MSDS Quartamin 86P Conc

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KCDS-No 000042-21 QUARTAMIN 86P CONC 1 / 7

Kao Corporation Revised Date June 18, 2014


Set Up Date March 18, 1996

SAFETY DATA SHEET


[1.PRODUCT AND COMPANY IDENTIFICATION]
PRODUCT NAME : QUARTAMIN 86P CONC
SUPPLIER : Kao Corporation
ADDRESS : 1-3,Bunka 2-chome,Sumida-ku,Tokyo 131-8501 Japan
DIVISION : Global Chemical Business
TELEPHONE NUMBER : 81-3-5630-7700
FAX NUMBER : 81-3-5630-7889
E-MAIL ADDRESS : [email protected]
EMERGENCY TELEPHONE NUMBER : 81-3-5630-7700
RECOMMENDED USE :
AND RESTRICTIONS ON USE

[2.HAZARDS IDENTIFICATION]
GHS CLASSIFICATION
PHYSICAL AND CHEMICAL HAZARDS
FLAMMABLE LIQUIDS : Category 2
HEALTH HAZARDS
ACUTE TOXICITY (Oral) : Category 4
ACUTE TOXICITY (Dermal) : Not classified
ACUTE TOXICITY (Inhalation) : Not classified(Vapours)
SKIN CORROSION / IRRITATION : Not classified
SERIOUS EYE DAMAGE / EYE : Category 1
IRRITATION
RESPIRATORY SENSITIZATION : Classification not possible
SKIN SENSITIZATION : Not classified
GERM CELL MUTAGENICITY : Not classified
CARCINOGENICITY : Classification not possible
REPRODUCTIVE TOXICITY : Category 2
SPECIFIC TARGET ORGAN TOXICITY
- SINGLE EXPOSURE : Category 1(central nervous system, kidney, systemic toxicity)
- REPEATED EXPOSURE : Classification not possible
ASPIRATION HAZARD : Classification not possible
ENVIRONMENTAL HAZARDS
HAZARDOUS TO THE AQUATIC ENVIRONMENT
- ACUTE HAZARD : Category 1
- LONG-TERM HAZARD : Category 1
- HAZARDOUS TO THE OZONE : Classification not possible
LAYER
GHS LABEL ELEMENTS
PICTOGRAMS OR SYMBOLS :

SIGNAL WORD : Danger


HAZARD STATEMENTS : Highly flammable liquid and vapour
Harmful if swallowed
Causes serious eye damage
Suspected of damaging fertility or the unborn child
Causes damage to organs (central nervous system, kidney, systemic toxicity)
Very toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS
KCDS-No 000042-21 QUARTAMIN 86P CONC 2 / 7
Kao Corporation Revised Date June 18, 2014

PREVENTION : Obtain special instructions before use.


Do not handle until all safety precautions have been read and
understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Take precautionary measures against static discharge. Use explosion-
proof electrical/ventilating/lighting. Use only non-sparking tools.
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid release to the environment.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE : IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
Rinse mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately
call a POISON CENTER or doctor.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower. Gently wash with plenty of water.
In case of fire : Keep away from sources of ignition and use appropriate
extinguishing media.
Collect spillage.
STORAGE : Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
DISPOSAL : Passed to a licensed waste contractor.
SAFE HANDLING ADVICE : This product may be solidified totally or partially according to the storage
condition. In that case, please warm-up for melting, then use at homogeneous
liquid.

[3.COMPOSITION / INFORMATION ON INGREDIENTS]


SUBSTANCE OR MIXTURE : Mixture
INGREDIENTS AND CONCENTRATION
RANGE
Ingredients Concentration Range(%) CAS RN
Stearyltrimethylammonium chloride 60 - 70 112-03-8
Isopropyl alcohol 25 - 35 67-63-0
Water 1 - 10 7732-18-5

[4.FIRST-AID MEASURES]
IN CASE OF INHALATION : Remove person to fresh air and keep comfortable for breathing.
IF exposed or concerned: Get medical attention/advice.
IN CASE OF SKIN CONTACT : Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF exposed or concerned: Get medical attention/advice.
IN CASE OF EYE CONTACT : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor.
IN CASE OF INGESTION : Call a POISON CENTER or doctor if you feel unwell. Rinse mouth.
IF exposed or concerned: Get medical attention/advice.

[5.FIRE-FIGHTING MEASURES]
EXTINGUISHING MEDIA : Powder, alcohol-resistant foam, water spray, carbon dioxide,sand
NOT SUITABLE EXTINGUISHING : No information available
MEDIA
KCDS-No 000042-21 QUARTAMIN 86P CONC 3 / 7
Kao Corporation Revised Date June 18, 2014

SPECIFIC HAZARDS : Produce irritating or toxic gases in a fire.


SPECIFIC METHODS : Keep away from sources of ignition and use appropriate extinguishing
media.Fight fire from upwind position if possible.
Do not flow the materials causing adverse effects into the environment
with effluent fire extinguishing agents.
PROTECTION OF FIRE FIGHTERS : Use goggles in combination with dust mask, and other protections as
appropriate to situation.
Risk of producing harmful gases such as carbon monoxide and
phosgene. Avoid inhalation of smoke or gases.

[6.ACCIDENTAL RELEASE MEASURES]


PERSONAL PRECAUTIONS, : Use goggles and protective gloves.
PROTECTIVE EQUIPMENT AND Large spills : Remove person to safety.
EMERGENCY PROCEDURE Ensure adequate ventilation.
ENVIRONMENTAL PRECAUTIONS : Avoid release to the environment.
METHODS FOR CLEANING UP : Cool down to solid in case of melt(be careful of heat),and then sweep or
vacuum spilled materials to drums or containers.
PREVENTION OF SECONDARY : Keep away from sources of ignition and prepare extinguishing media.
HAZARDS
Do not use tools producing sparkle.
Risk of slipping. Spilled material forms slippery floor.

[7.HANDLING AND STORAGE]


HANDLING
TECHNICAL MEASURES : Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
PRECAUTIONS : Keep away from source of ignition.
Avoid contact with eyes.
This product may be solidified totally or partially according to the storage
condition. In that case, please warm-up for melting, then use at
homogeneous liquid.
SAFE HANDLING ADVICE : Use an adequate ventilation.
Wash thoroughly after handling.
Use personal protective equipment as required.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
STORAGE
SUITABLE STORAGE CONDITIONS : Store container tightly closed in well-ventilated place.
Store locked up.
Keep away from source of ignition.
SAFE PACKAGING MATERIALS : No information available

[8.EXPOSURE CONTROLS / PERSONAL PROTECTION]


ENGINEERING MEASURES : Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Use local exhaust ventilation.
Use explosion-proof electrical equipment and prevent from static
electrocity.
Iron is apt to rust. Plant equipment should be treated with rust-resist.
LIMIT VALUES
ACGIH (TLV) : TWA 200 ppm,STEL 400 ppm
2-Propanol
OSHA (PEL) : PEL TWA 400ppm, TWA 980mg/m3, (2012 year edition)
Isopropyl alcohol
KCDS-No 000042-21 QUARTAMIN 86P CONC 4 / 7
Kao Corporation Revised Date June 18, 2014

PERSONAL PROTECTIVE EQUIPMENT


RESPIRATORY PROTECTION : Use chemical cartridge respirator for organic solvents, as appropriate to
situation.
HAND PROTECTION : Gloves (solvent-resistant)
EYE PROTECTION : Safety goggles
SKIN AND BODY PROTECTION : Solvent-resistant protective clothing
HYGIENE MEASURES : No information available

[9.PHYSICAL AND CHEMICAL PROPERTIES]


APPEARANCE
PHYSICAL STATE : Solid
COLOUR : White
ODOUR : Alcohol-like odour
pH : 6-8 (20% solution)
SPECIFIC TEMPERATURES / TEMPERATURE RANGES
AT WHICH CHANGES IN PHYSICAL STATE OCCUR
BOILING POINT : No information available
MELTING POINT : 38 ºC ( 100.4 ºF)
FLASH POINT : 22 ºC ( 71.6 ºF) (Cetaflash Closed-cup Apparatus)
FLAMMABILITY OR EXPLOSIVE PROPERTIES
FLAMMABILITY OR EXPLOSIVE : UPPER LIMIT : No information available LOWER LIMIT : No information
LIMITS available
VAPOUR PRESSURE : No information available
VAPOUR DENSITY : No information available
DENSITY (SPECIFIC GRAVITY) : No information available
SOLUBILITY
WATER SOLUBILITY : Soluble
SOLVENT SOLUBILITY : Soluble in ethyl alcohol
PARTITION COEFFICIENT: n- : No information available
OCTANOL / WATER (log Pow)
AUTO-IGNITION TEMPERATURE : No information available
DECOMPOSITION TEMPERATURE : No information available
ODOUR THRESHOLD : No information available
EVAPORATION RATE : No information available
FLAMMABILITY (SOLID,GAS) : No information available
VISCOSITY : No information available
OTHER DATA : No information available

[10.STABILITY AND REACTIVITY]


CHEMICAL STABILITY : Stable in general.
POSSIBILITY OF HAZARDOUS : May form flammable gas or vapor.
REACTIONS
May form explosive gas/air mixtures.
CONDITIONS TO AVOID : No information available
INCOMPATIBLE MATERIALS : No information available
HAZARDOUS DECOMPOSITION : No information available
PRODUCTS
OTHERS : No information available

[11.TOXICOLOGICAL INFORMATION]
ACUTE TOXICITY
KCDS-No 000042-21 QUARTAMIN 86P CONC 5 / 7
Kao Corporation Revised Date June 18, 2014

Oral
INFORMATION ON PRODUCT : Rat, LD50 : 1015 mg/kg (male), 1702 mg/kg (female)
Dermal
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : Stearyltrimethylammonium chloride: Category 4; Ref.(2)
Inhalation
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
SKIN CORROSION / IRRITATION
INFORMATION ON PRODUCT : Rabbit, undiluted, 4 hours semi-occluded application test (OECD404) :
Not classified
SERIOUS EYE DAMAGE / IRRITATION
INFORMATION ON PRODUCT : Rabbit, undiluted, OECD405 : Category 1
RESPIRATORY OR SKIN SENSITIZATION
RESPIRATORY
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
SKIN
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
MUTAGENICITY (GERM CELL MUTAGENICITY)
INFORMATION ON PRODUCT : Ames test (TA98,TA100,WP2try-) : Negative

Rec-assay, B.subtilis H17, M45 : Negative


INFORMATION ON INGREDIENTS : No information available
CARCINOGENICITY
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
IARC : Group 3: Not classifiable as to its carcinogenicity to humans.
Isopropyl alcohol
NTP : Not listed
EU : Not listed
OSHA : Not listed
REPRODUCTIVE TOXICITY
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : Isopropyl alcohol: Category 2; Ref.(1)
SPECIFIC TARGET ORGAN TOXICITY
- SINGLE EXPOSURE
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : Isopropyl alcohol: Category 1 (central nervous system, kidney, systemic
toxicity); Ref.(1)
- REPEATED EXPOSURE
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
ASPIRATION HAZARD
INFORMATION ON PRODUCT : No information available
INFORMATION ON INGREDIENTS : No information available
OTHER INFORMATION : No information available
KCDS-No 000042-21 QUARTAMIN 86P CONC 6 / 7
Kao Corporation Revised Date June 18, 2014

[12.ECOLOGICAL INFORMATION]
ECOTOXICITY : Rainbow trout, 96h, LC50 : < 0.1 mg/L
PERSISTENCE / DEGRADABILITY : No information available
MOBILITY IN SOIL : No information available
BIOACCUMULATIVE POTENTIAL : No information available
OTHER ADVERSE EFFECTS : BOD5 : 0 g/g
COD(Cr) : 2.75 g/g

[13.DISPOSAL CONSIDERATIONS]
Review "HANDLING AND STORAGE (Section 7)".
Passed to a licensed waste contractor.
Incinerate with little portions.
Risk of producing harmful gases such as carbon monoxide and
phosgene.
This material is containing flammable materials.
Be careful in case of incineration.
Remove the contents completely in case of disposal of the container.
Dispose of waste in accordance with local,state and federal regulations.

[14.TRANSPORT INFORMATION]
Follow all regulations in your country or region
INTERNATIONAL REGULATIONS
UN CLASS / UN NUMBER : Class 3 / UN1993
IATA : UN Number UN1993
Proper Shipping Name Flammable Liquid, n.o.s.(containing
Isopropanol)
Class 3
Packing Group II
IMDG : UN Number UN1993
Proper Shipping Name Flammable Liquid, n.o.s.(containing
Isopropanol)
Class 3
Packing Group II
Additional Information Marine pollutant
SPECIAL PRECAUTIONS FOR USER : Review "ACCIDENTAL RELEASE MEASURES (Section 6)".
Review "HANDLING AND STORAGE (Section 7)".
Ensure containers without breakage or leakage.
Ensure containers tightly fixed.
Follow all regulations in your country or region.
Keep away from source of ignition.
Emergency Response Guide(ERG) Numbers : 127

[15.REGULATORY INFORMATION]
Follow all regulations in your country or region.
INVENTORIES : ENCS(Japan) Yes
TSCA(USA) Yes
EINECS(EU) Yes
AICS(Australia) Yes
DSL(Canada) Yes
ECL(Korea) Yes
PICCS(Philippines) Yes
IECSC(China) Yes
KCDS-No 000042-21 QUARTAMIN 86P CONC 7 / 7
Kao Corporation Revised Date June 18, 2014

KAO Corporation is not able to check up the regulatory information in regard to the substances in your country or
region,therefore,we request this matter would be filled by your responsibility.

[16.OTHER INFORMATION]
REFERENCE : -Safety data sheet for chemical products - Part 1: Content and order of
sections(ISO 11014-1)
-International Chemical Safety Cards(ICSC) (Compiler's Guide)(1994)
(1)GHS Classification Database, National Institute of Technology and
Evaluation (NITE)
(2)Registry of Toxic Effects of Chemical Substances

To the best of the manufacturer's knowledge,the information contained herein is accurate. However, neither the
manufacturer, nor any of its affiliates, make any representations or warranties (expressed or implied), nor assumes any
liability(including liability for any direct, incidental, consequential, or other damages) with respect to the accuracy or
completeness of the information contained herein. Such information may be (without limitation) invalid if the specified
material is used in combination with another ,in a particular process, or under unusual conditions. Determination of
suitability of any material for any given purpose is the sole responsibility of the user who assumes all risk and responsibility
therefore. All materials may present unknown hazards and should be used with appropriate caution. The manufacturer
cannot and does not guarantee that the hazards described herein are the only ones that exist.

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