identified. Figure 88. This string weighing 145.70 carats consists
of attractive blue and golden brown beads measuring
approximately 7.91–8.48 mm in diameter. The beads
Figure 87. Under reflected light, the exposed surface were identified as composites fashioned from pieces
of the inclusion showed a metallic luster. Photomi- of dyed quartzite held in a polymer matrix. Photo by
crograph by Ziyin Sun; field of view 0.25 mm. Gagan Choudhary.

years now (see G. Choudhary, “A new type of composite
turquoise,” Summer 2010 G&G, pp. 106–113). Also pres-
ent were thick layers of polymer along the edges of the blue
and golden brown areas, which appeared green due to the
overlap of the blue dye with the golden flakes. Raman spec-
troscopy confirmed that these blue portions were quartz.
Recognizing these beads as composites was straightfor-
ward, but identification of the components required
Raman and EDXRF spectroscopy. Although these beads
were obviously created to offer something fancy and attrac-
tive to consumers at a low price, clear and complete dis-
closure remains imperative.
Figure 89. Color concentrations of blue dye were eas- Gagan Choudhary ([email protected])
ily visible along the fractures against a white back- Gem Testing Laboratory, Jaipur, India
ground, while the golden brown areas were composed
of copper-zinc based fine flakes. Also note the green-
ish polymer along the edge of the golden brown and SYNTHETICS AND SIMULANTS
blue areas. Photomicrograph by Gagan Choudhary;
magnified 48×. CVD synthetic diamond with unstable color centers. The
Indian Gemological Institute – Gem Testing Laboratory,
New Delhi recently examined a 1.42 ct (7.06–7.08 × 4.49
and were inert to long-wave UV. Their Chelsea filter reac- mm) round brilliant. Viewed perpendicular to the pavilion
tion was red, and under the desk-model spectroscope they facets with its table down, the sample displayed a grayish
displayed a band at approximately 650 nm. Under magni- yellow color, but a slight rotation changed the color to
fication, the blue areas displayed fluid inclusions that gave pinkish. On viewing the specimen parallel to the direction
the beads a cloudy effect. In addition, the abundant frac- of the growth planes, the sample appeared grayish yellow;
tures showed the presence of dye (figure 89) that was re- viewing perpendicular to these same planes, the sample ap-
sponsible for the beads’ blue color. Such features are peared pinkish.
commonly observed in dyed quartzite, but these were not Infrared spectroscopy showed features typical for type
sufficient to prove its identity. The golden brown areas, IIa diamond. Magnification revealed no internal features
which consisted of fine flakes (again, see figure 89) held in except for a feather on the girdle and the two growth
a soft polymer, were later identified by EDXRF spec- planes, which appeared textured. There are very fine pin-
troscopy as copper and zinc composites. Similar compos- point-like inclusions lying just along the planes (figure 90,
ites in which the components are held together in a left). These planes of pinpoints were also visible from the
polymer matrix have been known in the trade for several table (figure 90, right). Examined in the DiamondView
Figure 90. Left: These growth planes were observed in a CVD synthetic diamond; fine pinpoints were found along
the growth planes. Photomicrograph by Meenakshi Chauhan; magnified 30x. Right: Pinpoints along the growth
plane were also visible from the table. Photomicrograph by Meenakshi Chauhan; magnified 10×.

short-wave UV radiation of the DiamondView and re-
gained its initial color in approximately one minute under
the halogen light.
UV exposure produced unstable color centers in this
CVD synthetic diamond, which gave it a grayish blue
color. Heat removed the color centers, restoring the CVD
synthetic diamond to its initial grayish yellow color.
Meenakshi Chauhan ([email protected])
Indian Gemological Institute – Gem Testing Laboratory
INSTRUMENTS AND TECHNIQUES
The Foldscope and its gemological applications. The

Prakash Lab of Stanford University, a small team of gradu-
ate students led by bioengineering professor Manu Prakash,
has created a portable paper microscope called the Fold-
scope. Originally conceived for disease detection in remote
Figure 91. In the DiamondView, the 1.42 ct round
areas, it was later expanded for educational use. The con-
showed striations typical of CVD growth. Notice the
cept of the Foldscope won a $100,000 grant from the Gates
two parallel planes fluorescing stronger than the bulk
Foundation in 2012 and a $50,000 first prize from the 2014
of the crystal. The sample also showed moderate
Moore Foundation Science Play and Research Kit Compe-
phosphorescence (inset), another indication of CVD
tition, which challenges participants to reinvent scientific
growth. Images by Meenakshi Chauhan.
tools of the past to attract a new generation of scholars.
Speaking at the annual TED Conference in March 2014,
Dr. Prakash announced that the concept was prototyped,
(using less than 225 nm short-wave UV radiation) to reveal functional, and could be manufactured for less than $1
its growth patterns, the round brilliant showed parallel stri- each.
ations indicative of CVD growth (figure 91). It also exhib- Submissions were accepted for a beta test group (now
ited moderate phosphorescence under the UV lamp for closed) named the “10,000 Microscope Project.” The goal
approximately 20–25 seconds. (figure 91, inset), confirming was to get a Foldscope in the hands of 10,000 users world-
synthesis by a CVD process. wide, in medical and non-medical fields. The project re-
Upon removal from the DiamondView after approxi- quested users who understood microscopy and agreed to
mately two minutes of exposure time, it showed a distinct write detailed scientific studies based on their own re-
grayish blue color. After exposure to a 100-watt halogen search, to be collected and published to show the variety
bulb for about three minutes, the synthetic diamond re- of potential uses. Seeing a major application in field gemol-
gained its initial color (figure 92). ogy, this author requested and received a Foldscope.
This process was repeated, and the sample turned a Beta testers received Foldscope components and in-
grayish blue color after a single minute of exposure to the structions in December 2014. The body is made of a mate-
Figure 92. The CVD

synthetic diamond be-
fore (left) and after ex-
posure (right) to the
short-wave UV radia-
tion of the Diamond-
View. Photos by
Meenakshi Chauhan.

Figure 93. A fully assem-
bled Foldscope measures
approximately 7 × 2.5 in.
A toggled LED light
source is tucked into tabs
on the back, and the bot-
tom center slit accommo-
dates standard glass
microscope slides. Photo
by Kate Pleatman.
rial more like plastic than paper, to prevent tearing. Pieces ers in place freed the hands to manipulate the focus more
are punched out of perforated sheets and assembled like precisely. Focusing was the biggest obstacle, and late in the
origami (figure 93). The kit also contained interchangeable research the author inadvertently scratched a lens while
low-magnification (140×) and high-magnification (400×) trying to focus on a 1 mm corundum culet.
lenses, a 3V LED toggled light source, and a surprise: a cou- It was possible to clearly distinguish between natural
pler to connect to a cell phone for photomicrography. Due and synthetic stones, because the magnification levels
to its complexity, assembling the Foldscope may take an were exceptional (figures 94–96). Yet the small fixed size
hour or two. The device was ingeniously constructed, but of the slide opening made it difficult to use with loose
would it work with gems? stones in tweezers, and gems more than 8 mm in depth
Stones between 1 and 3 mm could be mounted onto could not pass enough light to view. Opaque material was
glass slides for study. Larger stones were held with gem not visible at all.
tweezers in the slide opening, to test whether the Fold- Research details, photos, and feedback were sent to the
scope would work with loose stones as well. Stones that Prakash Lab, along with design recommendations for
were transparent and relatively small produced impressive making the device more ideal for gemological use. Sugges-
results. The use of a binder clip to hold the slide or tweez- tions included protection for the lens to prevent scratching
Figure 94. This photomicrograph of synthetic opal,

taken using the high-magnification lens (400×), shows Figure 95. These fluid inclusions in quartz were
the characteristic cellular mosaic appearance. Pho- taken using the Foldscope’s low-magnification lens
tomicrograph by Kate Pleatman. (140×). Photomicrograph by Kate Pleatman.

Figure 96. These liquid inclusions in ruby are seen
using the low-magnification lens (140×). Photomicro-
graph by Kate Pleatman.
and a larger gap for examining non-slide materials such as

loose stones held with tweezers. An optional three- or
four-inch fiber-optic light attachment would offer illumi-
nation from any angle, even for mounted stones. The Fold-
scope team has been very attentive to the feedback,
although they have not committed to any alterations.
Time will tell if the suggested modifications are feasible.
No public release date or final price for the existing ver-
sion has been announced. For more on this tool, visit
www.foldscope.com. Sri Lankan heat treater Master Simon displays his
Kate Pleatman copy of the Fall 2014 G&G. The issue’s cover featured
Facets & Frosting him heating a star ruby using an old-fashioned blow-
Cincinnati, Ohio pipe technique. Photo by Vincent Pardieu.
For More on Tucson 2015

Explore the emerging trends, unique pieces, and production
updates from this year’s gem shows. GIA’s coverage from
Tucson provides an exclusive look at the gem and jewelry
industry through video interviews and photo galleries.
Visit www.gia.edu/gems-gemology/spring-2015-gemnews-tucson-2015-overview, or scan the QR code on the right.

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What are some of the featured articles in this issue?

What are some of the featured articles in this issue?

What locations are featured in the field reports section?

What locations are featured in the field reports section?

SPRING 2015

THE QUARTERLY JOURNAL OF THE GEMOLOGICAL INSTITUTE OF AMERICA

Vietnamese Blue Spinel

18 The Chinese Soul in Contemporary Jewelry Design

NOTES AND NEW TECHNIQUES

68 Gem News International

Editorial Review Board Copyright and Reprint Permission

About the Cover

Duncan Pay | Editor-in-Chief | [email protected]

EDITORIAL GEMS & GEMOLOGY SPRING 2015 1

Bai Gou/Chuong Tran

Blue Spinel Deposit

22 104º40 104º50 Day Nui Con Voi Range

May Trung Minh Tien Dai Thi Formation : quartz-mica-feldspath scist,

Nui Chua complex : olivine or pryoxene or

Marble Pargasite Blue Spinel Olivine

Figure 10. The samples in this study displayed the

WAVELENGTH (nm) 10.0 665

Figure 9. The UV-Visible spectra of typical blue 2.5 GREBLU2

2003; Garnier et al., 2008). As already mentioned, 0.0

Proposed Geological History. The ancient Paleo-

tremolite + calcite → diopside + dolomite

THE CHINESE SOUL IN

See end of article for About the Authors and Acknowledgments.

18 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

in jewelry design have been offered since the early

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 19

20 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 21

DEPICTIONS OF CHINESE PHILOSOPHIES

22 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

Figure 11. This necklace by Yue-Yo Wang features a

Figure 10. Taiwanese designer Yue-Yo Wang, pictured

In China, knotting art can be traced back to

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 23

INNOVATIVE DESIGN TECHNIQUES

ods while importing Western techniques. Zhang’s

24 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

Figure 16. Shirley

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 25

ing this technique. Her company is now the only one

26 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

Figure 20. This suite includes earrings and a

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 27

28 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015 29

ABOUT THE AUTHORS ACKNOWLEDGMENTS

30 CHINESE CONTEMPORARY JEWELRY GEMS & GEMOLOGY SPRING 2015

AMETHYST FROM BOUDI, MOROCCO

an off-road track to comply with environmental reg-

F or 25 years, the Moroccan locality of Boudi in the

See end of article for About the Authors and Acknowledgments.

32 NOTES & NEW TECHNIQUES GEMS & GEMOLOGY SPRING 2015

Orogens except Anti-Atlas system

Basement inliners of Anti-Atlas system