Diesel Addidative - ABRO Diesel Injector Cleaner DL-502
Diesel Addidative - ABRO Diesel Injector Cleaner DL-502
Diesel Addidative - ABRO Diesel Injector Cleaner DL-502
SECTION 1
Identification of the Substance and of the Company/Undertaking
MANUFACTURER’S NAME: ABRO INDUSTRIES, INC.
SECTION 2
Hazards Identification
Classification:
Flammable Liquids - Category 4 (Combustible)
Acute Toxicity, Inhalation - Category 4
Skin Irritation – Category 2
Eye Irritation – Category 2B
Carcinogenicity - Category 2
Specific Target Organ Toxicity (Single Exposure) – Category 3
Aspiration Hazard – Category 1
Chronic Aquatic Toxicity – Category 2
Label Pictogram(s):
Hazard Phrases: Flammable liquid and vapor. Harmful if inhaled. Causes skin irritation. Causes
eye irritation. Suspected of causing cancer. Suspected of causing genetic
defects. May cause respiratory irritation. May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways. Harmful to aquatic life.
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use. Do not handle until all safety precautions have been read and understood.
Avoid release to the environment.
Response: In case of fire: Use water spray, fog or foam. If on skin (or hair): Wash with plenty
of soap and water. Take off immediately all contaminated clothing and wash it
before reuse. If skin irritation occurs, get medical advice/attention. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Call a poison
center or doctor if you feel unwell. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention. If exposed or
concerned: Get medical advice/attention. If swallowed: Immediately all a poison
center or doctor/physician if you feel unwell. Do NOT induce vomiting.
Storage / Disposal: Store in a well-ventilated place. Keep cool. Store locked up. Keep container
tightly closed. Dispose of contents/container in accordance with
local/regional/national/international regulations.
SECTION 3
Composition/Information on Ingredients
SECTION 4
First Aid Measures
In Case of Inhalation
Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult, ensure airway is
clear and give oxygen. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR).
Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.
In Case of Ingestion
Do not induce vomiting. If spontaneous vomiting is about to occur, place victim's head below knees. If
victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to
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an unconscious person. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL
ATTENTION.
Note to Physician
If ingested this material represents a significant aspiration and chemical pneumonitis hazard. Induction of
emesis is not recommended.
SECTION 5
Fire Fighting Measures
Flammability Classification: Combustible Liquid
Flash Pt: > 140.00 F (60.0 C) Method Used: Pensky-Marten Closed Cup
Explosive Limits: LEL: No data. UEL: No data.
Autoignition Pt: No data available.
SECTION 6
Accidental Release Measures
Steps To Be Taken In Case Material Is Released Or Spilled
Large Spill:
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Approach release
from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into
an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see section 1 for emergency contact information and section
13 for waste disposal.
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Small Spill:
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Absorb with an
inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-
proof equipment. Dispose of via a licensed waste disposal contractor.
Environmental Precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform
the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
SECTION 7
Handling and Storage
Precautions to Be Taken in Handling
Isolate from sources of heat, sparks, and open flame. Open container in a well ventilated area. Avoid
breathing vapors and thermal decomposition products. Keep containers closed when not in use. Vapors
are heavier than air and will tend to accumulate in low areas. Avoid use in confined areas without
adequate ventilation. Areas of inadequate ventilation could contain concentrations high enough to cause
eye irritation, headaches, respiratory discomfort or nausea. Carefully evaluate processes using this
product at elevated temperatures to ensure safe operating conditions. Electrostatic buildup may occur
when pouring or transferring this product from its container.
SECTION 8
Exposure Controls/Personal Protection
Hazardous CAS# OSHA PEL ACGIH TWA Other Limits
Components
Fuel oil, no. 2 68476-30-2 No data TLV: 100 mg/m3 No data
Naphthalene 91-20-3 PEL: 10 ppm TLV: 10 ppm No data
STEL: 15 ppm
Proprietary Detergent NA No data No data No data
Solvent naphtha 64742-94-5 No data No data No data
(petroleum), Heavy
arom.
1,2,4- 95-63-6 No data No data No data
Trimethylbenzene
Polyalkyenepolyamine NA No data No data No data
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Respiratory Equipment (Specify Type)
Use approved organic vapor chemical cartridge or supplied air respirators when material produces vapors
that exceed permissible limits or excessive vapors are generated. Observe respirator assigned protection
factors (APFs) criteria cited in federal OSHA 1910.134. Self-contained breathing apparatus should be
used for firefighting.
Eye Protection
No special eye protection is normally required. Where splashing is possible, wear safety glasses with side
shields.
Protective Gloves
Neoprene, nitrile, polyvinyl alcohol (PVA), polyvinyl chloride and polyurethane gloves to prevent skin
contact.
Work/Hygienic/Maintenance Practices
Wash hands, forearms, and face thoroughly after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period. Appropriate techniques should be used to remove
potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
SECTION 9
Physical and Chemical Properties
Physical States: [ ] Gas [ X ] Liquid [ ] Solid
Melting Point: No data.
Boiling Point: No data.
Autoignition Pt: No data.
Flash Pt: > 140.00 F (60.0 C) Method Used: Pensky-Marten Closed Cup
Specific Gravity (Water = 1): 6.76 - 7.35 at 60.0 F (15.6 C)
Density: 0.811 - 0.881 at 60.0 F (15.6 C)
Vapor Pressure (vs. Air or mm Hg): No data.
Vapor Density (vs. Air = 1): No data.
Evaporation Rate: No data.
Solubility in Water: Insoluble
Percent Volatile: No data.
Appearance and Odor
Clear red liquid with a petroleum odor.
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SECTION 10
Stability and Reactivity
Stability: Unstable [ ] Stable [ X ]
SECTION 11
Toxicological Information
MIDDLE DISTILLATES, PETROLEUM: Long-term repeated (lifetime) skin exposure to similar materials
has been reported to result in an increase in skin tumors in laboratory rodents. The relevance of these
findings to humans is not clear at this time.
MIDDLE DISTILLATES WITH CRACKED STOCKS: Light cracked distillates have been shown to be
carcinogenic in animal tests and have tested positive with in vitro genotoxicity tests. Repeated dermal
exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and
increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in
severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations
resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung
function.
NAPHTHALENE: Severe jaundice, neurotoxicity (kernicterus) and fatalities have been reported in young
children and infants as a result of hemolytic anemia from overexposure to naphthalene. Persons with
Glucose 6-phosphate dehydrogenase (G6PD) deficiency are more prone to the hemolytic effects of
naphthalene. Adverse effects on the kidney have been reported in persons overexposed to naphthalene
but these effects are believed to be a consequence of hemolytic anemia, and not a direct effect.
Hemolytic anemia has been observed in laboratory animals exposed to naphthalene. Laboratory rodents
exposed to naphthalene vapor for 2 years (lifetime studies) developed non-neoplastic and neoplastic
tumors and inflammatory lesions of the nasal and respiratory tract.
Cataracts and other adverse effects on the eye have been observed in laboratory animals exposed to
high levels of naphthalene. Findings from a large number of bacterial and mammalian cell mutation
assays have been negative. A few studies have shown chromosomal effects (elevated levels of Sister
Chromatid Exchange or chromosomal aberrations) in vitro. Naphthalene has been classified as Possibly
Carcinogenic to Humans (2B) by IARC, based on findings from studies in laboratory animals.
DIESEL EXHAUST: Chronic inhalation studies of whole diesel engine exhaust in mice and rats produced
a significant increase in lung tumors. Combustion of kerosene and/or diesel fuels produces gases and
particulates which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or sulfur and
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hydrocarbons. Significant exposure to carbon monoxide vapors decreases the oxygen carrying capacity
of the blood and may cause tissue hypoxia via formation of carboxyhemoglobin.
TRIMETHYLBENZENES: This product contains Trimethylbenzenes. Literature data indicate that long-
term inhalation exposure causes blood effects in laboratory animals.
HEAVY AROMATIC NAPTHA: Heavy Aromatic Naphtha is a severe skin irritant, is an eye irritant, but is
not a skin sensitizer in mammals. Repeated inhalation exposures caused reduced growth rate, respiratory
tract irritation, congestion in liver and spleen, changes in blood tests and equilibrium disturbances. No
animal test reports are available to define carcinogenic, mutagenic, developmental, or reproductive
hazards.
PROPRIETARY DETERGENT: The Detergent is a severe skin and eye irritant and is a skin sensitizer in
animals. Effects of long term dermal exposures include hyperkeratosis and necrosis of the epidermis but
no evidence of increased incidences of tumors. Repeated dietary administration of high doses produced
depressed liver weights and body weight loss. Tests in animals demonstrate no carcinogenic activity. No
animal test reports are available to define developmental or reproductive hazards. The compound does
produce genetic damage in bacterial and mammalian cell cultures but has not been tested in animals.
CAS# 68476-30-2:
Acute toxicity, LD50, Oral, Rat, 12.00 GM/KG.
Results:
Behavioral: Ataxia.
Gastrointestinal:Hypermotility, diarrhea.
Nutritional and Gross Metabolic:Weight loss or decreased weight gain.
- Advances in Modern Environmental Toxicology., Senate Press, Inc., P.O. Box 252, Princeton Junction,
NJ
08550, Vol/p/yr: 6,1, 1984
CAS# 91-20-3:
Acute toxicity, LD50, Oral, Rat, 490.0 MG/KG.
Results:
Tumorigenic: Equivocal tumorigenic agent by RTECS criteria.
Blood: Lymphomas including Hodgkin's disease.
Tumorigenic Effects: Uterine tumors.
- Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al.,
Centre of International Projects, GKNT, Moscow Russia, Vol/p/yr: -,89, 1982
CAS# 64742-94-5:
Acute toxicity, LC50, Inhalation, Rat, 590.0 MG/M3, 4 H.
Results:
Effects on Newborn: Growth statistics (e.g., reduced weight gain).
- National Technical Information Service, Vol/p/yr: OTS0534724,
CAS# 95-63-6:
Acute toxicity, LD50, Oral, Rat, 5.000 GM/KG.
Results:
Maternal Effects: Other effects.
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
- Prehled Prumyslove Toxikologie, Marhold, J., Organicke Latky, Prague Czechoslovakia, Vol/p/yr: -,34,
1986
Irritation or Corrosion
Occasional skin contact with this product is not expected to have serious effects, but good personal
hygiene should be practiced and repeated skin contact avoided. This product can also be expected to
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produce skin irritation upon prolonged or repeated skin contact. Personal hygiene measures taken to
prevent skin irritation are expected to be adequate to prevent risk of skin cancer.
Carcinogenicity/Other Information
The International Agency for Research on Cancer (IARC) has determined that there is inadequate
evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC determined that there was limited
evidence for the carcinogenicity of marine diesel fuel in animals. Distillate (light) diesel fuels were not
classifiable as to their carcinogenicity to humans (Group 3A).
IARC has determined that there is sufficient evidence for the carcinogenicity in experimental animals of
diesel engine exhaust and extracts of diesel engine exhaust particles. IARC determined that there is only
limited evidence for the carcinogenicity in humans of diesel engine exhaust. However, IARC's overall
evaluation has resulted in the IARC designation of diesel engine exhaust as probably carcinogenic to
humans (Group 2A) because of the presence of certain engine exhaust components.
The International Agency for Research on Cancer (IARC) has also determined that there is sufficient
evidence for the carcinogenicity in experimental animals of light and heavy vacuum distillates, of light and
heavy catalytically cracked distillates and of cracked residues (including heavy thermocracked
distillates/residues) derived from the refining of crude oil.
The International Agency for Research on Cancer (IARC) and the Environmental Protection Agency
(EPA) have determined that naphthalene is a possible human carcinogen.
SECTION 12
Ecological Information
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- Acute Lethal Toxicity of Hydrocarbons and Chlorinated Hydrocarbons to Two Planktonic Crustaceans:
The Key Role of Organism-Water Partitioning, Abernethy, S., A.M. Bobra, W.Y. Shiu, P.G. Wells, and D.
Mackay, 1986
Bioaccumulative Potential
No data available.
Mobility in Soil
May partition into air, soil and water.
SECTION 13
Disposal Considerations
Waste Disposal Method
This product as produced is not specifically listed as an EPA RCRA hazardous waste according to federal
regulations (40 CFR 261). However, when discarded or disposed of, it may meet the criteria of an
"characteristic" hazardous waste. This material could become a hazardous waste if mixed or
contaminated with a hazardous waste or other substance(s). It is the responsibility of the user to
determine if disposal material is hazardous according to federal, state and local regulations.
SECTION 14
Transport Information
Multi-modal shipping descriptions are provided for informational purposes and do not consider container
sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not
indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed
for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of
the person offering the product for transport.
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Exceptions: None.
Environmental Hazards: Marine Pollutant
Transport in Bulk: N/A
Special Precautions:
Europe
(ADR/RID) UN/ID Number: UN1993
Proper shipping name: Flammable liquid, n.o.s. (Petroleum distallates, Trimethylbenzene,
Napthalene)
Hazard class: 3
Packing Group: III
Exceptions: None.
Environmental Hazards: Marine Pollutant
Transport in Bulk: N/A
Special Precautions:
SECTION 15
Regulatory Information
US EPA SARA Title III
Hazardous CAS# Sec.302 Sec.304 RQ Sec.313 Sec.110
Components (EHS) (TRI)
Fuel oil, no. 2 68476-30-2 No No No No
Naphthalene 91-20-3 No Yes 100 LB Yes Yes
Proprietary Detergent NA No No No No
Solvent naphtha 64742-94-5 No No No No
(petroleum), Heavy
arom.
1,2,4- 95-63-6 No No Yes No
Trimethylbenzene
Polyalkyenepolyamine NA No No No No
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US EPA CAA, CWA, TSCA
Hazardous CAS# EPA CAA EPA CWA EPA TSCA CA PROP 65
Components NPDES
Fuel oil, no. 2 68476-30-2 No No Inventory No
Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **
indicates statutory RQ.
Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a
chemical category.
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[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
SECTION 16
Other Information
NFPA Rating
Health: 1
Flammability: 2
Instability: 0
Special Hazard:
The supplier disclaims all expressed or implied warranties of merchantability or fitness for a specific use,
with respect to the product or the information provided herein, except for conformation to contracted
specifications. All information appearing herein is based upon data obtained from manufacturers and/or
recognized technical sources. While the information is believed to be accurate, we make no
representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore
users are responsible for verifying the data under their own operating conditions to determine whether the
product is suitable for their particular purposes and they assume all risks of their use, handling, and
disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance
upon, information contained herein.
This information relates only to the product designated herein, and does not relate to its use in
combination with any other material or process.
ABBREVIATIONS:
NG="NOT GIVEN" BT="BETWEEN"
<="LESS THAN" >="GREATER THAN"
ND = Not Determined NA = Not Applicable
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