NGA ISO 6974 Manual

Operating Manual
AC Natural Gas Analyzer ISO 6974

Manual part number 23070.042 version 4.0 2000
Software part number 23060.001 version 04.05
AC Analytical Controls BV
P.O Box 10054, 3004 AB Rotterdam
Innsbruckweg 35, 3047 AG Rotterdam, the Netherlands
Phone : +31-10-462 4811
Fax : +31-10-462 6330
E-mail : [email protected]
AC Analytical Controls Inc

3494 Progress Drive Bensalem, Pennsylvania 19020, USA
Phone : +1-215-638-7078
Fax : +1-215-638-7096
AC Analytical Controls Asia Pacific Ltd

30 Robinson Road, Robinson Towers #03-04 048546 Singapore
Phone : +65-324-9017
Fax : +65-324-9019
 Copyright to comply with SPARKS, OR COLUMN. KEEP THIS
Analytical Controls these requirements. SOURCES OF HEAT. COLUMN AWAY FROM
2000 POTENTIAL LIVE
WARNING WARNING ELECTRICAL
All Rights A warning calls HYDROGEN IS A SOURCES AT ALL
Reserved. attention to FLAMMABLE GAS. IF TIMES WHILE
Reproduction, a condition or HYDROGEN OR ANY HANDLING.
adaptation, or possible situation OTHER FLAMMABLE
translations that could cause GAS IS USED,
without prior injury to the user. PERIODIC LEAK
written permission TESTS SHOULD BE
is prohibited, CAUTION PERFORMED. BE
except as allowed A caution calls SURE THAT THE
under the copyright attention to a HYDROGEN SUPPLY
laws. condition or IS OFF UNTIL ALL
possible situation CON-NECTIONS ARE
First edition, that could damage MADE AND ENSURE
December 1995 or destroy that THAT THE INLET
product or the FITTINGS ARE EITHER
Printed in the
user's work. CONNECTED TO A
Netherlands COLUMN OR CAPPED
Safety Information AT ALL TIMES
HYDROGEN GAS IS
Throughout this PRESENT IN THE
MS-DOS and manual, the reader
Microsoft are INSTRUMENT. DO
and/or system NOT USE PLASTIC OR
registered operator will be
trademarks and RUBBER GAS LINES
required to utilize FOR HYDROGEN.
Windows is a hazardous
trademark of chemicals. During CAUTION
Microsoft the performance or All gases are
Corporation. routine dangerous when
Warranty maintenance, the compressed. Do not
reader and/or store cylinders where
The information system operator may they might be dropped
contained in this be exposed to or exposed to excess
document is subject potentially heat. Always direct
to change without dangerous the flow of
notice. electrical voltages compressed gases
Analytical Controls
and/or other away from people.
hazards. To reduce
makes no warranty the personal risk Electrical Hazards
of any kind with involved, the
regard to this WARNING
following DANGEROUS
material, guidelines are
including, but not ELECTRICAL
established. These VOLTAGES ARE
limited to, the requirements are
implied warranties PRESENT IN MANY
within accepted PARTS OF THE
of merchantability standards for
and fitness for a SYSTEM, EVEN WITH
general analytical THE POWER
particular purpose. laboratory
Analytical Controls SWITCHES TURNED
operation. Please OFF. UNPLUG ALL
shall not be liable refer to
for errors THE MAIN POWER
established safety CORDS FROM THE
contained herein or requirements and
for incidental or POWER SOURCE FOR
government safety ALL THE SYSTEM
consequential and disposal for
damage in COMPONENTS PRIOR
additional TO SERVICING ANY
connection with the information.
furnishing, OF THE SYSTEM
performance, or use Chemical Hazards COMPONENTS.
of this material. WARNING
WARNING
Safety Symbols LIGHT HYDROCAR- METAL CAPILLARY
BONS ARE TOXIC. COLUMNS ARE
Warnings in the UTILIZE THE CON- EXCELLENT
manual or on the TENTS OF ALL AC CONDUCTORS OF
instrument must be STANDARDS ONLY IN ELECTRICITY. THE
observed during all A FUME HOOD. OVEN HEATER COILS
phases of AVOID INHALING INSIDE THE OVEN IN
operation, service, FUMES AND CON- THE GAS CHROMA-
and repair of this TACT WITH ANY PART TOGRAPH ARE NOT
instrument. OF THE BODY. ELECTRICALLY
Failure to comply INSULATED AND
with these WARNING CARRY LETHAL VOL-
precautions LIGHT HYDROCAR- TAGE. TO AVOID
violates safety BONS ARE EXTREME- CONTACT WITH
standards of design LY FLAMMABLE. THE LETHAL ELECTRICAL
and the intended FUMES AND VAPORS VOLTAGE WHILE
use of the FROM LIGHT HYDRO- CHANGING METAL
instrument. CARBONS ARE COLUMNS, TURN OFF
Analytical Controls EASILY IGNITED. THE MAIN POWER TO
assumes no KEEP THE CONTENTS THE HP GAS
liability for the OF ALL AC VIALS CHROMATOGRAPH
customer's failure AWAY FROM FLAMES, BEFORE REMOVING
OR INSTALLING THE
Contents
Contents
TABLE OF CONTENTS PAGE
Pre-installation ............................. 1
Pre-installation Requirements..................................1-2
Gas Requirements...............................................1-3
Gas Purity ...................................................1-3
Physical Requirements..........................................1-4
Electrical Requirements........................................1-5
Pre installation Checklist.....................................1-6
System Configuration .........................................1-6
Software .....................................................1-6
Recording Important Numbers....................................1-7
Installation ................................. 2
Installing the Hardware........................................2-2
Introduction .................................................2-2
Cabling (General) ............................................2-2
Column Installation............................................2-4
Installing the AC Report Generator Software....................2-5
Introduction .................................................2-5
Installing the AC Report Generator Software ..................2-5
Microsoft Windows 95 or Microsoft Windows NT Instructions ..2-6
Report generator ............................. 3
Installing the AC Report Generator Software....................3-2
Introduction .................................................3-2
Installing the AC Report Generator Software ..................3-2
Microsoft Windows 95 or Microsoft Windows NT Instructions ..3-2
Introduction...................................................3-3
Creating Reports...............................................3-4
The Agilent ChemStation and AC Report Generator View...........3-5
Short Menus ..................................................3-5
Full Menus ...................................................3-6
Operating the Short Report Generator Menus.....................3-7
What Is a Sequence? ..........................................3-7
Single Analysis or Calibration Run ...........................3-7
Operating the Full Report Generator Menus......................3-8
The AC Report Generator Overview...............................3-9
The AC Report Generator Main Menus ..........................3-10
The AC Report Generator Data Base Menus .....................3-10
The AC Report Generator Report Template Menus ...............3-11
Operating the AC Report Generator Main Window.................3-12
AC Report Generator Main Menu Commands ......................3-12
File ......................................................3-12
View ......................................................3-12
Help ......................................................3-12
Operating the AC Report Generator Data Base Editor............3-13
The Data Base Editor Window .................................3-13
Inserting New Compounds ...................................3-15
Deleting an Existing Compound .............................3-15
AC Report Generator Data Base Editor Menu Commands ..........3-16
File ......................................................3-16
Options ...................................................3-17
View ......................................................3-17
Window ....................................................3-17
Help ......................................................3-17
Calibration Options .........................................3-18
Version 2000/4.0 Contents-2

Contents
Edit the Variables ..........................................3-19
Operating the AC Report Generator Report Template Editor......3-20
What Is a Report Template? ..................................3-20
Creating a New Report Template ..............................3-20
AC Report Generator Report Template Menu Commands ...........3-23
File ......................................................3-23
Functions .................................................3-23
Options ...................................................3-24
View ......................................................3-24
Window ....................................................3-24
Help ......................................................3-24
Adding or Editing a Compound ................................3-25
The Report Items Dialog .....................................3-26
The Special Field Dialog ....................................3-27
The Options Dialog ..........................................3-28
Setting Up a GC Method........................................3-29
What Is a ChemStation GC Method? ............................3-29
Creating a GC Method ........................................3-29
The Specify Report Dialog ...................................3-30
The Calibration Settings Dialog .............................3-31
The Calibration Table Dialog ................................3-32
The Run Time Checklist Dialog ...............................3-34
Calibration...................................................3-36
Calibrating Data Bases ......................................3-37
Calibrating by Using the Sequence ...........................3-37
Manually Calibrating the GC Method and Data Base ............3-38
The Formula Editor............................................3-40
Default Variable Names ......................................3-41
Creation of a New Calculation ...............................3-42
Editing the Formula Data Base ...............................3-44
Protecting Your Formula Data Base ...........................3-46
Editing the CONSTANT.CSV File ...............................3-46
Operation .................................... 4
Introduction...................................................4-2
AC NGA 6974 Separation Range .................................4-3
Why Is Analysis of Natural Gas Required? .....................4-3
Performance Assurance..........................................4-4
Configurtion...................................................4-5
Sequence of Analysis...........................................4-8
Analysis description...........................................4-9
Calculations..................................................4-10
Coversion factors.............................................4-12
Converting Heating Values .................................4-12
Operation.....................................................4-13
Calibration .................................................4-14
Method description............................................4-16
Spare parts kit and consumables kit NGA ISO 6974..............4-17
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1
Pre-installation
Pre-installation
Pre-installation Requirements
Pre-installation Requirements
This chapter contains pre-installation procedures for the AC Analytical Controls
Natural Gas Analyzer. Because AC Natural Gas Analyzers are based upon the
Agilent 6890 Series gas chromatograph (GC), make sure your laboratory meets
the environmental, weight, power, and gas requirements as described in the Site
Preparation and Installation Manual for the Agilent GC. This section contains
gas requirements, physical requirements, electrical requirements, a pre-installation
checklist for the AC Natural Gas Analyzer, and a record form.
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Pre-installation
Gas Requirements
Gas Requirements
Gas Purity
Some gas suppliers furnish “instrument” or “chromatographic” purity grades of
gas that are intended specifically for chromatographic use. We recommend only
these grades for use with Agilent GC detectors.
Only very low ppm levels (≤0.5 ppm) of oxygen and total hydrocarbons should be
present in the gas supplies. Oil-pumped air supplies are not recommended because
they may contain large amounts of hydrocarbons. The addition of high-quality
moisture, hydrocarbon, and oxygen traps immediately after the main tank pressure
is highly recommended. Refer to the section "Assembling the Gas Plumbing" of
the Agilent GC Site Preparation and Installation Manual for more information on
using traps.
Table 1-1. Gas Purity Recommendations
Usage of gas Gas type Minimal Pre-pressure Traps/filters

purity
bar / psi
Carrier Argon 99.995 7 / 100 moisture/charcoal1
Detector Gases Argon 99.995 5 / 75 moisture/charcoal1
Hydrogen 99.995 5 / 75
Air zero grade 5 / 75

(or better)
Support Gases Actuator air dry 5 / 75
1When the gas purity is according the recommendation, no filters are needed,
however it might be advisable to install the recommended filters, to avoid any
problems due to contamination.
NOTE It is preferable not to combine the air for valve switching with the air for the FID.
Version 2000/4.0 1-3 of 8

Pre-installation
Physical Requirements
Physical Requirements
• Width - Approximately 2.1 meters (7 feet) for the complete system.
• Depth - Approximately 0.6 meters (2 feet) for the complete system.
• Height - Approximately 0.8 meters (2 feet 8 inches) for the complete system.
• Weight - 70 KG (155 lb.)
The analyzer may be installed in any reasonably accessible area.
WARNING THE GAS CHROMATOGRAPH WILL VENT HOT OVEN AIR FROM
THE REAR OF THE GAS CHROMATOGRAPH WHEN THE OVEN IS
COOLING DOWN TO AMBIENT TEMPERATURE. ENSURE NOTHING
IS PLACED BEHIND THE GAS CHROMATOGRAPH THAT MAY
CONTACT THE HOT EXHAUST AIR. AC MANUFACTURES AN
ALUMINUM "OVEN EXHAUST DEFLECTOR" (AC PART NO.
59.40.200) THAT DEFLECTS THE EXHAUST AIR UP, AWAY FROM
THE REAR OF THE GAS CHROMATOGRAPH. THIS DEVICE EASILY
AND QUICKLY ATTACHES TO THE REAR OF THE GAS
CHROMATOGRAPH.
Version 2000/4.0 1-4 of 8

Pre-installation
Electrical Requirements
Electrical Requirements
For North America and geographical areas that use 110 - 120 VAC :
• Gas chromatograph: 110 - 120 VAC, 20 Amp grounded service. Please refer
to the Agilent manual for additional information if required.
• All accessories: 110 - 120 VAC, 6 standard 3 prong grounded outlets, the
MAXIMUM TOTAL current requirement for all of the accessories is 7.5
Amps.
For Europe and geographical areas that use 220 - 240 VAC :
• Gas chromatograph: 220 - 240 VAC, 10 Amp grounded service. Please refer
to the Agilent manual for additional information if required.
• All accessories: 220 - 240 VAC, 6 grounded outlets, the MAXIMUM TOTAL
current requirement for all of the accessories is 7.5 Amps.
NOTE Do not turn on the oven until all electrical and gas connections have been
completed and checked for correctness and leaks.
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Pre-installation
Pre installation Checklist
Pre installation Checklist

System Configuration
Agilent Vectra PCThe Agilent Kayak system bundle configuration changes on
a regular basis (typically every 6 months or so) to be faster, have a faster
computer chip, and have a larger hard disk drive (HDD). The following are
system guidelines:
• For one or two instruments, Agilent 6890 Series GC only:
Supported Configuration Recommended Configuration
Pentium/75 MHz Pentium III
32 MB of memory 64 MB of memory
• For three or four instruments, either an Agilent 5890 Series II or

Agilent 6890 Series GC:
• Supported Configuration Recommended Configuration
• Pentium/133 MHz Pentium III
• 48 MB of memory 128 MB of memory
• For each computer listed above, the following are also required:
- Hard disk drive 1 GB or more, larger disk
allows more data storage
- Floppy disk drive 3.5-inch for software loading
- CD-ROM For software loading
- Mouse Supported by Microsoft Windows
- Printer Hewlett-Packard LaserJet or DeskJet
- Video monitor SVGA or USVGA
Software
• Microsoft Windows NT
• Agilent G2070AA ChemStation revision A.07.01 higher
• Agilent G2071AA ChemStation additional instrument software
NOTE The Agilent G2070AA ChemStation software consists of "core" software plus one
Agilent GC instrument driver (either for the Agilent 5890 Series II or Agilent
6890 Series GC). Each additional Agilent GC requires the Agilent G2071AA
additional instrument software, up to a maximum of three add-ons for four
instruments per system.
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Pre-installation
Recording Important Numbers

In any verbal or written correspondence with Analytical Controls or Agilent
concerning your AC Report Generator or ChemStation software, you will need to
know the following information :
AC Report Generator Revision Code
AC Report Generator License No.
Agilent G2070AA Revision Code Example A.06.0X
Agilent G2070AA License No.
Microsoft Windows Type and Revision Code
Microsoft Windows License No.
Agilent Gas Chromatograph Serial No.
Agilent Computer Serial No.
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Pre-installation
Take a few minutes now to fill in the empty boxes above. The revision code is
found on the diskettes or CD-ROM. The license numbers are found on the
documentation shipped with the software.
NOTE ChemStation rev 04.02 can only be used with Windows 95. ChemStation 05.02
can be used with Windows 95 or Windows NT.
NOTE When using Windows NT, the HP-IB card must be of type 82341C and the
Agilent-IO library software must be installed.
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2
Installation
Installation
Installing the Hardware

Introduction
This chapter contains installation procedures for AC Analytical Controls Natural
Gas Analyzers for the Agilent 6890 Series gas chromatograph (GC). Refer to the
Site Preparation and Installation Manual of the Agilent GC for installation
information.
Cabling (General)
The Agilent GC communicates electronically with other instruments through
cables. Refer to the section “Connecting Cables” of the Site Preparation and
Installation Manual of the Agilent GC.
• The Agilent 6890 Series GC is connected to the computer via HP-IB or
LAN.
NOTE If you have additional HP-IB devices (GCs and automatic samplers) connected to
the computer, connect the HP-IB cables in sequential order. Do not connect all
HP-IB cables to a single HP-IB connector. Please refer to the appropriate Agilent
manual.
1
Computer Printer
6890
Mouse
1 HPIB / LAN interface PC - GC
Figure 2-1Cabling configuration for the Agilent 6890 Series GC.
2-2 of 6 Version 2000/4.0

Installation
GC rear side
3 1 Argon carrier
1
2
2 Argon reference TCD
5 4
9
6 3 Argon makeup FID
10 4 Air FID
7
5 Hydrogen FID
10
6 Air valves
8
7 INET / LAN
8 HPIB
9 Remote
10 Oven cooling
Figure 2-2Rear side connections
Version 2000/4.0 2-3 of 6

Installation
Column Installation
Column Installation
NOTE AC Natural Gas Analyzers come with pre installed and checked-out columns.
WARNING TEMPERATURE-SENSITIVE ITEMS (GAS CYLINDERS, CHEMICALS,

REGULATORS, ETC) SHOULD NOT BE LOCATED IN THE PATH OF
THE HEATED EXHAUST. ALSO, EXERCISE CARE WORKING AT THE
REAR OF THE INSTRUMENT DURING COOL-DOWN CYCLES TO
PREVENT POSSIBLE BURNS.
Please refer to the appropriate chapter in the Agilent GC manual for correct
installation of the capillary column.
2-4 of 6 Version 2000/4.0

Installation
Installing the AC Report Generator Software

Introduction
The AC Report Generator is a software package for gas analyses that enables you
to create your own reports. These reports contain the composition results of the
analyses in a customized layout. Furthermore, by using the physical constants
stored in a data base and by using formulas residing in the software, various gas
properties can be calculated and reported as well. You can edit both the reports
and the data bases.
For operating the various Agilent parts, please refer to the appropriate Agilent
manuals.
NOTE A working knowledge of MS-DOS, Microsoft Windows, and Agilent G2070AA

ChemStation is required to install and utilize the AC Report Generator
successfully.

These installation steps assume that the following software is already installed on
the computer's hard disk:
• Microsoft Windows 95 or Microsoft Windows NT
• Agilent G2070AA ChemStation revision A.05.02 or higher
If one of these is not installed, you must install it first. For installation
information, refer to the installation guide of the appropriate program.
Version 2000/4.0 2-5 of 6

Installation
Microsoft Windows 95 or Microsoft Windows NT Instructions

1 Turn the computer and monitor on. The computer will boot up and start Microsoft
Windows.
NOTE It is possible that the computer does not start in Microsoft Windows but in MS-
DOS. This is shown with a black screen with a DOS prompt ">". To start
Microsoft Windows from MS-DOS, type “WIN” after the DOS prompt.
2 Insert the AC Report Generator software CD-ROM into the CD-ROM drive.
3 From the Microsoft Windows 95 or NT main screen, click the Start icon (bottom
left-hand corner of screen), and select Run....
4 In the Run dialog, select d:setup, and click the [OK] button.
5 The program starts and will ask several questions. Follow the instructions on the
screen.
2-6 of 6 Version 2000/4.0

3
AC Report Generator
AC Report Generator

Introduction
The AC Report Generator is a software package for gas analyses that enables you
to create your own reports. These reports contain the composition results of the
analyses in a customized layout. Furthermore, by using the physical constants
stored in a data base and by using formulas residing in the software, various gas
properties can be calculated and reported as well. You can edit both the reports
and the data bases.
For the various Agilent parts, please refer to the appropriate Agilent manuals.
NOTE A working knowledge of MS-DOS, Microsoft Windows, and Agilent

ChemStation is required to install and utilize the AC Report Generator
successfully.

These installation steps assume that the following software is already installed on
the computer's hard disk:
• Microsoft Windows 95 or Microsoft Windows NT
• Agilent G2070AA ChemStation revision A.04.02 or A.05.02
If one of these is not installed, you must install it first. For installation
information, refer to the installation guide of the appropriate program.
Microsoft Windows 95 or Microsoft Windows NT Instructions

1 Turn the computer and monitor on. The computer will boot up and start Microsoft
Windows.
NOTE It is possible that the computer does not start in Microsoft Windows but in MS-
DOS. This is shown with a black screen with a DOS prompt ">". To start
Microsoft Windows from MS-DOS, type “WIN” after the DOS prompt.
2 Insert the AC Report Generator software disk into the disk drive.
3 From the Microsoft Windows 95 or Microsoft Windows NT main screen, click the
Start icon (bottom left-hand corner of screen), and select Run....
4 In the Run dialog, select a:setup, and click the [OK] button.
5 The program starts and will ask several questions. Follow the instructions on the
screen.
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AC Report Generator
Introduction
Introduction
This section describes the software of the AC Analytical Gas Analyzers. The AC
Gas Analyzers are controlled by dedicated software—the AC Report Generator
integrated with the Agilent ChemStation operational software. Refer to the
appropriate Agilent ChemStation manual for more information.
The AC Report Generator is a software package that automates calculations of the

physical properties of a gas. The software includes several standard report
formats, and you can also create a report customized to your needs.
A standard data base for compounds constants is included. An edit mode allows
you to change the data base; however, the use of passwords prevents unauthorized
use of the data base. Several data bases for different temperatures and pressures
can be created.
The calculation formulas for the physical properties are stored in a data base as
well. This data base can be expanded with customized calculations with the aid of
a separate program.
The AC Report Generator is an external program that can be executed from the
Agilent ChemStation environment. A special menu view is added to the Agilent
ChemStation for this purpose.
This chapter describes the main components and features of the AC Report
Generator for the AC Gas Analyzers that will help you understand this software.
You should know MS-DOS, Microsoft Windows, and Agilent G2070AA
ChemStation to use the AC Report Generator successfully.
For the various Agilent parts, please refer to the appropriate Agilent manuals.
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AC Report Generator
Creating Reports
Creating Reports
The AC Report Generator is started automatically after the analysis and will print
a customized report on the default printer.
NOTE The AC Report Generator can also be used as standalone software for
reprocessing purposes.
The AC Report Generator uses the integration report of the Agilent ChemStation
and a report template file that you create. This template is linked to a data base
file containing a list with compounds and their physical constants and relative
response factors. You specify the template name in the GC method under the
“Runtime Checklist”. The data base also specifies a calibration mechanism that
will be used for the calculations.
Special calculations for gas analysis are implemented in a formula data base. You
can select these calculations in the customized report template. The formula data
base can be expanded with your calculations using a separate program.
NOTE The formulas may not contain iterative constructions. Contact AC Analytical
Controls bv for those calculations.
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AC Report Generator
The Agilent ChemStation and AC Report Generator View
The Agilent ChemStation and AC Report Generator

View
The Agilent ChemStation and AC Report Generator software operates on two
levels, short menus and full menus. The following flow charts explain the
software organization of both levels. The commands give you access to standard
features of the Agilent ChemStation such as running a method or sequence,
loading a data signal, and calibrating a data signal manually. It also gives access
to the AC Report Generator itself for setting up or editing data bases and
customized reports. The AC Report Generator is a separate program with its own
menus. This is explained in more detail in the following sections.
Short Menus
RunControl Method Sequence View Help

Run Method Load Sequence Parameters 1 Method and
Method Run Control
Sample Info Print Sequence Table 2 Data Analysis
Method
Run Load Sequence 3 Report
Sequence Layout
Pause Sequence Save Sequence 4 AC Report
generator
Resume Sequence Save Sequence As Show Top Toolbar
Stop Print Sequence Show Status Toolbar
Run/Inject/Sequence
Partial Sequence Reprocessing Copy
Change Access Level
Chemstation Scheduler
Chemstation Status
The Agilent multitechnique ChemStation operational software commands are
underlined to give you an insight of the integration with the AC Report Generator
software. For more information about the Agilent multi-technique ChemStation
software, refer to the operation manual or the Agilent multitechnique ChemStation
Help screens.
NOTE These commands are also available in different views of the Agilent ChemStation;
however, do not use the commands in these views if operating with the AC Report
Generator.
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AC Report Generator
The Agilent ChemStation and AC Report Generator View
Full Menus
RunControl Method Sequence Setup View Help

Run Method Load Method Sequence AC Report 1 Method
Parameters generator Setup and Run
Control
Sample Info Save Method Sequence 2 Data Analysis
Table
Run Sequence Save Method Load 3 Report
As Sequence Layout
Pause Print Method Save 4 AC Report
Sequence Sequence generator
Resume Save Show Top
Sequence Sequence As Toolbar
Stop Print Show Status
Run/Inject/ Sequence Toolbar
Sequence
Partial Reprocessing
Sequence Copy
Change Access
Level
Chemstation
Scheduler
Chemstation
Status
To switch between the short or full menus, select View / 1 Method and Run
Control, then View / Short Menu or Full Menu, and then View / AC Report
generator.
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AC Report Generator
Operating the Short Report Generator Menus
Operating the Short Report Generator Menus

You can create or load sequences and run the sequence using the short menus. It is
also possible to perform a single analysis by editing the sample information and
running the current selected method. Reporting the data will be automated.
What Is a Sequence?
A sequence is a series of instructions that automate the analysis of samples. A
sequence can be used to inject each sample automatically and to acquire and
analyze the data according to the method you have specified for the sample. A
sequence can also include calibration samples to calibrate your system.
When the sequence starts, it will show information on the screen about the sample
to be injected. After pressing the GC Start button, the analysis will be started.
NOTE For full automation of gas analyses with a sequence, you will need a gas sampling
valve.
For more information about how to use the sequence editor, refer to the Agilent
multitechnique ChemStation manuals or Help screens.
Single Analysis or Calibration Run

By selecting RunControl / Run Method, a single analysis will be performed
based on the information entered in the sample information dialog. Choose this
dialog by selecting RunControl / Sample Info. For more information about this
dialog, refer to the Agilent multitechnique ChemStation manuals.
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AC Report Generator
Operating the Full Report Generator Menus
Operating the Full Report Generator Menus

You can analyze data and access the AC Report Generator Setup as well as load,
edit, and/or run sequences in the full menus. Refer to the section “Operating the
Short Report Generator Menu” for more information.
You are authorized to start the AC Report Generator to set up data bases or report
templatesby selecting Setup / AC Report Generator Setup. Also calibration or
recalibration of the GC method can be performed manually. The latter can be
necessary when creating or editing GC methods.
The next sections describe in detail how to use the AC Report Generator to set up
data bases and/or report templates.
For information about calibration or recalibration, refer to the Agilent

multitechnique ChemStation manuals or Help screens.
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AC Report Generator
The AC Report Generator Overview

Start the program from the Agilent ChemStation by selecting Setup / AC Report
Generator Setup in the full menus of the AC Report Generator menu.
The AC Report Generator contains five areas:

• The title bar shows the name of the AC Report Generator screen.
• The menu bar gives you access to the menu commands.
• The toolbar consists of icons to give you quick access to the menu
commands.
• The frame window is an area where windows or icons of new or existing
data bases and/or report templates appear after selecting File / New or File
/ Open.
• The message bar gives you information about the current selected menu or
item.
Title
Menu
Tool
Frame
Status
Figure 3-1. The AC Report Generator screen.
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AC Report Generator
Data base and/or report template windows can be displayed in the frame window
by selecting File / New (to create a new file) or File / Open (to open an existing
file). Each window has its own menu attached to it. The menu of the current
selected window will be displayed. Select Window to switch between the
different windows or let them display differently. Select View to switch the icons
toolbar and the status bar on or off.
The AC Report Generator Main Menus
You can create new data bases and/or report templates or switch to a different
Agilent ChemStation instrument.
File View Help
New Toolbar Contents
Open... Status Bar How to use help
Select Search for help on...
Instrument
Exit About AC Report generator
The AC Report Generator Data Base Menus
The data base window contains information about the physical constants of the
compounds and the way they are calibrated.
File Options View Window Help
New Calibration Toolbar New Contents
Options Window
Open... Convert Status Cascade How to use help
standards Bar
Close Edit Variables Tile Search for help on...
Print... Arrange About AC Report
Icons Generator
Save
Save As...
Protect database/
Enter password
Exit
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The AC Report Generator Report Template Menus
This window displays your report template, and you are able to change it.
File Functions Options View Window Help
New Select Options Toolbar New Contents
Database Window
name
Open... Select Status Cascade How to
Agilent Bar use help
Report
name
Close Edit font Tile Search for
help on...
Save Edit report Arrange About AC
field Icons Report
Generator
Save As... Add
compounds
Protect Add Report
template/Enter header
password items
Store Add special
calibration field
Print...
Print Preview
Print Setup...
Exit
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Operating the AC Report Generator Main Window
Operating the AC Report Generator Main Window

You can open and/or create data bases and report templates in the main window.
You can also switch the AC Report Generator to another instrument session of the
Agilent ChemStation. All file paths, such as main data path and the methods path,
will then be reset to the appropriate directories from the Agilent ChemStation.
AC Report Generator Main Menu Commands
File
New Creates a new empty data base or report
template
Open Loads the desired data base or report template
Select Instrument Switches to another ChemStation instrument
Exit Terminates the program and returns to the

Agilent ChemStation
NOTE Once a file has been loaded or created, the menus will change to the
corresponding file type (data base or report template).
View
Toolbar Switches the toolbar On or Off
Status bar Switches the status bar On or Off
Help
These menu commands give you online assistance when operating the AC Gas
Analyzers.
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Operating the AC Report Generator Data Base Editor

The Data Base Editor Window
The data base editor is a window where you can edit the physical constants of a
list of compounds. Each compound is numbered with a calibration number, which
is a reference number to the group (Grp area) peak in the Calibration Table of the
GC method.
The data base editor window consists of two areas:

• The compound relative areas, such as Calnr, Compound, Signal, and
physical constants
• The metering constants, which are used for the certain calculations and
also specify at which temperature and pressure the physical constants are
measured
Figure 3-2. The data base editor window.
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Select an area by clicking it with the mouse button. Press [Tab] to switch from
one area to the next. The columns will switch automatically to the left or right
when you reach the edge of the box. The area is in overwrite mode. To switch to
edit mode, press [Esc] or double-click with the mouse in the area. In edit mode,
the left and right arrows on your keyboard move the cursor in the area to edit the
value.
The Calnr area is used as a reference number to the calibration table of the GC
method. Each compound must be entered in the GC calibration table and must
have the Calnr in the Grp field. This will identify the peak in the calibration and
link it to the data base.
The Compound area is shown in the report template when selecting a compound
for the report. Each compound must be assigned to a signal group. This is a
number entered in the Signal area. For each signal group, one compound must be
marked as Absolute Compound. This area can be checked or unchecked by
clicking the area or pressing the space bar. You must calibrate this compound for
the Absolute Response using an external standard. You can enter a value here or
do this automatically using a calibration level. Refer to the section “Calibrating
Data Bases” for more information.
NOTE The signal numbers are renumbered automatically after a calibration analysis.
The Absolute Response area can also be entered as a formula. Start the field with
an “=” sign. The formula can consist of standard operators such as:
* : multiply by
/ : divide by
+ : add to
- : subtract from
area[calnr] : The integration area of the compound with
calibration number calnr.
mol[calnr] : The unnormalized mol percentage of the compound with
calibration number calnr.
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See the absolute response area of the hexane compound in figure 3-2. This is an
example of how the GPA method calculates the hexane contents in the sample.
NOTE When referring to mol percentages of other compounds, these compounds must be
able to calculate the mol percentage.
The Relative Response area is used in combination with the Signal area. The
integration area of the compounds in the same Signal group will be multiplied
with the Absolute Response of the Absolute Compound and the Relative
Response factor. This final result will be the molar percentage of the compound.
Relative response factors can be found in the appendixes. They depend on the
type of detector used.
The Metering constants area is where the physical constants of the compound
can be entered. Make sure you enter the constants in the appropriate units. It is
possible to add new physical constants to the area for user calculation purposes.
Refer to the section “The Formula Editor.”
NOTE Many physical constants can vary depending on the units used or the conditions
(temperature and pressure) under which they were determined. When editing a
data base, you must be aware of this because this can influence the outcome of the
calculations.
Inserting New Compounds

1 Select the insertion point by clicking on the appropriate row in the No area.
2 Click the [Insert] button.
3 Enter a unique number in the Calnr area.
4 Fill in the areas of the compound.
Deleting an Existing Compound

1 Select the insertion point by clicking on the appropriate row in the No area.
2 Click the [Delete] button.
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AC Report Generator Data Base Editor Menu Commands
File
template
Open... Loads the desired data base or report template
Close Closes the selected window
Print... Prints the contents of the data base
Save Saves the data base on disk using the same

name
Save As... Saves a new data base on disk and names the
data base
Protect database/ Choose Protect database to protect the data

Enter password base with a password or Enter Password
when the data base is protected. To unprotect
a data base permanently, just click the [OK]
button in the Enter password dialog and save
the data base.

Agilent ChemStation
NOTE There can be an unlimited amount of data base files. This is only limited by the
amount of disk space available.
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Options
Calibration Options Sets up the normalization mechanism
Convert standards Enters a dialog where calibration standard

concentrations can be converted from weight
% or gas volume % to mol %
Edit variables Adjusts the name, unit, and number of the

variables for the data base
View
Window
These menu commands can organize the display of your windows (data base and
report template windows). For more information, refer to the manual supplied
with Microsoft Windows.
Help
Analyzers.
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Calibration Options
Select Options / Calibration Options to display the Calibration Options dialog
box. A maximum allowable deviation for the calibration analysis can be entered.
Figure 3-3. The Calibration Options dialog box.
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Edit the Variables
Select Options / Edit variables to display the Constants dialog box. In this
dialog, you can alter the contents of the data base. New physical constants can be
added or removed.
Note This operation should be performed before editing the data base.
The Name area lists the name of the physical constant. The Unit area lists the unit
of measure of the constant. The Variable area lists the internal name of the
variable. This name can be used in the formula data base for calculations.
Note Do not change these names without changing the formula data base. Never change
the names Compressibility, MolWeight, and Density because these are used for
the calculations of the weight %, gas vol %, and liquid volume %.
The Decimals area lists the precision of the variable, and the Max area lists the
maximum allowable value you can enter for the constant.
When you click the [Add] or [Delete] button, constants can be added or removed
from the table. The constants will always be added to the end of the table.
Figure 3-4. The Edit Constants dialog.
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Operating the AC Report Generator Report Template Editor
Operating the AC Report Generator Report Template

Editor
What Is a Report Template?
A report template is an empty layout of the final report of your analysis. It
consists of a series of object areas that display values such as text, percentages
(mol, weight, etc) of a compound, report header information, or calculation
properties.
The report can be set up for one or more pages. Each page contains a number of
lines and a number of characters per line depending on the chosen font size.
NOTE This is approximately 38 lines and 75 characters for pitch 12.
Figure 3-5. The report template window.
A caret refers to the current position on the report page. Each object can be
selected by clicking it with the mouse button. The text will show up as white text
on a black background. Pressing the Delete key will remove the object. To move
an object, click it with the right mouse button, drag it to another position, and then
release the mouse button.
Some areas in the dialog can be converted with small calculations. The standard
operators that can be used in such areas are: multiply by (*), add to (+), subtract
from (-), divide by (/), natural logarithm of x
(Ln(x)), and the inverse natural logarithm of x (InvLn(x)).
Creating a New Report Template
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1 Select File / New.
2 Select Report template file from the dialog box, and click the [OK] button.
3 Select Functions / Select Database name, select the appropriate data base file,
and click the [OK] button.
4 Click with the left mouse button in the top left area of the report template window
to position your caret.
5 Select Functions / Add Report header items.
6 Select a header item (e.g., Data File Name) from the Report option area, and
click the [OK] button.
7 Repeat steps 4–6 for every item you want to include in your report.
8 Select a position with the left mouse button to add a section below the header
items, containing some calculations.
9 Select Functions / Add special field.
10 Select a calculation (e.g., Ideal density of gas) from the Type area, and click the
[OK] button.
11 Repeat steps 8–10 for every calculation you need to include in your report.
12 Select a position with the left mouse button to add a list of compounds with the
concentrations to the report.
13 Select Functions / Add compounds.
14 Click the [Select All] button to select all available compounds.
15 Select the concentrations to be displayed and other fields by checking them in the
Check area.
16 Click the [OK] button.
17 Select a position below the last compound name in the template to add a line with
the totals of each column in the compounds list.
18 Select Functions / Add compounds.
19 Select the same concentration areas as in step 15, and enter in the name field a
width of approximately 46 to align the columns better.
20 Deselect the Add Column Header check box.
21 Type “Totals” in the Name area.
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22 Click in the Formula area.
23 Now directly click a compound name from the list box, and enter a “+” sign.
24 Repeat step 22 for all compounds, but do not put a + sign after the last compound.
25 Click the [Deselect All] button.
27 Select the first line in the template to add a user text at the top of the report.
28 Select Functions / Add special field.
29 Select “Text output” from the Type area.
30 Type the necessary text (e.g., Customized report) in the Name area, and click the
[OK] button.
31 Select File / Save to save the report template.
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AC Report Generator Report Template Menu Commands
File
template
Open Loads the desired data base or report template
Close Closes the selected window
Save Saves the report template on disk using the

same name.
Save As... Saves a new report template on disk and

names the report template.
Protect template/ Choose Protect template to protect the

Enter password template with a password or Enter password
when the template is protected.
Store calibration Saves the absolute response factors of the

compounds into the connected data base
Print... Prints the customized report on the selected

printer
Print Preview Previews the printout on the screen
Print Setup... Sets up the printer

Agilent ChemStation
NOTE There can be an unlimited amount of report template files. This is only limited by
the amount of disk space available.
Functions
Select Database Connects the report template with a data base
name
NOTE This will erase the contents from the report template.
Select Agilent Selects a ChemStation integration report

Report name (extension *.csv). The report calculator will
calculate the results and show this in the
report template.
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Edit font Changes the character font of the report
Edit report field Opens the appropriate dialog for the selected
field on the report template
Add compound Opens a dialog where compounds’ fields can

be added to the report template
Add Report header Opens a dialog where report header fields

items can be added to the report template
Add special field Opens a dialog where special calculations

fields can be added to the report template
Options
Options Sets the number of pages of the report
template and an option to report to comma-
separated file format (CSV)
View
Window
These menu commands can organize the display of your windows (data base and
report template windows). For more information, refer to the manual supplied
with Microsoft Windows.
Help
Analyzers.
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Adding or Editing a Compound
Select Functions / Add compounds to edit a compound object in the Edit
Compound Item dialog. This dialog is also used to add new compound objects to
the report template.
NOTE Multiple compound objects can be created only if the dialog is entered through
Functions / Add compounds.
Figure 3-6. The Edit Compound Item dialog box.
The Name area lists the name of the compound. It can be used to change the
default name from the data base. The Formula area can be used to enter a simple
calculation. The standard operators that can be used are: multiply by (*), add to
(+), subtract from (-), divide by (/), natural logarithm of x (Ln(x)), and the inverse
natural logarithm of x (InvLn(x)).
NOTE Make sure that your calculation equation is legal and does not contain unknowns.
The result will otherwise be reported as “E304” during calculations.
The results of the compounds can be obtained by first clicking in the Formula
area, then entering an operator, and clicking the necessary compound. If the
Formula area is empty, an operator is not required. A string will be added to the
Formula area such as “C[10].” The number refers to the calibration number of the
compound. You can also type in “C[10]” instead of selecting it. The formula
calculation will be performed on the concentrations that are checked in the Check
area.
The Add Column Header area adds a descriptive text at the top of the selected
compound objects explaining the columns. This area will be disabled when an
existing compound object is being edited.
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Click the [Select All] button to select all the compounds in the Select compound:
list box. Click the [Deselect All] button to deselect all the compounds in the
Select compound list box.
The Field area lists what properties can be displayed for a compound. You can
select a property by checking the Check area of the field. The Width area
specifies the width of the column field to be used. This is expressed in the number
of characters and is an approximation depending on the type of font chosen. The
Decimals area sets the number of floating point decimals for the concentration
and area fields.
The Report Items Dialog

With the Report Items dialog, essential information of how the analysis is
performed can be added to the template, such as the date the analysis was
performed, the data file name, the sample name, etc. Select Functions / Add
Report header items to enter the Report Items dialog.
Figure 3-7. The Report Items dialog box..
You select the required feature in the Report option area. The Tabstops area can
be used to specify the width of the columns. A default value will be used
automatically. The column widths must be separated by a comma. For example
“15,20” sets the width of the first column (the name of the feature) to 15
characters and the second column (the result) to 20 characters.
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The Special Field Dialog
Numerous calculations can be selected in your report. Select
Functions / Add special field to enter the Select special calculation dialog. With
this dialog, you can select which calculations you want to perform on your
sample. It is even possible to add new calculations to the formula data base by
using the separate formula editor program. Refer to the section “The Formula
Editor” for information on this.
Figure 3-8. The Select special calculation dialog box.
Each calculation object consists of three fields: its name, the calculated value, and
the unit of measure in which it is expressed. The widths of the fields can be
altered in the Tabstops area, but a default will be used automatically. The result is
formatted to the specified number of floating point decimals in the formula data
base. You cannot, therefore, alter that here.
You can select the required calculation in the Type area. The Name and Unit area
are set automatically with the appropriate name and unit of measure, but you can
change them anytime.
A variable will be set in the Formula area. This variable can be converted to
another unit of measure or value by editing the Formula area. You can use the
standard operators for this purpose (+, -, *, /, Ln, and InvLn). You can even use
other variable names when multiplying variables.
Example: The real density of a gas mixture is the ideal gas density divided by the
compressibility of the gas mixture. Entering “DGas/Zmix” in the Formula area
can perform this.
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The Options Dialog
Select Options / Options to enter the Options dialog. This dialog is used to set
some report options.
Figure 3-9. The Options dialog box.
The total to be displayed and printed pages can be set with the Number of Pages
area. You will not lose the objects on the second page if you accidentally set the
number of pages to 1. Simply set the number of pages to 2 again, and the objects
will reappear.
Check the Spool results to CSV file check box to create a “REPORT.CSV” in
your data directory. This is a special comma-separated file format with the results
of your analysis. The file can be read into Microsoft Excel or other programs
using an import filter for comma-separated file format.
Each report object is entered in the file as a separate line. The order that the lines
will be arranged is in the time order that you created the objects to be in the report
template. Once you have created the template, the order will stay the same;
however, as soon as you alter the contents of the template, the order can change.
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Setting Up a GC Method
What Is a ChemStation GC Method?
In the Agilent ChemStation, an analysis is performed by running a method. This
can be done either by running a sequence for multiple sample analyses or by using
the start run option for a single analysis.
A ChemStation method is a file containing the parameters that an Agilent

ChemStation instrument needs to perform an analysis. These param-eters are the
instrument parameters, the integration events, the calibration parameters, the
calibration table, and the report specifica-tion. Refer to the Agilent multitechnique
ChemStation manual for more detailed information about ChemStation features.
The Agilent ChemStation creates two report files on disk when the analysis is
finished. The AC Report Generator uses these files for its calculations. Therefore,
several settings of the GC method are required to work with the AC Report
Generator.
Creating a GC Method
To create a GC method, you should enter several requirements. In the next
section, a full explanation is made about the requirements. There are, however,
more options available in the dialogs. For more informa-tion about these, please
refer to the Agilent multitechnique ChemStation manuals.
The GC method must contain:

• An oven temperature program
• A runtime table for valve and signal switching
• An integration events table that will integrate the peaks correctly
• A calibration table containing all compounds
• A link to a report template to report and print a gas report.
Specific information, such as the oven temperature program and a runtime table
for the valve switching, will be discussed in the appropriate analyzer chapter.
Refer to the Agilent multitechnique ChemStation manuals for the integration
events table.
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The Specify Report Dialog
Make sure that the correct GC method is loaded. In the Agilent ChemStation,
select View / 2 Data Analysis and then select Report / Specify Report to enter
the dialog.
Figure 3-10. The Specify Report dialog box of the ChemStation method.
Some items must be set or selected to operate correctly together with the AC
Report Generator. Set Calculate: to “Norm%”, Based On: to “Area”, and Sorted
By: to “RT” in the Quantitative Results group. The Report Style: area must be
set to minimal on “Short”.
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The Calibration Settings Dialog
In the Agilent ChemStation, select View / 2 Data Analysis and then select
Calibration / Calibration Settings to enter the Calibration Setting dialog. This
dialog sets the way the Agilent ChemStation will calibrate the integration report.
The AC Report Generator can only use one-point and linear calibration curves.
All other curves will not be handled by the AC Report Generator.
Figure 3-11. The Calibration Settings dialog box of the ChemStation

method.
In the Default Calibration Curve group, make sure that the Type area is set to
“Piecewise” or “Linear”.
For diagnostic purposes, it is advisable to set the Calculate Uncalibrated Peaks

area by clicking on the With Rsp Factor option button with the setting at
1.00000.
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The Calibration Table Dialog
In the Agilent ChemStation, select View / 2 Data Analysis and then select
Calibration / Calibration Table Options to enter the Calibration Table dialog.
This dialog serves a few functions:
• To store the available compounds in the chromatogram at their respective
retention times
• To set a link for each compound with a unique number (entered in the Grp
area) with the Calnr area in the AC Report Generator’s data base
• To set the calibration standard amount for multiple levels/standards
• To update retention times and response factors automatically based on a
recalibration table
Figure 3-12. The Calibration Table Options dialog box of the Agilent
ChemStation method.
The RT area lists the retention time. The Signal area lists from the detector. This
area is different from the Signal area in the AC
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Report Generator’s data base. The Compound area lists the name of the
compound. This name will only be printed in the calibration report of the Agilent
ChemStation and will not be used for the AC Report Generator.
The Grp area is a unique number. It refers to the compound in the data base with
the same Calnr. The Lvl area lists the calibration level. You can have multiple
calibration standards. Each standard must be assigned to a calibration level. The
Amt mol % area lists the concentration of your standard.
NOTE It is always important to use calibration concentrations in mol %. The AC Report

Generator relies on this. If your standard is given in a different concentration unit
of measure, use the data base function Options / Convert standards to obtain
concentrations in mole %.
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The Run Time Checklist Dialog
In the Agilent ChemStation, select View / 1 Method and Run Control and then
select Method / Run Time Checklist to enter the dialog. This dialog lists the
options that the Agilent ChemStation will perform when running a GC method.
The Pre-Run Command / Macro area contains information about which macro
will be run before the analysis. Please type “AC_SendPIDSettings” in this area.
This macro will send thermal PID constants to the GC before the actual analysis.
These constants adjust the thermal zone’s isothermal stability. They can be
adjusted in an .ini file in the instrument directory (e.g.,
C:\AgilentCHEM\1\PID.INI).
The Post-Run Command / Macro area contains information about which macro
command will be run after the analysis. The AC Report Generator will be run
from the macro “gas_run”, and this macro has a parameter that specifies the name
of the report template file. Figure 3-13 shows that the AC Report Generator will
be executed after the analysis and that it will create a gas report based on the
template file “ISO6976”.
Figure 3-13. The Run Time Checklist dialog box.
The name of an integration method is listed in the Analysis Method for Second
Signal area. This GC method will only be used to integrate the second signal of
the Agilent ChemStation. It does not program the oven and temperature zones. It
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is especially useful when having difficulties in integration of two signals with the
standard GC method.
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Calibration
Calibration
Calibration of a gas chromatographic system must be performed on a regular basis
to establish response factors. A gravimetric calibration standard, containing
known amounts of the compounds in it, is used for the calibration.
You should also calibrate if you injected sample in a loop under atmospheric
conditions. The barometric pressure will then influence the total amount of sample
in the loop. For those systems, a day-to-day calibration is required to compensate
for barometric pressure differences.
You need to calibrate all compounds that are checked as Absolute Compound in
the data base editor except for those that are based on a response formula.
You need to create a GC method calibration table containing concentrations for all
those marked compounds. The concentrations must be entered in mol percentages.
If the calibration standards are in weight % or gas vol %, you can convert these by
selecting Options / Convert standards in the data base editor.
NOTE You are allowed to use multiple calibration standards by defining various
calibration levels. But only one-point or linear calibration techniques may be
used.
A special calibration report is created in the AC Report Generator when you open
a standard ChemStation calibration report. This calibra-tion report is a fixed
template, so it cannot be altered. It consists of a list of compounds, their found
concentrations (mol %), the concentrations in the standard, and the difference
between those two. Both values are underlined and displayed in red if the
difference exceeds a criteria specified by the user. Refer to the “Calibration
Options” section.
The absolute response factors found are compared to the factors from the previous
calibration, and if the difference exceeds the user-specified percentage, those
response factors are underlined and displayed in red as well. These new absolute
response factors will be stored in the data base if you are calibrating automatically
via postrun. The specifications can be entered in the data base under the
Calibration Options dialog.
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Calibration
Calibrating Data Bases
In the Agilent ChemStation, a calibration can be performed in different ways. You
can select View / 1 Method and Run Control and then select RunControl / Run
Sequence to run a sequence. The calibration will then be fully automated based
on a calibration level that you supply. You can also recalibrate manually later by
selecting View / 2 Data Analysis and then selecting Calibration / Recalibrate.
Calibrating by Using the Sequence
Sequences are normally used for multiple sample analyses. This requires the use
of an automatic sampler or a gas sampling valve.
First select View / AC Report generator. Then select Sequence / Sequence

Table... to enter the Sequence Table dialog. For an exact description of how to
use the sequence editor, please refer to the Agilent multitechnique ChemStation
manuals.
In the Sequence Table dialog box in figure 3-14, you can see an example of how
you can set an analysis as a calibration run. The Cal Level area lists the reference
number for the recalibration table in the GC method. This level contains the
concentration information of the calibration standard. For more information on
this, refer to the Agilent multitechnique ChemStation manuals and Help screens.
Figure 3-14. The sequence editor.
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Calibration
Manually Calibrating the GC Method and Data Base
Manual calibration can be necessary if the automatic calibration fails. This might
be possible if you set the method up the first time, or when the retention times are
shifted too far outside the calibration window. The manual calibration can only
be selected in the Full menu view.
1 Select View / 2 Data Analysis.
2 Select File / Load / Method to load the GC method.
3 Select File / Load Signal to load the data signal.
4 Select Calibration / Recalibrate.
Figure 3-15. The Recalibrate dialog box.
5 Enter a calibration level for your standard. If there is only one standard, it will
probably be 1.
6 Check Average option button if the response factors need to be averaged with the
last responses. Check the Replace option button if the response factors can be
replaced.
8 On the message box “Calibrated peak(s) missing. Update the identified peak(s)”,
click the [OK] button.
9 Click the [OK] button in the calibration table.
10 On the message box “Do you want to remove lines with a zero amount ?”, click
the [No] button. The GC method is now calibrated. The next step is to calibrate
the data base connected to your report template.
11 Select View / 4 AC Report generator.
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Calibration
12 Select Setup / AC Report generator Setup to start the AC Report Generator
program.
13 Select File / Open to open your report template (*.TFI file).
14 Select Functions / Select Agilent Report name to open the report.
15 Now the calibration will be listed on the screen. Select File / Store Calibration.
This stores the response factors in the connected data base.
16 Selecting File / Exit to close the program.
There are two ways that the program can be used, either automatically with the
postrun option or manually by direct processing.
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The Formula Editor
The Formula Editor

The formula editor is a tool that can be used to add or to change the available
calculations. This tool cannot be started from outside the Agilent ChemStation
environment.
The Formula Editor is located in the subdirectory “GASPROG” under the Agilent
ChemStation root (usually “C:\AgilentCHEM’). The calculations are stored in the
same directory in the file “RGAFORM.FOR.” You can enter the Formula Editor
dialog by double-clicking the file “FORMEDIT.EXE.”
Each calculation must be simple based on straightforward calculation operators

such as adding (+), subtracting (-), multiplying (*), and dividing (/). Bracketing
can be used to set the calculation priority. For example, “A*(B-C)” will first
subtract “C” from “B” and multiply the result with “A”.
NOTE Iterations and recursive calculations are not allowed.
You can use the natural logarithm to raise numbers to a power. Ln(x) will take the
natural logarithm from “x”. InvLn(x) will reverse this process. For example, “xy
can be expressed as “InvLn( y*Ln(x) )”.
Each compound is stored in the data base. Each percentage and each physical
constant has a unique variable name. To access these variables, a special function
is available called Sigma. The sigma function will summate the result of the
“function” for each compound in the data base.
NOTE You are not allowed to use the sigma function twice in one formula.
For example the “inferior molar calorific value” for the sample is calculated as:
max compounds
Molar Calorific Value = ∑ ( mol * InfCal )
j=1
j j
This means it is the sum of the function “mol fraction multiplied with the inferior
heating value” for all compounds. In the data base, this would be entered as
“Sigma(mol% * InfCal)/100”. The factor 100 is to convert the mol percentage to a
mol fraction.
Each calculation result will be assigned to a variable name. You can use these
names again in different formulas.
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AC Report Generator
The Formula Editor
Default Variable Names
The next variables can only be used in the Sigma( ) function. You can change the
predefined constants. Also, new variables can be added for compounds. Refer to
the section “Editing the CONSTANT.CSV file.”
Table 3-1. The Default Compound-Related Variables
Variable Name Use
Mol % Mol percentage normalized to 100%
Unmol % Mol percentage
Wt % Mass percentage normalized to 100%
Vol % Gas volume percentage normalized to 100%
Lqvol % Liquid volume percentage normalized to 100%
Pres The metering pressure at which constants are
determined in Pa
Temp The metering temperature at which constants are
determined in K
Predefined
Constants
Molwt Molar weight in g/mol-1
Density Liquid density in g/ml-1 or specific gravity
Rvp Vapor pressure in psi
Compress Compressibility
Sum Summation factor
InfCal Inferior calorific value in kJ/mol-1
SupCal Superior calorific value in kJ/mol-1
Hn Gross heating value in BTU/mol-1
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AC Report Generator
The Formula Editor
Creation of a New Calculation
The next steps will guide you in creating a new calculation formula.
1 Determine exactly how the calculation must be performed in scientific notation.
2 Determine which variables you need for the calculation and how they are named.
3 Proceed with step 5 if all variables are available in the compound data base. See
figure 3-2.
4 Add the necessary variables in the “CONSTANT.CSV” file. Refer to the section
“Editing the CONSTANT.CSV File.”
5 Write down the complete scientific formula in data base notation format (using
operators and the functions Sigma, Ln, and InvLn).
NOTE Make sure that the units of measure of the variables comply with each other in the
formula.
6 Split the formula into subformulas if more than one Sigma function is used.
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AC Report Generator
The Formula Editor
Example: The calculation of the ideal inferior calorific value on volume basis.
1 The scientific notation would be:
The ideal inferior calorific value on volume basis:
~ o
(t1,V (t 2, p2)) =
o P2
H H (t1) *
R * T2
,
where
The ideal calorific value on molar basis:

max compounds
∑
o o
H (t1) = ( x j * H j (t1)
j =1
2 You need the variables Xj and Hj, which are the mol fraction (mol %) and inferior
heating value (InfCal), and the metering constants P2 (Pres) and T2 (Temp).
The gas constant is supplied in the formula data base as R.
3 Every constant is known so proceed with step 4.
4 The formula would be:
(Sigma(Mol% * InfCal)/100) * Pres/(1000 * Temp * R)
5 The inferior calorific value on molar basis is already calculated in another

formula, so replace the part “Sigma(Mol% * InfCal)/100” with the variable
“H_Inf_Mol” to obtain:
H_Inf_Mol * Pres/(1000 * Temp * R)
This formula could be entered in the formula data base.
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AC Report Generator
The Formula Editor
Editing the Formula Data Base
First you need to load the correct data base. For the AC Report Generator, the
only file to be used is located in the subdirectory “GASPROG” under the
ChemStation directory (usually C:\AgilentCHEM) and is named
“FORMEDIT.EXE”. Double-click “FORMEDIT.EXE” to open the Formula
Editor dialog. Select File / Open, select “RGAFORM.FOR” from the File Name:
area, and click the [OK] button. Now select File / Edit the formulas to open the
Formulas dialog.
The list box area, located in the lower part of the dialog, lists all available
calculations that exist showing you the variable name, the formula name, and the
unit. The calculations are ordered alphabetically on the variable name.
With the [Add] and [Delete] buttons, calculations can be added or deleted from
the list box. The current selected calculation is listed in the other areas where it
can be edited.
The Variable name area lists the name used in the calculations internally. You
can use any character you like; however, avoid the use of numbers and operators
such as *, /, +, and -.
NOTE Do not use variable names that are already assigned to constants variables.
Figure 3-16. The formula editor.
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AC Report Generator
The Formula Editor
The Formula area lists the calculation formula. Type your calculation here. The
Unit area lists the unit in which the calculation will be expressed. The Formula
text lists the Namearea that can be selected in the Select Special Calculation
dialog. This information together with the unit can be changed later on in the
report template.
The Order area is very important and specifies the calculation order. This must
be used when a variable is used in the formula, which itself is based on another
formula. The calorific value, for example, means that the “ideal molar calorific
value” will have order number 1 and, therefore, will be calculated first, and the
“ideal volume calorific value” must have order number 2.
The Number Format area lists the formatting string for the calculation result.
The number specifies the number of decimals the result displays.
The Variable Visible check box indicates whether the calculation will be visible
in the report template or not. This is useful if you are using subcalculations and do
not want the user to see them.
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AC Report Generator
The Formula Editor
Protecting Your Formula Data Base
You can protect your data base with a password. After you are finished editing the
formulas, select the command File / Enter new Password. Now type in a
password, and click the [OK] button. Save the file with the command File / Save
or Save as.
If you load a file, then the file can be locked with a password. You can edit its
contents; however, Save and Save As are disabled. First select File / Enter
Password, and type in your password. The Save and Save As commands will be
enabled if the password is correct.
Editing the CONSTANT.CSV File

The CONSTANT.CSV file is located in the GASPROG directory under the
ChemStation directory (usually C:\AgilentCHEM). It contains information about
the physical constants in the compound data base. They will be listed in the
compound data base editor window.
If a calculation requires additional compound information, then you can add this
to the file. The file is in comma-separated format. Open the file with Microsoft
“Notepad”.
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AC Report Generator
The Formula Editor
Table 3-2. The “CONSTANT.CSV” File
"MolWeight","g/mol","molwt",3,0,2000
"Density","g/ml","density",4,0,2
"Vapor Pressure","psi","rvp",2,0,1000000
"Compressibility","","compress",4,0,2
"Summation factor","","sum",4,-1,2
"Inferior Calorific Value","kJ/mol","infcal",2,0,1000000
"Superior Calorific Value","kJ/mol","supcal",2,0,1000000
"Gross heating value","Btu/mol","Hn",1,0,1000000
Each character string must be bracketed with quotation marks. Numbers should
not be bracketed.
The first string area lists the name that will show up in the compound data base
editor. The second is the unit of the constant. The third string is the calculation
variable that can be used in the formula data base to reference the constant. The
fourth area lists the number of decimals displayed in the constant in the compound
data base. The last two areas lists the minimum and maximum values of the
constant.
NOTE Do not change the order and variable names of the current CONSTANT.CSV file
because the existing compound data bases will contain incorrect information.
Add new constants to the end of the .CSV file on a new line. The maximum
number of constants in the file is 50.
Version 2000/4.0 3-47 of 47

4
Operation
Operation
Introduction
Introduction
This section describes the operation, configuration, and analysis of the AC
Analytical Controls Natural Gas Analyzer (NGA) ISO 6974. The AC system is
based upon the Agilent 6890 Series gas chromatograph (GC). Refer to the
appropriate Agilent manuals for detailed information on the Agilent GC.
The AC Analytical Controls Natural Gas Analyzer (NGA) ISO 6974 consists of an
Agilent 6890 Series gas chromatograph (GC) optimized for ISO 6974 natural gas
analysis, the ChemStation, and the AC Report Generator software. The AC NGA
6974 determines hydrogen, helium, oxygen, nitrogen, carbon dioxide, and
hydrocarbons from C1 up to C8. The AC NGA 6974 application complies with the
international standard ISO 6974 for natural gas analysis. The application incorporates
a high level of automation: the dedicated software controls all events within the
system, performs calibration, and reports the calculated physical properties and the
individual components’ concentrations of the natural gas streams.
Natural gas is a major energy source for domestic, commercial and industrial
customers. It can be used within change to its composition as found in the gas
reservoir. Natural gas generally consists of methane and other saturated
hydrocarbons and some non-flammable gases. Analysis of natural gas is required to :
• Calculate physical properties to determine market value.
• Assure product quality
• Monitor and adjust production processes.
• Calculate mix ratios to optimize furnace performance.
The value of an individual natural gas is primarily determined by the amount of

thermal energy it contains, as measures in British thermal units (Btu) or calorific
value (CV) . The value also depends on certain other physical properties such as
liquid content, burning characteristics, dew point, density and compressibility. The
composition of an individual natural gas varies depending on its source.
Version 2000/4.0 4-2 of 17

Operation
Introduction
AC NGA 6974 Separation Range

• Hydrocarbons C1–C8
• Inert gases: helium, hydrogen, oxygen, nitrogen and carbon dioxide.
Table 4-1. Typical Concentration Ranges of Natural Gas Components

Component Mole % Component Mole %
Hydrogen 0.01–1 Methane 50–100
Helium 0.01–1 Ethane 0.1–15
Oxygen 0.1–1 Propane 0.001–5
Nitrogen 0.1–40 C4–C8 0.01–0.5
hydrocarbons
Carbon Dioxide 0.1–30
Why Is Analysis of Natural Gas Required?

Analysis of natural gas is required to:
• Calculate physical properties to determine the market value
• Ensure the product quality
• Monitor and adjust processes
• Calculate mix ratios to optimize furnace performance
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Operation
Performance Assurance
Performance Assurance
The AC NGA 6974 systems and methodology are thoroughly tested to comply with
ISO 6974 performance specifications. The assured performance in terms of
concentration and retention time repeatability of the AC NGA 6974 exceed the
required ISO 6974 repeatability by several factors due to the HP 6890 Series GC’s
excellent stability of the pneumatics and temperature control. Table 4-2 shows the
assured repeatability for the AC NGA 6974.
Table 4-2. Comparison of ISO 6974 Specifications with AC NGA 6974
ISO 6974 Assured
Repeatability Repeatability
Concentration
Relative Standard Relative Standard
Range
Deviation (%) Deviation (%)
% mole/mole
10–100 0.1 0.05
1–10 1 0.5
0.1–1 10 2
0.01–0.1 30 5
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Operation
Configurtion
Configurtion
The AC NGA 6974 application for determining composition of natural gases uses an
Agilent 6890 Series GC with electronic pneumatics control (EPC) equipped with
packed GC columns, a thermal conductivity detector (TCD), and a flame ionization
detector (FID) configured in series. The AC NGA 6974 utilizes argon as carrier gas.
This carrier gas allows detection and quantification of helium and hydrogen.
Figure 4-1 to
Figure 4-5 illustrates the flow diagram, the column positions, the chromatogram, the
data base and the report for the AC NGA 6974.
Table 4-3 to Table 4-7 shows the typical concentration ranges, comparison of
specifications, retention time repeatability, column descriptions, used valves,
positions, description and part numbers for the columns, the valves used in the
instrument, standard possible calculations, conversion factors, GC method setpoints
and the runtime table for the AC NGA 6974.
Column 1 Column 2
Front Inlet (Argon)
Front Detector
V2 V3 V4
1 1 1
2 6 2 6 2 6
TCD FID
PTA
Gas sample in V1 5 3 5
3 5 3
4 4 4 Back Detector
on/off
1 mL
Gas sample out
Figure 4-1. The AC NGA ISO 6974 flow diagram.
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Operation
Configurtion
Column 2
Column 1
Figure 4-2The AC NGA 6974 column positions in GC .
Table 4-3. Description and Part Numbers for NGA ISO 6974
Configuration
Column Description Part No. for Maximum
Replacement temp °C
1 2 m x 1/8 in., HayeSep R 10.70.103 250
(80–100 mesh)
2 3 m x 1/8 in., Molsieve 13X 10.70.102 375
(80–100 mesh)
For conditioning these columns, they have to be mounted in a separate GC.
The maximum oven temperature is 175°C.
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Operation
Configurtion
Table 4-4. Valves used in the instrument

Valves Function
Valve 1 Sample introduction ON/OFF valve
Valve 2 Gas sampling valve
Valve 3 Stop flow column 1
Valve 4 Stop flow column 2
Vale 1 is used to make reproducible and operator-independent injections. Valve 1

blocks the gas sample to the GSV. The sample flush time and injection time are time
table controlled.
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Operation
Sequence of Analysis
Sequence of Analysis
Standby
column 1 column 2 TCD FID
Injection
Elution column 2
Elution column 1
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Operation
Analysis description
Analysis description
The AC NGA 6974 is equipped to analyze natural gas streams according to ISO
6974. The system contains two columns and three six-port valves.
A gas sampling valve (V2) injects the sample in column 1 (HayeSep R) to separate
inert gases and methane from the C2–C8 hydrocarbons. Inert gases (excluding
carbon dioxide) and methane elute to column 2 (Molsieve 13X) while the C2–C8
fraction is retained on column 1. Column 2 separates the inert gases (excluding
carbon dioxide) and methane, which elute to the TCD for quantification. After
elution of methane, column 2 is bypassed, and the C2–C8 fraction plus carbon
dioxide elutes from column 1, utilizing a column oven temperature program. The C2
and C3 components are quantified on the TCD, while C4–C8 hydrocarbons are
quantified with the FID. Final results are reported with the AC NGA 6974 software.
Refer to Figure 4-1 for the flow diagram.
Figure 4-3 illustrates the chromatogram produced on an AC NGA 6974 system for a
natural gas sample analysis according to ISO 6974. Table 4-1 shows the typical
concentration ranges of the components analyzed.
TCD1 B, (D0831\SIG10002.D)
18.119 - Neopentane
19.685 - n-Pentane
16.249 - n-Butane
19.263 - i-Pentane
15.602 - i-Butane
5.486 - Methane
22.689 - n-Hexane
Norm.
2500
2000
1500
1000
8.452 - Carbondioxide
4.311 - Nitrogen
9.416 - Ethane
12.515 - Propane
3.498 - Oxygen
500
0 5 10 15 20 25 min
Figure 4-3. The AC NGA ISO 6974 analysis.
Version 2000/4.0 4-9 of 17

Operation
Calculations
Calculations
This section describes the automatic calculation and reporting of some physical
properties and the individual component concentrations. The AC NGA 6974 uses
the AC Report Generator software fully integrated with the multi technique
ChemStation in a Microsoft Windows environment to control all GC functions. This
integrated software package automates all aspects of the calibration, the gas analysis
through customized data reporting.
The AC Report Generator defines many calculations for the analyst according to
methods such as ASTM D 2421, D 3588, ISO 6976, and GPA 2172. In addition to
these, you can add your own calculations. Table 4-5 shows the standard available
calculations.
Table 4-5. Standard Calculations According to ISO 6974

ISO 6974
Liquid volume
Liquid vapor pressure
Compressibility of mixture
Real specific gravity at 15.55°C (60°F)
Real Btu
GPM
Ideal calorific value on molar basis (inferior + superior)
Ideal calorific value on mass basis (inferior + superior)
Ideal calorific value on volume basis (inferior + superior)
Real calorific value on volume basis (inferior + superior)
Ideal wobbe index (superior)
Real wobbe index (superior)
Density
NOTE Additional calculations can be added manually to the report.
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Operation
Calculations
To reduce operator involvement, the software contains a standard data base (see
Figure 4-4) for components’ constants and formulas. A user-friendly edit mode
allows authorized users to edit the data base. The AC Report Generator software
includes several standard report formats, and you can create customized reports
easily. Table 4-6 illustrates some conversion factors for the units of the results.
The AC NGA ISO 6974 uses the AC Report Generator fully integrated with the
multitechnique ChemStation in a Microsoft Windows environment to control all
GC functions. This integrated software package automates all aspects of the
calibration, the gas analysis through customized data reporting. Refer to chapter 3,
“Understanding the AC Report Generator,” for more information about operation.
Oxygen is in the database but will not be reported. Oxygen is used as a correction
factor for sampling errors.
Figure 4-4. The AC ISO 6974 data base.
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Operation
Coversion factors
Coversion factors
Table 4-6. Conversion Factors Physical Constants
Unit SI Unit
Btu 1055.056 J
lbm 0.45359337 kg
ft 0.3048 m
gallon 0.003785412 m3
psia 0.06804596 atm
atm 101325 Pa
Converting Heating Values

To simplify the software and data base, the basis of all calculations is mole.
Therefore, physical constants need to be converted to the correct unit of measure.
The correct unit of measure is listed above the table of each data base column.
Conversion of the gross heating value from Btu/lbm to KJ/mole can be done with
the equation:
1055056
. kJ / btu
g / mol M r
1btu / lbm = value * * , KJ/mole
45359337
.
To convert the gross heating value from MJ/m3 to KJ/mole, use:
R *T
1 MJ / m3 = value * , KJ/mole
P
where
Mr : Molweight in g/mole
P : the pressure 101.325 Pa
R : 8.31448 J/mole.K
T : 288.15 K
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Operation
Operation
Operation
For detailed information on how to operate the HP ChemStation, refer to the Help
file of the HP ChemStation. For information about the AC Report Generator, use
the Help option.
For the ISO 6974 application, the following files are supplied:
• ISO6974.M—a GC method for the HP 6890 Series GC
• ISO6974.TFI—a special report template (optional)
• ISO6974.RDB—a data base containing the physical constants of the

compounds (optional)
NOTE The calculations of the ISO 6974 method are based on ISO 6974. The
ISO6974.RDB data base contains constants taken at a temperature of 15°C (288.15
K) and 1 at (101,325 Pa). Therefore, the calculations are based on this temperature
and pressure. If calculations are required for a different temperature, create a new
data base and report template.
Use the ISO6974.M GC method for analyses of your calibration standards and
samples. The AC Report Generator starts automatically after the analysis. The special
customized report is used for the final results.
Figure 4-5 shows the customized report for the ISO 6974 method. For information
about the GC method, refer to the Method description at the end of this chapter.
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Operation
Operation
Calibration
The components up to C3 are quantified on the TCD. The rest of the components
are quantified on the FID. The relative response factors are determined with
reference standards.
NOTE Because the AC Report Generator operates on mole percentages, the

concentrations must be specified in mole %.
The Report Generator software calculates the results. The system has to be calibrated
as follows :
• Enter the concentrations of the components in mol% in the

calibration table.
• Let chemstation calculate the response factors (recalibrate).
Reprocess a complete data file with the updated response factors and calibration
table and check the results with the concentrations on the label of the gas cylinder.
Version 2000/4.0 4-14 of 17

Operation
Operation
ISO 6974
Sample name GAS 403

Operator AC
Acquired on 9/4/2000
Data File Name C:\HPCHEM\1\DATA\D0904\SIG10002.D
Database name C:\HPCHEM\1\METHODS\ISO6974.RDB
Name Ret. time Area Mol% Vol%

Hydrogen 0.000 0 0.000 0.000
Helium 0.000 0 0.000 0.000
Carbondioxide 8.453 494 3.000 2.993
Oxygen 0.000 0 correction for air
Nitrogen* 4.317 1560 9.000 9.026
Methane 5.487 46174 81.825 81.923
Ethane 9.415 1557 3.000 2.984
Propane 12.508 484 1.010 0.995
n-Butane 16.242 426272 1.000 0.968
i-Butane 15.595 171744 0.402 0.390
n-Pentane 19.681 217420 0.413 0.388
i-Pentane 19.260 103028 0.196 0.186
Neopentane 18.115 52734 0.103 0.099
Cyclopentane 0.000 0 0.000 0.000
2,2-Dimethylbutane 0.000 0 0.000 0.000
2,3-Dimethylbutane / 0.000 0 0.000 0.000
isohexane
Hexane / 3-Methylpentane 22.686 32568 0.051 0.047
Benzene / cyclohexane 0.000 0 0.000 0.000
2-Methylhexane 0.000 0 0.000 0.000
3-Methylhexane 0.000 0 0.000 0.000
Heptane 0.000 0 0.000 0.000
Methylcyclohexane 0.000 0 0.000 0.000
Toluene 0.000 0 0.000 0.000
Octane 0.000 0 0.000 0.000
Calculation results:
Real relative density of gas 0.6812
Real wobbe index (superior) 44.51 MJ/m3
Real superior cal. value 36.73 MJ/m3
(vol)
Real inferior cal. value 33.19 MJ/m3
(vol)
Compressibility of mixture 0.9976
* After correction for air
Figure 4-5. The AC NGA ISO 6974 Report Generator Report.
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Operation
Method description
Method description
Table 4-7. ISO 6974 GC Method
Oven
Initial 75°C Final temp 1: 225°C
temperature:
Initial time: 7 min Final time 1: 30 min
Ramp 1: 5°C/min
Flow (Ar): 30 ml/min
FID TCD
Temperature: 250°C Temperature: 150°C
Flow (H2): 35 ml/min Ref flow (Ar): 20 ml/min
Flow (air): 350 ml/min Negative On
polarity:
Run Time Table
Valve Typical Time* Setting Description
Signal 1 0.01 Back detector Signal switch
Signal 1 0.01 ZERO ON
Valve 3 0.01 OFF Column 1 flow
Valve 4 0.01 OFF Column 2 flow
Valve 1 0.01 ON Flush sample
Valve 1 0.90 OFF Stop flushing sample
Valve 2 1.00 ON Inject sample
Valve 2 2.00 OFF Reset injection valve
Valve 3 1.80 ON Stopflow column 1
Valve 3 5.00 OFF Flow column 1
Valve 4 5.00 ON Stopflow column 2
Signal 1 15.00 Front detector Signal switch
Signal 1 15.00 ZERO ON
*Times will be fine-tuned and included with checkout documentation for each gas analyzer
Version 2000/4.0 4-16 of 17

Operation
Spare parts kit and consumables kit NGA ISO 6974
Spare parts kit and consumables kit NGA ISO 6974
Spare parts NGA ISO 6974 68485.055
Valve 6-port nitronic 60 10.25.029
Actuator LSV/6, 10-port GSV 28431.002
Solenoid 24V for inlet block 10.11.106
Temp. sensor assy. Pt-100 40.01.046
Consumables kit NGA ISO 6974 68486.055
HayeSep R column 10.70.103
Molsieve 13X column 10.70.102
PTA column 84.52.200
Version 2000/4.0 4-17 of 17

Index
Index
INDEX
(InvLn(x)), 3-20, 3-25 AC Report Generator Main Menu

(Ln(x)), 3-20, 3-25 Commands
Absolute Compound, 3-14, 3-15 File
Absolute Compounds, 3-36 Exit, 3-12
Absolute Response, 3-14, 3-15 New, 3-12
AC Natural Gas Analyzer 6974 Open, 3-12
column positions, 4-7 Select Instrument, 3-12
AC Natural Gas Analyzer ISO 6974 Help, 3-12
flow diagram, 4-6 View
AC Natural Gas Analyzer ISO 6974 Status bar, 3-12
separation range, 4-3 Toolbar, 3-12
AC Report Generator AC Report Generator main menus
introduction, 3-3 File
overview, 3-9 Exit, 3-10
AC Report Generator Data Base New, 3-10
Editor Open..., 3-10
operation, 3-13 Select Instrument, 3-10
AC Report Generator data base Help
editor menu commands About AC Report Generator,
File 3-10
Close, 3-16 Contents, 3-10
Exit, 3-16 How to use help, 3-10
New, 3-16 Search for help on..., 3-
Open..., 3-16 10
Print..., 3-16 View
Protect database/Enter Status Bar, 3-10
password, 3-16 Toolbar, 3-10
Save, 3-16 AC Report Generator Main Window
Save As..., 3-16 operation, 3-12
Help, 3-17 AC Report Generator report
Options template editor
Calibration Options, 3-17 what is a report template, 3-
Convert standards, 3-17 20
Edit variables, 3-17 AC Report Generator report
View template menu commands
Status bar, 3-17 Add compound, 3-24
Toolbar, 3-17 Add Report header items, 3-24
Window, 3-17 Add special field, 3-24
AC Report Generator data base File
menus Close, 3-23
File Exit, 3-23
Close, 3-10 New, 3-23
Exit, 3-10 Open, 3-23
New, 3-10 Print Preview, 3-23
Open..., 3-10 Print Setup..., 3-23
Print..., 3-10 Print..., 3-23
Protect database/Enter Protect template/Enter
password, 3-10 password, 3-23
Save, 3-10 Save, 3-23
Save As..., 3-10 Save As..., 3-23
Help Store calibration, 3-23
About AC Report Generator, Functions
3-10 Edit font, 3-24
Contents, 3-10 Edit report field, 3-24
How to use help, 3-10 Select Database name, 3-23
Search for help on..., 3- Select HP Report name, 3-
10 23
Options Help, 3-24
Calibration Options, 3-10 Options
Convert standards, 3-10 Options, 3-24
Edit Variables, 3-10 View
View Status bar, 3-24
Status Bar, 3-10 Toolbar, 3-24
Toolbar, 3-10 Window, 3-24
Window AC Report Generator report
Arrange Icons, 3-10 template menus
Cascade, 3-10 File
New Window, 3-10 Close, 3-11
Tile, 3-10 Exit, 3-11
AC Report Generator License No, New, 3-11
1-7 Open..., 3-11
Version 2000/4.0 Index-2

Index
Print Preview, 3-11 AC natural gas analyzer GPA
Print Setup..., 3-11 2261 three-valve, 4-15
Print..., 3-11 calibration concentrations, 3-33
Protect template/Enter calibration options, 3-18
password, 3-11 calibration report, 3-36
Save, 3-11 Calibration Settings dialog, 3-
Save As..., 3-11 31
Store calibration, 3-11 Calibration Settings dialog box,
Functions 3-31
Add compounds, 3-11 Default Calibration Curve, 3-
Add Report header items, 31
3-11 Type, 3-31
Add special field, 3-11 Uncalibrated Peaks, 3-31
Edit font, 3-11 With Rsp Factor, 3-31
Edit report field, 3-11 calibration standard, 3-36
Select Database name, 3-11 calibration table, 3-13
Select HP Report name, 3- Calibration Table dialog, 3-32
11 Calibration Table Options dialog
Help box, 3-32
About AC Report Generator, Amt mol %, 3-33
3-11 Compound, 3-33
Contents, 3-11 Grp, 3-33
How to use help, 3-11 Lvl, 3-33
Search for help on..., 3- RT, 3-32
11 Signal, 3-32
Options Calibrations Options dialog, 3-
Options, 3-11 36
View Calnr, 3-13, 3-14, 3-32, 3-33
Status bar, 3-11 caret, 3-20
Toolbar, 3-11 Check area, 3-25, 3-26
Window ChemStation, 3-29
Arrange Icons, 3-11 column
Cascade, 3-11 Hayesep R, 4-18
New Window, 3-11 installation, 2-4
Tile, 3-11 Molsieve 13X, 4-18
AC Report Generator Revision PTA, 4-18
Code, 1-7 Compound, 3-13, 3-14, 3-33
AC Report Generator software, 4- compound relative areas
11 Calnr, 3-13
actuator, 4-18 Compound, 3-13
adding compounds, 3-25 physical constants, 3-13
Agilent Computer Serial No, 1-7 Signal, 3-13
Agilent G2070AA License No, 1-7 compounds
Agilent G2070AA Revision Code, adding, 3-25
1-7 deleting, 3-15
Agilent Gas Chromatograph Serial editing, 3-25
No, 1-7 inserting, 3-15
Amt mol %, 3-33 compounds constants, 3-3
analysis Compressibility, 3-19
AC natural gas analyzer ISO Concentration range, 4-3
6974, 4-10, 4-16 concentrations, calibration, 3-
analysis descrption 33
AC Natural Gas Analyzer ISO configuration
6974, 4-10 AC Natural Gas Analyzer ISO
Analyzis Method for Second 6974, 4-6
Signal, 3-34 configuration, system, 1-6
area, 3-14 connections
Argon, 1-3 rear side, 2-3
Average, 3-38 CONSTANT.CSV file
barometric pressure, 3-36 editing, 3-46
Based On:, 3-30 Constants dialog box, 3-19
Btu, 4-2 Compressibility, 3-19
cabling, 2-2 Decimals area, 3-19
cabling configuration, 2-2 Density, 3-19
Cal Line, 3-37 Max area, 3-19
Calculate:, 3-30 MolWeight, 3-19
calculation Name area, 3-19
new, 3-42 Unit area, 3-19
calculation errors Variable area, 3-19
E304, 3-25 Conversion factors Physical
calculations Constants, 4-13
AC Natural Gas Analyzer ISO converting heating values, 4-13
6974, 4-11 creating a GC method, 3-29
calibrating, 3-37, 3-38 creating a new report template,
calibrating data bases, 3-37 3-20
calibration, 3-36 CV, 4-2
data base editor window, 3-13

Index
data bases Cal Line, 3-37
set up, 3-8 Specify Report
Decimals area, 3-19, 3-26 Based On:, 3-30
Default Calibration Curve, 3-31 Calculate:, 3-30
default variable names, 3-41 Quantitative Results, 3-30
Delete key Report Style:, 3-30
report object, 3-20 Sorted By:, 3-30
deleting an existing compound, Specify Report dialog box, 3-
3-15 30
Density, 3-19 Edit Compound Item
dialog box dialog box
Calibration Settings, 3-31 Name area, 3-25
Default Calibration Curve, Edit Compound Item dialog box,
3-31 3-25
Type, 3-31 Add Column Header area, 3-26
Uncalibrated Peaks, 3-31 Check area, 3-25, 3-26
With Rsp Factor, 3-31 Field area, 3-26
Calibration Table Options, 3- Formula area, 3-25
32 Width area, 3-26
Amt mol %, 3-33 Edit Compound Items dialog box
Compound, 3-33 Decimals area, 3-26
Grp, 3-33 edit the variables, 3-19
Lvl, 3-33 editing compounds, 3-25
RT, 3-32 editing the CONSTANT.CSV file,
Signal, 3-32 3-46
Constants, 3-19 editing the formula data base,
Compressibility, 3-19 3-44
Decimals area, 3-19 errors
Density, 3-19 calculation
Max area, 3-19 E304, 3-25
MolWeight, 3-19 Field area, 3-26
Name area, 3-19 flow diagram
Unit area, 3-19 AC Natural Gas Analyzer ISO
Variable area, 3-19 6974, 4-6
Edit Compound Item, 3-25 formula, 3-14, 3-45
Add column header area, 3- Formula area, 3-25, 3-27
26 formula data base
Check area, 3-25, 3-26 editing, 3-44
Field area, 3-26 protecting, 3-46
Formula area, 3-25 formula editor, 3-40, 3-44
Name area, 3-25 Formula text, 3-45
Edit Compound Items Formulas dialog, 3-44
Decimals area, 3-26 Formulas dialog box
Width area, 3-26 Formula, 3-45
Formulas Formula text, 3-45
Formula, 3-45 Number Format, 3-45
Formula text, 3-45 Order, 3-45
Number Format, 3-45 Unit, 3-45
Order, 3-45 Variable name, 3-44
Unit, 3-45 Variable Visible, 3-45
Variable name, 3-44 full menus, 3-5, 3-6, 3-8, 3-9
Variable Visible, 3-45 Method
Options, 3-28 Load Method, 3-6
Number of Pages area, 3-28 Print Method, 3-6
Spool results to CSV file, Save Method, 3-6
3-28 Save Method As, 3-6
Recalibrate, 3-38 operation, 3-8
Average, 3-38 RunControl
Replace, 3-38 Pause Sequence, 3-6
Report Items, 3-26 Resume Sequence, 3-6
Report option area, 3-26 Run Method, 3-6
Tabstops area, 3-26 Run Sequence, 3-6
Run Time Checklist, 3-34 Sample Info, 3-6
Analyzis Method for Second Stop Run/Inject/Sequence,
Signal, 3-34 3-6
Post-Run Command / Macro, Sequence
3-34 Load Sequence, 3-6
Pre-Run Command / Macro, Partial Sequence, 3-6
3-34 Print Sequence, 3-6
Select special calculation, Save Sequence, 3-6
3-27 Save Sequence As, 3-6
Formula area, 3-27 Sequence Parameters, 3-6
Name area, 3-27 Sequence Table, 3-6
Tabstops area, 3-27 Setup
Type area, 3-27 AC Report generator Setup,
Unit area, 3-27 3-6
Sequence table, 3-37 View

Index
1 Method and Run Control, Oven Exhaust Deflector, 1-4
3-6 overview
2 Data Analysis, 3-6 AC Report Generator, 3-10
3 Report Layout, 3-6 part numbers, 4-7
4 AC Report generator, 3-6 performance assurance
Change Access Level, 3-6 AC Natural Gas Analyzer ISO
Chemstation Scheduler, 3-6 6974, 4-4
Chemstation Status, 3-6 physical constants, 3-13
Reprocessing Copy, 3-6 physical properties, 3-3
Show Status Toolbar, 3-6 physical requirements, 1-4
Show Top Toolbar, 3-6 Post-Run Command / Macro, 3-34
gas purity, 1-3 pre installation checklist, 1-6
gas requirements, 1-3 predefined constants, 3-41
GC method preinstallation requirements, 1-
creating, 3-29 2
ISO 6974, 4-17 Pre-Run Command / Macro, 3-34
Setting Up, 3-29 pressure, 3-13
what is a ChemStation GC Pt-100, 4-18
method?, 3-29 Quantitative Results, 3-30
GC method calibration table, 3- rear side connections, 2-3
36 Recalibrate dialog box, 3-38
Grp, 3-14, 3-32, 3-33 Average, 3-38
Grp area, 3-13 Replace, 3-38
hardware Recording Important Numbers, 1-7
installation, 2-2 recursive calculations, 3-40
HP-IB, 2-2 Relative Response, 3-15
hydrocarbon Replace, 3-38
trap, 1-3 Report Items dialog, 3-26
inserting new compounds, 3-15 Report Items dialog box, 3-26
installation Report option area, 3-26
AC Report Generator software, Tabstops area, 3-26
2-5, 3-2 Report option area, 3-26
AC Report Generator Software, Report Style:, 3-30
2-5, 3-2 report template, 3-20
column, 2-4 report template file, 3-4, 3-34
hardware, 2-2 report template window, 3-20
introduction, 4-2 report template, new
AC Report Generator, 3-3 creating, 3-20
iterations, 3-40 report templates
LAN, 2-2 set up, 3-8
Lvl, 3-33 reports
Max area, 3-19 creating, 3-4
metering constants, 3-15 Requirements
pressure, 3-13 electrical, 1-5
temperature, 3-13 Retention Time Repeatability, 4-
Microsoft Excel, 3-28 5
Microsoft Windows License No, 1- RT, 3-32
7 Run Time Checklist dialog, 3-34
Microsoft Windows Type and Run Time Checklist dialog box,
Revision Code, 1-7 3-34
mol, 3-14 Analyzis Method for Second
MolWeight, 3-19 Signal, 3-34
multiple levels, 3-32 Post-Run Command / Macro, 3-
Name, 3-45 34
Name area, 3-19, 3-25, 3-27 Pre-Run Command / Macro, 3-34
new calculation, 3-42 Select special calculation
new report template dialog box, 3-27
creating, 3-20 Formula area, 3-27
Number Format, 3-45 Name area, 3-27
Number of Pages area, 3-28 Tabstops area, 3-27
one-point and linear calibration Type area, 3-27
curves, 3-31 Unit area, 3-27
operation separation range
AC Natural Gas Analyzer ISO AC Natural Gas Analyzer ISO
6974, 4-14 6974, 4-3
AC Report Generator Data Base sequence, 3-7
Editor, 3-13 sequence of analysis
AC Report Generator Main AC Natural Gas Analyzer GPA
Window, 3-12 2286, 4-9
full menus, 3-8 Sequence Table dialog box, 3-37
short menus, 3-7 Cal Line, 3-37
Options dialog, 3-28 set up
Options dialog box, 3-28 data bases, 3-8
Number of Pages area, 3-28 report templates, 3-8
Spool results to CSV file, 3- setting up a GC method, 3-29
28 short menus, 3-5, 3-7
Order, 3-45 Method

Index
Load Method, 3-5 solenoid, 4-18
Print Method, 3-5 Sorted By:, 3-30
operation, 3-7 Special Field dialog, 3-27
RunControl Specify Report dialog, 3-30
Pause Sequence, 3-5 Specify Report dialog box, 3-30
Resume Sequence, 3-5 Based On:, 3-30
Run Method, 3-5 Calculate:, 3-30
Run Sequence, 3-5 Quantitative Results, 3-30
Sample Info, 3-5 Report Style:, 3-30
Stop Run/Inject/Sequence, Sorted By:, 3-30
3-5 Spool results to CSV file, 3-28
Sequence standard operators, 3-20
Load Sequence, 3-5 system configuration, 1-6
Partial Sequence, 3-5 system guidelines, 1-6
Print Sequence, 3-5 Tabstops area, 3-26, 3-27
Save Sequence, 3-5 temperature, 3-13
Save Sequence As, 3-5 trap
Sequence Parameters, 3-5 hydrocarbon, 1-3
Sequence Table, 3-5 moisture, 1-3
View oxygen, 1-3
1 Method and Run Control, Type, 3-31
3-5 Type area, 3-27
2 Data Analysis, 3-5 Uncalibrated Peaks, 3-31
3 Report Layout, 3-5 Unit, 3-45
AC Report generator, 3-5 Unit area, 3-19, 3-27
Change Access Level, 3-5 valve
Chemstation Scheduler, 3-5 6 port, 4-18
Chemstation Status, 3-5 valves, 4-8
Reprocessing Copy, 3-5 Variable area, 3-19
Show Status Toolbar, 3-5 variable name, 3-40, 3-44
Show Top Toolbar, 3-5 Variable Visible, 3-45
sigma, 3-40 Width area, 3-26
Signal, 3-13, 3-14, 3-15, 3-32 window
single analysis or calibration data base editor, 3-13
Run, 3-7 report template, 3-20
software, 1-6 With Rsp Factor, 3-31
installation, 2-5, 3-2

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Operating Manual

AC Natural Gas Analyzer ISO 6974

AC Analytical Controls Inc

AC Analytical Controls Asia Pacific Ltd

Version 2000/4.0 Contents-2

Version 2000/4.0 Contents-3

Version 2000/4.0 1-2 of 8

Usage of gas Gas type Minimal Pre-pressure Traps/filters

Carrier Argon 99.995 7 / 100 moisture/charcoal1

Detector Gases Argon 99.995 5 / 75 moisture/charcoal1

Air zero grade 5 / 75

Support Gases Actuator air dry 5 / 75

Version 2000/4.0 1-3 of 8

• Depth - Approximately 0.6 meters (2 feet) for the complete system.

• Weight - 70 KG (155 lb.)

The analyzer may be installed in any reasonably accessible area.

Version 2000/4.0 1-4 of 8

Version 2000/4.0 1-5 of 8

Pre installation Checklist

• For three or four instruments, either an Agilent 5890 Series II or

Version 2000/4.0 1-6 of 8

Recording Important Numbers

AC Report Generator Revision Code

AC Report Generator License No.

Agilent G2070AA Revision Code Example A.06.0X

Agilent G2070AA License No.

Microsoft Windows Type and Revision Code

Microsoft Windows License No.

Agilent Gas Chromatograph Serial No.

Agilent Computer Serial No.

Version 2000/4.0 1-7 of 8

Version 2000/4.0 1-8 of 8

Installing the Hardware

1 HPIB / LAN interface PC - GC

Figure 2-1Cabling configuration for the Agilent 6890 Series GC.

2-2 of 6 Version 2000/4.0

Figure 2-2Rear side connections

Version 2000/4.0 2-3 of 6

WARNING TEMPERATURE-SENSITIVE ITEMS (GAS CYLINDERS, CHEMICALS,

2-4 of 6 Version 2000/4.0

Installing the AC Report Generator Software

NOTE A working knowledge of MS-DOS, Microsoft Windows, and Agilent G2070AA

Installing the AC Report Generator Software

Version 2000/4.0 2-5 of 6

Microsoft Windows 95 or Microsoft Windows NT Instructions

2-6 of 6 Version 2000/4.0

Installing the AC Report Generator Software

NOTE A working knowledge of MS-DOS, Microsoft Windows, and Agilent

Installing the AC Report Generator Software

Microsoft Windows 95 or Microsoft Windows NT Instructions

Version 2000/4.0 3-2 of 47

The AC Report Generator is a software package that automates calculations of the

Version 2000/4.0 3-3 of 47

Version 2000/4.0 3-4 of 47

The Agilent ChemStation and AC Report Generator

RunControl Method Sequence View Help

Version 2000/4.0 3-5 of 47

RunControl Method Sequence Setup View Help

Version 2000/4.0 3-6 of 47

Operating the Short Report Generator Menus