Donald v. Rosato - Plastics E.nd Use Applications
Donald v. Rosato - Plastics E.nd Use Applications
Donald v. Rosato - Plastics E.nd Use Applications
This SpringerBrief Plastics End Use Applications covers approximately 120+ plastics
applications and trends in the major end use areas of electrical and electronic, indus-
trial, transportation, consumer products, medical, emerging, and related subsectors.
Plastics play an indispensable role in a wide variety of markets, ranging from packaging
and building & construction to transportation, consumer and institutional products,
furniture and furnishings, electrical & electronic components, medical and others. This
enormous variety of end uses for plastics materials is what gives the industry its remark-
ably dynamic character. This also offers an exciting and significant challenge to com-
panies, to find the optimum mix of markets and customers to pursue that which fits with
the products it makes, the services it offers, and its financial goals.
Plastics End Use Applications provides a simplified, practical, and innovative
approach to understanding the design and manufacture of plastic products. This
unique review will expand the reader’s understanding of plastics technology by
defining and focusing on current and future technical trends. Plastics behavior is
presented to enhance the capability of fabricating products that meet performance
standards, low cost requirements, and profitability targets.
Application examples include toys, medical devices, cars, boats, underwater
devices, containers, springs, pipes, buildings, and aircraft. Also covered are
behaviors associated with different plastic materials (thermoplastics, elastomers,
reinforced plastics) and the many fabricating processes (extrusion, injection
molding, blow molding, forming, foaming, reaction injection molding, rotational
molding). This material is presented so that both technical and non-technical reader
can understand the interrelationships of materials to processes to applications. Also
examined are different plastic products and their related critical factors, from meet-
ing performance requirements in different environments, to reducing costs, and
targeting for zero defects. Examples used include small to large, and simple to
complex shapes. Major specific plastic end-use markets covered include packaging,
building and construction, automotive, electrical and electronic, appliance, medical,
consumer products, toy, recreation and leisure, furniture, office products, lawn and
garden, marine and boat, aerospace, industrial, agriculture, waste management,
government, export, and other and emerging.
v
vi Preface
Donald V. Rosato
Contents
vii
viii Contents
Keywords Plastic•Electronics•Prototypes•Packaging•Urethane•Composites
•Polyphthalamide•Ergonomic•Medical•Electroluminescence
1.1 Overview
1.1.1 Overview
This“PlasticsEndUseApplications”SpringerBriefcoversapproximately120+plas-
tics applications and trends in the major applications areas of (1) plastics industry
fundamentals,(2)electricalandelectronicapplications,(3)industrialapplications,
(4) transportation applications, (5) consumer products applications, (6) medical,
emerging,andotherapplications,and(7)plasticsapplicationscompanysourceguide.
Letustakeabrieftourofthenearly120+emerging,globalplasticsapplications
highlightscoveredintheSpringerBriefasfollows.
• PlasticLogicLtd.(UK),aleadingdeveloperofplasticelectronicsincluding
printedlexiblethinilmtransistor(TFT)arrays,isdevelopingandexploiting
aportfolioofintellectualpropertybasedoninkjetprintingofactiveelectronic
circuitsusingadvancedplasticmaterialstoformthinilmtransistorsthatcan
beusedinactivematrixbackplanesthatdrivedisplays.Otherpotentialappli-
cationsincludesmartlabels,smartpackaging,andradiofrequencyidentiica-
tion(RFID)devices.Plasticselectronicscanbeproduceddirectlyathighspeed
from CAD data to large, lexible surfaces using ink jet printing equipment
rather than complex photolithography and vacuum systems used to make
today’s transistors. With the process’ low temperatures, substrates used can
alsobeplastic.
• DysonLtd.(UK)realizedthatwithmostvacuumcleanersthebagquicklyclogs
withdustasthesuctionhadtopassthroughthebag,andacloggedbag,evenwith
aslittleas10oz.ofdirt,cancutthesuctioninhalfsothemoreabagisusedthe
lesseffectiveitbecomes.EntrepreneurJamesDysonsetouttosolvetheproblem.
Fiveyearsand5,000prototypeslater,theworld’sirstcyclonicbaglessvacuum
arrived.Whennoneofthemajormanufacturerswereinterested,Dysonlaunched
hisownvacuumcleanercompany.Now,DysonCyclonicVacuum,Europe’shottest
homeappliance,hascometoAmerica.
• OnTech(U.S.)hasoneofthemostinnovativepackagingsolutionsrecentlyintro-
duced as North America’s irst self-heating container, designed to heat liquid
contentssuchascoffee,tea,cocoa,soups,andalcoholicbeverages.Createdby
OnTech,Inc.,thenewself-heatingcontainerisasafeandeasy-to-activateconcept
thatheatsupthecontentsofitspackagetoapproximately145°Fwithinminutes.
Thecompanynowhas102approvedutilitypatentclaimsintheUSandpatents
in36othercountries,includingtheUK,China,andJapancoveringanymulti-
chamber plastic product that must be retorted, or sterilized during a heating
process.InEurope,somemetalcontainerscanself-heatandothershavetrieda
mixofmaterialstocreatethesameresultbutwithlimitedcommercialresults.
Metalhasatendencytocollapseorcrushduringthesterilizationprocess,when
thecontainerhastobeheatedto250°F.
• AccordingtoStyleSolutionsInc.(U.S.),customizedconstructionproductsand
largebuilderswilldrivethegrowthofurethanemillworkin2005.Theirmhas
createdmorethan300customizedproductsinthepastyearforbuildersacross
theUS.Thebuildingandconstructionindustryhasseenunprecedentedadvances
intheacceptanceanduseofurethanemillworkonbothexteriorsandinteriorsof
commercialandresidentialbuildings.Just5yearsago,woodmouldingproiles
waspredominatewithfewengineeredplasticonesseen.Todaythereverseistrue
withlow-maintenanceproducts,suchasurethane,composite,andplasticmould-
ingsprominentinallregionsofthecountry.Urethanemillwork,whichstandsup
to high temperatures in the summer and frigid snowy weather in the winter
months,isbeingincreasinglyusedwithotherproductssuchasdoors,windows,
andvinylsiding.
1.1 Overview 3
• JohnsonControls(U.S.)statesthatatopofthelinecarisnowequippedwithan
averageoftenantennae,andthatnumberisexpectedtosoonincreasetoasmany
as16ascarmanufacturersintroducesystemsformonitoringandautomatically
regulatingthedistancefromthevehicleinfront,andinstallwarningsensorsto
avoidcollisionswhenreversing.Thesenumerousantennaehavebeengenerally
spreadovertheentirebodyshell,presentingachallengetodesignerswhohaveto
guaranteeoptimumreception.Anewantennamoduledevelopedasajointproject
by Johnson Controls and Volvo demonstrates a way round the problem. The
moduleaccommodatesalltheantennaeandrelevantreceivers(radio,TV,GPS)
inoneunit.MadeofsteelandDurethanBM130H2.0polyamidesuppliedby
BayerMaterialScience,itismanufacturedusingtheplastic/metalhybridtech-
nologyalreadyestablishedforproductionofvehiclefront-ends.
• ScaledComposites(U.S.)andVirginAtlantic(UK)haveunveiledtheGlobalFlyer
V. The pioneering aircraft, said to be the world’s most eficient jet plane, has
been piloted in an attempt to achieve the irst solo, nonstop around the world
light.Theaircraftcompletedthe80-hvoyageononetankoffuel.VirginAtlantic
isthesponsorthe38.7-footlong,singleenginejet,witha114-footwingspan.
ScaledCompositesspentmorethan4yearsdesigningandbuildingtheaircraft.
Thecompanyusedcomputer-aidedaerodynamicstudiesandbuiltthestructure
entirelyfromultra-lightcarbon,Kevlar,glass,andacombinationofreinforced
epoxyandpolyestercompositematerials.
• SolvayAdvancedPolymers’(U.S.,Belgium)AmodelPolyphthalamide(PPA)has
brokenintothewineindustry.Typicallyfoundinautomotive,electrical,andindus-
trial product applications, Solvay Advanced Polymers LLC’s high-performance
polymerhasfoundanewuseasathreadedanchorforthepatentedtwist-to-uncork
winepackagingdesignedbyGardnerTechnologies,Inc.,aNapa,CA,basedmanu-
facturer.ThenewproductcarriestheMetaCorktradenameandwasondisplayat
therecentKFairinDüsseldorf.MetaCork™consistsofahardplasticcapsulewith
athreadedinteriorsurface,amatchingplasticthreadedcap,andanaturalorsyn-
theticcorkittedwithathreadedanchor,madefromAmodelPPA,thatisscrewed
intothecorkduringthebottlingprocess.
• Anattractivenewchair,partofcontractfurnishingsmanufacturerAllsteelInc.’s
(U.S.) ‘Get Set’ line of ofice chairs, tables, and accessories, is its Get Set
multi-purpose room seating/ofice side chair. The new chair, a comfortable,
lexible solution for learning environments, is designed for both horizontal
nestingandverticalstacking(uptofourhigh)forversatile,easytransportation
andstorage.Thoughportabilityisaplus,thebeneitofGetSetchairsisthehours
of comfortable seating they provide. Unlike non-padded folding or stacking
4 1 ExecutiveSummary
chairsoftenusedinalearningsetting,GetSetchairsfocusoncomfort,featuring
seatcushionsandaunique‘lexback,’whichhasastructurethatlexesnaturally,
tocounterbalancebodyweightandconformtosupportusersofdifferentshapes
andsizes.Anergonomicslopingarmoptionalsoallowsfornaturalmovementof
the body. Perforations in the chair back allow air circulation, an important
consideration,aswell.Durablemulti-surfacecastersmakemovementeasy.
• PuratechGmbH’s(Switzerland)operatingmicroscopesplayacrucialroleinthe
operatingroom.Theymustdelivertopperformanceinahighlydemandingenviron-
mentandtheymustbelightweight,alwaysaccessiblebutneverinthewayduring
demandinganddetailedwork.Consequently,theseinstrumentsareequippedwith
highlysophisticatedbalancingsystemsthatensurehigh-precisionmovementofthe
complexopticalsystemwithoutmanualinvolvementonthepartofthesurgeon.The
armwhichthemicroscopemovesonmustthereforebeaslightaspossible.High-
performanceplasticslikethelightweight,robust,Baydur110polyurethanesystem
fromBayerMaterialScienceAGareidealforuseinthisapplication.
• BreeCollectionGmbH(Germany),aninternationalleatherandbagspecialist,
has created an illuminated business handbag using Smart Surface Technology
(SST). Bree had been toying with the idea of illuminating the dark insides of
handbagsforsometime,butlackedanelegantsolution.Theanswerisnowavail-
ableasSmartSurfaceTechnologydevelopedbyBayerPolymers,inpartnership
withLumitec,aspecialistinelectroluminescence(EL)andprecisionelectronic
components. EL is method of generating light reminiscent of the chemical
methodemployedbyirelies.Engineersareusingailmthatlightsuponappli-
cationofavoltagetoachieveelectroluminescence.AnadvantageofEListhatit
doesnotproduceheat.Howeveruntilnow,onlylatsurfacesoflimitedsizecould
be achieved. Smart Surface Technology makes it possible for the ilms to be
shapedtoilluminateanyconceivablegeometry.Incorporatedinanonconductive
layer,theilminBree’shandbaglightsupatthepressofabutton.BayerPolymers
seesthemainapplicationforthistechnologyintheautoindustry.Incandescent
lampsincarswillbecomeobsolete.Instrumentpanelswillbedesignedtotake
uplessroomandacar’sinteriorheadlinerwillglowinasoftglare-freelight.
1.2.1 Scope
ThePlasticsEndUseApplicationsscopeencompassesemergingtechnologyand
trendsinthefollowingmajorandsubtopicplasticsapplicationsfocusedareas:
1.2 ScopeandMethodology 5
(continued)
– Do-it-yourselffaucets – Non-slipgardentools
– TimeexpiredDVDs – Functionalstylizedglazing
Toy applications Medical applications
– Toyapplicationsmarket – Medical applications introduction
– Rotomoldedtoys – HightechIVcatheters
– Large-scalebuildingtoy – Life-savingitemssafelypackaged
– Highlyprecisegamejoysticks – Highlymaneuverablesurgicalmicroscope
– Hightechlearningtoys – Surgicalmicrotools
– Importproofseasonaltoys – Micro-sizedassaydisks
Recreation/leisure applications – HomehealthcareCPAPsystems
– Recreation/leisure applications introduction Emerging applications
– Ultralightfoldablekayak – Emergingapplicationsintroduction
– Clear corrosion-resistant pool cleaners – Plasticbonewoundrepair
– Crosscountryskiing/skating – Satellite TV car antennas
– Snowskates – Luminescenthandbags
– Laserline golf tees – ‘Virtuallayering’clothingfabrics
– Light,eficientgolfclubmerchandisingcarts Other applications
Furniture applications – Governmentapplicationsintroduction
– Furnitureapplicationsintroduction – Driversafelampposts
– Polyurethanefoamquiltingreplacement – Agelessundergroundpipe
– Lightweightcompositetables – Superstrongwaterpipe
– Naturallylexingoficechairs – CompositeUCAVs
– Performanceenhancedwindowshades – Wastemanagementapplications
– Renewableresourcesleepproducts introduction
– Environmentallyfriendlychairs – RecycledPETmineshaftreinforcement
Lawn and garden applications – Wastecarpetiberproducts
– Lawnandgardenintroduction – Nyloncarpartsrecycling
– Novelplasticfencing – Eco-eficientmechanicalrecycling
– Miracle-gromultipurposepails – Environmentallymarketedirrigationpipe
1.2.2 Methodology
ThemethodologytocreatePlasticsEndUseApplicationsincludedgloballydevel-
oping and reviewing data, information, and analysis in emerging technology and
trendsfrommultiplesourcessuchas:
1. Directcompanyinputfrom120+technologysourcesasoutlinedbelowinthe
webwatchdirectoryandChaptereight’sapplicationscompanysourceguide
2. 10+majortradeshows(i.e.,NPE,Fakuma,KFair,etc.)
3. 5+majorannualtradeassociationmeetings(i.e.,ANTEC,APME,PPI,etc.)
4. 15+ major trade journals (i.e., Plastics Technology, Kunststoffe Plast Europe,
ModernPlasticsInternational,etc.),and
5. 15+ major database (i.e., Derwent World Patents, etc.), reference work (i.e.
Plastics Institute of America Plastics, Engineering, Manufacturing and Data
Handbook,etc.)andstudysources(i.e.,Freedonia,etc.).
1.2 ScopeandMethodology 7
Aglobalwebwatchdirectoryof120+companynamesandwebaddressesarranged
chronologicallyfromChaps.3–7aresummarizedforyourreferenceconvenience
immediatelybelow.Additionalcontactinformationfor625globalplasticsapplica-
tionsorientedcompaniesiscontainedinChap.8.
(continued)
IrritrolSystemsEuropeS.r.l. www.irritrol.it
AgContainerRecyclingCouncil www.acrecycle.org
5. Transportation end use applications
SolvayAdvancedPolymersLLC www.solvayadvancedpolymers.com
DowAutomotive www.dow.com/automotive
Schefenacker/FreeglassAG www.schefenacker.com
DuPont Canada Inc. www.ca.dupont.com
MeridianAuto.Systems,Inc. www.meridianautosystems.com
BayerMaterialsScienceAG www.bayermaterialscience.com
BrussNorthAmerica www.brussna.com; www.bruss.de
StamaxBV,SABICEurope //polymers.sabic-europe.com
GeneralMotorsCorp. www.gm.com
FordMotorCo. www.ford.com
NorthropGrumman www.northropgrumman.com
MCGillCorp. www.mcgillcorp.com
ScaledComposites,LLC www.scaled.com
DuPont Co. www.dupont.com/et
BoeingPhantomWorks www.boeing.com/phantom
BallisticRecoverySystemsInc. //brsparachutes.com
Boeing Co. www.boeing.com
MercuryMarine www.mercurymarine.com
GenmarHoldingsInc. www.genmar.com
Victrexplc www.victrex.com
BrighamYoungUniversity www.byu.edu
MFGConstructionProductsCo. www.mfgcp.com
ArmorDock www.armordock.com
6. Consumer products end use applications
Ergodyne www.ergodyne.com
Rogers Corp. www.rogerscorporation.com
SonyDiscTechnologyInc. www.sdt.sony.co.jp
SagomaPlastics www.sagomaplastics.com
RubbermaidEurope www.rubbermaid-europe.com
BASFEngineeringPlastics www.basf-ag.de
TheGilletteCompany www.gillette.com
GrahamPackagingCo. www.grahampackaging.com
Moen Inc. www.moen.com
FlexplayTechnologies,Inc. www.lexplay.com
Step2 Co. www.step2.com
SagomaPlastics www.sagomaplastics.com
LogitechInc. www.logitech.com
LeapFrogEnterprises,Inc. www.leapfrog.com
GrandVentureLtd. www.grandventure.com
FirstlightKayaks www.irstlightkayaks.com
GEAdvancedMaterials www.geadvancedmaterials.com
GateSkate,Inc. www.gateskate.com
Salomon www.salomonsports.com
SpiritofGolfGmbH E-mail:[email protected]
(continued)
1.2 ScopeandMethodology 9
(continued)
MeeseOrbitronDunneCo. www.modroto.com
BayerMaterialsScienceAG www.bayermaterialscience.com
AllsteelInc. www.allsteelofice.com
HunterDouglas,Inc. www.hunterdouglas.com
PaciicCoastFeatherCo. www.paciiccoast.com
HermanMillerInc. www.hermanmiller.com
KroyBuildingProducts,Inc. www.kroybp.com
UnimarkPlastics www.unimarkplastics.com
FiskarsCorp. www.iskars.i
WendlandConservatoriesLtd. www.wendland.uk.com
7. Medical, emerging and other end use applications
NDHMedical,Inc. www.ndhmedical.com
StoropackHansReicheneckerGmbH www.storopack.com
PuratechGmbH www.puratech.ch
ERBEElektromedizinGmbH www.erbe-med.de
TecanGroup www.tecan.com
RTP Co. www.rtpcompany.com
AdvancedCeramicsResearch,Inc. www.acrtucson.com
SarnatechBNLLtd. www.sarnatech-bnl.com
BREECollectionGmbH&Co.KG www.bree.de
MaldenMillsIndustry,Inc. www.polartec.com
EuroProjects(LTTC)Ltd. www.europrojects.co.uk
DowChemicalCo. www.dowcontinuum.com
SekisuiChemicalCo. www.sekisui.co.jp
NorthropGrummanIntegratedSystems www.northropgrumman.com
JennmarCorp. www.jennmar.com
CarpetAmericaRecoveryEffort(CARE) www.carpetrecovery.org
DuPontEngineeringPolymers,ATC www.plastics.dupont.com
PlasticsEurope www.apme.org
Delta Plastics www.deltapl.com
Chapter 2
Plastics End Use Application Fundamentals
2.1 Introduction
Plasticsplayanindispensableroleinawidevarietyofmarkets,rangingfrompackaging
andbuilding&constructiontotransportation,consumerandinstitutionalproducts,
furnitureandfurnishings,electricalandelectroniccomponents,medicalandothers.
Thisenormousvarietyofendusesforplasticsmaterialsiswhatgivestheindustry
its remarkably dynamic character. This also offers an exciting and signiicant
challenge to companies, to ind the optimum mix of markets and customers to
pursue thatwhichitswiththeproductsitmakes, theservices itoffers,and its
inancialgoals.
Somecompaniesconcentratetheireffortsprincipallyonthelargerendusemarkets,
butmanyothersinditsafertospreadtheirbusinessoveranumberofapplication
areas.Thetypeofproductsacompanymakesdeinesitsmarketingefforts.Packaging
isthelargestenduse,followedbybuilding/construction,automotive,andelectrical/
electronic.Extrusionistheprimaryprocessusedinplasticssincemostpackaging
andbuilding/constructionproductssoldinareextruded.Injectionmolding,thenext
mostimportantprocess,isusedformostcomplexparts.Blowmoldingisalsoexten-
sivelyusedinthemanufactureofpackagingproducts.‘Other’processesusedare
mainlythermosetprocesses,suchascompressionandtransfermolding,andreac-
tioninjectionmolding.
While somewhat arbitrary and not always consistent within the industry, an
application is typically categorized by its main attributes; therefore, an electrical
connectorinacarwiringharnessisusuallyconsideredtobeanautomotiveapplication,
whileelectricalconnectorsemployedinavarietyofendusesareconsideredtobe
electrical/electronic applications. The following segments are primary market
groupingsusedbymostindustryanalysts.
Packagingconstitutesthesinglelargestenduseforplasticmaterials,accountingfor
approximately30%ofallplasticsused.Plasticsareenjoyingsubstantialgrowthas
apackagingmedium,attheexpenseoftraditionalmaterialssuchasglass,metals,
and paper, in spite of environmental pressures on plastics materials in general,
becauseplasticpackagesarelighterweight,morelexible,andeasiertoprocess.
Plasticpackagingalsodisplaysproductmoreattractivelythandomostcompeting
materials,offersbetterprotectionagainstspoilage/breakage,andprovidessavings
infreightcosts(primarilyfueleconomy).Plasticresinsmostoftenusedinpackaging
arepolypropylene,polyethylene,polystyrene,polyvinylchloride,andpolyethylene
terephthalate, though nylon 6 is also used, largely as ilm in food packaging for
meat.Post-consumerrecyclingisalsoanimportantconsiderationforPE-andPET-
basedpackaging;somemajorendusersandsomegovernmententitiesevenspecify
recycledcontent.Becauseeconomicsarefrequentlyaprincipalfactorinchoosing
onematerialoveranother,commodity-typematerialstendtobefavoredfortheir
lowercost.Thegrowthofplasticspackagingisdueinnosmallparttothetechnologies
availabletoconvertmaterialsintopacksofdifferentforms,lexible,semi-lexible
andrigid,athighspeed,whichhashadacrucialroleinminimizingthecostof
plasticspackaging.
Plasticpackagingcanbegroupedintofourareasas:
• Primarypackagingfortheinalproduct,intheformofbags,pouches,bottles,or
othercontainers.
• Secondarypackagingfortheprimarypackagedproduct,intheformofshrinkor
stretchilms,bottlecrates,andtransitcontainers.
• Retailpackaginginsupermarketsandotheroutlets,intheformofbagsonthe
reel,wicketedbags,checkoutbags,andshoppers.
• Consumerpackaging,intheformoffreezerbagsandclingilms.
Film and containers for consumer goods and food constitute the bulk of the
packaging market and are truly commodities, using commodity polymers.
Polymethylpentene-Ihasfoundsomespecialtyfood-packagingapplicationswhere
itsunusualcombinationoftransparency,gaspermeability,andheatandchemical
resistancepropertiescansometimesoffergreatervaluethanthecommoditypolymers.
One of the attractive aspects of the packaging market is its relative resistance to
economiccyclicality,atleastinfoodpackaging.Theongoingtransitioninbeverage
and food packaging from other materials to plastics has beneited processors,
particularly blow molders, serving the aseptic and hot-illed packaging markets
2.1 Introduction 13
whereglobaldemandhasmorethandoubledinthelast3years.IntheU.S.,thearea
ofhighestgrowthinconsumerpackaging(20–30%AAGR)ispolypropyleneretort
pouches,whichareneededtokeepfoodfreshforthemilitary.Retortpackagingis
beingusedinbrand-newapplications,suchasrice,tunaish,yogurt,puddings,and
evenpetfoods.Themarketisquicklymovingfromstandardpolyethylenepouches
toPPretortpouches.
Anumberofspecialtyuses,suchasindustrialmachineryandcustompackaging,
aremuchsmallerinvolumebutofferbetterearningspotentialtoboththesupplier
andtheuser.Theseusescanrangefrommade-to-orderpolystyrenefoamprotective
moldings to injection molded acrylic cases for small tools. Three key packaging
markets – healthcare, high-visibility, and protective – are expected to see strong
growthof4.7to5.2%from2010through2015,withgovernmentregulationsand
consumerbuyingtrendsdrivingtheincreases.
Withemphasisonhealthcarecostcontrol,plasticsindincreaseduseinapplications
inhealthcarepackaging.Factorsinluencingtheincreasedpenetrationofplasticsin
healthcarepackagingareincreaseduseofdisposableproducts,anagingpopulation,
continuingcostpressuresonsuppliers,increasinginluenceofhospitalandhealthcare-
relatedpurchasinggroups,continuedshifttooutsidecontractpackaging,andmoreand
moreemphasisonchild-resistant/senior-friendlyandtamper-evidentpackaging.The
majorplastichealthcarepackagingproductsaresegmentedintotwogroups:medical
andpharmaceutical.Theformerincludeintravenous(IV)bags,otherbagsandparts,
kits,tubingandcontainers,syringes,trays,andamiscellaneousgroup.Pharmaceutical
packaging products are made up of closures, bottles/vials, blister packaging, and a
miscellaneouscategory.Bottles/vials,tubing/containers,syringes,kits,areestimatedto
be the leading healthcare packaging applications, accounting for over 83% of total
plasticvolumein2010.
Inpharmaceuticals,blisterpackswillgrowfastestfollowedbyplasticbottles.
Unit-doseregulationsforinstitutionaldrugs,alongwithclinicaltrialsandover-the-
countermedication,arefactorsinluencingblisterpacks’strong6.3%/yeargrowth.
Inmedicalpackaging,severalmajorproducersofhigh-tech,highlylayeredlexible
ilmsforbarrierfoodwraphaverecentlyqualiiedtheirirstcoextrudedilmsfor
medicalpackaging.Food-ilmcompanieshadtriedforyearstoapplytheirlow-cost
production,economiesofscale,andexperiencewithhighlylayeredstructurestothe
medicalmarket.Nowtheyarebecomingfactorstoreckonwithinthishigh-priced
specialty business. Requirements for medical packaging are very different from
thoseforfoodwraps.Flexiblefoodpackageshavetoprovidetightoxygenbarrierto
preserveprocessedmeatsandcheese.Extrudedilmsformedicalpackageshaveto
provideamicrobialbarrier,resistpuncture,andsurvivesterilization.Whatthefood
ilmcompanieshavetoofferisexpertiseinhighlylayeredstructures.Coextrusion
cutscostinseveralways.Itcanreplaceexpensivematerialsanduseresinsmore
eficiently.Itcanalsoinsomecasesreducethenumberofproductionstepsbyelimi-
natingcoatingorlaminating.
Inhigh-visibilitypackagingsuchasclamshellsandblisters,consumerspending
onlargerandcostlieritems,coupledwithretailers’needstodetertheftwhileletting
buyersinspectpackagecontentswilldrivegrowthof5.1%/year.Demandforclamshells
14 2 PlasticsEndUseApplicationFundamentals
willremainstrong,despitetheirhighcost,forthebeneitstheyprovideinpackaging
large,heavyproductsaswellasmultiplecomponents.Theycanalsobedisplayed
onpegsaswellasshelves.
Burgeoninginternetandmail-ordersalesalongwithspecializedpackagingneedsin
electronics,medical,andothermarketswillincreasedemandforprotectivepackaging
by5.2%/year.Buttherewillbegainsforfoamedrolls,andinlatablebagswillpostthe
fastestgrowth.Foamswillgrow5.3%/year,whileprotectivemailerswillgain5.0%/
year,insulatedshippingcontainers6.2%/year,andinlatablebags8.1%/year.
Thedigitalvideodisc(DVD)markethasalsoinspiredpackagers’attention.The
DVDhasbeenabreakawaywinnerinthemultibillion-dollarhomeentertainment
industry.Morethan60%ofU.S.householdsnowownaDVDplayer,andby2011
sowillmorethan67%ofEuropeanhomes.MoneyspentbuyingandrentingDVDs
overtookspendingonVHScassettesin2010,andby2015willaccountfor93%of
spending on video software. DVDs are purchased at much higher rates, making
packaging more important to consumers. DVD packaging is almost exclusively
produced in polypropylene.
Buildingandconstructionisthesecondlargestendusemarketforplasticswith28%
ofplasticsmaterialsconsumedinthismarketsector.Asinpackaging,plasticshave
displacedsuchtraditionalmaterialsaswood,glass,andmetal,basedonimproved
performanceandlowercost.Forpipes,valves,andittings,plasticsoffersuperior
corrosionresistanceandarelighter,easiertoinstall,andmorecost-effectivethan
theiralternatives.Impervioustochemicalsandsulfur-bearingcompounds,plastic
pipingsafelytransportseverythingfromfreshwatertosaltwater,andfromcrude
oil to laboratory waste. These qualities also have combined with plastics’ high
strength-to-weight ratio to produce materials for bridge and other infrastructure
construction, including tough reinforcement rods, nonskid surfacing and quickly
installed replacement decking. In this distinctly cyclical industry, most of the
volumeusageisprocessedbyextrusion,suchasforpiping,conduit,wireinsulation,
siding,reservoirliners,erosioncontrolnetting,orarchitecturalsheeting.Sometimes
this category includes such agricultural end uses as irrigation pipe and ittings,
mulchilms,andfencing.Formarketparticipants,thereareanumberofregulatory
hurdlestoovercomesuchastheUnderwritersLaboratories(UL)listingsandthe
NationalSanitationFoundation(NSF)listingsforbothpotableandwastewater.For
proprietary processors, parts must comply with applicable building codes at the
local,regional,andnationallevels.
In the construction of buildings, plastics abound in plumbing ixtures, siding,
looring, insulation, panels, doors, windows, glazing, bathroom units, gratings,
2.2 OtherMajorMarkets 15
r ailings,andagrowinglistofbothstructuralandinteriorordecorativeuses.For
commercialbuildingsthatcontainsensitiveelectronicequipment,plasticscanprovide
ahighlyprotectivehousingthatdoesnotinterferewithradiofrequencyormagnetic
waves.Inresidentialbuildings,single-familiesincreasinglyopttorefurbishexisting
olderhomestosuittheirgrowingneeds.Remodelingcontractorsanddo-it-yourselfers
increasinglyturntolight,strong,easilyhandledplasticstomakeimprovementsand
repairs,fromceilingtilestoadvancedwiringandmodernbathroomixtures.Inbuild-
ingadditionsaswellasnewconstruction,bathroomixturessuchastubs,showers,
andsinkscanbeconstructedinonepiece,walls,pipes,andall,thenpositionedand
attached to the building frame, producing signiicant savings in construction and
installation costs. In older home restoration, plastics can provide the best of both
worldsduplicatingyesterday’sbeautyusingtoday’ssuperiormaterials.Architectural
touches such as decorative wall, door and window moldings can be achieved that
mimicmarbleorhandcarvingsbutoffertheeaseofcareanddamageresistance.
Durable,lightweightandcorrosionresistant,plasticsofferfuelsavings,designlex-
ibility and high performance at lower costs to designers facing today’s complex
transportationneedswhetheronlandorsea,intheairorinspace.
Auto makers choose plastic parts for their durability, corrosion resistance,
toughness, ease of coloring and inishing, resiliency and light weight. Plastics
havesigniicantlyreducedtheweightoftheaveragepassengercarsavingmillions
ofgallonsofgaseachyear.Plasticshavefoundtheirwayintoautomobilecompo-
nentssuchasbumpers,fenders,doors,safetyandrear-quarterwindows,headlight
and sideview mirror housings, trunk lids, hoods, grilles and wheel covers.
Automobiledesignersalsodiscoveredthatplasticssolveoneoftheirmostcompli-
cateddesignproblems,namely,whattodowiththefueltank.Usingplasticgives
themthefreedomtoittanksintotheoverallconceptratherthandesigningaround
theunwieldybutessentialpart.Advancesinenginetechnology,fuelmanagement,
and emissions requirements continue to drive up under-the-hood temperatures.
Wherecertainhigh-temperatureplasticswereadequateafewyearsago,todaythat
isnolongerthecase.Theseautomotiveadvancesaredrivingtheuseofhigherend
plasticsunderthehood,aswellasthedevelopmentofnewplasticsandcoatingto
betterperforminnewunder-the-hoodenvironments.Inautomotiveinteriors,plastics
usedinlooring,seats,dashboards,andpanelingmaintaintheirattractiveappear-
ance and are easy to clean.
Plasticsversatilityisaidingtheautomotiveindustrytomeetevermorechallenging
requirements in terms of economical performance, safety, comfort, and environ-
mental considerations. The automotive industry is the single largest end user for
many engineering plastics, such as nylon, polycarbonate, acetal, or modiied
polyphenyleneether.Itisalsoanimportantmarketforcommoditypolymerssuch
PP,PE,andPVC.Automotivebusinessisnotoriouslycyclical,andsupplierscan
16 2 PlasticsEndUseApplicationFundamentals
easily ind their orders canceled literally overnight if demand takes a downturn.
Automotivebusinesscyclesnotonlyincludetheupsanddownsoftheoveralleconomy
butalsothoseofindividualbrandsandmodels.Operatingsuccessfullyinacyclical
industryrequirescompaniestohaveconsiderablelexibilitywithrespecttomanu-
facturingcapacity,andinancialreserves.Nevertheless,companieshaveprospered
by learning how to cope with these problems successfully. Recent industry esti-
matesexpecttheuseofengineeringthermoplasticsinexteriorautomotiveapplica-
tionstogrowby4.8%annuallythrough2010.
Theelectricalandelectronic(E/E)endusemarketisthethirdlargestmarketfor
plasticsapplicationsrangingfromminiatureconnectorstolargehousings.Anever-
growinguniverseofelectronicequipment,components,andgadgetsisexpanding
the world and improving lives. In this age of electronics, computers power the
businessworldandteachskillstotoddlers.Communicationssystemsreachthefar
cornersoftheearthandbeyond,tasksthatoncetookmanyhoursnowcanbeaccom-
plishedinminutesandleisurehourshavebecomemorevaried.InE/Eusesinthe
home,plasticswithpremiumthermalandinsulatingpropertiesareusedtoinsulate
nearlyallhousewiringandarealsousedinelectricswitches,connectors,andrecep-
tacles.Lightweight,durable,attractive,andcost-effectiveplasticsareusedinnearly
allsmallappliancesfromcoffeemakerstohairdryersandshavers.Thematerials
arealsoindispensableinmajorappliances,whichwouldcostatleast25%moreand
use30%moreenergythansimilarproductsproducedwithoutplastics.Allrefrigerators
today, for example are insulated with thermally eficient plastic foam, and their
interiorsaremadeofdurable,easy-to-cleanplastics.
Animportantaspectoftheelectrical/electronicmarketinmanyapplicationsis
thefasttime-to-marketdemandsoftheindustryof6monthsorlessandtherela-
tivelyshortproductlifecyclesfromonetooneandahalfyears.Thisrequiresthat
suppliersworkwithendusersonnewapplicationsfromthebeginning,butthisalso
preventsothersuppliersfromdisplacingorevensharingbusinesswithanexisting
supplierexceptinthecaseofmajorqualityordeliveryfailures.Cellphonesarea
typicalexampleofsuchapplications.Withoutplastics,mostoftheelectronicprod-
uctsusedtodaywouldnotbepracticaloreconomical.Designersofcomputersand
businessequipmentchooseplasticsfortheirtoughness,durability,easeoffabrica-
tionintocomplexshapes,andtheirelectricalinsulationqualities.Plasticshavebeen
fundamental to electronic progress for decades, housing electronics, insulating
componentsfromalltypesofinterference,andprotectingparts.Infact,micropro-
cessorminiaturizationwouldnothavebeenimpossiblewithoutthequalityandcost-
effectiveness of plastics. The continuing miniaturization of circuit boards and
componentssuchascomputerchipsincreasinglyreliesonhigh-performanceplastics
toprovidetough,dimensionallystablepartsthatcanwithstandboththestressof
assemblyandthestrainofuse.Withplastics,electronicdesignerssimultaneously
candecreasesizeandincreasethefunctionalityofcircuitryinconsumer,business,and
2.3 KeyCrossoverMarkets 17
industrialelectronics.Inthemodernfactory,automatedproductionreliesonplastics
forcontrolpanels,housings,printedwiringboards,sensors,androboticcomponents.
Corrosion-resistant,lexibleplasticalsoservesasconduitforelectricalwiring.
The E/E market requires that both materials and parts for each new product be
evaluatedagainstUnderwritersLaboratories(UL)requirements.Materialsmustbe
offeredinlame-resistantformulationsiftheyarenotalreadyinherentlylameresis-
tant.RegulatoryrequirementsinEuropealsomandatethatlameresistancebeachieved
withouttheuseofhalogenatedcomponents.WhileaULlistingforlameresistance
foraqualiiedproductisrelativelyquickandinexpensivetoget,anotherimportant
ULrequirement,thelimitingtemperatureindex(LTI),whichspeciiesthemaximum
continuoususe(operating)temperatureforamaterialtypicallytakesfromonetoone
andahalfyearstoobtain.Theexpenseofobtainingandmaintainingtheselistings
demandsthatthemarketpotentialforeachproductbesuficienttojustifythem.
Consumerproductscovermanyapplications,fromcosmeticsandtoothbrushesto
housewares, toys, recreational goods, furniture, lawn/garden equipment, and
others.Consideringthediversiicationofthiscategory,itisextremelydificultto
assignoverallgrowthiguresthoughthereareanumberofveryproitableniche
opportunities. Trends in disposable personal income play a major role in the
purchase of these products with any growth in real wages boosting consumer
spendinginthissector.Thedownsideofbusinessinconsumergoodsisthatthe
productlifecyclesareoftenshort,andmostapplicationsarepricesensitive.Also,
manyoftheenduseshaveseasonalpatterns.Consumernon-durablesaredeined
asitemsexpectedtolastlessthan3yearsandconsistmostlyofsingleuse,dispos-
ableitems,suchassingleusecups,picnictableware,anddisposablediapercom-
ponents,andspecialtypackaging(e.g.,cosmeticscases).Costisking,asonewould
expectinsuchcommodityapplications.
Althoughsyntheticibersarenotwidelythoughtofaspartoftheplasticsindustry,
theyareandstronglyaffectthesupplyandpricesoftheirbaseresins.Thegreatmajority
ofibersareusedforconsumergoods,suchascarpetingandclothing.Whenhousing
startsorconsumerpurchasingpassesthroughadipintheireconomiccycles,inte-
gratedpolymer/iberproducershavemorecapacitytodiverttoplasticresinsales.
Industrialcomponentsmainlydealwithmachineryparts,suchaspumphousingsand
impellers,conveyorlinks,orgearsandbearings.Thismarketishighlyfragmented
18 2 PlasticsEndUseApplicationFundamentals
withlowcompetitivevisibilityandhighvalueinuse,andthereforehighproitability.
Productlifecyclesaretypicallylong.Endusersareoftenlocal,andvolumesoften
tendtobesmall.Thematerialsusedaremainlyengineeringandhigh-performance
polymers though the full range of plastics from commodities to specialties are
employedinthissector.
Rod,tubing,andsheetaretypicalsemi-inishedshapeswhicharemechanically
fabricatedintootherpartsforarangeofunidentiiedenduses.Semi-inishedshapes
areoftenusedtomakeprototypepartsforevaluationorevensmallnumbersofcom-
mercialparts.Thoughthismarketsegmentisimportantintermsofsize,itsgrowth
rateislessthanmanyothersanditisverycompetitivewithconsiderableconsolida-
tiontakingplaceinrecentyears.Shapeproducersrarelyhavedirectcontactwith
endusers,theirroutetomarketbeingalmostentirelythroughstockshapedistribu-
tors,agroupseparatefromplasticmaterialdistributors.
Several other major market segments include (1) medical and (2) aerospace and
military.
Themedicalmarketisafastgrowth,recessionproofplasticsmarketapplication
area.Medicalproductstypicallyaredividedintotwocategories,disposablesand
durableequipment.Thoughmedicaldisposablesarecommodity-typeproductswith
emphasisoncost,reliabilitydemandsarehighmakingproitmarginsmuchbetter
thanmostcommoditymarkets.Manymedicaldisposablessuchascatheters,blood
bags,IVbags,etc.,arerelativelyhightech.Thehightechnatureofdurablemedical
equipmentalsoprovidestheopportunityforhighermarginbusiness,butasreliabil-
itydemandsarealsohigh,exposuretoproductliabilityclaimscanbesigniicant.
Aerospaceandmilitaryenduseareasareamongthemostchallengingplastics
markets.Marketendusersarehighlyfragmented,volumesarerelativelysmallto
medium,andapplicationdevelopmentshaveverylongtimelines,thoughproduct
lifecyclestendtoalsobelong.Onceamaterialisapproved,asuppliercanusually
lookforwardtoaverylongrunofmanyyearstoevenseveraldecades.Competitors
areunlikelytobeabletoqualifytheirmaterialasanalternatesource.Partscontracts
howeveraregenerallyputupforbidsannually,sothataprocessormustdefendthe
businesseveryyear.
Chapter 3
Electrical and Electronic End Use Applications
Keywords Electrical•Electronic•Fuelcell•Transistors•EMI•LCP•PEEK
•Oficeproducts•Appliance•Recycle
Plasticsisanindispensablematerialfortheelectricalandelectronicssector(E/E).
Manyoftoday’snewtechnicaldevelopmentscapitalizeonthelatestversionsofnew
generationplastics.Asaresult,devicessuchascellphonesarebecomingsmaller
and lighter. Lightweight, durable, attractive, and cost-effective plastics are also
beingusedinnearlyalloursmallappliances.SomesectorsoftheE/Emarkethave
beenevolvingtowardbecomingcommoditybusinessesbuttherearestillanumber
ofhigh-performance,attractiveopportunitiesinspecialtysectors.Aneedexistsfor
highertemperatureresistancematerialswithprocessingcharacteristicssuitablefor
useinthinnerwalled,smallercomponents.EventhelargestsubcategoryoftheE/E
market, wire and cable, which has a range of commodity, and semi-commodity
applicationsstillhasmanyspecialtyapplications,andnewproductandapplication
development across the E/E sector continues to result in signiicant, proitable
businessasperformancerequirementskeepratchetingup.
Equipmentandmaterialssuppliersaremakingprogressinthecompressionmolding
ofthermosetbipolarplatesforfuelcells.BulkMoldingCompoundsInc.(BMCI)
says graphite-illed thermoset vinyl ester bipolar plate technology offers the best
overall performance, productivity, and cost for use in PEM (proton exchange
membrane) fuel cell applications compared to metallic and other composites.
Conductivity of the plates is now around 70 Siemens/cm versus 20–30 S/cm for
plateslaunchedafewyearsback.BMCIattributesthistomorehomogeneousdistri-
butionofconductiveadditivesinthecompound.Inaddition,BMCIhasintroduced
anewhigh-temperaturecure(370°F)package,whichreducescuretimesby50%(to
around15s)andeliminatesthe15–20minpost-bakerequiredtoremoveresidual
volatilessuchasstyrenemonomer.
BMCIhasalsodevelopedavinylesteradhesive/sealantforuseinbondingthe
coolingchannelsideoftheplatesfromadjoiningcellstoformawell-sealedpathfor
the stack coolant. Like the bipolar plate compound, this adhesive is also highly
conductive.Comparedtootheradhesivesusedinthisapplication,itisalsosubstan-
tiallylessexpensiveandreducesthevoltagedropbetweenplatesby30–50%.As
fuel cell usage becomes commercial and volumes grow, the recycle of fuel cell
components will become an issue. BMCI has completed regrind trials with very
encouragingresultsandworkiscurrentlyunderwaywithcompaniessuchasPlug
Power,Inc.andGeneralMotors.
CambridgeDisplayTechnology(CDT),agloballeaderintheresearch,development,
andcommercializationoflightemittingpolymers,targetedforuseinelectronicdisplay
products used for information management, communications, and entertainment, is
workingjointlywithSumitomoChemical(www.sc-sumitomo-chem.co.jp)todevelop/
scale-up a new range of solution processable polymer light emitting diode (PLED)
materialsdesignedforuseinlatpaneldisplays.Featuresincludereducedpowercon-
sumption,size,thickness,andweight,verywideviewingangle,superiorvideoimag-
ingperformance,andthepotentialforuseonlexibledisplaysubstrates.Thecompanies
arefocusingonnewsolutionprocessable,phosphorescentmaterials,suchasdendrim-
ers, which exhibit very high eficiencies and good stability. Dendrimers are nearly
perfect monodisperse macromolecules with well deined, starlike structures. High-
eficiencyemittersareespeciallyimportantinprintableportableelectronicdisplaysfor
devicessuchascellphonesanddigitalcameras,wherebatterysuppliesareused.The
materialsarealsoexpectedtoindapplicationsforTVdisplaysandlightingdevices.
In the US, companies operating in the same ield as CDT include Gyricon, a
spin-off of Xerox, and E-Ink. Their displays differ from CDT’s in that they use
relectionratherthantransmission,andareeasiertoapplyontolexiblesubstrates.
Thedisplaysentailalayerofmicroscopicspheresofblackandwhiteparticleswith
negativeandpositivechargesrespectivelysandwichedbetweentwoilms.Depending
onthechargeputacrosstheilms,thesphereslookblackorwhiteandcanmakea
monochromeimage.E-Inkhasalreadydemonstratedcolorimagesinasimilarway.
Gyricon is targeting remotely updatable signage, and E-Ink is concentrating on
portable e-readers. Its technology is currently used in display for Sony’s Librié
e-book reader. CDT is mainly concerned with displays in more conventional
equipmentlikelaptops.
3.1 ElectricalandElectronicApplications 21
PlasticLogicLtd.,aleadingdeveloperofplasticelectronicsincludingprintedlex-
ible thin ilm transistor (TFT) arrays, is developing and exploiting a portfolio of
intellectual property based on inkjet printing of active electronic circuits using
advancedplasticmaterialstoformthinilmtransistorsthatcanbeusedinactive
matrixbackplanesthatdrivedisplays.Otherpotentialapplicationsincludesmart
labels,smartpackaging,andradiofrequencyidentiication(RFID)devices.Plastics
electronicscanbeproduceddirectlyathighspeedfromCADdatatolarge,lexible
surfacesusinginkjetprintingequipmentratherthancomplexphotolithographyand
vacuumsystemsusedtomaketoday’stransistors.Withtheprocess’lowtempera-
tures,substratesusedcanalsobeplastic.
The company recently announced a non-exclusive agreement with E Ink of
Cambridge, MA, the leading developer and marketer of electronic paper display
technology,tocooperateonthedesignandfabricationoflexibleallplasticelec-
tronicdisplays.EInkandPlasticLogicwilltocombinetheirtechnologiestopro-
duce high-resolution active-matrix displays suitable for applications from smart
cardsandcellphonestowirelesselectronicreaders(e.g.,e-newspapers,e-books,
e-maps).Theliquidcrystalactive-matrixdisplayscommerciallyavailabletodayare
produced using two sheets of heavy, fragile glass and require multiple vacuum
depositionandhighprecisionlithographicsteps.Incontrast,theEInkandPlastic
Logicdisplaysarelexible,thin,lightweight,bright,highcontrast,shatterproofand
canbeproducedatlowcostinhighvolume.PlasticLogiciscurrentlyexpandingits
existingplasticelectronicsmini-lab,installingaprototypeline,andistargetingfor
furtherproductionscaleup.
EInkprovideselectronicinkinsheetsofimagingilmthatareideallysuitedfor
lexibledisplayapplicationsduetotheirthinformfactorandinherentlexibility.
E Ink’s electronic ink is an image stable relective display technology that uses
ultra-low power but is easily read under any lighting condition including direct
sunlight.Unlikeliquidcrystaldisplays,theimageonEInkdisplayslooksthesame
fromallviewinganglesandwillnotdistortwhentouchedorlexed,makingthem
suitableforlexibledisplaysandportabledevices.EInkImagingFilmenteredmass
productionlastyearasanenablingcomponentintheuniqueSONYLIBRIéelec-
tronicreadingdevicecurrentlyavailableinJapan.
MSDIgnition,aworldleaderinperformanceautoignitiontechnology,ismoving
uptoDuPontThermxPCThigh-performancepolyesterforcoilformsinitsignition
coils.TheirstMSDcoiltomakeuseofThermxisitsBlasterSS,foundinboth
automobilesandNASCARracers.WitheficientE-corewindings,theBlasterSS
generates300mAatupto40kV.Thecoils,withabobbinmoldedfromPCT,have
withstoodtestsat70,000V,thelimitofMSDIgnition’stestrig,withnoarcing,or
crackingofthecoilform.
22 3 ElectricalandElectronicEndUseApplications
MSDIgnitionistransitioningtoThermxPCTforbobbinsinallhigh-performance
racing/streetusecoils.Innewdesigns,PCTalsoallowssmallerbobbinsandreduced
coilsize.Thematerialhasexcellentdielectricpropertiesatelevatedtemperature
andahighmeltingtemperature.Vibrationresistanceisanotherkeybeneitofthe
PCTcoils.MostMSDignitioncoilsarepottedinepoxy,whichadhereswelltothe
PCT.Theresultislessvibrationseparation.TheBlasterSScoil’shousingandcover
arebothmoldedfromDuPontRyniteFR530PETpolyester,whichprovidesgood
strength,stiffness,andtoughnessatunderthehoodtemperatures.MSDIgnitionhas
adoptedPETforarangeofcoilforms,housings,andotherignitionsystemcompo-
nents.AttheAtlantaMotorSpeedwayNASCARseries,thethreeleadteamsofDale
Earnhardt Jr., Jeremy Mayield, and Kasey Kahne all used MSD 6HVC Ignition
Control.
CooperWiringDevicessubsidiaryofCooperIndustries,aworldwidemanufacturer
ofelectricalproductsandtools/hardware,hasswitchedtoBayerPolymers’Makrolon
PCforuseinitsnewlineofmid-sizethermoplasticwallplates.Polycarbonatewas
selected,versusothermaterialssuchasthermoseturea,foritsprocessingease,high
structuralrigidity,andsuperiorresistancetowarping,impact,andabrasion.Using
thismaterialinaninjectionmoldingprocessallowedCoopertoreducecycletimes
andeliminatecostlysecondaryoperationsrequiredtoremovelashduringthemolding
process.Thecompany’snewlineofmid-sizewallplatesaddsafull0.375″ on all
sidestoNEMAstandard-sizeplates,providingneededgapcoverageforovercutsor
otherlargewallboard-to-boxopenings.Withpolycarbonate,Coopers’newlineof
wallplateshasahighglossinishandisresistanttosoiladherence.Inaddition,the
wallplatesareeasilycleanedincomparisontoothermaterialsurfaces.Thelineis
ULlistedandCSAcertiied,andmeetsNEMAWD-1andWD-6compliance.The
thermoplasticwallplatesareavailableinmultiplecolorsandvariousconigurations
for toggle switches, receptacles, decorator, blank, power receptacles, telephone/
coaxialcable,combinationdevices,andpre-markedspecialuses.
Researchers at the University of California at Berkeley in an industry irst have
printedplasticpentacenetransistorsdirectlyontoclothibers.Theapproachmaybe
usedtoembedsensing,actuation,anddisplaysintoclothingandsurfacecoverings.
The process, which is compatible with textile manufacturing, does away with
expensivemasks,ornegatives,whicharenormallyusedinprintingcircuitsonsilicon.
Instead, the researchers developed a new mask that is made up entirely of textile
ibers.ThetransistorscreatedbytheBerkeleyresearchteamwerefabricatedusinga
125 mmdiameteraluminumwireasthegateline.Thiswirecanbewovendirectlyinto
3.1 ElectricalandElectronicApplications 23
an‘e-textile’toserveasagateinterconnect.Theiberwasmaskedwithorthogonal
overwoven50mmdiameterwires,whichservedaschannelmaskswithatransistor
formedateveryintersection,while100nmgoldwasevaporatedtoformsourceor
draincontacts.Allthetransistorswere~125/50mm,sincetransistorswereformed
onlyonthesurfaceofthegatewire,whichwasexposedduringpentaceneevaporation.
Thetransistorsthatresultedaresimilartoconventionalinvertedtopcontactedpenta-
cene thin ilm transistors (TFTs). However, the entire transistor was formed on a
metallicgatewire,permittingeasye-textileintegrationtocreate‘smartcloth’.
AutotronicControlsCorp.’s(ACC)newMSDdigitalignitiontesterusedtocheck
ignitionperformanceinracingcarsandotherhighpoweredvehicleshasahousing
moldedfromDupont’sZytelEMXnylonshieldingresin.Thematerialeffectively
shields sensitive microprocessor circuitry against electromagnetic interference
(EMI), or noise. ACC evaluated an unshielded housing but found that electrical
noisecausedproblemswiththeunit.TheZytelEMXprovideseffectiveshieldingin
asturdyhousingproducedusingstandardinjectionmoldingtechnologyatalower
total cost than using coated shielding. The new housing show virtually no noise
problemsduringieldtrials,asigniicantaccomplishmentsinceMSDignitioncoils
usedinhighpoweredracingcarscangenerateupto50,000Vofelectricalpotential
inrepeatedbursts,generatingintenseelectricalnoise.
RacingcrewsusetheMSDignitiontestertocheckignitioncontrolandcoiloper-
ationwithouthavingtoremovethemfromthecar.Thetesterproducesasimulated
triggersignalthatiresthecar’signitioncoiljustasiftheenginewererunning.
Ifthesparkfailstojumpthegapinthetester,thereisanignitionproblem,which
thetestercanhelptracedown.Withthebuilt-inhousingshieldingprotectionpro-
videdbyZytelEMX,AutotronicControlseliminatesthecostofapplyingaconduc-
tiveshieldingcoatingrequiredwithaconventionalplastichousing.Whileametal
housingwouldhaveprovidedeffectiveshielding,itwouldhaverequiredagreater
toolinginvestmentandcostlyinishingstepsforeachpart.
EpcosAG,amajordeveloperandmanufacturerofelectroniccomponents,chose
DuPont Zenite LCP for its coil formers to produce SMD transformers used in
telecommunicationsequipment.Thisliquidcrystalpolymerhasthehighdielectric
strength/thermal resistance, and good melt low properties essential for making
miniaturized electronic components for mounting on circuit boards using SMD
technology.Digitalsubscriberline(DSL)technologyisoneofthefastestgrowing
technologiesforbroadbandinternetaccessandcallsforinterfacetransformerswith
24 3 ElectricalandElectronicEndUseApplications
minimalsignaldistortionandloss.Epcos’speciallydevelopedEPXandEPOseries
coregeometriesmadeofT66andT57ferritematerialsoffergooddatatransmission
ratescombinedwithgreaterminiaturization.
Dupont’sZenite7130glassiberreinforcedLCPcombinesgoodtoughnesswith
aheatdelectiontemperatureof289°Candhighdimensionalstabilitytomakethe
coilformersfortheseapplications.Asthematerialusesnohalogenadditives,itis
recognizedbyUnderwritersLaboratoriesasUL94V-Oat0.75mm.Sincetheinjec-
tionmoldedpartsdonotneedtobedelashed,processingcostswithLCPislessthan
thatwiththermosetresins.Thecompanycaninjectionmoldveryinecoilformers
witha0.4mmwallthicknessanda25mm2footprint.Theliquidcrystalpolymer’s
high strength and impact resistance allows these precision parts to withstand the
stresses that occur during coil winding and the material’s high thermal delection
temperatureallowspartstowithstandtemperaturepeaksupto260°C,whichoccur
duringrelowsoldering,whenthetransformersaremountedonthecircuitboard.
Cabasse,anultrahighyieldspeakersystemsmanufacturerbasedinFrance,hasturned
to Victrex PEEK polymer to produce the spiders on its latest range of professional
loudspeakers.Thisinnovativeuseofthehigh-performancepolymerallowsCabasseto
signiicantlyimprovethepowercapacityofthetransducer.Anelectrodynamicloud-
speakerisatransducerwithaverypooryield.Allpartssurroundingthemovableunit
insidethese1,000Wspeakers(acousticdiaphragm,coil,spiderandfrontsuspension)
mustexhibitoutstandingheatresistance,as97%oftheelectricalpowerdeliveredby
theampliierisdissipatedintheformofheat.Spidersaretraditionallymanufactured
fromacottonfabriccoatedwithphenolicresin.However,atfullpower,Cabassehas
measuredtemperaturesashighas270°Cinthecoilareaofitsnewrangeofprofes-
sionalspeakers.Withaveryhighmelttemperature(343°C),andacontinuousoperat-
ingtemperatureofupto260°C(UL746B),monoilamentyarnmadeofVictrexPEEK
polymergavethecompanythenecessaryhigh-temperatureresistance.
An additional factor Cabasse’s in material selection was strength and fatigue
resistance, as guide parts such as the spider must withstand signiicant displace-
ments.ThePEEKpolymerfabricdeliversanidealcombinationofstiffness,elonga-
tion at yield and very high fatigue resistance and the polymer’s inherent ease of
processing has also simpliied Cabasse’s manufacturing process and improved
productivity.
EXO, an overmolding system developed by Inclosia Solutions, a unit of Dow
ChemicalCo.,isaninnovativetechnologythatallowsfur,leather,variousfabrics,
3.1 ElectricalandElectronicApplications 25
andevenwoodandmetaltobeincorporatedintothesurfaceofcasingsforportable
devicessuchascellphones,laptopcomputers,andpocketcalculatorsandbrings
newopportunitiesforco-brandingtooriginalequipmentmanufacturers(OEMs).In
amarketwherestate-of-the-artelectronicsperformancefeaturesarenolongerthe
onlydifferentiatingfactorsinelectronicspurchasedecisions,brandingandappear-
anceenhancedbymoldedinfabricsandothermaterialsareincreasinglyimportant
driversinmotivatingconsumerpurchase.
ThefamilyofEXOsystemsolutionsdevelopedbyinclosiaisdesignedforhigh
volumeproductionofawiderangeofenclosures,avariantoftwoshotovermolding
allowsvirtuallyanytypeofmaterialtobeincorporatedinacoveringwhilemeeting
cost, quality, durability, and volume requirements critical for production of elec-
tronicdevices.Theprocessstartswithplacingapre-cutdecorativeinsertintoan
injectionmold.Oncemoldingstarts,theirstshotcoverstheinsertwithathermoplastic
substrate,whichalsoformstheenclosuresstructureasrequiredbytheapplication.
Anoptionalsecondshotcanbeusedtoencapsulatetheedgesofthebackmolded
material. The overmolded material is permanently bonded on the outside of the
enclosuresotherearenoissueswithfrayededgescompromisingtheintegrityofthe
internalcomponents.Asonemoldcanbeusedfordifferentmaterials/fabrics,retool-
ingisnotnecessarybetweencoveringchanges,whichfurtherincreasesspeedand
costadvantages.
Sportingeventsandrockconcertsarefrequentlyelectronicextravaganzasrequiring
enormousquantitiesofcableforlighting,sound,andothermedia.Now,Flexalloy,
anadvancedPVC-basedTPEfromthevinyldivisionofTeknorApex,isallowing
theEntertainmentDivisionofCoastWireandPlasticsTechnology,acablemanu-
facturerspecializingintheseapplications,tosupplycablethatislighter,morelex-
ible, and more resistant to extreme cold than cable produced using conventional
compounds.
Flexalloy-based cable products have half the weight of other cable products
making it possible for users to dramatically increase overhead lighting without
exceedingthelimittotheweightthataneventceilingstructurecansupport.Based
on ultra high molecular weight (UHMW) PVC resin, Flexalloy compound also
provides greater lexibility than conventional vinyl, even at low temperature, a
criticaladvantageatoutdoorwintereventssuchasthewinterolympics.Evenin
warmer environments, lexibility is important for timely wiring to be used at
crowdedentertainmentvenues.Fortheseapplications,CoastWirehasintroduced
anewlineofentertainmentcable‘FlexOLiteTouringCable’basedonFlexalloy
compound. Flexalloy products provide the elasticity of non-vinyl TPEs, plus
greater toughness, abrasion resistance, and low-temperature performance than
conventionalvinyl.
26 3 ElectricalandElectronicEndUseApplications
Astheeconomycontinuestorebound,techspendingforcomputersandperipher-
als has increased as well, although not to pre-2008 levels. The computers and
peripheralssegmentshoweda14%annualincreasefrom2005to2008.PCship-
ments globally grew by 13.5% in 2008, bringing the market size to more than
175millionunits.Growthratesfor2010andsubsequentyearsareforecasttorise
moreslowly,withshipmentsexpectedtogrowbynearly11%in2010andabout
8%annuallyfrom2011to2015.Wirelesscapabilities,fallingprices,andthegrow-
ingneedformobilityhaveincreaseddemandfornotebooks;however,manybuyers
remainpricesensitiveandcontinuetoevaluatethebeneitsofmobilecomputing.
While portable PCs continue to grow much faster than desktops, recent results
demonstratethecontinuingcompetitivenessofdesktopsystems.Worldwideship-
mentsofdesktopPCsgrewby13.4%year-on-yearin2010,upfrom9.6%in2009,
whilegrowthinportablePCsslowedto28.5%in2010,frommorethan35%in2008.
Desktopscontinuetorepresentmorethan70%ofworldwidePCshipments,andtheir
stronggrowthhelpedboostgrowthexpectationsfortotalPCshipmentsin2010.
Trendsinportableelectronicsrequirelongerlastingpower,moreenergythancur-
renttechnologiesmightbeabletoprovide.MTIMicroFuelCellsInc.isdeveloping
miniaturized fuel cells suitable for handheld electronic devices to replace power
packscurrentlyusedbyOEMsinmanyrechargeablehandheldelectronicdevices
likePDAsandsmartphones.Mobioncordfreerechargeablepowerpacksarebased
on direct methanol fuel cell (DMFC) technology. A recent Allied Business
Intelligence(ABI)studyseesalmost22%ofallhandheldelectronicdeviceswith
rechargeablepowerpacksbeingpoweredbyDMFCsby2011.
MTIMicro’sDMFCsystem,basedonworkcontainedinmorethan50patents,
consistsofauniquefuelcellarray,customfuelfeedcontrolanduserreplaceable
methanolfuelcartridges,isintendedinitiallyforintegrationintoindustrialhand-
heldelectronicOEMdevices.Productlaunchisplannedforearly2011.Undera
strategic alliance agreement, MTI Micro has incorporated DuPont’s membrane
electrodeassemblyinthecoreoftheproprietaryfuelcellsystem.Thebest-known
andmostwidelyusedmembranematerialusedinthisapplicationtodayisNaion,a
polyperluorosulfonic acid product that is cast into ilm and supplied by DuPont
Fluoroproducts.FlextronicswillassemblethisinitialproductatFlextronics’spe-
cialized‘ProductIntroductionCenter’inSanJose,CA.Thepowerpacktechnology
isdesignedtoincreaseruntime(timebetweenrecharges)twototentimesoverthat
ofexistingbatterytechnologies.
3.2 OficeProductsApplications 27
AtthecoreofMobiontechnologyisitsuniqueapproachtomanagingwaterthat
isproducedbythechemicalreactionatthecathode,andrequiredforthechemical
reaction at the anode. MTI Micro’s Mobion technology simpliies the traditional
approachinwhichwatermustbeexternallypumpedfromthecathodetotheanode
side for the chemical reaction to occur and energy to be produced. Using MTI
Micro’sproprietarytechnologythewaterrequiredfortheprocessonthefuelsideis
transferredinternallywithinthefuelcellfromthesiteofwatergenerationontheair
side of the cell. This internal low of water takes place without the need for any
pumps,complicatedre-circulationloopsorothermicro-plumbingtools.Asaresult
ofthewaterreallocationinternaltothefuelcell,thesystemcanaccept100%‘neat’
methanol and the elimination of ‘micro plumbing’ makes more room available
withinthepackforthefuel.ThenetresultisthatMobionfuelcellsareeasierto
manufacture. They are also more compact, making Mobion-based DMFCs small
andlightenoughforhandhelddevices.
Lightweight, unbreakable, large area displays that can be rolled up into a small
housingwhennotinuseareparticularlyattractiveformobileapplications.Workis
progressingatPolymerVision,aPhilipsTechnologyIncubatorthatwilltransform
thewayinformationisviewed,particularlywhenweareonthemovebyproviding
lexibledisplaysnotmuchsmallerthanacomputer,thatrollupandtuckawaywhen
notinuse.AfteryearsofworkonpolymerelectronicsPhilipsisproducingproto-
typesofultra-thin,largearea,rollabledisplaysandintendstomoverapidlytoward
a commercial production process. One prototype, designed for e-newspapers,
suggestsadualscreenfoldablestickmechanismtoallowdualfunctionalityofthe
productasbothe-newspaperande-book.Newscanbedownloadedviasubscrip-
tionsdirecttoaPCinbox,oruploadedfromnewskiosksasone-timepurchases.
Easyone-buttonbrowsingandsimpleelegantdesignwouldappealtobothtradi-
tional reader and early technology adopters. The displays combine active matrix
polymer driving electronics with a relective ‘electronic ink’ front plane on an
extremelythinsheetofplastic.Ultimately,lexiblelargeareadisplaysthatcanbe
integratedintoeverydayobjectslikeapencouldbefeasible.Suchdisplayswould
greatlystimulatetheadvanceofelectronicbooks,newspapers,magazines,andnews
services; applications that currently depend on fragile, large laptops or small,
low-resolutiondisplaysofmobilephones.
PolymerVisionhasmadeorganics-basedQVGA(320×240pixels)activematrix
displayswitha5in.diagonal,aresolutionof85dpi,andabendingradiusof2cm.
The displays combine an active-matrix back plane containing polymer driving
electronicswitharelectivefrontplaneof‘electronicink’developedbyEInkCorp.
Electronic ink based displays can have thin lexible construction, as they do not
require cell gap control. Displays made with electronic ink technology are ideal
candidatesforreadingintensiveapplicationsbecauseoftheirexcellent,paper-like
28 3 ElectricalandElectronicEndUseApplications
WithLogitech’snewio2PersonalDigitalPen,itispossibletotakenotesatameeting
withpenandpaper,returntotheoficeandtransferthehandwritingtocomputer.
This application provides development opportunities for polycarbonate, PPO/PS,
andsofttouchTPEtypeengineeringplastics.TheLogitechio2retailpackageconsists
of the pen, a USB cradle and recharging station, Logitech io2 software, special
preprinted digital paper, an AC adaptor and ive ink reills. The pen software is
compatiblewithWindows98orhigher.
Anopticalsensorlocatedbeneaththe$200electronicpen’sballpointtipcaptures
thehandwrittennotesbyrecordingapatternofdotscreatedwhenthepenisusedto
writeonspecialdigitalpaper.Thedigitalpaper(withAnotofunctionality)iscreated
byprintingaproprietarypatternofverysmalldotsonpaperthatisperceivedbythe
eyeasslightlyoffwhiteincolor.Theprinteddotpatternlocateswordsandimages
onthepaperandassurestheyappearinthesameplaceindigitizediles.Thepen,
usedasaregularballpointpen,isactivatedbyremovingthecapanddeactivatedby
replacingthecap.Whenincontinuoususethepen’sbatteryhastypicallya3-hlife.
Upto40pagesofhandwritingcanbestoredinthepen’s856-kBlashmemory.The
capturedwritingcanthenbetransferredtoacomputerbyplacingthepenintoa
dockconnectedtothePCviaaUSBport.Thehandwrittenimagescanbepasted
into various applications including word. The Logitech io2 pen is a new product
categoryandrepresentsaplatformwithanenormouspotentialforgrowthparticu-
larlyasgoodhandwritingrecognitionsoftwarebecomesavailable.
Logitech, the world leader in Web cameras, has a new web camera, Logitech
QuickCamOrbit,thatoffersuniquefeaturesincludingmechanicalpanandtiltas
wellasanelegantform.ThecameracombinesovermoldedTPOtoapolycarbonate
shellbaseinitsuniquesleekdesign.Itisidealforvideoinstantmessaging,sinceit
physicallymovestokeepaperson’sfaceautomaticallycenteredintheieldofview.
Aheavybasecontainsthemotortoswivelthecamera,toppedbyaglobeslightly
smallerthanatennisball,whichhousesthecameraandaredLEDbehindaclear
plastic shield. The camera is built into the globe and positioned on a motorized
mountthattiltsupanddown.
Logitech designs, manufactures, and markets personal interface products that
enable people to effectively communicate in the digital world. The Logitech
QuickCamOrbitistheindustry’spremierwebcam.TheQuickCamOrbitmechanical
3.3 ApplianceApplications 29
panandtiltfeatureallowsthewebcamtophysicallyturn128°side-to-sideand54°
up-and-down, freeing users from manual camera maneuvering. Logitech’s face-
trackingsoftwareenablesthecameratoautomaticallyfollowaperson’sface,keep-
ingitcenteredintheieldofview.Auto-zoomtechnologyofferstheoptiontozoom
inuptothreetimesthenormalviewingsize.QuickCamOrbitcapturesupto1.3
megapixelstillphotos,andtrue640×480videoswithitshigh-qualityCCDsensor.
A 9-in. stand is included, so the camera can be elevated to eye-level, and also a
built-inmicrophoneforeasyadditionofaudiotoinstantmessagingorvideoclips.
ImationCorp.,aworldwideleaderinremovabledatastoragemedia,hasintroduced
itsnewdoublelayerDVD+Rmedia,theindustry’snextadvancementinDVDtech-
nology,tomeettheincreasingstoragerequirementsofconsumersforhigh-capacity
applicationssuchasdigitalvideo.Thenewdiscnearlydoublesthestoragecapacity
ofaDVDrecordablediscfrom4.7GBto8.5GBonasingleside,withouthaving
toturnthediscoverduringrecordingwhileremainingcompatiblewithDVDvideo
playersandDVD-ROMdrives.
ThenewmediaachievesthehighercapacitybyusingaduallayerDVD+Rsys-
temwithtwothinembeddedorganicdyeilmsfordatastorage,whichareseparated
byasemi-relectivelayerandaspacerlayer.Therecordingprincipleisbasedon
irreversiblymodifyingthedye’sphysicalandchemicalstructure,inducedbyheat-
ingwithafocusedlaserbeam.Therecordedmarkshavedifferentopticalproperties
thantheirunmodiiedsurroundings,givingthesameread-outsignalsasread-only
discs,basedonthelengthoftherecordedmarksandunmodiiedspacesbetween
them.AccordingtotechnologydevelopersPhilipsandMitsubishiKagakuMedia,a
keychallengetoovercomewastominimizetheinterferencebetweendatarecorded
intheirstrecordinglayer(L0)whilerecordingonthesecondlayer(L1).Inaddition,
theirstlayerrequirestheuseofatransparentthinmetallayerthatshouldstillhave
enoughcoolingpowerallowingcontrolledrecordingofdataintheirstlayer.Philips
in cooperation with MKM were able to reach major innovations in the materials
usedforthespacerlayer,thetransparentmetalrelector,andrecordinglayerswhile
remainingwithintheboundariessetbytherequirementsforbackwardscompatibility
withdoublelayerDVD-ROM.
Acontinuedstrongnew-homemarketandanequallystrongremodelingmarketis
keepingthedemandformajorandsmallappliancessteady,withnearlyallcatego-
riesoflargeappliancesexpectedtoregisteraminoruptickinunitssold.Topropel
30 3 ElectricalandElectronicEndUseApplications
theappliancemarketintobiggerandbettertimes,manyofthemajormanufacturers
aremovingintotheveryhigh-endmarket.GEAppliances,Whirlpool,andothers
aremakingapushintoanareaofthemarketwherepricepointsnear$2,000are
commonforbig-ticketdurablessuchasrefrigerators,freezers,clotheswashers/dryers,
andversatilestove/oven/refrigeratorcombos.Addedfeaturesinthese‘smartappli-
ances’arecreatingavaluethatthemajorappliancemakershopewilltranslateinto
biggerproits.
Theotherendofthismarketiscrowdedwithproductsinthe$500pricerange,
withentrantsfromChinaandKorea(LGElectronics,forone)squeezingthisendof
themarket.Competitioninthesmallappliancecategoryisnotmuchbetter,with
smallappliancemanufacturingjustaboutnonexistentintheUS.Muchofthatmar-
ketwenttoMexicoadecadeago,andwhatdidnotmovesouththenhasnowmoved
totheFarEast—Chinaparticularly.Mexicoisstillhometoanumberofappliance
manufacturingplants,wherecompaniessuchasMaytag,Bissell,Hoover,Eureka,
andWhirlpool,amongothers,havemaquiladoraplantsontheborder.
Japan’shomeappliancerecyclinglegislation,makingitmandatoryformanufactur-
ers to charge consumers for collecting old appliances, is transforming appliance
material selection and design. The legislation sets minimum recycling rates by
applianceweight;with60%ofanairconditioner’sweighttoberecycled,50%ofa
refrigerator,50%ofawashingmachine,andsoon.Itisexpectedthattheserates
willbeincreasedto80–90%by2011.
InresponsetothelegislationJapan’sappliancemakersaremakingtheirproducts
more readily recyclable by using fewer plastics and grades, and plastics that are
easier to recycle. PS, considered easier to recycle, is used rather than ABS over
concernthattoxicsubstancesderivedfromacrylonitrilemaybeemittedifABSis
incinerated. Both Fujitsu and Matsushita switched from using ABS in air condi-
tionerdrainpanstoanalloyofsyndiotacticpolystyrene(SPS)andpolystyrene.
APS/SPSalloyisalsobeingusedinplaceofglassiberreinforcedPBTinavacuum
cleanerblower.Similarly,polypropyleneisreplacingABSinvacuumcleanerhous-
ings. In refrigerator designs, trays now are more likely to be chemical-resistant
GPPSthanASresinandPVCisalsobeingavoidedwithelastomersusedinplace
ofPVCforrefrigeratorgaskets,andvacuumcleanerhoses.Thenumberofgrades
employed in appliances is also being reduced, for example, in refrigerators, the
numberofgradesusedhasdroppedfrom30to10orless.
Withmostvacuumcleaners,thebagquicklyclogswithdustasthesuctionhadto
passthroughthebag,andacloggedbag,evenwithaslittleas10oz.ofdirt,cancut
3.3 ApplianceApplications 31
thesuctioninhalfsothemoreabagisusedthelesseffectiveitbecomes.Entrepreneur
JamesDysonsetouttosolvetheproblem.Fiveyearsand5,000prototypeslater,the
world’sirstcyclonicbaglessvacuumarrived.Whennoneofthemajormanufacturers
wereinterested,Dysonlaunchedhisownvacuumcleanercompany.Now,Dyson
CyclonicVacuum,Europe’shottesthomeappliance,hascometoAmerica.
TheDysonhassevenABSplasticconicalcylinderswith100,000G’sofspinning
centrifugal force. No bag or ilters are in the main cyclone chamber to obstruct
airlow,sothereisnocloggingtoreducesuction.Dirtanddebrisareliterallythrown
outoftheairstream,whichcanreadilybeseenthroughtheclearPPchamber.Deep
inside,alifetimeHepaFilterwithBactisafescreenkillsharmfulbacteriaandtraps
microscopicparticles,protectingsufferersfromairbornepollutants.Ergonomically
designed, the Dyson’s agility and ingenious lexibility makes tedious vacuuming
intoasatisfyingpleasure.Thevacuumisperfectlybalancedandadjustsautomatically
todifferentcarpetheights.Althoughtechnicallyanupright,theDysonoutperforms
thebestcanistersonbareloors.A17-foothoseaccessedbydetachingthehandle
canbeusedtoreachunderfurniture,oruseonstaircases.Thecollectionchamber
releasesfromthemainunitforemptying.
Keywords Packaging•RFID•Container•Stretchilm•Building•Construction
•Industrial•Fasteners•Pallets•Agricultural
Plasticsremainthematerialofchoiceforpackaging,increasinglysubstitutingfor
othermoretraditionalmaterialsbecausetheyarelightweight,lexible,andeasyto
process. Packaging constitutes the single largest end use for plastic materials, in
2010accountingforapproximately34%ofallplasticsusedintheUSand37%of
allplasticsusedinEurope.Plasticsusedinpackagingareprimarilythecommodity
resins:polypropylene(PP),polyethylene(PE),polystyrene(PS),polyvinylchloride
(PVC),andpolyethyleneterephthalate(PET).Semi-commoditynylon6(PA6)isan
important exception, because ilm for food (mostly meat) packaging is a major
market for this polymer. Packaging has become the major market for plastics
becauseplasticsofferbetterprotectionagainstspoilage/breakage,displayproducts
moreattractivelythandoconventionalmaterials,arelighterinweightthantradi-
tionally used paper, glass, and metal products, and offer savings in freight costs
(primarilyfueleconomy).Theneedforimprovedproductperformance,fasterpack-
agingspeedsanddowngaugingisdrivingthedevelopmentofleadingedge,cost-
effectivepackagingsolutions.
Lachenmeier,oneoftheleadingmanufacturersofend-of-linepackagingmachin-
ery, has developed a new generation of stretch hood machines, which presents
considerableadvantagesforendusers.Theinnovativestretchtechnology,offering
signiicantcostreduction,improvedopticalproperties,andoutstandingloadstability,
ispositioningstretchhoodasthenumberonechoiceasanend-of-linewrapping
methodforawiderangeofindustries.Theblownilmbusinessforstretchhood
applicationsisprojectedtoincreaseby22%/yearthrough2011inEuropealone
comparedto5.5%/yearforstretchilm.Stretchhoodsareelasticilmtubesusedto
wrapastackedpallet.Stretch(monoormultilayer)ilm,circularlywrapped,domi-
natesthepalletwrapmarketwitha67%marketshare.Anothercompetitor,shrink
hoodilm(ilmtubesshrunkaroundastackedpalletbyapplyingheat),isexpected
todeclineby2.3%/yearthrough2011.ThetotalEuropeanmarketforpalletwrap
is 1.5 million tonnes/year. While the pallet wrapping ilm market will advance
signiicantlyinvolumeterms,stretchilmcapacityutilizationisforecasttoremain
below80%,basedonannouncedcapacityincreases.Thusmarginswillbeunder
pressureandsupplywillrestructurewithnumerousshrinkhoodilmandstretch
ilmplayersexitingthebusiness.
Whenhoodstretching,anundersizedilmhoodisstretchedhydraulicallytoa
dimensionmatchingtheexactoutercircumferenceoftheload.Thefourgrippers,
whichhavestretchedtheilm,traveldowntheloadapplyingtheilmandinally
securingitunderneaththepallet.Thisbottomstretchensuresareliableholdbetween
pallet and load and secures the pallet for storage and transportation. Test results
showthatawiderangeofproductscanbeneitfromthistechnology,notonlybagged
productslikecementorchemicals,butalsobricks,appliances,food,beverages,and
otherbottledgoodswhichwereinitiallytoounstableforthiswrappingmethod.
Lachenmeier’snewstretchunitprovidesacontrolledapplicationofthestretch
hood ilm with every step of the application procedure fully controllable from
stretching the ilm, to the application over the load, and inal release of the ilm
underthepallet.Ailmhoodwithasmallercircumferencethantheloadiswound
uponfourstretchunitsandstretchedtoasizematchingtheexactoutercircumference
oftheload.ThankstotheLachenmeiertopstretchilmunwindingsystem(patent
pendingEP1.184.281),bymeansofwhichacontrolledamountofilmisunwound
duringstretching,thin,fragileilmareas,especiallyonthecornersoftheproduct,
areavoided.
Wal-MartStoresInc.with$245billioninrevenuesistheworld’slargestcompany.
Itisthreetimesthesizeoftheworld’sNo.2retailerFrance’sCarrefour.Withcosts
aprimaryfocusWal-MarthastakenamajorinterestinRFID(radiofrequencyiden-
tiication),wheretinycomputerchipsonpackagesallowradiofrequenciestomonitor
theirlocationinthesupplychain.
Though RFID is gaining interest among retailers such as Target Corp. and
Carrefour,Wal-Martistheleadingforce.Theretailcolossusisaskingitstop300
suppliers to produce radio controlled microchip tags to be applied to shipping
4.1 PackagingApplications 35
containers/pallets.Thecompanybegananewerainsupplychainmanagement.
At that time, Wal-Mart and eight product manufacturers started testing electronic
product codes (EPCs), that is RFID tags marked with an EPCglobal symbol, at
select Supercenters and one regional distribution center in the Dallas/Fort Worth
metroplex.EPCglobalisajointventureofEANInternationalandtheUniformCode
Council.ItistheorganizationchosenbyindustrytodevelopstandardsforRFID
technologyintheglobalsupplychainbasedonuserneedsandbusinessrequire-
ments.Simultaneously,Wal-Mart’stop100suppliers–plus37volunteers–have
beenworkingtowardbeinglivewithEPCSinNorthTexasbyQ12011.Thecompany
hasalsodiscussedimplementationplanswiththeirnexttop200supplierswiththe
expectation that these suppliers will begin EPC tagging of cases and pallets by
January2012.
Theradiotagswillalloweverypackagetobeidentiiedandtrackedenrouteto
everydestinationthroughasignalsentbycomplexcircuitry.Inthesupplychain
application,passiveRFIDchipswithsmallantennaeareattachedtocasesandpallets.
When passed near a ‘reader,’ the chip activates and its unique product identiier
codeistransmittedbacktoaninventorycontrolsystem.ReadersusedbyWal-Mart
haveanaveragerangeof15feet.
AsWal-Martisreshapingplasticspackaging,adoptingRFIDtechnology,plastics
processors face a daunting cost containment challenge. Thirty billion tags are
required, which currently cost 30¢/tag. That price needs to be less than 5¢, and
supplierswanta1¢tagtorespondcost-effectively.
FollowingtheirstrongsuccessinEurope,allplasticgallonpaintcansareentering
NorthAmerica’sretailpaintmarket,withthePCCGroup(ThePlasticCanCompany)
recentlyintroducinganinjectionstretchblowmoldedclear,onepiecePETcan.The
companyexpects,basedonsuperiorcost,functionality,andmanufacturability,that
15%ofsteelcansintheUSwillbeconvertedtothePCCGroup’sPETdesignby
early2011.PCC’stechnology,whichisavailableforlicense,moldstherimintothe
preform,allowingonepiecePETcans,fortheirsttimetobeblownonsinglestage
injectionstretchblowmachines.ThesnaplidisalsoPET.WhatdistinguishesPET
cans from other plastic versions is their resistance to both water- and oil-based
paints,andtheirabilitytobeeitherclearorcolored.BlowmoldedPETcontainers
willtransformpaintpackagingeconomicsintheUS.AroundPETcanisableto
dropintotheexistingpaintindustryinfrastructurewithminormodiications.
InitialuseofPETcansinNorthAmericawasbyInnopackinMexico,which
recently launched four sizes (1/4–4 L) for a Mexican customer. Three sizes are
moldedonaHuskyone-stageIndexSB-125machine,whilethe4Lcontaineris
moldedonAokione-stagemachines.InnopackisaleadingMexicanPETbeverage
containers/capsmolder.Thecompanydevelopedasee-throughlabelandsnap-on
PEhandleforthe4Lcans.
36 4 IndustrialEndUseApplications
One of the most innovative packaging solutions recently introduced is North
America’s irst self-heating container, designed to heat liquid contents such as
coffee,tea,cocoa,soups,andalcoholicbeverages.CreatedbyOnTech,Inc.,thenew
self-heatingcontainerisasafeandeasy-to-activateconceptthatheatsupthecontents
ofitspackagetoapproximately145°Fwithinminutes.Thecompanynowhas102
approvedutilitypatentclaimsintheUSandpatentsin36othercountries,including
theUK,China,andJapancoveringanymultichamberplasticproductthatmustbe
retorted,orsterilizedduringaheatingprocess.InEurope,somemetalcontainers
canself-heatandothershavetriedamixofmaterialstocreatethesameresultbut
withlimitedcommercialresults.Metalhasatendencytocollapseorcrushduring
thesterilizationprocess,whenthecontainerhastobeheatedto250°F.
TheOnTechself-heatingcontainerhasthreemainparts,thesix-layerplastic
container,aninnerplasticcone,andawaterholdingactivation‘puck.’Theinner
coneholdsthecrushedcalciumoxideor‘quicklime,’usedintheheatingprocess,
andtheoutercontainerbodyholdsthebeverageproduct.Thepuck,whichholds
thewatertoreactwiththecalciumoxidewhenactivated,itsinsidethecone,and
atamper-evidentfoilmembranesealstheoperatingmechanism.Toactivate,the
consumerremovesthetamper-prooffoilandfirmlypressesdownonabutton
onthecontainerend.Thisreleasesthewatercontainedinthepuckintothecal-
ciumoxidewithintheconeandbeginsathermalreactionthatheatstheinnercone
to250°F.Thisheatsthebeverageinthecontainerto145°Fin6–8min,whilethe
lukewarmoutershellremainsacomfortabletemperaturetohold.Thebeverage
willstayhotforatleast20minandwarmforuptoanhour.Thehighbarrier
disposable container is shelf stable and does not require refrigeration prior to
opening.
Thesix-layerplasticcontainerconsistsoffourFDAapprovedplasticmaterials:
polypropylene,anEVOHoxygenbarriermaterial,atielayer,andaregrindlayer.
Theresultisastrong,safecontainerthatmaybeusedwithmanydifferenttypes
ofproducts.Thecontainerisdesignedtowithstandnormalmanufacturingproce-
duresforthecanillingindustryandcanthereforesurvivetheretortprocessas
requiredbytheFDAforcanningcertainfoodproducts.TheOnTechcontaineris
a standard 16 ounce size and will hold 10 ounces of product (the remaining
6ouncesisoccupiedbytheinnerheatingcone).Itisdesignedtoaccommodate
standardfilllinesandissuitableforhotfill,retortorionizedpasteurization.
A smaller,standard12ounceOnTechcontainerisplannedtohold7ouncesof
product,suitableforbabyformula,sake,specialtydrinks,etc.Thecontainercan
alsobemoldedintocustomshapestoitspeciicneeds(soupbowl,mug,baby
bottle).Eachofthecontainerswillbearthelabel‘PoweredbyOnTech,’toremind
consumersofthetechnologybehindtheproduct.Thecompanyisalsoworkingon
thenextiteration,aself-coolingplasticcontainerthatwouldchilltheliquid,such
asbeerorsoftdrinks.
4.1 PackagingApplications 37
Easiwrap,thesignatureproductfromEasiwrapInternational,ismadewithanew
technologythattransformsconventionalthinkingaboutstretchilm.Theengineered
palletizing ilm is a stretch ilm that acts more like a shrink ilm. Elastic like
Easiwrap’sstretch‘memory’ispre-programmedatthemanufacturingstagethrough
auniquetechniquethatmakesitseemmorelikeashrinkilm.Theproprietaryilm
andmanufacturingprocesswasthebrainchildofIrishengineerPhillipDorn,who
inventedthetechnologytomaketheblownilmandthemixofmaterialsthatgointo
it.WhenthecornersoftheEasiwrapilmaretugged,itshrinkstoitastightasan
elasticstocking.Aslighttuginthecornerorientsthemolecularstructure,startingit
shrinkingfor20–30minafteritiswrappedaroundaskid.Sincereactivityofthe
ilmstartswiththattug,thewrapcanbeappliedlooselytoapalletloadthentight-
enedmakingthepalletwrappingoperationeasierandquicker.Withits300%bilat-
eralstretch,theilmcanconformtoirregulardimensionsonthepalletandreduces
ilmusage,reducingmaterialwaste,increasingproductivity,andmakingthecost
perpalletmorecompetitive.Byformingatightittheilmresistsnicksandpunc-
tures providing excellent product protection from damage in transit. Customers
includewindowfabricators,buildingsupplyirmsandfood/beveragedistributors.
Gatorade’s‘ThirstQuencher’brandinnowpackagedinaredesignedcontainer,the
irsthotilledrectangularPETgallonbottletoreachthemarketdomesticallyorinter-
nationally..Thenewbottle,createdbyOwens-Illinois(O-I)PlasticsGroup,replaces
theround‘space-consuming’shapepreviouslyused.Theredesignedgallonbottleis
easiertohandle,allowsretailerstodisplaymoreproductonstoreshelvesandcustomers
canstorethebottlemoreeasilyintherefrigeratordoororothertightplaces.
Consideringthatagallonweighs8pounds,thecontainercanbecumbersome
anddificulttogrip.Toimprovehandling,O-Idesignedabalehandleforthebottle
togiveusers,particularlychildren,somethingtoholdontowhentakingtheproduct
from the refrigerator and pouring it into a cup. The custom HDPE Uni-Pak bail
handle,whichisappliedtothebottlepriortoillingissuppliedbyPakTech.Inaddition
to creating a rectangular package that was easy to handle and pour, Gatorade
required a bottle that could be illed on existing bottling lines. This necessitated
positioningthehandlesothattheneckcouldstillbegrippedduringtheillingoper-
ation.Thebottleismoldedwithrecessedhandgripsoneithersidethatandribbed
panelsthat,togetherwiththerecessedgrips,maketheheavybottleeasiertomaneu-
verwhilepreventingpanelingduringhotillingattemperaturesupto180°F.From
initialconceptofthecontainertoproduction,thenewmonolayerPETbottletook
6monthstocomplete.
38 4 IndustrialEndUseApplications
Buildingandconstruction(B&C)isthesecondlargestendusemarketforplastics.
Thebuildingandconstructionindustryusesplasticsforarangeofapplicationsfrom
insulation to piping, window frames to interior design. It is plastics durability,
strength,resistancetocorrosion,lowmaintenanceandaestheticallypleasinginish
thatensurestheircontinuedpopularityinthesector.Mostofthevolumeusageis
processedbyextrusion,suchasforpiping,conduit,wireinsulation,siding,reservoir
liners,erosioncontrolnetting,orarchitecturalsheeting.Asinpackaging,plastics
have displaced such traditional materials as wood, glass, and metal, based on
improved performance and lower cost. Considering the volumes involved, the
marketplacetendstofavorcommoditieswhereverpossible.
KadantCompositesInc.isusingapapersludgeby-productmixedwithplasticto
produceextrudeddeckboards.Biodac,aKadantpatentedproduct,isasynthe-
sizedrecoveryofshortandlongcelluloseibers,precipitatedcalciumcarbonate
andkaolinclaythatwouldotherwisegotoalandill.AKadantsistercompany
producesagranulefrompapersludge,apaperrecyclingwasteproduct,which
has found application in a variety of industrial uses particularly as a carrying
agentforfertilizer.Intheprocessofextrudingthatgranule,averymicroscopic
granuleiscreatedthatwastoosmalltobeusedinanyoftheapplicationsthatthe
sister company was selling into, and it was being hauled off to landill. Now
instead,thematerialismixedwithrecycledpolyethyleneandricehullstomake
GeoDeck.
TheBiodacgranules,whichareuniforminsizeandshape,andmixextremely
wellwithHDPE,areacriticalelementintheproductionofacompositebuilding
material being used to produce Kadant’s extruded Geodeck deckboards. Unlike
woodibers,whichcontainligninandtanninthatinhibitresinbonding,Biodacis
lowinthosechemicalsandcompoundsmorereadilywithplastics.Kadantdevel-
opedGeoDeckdeckproiles,hollowtongue-in-grooveboardsofHDPEwithupto
30%Biodacplusadditionaliberfromricehulls.Thecompositesareapproximately
one-third plastic, one-third mineral, one-third iber. Up to 70% Biodac could be
used,butthesehighlevelsaretooabrasiveforthecompoundingextruders.Whiteners
andbrightenersfromthepaperboosttheeffectofcolorantsinGeoDeck,makingit
lesssubjecttofadingthanwood–plasticcomposites.Theproducthasgreaterdimen-
sional stability and less moisture absorbance than competing composites. That
granuleisthekeyingredientthatgivesGeodeckitsfaderesistanceaswellasforming
avery,strongproduct.
4.2 BuildingandConstructionApplications 39
GeoDecksaleshavegrownfromunder$2millionin2007tomorethan$15million
lastyear.KadantCompositeshasdevelopedothernewbuildingproductscontaining
Biodac,includingcorrugatedrooftilesthatlooklikeredclay,andlat,squaretilesthat
resembleslateandisalsointroducingnewGeodeckproducts.
According to Style Solutions Inc., customized construction products and large
builderswilldrivethegrowthofurethanemillworkin2010.Theirmhascreated
morethan300customizedproductsinthepastyearforbuildersacrosstheUS.The
buildingandconstructionindustryhasseenunprecedentedadvancesintheaccep-
tanceanduseofurethanemillworkonbothexteriorsandinteriorsofcommercial
andresidentialbuildings.Just5yearsago,woodmouldingproileswerepredominate
withfewengineeredplasticonesseen.Todaythereverseistruewithlowmainte-
nanceproducts,suchasurethane,composite,andplasticmouldingsprominentinall
regionsofthecountry.Urethanemillwork,whichstandsuptohightemperaturesin
thesummerandfrigidsnowyweatherinthewintermonths,isbeingincreasingly
usedwithotherproductssuchasdoors,windows,andvinylsiding.
StyleSolutionsrecentlyintroducedanewlineofdecorativemouldingpiecesthat
canbemanipulatedtoitmostanycurveorbend,makingiteasyforhomeownersto
addmouldingaccentstotheirhomes.Thenew‘FlexibleMouldings’withtheirm’s
mostpopularmouldingproilesallowsconsumerstotrimradiuswalls,curvedstair-
ways,andarchedentryways.Eachpiece,madeoftough,high-performanceurethane,
vinyl,orstyrenicelastomermaterials,canbebentmorethanoneway,makingit
possibleto‘snake’lexiblemouldingdownastaircaseorcurveitcompletelyaround
acolumn.Forinteriorandexteriorapplications,themouldingsresistinsectinfesta-
tion, rotting, decay, and splintering. The closed cell structure used also prevents
water penetration and absorption. Each moulding piece comes pre-primed. The
uniquelexiblepre-primertopcoatstretcheswiththemouldingtominimizecracking.
Onceinstalled,thelexiblemouldingscanbepainted,stained,orfauxinished.
Bayer’sArtwalkmarriesthepracticalwiththebeautiful.Asuccessful marketing
concept,Artwalkinnovativecoatingsisthebrandnameforanewlineofpolyure-
thanerawmaterialsfromBayerMaterialScienceforcreatingindividualandhighly
decorativeloorsforindoorandoutdoorapplications.Amongtheloorcoverings
formulated with Bayer’s Desmodur (blocked polyisocyanates) and Desmophen
(polyether, polyester and acrylic polyol) are cast resin coatings or terrazzo-look
granularrubberlooring.Onedesignadvantagesharedbythesesystemsisthatthey
canbelaidonseamlesslyonsiteandveryintricatedesignscanbeappliedoverthe
40 4 IndustrialEndUseApplications
surfaceandparticularlytothecurvedsurfacesatcolumns,sharpcorners,orirregular
lengthsofwall.Itisalsopossibletocreateparquet-typeinlaysandlogos.Themate-
rialsofferavarietyofuniquedesignoptionstoproduceone-of-a-kindloorsurfaces
thatcanimpartaclearidentity.
Withthelargeassortmentofcolorsavailableforbothsystems,theloordesign
possibilities are almost endless. In addition to the cast resin coatings with their
myriaddesignpossibilities,theArtwalklinealsoincludescoloredgranularrubber
loor coverings. Depending on the system selected, a combination with various
specialeffectadditivessuchasaluminumparticles,glitter,woodpieces,orchipsis
alsopossible.Bothcoatingsystemscanalsobeformulatedtomeetspeciicstringent
functionalrequirements,i.e.highabrasionresistance,mechanicalstrength,color-
fastness, resistance to chemicals, crack bridging, and ease of maintenance. They
adheretoalmostanysubstrate.Bothcoatingsystemsurfacesdeadenthesoundof
footsteps.Anotherimportantcharacteristicistheirhighyellowingresistance,which
ensuresalong-lasting,pleasingappearanceoftheloors.
Hard-wearing granular rubber loors combine optimum creative freedom with
maximumwearresistance.Amixtureofrubbergranulesandapolyurethanebinder
(Desmodur/Desmophen) makes it possible to produce seamless graphic designs.
Thematerialcanbeusedtoachievesmoothandgradualcolortransitions,aswellas
interplaysoflightanddark.Dependingonthecompositionoftherubbergranule/
bindermixture,theloorcoveringrangesfromsoftthroughlexibletoductile.The
polyurethanegranularrubberlooring,byitsverynature,canbeusedtolevelout
signiicantirregularitiesinthesubstrate.Noscreedisrequiredundergranularrub-
berlooring.
BayeristargetingboththepublicandprivatesectorswithArtwalk,inparticular
showcasebuildingssuchaschainstores,restaurants,sportsstadiums,hotels,banks,
insuranceofices,itnessstudios,andilmstudios.Aixtureofthesuccessfulmar-
ketingconceptistheBayerMaterialScienceofferextendedtoarchitectsandplan-
nerstocoordinateallaspectsofprojectimplementation.Projectteamscomprising
designers,formulators,andapplicatorscanbeassembledforeachpropertyandcustom
solutionsdevelopeduponrequest.
Licenses, for the use of SPS technology, have recently been awarded to major
companiesinEuropeandNorthAmerica.
Thehugesteelelementsusedinshipbuildingorbridgestructuresareexposedto
enormous mechanical stresses. In conventional steel construction steel plates are
reinforced with welded-on longitudinal ribs to maximize stiffness and minimize
deformationinaprocessthatrequiresappreciablelabor.Theweldsoftheseribsarealso
typically the irst point of attack for corrosion and fatigue. SPS is a much more
effective,elegantmethodofreinforcinglargesteelcomponents.Theelastomeris
simplyinjectedbetweenthetwosteelplatesinplaceoftheweldedlongitudinalrib
reinforcements. The result is a stiff steel-polyurethane-steel composite, which
dramaticallyreducesconstructioncomplexityandremovesthemajorityoffatigue
andcorrosionpronedetailswhencomparedtostiffenedsteel.SPSstructuresare
lighterandfastertobuildthanconventionalmaritimeandcivilengineeringstructures
andalsoofferbuilt-inprotectionagainstireandvibration.Otherbeneitsinclude
acousticinsulationandimproveddimensionalaccuracy.
CPFilmsInc.istheworld’slargestmanufacturerofsolarcontrolandsafetywindow
ilm for automotive and building applications. The company, with DuPont Teijin
Films(www.dupontteijinilms.com),isjointlydevelopingandmarketingLLumar
MagnumsafetyandsecurityprotectiveilmsmadewithMylarfromDuPontTeijin
Films.Damageandinjuryfromprojectedglasscanbeextensive.Thealliancebrings
technologyandexpertisetocommercialandresidentialmarketstohelpcontrolor
preventdamageandinjuriesthroughexpandedapplicationofwell-designedsafety
andsecuritywindowilm.
LLumarMagnumsafetyandsecurityilmsprovideaprotectivesheathonthe
interiorofglassthathelpsholdfracturedshardsofglasstogethershouldabreak
occur,whetherfromnaturaldisaster,terroristact,vandalism,theft,oraccident.
Themicrothinilmiscomposedofmultiplelayersofstrong,clear,specialgrade
Mylarpolyesterilmandmetallizedcoatingsbondedtogetherwithauniqueadhe-
sivetoformashieldthatholdsglassinplace.Theilmalsoresistsscratchingand
providessolarprotectionbyscreeningoutradiantheat,anddamagingultraviolet
rays, while delecting harsh glare. The security ilms are available in ive
thicknesses:4,7,8,11,and15-mil.The4-mililmsareconsideredtobesafety
ilmsratherthantruesecurityilms.The7-mililm,thestandardsecurityproduct,
offersresistancetobreakage.The8-mililmsofferbothsolarcontrolaswellas
securityprotection,while11-mililmsarerecommendedforhigh-riskareas,such
asstorewindows,andofferssomelevelofprotectionincaseofexplosions,where
thegreatestdangertobuildingoccupantsislyingglass.The15-mililmsoffer
the ultimate in protection in highest-risk areas, and give signiicant protection
fromexplosions.
42 4 IndustrialEndUseApplications
Industrialisoneofthosecategoriesthatcoveralotofterritory–everythingfrom
heavyequipmenttonutsandbolts.Caterpillar,themarketleaderinheavyequip-
ment,saysitsmachinesalesinNorthAmericafor2010rose19%fromayearear-
lier, the biggest gain since 2006. Foreign sales were down 6%, but worldwide
infrastructureconstructionispushingupsalesofequipmentgloballyby7%.Others
servingtheconstructionequipmentsegmentarealsoexperiencingpositivegrowth.
Ingersoll Rand Co. reported strong sales of generators, compressors, and Bobcat
constructionequipment.Inthenutsandboltsendoftheindustrialmarketsegment,
industrialfasteningsystemsareprojectedtogrow5.6%through2011,fueledbya
healthy increase in durable goods production and construction. Strong sales of
higher-performancespecialtyproductssuchasaerospace-gradefastenerswillexpe-
riencethefastestgrowthasmanufacturersreplacecommodityitemswithcustom
designs.Amongthetop45playersinthismarketareIllinoisToolWorks,Textron,
EmhartFasteningTechnologies,SPSTechnologies,Alcoa,andPark-Ohio.
In between heavy equipment and fasteners, industrial conglomerates include
HoneywellInternationalInc.,a$22billionmanufacturerofproductsforbothindus-
trialandresidentialmarkets.Honeywellmakescontrolsforheating,cooling,venti-
lation, humidiication, industrial process automation, and video surveillance, as
wellasaccesscontrolequipment,security/irealarmandindustrialsafetysystems,
and home automation systems in its automation and control products segment,.
Honeywell’s2010earningsgrewbetween9%and17%inallfourofitsoperating
segments. ITT Industries is a diversiied industrial manufacturer whose Fluid
TechnologyandMotion&FlowControlunitsproduceswitches,valves,pumps,and
luidhandlingsystems.ITTexpectsimprovingconditionsinitskeymarketstopro-
vide solid growth opportunities. Tyco International’s Engineered Products &
Servicesbusiness,with2009revenuesof$4.7billion,sawitsmarketsegmentsgrow
in2010.Productsforindustrialprocessequipmentandwater/wastewatersystems
includesuchthingsasvalves,actuators,controls,andthermalcontrolsystems.
CreativePlastics&Design(CPD)hasdesignedandmanufacturedaplasticdeck
pan (patent pending) that replaces the industry standard stainless steel pan used
insiderefrigerated/frozenfoodandbeveragedisplaycases.Thedeckpancreatedfor
refrigerationsystemscompanyHillPhoenixservesasabarrierthatseparatesand
protectsperishablefoodsfromthefreezer’scooling/selfdefrostcycle.Thenewpan,
madefromHDPE,featuresablow-moldeddesignthatoffersgreaterdurabilityand
foodsafetythantheoriginalstainlesssteelpan,whilecuttingprocessingcostsby
67%andweightby30%.
4.3 IndustrialApplications 43
TheCPDdesignfeaturessupportingridgesonthepan’stopandbottomsurfaces.
Addingrigidityanddurabilitytoallsidesofthepan,thenewdesignenablesitto
meetrequirementsforstatic,side,axial,andtorsionalloadsaswellasforimpact
strength.AccordingtoCPD,theHDPEresinselectedwastheonlyplasticmaterial
thatcouldmeetimpactstrengthrequirementswithoutbecomingbrittleandweak
during testing at refrigerator/freezer operating temperatures. The new deck pan
designalsodeliversaninsulationfactorofR-3withoutusinganyfoambackingor
covering.ThenewdisplaycasedeckpanhasearnedNationalSanitationFoundation
(NSF)approvalpermittingcontactwithfoodandcanservenotonlyasabarrierbut
alsoasanattractivedisplayrack,ittingexistingrefrigeratedcases.
Withstricterhygienestandards,concernsaboutpests,andgreaterdesignfeatures,
theplasticpalletmarketisenjoyingglobaldemandgrowthofmorethan10%/year
Atleastfourplasticsprocessesareseeingextensiveuse:injectionmolding,rota-
tionalmolding,single-ortwin-sheetthermoforming,andstructuralfoammolding.
Respondingtodemandgrowth,KigaGmbHhasdevelopedalightweightplastic
palletthatiscostcompetitivewithuntreatedwoodenones.Thesesingleusepallets
madeofrecycledpolyethyleneorpolypropylenearefrequentlyusedtoshipprod-
uctstotheEuropeanUnion,China,Japan,Australia,andothercountriesthatdonot
allowtheentryofuntreatedwoodenpalletsforfearthatinsectsmaybeharboredin
thewood.Singleusepalletsofrecycledplastictypicallycost€5–€6,whilethose
usingvirginmaterialdesignedtomeetextremehygienicstandardsandhigh-strength
requirementscancostasmuchas€50.
Plasticpalletsaremoredurablethanwoodenpalletsinmulti-tripapplications
whereplasticpalletscanoftensurvive100trips,comparedto10tripsforwood.
KigausesrecycledPETforsomepalletsasthematerialisstrongerthanPEandalso
insertsironbarsinotherstoimproveloadstrength.Thecompany,whichbothinjec-
tionmoldsandcompressionmoldspallets,recentlystartedthermoformingacol-
lapsibleversionforChrysler.Collapsibleversionsrequirelessstoragespaceafter
theyhavebeenemptied,animportantpointformanyautomotiveOEMsandother
manufacturers.Thermoformingallowstheuseofmuchlessexpensivetooling–in
therangeof€10,000vs.€250,000forinjectionmoldsandthetoolingcanbemade
in3–4weeks.Butinjectionmoldedpalletscanbemorepreciselymanufactured,an
importantcontrasttowoodenpallets,whichmayhaveknotholesandeventually
sag,warp,orbend.Injectionmoldedunitsshowlittlechangeovertime,andthisis
criticalinmanyirmswhereincreasinglyitisrobotsthatareunloadingpallets.
Quality labware manufacturer, Nalge Nunc International (NNI), an ISO 13485
certiiedworldleaderintheproductionandsupplyoflaboratoryplasticwareforuse
44 4 IndustrialEndUseApplications
in research and educational laboratories, has reduced product and manufacturing
costsintheirlatestlineofdisposablelasks.ThenewNalgenesteriledisposable
lasks,idealforshakerandsuspensioncellculture,mediapreparationorstorage,
combineaninnovativelightweightdesignwiththeversatilityofEastmanChemical’s
PETGplastic,Eastarcopolyester6763,todeliveracosteffective,completelydis-
posableproduct.LowermaterialandprocessingcostsallowNNItoofferthenew
Nalgenesteriledisposablelasksatroughly60%ofthecostofcompetingbrands.
Thelasksareready-to-use,ingammasterilizedindividualpackages.Theyarealso
freefromtheyellowingtypicallyassociatedwithotherpolymerswhenexposedto
gammasterilization.
Designed for disposability, amorphous copolyester enabled NNI to mold an
extremely light weight, thin walled product with the performance integrity of its
heavierpolycarbonatecounterpart.Thereadilydisposablelasksweighonlyafrac-
tion of that of other materials including glass or polycarbonate, making disposal
morecosteffective.Disposabilitygreatlyreducestheriskofcross-contamination,
andthelaskscanbecleanlyincinerated,allowinglaboratoryprofessionalstoreal-
izeprocesseficienciesfrominitialusetoinaldisposal.
Tecan,aleaderintheLifeSciencessupplyindustry,isworkingwithCorningInc.to
offer an innovative microplate handling system for low volume microplate assay
applications.Whilesmallliquidvolumescanbedispensed,theabilitytoworkwith
lowvolumes(lowmlornl)forvariousassayandmolecularbiologyapplicationshas
beenseverelylimitedbyrapidevaporation,especiallyattheelevatedtemperatures
typically required for many types of assays. For these applications, Tecan and
CorningLifeScienceshaveassembledaninnovative,newmicroplatehandlingsys-
tem,whichcombinesTecan’sTe-LidderCOCplasticmicroplatelidhandlingmodule
andCorning’sRobolidtechnology.Thesystemprovidesanidealsolutionforsealing,
unsealing,andresealingavarietyofcommonlyused96and384wellmicroplates.
Tecan’sTe-LidderisaroboticworkstationaccessorydesignedforusewithCorning’s
Robolid,anovelmicroplatesealthatincorporatesasiliconecapmatintoastandard
polystyreneplatelid.Thiscombinationprovideseachwellonastandardplatewitha
liquidtightsealinaformatthatisautomationcompatible.Tecan’sTe-Lidderisspecii-
cally designed for use with Robolid technology on Tecan Workstations and TRAC
RoboticSystems.Thispatentedtechnologyisdesignedforeasyandquickremovalof
tightsealingRobolidsfromawidevarietyof96and384wellplates.
Toreducecostandweight,RTPCompanyteamedwithVolvotodeveloptwotypes
ofVolvotruckbrackets,apairofL-shapedfaringbracketsusedtomechanically
4.3 IndustrialApplications 45
fasten the truck cab’s aluminum grab handle to the truck cab side, and brackets
designedtoholdaroofmountedsatellitedish.Requirementsforthenewinjection
moldedgrabhandlebrackets,whichareprominentlylocatedonthetruck,included
aqualitysurfacethatcouldbetopcoatpaintedwithoutprimertocontrolcost.The
grab handle also had to pass testing in which it was subjected to a 250 lb load,
necessitating a minimum bracket tensile strength of 20,000 psi. In addition, the
material replacing the formerly used metal had to display shrinkage rates corre-
spondingtothoseoftheexistingtool.Thesatellitebracketrequiredalexuralmod-
ulusofatleast1.2millionpsi,andsinceitdidnotrequirepainting,thematerial
would have to withstand chemical and ultra violet radiation exposure of typical
highwayconditions.
Thetruckbrackets,formerlyofbandedsteel,wereinjectionmoldedfromRTP’s
4700Seriespolytrimethyleneterephthalate(PTT)compound,whichcontainsboth
a UV protection package and glass iber reinforcement. PTT is a semicrystalline
polyester,closelyrelatedtothemorecommonthermoplasticpolyestersPETand
PBT,butistypicallyalessexpensivematerial.RTPCo.’snewRTP4700Seriesbal-
ances the physical properties of PET with the processing characteristics of PBT.
ThePTTcompoundsofferstrength,stiffness,andhighheatdelectiontemperatures
ofPET;lowmelt/moldtemperaturesandwideprocessingwindowofPBT;basic
polyesterbeneitsofdimensionalstability,electricalinsulation,andchemicalresis-
tance;andcostsavings.
Agricultural plastics continue to account for just 1.9–2.6% of the total plastics
consumed,intheUnitedStatesandEurope,buttheyhaveavitalroletoplay.Plastics
based agricultural systems provide effective solutions to crop growing: in arid
regions,forexample,plasticspipinganddrainagesystemscancutirrigationcosts
byonetotwo-thirdswhileasmuchasdoublingcropyield.Theagriculturalsector
isalsoasigniicantapplicationforplasticilmusedforsoilconditioning,cropcover
andgrowstunnels.Elsewhereplasticsareusedforpesticideandfertilizerpackag-
ing,andtoproducefarmimplementsandequipment.Plasticsalsoplaysagrowing
roleinanimalhusbandrydisplacingtraditionalmaterialsaswood,andmetalsfor
productssuchasfeedtroughs,wateringtanks,grainbins,andevenhorseshoes.
Land mines pose a lingering threat beyond risks to life and limb. Strewn across
farmlands, mines can cause famine by rendering ields unusable. In cooperation
withCaterpillarInc.,CountermineTechnologiesABhasdevelopedOracle(Obstacle
RemovalandCleanLandEquipment)acompleteuniquedeminingandlandrecla-
mationsystem.
OraclebasedonCaterpillar’sofftherackloaderscosts1/100asmuchasamili-
tarysystemtosetupandrun.ThesystemconsistsofSpitire,amineclearingtool,
whichclearsminesplacedbothinandonthegroundtoadepthof45cm,willin
excessoftheUN20cmrequirement.Thepatentedtooldestroysaminebeforeit
detonates.Mountedonacaterpillar,theSpitiretoolcanclearupto15,600m2/h
withaclearancerateof99.6%.Girdedbysteelplatedarmor,yetemployinglight-
weightRIM,SRIMandrelatedreinforceplasticcompositepartsforinteriorweight
reductionandfueledbyatowalongpowerplant,itusesitsmassivesharptoothed
rotortoshredminesbeforetheygooff,orifnot,tosimplysmothertheexplosion.
Oracle also tills the ground as it traverses the ield so that the land can be used
directly after the mine clearance operation. Farmers welcome Oracle with open
arms,andtypicallythrowtheOracleteamaparty.
Senior&Dickson,aUK-basedmolderandtoolmaker,hasproducedtheirstever
plastichorseshoe.Theshoe,producedonbehalfofLightfootHorseshoesLtd.isa
two-shotinjectionmoldingusingNylon6.6,andaTPEcompound.Inadditionto
4.4 AgriculturalApplications 47
the two plastic compounds, the horseshoe contains a small steel strip, which is
insertedinthemold.
The new plastic horseshoe, the Jameg Sprinter, offers many advantages over
traditionalsteeloraluminum.Designedtobegluedtothehoof,theshoeincludesa
seriesofremovableclipstoaidinittingandauniquerubberliftonthefootside
surfacetohelpcreatethecorrectacrylicadhesivethickness.Nonailsarerequired,
animportantfactorasnails,whichdamagethehoofcanlimitthenumberoftimes
ananimalcanbereshod,andinthecaseofracehorses,thefrequencythatitcan
compete. Equally important, because a horse’s hoof is effectively a polymer, the
nylonshoebaseproducesbothstrengthandlexibility,workinginharmonywiththe
hoof,notagainstit.Onceattached,theshoebecomespartofthehoof,allowingitto
expandandcontractnaturally.UltralightweightandslipresistanttheSprintercan
beittedwithstudsandusedonhorsesinvolvedinarangeofdisciplines.Theyare
lesslikelythansteelshoestocauseinjurytoafallenrider,andareidealforbrood
mares,horsesatrest,andthosewithpoororbadlybrokenfeet.
TheJohnDeere7000Engineenclosureistheirstuseofco-injectiontoproduce
costeffectivelargepartsfromengineeringgradematerialinthickwalls–6mmto
8mm.Molder,BemisManufacturingCompanyaleadingglobalmanufacturerof
diverseproprietaryandcustomplasticproducts,usescoinjectionmolding,allowing
regrindtobeusedinthecoretoreducecosts.ThehoodandsidepanelsoftheJohn
Deere 7000 engine enclosure consist of a skin of polycarbonate/polybutylene
terephthalate,andacoreofregrindABS.Thisconstructionyieldspartswithexcel-
lenthighimpactstrengthandverygoodpartstiffness.Thehoodalsoincludesaone
piecefrontgrilleframeallowingtheentiregrilleandlightsystemtobemountedto
the frame as a module. Each hood assembly contains 15–20 pounds reclaimed
material.Apolyurethanetopcoatisappliedtothecosmeticbodypartsofthetractor
engine enclosure.
Threemoldmakerswereinvolvedtoproducetherequiredmoldsforthetractor
engineenclosureTriangleToolCorporationandToolingTechnologies,Inc.,bothof
Milwaukee, WI, and CDM Tool & Manufacturing of Hartford, WI. The tooling,
madebyTriangleTool,includestwolargecorepulls,foursetsofexpandinglifter
units,andsevencollapsingcoresections.
Systems Europe Srl, a Rome-based European subsidiary of Toro Irrigation, has
developedalargeagriculturalilterthathashighburststrengthandexcellentenvi-
ronmentalresistance.Takingoverayeartodevelop,thenewcartridgeilter,which
48 4 IndustrialEndUseApplications
ispositionedbetweentheinletandoutletsystemsoftheirrigation’smainpipeline
servestocleanthewater,eliminatingdustandotherparticlesandensuringasmooth,
constant,anduninterruptedlowofwater.Theilterconsistsofthreeparts,themain
body,thethread,andthecylinder.
ThecompanychoseZytelfortheirrigationilterasthenylonresinhasexcellent
mechanicalandburststrength,andoutstandingresistancetoultra-violetrays,water
andarangeofchemicalsandfertilizers,evenattemperaturesof80°Cinhotsum-
mersunshine.Theilterinproductliteratureisdescribedasresisting10barpres-
sure,andToro/Irritrolsaysithasresistedextensivetrialsatupto24barpressure,
providingasafetymarginofmorethan2:1.Toro/Irritrolistargetingthishighqual-
ityilteratmid-levelfarmersworldwide.
Morethan7.3millionlbofcropprotection/pesticidecontainerswerecollectedfor
recyclein2010.Thirtymembercompanies,throughtheAgContainerRecycling
Council(ACRC),fundpesticidecontainerrecyclingprogramstocollecttheHDPE
plasticcontainersthroughouttheUS.Ifnotmanagedproperlypesticidecontainers
canposeanenvironmentalhazard.Farmerswerepreviouslyburyingthecontainers
onthefarm,sendingthemtothelandill,orusingthemimproperlytostoreother
chemicals.Facedwithgrowingconcernsaboutthehandlingoftheemptycontain-
ers,farmersandpesticideproducerssawvalueinproactivelycreatingasystemto
addresstheenvironmentalconcernssurroundingpesticidejugsandbottlesbefore
thegovernmenttooklegislativeaction.
Oneofthemostsuccessfulandinnovativerecyclingprogramsinthecountry,the
ACRCrecoversmorethan30%ofthe30+millioncontainersproducedeachyear.
TheACRCpaysforthecollectionandrecyclingofusedcontainersofbothcouncil
members and nonmembers. Containers must be triple-rinsed or pressure washed
beforebeingcollected.Theemptybottlesareinspectedwhentheyarereturnedto
ensurethattheyareproperlycleaned.Somecollectionsitesareoperatedthrough
publicagencies,andmanyarelocatedatcropprotectionproductsdealers.Contractors
often grind the containers at the collection site for easier transportation. Recycle
applicationsarelimitedtononconsumerproductsthatdonotposeasigniicantrisk
ofhumanexposureincludingtheinnercoreofmarinepilings,anddrainagepipe.
Chapter 5
Transportation End Use Applications
Keywords Transportation•Automotive•Thermoplastic•Thermoset•Adhesive
•Glazing•Carboniber•Aerospace•Marine•Boat
Thetransportationindustryisthelargestconsumerofengineeringplastics,bothas
thermoplasticsandasthermosets.Thisindustryisalsothetestinggroundfornew
productsandprocesses,andaleadingindicatorofplasticsusageinotherindustries.
Thesafeandcost-effectivetransportationofpeopleandgoodsisvitaltotheglobal
economy. As modern modes of transportation have evolved to meet increasing
demands for safety, environmental protection, and speed, the use of p lastics in
transportationmanufacturinghasgrownconsiderably.Allformsoftransportation
requireenergytooperateandfuelrepresentsasigniicantpartofoperatingcosts.
Reducing vehicle weight be it cars, airplanes, boats, or trains can cut fuel
consumption dramatically. Used in the service of vehicle exterior parts, plastics
are durable, do not corrode, and require little maintenance. They allow a unique
freedomofdesignandthepartsarefastandeconomicaltomanufacture.Invehicle
interior applications, the various plastics ittings, such as, looring, seats, dash-
boards, and paneling maintain their attractive appearance and are easy to clean.
Durable, lightweight, and corrosion-resistant plastics offer fuel savings, design
lexibility,andhighperformanceatlowercoststodesignersfacingtoday’scom-
plextransportationneeds.
Plasticsplayamajorroleintoday’svehicles.Theautomotiveindustryisthesingle
largestenduserformanyengineeringplastics,suchasnylons(PAs),polycarbonate
(PC),acetal(POM),ormodiiedpolyphenyleneether(PPE).Itisalsoanimportant
marketforcommoditypolymers(e.g.,PP,PE,andPVC).Automakerschooseplastic
partsfortheirdurability,corrosionresistance,toughness,easeofcoloringandin-
ishing,resiliencyandlightweight.Automobiledesignersalsodiscoveredthatplas-
ticssolveoneoftheirmostcomplicateddesignproblems:whattodowiththefueltank.
Usingplasticgivesthemthefreedomtoittanksintotheoverallconceptratherthan
designingaroundtheunwieldybutessentialpart.Moreplastics,byvolume,thansteel
arenowusedintoday’scarsforamyriadofcomponents.Attheendofavehicle’s
workinglife,plasticscomponentscanberecycledortheenergycanberecovered
through incineration. Plastics versatility aids the automotive industry in meeting
evermorestringentrequirementsintermsofeconomicalperformance,safety,com-
fort,andenvironmentalconsiderations.Recentindustryestimatesexpecttheuseof
engineering thermoplastics in exterior automotive applications to grow by 4.8%
annuallythrough2011,whichwouldequatetoatotalofmorethanonebillionlb/
year.By2012,theigureisexpectedtoclimbto1.3billionlb.
SolvayAdvancedPolymers,LLC,asubsidiaryofSolvayAmerica,Inc.,produces
high-performancepolymersthatareusedinawiderangeofdemandingapplications
includingautomotive.Severalrecentautomotiveunder-the-hoodapplicationdevel-
opments have expanded the use of Solvay’s high-performance polyphthalamide
(PPA)inthismarketsector.
Carburetorexpert,WillyKrup,developedauniquefuelpickuptubeforusein
oval track racers, where the nearly constant left turns otherwise push fuel to the
rightsideofacarburetor’sloatbowl,reducinglowtothejetsthatfeedthecylin-
dersontheleftsideoftheengine.Krupinnovatedafuelpickuptubethatreturns
thiserrantfueltothefuelmeteringblock,assuringconstantlow–andconsistent
power – through even the fastest turns. When the large amounts of machining
requiredtomakethepartsinaluminumwasdemonstratedtobecostineffective,the
designerturnedtoplasticforanaffordablecompositesolution.AmodelAS-1133
HS, a heat stabilized, glass reinforced PPA that combines a high heat delection
temperaturewithhighlexuralmodulusandhightensilestrengthprovedtobeupto
thetask,whenmoldednylonfailedtostanduptotheheat/coolcyclesandcorrosive
alcoholfuelencounteredintheraceenvironment.
Inotherareas,anewcoatingdesignatedIC-105,developedbyTechLineCoatings,
Inc. of Murrieta, CA, is expanding the window of opportunity of PPA in high-
temperatureunder-the-hoodapplications.Thecoatingprovidesthermalrelectivity
whenappliedtothesurfaceofpartsmadeofPPA.Thecompanyspecializesincoatings
5.1 AutomotiveApplications 51
forthehigh-performanceautomotivemarket.Thenewproductbasedontechnology
usedinitsICfamilyofcoatingsformetalsistheirstdesignedbyTechlinespecii-
callyforapplicationtoplastic.Intesting,PPAsampleplaquescoatedwithathin
ilmofIC-105weresubjectedtodirectcontactwithaheatsourceat600°F.After
extendedexposure,thetemperatureoftheplasticinthesamplesremainedatapprox-
imately400°F.
The190–200°Fdifferentialissigniicantforplasticssuchaspolyphthalamide,
polyamides,oramide-imidesthatareintendedforuseincomponentsofanauto-
mobilepowertrain.Whiletheseplasticshaveexcellentqualities,almostallbegin
tolosetheirprimarycharacteristicsabove500–550°F.Advancesinenginetechnol-
ogy,fuelmanagement,andemissionsrequirementscontinuetodriveupunder-the-
hoodtemperatures.Wherethesetypesofplasticswereadequateafewyearsago,
todaythatisnolongerthecase.Atypicalexampleistheengine’sair-induction
systemwherematerialssuchasAmodelPPAarereplacingaluminum.Incontact
with high-temperature air, the end tanks surface of the turbocharger air cooler
housingcanundergooxidationthatcancontaminatetheturbochargersystem.The
IC-105coatingtechnologyimprovesthewindowofopportunityforAmodelgrades
tobeusedinhigher-temperatureapplications,notonlyasareplacementforalumi-
num, but as an alternative to much more expensive polymers such as PEEK
(polyetheretherketone).
Solvay’s PPA has also been speciied in the irst known composite automotive
performanceaftermarketmanifold.AmodelA-6135PPAwasspeciiedforthenew
LSX air intake manifold engineered and designed for performance parts provider
Fuel-Air-Spark Technologies (FAST). FAST wanted a part that outperformed the
stocknylonmanifold,butwasnotsubjecttotheweightandheatpenaltiesimposed
byanaluminumreplacement.TheLSXmanifoldwillreplacethestockairintakethat
comeswiththeeight-cylinderenginesintheChevroletCorvette,andCamaroaswell
asPontiac’sFirebird.UsingA-6135,designerswereabletoincreaseairlowby25%
andmaketherunnerslongertomaintainlowendtorque,therebyadding20hptothe
360availablefromtheV-8stheLSXisdesignedtoit.Turboorsuperchargersele-
vatemanifoldpressuresomaterialstrengthisalsoimportant.Flexuralmodulusof
theA-6135isatleast20%greaterthanthatofnylon6or6/6,andoffersgreaterresis-
tancethannylontotensilecreep,whichcouldcauseairleakageatthemanifold’s
gaskets.A-6135alsohasthechemicalresistancerequiredinunder-the-hoodapplica-
tionsandismoreresistantthannylontodegradationfromnewlong-lifecoolants.
DowAutomotive’snewLESAadhesive(LowEnergySurfaceAdhesive)technology
hasenabledthedivisiontointroduceinnovativeandcost-effectiveconstructionof
front-endsystems.Thenewapproachaddressesindustryneedsforimprovedquality
andperformancewhilecuttingcostsandreducingweight.LESAisatwo-partsystem
thatcuresatroomtemperatureinthepresenceofoxygenfromtheair.Opentime
52 5 TransportationEndUseApplications
aftermixingcanbevariedfrom2to15min.Bondedassembliescanbehandled
afterafewminutes,thoughfullcuretakes24h.
Thenewfront-endsystemproducesanadhesivelybondedtwo-piececonstruc-
tionfront-endcarrierthatallowsmaterialsandmanufacturingprocessestobeopti-
mizedwithreducedmanufacturinginvestment.LESAcanbondsimilarordissimilar
substrateslikeplastictoplasticorplastictometalwithouttheneedofaprimer.The
modiiedfront-endcarrierlowersthemassofmetalandplastictoreducecostwhile
LESAaddsstiffnessandoveralldurabilitybyreducingfatigueandfailureofspot
welds and other traditional fasteners. Structural noise is also reduced using the
adhesive by limiting vibration caused by mechanical fasteners and spot-weld
fatigueimprovement.Thisnewapproachintegratesadvancedadhesivetechnology
withuniquedesignofaplastic(polypropylene)moldingandmetalreinforcement.
Theadhesivetechnologyenablesacontinuousbondbetweentheplasticandmetal
partforaddedstiffnesswithoutpre-treatmentofthesubstrates.Thedesignincorpo-
ratesaclosedboxsectionnotpossiblewiththetraditionalovermoldingtechnique,
enablingmaximumstiffnesswithminimumweight.
OneoftheleadingdevelopersofopticalplasticsforautomotiveglazingisFreeglass
GmbH, a joint venture between glassmaker Saint Gobain and plastics processor
Schefenacker,aspecialistinexteriormirrorsandlighting.Inadditiontotherear
sidelitesforDaimlerChrysler’sSmartFortwocoupeandSmartroadster,thebusi-
ness is also producing four polycarbonate glazing components, including a 1 m2
sunroofforthe4-doorSmartForfoursedan.
Freeglass has invested in Krauss-Maffei swivel platen machines for multi-
componentinjectionmolding.TheKrauss-Maffeiexpansioncompressionmolding
process, combined with swivel platen technology, makes it possible to produce
largeareapartsvirtuallyfreeofinternalstresses.Postmold,thesurfaceofthePC
partsarecoatedforultravioletandscratchprotection.Theplasticsunroofmoduleis
7 lbs lighter than an equivalent glass module when the frame is integrated. This
weightreductionlowersthevehicle’scenterofgravity,helpingtoimprovedriving
characteristics. The technology also opens the opportunity for innovative design
andtheintegrationofvariousfunctionalelementssuchaslightingsystems.
RoofappliquésarebeingmoldedfromDuPontRynitePETthermoplasticpolyester
resinfortheSaturnVUEsportsutilityvehicle.Theappliquéslongcurvedexterior
partsareattachedtothemetalspaceframeabovedoorsandbehindrearsidewindows.
Whileprovidingainishedlook,theyalsohelpchannelrainwaterawayandprovide
arigid,smoothsealingsurfacefordooredgeweatherstripping.
5.1 AutomotiveApplications 53
SaturnspeciicationsfortheappliquécallforaClassAinishA,ademanding
surfacequalityspeciicationforpartsthataretobesubsequentlypainted.Thepainted
Rynitegivestheglossrequiredtomatchtheotherexteriorsurfacesofthevehicleat
signiicantly lower cost than the alternatives. SMC or metal parts would require
extensiveinishingstepspriortopartpainting,whileSaturn’sRynitePETappliqués
requireonlyminimalsurfacepreparation.Thematerialwithitsdimensionalstability,
low coeficient of linear thermal expansion and warp resistance also meets the
consistentitrequirement.Theappliqués,whicharesubjecttohighthermalloadin
sunlight,resistheat-relatedexpansionandwarping.Atmospherichumidityalsohas
noeffectonthedimensions,strength,andtoughnessofthematerial.RyniteRE5309,
which contains glass iber and mineral reinforcements, has excellent stiffness, a
crucial factor to assure irm door sealing. Molded-in screw holes in the appliqué
eliminatetheneedfordrillingandallowprecisionittingtothespaceframe.
Carboniberisappearingonconceptcarsatbothendsofthemarket.Whilethe$15/lb
priceofcarboniberversusamarketrequirementof$5/lblimitswideacceptance,
itshighstrength,lowweight,andprestigemakethematerialattractive.Intermsof
prestige,atthehighendofthemarket,Chrysler’sconceptMEFour-Twelvesports
car,whichifproducedwouldsellforover$100,000,hasacarboniber/aluminum
body,andcarboniberisalsousedfortheseatstructureframe.Attheotherendof
themarket,Chryslerislookingatthematerial’slightweighttosqueezemorethan
45mpginfuelusagefromitsSlingshotconceptvehicle,asmallcitycarbasedon
theEuropeanSmartroadster.Fornow,however,thecomposite’shighcostwillnot
permititsuseinavehicleintendedtosellforunder$20,000.
Whilefewconceptcarsmaybecommerciallyproducedwithcarboniber,itsuse
concept applications shows there is growing interest in the material. Many from
compositeexperts,touniversitiesandautomakersarestudyingwaystomakethe
materialmoreeconomical.Thoughtherawmaterialcostisdropping,thereisasyet
no way to mold carbon iber in high enough volumes to production costs. Auto
companiesarecurrentlymakinglimiteduseofthematerialstrategicallyplacingit
whereitisneeded.Meanwhile,companieslikeMeridianAutomotiveSystems,a
keyNorthAmericanproducerofsheetmoldedcomposites(SMC),areworkingto
lowerthecomposite’scost.
Atopofthelinecarisnowequippedwithanaverageoftenantennae,andthat
numberisexpectedtosoonincreasetoasmanyas16ascarmanufacturersintro-
duce systems for monitoring and automatically regulating the distance from the
54 5 TransportationEndUseApplications
vehicle in front, and install warning sensors to avoid collisions when reversing.
These numerous antennae have been generally spread over the entire bodyshell,
presentingachallengetodesignerswhohavetoguaranteeoptimumreception.
A new antenna module developed as a joint project by Johnson Controls and
Volvodemonstratesawayroundtheproblem.Themoduleaccommodatesallthe
antennae and relevant receivers (radio, TV, GPS) in one unit. Made of steel and
DurethanBM130H2.0polyamidesuppliedbyBayerMaterialScience,itismanu-
facturedusingtheplastic/metalhybridtechnologyalreadyestablishedforproduc-
tionofvehiclefront-ends.
The1.8-kgantennamoduleislocatedunderaplasticcoverontherearroofof
theVOLVOXC90SUV.Theantennaeareintegratedintoailmthatformspartof
the plastic cover. The various ixing elements and backing for the ilm, which
extendsacrossthewidthofthevehicle,arealsomadeofpolyamide.Thereceivers,
such as the FM/AM, Digital Audio Broadcasting (DAB), and TV tuners, are
screwedtothemetalsupportofthehybridconstructionobviatingtheneedfora
largenumberofcables.
NorthAmerica’sirsthigh-volumethermoplasticvalvecoverwasintroducedonthe
ChryslerTown&Country,DodgeCaravanandGrandCaravanwith3.3and3.8LV6
engines. The valve cover, manufactured by Bruss Sealing Systems from DuPont
Minlonmineralreinforcednylon,reducesweightbymorethan65%andcutscost
signiicantlycomparedtometal.Theinnovativethermoplasticvalvecoveralsohas
anintegratedair/oilseparator,whichsigniicantlyreducestheamountofoilpulled
intotheengineandanintegratedpositivecrankcaseventilation(PCV)valvehousing,
whichhelpsreduceevaporativeemissionstoreduceenvironmentalimplications.
AChrysler,Bruss,andDuPontEngineeringPolymersteamensuredthisprogram
went from CAD drawing to commercial launch in less than 22 weeks ensuring
introductionforthecurrentvehiclemodelyear.Thevalvecoverismadeofglass/
mineral reinforced Minlon that has a balance of stiffness, strength, dimensional
stability,andwarpageresistance.Theswitchfrommetaltothermoplasticeliminated
costlye-coatingandseveralsecondarymachiningsteps.Runnersandscrapfromthe
injectionmoldingmanufacturingprocessaremeltrecycled.
Demandforlongiberreinforcedthermoplastic(LFT)compositesinautomotive
applicationsiscontinuingtogrow,particularlyinEurope.Unlikeconventionalshort
iberreinforcedmaterials,thelongeribersinmoldedpartsmechanicallyinteract
witheachothertoformaninternalglassiberskeletonthatlimitsanisotropicshrinkage
andgreatlyreduceswarpage.Thecompositematerialswithhighstiffnessandlow
weightareexcellentmetalreplacements. Thehighleveloflongglassibersalso
givesthemmetal-likecoeficientsofexpansion.Anylonbasematerialilledwith
50%glassiberhasexcellentresistancetoautomotiveluidsandcantoleratethe
high-temperatureexposuresofthisapplication.
5.1 AutomotiveApplications 55
SABICproducesStamaxPpolypropyleneLFT,amaterialwithgoodthermal/
mechanical properties suitable for semistructural applications. It is used to mold
front-end modules on the Porsche Cayenne, VW Touareg, and Mini Cooper.
Meanwhile, LNP Engineering Plastics’ Verton MFX, a 40% LFT PP is used to
injectionmoldMazda6frontendanddoormodules.
Ticona’sCelstran30%LFTisusedtoproducedoormodulesanda50%illed
nylon6/6Celstranisusedinthegrilleopeningretainer(GOR)oftheJaguarXJ.
DuPontRynitePETpolyesterresinisusedtomoldaGORfortheLincolnNavigator
andFordExpedition.Thematerial’shighresistancetoheatsagallowsittowith-
standFord’se-coatingcuringprocess.Frontendcarriersof40%glassiber/PPare
producedbytheFaureciaGroupinFrance.Thesecomponentsareproducedwitha
Krauss-Maffei IMC machine, which compounds the formulation on a twinscrew
extruderyokedtoaninjectionmoldingmachine.
FordMotorCo.istakingalighterapproachtodesignwithitsGloCarconcept.The
caruseslightemittingdiodestochangebodypanelcolor,andbrightnessinresponse
56 5 TransportationEndUseApplications
tosafetyconditionsanddriver’swhim.Launchedlastyear,theconceptcarison
display at the Cooper-Hewitt, National Design Museum as part of its exhibit
‘National Design Triennial: Inside Design Now.’ The customizable GloCar was
designedtobesafe,fun,andevokeemotion.Illuminatedbytranslucentbodypanels
andLEDlights,thesoftglowingvehicleoffersenhancedvisibility.Anadditional
safetyfeaturestemsfromthefactthatthecarcanbeseenfromallangles,notjust
headlightsandtaillights,makingitveryvisibleatnight.Therearpaneldoublesasa
brakelight,andthesidepanelsasblinkers.Whensomebodycomestooclose,the
panelsincreaseinintensity,signalingthedrivertokeepadistance.
TheGloCarlightingcombinedwithinjectionmoldingcanpotentiallyeliminate
the need for vehicle paint, reducing manufacturing complexity. The concept car
projectsanimageofconcern,safety,intelligence,andlightness.Builtasadesign
exerciseitfocusesontheprospectiveneedsofdriversandshowsafuturewherecars
aremoreoptimisticandintelligent.Thevehicle,poweredbyfuelcelltechnology,is
built around a lightweight aluminum space frame with aluminum extrusions and
castings.Therearenoplanstoproducethecar.
Duringthepast50years,aeronauticstechnologyhassoared,withplasticsplayinga
major role in aircraft, missile, satellite, and shuttle development for civilian air
travel,militaryairpower,andspaceexploration.Plasticmaterialscanbelexible
enough to withstand helicopter vibration but rigid enough to ensure safe cargo.
They can be transparent for easy observation, shatter resistant and offer ballistic
protection, and, most signiicantly, they can be both lightweight and strong.
Aerodynamicrequirementsofaerospaceproductsdemandmaximumdesignlexi-
bility and minimal weight. Plastics can be formulated to meet a wide variety of
speciicationsandareidealforcomponentsincorporatingsmoothcurves.Composites
arewidelyusedinthepanelsofmilitaryjetsandhelicoptersaswellasforwing
skins,nacelles,fairings,lapsandhelicopterrotor-bladesincommercialapplications.
Plasticsarealsofoundthroughoutaircraftinteriorsinbulkheads,galleys,stairunits,
seating,andlooring.
Asinconventionalaircraft,minimizingweightisimportantinthenewunmanned
airvehicles(UAVs).Some,suchasNorthropGrumman’sGlobalHawk,aredesigned
forprolongedlightsathighaltitude.Cruisingatextremelyhighaltitudes,Global
5.2 AerospaceApplications 57
Hawkcansurveylargegeographicareaswithpinpointaccuracy,togivemilitary
decision-makersthemostcurrentinformationaboutenemylocation,resources,and
personnel.AlthoughGlobalHawk’sfuselageisaluminum,mostofitsotherstructures,
includingcertainfuselagecomponents,arecomposite.Lowairframeweightmeans
thathalfthe25,600lbmaximumtakeoffweightisfuel,providing34hoflight.The
UAV’swing,longerthanthatofaBoeing737,comprisesfourI-beamsparsand
prepregfacesheets,withcarbon/epoxysparsandenvelopebondedtogether.Leading
andtrailingwingedgesareNomexaramidhoneycombcoredsandwichlaminates.
M.C. Gill Corp delivered to aircraft manufacturer Airbus Industrie in Toulouse,
France,theirstsetofanewtypeofcompositehigh-performanceloorpanelsfor
theA380cockpitandtwoelectronicequipmentbays.Thecompletesetconsistsof
67partsfabricatedfromGillfab5509panels,whichwerespeciicallydesignedfor
thisapplication.Thesehigh-performancecompositeproductsarelowsmokeaircraft
sandwichpanelsofaKevlarhoneycombcore,withfacingsmadeofphenolicresin
reinforced with cross-plied unidirectional carbon and a thin iberglass overlay to
protectagainstgalvaniccorrosion.
TherawstockpanelsweredevelopedandmanufacturedattheM.C.GillCorporation
headquartersfacilityinElMonte,CA,thendetailedattheM.C.GillEuropeplant,
whichhasextensiveknowledgeandexpertiseindetailingcomplexloorpanelsfora
range of aircraft and customers. Detailing activities included drilling, machining,
folding, and fabricating the panels into precise conigurations to meet engineering
speciications.Theequipmentbaypanelsweretreatedwithanon-slipsurface.
VirginAtlantichasunveiledtheGlobalFlyerV.Thepioneeringaircraft,saidtobethe
world’smosteficientjetplane,achievedtheirstsolo,non-stoparoundtheworld
light.Ifsuccessful,theaircraftwillcompletethe80hvoyageononetankoffuel.
VirginAtlanticisthesponsorthe38.7footlong,singleenginejet,witha114-foot
wingspan.ScaledCompositesspentmorethan4yearsdesigningandbuildingthe
aircraft.Thecompanyusedcomputeraidedaerodynamicstudiesandbuiltthestruc-
tureentirelyfromultra-lightcarbon,Kevlar,glass,andacombinationofreinforced
epoxyandpolyestercompositematerials.
On takeoff, the plane will weigh 22,000 lbs, with over 84% of that weight
beingfuelandlessthan80hand23,000mileslater,itwillhaveshed18,000lbs
to land at its dry weight of a little under 4000 lbs. The GlobalFlyer’s 3-body
coniguration (twin-boom fuselage, and seven foot cockpit pod) spreads the
aircraft’s weight across the wing reducing the peak bending load and aircraft
58 5 TransportationEndUseApplications
weight.ThelightwilltakeofffromtheUS,inearly2005,lyingat45,000ftand
traveling 21,300 miles (with jet stream) at speeds in excess of 985 mph. On
completionofthetrip,GlobalFlyerwillhavetraveled75%furtherthantherange
recordsetforjetpoweredplanes.
Sincethestartofmannedspacelight,DuPonthasbeenprovidinghightechmaterials,
essential for lighter weight, reduced volume, durability, and environmental resis-
tance. Dupont Electronic Technologies have a broad range of advanced circuit
materials,manyMarstestedontherecentrovers,SpiritandOpportunity.
SeventyyardsoflexiblecablecircuitsmadeofthinDuPontPyraluxlaminates/
compositesreplacedbulkyroundcablestosave60–70%volumeineachMarsrover.
The Pyralux lexible circuits connected each rover ‘brain’ to their robotic arm,
cameras,highgainantenna,wheels,andsensors.Pressuresensitivetapemadefrom
DuPontKaptonpolyimideilmwasusedthroughouttocontrolvibration.Pyralux
lexiblecablessecuredwithKaptontapeoffereddurable,lightweightenvironmental
resistance at Mars temperatures of –120°C to 22°C. Hundreds of Kapton strip
heaterswereusedtomaintainminimumtemperaturesintheextremelycoldmartian
atmosphereandallowtheroverstousesmallersolarpanelsandbatteries.Kapton
ilmworkedwithlayersofDuPontTelonluoropolymerresinandPyraluxlexible
cables to provide power from the Rover electronics module to hardware compo-
nents.Thelexiblejointsoftheroboticarm,whichhadtowithstandrepeatedbending
inextremeenvironments,usedKaptonandPyralux.Kaptonstripheaterswerealso
wrapped around motors on the robotic arm to keep them running at optimum
temperature and eficiency. Metallized Kapton was used in thermal shielding for
heat-sensitivecomponents.Theairbagsusedfortheroverslandingswerethreaded
andreinforcedwithDuPontKevlariber.
Thesameplasticfoamtechnologydesignedformanufacturingsurfboardsisbeing
appliedtothestructuralcorematerialforwingsoftheX-45Aunmannedcombat
aerialvehicle(UCAV).CentraltotheFoamMatrix’technologyisaunique,patented
processforproducingnetmoldedstructureswithouttheneedformulti-pieceassemblies.
FoamMatrix’highlyintegratedstructuresreplacethelargenumberofindividual
partsusedin‘traditional’aircraftmanufacturingwithasinglecomponentthatsatisies
the requirements. Using the irm’s ‘Foam Matrix Core’ (FMC) system for the
X-45A,theribs,stringers,electricalconduit.andotherwingpartsaremachinedinto
asinglemoldtool.Theentirewingismoldedasaone-piecefoamcore.Oncuring,
thefoamcoreiswrappedincompositeibersandreturnedtotheFMCmoldtoolfor
resininjectionandinalcure.
5.2 AerospaceApplications 59
TheFMCsystemreducespartscount,providesseamlessconstruction,reproduc-
ibility,shorterproductioncycletime.andlowercost.Useofthefoamalsoeliminates
structure hollow cavities, improves damage resistance in handling/assembly, and
reducesthepossibilityofdelamination.Astheskinsarebackedbythefoam,ield
repairsareeasier.Boeingfoundthehigh-strengthlightweightconceptprovidedan
attractivealternativetoconventionalwingdesigns.PhantomWorks,Boeing’sR&D
unit, has built several X-45A UCAVs under a $191 million agreement with the
DefenseAdvancedResearchProjectsAgencyandtheUSAirForce.Thewingsare
designed to be removed from the fuselage, and the disassembled aircraft can be
storedforupto10years.
EclipseAviation’snewsix-seaterairtaxismayboastasafetyfeaturenojetlinercan
match:aparachutelargeenoughtoloattheplanetothegroundintheeventofan
in-airemergency.Eclipseiscreatingthesix-seaterlowcost/luxuryairtaxistotrans-
form business travel. Ballistic Recovery Systems (BRS) has a $600,000 SBIR
(SmallBusinessInnovativeResearch)awardfromNASAtodevelopaparachutefor
six-seatjetairtaxis.
Originallydesignedforlighterweightultralightsandexperimentalaircraft,BRS
hasachievedthetechnologicalabilitytodevelopparachutesystemsforconventional
aircraft.ThejettaxiparachutewillbeascaledupversionofthechuteBRSalready
suppliestoCirrusDesignforitsfour-seaterpropellerplanes.BRS’uniqueproprie-
taryemergencyballisticparachutesystemisdeployedwithasolidfuelrocketmotor.
Thesystem,whichmakesuseofextremelylightweightnylon/polyesterfabricand
components, is pressure packed under 40,000 pounds of pressure. The resulting
packagecanweighaslittleas15pounds(ultralight),45pounds(Cessna150),or
67pounds(Cessna172).Chutesystemattachestotheairframeatthreelocations,
twoattheleadingedgewheretheleadingedgemeetsthefuselageandoneaftofthe
baggagearea.Costofatypicalsystemisgenerally5–10%ofthevalueoftheaircraft.
Avemco,theleadingaviationinsuranceunderwriter,grantsadiscountoninsurance
premiumsforthosepilotschoosingtolywiththeBRSsystem.
Boeingisintroducingaseriesofinnovativefeatureswithitsnew7E7‘Dreamliner’
airplane,frominitialconceptandnametodesign,interiors,materialsofconstruction,
and inal assembly processes. The plane, recently introduced to customers, is
expectedtobeavailableforservicein2008.Thenewsupereficientjetlinerwillbe
theirstcommercialjetlinertohavethemajorityofitsprimarystructure,including
wingandfuselage,tobemadeofcompositesratherthanaluminum.Theredesigned
60 5 TransportationEndUseApplications
interiorwillfeaturedynamiclighting,largerlavatories,morespaciousluggagebins,
andelectronicwindowshadeswithadjustabletransparency.
The company conducted extensive analysis before choosing, a carbon/epoxy
compositefortheprimarystructureandatitanium/graphitecompositeforthewings.
Compositesofferednumerousadvantagesincludingbetterdurability,reducedmain-
tenance requirements, and increased potential for future developments. Boeing
believesthechoicewillhelpthemtotakeadvantageofthemostmodernmaterials
technologiesasitstartsintothesecondcenturyoflight.TorayIndustries’Torayca
prepreg composites will be used in the primary structural areas. This material, a
combinationofhigh-strengthcarboniberandtoughenedepoxyresin,hasbeenused
ontheBoeing777instructuralapplicationssuchastheempennageandloorbeams.
Projectedtobe20%morefueleficientthancurrentjets,the7E7and7E7Stretch
willcarry200–250passengersonroutesofupto6,600–8,000nauticalmiles.
Becausetheyprovidesuperiorweighttostrengthratiosandresistweatherandsalt-
watermuchbetterthanmetalorwood,plasticshavefoundnumerousapplications
in the marine industry. The real plastics revolution in boatbuilding began in the
1940s,wheniberglasshullsmadetheirdebut.Boatsweresleeker,betterlooking,
morefueleficient,moremaneuverable,andeasiertomaintain.Today,boatbuilders
looking for strength and lighter weight turn to plastics for sails, rudders, dagger
boards,centerboards,slats,sparsandwings,aswellashulls.Compositeuseinthe
nauticalworldgainedconsiderablenoticewhenAmerica’sCupentriesbeganusing
advancedcompositesinfuturisticdesignsforbothhullsandmasts.Today,compos-
itesandotherplasticsindwideapplicationbothonandbelowtheseainapplica-
tionssuchaspersonalwatercraft,jetboats,sailboats,sterndriveboats,outboard
boatsandinboardboats,divingequipment,offshoreplatforms,aswellascommer-
cialandmilitaryvessels.
Afterinvesting5yearsand$100millioninitsnewlineoflarge,4-strokeoutboard
engines, Mercury Marine’s sleek new ‘Verado’ outboard engine cover is a real
winner.Besidesvisualappeal,theengineincludessometechnicalinnovations.In
comparingcompressionmoldedSMC,thermoforming,RIMandinjectionmolding,
thedesignteamfoundthatinjectionmoldingwouldaffordgreaterdesignlexibility,
parts integration, lower costs for assembly and paint, lower overall weight, and
higheryields.
5.3 MarineandBoatApplications 61
Theuppercowlisthelargestinjectionmolded,glassreinforcednylonpartever
made.Itweighs11lbs,20%lessthanifmadefromMercury’straditionalmaterial,
compressionmoldedSMC.Thecombinedupper/lowernyloncowlsweigh30%less
thanwithSMCandcost46%lessthanSMCmodels.Theenginecoverhastobe
structurallysound,abletowithstandhittingaloatinglogwhiletravelingat40mph.
Thedesignteamspent18monthstocomeupwithanaggressive,powerfuldesign
fortheVerado.Injectionmoldingallowedadditionaldesignfreedom,givingcrisper
edgesandahighglosslookonsomeofthepartsoutofthemoldsotheywouldnot
havetobepainted.Theinalcowlingdesignconsistsoffourprimaryparts,thetop
cowl,rearcowl,astructuralrib,andfrontcowl,alongwithtwomatingpartsthat
comprise the lower cowl. Glass illed nylon 6/6 is used for the top, rear, and rib
members,whilstthefrontismoldedfrommineral/glassillednylon.Themassive
635lb,4-stroke,275horsepower(200,225,250hpalsoavailable)engine,Mercury’s
irstsuperchargedoutboardfortheconsumermarket,willretailforabout$18,000.
GenmarHoldings,Inc.introduceditslatesttechnologicalinnovation,theWindsor
Craft pontoon, at the Minneapolis Boat Show. The pontoon market segment has
grownmorethan50%duringthepast5years.Genmar,theworld’slargestbuilder
ofrecreationalboats,isproducingthemostlyrotationalmolded24fttri-hullpon-
toon from more than 2,600 lbs of polyethylene. Unlike a traditional pontoon’s
aluminum hull, the PE withstands saltwater, alleviating concerns about saltwater
corrosion. The tri-hull pontoon boat, constructed using the company’s patented
Ropleneconstructionprocess,featuresalifetime,limitedwarrantyonthehulland
enhancedperformancecharacteristicsprovidingbig-waterhandlingwhileoffering
alevelofcomfortandstylepreviouslyunavailableinapontoonboat.
Ropleneisapatenteddual-wallconstructionsystemmadebyrotomoldingmarine-
gradePE.ThisadvancedtechnologywasdevelopedbyGenmarsubsidiaryTriumph
BoatsandallowsGenmartobuildhigherquality,strongerboatswithlimitedlifetime
warrantiesatalowercosttotheboatingconsumer.LLDPEisusedforthethreehulls,
fold-upcabana/changingstation,consoleandbasestructure;high-densityPEisused
fortheloorandsides;andcross-linkedPEforthefueltank.
SingleBuoyMooringsofMonacoisusingPTFEilledVictrexPEEKpolymerto
overcomecorrosionproblemswithbronzebearingandthrustwashercomponents
usedinthecompany’ssubseamooringsystems.Thecompanyisamajorsupplierof
loatingproduction,storage,andofloadingsystems(FPSOs).Designedandmolded
by3P/EGCofTexas,thepolymerbearingsandthrustwashersinthemooringand
62 5 TransportationEndUseApplications
drivingchainsystemshaveanextendedservicelife,signiicantlylessweight,and
excellentloadbearingcapabilitiescomparedtothoseofthebronzeparts.
Corrosion resistance in subsea environments is of particular importance since
theseplatformsareconstructedinopenorunprotectedwatertofacilitatethemooring
oftankersatoffshoreoil/gasexplorationstationsthathavenojettiesandbreakwaters.
Unlike bronze components, which can develop severe galvanic corrosion, PEEK
bearings and thrust washers provide long-term corrosion resistance and superior
wearresistance.Thebronzepartsaresubjecttoprematurewearandreducedservice
lifeshouldtheyrundryunlikePEEKparts,whichrequirenoexternallubrication.
ThePEEKmaterialalsoprovidessigniicantweightsavings,importantasthemooring
bearingsandthrustwasherscanbeupto50cmindiameter,withwallthicknesses
ofupto5cm,andareextremelyheavyanddificulttohandlewhentheyaremade
ofbronze.3P/EGChasdevelopedatailor-madeprocesstomoldthelargePEEK
polymercylinderswithoutdefects.
Ideallysuitedtotherotationalmoldingprocess,rotationallymoldedkayaks,essen-
tiallyhollowparts(withaholecutforthepersontoenter),haveastrongpositionin
thesmallmarinecraftmarket.However,iberreinforcedplastickayaksalsomaintain
agoodmarketposition.Competitionissimilarlyvigorousbetweenrotomoldedand
FRPcanoesaswellasothersmallboatsuptoabout20feetlong.Rotomoldedboats
areabletochallengeFRPprimarilythroughpricewitharotationalmoldedkayak
sellingforroughly60%ofthepriceofanFRPkayak.
Rotomolding is easier to automate and, while cycle times are long, they are
measurablylessthanFRPcuretimes.Polyethylenerawmaterialcostsarealsoless
thanthoseofFRP,andPEpartshavehigherimpacttoughness,astrongsellingpoint
forsmallrotomoldedwatercraftoftenusedinruggedenvironments.Ontheother
hand, small FRP watercraft have a better surface inish/color and are capable of
moreinnovativedesigns.RepairisalsoproblematicfortherotomoldedPEboats,
requiringnon-aestheticthermallyweldedpatches.Additionally,FRPpartscanbe
made stiffer allowing lower wall thickness and all important lower weight. To
increasestiffness,PEwatercrafthaverecentlybeensuccessfullyrotomoldedwitha
doublehullandfoamedinterlayer.
ManyofNewYork’sHudsonRiverpiers,builtwithwoodenpiles,aremorethan
50 years old, have become corroded, and are losing their structural integrity.
Additionally, with signiicant improvements in the river’s water quality, wood
boringworms,whicheatthroughthewoodenpiles,arethrivingintheriver.
5.3 MarineandBoatApplications 63
Thesecorrodedwoodenpiersupportsarebeingrestoredusingmorethan1½miles
ofiberreinforcedplastic(FRP)sleeving.MFGConstructionProductsCo.,aleading
supplierofcompositeproductstotheconstructionindustry,producedthesleeves
neededfortherestorationusingageneralpurposepolyesterresin,reinforcedwith
30% glass iber chopped strand mat. The sleeves it around each pile to form a
jacket,andepoxygroutisthenpumpedintothespacebetweenthejacketandthe
pile.Madewithoutagelcoat,thesleevesaretranslucent,allowinggroutlevelstobe
monitoredduringinstallation.Thepilerepairsleevesaremanufacturedindividually
accordingtopilelengthanddiameter.Adiverwrapsthesleevearoundeachpile
thenfastensitinplacewithatongueandgroovejoint.Nylonstrapsareaddedto
provideextrasupportandthegroutisthenpumpedin.Onedivercaninstall6–10
sleevesperday.Repairingthepilesusingtheiberreinforcedplasticsleevesismuch
moreeconomicalthanreplacingthepilingsorrebuildingthepier.
StartupcompanyArmorDockSystemsInc.,isusingPVCtomakepilings,boatlifts,
ishcleaningstations,andothersimilarmarineproducts.Thenewcompanyisout-
sourcingproductiontopipeextruderHawkPlasticsCorp.andMaconPlasticsInc.
ofMacon,GA,whichhandlesthefabrication.ArmorDockchosePVCforitslong
50yearservicelife,comparedwithtimber’sprojected15-yearlifeinmarineservice.
The PVC products are also light and easy to handle. ArmorDock was created in
responsetotheneedtoindalternativestotimbertreatedwithchromatedcopper
arsenate(CCA).ItisexpectedthattheEnvironmentalProtectionAgencywillphase
outCCA-treatedtimberformarineandwaterapplications,followingthephaseout
of wood treatment in land applications. The PVC pilings, available in 8–12 in.
diameter,donotrequirereinforcement,butcanbeilledwithasubstancesuchas
crushedstone.Theirmhasfourpatentsandisworkingonotherproductsincluding
sea walls and bulkheads. In pile accessories are also produced, including in-pile
docklights,in-pilewaterstations,in-pileelectricalreceptacles,andin-pilecharging
stations. ArmorDock PVC is impact modiied, so it can withstand abuse applied
whenitisdrivenintothegroundandcanalsowithstandtheimpactofboats.
Chapter 6
Consumer Products End Use Applications
Keywords Consumerproducts•Polycarbonate•Blu-ray•Hightemperature•Toy
•Recreation•Leisure•Furniture•Lawn•Garden
Consumerproductscoveralotofterritory–everythingfromcosmeticsandtooth-
brushestohousewares,toys,recreationalgoods,furniture,lawnandgardenequipment,
etc.Consideringthediversiicationofthiscategory,itisextremelydificulttoassign
overallgrowthiguresthoughthereareanumberofveryproitablenicheopportuni-
ties.Trendsindisposablepersonalincomeplayamajorroleinthepurchaseofthese
productswithanygrowthinrealwagesboostingconsumerspendinginthissector.
Thedownsideofbusinessinconsumergoodsisthattheproductlifecyclesareoften
short,andmostapplicationsarepricesensitive.Also,manyoftheenduseshave
seasonal patterns.
SolvayAdvancedPolymers’AmodelPolyphthalamide(PPA)hasbrokenintothe
wine industry. Typically found in automotive, electrical, and industrial product
applications, Solvay Advanced Polymers LLC’s high-performance polymer has
foundanewuseasathreadedanchorforthepatentedtwist-to-uncorkwinepackaging
designedbyGardnerTechnologies,Inc.,aNapa,CA-basedmanufacturer.Thenew
productcarriestheMetaCorktradenameandwasondisplayattherecentKFairin
Düsseldorf.MetaCork™consistsofahardplasticcapsulewithathreadedinterior
surface,amatchingplasticthreadedcap,andanaturalorsyntheticcorkittedwith
athreadedanchor,madefromAmodelPPA,thatisscrewedintothecorkduringthe
bottlingprocess.
Twisting the plastic capsule eases the cork out of the bottle, thanks to mated
threadsinsidethecapsuleandontheneckofthebottle.Onceremoved,thecork
alongwiththeanchorandthetopcapcanbepushedoutofthecapsuleunit.The
plasticcapsulecanbereturnedtothebottlefordrip-resistantpouring,andthecap
canbescrewedbackonforaleak-proofseal.Thedesignoftheanchoriscriticalto
thedesignofMetaCorksincetheaveragebreakawaytorquerequiredbetweenthe
anchor and capsule to extract a natural cork is about 14.5 inch-pounds. Gardner
TechnologiesselectedAmodelPPAbecauseitcanwithstandmorethantwicethat
leveloftorque.TheAmodelmaterialusedintheMetaCorkisa45%glass-reinforced
gradeofPPAresin.Thematerialhasverygoodlowcharacteristics,makingiteasy
tomoldthethreadedanchororotherpartswithcomplicatedgeometries.
Ergodyne,apioneerinthedevelopmentofproductsforworkercomfortandsafety,
hasintroducedProFlexX-Factorgloves,designedtoofferanewstandardinprotection
for extreme work environments such as those encountered by emergency, rescue
andconstructionworkers.Thespecializedglovesofferuniquedesignelementsto
delivertherequiredcombinationofprotectionanddexterity.Featuresandbeneits
oftheProFlexX-FactorglovesincludeKeprotec,whichemploysDuPont’sKevlar
(730/732) or Armortex, which employs DuPont’s Kevlar/Nomex (726/728) over
Amarasyntheticleatheroningers,thumb,andpalmtoreinforceagainstabrasions.
Double-needle Kevlar (730/732) or double-needle 3-ply 280D nylon (726/728)
stitchingprovidesaddeddurability.EVApaddingprotectsknucklesagainstscrapes,
cuts,andbruisesandalsodampensshock,impact,andvibration.Theuseofrelective
nylonontheglovebacksimprovesworkervisibility.Theelasticcuffpreventsthe
introductionofdangerousoruncomfortabledebris.PVCingertipspreventslipping
andimprovegrip.Astretchspandexshellensuresmaximumcomfortandit.
RogersCorp.offersacollectionofhigh-performancefoamsforuseinthecommu-
nications, transportation, and consumer markets. The company’s Poron urethane
and Rogers polyolein foams offer a broad range of design solutions for energy
absorptioninapplicationsfrominsolesandsocklinerstolifejacketcushioningand
backpacks,whereperformanceandcomfortareessential.
Poronurethanesareafamilyofhigh-performancecellularfoamsthatareideally
suitedtofootwearapplications.Poroncomesinawidevarietyofcolors,thicknesses,
6.1 ConsumerProductsApplications 67
densities, and surface textures to accommodate footwear for any type of activity,
fromhigh-impactsportstoelegantorformaloccasions.Alightweightcellularmate-
rial,Poronurethaneprovidesinsoleswithgreatershockabsorptionthanmanyother
materials.Italsoprovidesbreathability,formingpermeablelayersthatdrawwater
vaporandperspirationawayfromthefoottohelpkeepshoesandfeetdry.Depending
ontheapplication,Poronurethanescombinereadilywithothermaterials,including
fabrics,typicalEVAs,andmoldedurethanes.Itisalsoeasilydiecut.Inallapplica-
tions,itpromotesdurability,abrasionresistance,friction,tension,andstitchstress.
SincePoronmaterialsaremadewithoutplasticizers,theshoeinsolesdonotshrink
orbecomebrittleandcrackwithage.Rogerspolyoleinfoamsarecross-linkedelas-
tomeric and plastomeric polyethylene-based foam materials offered in roll or bun
forminawiderangeofthicknesses,densities,andcolors.Thelightweightfoamsare
thermoformableandeasilyheatlaminatedtoothermaterials.Theypossessexcellent
tensile/elongationpropertiesandareusedinmanysportsandleisureapplications.
SonyandarchrivalToshibawereonacollisioncoursetoworkwithilmproducers
tomakethenextgenerationofhighdeinitionDVDs.WarnerBros.,Paramount,and
UniversalhavesignednonexclusiveagreementswiththeHDGroup,aconsortium
headedbyToshiba,tomakethenewHD-DVDformatwhichwasdiscontinuedin
2008.Meanwhile,DisneysignedanonexclusiveagreementwithSonytoproduce
itsvideosasBlu-rays.Equipmentmakersandreplicatorsmonitoredthesituation
closely in order to eficiently adapt the format the marketplace would ultimately
choose.Thebattlewasreminiscentofthe1980sightbetweenSonyandJVCover
the creation of the irst-generation of video cassettes. Sony opted for Betamax
thoughtheindustryeventuallyadoptedtherivalVHSstandard.
TheBlu-raydisk,whichSonydevelopedwithMatsushita,holdsuptoivetimes
thecontentpossiblewithcurrentDVDs,25GBforasingle-layerBDand50GBfor
aduallayer,whileastandardDVDcanhold4.7GBofcontent.Thistechnologyis
beingpushedbySonyandalargecoalitionthatincludesmostoftheindustry’slarg-
estconsumerelectronicsandcomputermakers.TherivalHD-DVDformat,which
wasdevelopedbyToshibaandwasmarketedalongwithNECandSamsung,was
expectedtobeonthemarketmorequicklybecauseitrequiredfewermodiicationsto
existingDVDtechnology.IthadthreetimesthecurrentspaceonaDVDbutwas
cheapertoproducethanBlu-ray.ThethreestudiosthatsignedwithToshibasaid
theyexpecedttobeginsellingsomeDVDsontheToshiba-backedformat.HD-DVD
machines would be able to play older discs and also would enable replicators to
retoolwithoutmajorequipmentchangesfortheHDcapability.Replicatorsofthe
revolutionary Blu-ray format require mostly new equipment. Sony’s new device
recordsandplaysbackBlu-raydiscsbutcanalsoplaybackDVD,DVD-RW,DVD-R,
CD,andCD-RWdiscs.However,therecorderwillnotbeabletoreadDVD-RAM
orDVD+RWdiscs.
68 6 ConsumerProductsEndUseApplications
ResinsupplierSabicInnovativePlasticshadastakeinthecontest.Thecompany
exploredqualiicationsofpossibleBlu-raymaterialsover2years.NorylEXLN0090
hasprovenitselfinBlu-raytrialsvs.optical-gradeLexanpolycarbonate.TheNoryl
product“showsbetterdimensionalstabilitythanstandardPC.”BDmaterialswillbe
moreexpensivebutaBDsystemrequiresonemoldingmachineinsteadoftwoand
onesputteringmachineinsteadoftwo.
Sagoma Plastics invests in its own ideas, investing 10% of sales in product and
productiondevelopment.OneofSagomaPlastics’latest,patentpending,proprie-
taryproductsisanattractive,high-qualitypackageforopticaldisksthatcombines
thefamiliarlookandfeelofatraditionalbookwiththeversatility,durability,and
highqualityofinjectionmoldedplasticpages.SagomacallsitDigitalBook.Disks
areplacedineitherasingle-ordouble-sidedtraythatcanbeleafedthroughlike
pagesinabook.AsingleDigitalBookcanholdupto34CDorDVDdiscs.Ituses
custom-colored disk-holding ‘pages’ molded from ABS, PC, or HIPS, materials
that are stronger than the crystal PS used in conventional jewel boxes. The
DigitalBookdesignprovidesampleroomtopackagepromotionalproducts,premiums,
andliteraturealongwiththedisks.Itsmultiplecoveroptionsincludeaclassichard
bookcoverorsoftcovertreatmentdoneinlinen,leather,orpaper,oraplasticpocket
covertreatmentwheregraphicsareslidbehindaclearplasticsleeve.
ThemarketfortheDVD/CDbookpackagingispotentiallyverylarge.Sagoma
haspatentsonthehigh-speedautomationtoproducetheseproducts.Theyareinvesting
$1millionforequipmentandarelookingforalargermanufacturingfacility. The
companyexpectstodoubletheirTCBSbusinessoverthenext2years.
RubbermaidhasadoptedanewEUfoodcompliantgradeofSantoprenethermo-
plasticvulcanizate(TPV)fromAdvancedElastomerSystems(AES)forthesealin
its food container lids. Following European food contact legislation, AES devel-
opedanewTPVthatmeetsthelatestlegislationandisidealforapplicationsinfood
andbeveragemarkets.AEScollaboratedwithRubbermaidtoensurethatthenew
EU food compliant TPV grades would match Rubbermaid’s part design and
processing requirements. Complying with the latest requirements of the Plastics
Directive2010/72/ECforaqueous-basedfood,thenewgradesexhibitgoodchemical
resistance,outstandingcompressionsetandtemperatureresistancewithexcellent
sealingpropertiesacrossawiderangeoftemperatures.Asaresult,theyaremicro-
wave,freezer,anddishwashersafe.ThenewSantopreneTPVingradesareavailable
6.1 ConsumerProductsApplications 69
inthreehardnesses:Shore55A,64A,and73A.Typicalapplicationsforthesegrades
include food and beverage closure cap liners, beverage packaging applications,
otherfoodpackagingapplicationsrequiringhighperformancesuchassealability
andhigh-temperatureresistance.
Tupperware,oneoftheworld’sleadingmanufacturersofplastichouseholdproducts,
has developed a range of new tableware, in cooperation with BASF. The new
attractivelydesignedtablewareislightweight,durable,andalsocapableofwith-
standing temperature extremes. To meet Tupperware needs, BASF researchers
developedanovelmodiiedUltrasonproduct.Thenewmaterial,designedforthe
Tupperwareproduct,isspeciallyformulatedpolyethersulfone(UltrasonE,PES),
towhichBASFaddedUVstabilizers.Thematerialisbreakandimpactresistant
andparticularlytough.Thisthermallystablethermoplasticcanwithstandtempera-
tures from −50°C to 220°C without effect. The innovative plastic tableware can
thereforebetransferreddirectlyfromdeepfreezertomicrowaveandthenplaced
onthetableasattractivelydesignedservingdishes.Thematerial,suitableforfood
contact applications, has excellent resistance to food staining and dishwasher
detergents.Becauseofitsexcellentperformance,Tupperwareisgivinga30-year
guaranteeonthenewtableware.Thetransparentcontainersthatrevealthecontents
ataglanceareavailableinavarietyofcolors.Otherpossibleapplicationsarebaby
bottlesandfoodserviceapplicationsforairlines,restaurants,andlarge-scalecatering
kitchens.
Gillette’snextgenerationtriple-bladeshavingsystemtheGilletteM3Poweristhe
world’smosttechnologicallyadvancedandexpensivemass-marketwetrazor.The
batterypoweredplasticladenupgradetotheGillettelagshipMach3lineisaunique
razor. Users press a button on the handle to activate a small motor to produce a
gentle pulsing action said to stimulate hair upward and away from the skin to
produceaclosershave.TheM3Power,whichissaidtooutperformallmen’sshaving
systems,includingGillette’sMach3Turbo,operatesunder62patents.Otherinnova-
tions in the shaver include proprietary blades enhanced by a new coating, called
‘thinuniformtelomer,’whichprovidesaperceptibleimprovementinshavingcomfort
throughoutthelifeoftheblade.ThebladecartridgefeaturesanIndicatorLubrastrip
infusedwithVitaminEandAloeforaddedmoisture,andanergonomicallyengi-
neered handle with strategically placed gripping surfaces to enable one to shave
70 6 ConsumerProductsEndUseApplications
safely at any angle. M3Power also is shower-safe, allowing convenient shower
shaving. The shaving system includes the reillable razor, two cartridges, and an
AAADuracellbattery.
Graham Packaging, a worldwide leader in the design, manufacture, and sale of
customizedblow-moldedplasticcontainersforthebrandedfood/beverage,house-
hold/personalcare,andautomotivelubricantsmarkets,hasdevelopedanewpack-
aging phenomenon. The unique design is a blow-molded stand-up plastic tube,
whichwhensqueezedexposesapopupdomerevealingasmall,13mmdiameter
threaded cap from a recess in the tubes base. The small resealable closure and
domecanberetractedbackintothetubebasewhennotinusesothatthecontainer
can stand on end. In order for conventional tubes to stand upright, a large and
costlycapisrequiredtoserveasabaseonwhichtostand.
The patent-pending Graham Flexa Tube is constructed in one piece with no
welds.Simpleandsturdy,thenewtubedesigniseasierandlessexpensivetomanu-
facturethanareconventionaltubes.Thepopupdomehasalivinghingethatallows
the dome to pop in and out of the tube base. The sealed end of the tube can be
formedwithahookoreyelet,sothatitcanbehungfromadisplayrack.Thetubeis
availablein40,50,and58mmdiametersizes.MadewithLDPE,thepackagingwas
initiallyintroducedasahaircareproductcontainer.Thepackageisbeingconsid-
eredasacontainerforarangeofproductsfromcreamsandlotionstospreadable
foods,sauces,condiments,andhousehold/chemicalproducts.
MoenInc.,oneoftheworld’slargestresidentialandcommercialplumbingproducts
producers,ismanufacturingnewkitchenfaucetdeckplatestomakeitsimplerfor
plumbersand‘do-it-yourself’consumerstoinstall.Theplateshaveabuilt-inther-
moplasticvulcanizate(TPV)lipsealofSantopreneTPVfromAdvancedElastomer
Systems,LPthatcreatesthewatertightbarrierbetweenthefaucetandthecounter-
top,eliminatingtheneedtoapplyplumber’scaulkduringinstallationtoachievethe
seal.Thepre-installedTPVgasketmakesinstallationfaster,andreducestoolsand
materialsnecessaryforfaucetinstallation.InstallingaMoenkitchenfaucetwiththe
redesignedTPVdeckplatesealssimplyrequiresinsertingthefaucetthroughthe
sinktop,tighteningthenuts,andattachingthewatertightsupplylines.Theinnova-
tivenewdeckplateswillbeincludedinallofthecompany’skitchenfaucets.
Duringatwo-shotinjectionmoldingprocess,anarrowgroovearoundtheperim-
eteroftheovaldeckplateisinjectedwithanylonbondablegradeofSantoprene
TPV to create the lip seal. The TPV forms a virtually unbreakable bond to the
6.2 ToyApplications 71
durable nylon deck plate to produce a watertight surface. This process enabled
Moen to reduce cycle times versus a previously used procedure that injected an
EPDM/nitrogen-illedfoamintoagroovetocreatethegasket.
Retailersaredevotinglessshelfspacetotraditionaltoysandmoretohighlyproit-
ablevideogames.Larger,higher-pricedtoyssuchasride-ontoysandplayground
equipment (typically rotomolded) that offer lower sales for the amount of aisle
spacetheyconsumeasaresultarefeelingthecrunch.Manysmallcompaniespar-
ticipate in the toy market, but four major injection molders dominate. They are
Fisher-Price (part of Mattel), Mega Bloks, Little Tikes Co. (part of Newell
Rubbermaid),andAmericanPlasticToys.Togethertheyrepresent77%oftheinjec-
tion molded toy business in North America. Polypropylene is the most common
materialutilizedinthismarket,representingapproximately38%ofinjectionmolded
toys.SecondbiggestisHDPEat25%ofthemarket.Polystyrene,ABS,polycarbon-
ate,andLDPEresinsarealsoutilizedinconsiderableamounts,buteachconstitutes
lessthan10%ofthebusiness.Fastestgrowth(3.8%/year)isforecastforPS;nextare
PPat3.2%/yearandHDPEat2.3%/year.Alltheotherresinsareexpectedtodecline
in poundage from 2010 to 2012.
72 6 ConsumerProductsEndUseApplications
Step2Co.,amultinationalmanufacturerandmarketerofhigh-qualityplasticpro-
ductsforchildren,makesextensiveuseofrotationalmolding,aprocessthatStep2
founder and former president of The Little Tikes Company Tom Murdough pio-
neeredforuseintheconsumerproductsmarket.
Whilemanufacturingtoysusingrotationalmoldingallowsfortremendouscreativity,
tosuccessfullypushtheenvelopeandgetthemostoutoftherotationalmoldingprocess,
itisimportanttounderstandhowthemoldsaremade.Forexample,designerscanpre-
ventwarpingonlargesurfaceareas,suchasthesidesofachildren’sclimber,byadding
subtle features like crowning, contours, textures, and a slight ‘pillowed look.’ Mass
retailerconcernsaddanotherdesigndimensionforrotomoldingdesigners.AtStep2,
manyoftheproductsarebigandbulky.Thecompanyexpendsalotofeffortdesigning
forpackagingandassemblytominimizeproductpackagesize.OneofStep2’slatest
toys,its‘NaturallyPlayful’picnictable,hasfoldoutlegsthatthecustomersnapsinto
placeforapermanentit–adesignthatsavesconsiderablespaceinthebox.
Sagoma Inc. is one of the few toy producing companies located in the US. The
companyproducespopular,competitivelypricedtoysbearingitstrademarkthatare
marketedandsoldbyitsstrategicallyandcustomer,TaurusToyCo.ofPortland,
ME.Onesuccessfultoyisits‘NoEnds,’alarge-scalebuildingtoythatallowschil-
drentobuildlarge-scaleforts,dollhouses,puppettheaters,helicopters,airplanes,
animals/dinosaurs,andmorefrombasicbuildingcomponents.Thetoysencourage
childrentolearntobuild,create,workingroups,developthree-dimensionalrela-
tionshipskills,andhavealotoffun.Thoughchildrencanbuildthingstolargescale,
thepartsareinrelativelysmallboxes,lessthan24" × 24" × 24".
Thecompanyalsodoesproprietaryproductdevelopmentforothertoycompa-
nies, and helps design, develop, build Stereolithography model/prototype, and
assistsinthetoolbuildingforsuchproductstomakeforoptimumeficienciesin
molding.Thecompany,astate-of-the-artinjectionmolderandassembler,provides
both product design and/or injection molding services. The designers and engi-
neersatSagomaareresponsibleforbothnewproductdesignanddailymanufactur-
ing.Thecompanyenjoysseveralallianceswithlocalcompanies,rapidprototypers,
machineshops,andtoolshops,whichhavelastedmorethan30years.
Logitech’slatestcontrollerforthePlayStation2istheLogitechFlightForcejoystick.
Joysticksareallaboutpreciseandnaturalcontroloflightandspacecombatgames.
6.2 ToyApplications 73
Inadditiontoexcellentcontrol,FlightForceprovidestheexcitingimmersivenessof
Logitech’s force feedback technology. This force feedback joystick lets gamers
experience the sensations of light combat, including weapon recoil, missile
launches,explosions,andothereffects,incompatiblegamesforPlayStation2.Soft
touchTPV,ABS,andpolycarbonateplasticsareusedthroughouttheapplication.
LogitechFlightForcefeaturesatwisthandlewithversatilehandgrippositionsfor
easy rudder control and improved hand comfort in tense game situations. Seven
actionbuttons,fouronthehandle,twoonthebase,andatrigger,provideabroad
rangeofcontroloptionstodelivereasyaccesstoireweapons,selecttargets,and
performotherfunctionsusingbothhands.Thehandlebuttonsandaneight-wayhat
switcharedesignedforquickaccess.Ahighprecisionthrottleprovidesaccurate
powermodulation,whilethesubstantialbase,whichcontainssteelweights,ensures
stabilitywhenthegoinggetsexciting.
Electroniclearningaidsareoneofthefewgrowthcategoriesinthe$25billionUS
toyindustry.Parentsspentmorethan$820milliononelectroniclearningtoysfor
preschoolersin2010alone,despitealackofproofthattheywilljumpstarttoddlers
onthepathtoperfectSATscores.AsizzlinghotproductisLeapFrog’sLeapPad,a
learningaidthatemitssoundsandmusicwhenkidstouchastylustoapictureor
letter.Inwhatisshapingintoablisteringtoybattle,Mattel’sFisher-Priceresponded
withitssimilarsmashhit,introducingitsPowerTouch.LeapFrogcounteredwith
threenewproductsandslappeditsrivalwithapatentinfringementlawsuit.
IntryingtobeatLeapFrog,MattelendeavoredtomakeitsPowerTouchunique.
WhilekidsuseastyluspentointeractwithaLeapPad,theyonlyneedtousetheir
ingerstooperatePowerTouch.Inaddition,thePowerTouchconsoleautomatically
recognizeswhenapageisturned.LeapPadusersmustpushabuttontocontinue,
something that can confuse small children. LeapFrog has since come out with
LittletouchLeapPad,basicallyatouch-sensitiveplasticslab.Byplacingaspecially
designedbookinaholderontheslab,andinsertingaprogramcartridge,thepic-
turesonthebookpagesbecometouch-sensitivebuttons.Theproductsarepossible
asaresultofhigh-speedchipsandcompactmemory.Thesamecapabilitiesafew
yearsagowouldhaverequiredaCD-ROManda$2000computer.
Unlikemanyplasticsprocessingmarkets,foreigncompetitionisnotabigconcern
atseasonalproductsblowmolderGrandVenture.Seasonalblow-moldedproducts
arebig,bulky,anddonotshipwell,astheycannotbestackedandtheycontainalot
of air. The irm’s top Christmas product was 38 in. light-up Santa. The seasonal
74 6 ConsumerProductsEndUseApplications
productscompanyalsooffersarangeofblow-moldednativityscenes,stars,lambs
reindeer,snowmen,andotherChristmassubjects.Thecompany’slargestChristmas
themedblow-moldedproductisa68in.light-upSantainareindeer-drawnsleigh
thatthecompanyrecentlyintroduced.
All of Grand Venture’s products are made of HDPE and are molded by its
sisterirm,FalconPlasticsInc.,whichsharesitsWashingtonlocation.Falcon
hadsalesof$12millionlastyearandalsoblowmoldstrashpails,andlawnand
garden products for Grand Venture. Grand Venture typically takes seasonal
ordersforHalloweenandChristmasinQ1oftheyear.ItbeganmoldingSantas
andotherChristmasproductsinJuly,toshiptoitsbiggestcustomerWal-Mart
Stores Inc. Christmas is still the top market for seasonal plastic products
marketer.
IntheUS,thewholesalevalueofmanufacturers’shipmentsofsportsequipmentand
recreation-relatedproductsclimbedto$120millionand$334million,respectively,
in 2010. Similar to toy manufacturing, production of many sport and recreation
productshavemovedoff-shoretoAsianmolders.Alsolikemanyothermarketsec-
tors,traditionalmaterialssuchascanvas,leather,wood,andmetalusedinthemanu-
facture of sports and recreational products are increasingly displaced by a wide
rangeofplasticmaterials.Productssuchashikingequipment,campinggear,climb-
ingboots,backpacks,snowshoes,skatesarcheryequipment,andmanyothers,even
kayaks,areincreasinglymadeofhightechcompositesandotherplasticmaterials
primarily for their excellent strength to weight ratios, water resistance, abrasion
resistance, etc.
FirstlightFoldableKayaksofNewZealandhavelaunchedanewrangeoffoldable,
strongandexceptionallylightweightkayaks.Thesedismantablekayaksaremade
upofalexibleouterskininDesmopanTPUandaframeincarboniber/Kevlar
iber.TheskinforthekayakisproducedbyEpurex,aBayerMaterialSciencesub-
sidiary,specializinginextrudedDesmopanTPUilm.Theentirehullismadefrom
asinglepieceofmaterial,meaningtherearenoseamsunderthewaterline.Desmopan
(TPU)waschosenforitshighabrasionresistance,lexibilityoverawidetempera-
turerange,goodresistancetoweatherexposure,transparencyifnecessary,freedom
fromplasticizers,soitdoesnotshrinkanditsexcellentchemicalresistance.These
6.3 RecreationandLeisureApplications 75
advantagespermitadimensionallystable,3Douterskinwhichistear-resistantyet
stilllightweight.
Thekayaks,weighing8–10kg,folddownintoabackpack-sizedpack.Assembling
thekayaktakesabout20min.UseofcompositecarboniberandKevlarrodsisthe
keytoprovidingtheultimateinlightweightfoldingkayaks.Notonlyaretheserods
lightandstrong,buttheyprovideexcellenttorsionalrigidity.Thecrossribsmade
fromDupont’sZytelhigh-performancepolyamideareexceptionallystrong,yetwill
lextoallowtherodstoconformtotheshapeofthekayak.Thethree-dimensional
shapeofthebowandsternisformedusinglightweightmoldedfoamendunitsthat
cushionandprotecttheinsideoftheskinfromdamagecausedbychafingfromthe
frameandreinforcethebowshape.
All-terrainskatesfromGateSkate,Inc.aredesignedtogooveranytypeofsurface
includingasphalt,dirt,gravel,grass,andmountaintrails.Thankstoaninnovative
designwitharuggedchassismoldedfromanewsuperstrongDuPontZytelHTN
highperformancepolyamideresin,andpneumatictires,TrailSkaterollseasilyover
bumps,cracks,anddebris,whilehand-operatedhydraulicbrakesallowskatersto
easilycontrolspeedandstopquicklywhileremainingcomfortablybalanced.
76 6 ConsumerProductsEndUseApplications
Thechassis,essentiallyaskionwheels,mustwithstandrepeateddynamicloading
under the rider’s full weight. Long glass ibers in the 50% glass-illed Zytel
HTN51LG50HSLresinarecrucialtothechassis’performanceprovidingimproved
fatigue performance, impact resistance, and surface appearance. The design is a
challengingone.The21in.longchassishaswallsectionthicknessesof0.04–0.79in.
Load-bearing requirements make avoidance of stress concentration essential and
thereforemolddesignprovedcritical.DuPontUSspecialistsusingmoldlowanal-
ysisrecommendedthegatelocation,andlocalspecialistsinChinarecommended
enlargementofthegatetoenhanceiberorientationandimprovementsinventingto
assurecompletemoldill.
GlobalsportsequipmentmanufacturerSalomonisusingDuPontDelrinacetalresin
fortheskisectionofitsnewconcept,‘bombproof’PP3Kurbsnowskate.PP3,the
codename for a well-known, ‘bombproof’ Russian submarine, was selected to
communicatethatthePP3KURBresistsshocksanddamagefromsmallstones.Snow
skating,asnowboard-typesportrecentlylaunchedintheUS,differsfromsnowboard-
inginthattheuserisnotattachedbybindingstotheboard,givingthesnowskatera
greater feeling of freedom.
TheacetalresinchosenfortheskisectionofPP3Kurbistentimestougherthan
HDPE,thestandardmaterialforskirunningbases,providingsigniicantlyimproved
mechanicalresistanceagainstsmallpebbledamage.Theacetalresinisalsolexible
whileremainingstiffandstrong.Userscanlextheskibypushingdownontherear
ofthemaplewooddecktocompletesigniicantlymorecomplexjumpsandtricks
thanwithprevioussnowskatemodels.Thedesignfreedomgivenbytheacetalalso
meansthatSalomoncoulddesignsidechannelsintotheskisectionforaddedstability
whentheuserwantstorideoversoft,mountainsnow.Meanwhile,inorderforusers
tousetheirsnowskatesintheevenings,downintheresorts,central‘grindchannels’
areincludedinthedesignforextrastabilitywhentheuseris‘grinding’alonghandrail
sectionsofskateboardparks.
TheLaserlinetee,agolinginnovation,wasdevelopedbyEurope’smostsuccessful
golfplayer,NickFaldo,usingBayer’sMakrolonpolycarbonate.Thenewteeprom-
ises precise ball contact, improved light path, and increased hit quota which all
translatesintoanimprovedgame.Unliketraditionaltees,theteepinhasbeenmoved
8mmtowardsthelagandensuresthedirectcontactwiththeballwithouttouching
thetee.Thedevelopmentimprovesballcontactateveryteeoffprovidingbothama-
teurs and professionals with a more precise game. When developing the tee, the
6.4 FurnitureApplications 77
manufacturers, ‘Spirit of Golf’ and Nick Faldo, chose polycarbonate as the high
tech material has exceptional shock resistance and is unbreakable, giving the
Laserlineteeaclearadvantagecomparedtoclassicalwoodenandtraditionalplastic
tees.TheLaserlineteeiscompletelyrecyclableandcomplieswithEuropeanenvi-
ronmentalrequirements.Theinnovativeteeisavailableinarangeofcolorsandcan
beobtainedingolfsportsshops.SpiritofGolf,theexclusiveBallyGolflicensee,
recentlyintroducedtheLaserlineteetotheUnitedStatesmarket.
MeeseOrbitronDunne(MOD)Co.’sAmericanRotationalMolding(ARM)Group
redesignedandmanufacturedacustomgolfclubmerchandisingcartforCallaway
GolfCo.Themerchandisingcart,akeyelementinCallaway’scustomclubitting
system,isaportablescooterthatholds56woodsandironsandanIBMThinkPad
data acquisition system. It reportedly enables Callaway teaching professionals to
gatherdatafromeachswingandrecommendidealclubsizeswiththeaidofthe
company’sproprietaryittingsoftware.
MOD/ARM redesigned the cart to add strength, longevity, and visual appeal
whileguardingagainsttheelements.Asleek,durable,rotationallymoldedpolyeth-
ylene structure replaced the earlier fabricated metal and vacuum formed plastic
panelstructure.Thenewdesignreplacedhundredsofpartsandfastenersandassoci-
atedassemblyrequirementswithninerotationallymoldedpanels,threeinjection
molded wheels, and one extruded tube to protect each club. The simpliication
increasedproductionrates,aidedqualityassurance,andcontributedtoanoverall
costreductionof75%versustheoriginalmetalcart.Whilecuttingcosts,MOD/
ARMengineersaddednumerousamenitiesandsecurityprecautions.Thecartwas
redesigned to it through standard-sized doorways. A cumbersome front wheel
assemblywasreplacedwithasinglefrontwheelthatswivels360°.Anewbrake
haltsthecartwhenmovementisnotdesiredyetremainshiddenfromviewforvisual
appeal.Aclevertowingbar,whichstowsinsideacompartmentatthefrontofthe
cartwhennotinuse,wasaddedtopermittowingwithagolfcart.
Thefurnituremarketconsistsofiveprimarycategories,homeandoficefurniture,
juvenileorinfantfurniture,publicseating(school,lecturehall,stadium,andarena),
outdoorandpatiofurniture,andmiscellaneousfurnitureparts.Injectionmoldedfur-
nitureconsumesthemostplasticresin.In2010,thefurnituremarketaccountedfor4%
78 6 ConsumerProductsEndUseApplications
oftotalthermoplasticsales.IntheUnitedStates,domesticinjectionmoldedfurniture
consumed an estimated 409.9 million lb of resin in 2010. With an average annual
growthratearound3%,thismarketcouldgrowto475millionlbby2012.Polypropylene
constitutesaround80%oftheresinconsumedforinjectionmoldedfurniture.HDPE
isadistantsecondplaceataround7%,andpolystyreneisthirdat6%.
Withintheinjectionmoldedfurniturecategory,outdoorfurnitureisthelargest
segment (44% of the total), home and ofice furniture is the second largest area
(25%),juvenileandinfantfurniturerepresents22%ofthemarket,publicseatingis
6%,andthemiscellaneousfurnituresegmentrepresents3%.Muchoftheinjection
moldedfurnituremarketisdirectlyrelatedtothehousingmarket.Changesinthe
levelofordersforhousing-relatedfurnitureproductsarriveabout6monthsafter
anysharpchangesinhousingstarts.
BayerMaterialScienceAGhasrecentlydevelopedanextremelylightpolyurethane
foamtoreplacethepaddedquiltingthatnormallymakesupabout10–15%ofthe
volumeofupholsteredfurniture.KnownasHyperNovathishighlyelasticmaterial,
thankstothespatialcrosslinkingofitspores,ismoredimensionallystablethanthe
polyesteriberleeceandothermaterialstraditionallyusedinthisservice.Using
HyperNova,theseatsurfaceofupholsteredfurnitureremainslargelyunaffectedby
frequentuse,alwaysrecoveringitsshapewhenyoustandup,leavingnowrinklesor
creasesandtheupholsterypaddingwillretainitsresilienceovermanyyears.An
additionalbeneitofthisverysoftpolyurethanefoamisitsexceptionalbreathability:
itisextremelypermeabletoairandcanabsorbupto10%ofitsweightinmoisture
andemititagainlater.Thebreathablefoamwasmanufacturedinclosecooperation
withHenneckeGmbHofSanktAugustin,Germany.Theenvironmentallyfriendly
foam uses only carbon dioxide for blowing agent. For allergy sufferers, the new
polyurethanefoamisresistanttomiteandmicrobeinfestations.
Under the name ‘Triple-E luxe tafels,’ Dutch irm Tinga R&D BV is marketing
lightweight,stackabletablesthatarefareasiertohandlethan‘conventional’wooden
furniture,thankstoasandwichcompositeusingBaypreg,apolyurethanesystem
fromBayer.Sandwichcompositeswereoriginallyconsideredexoticmaterialspri-
marilyusedinaerospaceandmorerecentlyautomotivemanufacturing.Nowthanks
toapromisingideafromTingaR&D,theywillsoonbefoundinlectureordining
hallsandcafeterias.
Setting up and taking down tables in a multipurpose room is usually a heavy
chore. Tinga recognized the potential that sandwich composites with their low
6.4 FurnitureApplications 79
weightandhighstrengthmightofferthefurnitureindustry.Usingasandwichdesign
theTriple-Etablesweighonly12.5kgdespitemeasuring80×200cm.Thecoreof
thesetablesismadeofalightweightrigidPUfoam,reinforcedtopandbottomwith
laxmatstoabsorbtensileforces.Theexternalsurfaceiscoatedwithanextremely
tough,washableplasticilmavailableinimitationwoodorcoloredinishes.The
tableedgesarereinforcedwithsolidwood.Tomanufactureasandwichcomposite,
theibermatsarethoroughlyimpregnatedonbothsideswithPUinasprayprocess.
The sandwich components are then placed in a preheated mold and pressed into
inalshapeatanelevatedtemperature(60–120°C)andpressure(6–8bar).ThePU
curesinminutes.Thesandwichcompositerequiresnoaftertreatment.Thishighly
economical,one-stepprocessproducesadurable,verytoughandrigidcomposite
thatcanwithstandevenhighmechanicalloads.
An attractive new chair, part of contract furnishings manufacturer Allsteel Inc.’s
‘GetSet’lineofoficechairs,tables,andaccessories,isitsGetSetmulti-purpose
roomseating/oficesidechair.Thenewchair,acomfortable,lexiblesolutionfor
learningenvironments,isdesignedforbothhorizontalnestingandverticalstacking
(uptofourhigh)forversatile,easytransportationandstorage.Thoughportabilityis
aplus,thebeneitofGetSetchairsisthehoursofcomfortableseatingtheyprovide.
Unlikenon-paddedfoldingorstackingchairsoftenusedinalearningsetting,Get
Setchairsfocusoncomfort,featuringseatcushionsandaunique‘lexback,’which
hasastructurethatlexesnaturally,tocounterbalancebodyweightandconformto
supportusersofdifferentshapesandsizes.Anergonomicslopingarmoptionalso
allowsfornaturalmovementofthebody.Perforationsinthechairbackallowair
circulation,animportantconsideration,aswell.Durablemulti-surfacecastersmake
movementeasy.
Innovative Injection Technologies Inc. of West Des Moines, Iowa, injection
moldsseveralpartsforthestackingoficechair,from18%glass-illednylon,using
gas-assisted molding.
DuPontDelrinacetalresinisusedforthegearsinaninnovativenewgearboxfor
HunterDouglas’sUltraGlideliftingsystem,whicheasesheightadjustmentofhon-
eycombwindowshades.Thelow-frictiongearboxallowsHunterDouglastoextend
theirproductofferingtolargershades,byprovidingamechanicaladvantagetolift
weightsupto7lb,aboutdoublethatwithoutagearbox.
Performance Gear Systems, Inc. (www.performance-gear.com) designed the
gearboxtomeetHunterDouglas’sneedsforsmoothoperationandlowwearina
80 6 ConsumerProductsEndUseApplications
compactpackagethatitsinthespacelimitedconinesoftheshade’sheadrail.
Thegearboxcontainsthreegears,input,parallel-mountedcluster,andoutputgear.
PerformanceGearInc.injectionmoldsallthreegearsfromaspeciallyformulated
ultra low friction grade of Delrin containing 10% by weight of DuPont Telon
PTFEluoropolymerinmicropowderform.Theconnectorismoldedfromgeneral
purposegradeDelrin500P.Telon’slocked-inlubricatingactionensuresthatthere
isnoriskoffabricstaining,apotentialproblemwithexternallylubricatedresins.
Othercomponentsofthegearboxarethehousing,housingcap,andretainer.The
retainerholdsthegearsinthehousingandhasanintegralbearingshaftforthe
inputandoutputgears.PerformanceGearmoldsthesepartsfromDuPontZytel
132Fnylonresin,anunreinforced,fastcyclingPA66grade.
Pillows,comforters,mattresspads,andiberbedsilledwithNatureWorksibersare
beginningtoappearonstoreshelves,offeringconsumersanewandnatural-based
alternativetotraditionalsyntheticibers.Thenewibersmadefromanentirelycorn
derivedproductweredevelopedbyPaciicCoastFeatherCo.,aleaderintheUS
andCanadianbeddingindustry.Thesenewbeddingproductsprovidenaturalcom-
fort and warmth with superior performance attributes versus polyester iberill.
These new products provide a natural loft and resilience to give greater support
whilesleeping,whiletheinsulatingwarmthandwickingattributesmakeforadryer
andmorecomfortablesleepexperience.Overall,NatureWorksiberscombinethe
bestphysicalcharacteristicsofnaturalillsandpolyestersyntheticsbutwithsupe-
riorperformancethatwillnotdiminishafterwashingsorthroughextendeduse.The
new natural-based ibers deliver great comfort, loft, and durability without the
‘environmental shortcomings’ of petroleum-based, polyester ibers. NatureWorks
uses20–50%lessfossilresourcesintheproductionprocessthanconventionalplas-
tics,resultinginsigniicantlylessCO2 emissions.
TheMirramidlevelexecutivechairisHermanMiller’smostadvancedlaunchfol-
lowingtheir‘DesignfortheEnvironment’protocols,whichprovidesguidelinesthat
engineers/designersmustmeetateverystageFortheMirrathatmeantconsidering
notjustthetypesofresinsused,butthebreakdownofallmaterialsincludingstabi-
lizerinthenylonandpigmentforthepolypropylene.Workingundertheguidelines
oftheMcDonoughBraungartDesignChemistrysystem,HMIdroppedtheuseof
PVC,replacingitwithnylonorTPE.
Theeffortaffectedthechair’soveralldesign.Inadditiontocomfortduringitswork
life,thechairisdesignedforeasydisassemblyforrecycling.Atypicalchairbacksup-
porthasstructuralsteelwithanovermoldedplasticskin,andadjustmentmechanismsof
6.5 LawnandGardenApplications 81
overmolded screws and springs. Nearly impossible to recycle, Mirra designers and
engineersdecidedtouseanallpolypropyleneseatbacksupportedbyaglassilled
structuralnylonspine,withacompositeleafspring.Anonillednylonwebbingprovides
additionallumbarsupport.Thechaircanbedisassembledforrecyclingwithin30s.
The$30billionUSlawnandgardenmarketwhichconsistsofthreeprimarycatego-
ries–outdoorequipment,supplies,andprofessionallawncareservices–isexpected
togrowby5.5%annuallythrough2012asAmericanhomeowners,nowatarecord
number,settleintotheirnewlyacquiredpropertiesandbabyboomersenterthepeak
yearsforgardeningpopularity.Drivingthismarketareextremelyfavorabledemo-
graphics,continuedhomeownerafluence,andanewfocusonpush-marketingby
theconsolidatingmajorplayers,aproliferationoflawnandgardenretailers,and
numerousnewproductsintroducedtosatisfytheneedsofmillionsofhomeowners.
Additionally,golfcoursesarebigbusinessforthelawnandgardenmarket.
KroyBuildingProducts,Inc.,aleadingmanufacturerofvinylfencing,decks,railing,
accessories,decorativestructures,andspecialtybuildingproducts,hasintroduceda
novelnewvinylfencetechnologythatofferssuperiorstrengthandperformance.The
newtechnology,named‘FusionFence,’usessonicweldingratherthanglueduring
theassemblyprocess,tocreateastronger,moredurablefence.Fusionweldingthe
vinylcomponentstothemainframeofthefencesectionproducesasturdierand
more solid fence.
Kroy’s new Fusion Fence also simpliies the purchase/installation of compo-
nents,producingasingleunitthatiseasytopurchase,transport,andinstall.Every
FusionFencevinylsectioniscustommanufacturedtopreciselyitthecustomer’s
speciications.AllFusionFencevinylproilesaremanufacturedviaanextrusion
process,fabricatedwithcomputerizedmachineryandassembledwithfusionvinyl
weldersforsuperiorstrength,durability,andaesthetics.Thetechnologyisavailable
inawiderangeoftraditionalandclassicfencedesignsforboththenewconstruction
andremodelingmarkets.
SeekingtoredesignitsMiracle-Gropail,ScottsCo.,theworld’slargestmarketerof
branded consumer and garden products enlisted the aid of Unimark Plastics.
82 6 ConsumerProductsEndUseApplications
FiskarsCorp.,aleadingmanufacturerofscissorsandknives,hasintroducednon-slip
gardenpruners.Fiskarsrequiresanydesigntounifyallthequalitiesofanergonomic
product,includingquality,viability,safety,andcomfort.Startingfromthisdesign
philosophy,Fiskarslookedtodesignthreenewgardeningerlooppruners.Thecom-
panywantedtoproducethesetoolswithgripsthatweremorecomfortable,softand
slip-resistantthanpreviousdesigns,makingtheprunersmucheasiertouse.Fiskars
initiallyconsideredusingamodiiedgradeofpolyamide,thetraditionalmaterialfor
gripsintheseapplications,butthisoptionprovedtobetoocostly.Alternativemate-
rialswereassessed,anditsoonbecameclearthatSantoprenethermoplasticvulcani-
zates(TPVs)wouldproducethedesiredlevelofcomfortandsoftness.
Thegripsforthetoolsareproducedusingatwo-shotinjectionmoldingprocess,
consistingofashotofblacknylon6with30%glassiber(DurethanBKV130)
followedbyashotofgraySantopreneTPV8291-70PA,eliminatingtheneedfor
adhesivesorassemblyprocedures.
their conservatory roofs to stay clean. The Sabic Innovative Plastics’ Lexan
Thermoclear Easy Clean sheet is part of the Lexan Thermoclear sheet range of
lightweight,weather-andimpact-resistantsheetsextrudedfromLexanresin.Lexan
ThermoclearEasyCleansheetfeaturesaspecialcoatingontheoutsidesurfacethat
provides self-cleaning properties.
Suitableforallapplicationsthatareexposedtorainorwater,thisspeciallytreated
Lexan sheet has a special hydrophobic coating developed by Sabic Innovative
Plasticsthatreducestheangleofwaterdropsonthesheetfrom101°to66°.Asa
resultthedropsofwatergetbiggerandtransportanddrainoffthedirtonthesheet.
Themulti-wallsheethasUVprotectiononbothsidesandtheuniqueEasyClean
propertiesontheupperside.Thesheet,whichisproducedinarangeofthicknesses,
offershighlighttransmission,goodinsulationproperties,andgoodimpactresis-
tance.Sabicbackstheself-cleaningpropertiesoftheproductwitha3-yearwarranty,
althoughtestsindicateitwilllastsigniicantlylonger.
Chapter 7
Medical, Emerging, and Other End
Use Applications
Keywords Medical•Catheter•Surgical•Emerging•PLA•Luminescent•Virtual
layering•Government•Pipe•Wastemanagement
Medicalisastrongandgrowingmarket,particularlyasthebabyboomergeneration
entersoldage.Theindustryprojectsdemandfordisposablemedicalsupplieswill
grow5.6%annuallythrough2012.Gainswillbeledbydrug-elutingstents,preilled
inhalers,andsyringes,aswellascellularanalysis,nucleic,andbloodglucosediag-
nosticdevices.USdisposablemedicalsupplieswasa$60.3billionindustryin2010,
with the largest players being Johnson & Johnson, Abbott Laboratories, Becton-
Dickinson,Kimberly-Clark,BaxterHealthcare,3M,BostonScientiic,andRoche.
TheUSmedicaldeviceindustryproducesone-halfoftheworld’smedicaldevices
andconsumesapproximately40%oftheworld’soutput.Mostofthemarketisheld
by just 17 companies that account for 65% of the total revenue in this segment.
Althoughthereareapproximately6,000medicaldevicemanufacturersemploying
about 400,000 people, roughly 80% of those companies employ fewer than 50.
Manyaresmall,entrepreneurialirmsthatproduceveryspeciicdevices.Themarket
isprojectedtoreach$68.9billionthisyearand$74.5billionin2011.
Medical device contract manufacturer NDH Medical, Inc. is patenting its novel
extrusion process to produce unique catheter tubing for a new line of catheters.
The extrusion process produces multi-lumen catheter tubing with varying wall
thicknesses.NDHusedthenewprocessindevelopingtheirstproductutilizingthe
FlatCath Hemodialysis Catheter technology under an agreement with FlatCath,
LLCofGeorgia,ajointventurebetweenHatchMedicalLLCandthetubinginventor,
Aubrey Palestrant, M.D. Palestrant holds a patent on the tubing. Large, multi-
lumencathetersareregularlyplacedintothevenoussystemtoperformhemodialysis,
infusionoraspiration.Catheterplacementoftencreatesturbulenceandsluggish
bloodlowresultinginamyriadofpatient-relatedhealthconcerns.TheFlatCath
technologyfacilitatesasigniicantlyreducedcross-sectionalcatheterproilewithin
thebloodvesselwhenthecatheterisnotinusereducingtheriskofbloodclotsand
complications. NDH Medical specializes in custom extrusion of single-lumen,
paratubing, multi-lumen, and co-extruded tubing. The company provides insert
molding,injectionmolding,padprinting,assembly,andotherservicesaswellas
in-housetoolingdesignandfabrication.
Storopack,aleadingmanufacturerofstructuralmoldedpackaging,isusingBASF’s
NeoporexpandablePSforboxesusedinthetransportofbloodproductsandorgans.
Sincetheselife-savingproductsmustbemaintainedatconstanttemperature,good
thermalinsulationisessential.StoropackmoldsNeopor,whichcomesintheform
ofsmallblackbeads,intosilver-greyfoamblocksandshapes.Neoporhasoutstand-
ingheatinsulationproperties,highcompressivestrength,impactabsorption,light-
ness and moisture resistance. It also contains infrared absorbers and relectors,
whichlowerthefoam’sthermalconductivityandgiveititssilvergreycolor.
One package is a blood product foam container called MonoTripleBox that
Storopack designed with medical products company Delta T of Germany. The
MonoTripleBox is a highly insulating Neopor box designed for shipping blood
products by post or courier. The box, comprising two foam halves with walls
65–80mmthick,canholduptothreetemperaturecontrolpacks,containingbagsof
blood or plasma. The temperature control packs by Delta T called ‘x°-Control’
resembledomesticfreezerpacksandcontainaspecialhydrocarboncoolingmedium,
whichisusedtomaintainthebloodproductsatastabletemperatureduringtransport.
OnceencasedinNeopor,redbloodcorpusclescanbemaintainedat2–8°Cforover
24hatanambienttemperatureof25°C.
Operating microscopes play a crucial role in the operating room. They must
deliver top performance in a highly demanding environment and they must be
lightweight,alwaysaccessiblebutneverinthewayduringdemandinganddetailed
work. Consequently, these instruments are equipped with highly sophisticated
7.1 MedicalApplications 87
balancing systems that ensure high-precision movement of the complex optical
systemwithoutmanualinvolvementonthepartofthesurgeon.Thearmwhichthe
microscopemovesonmustthereforebeaslightaspossible.High-performance
plasticslikethelightweight,robust,Baydur110polyurethanesystemfromBayer
MaterialScienceAGareidealforuseinthisapplication.
LeicautilizesBaydur110polyurethaneforallsixhousingcomponentsinitsnew
M520F40operatingmicroscope,manufacturedbytheSwisspolyurethaneproces-
sorPuratechGmbHofAltendorf.TheBaydur110moldedpartshavethinwalls,
makingthemlightweightwhilestillextremelystiff.Thesepropertiesenabledthe
Leicaengineerstoavoidusingasheetmetaloraluminumframework,whichwould
have made the arm signiicantly heavier. The Baydur material also has excellent
lowabilitysothatevencomplexproductgeometriessuchasribbing,apertures,or
undercutscanberealizedeasilyinasinglestep.Thesethin-walled,high-strength
housings allow complete and reliable protection of the electronics and delicate
mechanicalcomponents.Also,assharpcornersandedgesareavoidedinthedesign,
theoperatingmicroscopeiseasytocleananddisinfect.Thisisfacilitatedbythe
goodcoatabilityandexcellentchemicalresistanceofthepolyurethane.
ERBEElektromedizinGmbHhasdevelopedmicrotweezersfornon-invasivesurgery
(keyholesurgery),withhandleandworkingpartsmoldedofglass-reinforcedDuPont
Zytel.Thisbipolarmicrotweezerisamulti-purposeinstrumentthatcangrasp,open,
andpreparethetissueandadministerlow-intensityelectricalcurrenttostopbloodlow.
Thehandle’sindividualpartsincludethemainhousing,acablechannelatthebackand
aholderatthefrontforametaltube,whichguideswiresthatoperatethetweezerjaws.
ERBEandsystemsupplierPEZETchoseDupont’sZytel70G30HSLinplaceof
PEEKoriginallyplannedforthehandle.TheZytel,aglass-reinforced,heat-stabilized,
hydrolysisresistantgradeofnylon66,wasmodiiedbyincorporationofamaster-
batchtoacceptlaser-marking.Veryprecisepartscanbemoldedfromthishigh-per-
formanceresin.Thankstoitsdimensionalstability,thepartsretaintheirfunctionality,
evenaftermultiplesterilizationsinanautoclavewithsuperheatedsteamat134°C.
Like all nylons, it also offers long-term resistance to the cleaning agents used in
hospitalsandmedicalfacilities,suchasthoseinvolvedinlushingthemetaltube.
Tecanhasdevelopedafast,lowcost,easytousemicrolab,LabCD.Asthemicro-
lab Uses less than 10 mL for analysis, it also cuts consumption of valuable test
compoundsbyupto90%.Thesystemmovestestcompoundsandreactantsthrough
tinychannelsbyspinningaCD-sizeddiskatprecisespeeds,toperform48simul-
taneous drug screening assays.
88 7 Medical,Emerging,andOtherEndUseApplications
Scientistsworkingindrugdiscovery,molecularbiology,andrelatedareasrelyon
high-throughputassaystoevaluatehowcompoundsareabsorbed,metabolized,and
excreted,andthetoxiceffectsproduced.The5mmthick,124mmdiameterdisk
consistsofanupperhalfcontainingthesystemschannelsbondedtoalowerhalfwith
thestorageandmeasurementwells.SamplesaretransferredtothediskbyTecan’s
GenesisworkstationanditsUltrasystemgovernsspinningandmeasuresreaction
productsusingabsorbance,luorescence,andluminescence.Tecanevaluatednumer-
oustransparentpolymersforthediskbeforeTicona’sTopascyclicoleincopolymer
(COC) was selected. The COC provides low autoluorescence and excellent UV
transmittanceinmoldedparts,minimizingbackgroundnoise.WeidmannPlasticsof
Switzerlandmoldsthedisks.Theirm’smicromoldingexperienceandproprietary
technologiesenabledittomeetthe±2mmtolerancesofthedisk’stiny50mmchan-
nels.COChastheinherentdimensionalstabilitynecessarytoholdthosetolerances,
anditssurfaceenergyallowstheluidstolowpredictablyintothemicrochannels.
TAGAMedicalTechnologiesisusingapolycarbonatecompoundsuppliedbyRTP
Companytoproduceaproprietarysetofbaflesinitshumidiiersystemusedto
help obstructive sleep apnea (OSA) patients. Known as the Velocity Passover
humidiier, the system serves to counteract the dehydrating effect of use of
ContinuousPositiveAirPressure(CPAP),inwhichairispumpedtothebackofthe
patient’sthroattopreventthetissuecollapsethatblocksrespirationinOSApatients.
Thehumidiierprovidescool,moistairtothepatientduringCPAPtreatmentmini-
mizingthedehydratingeffectthatcanleadtosinusproblems.
TAGA Medical worked with RTP and molder Elyria Plastics to fabricate the
plasticbaflesystemfromacustomizedRTP300Seriespolycarbonatesuppliedas
a transparent blue compound. As the humidiiers must be portable, strength and
impactresistanceareamust.Sincewallsareasthinas0.050in.,thecompounduse
requiredlubricityandsuperiorlowproperties.Asthehousingfunctionsasawater
reservoir,transparencyallowsthepatienttoseewhenareillisrequired.Theinal
productwasformulatedwithFDAcompliantresinandpigment,tomeetClass2
FDA510Kstandardsandincorporatedhighflowandlubricationadditives.
AnotchedIzodimpactstrengthto15ftlbs/in.andlexuralmodulusof0.34psi×106
providedrequiredstrengthandrigidity.
Oneofthemostexcitingemergingmarketinrecentyearsinvolvesconductiveand
light-emittingpolymerswhicharechangingthefaceofelectronics.Amovementis
7.2 EmergingApplications 89
currently underway that will transform the way we view information, especially
whenweareonthemove.Companiesarenowproducingprototypesofultra-thin,
large-area,rollabledisplaysonaroutinebasis.Thetechnologywillalsomakepos-
sibletheproductionofmuchlarger,3-Dhigh-deinitiondisplaysforbothindoor
andoutdoorapplications.Engineersarealsonowcapableofcreatingelectrolumi-
nescentilmthatcanbeilluminatedmuchlikeirelies,withtheapplicationofa
voltage.Elsewhere,manynewapplicationsareemerginginthemedicalarea,with
plasticboneapossiblenewmarket.
One strongest indication that a new technology has bridged the gap from an
intriguingtoemergingtechnologyiswhencapitalisbeingbet.Oneofthelargest
wagersmadeonnewplasticisthatplacedbyNatureWorksLLConpolylactides
(PLA), a plastics made from a bio-based monomer created by fermenting corn.
NatureWorkshasinvested$750millionand10yearsofR&DontheirNatureWorks
PLAplant,whichrecentlybeganoperation.
Anothermeasureofanemergingmarketishighgrowthrate,typicallyatorabove
10%.Bythisdeinition,plasticpalletsnotthoughtofasnewareanemergingmar-
ket.Globaldemandisstillgrowingatbetterthan10%/year,andnosingleproduc-
tionprocessisyetpredominantintheirmanufacture.Mostapplicationsonreaching
theirapexwillhaveoneprocessdominate,ortwocompetetosomedegree.Forpal-
letprocessing,thereareatleastfourplasticsprocessesextensivelyused:injection
molding, rotational molding, single- or twin-sheet thermoforming, and structural
foam molding. Elsewhere, business is booming in blown ilm for stretch–hood
applications.InEuropealonethestretch–hoodwebmarketisprojectedtogrowby
morethan22%/yearthrough2012,comparedto5.5%/yeargrowthforstretchilm.
AdvancedCeramicsResearch(ACR)Inc.hasdevelopedanewtypeofartiicial
bonestrongenoughtosupportnewbonegrowthbutporousenoughtobeabsorbed
andreplacedbythehumanbody.Thematerialdeveloped,dubbed‘Plasti-Bone,’
ismadefromabiologicallycompatibleplasticwithaceramiccoating.Themate-
rial which the company expects to reach market within 5 years holds promise
overmetallicinserts,whichcannotbeabsorbedbythebodyandmusteventually
bereplaced,andalsobiologicalmaterialsthataretoobrittletosupportanysig-
niicantforce.
In the case of a crushed arm bone for example, doctors could convert bone
scansofthegoodarmintocodefortheconstructionofareplacementpartforthe
injured arm bone. The code would be used by rapid prototyping equipment to
makethedesiredartiicialbonesegmentfromapolymercoatedwithathinlayer
ofporouscalciumphosphate.NaturalbonebeginsbondingtothePlasti-Bonein
8 weeks. Eventually, the implant is ‘bioresorbed’ replaced by new bone tissue.
ACR developed the material under a grant from the Ofice of Naval Research,
whichisseekingadvancedbonetreatmentsforthewounded.Theabilitytouse
rapidprototypingtechnologytoquicklycreatecustomitartiicialbonematerial
90 7 Medical,Emerging,andOtherEndUseApplications
is a major beneit of the product. The tissue engineering market is expected to
reach$80billioninsalesby2012.
SarnatechBNL,aspecialistdesignerandmanufacturerofinnovativeplasticbearing
solutions,hasteamedwithKVHIndustriestoproducetwomoldedpartsforKVH’s
new TracVision A5 for cars. The system allows access to satellite TV while the
vehicle is moving, using a roof-mounted pancake-shaped satellite TV antenna
designedspeciicallyforpassengervehicles.Motorsrotatetheantennaasthecar
turns. A computer control device keeps track of signal strength and rotates the
antennatokeepitpointedatthesatellite.
Abearingandagiantthrustraceformtheantenna’smobilebase.Withheightof
thelow-proileantennaixedat4.5in.,anultrathinbearingwasrequired.Sarnatech
designedabearing3/8in.highusingBASF’sUltraformPOM(polyoxymethylene)
copolymer,withthepitchcircleoftheracewayaslargeaspossibletooffermaxi-
mumsupport.Integratedfeaturesincludebeltdriveteeth,brassinsertstoafixitto
theantennaunit,andmoldedpadsforstability.Usingplasticinsteadofsteelcutthe
bearingweightby50%andcostsbyathird.Agiantthrustracewitha25in.outside
diameterwasdesignedtosupporttheperimeterofthe30.5in.wideantenna.This
largePOMpartwasformedineightidenticalsectionswitheachsectionmoldedin
oneshot.Theeightsectionsoftheinishedthrustraceittogethereffortlesslyby
meansofanintegralclipconnectiondesign.
BreeCollectionGmbH,aninternationalleatherandbagspecialist,hascreatedan
illuminatedbusinesshandbagusingSmartSurfaceTechnology(SST).Breehad
beentoyingwiththeideaofilluminatingthedarkinsidesofhandbagsforsome
time,butlackedanelegantsolution.TheanswerisnowavailableasSmartSurface
TechnologydevelopedbyBayerPolymers,inpartnershipwithLumitec,aspe-
cialistinelectroluminescence(EL)andprecisionelectroniccomponents.ELisa
methodofgeneratinglightreminiscentofthechemicalmethodemployedbyire-
lies. Engineers are using a ilm that lights up on application of a voltage to
achieveelectroluminescence.AnadvantageofEListhatitdoesnotproduceheat.
However until now, only lat surfaces of limited size could be achieved. Smart
SurfaceTechnologymakesitpossiblefortheilmstobeshapedtoilluminateany
conceivablegeometry.Incorporatedinanonconductivelayer,theilminBree’s
handbaglightsupatthepressofabutton.BayerPolymers,seesthemainapplica-
tion for this technology in the auto industry. Incandescent lamps in cars will
7.3 OtherApplications 91
becomeobsolete.Instrumentpanelswillbedesignedtotakeuplessroomanda
car’sinteriorheadlinerwillglowinasoftglarefreelight.
Malden Mills Industry’s Polartec Heat Technology provides warmth on demand
duringstopandgoactivities.Batterypowered“PolartecHeat”polyesteribercloth-
ingpanelsreducetheneedtoaddorsubtractlayersofclothingasweatheroractivity
levelschange.Thethin,lexible,lightweightpanelsaredurable,machinewashable,
anddesignednottointerferewithagarment’sfunction.Theheatcontrollerwitha
molded PBT/ABS alloy housing provides temperature adjustment as necessary
usingthreemodes:fullpower,oscillate,orpoweroff.Theheatpanelsarepowered
by lightweight lithium ion batteries, rechargeable without removal from the gar-
ment,usingstandard110Vhouseholdcurrent,asolarpoweredcharger,oravehi-
cle’s12Vcigarettelighterport.Batterylifeis5honoscillateand2.5honfull
power.
Thermal Mannequin Testing at the US Army Natick Soldier Systems Center
havedemonstratedtheincreaseinthermalinsulation(clo).Whensetonlow,Polartec
HeatTechnologyaddsanadditional.093clotothebody’smicroclimate,theequiva-
lentofaddinganadditionallayerofPolartec100Seriesleece.Whensetonhigh,
anadditional1.51cloisaddedtothebody’smicroclimate,equivalenttoaddingan
additional layer of Polartec 300 Series leece. This “virtual layering” allows the
wearertoquicklyaddandsubtractinsulationatthetouchofabutton.
Numerous US plastics injection molders have discovered that the best offense
againstglobalcompetitionisagooddefense–i.e.,manufacturingforthelargest
purchaserofgoodsandservicesintheworld,theUSDept.ofDefense.Themili-
tarybudgetforFY2011is$600billionwithmorethanhalfthatspentonhardware.
Considering the homeland security implications, the military/defense market is
onemarketplacethatisdeinitelynotgoingoffshore.Manynewapplicationsunder
development call for the lightweight functionality that plastic parts can provide
andmirrormanyoftheopportunitiesforplasticsinthenonmilitarymarkets,such
as aerospace, vehicular equipment and components, building and construction,
E/E,telecom,medical/dental,appliances,packaging,andITparts.Innonmilitary
governmentmarkets,thereissigniicantopportunityforplasticsandplasticparts
92 7 Medical,Emerging,andOtherEndUseApplications
producers as much of the North American and European infrastructure, from
bridges to tunnels, power and pipelines to telephone poles and street light stan-
dardsandlightingsystems,builtinthe1950sand1960sneedstoberenovated,
rebuilt,orreplaced.
InresponsetoEuropeanpassivesafetylegislation(EN12767,introducedtoreduce
deaths/seriousinjuriesresultingfromvehiclescollidingwithroadsidestructures)col-
lapsingplasticlightposts,abletoabsorbmuchoftheforceinacollision,havebeen
developedasaEurekaproject(apan-Europeannetworkformarket-oriented,indus-
trialR&D).Thereareapproximately165millionutilitypoles,andsimilarstructures
inusethroughoutEurope(16millionintheUK)with200motoristdeathsand3,000
injuries/yearintheUKinvolvingcarscollisionswithsteelorconcretelightingcol-
umns.Thesecolumnsandpoles,insteel,aluminum,wood,orreinforcedconcrete,are
pronetocorrosionduetothecombinationofroadsalts,groundconditions,anddog’s
urine,limitingtheirlifeto20–25yearsandnonebehaveinapassivesafemanner.
‘Thermopole’ lamp post, a iber reinforced plastics post, developed by Euro-
ProjectsLtd.,islightweight,durable(40yearslife),maintenancefree,andismade
of the only material to demonstrate passive safety performance when tested in
accordancewiththenewEuropeanstandard.FRPmaterialsbasedonthermosetting
polyesterresins,usedwidelyinlagpoleconstruction,notbeenusedincolumnsand
signposts due to high cost, and lack of engineering conidence. Thermopole can
withstandtheelements,includinghighwinds,butfailswhenacarhitsit,crumbling
or hinging to absorb the impact. Prototypes are stronger than steel, maintenance
free,andrecyclable.Over400compositelightingcolumnshavebeeninstalledin
theUKonatrialbasis.Todatetherehavebeenfourmajorhigh-speedaccidents
involvingthecompositecolumnsresultinginnodeaths.
Dow’sContinuumbimodalPEresinsoffertheopportunitytoinstallanew,virtually
leak-free pipe system or to cost-effectively rehabilitate an existing system using
trenchless technology. The Continuum bimodal PE resins made by proprietary
UnipolIIprocesstechnologyareafamilyofperformancedifferentiatedPEresins
developedfortheundergroundconstructionmarket.ThesePEresinsprovidelonger
lifeexpectancyandoutstandingstrengthforpressurepipeandittingsusedinwater
and natural gas distribution, mining, and oil/gas processing. The resins offer
improvements in long-term strength, temperature performance, and resistance to
slow crack growth and rapid crack propagation compared to traditional PE pipe
7.3 OtherApplications 93
materials.TheperformanceadvantagesofContinuumBimodalPEresinsprovide
anidealsolutionforhelpingixthenation’sagingwater,wastewater,andnatural
gasdistributioninfrastructure.
SekisuiChemicalhasdevelopedanewcompositethree-layerPEpipethathassupe-
riorstrengthtoconventionalPEwaterpipes,allowingsigniicantreductionofwall
thicknessesandrawmaterialcoststhatmorethanoffsetshigherproductioncosts.
Thecompany,whichisexploringlicensingthetechnology,suppliesthepipesunder
thebrandnameEslonPEUltra.OneareaoffocusforSekisui’sUrbanInfrastructure
andEnvironmentalProductssubsidiarythatproducesthenewpipeisonnewinstal-
lationsforwatersupplyandsewerpipelinesaswellasreplacementsofconventional
pipeswithanti-corrosivepiping.
The pipes consist of inner and outer layers of HDPE sandwiching a sheet of
highlystretched(20–30fold),highlyoriented,spiral-woundEcosurfHDPEsheet.
Theinnerlayerisirstextruded,andthesheettheniswoundroundthisinnerlayer.
Thesemi-inishedpipeisnextfedthroughaspecialextrusiondietoaddtheinal
layer.Thesheethasatensilemodulusof15GPa,atensilestrengthof500MPa,and
elongation of 10%. The complex process is cost-effective for pipes with outside
diametersof200mm,while400mmpipesare30%lowerincost.A200mmEslon
PEUltrapipehashalfthewallthicknessofSekisui’ssingle-layerPEpipes,allow-
ingasingleworkertocarrya5mlongpipe,easinginstallation.Theirstcommer-
cial application of the product was in high-pressure piping to pump water up a
mountainsideinNaganoPrefecture.
TheUCAV-N,unmannedcombatairvehiclefortheNavy,isenvisionedasaship-
based, ‘irst day of the war’ force multiplier. Designed with stealth features and
shaped like a kite, Pegasus is constructed largely with composite materials. The
aircraftmeasures27.9feetlongandhasanearlyequalwingspanof27.8feet.The
goalofthejointDARPA/Navyprojectistodemonstratethetechnicalfeasibilityfor
aUCAVsystemtoeffectivelyandaffordablyconductsea-basedtwenty-irstcentury
surveillance, suppression of enemy air defenses, and strike missions within the
emergingglobalcommandandcontrolarchitecture.NorthropGrumman’sX-47A
hassuccessfullylandednearapredesignatedtouchdownpointtosimulatethetail-
hookarrestmentpointonacarrierlightdeck.Theshipboard-relativeglobalposi-
tioning satellite system is used as the primary navigation source for increased
landing precision.
94 7 Medical,Emerging,andOtherEndUseApplications
Since1990,theplasticsindustry,asindividualcompaniesandthroughorganizations
suchastheAmericanPlasticsCouncil,hasinvestedmorethan$1billiontosupport
increased recycling and educate communities in the United States. Conserving
resourcesmeansusinglessrawmaterialsandenergythroughoutaproduct’sentirelife
from development through disposal. Plastics are derived from natural resources –
typicallyoilandnaturalgas.Andyet,becauseofplastics’uniquecharacteristics–
lightweight, durability, formability – they often conserve more resources during a
product’slifewhencomparedtoothermaterials.Whiletherehasbeenmuchdiscus-
sionintheUSregardingwastemanagement,recycle,andresourceconservation,both
EuropeandJapanaregloballeadersinintroducinglegislationandimplementingpro-
gramstocontrolwastemanagementandconserveresources.
JennmarCorp.,togetherwithTerrasimcoInc.,NapcorandtheTOPBottleProject
have announced a major new technology and application use for post-consumer
PETbottlematerial.TheprocessdevelopedbyTerrasimcoInc.,aMartinsburgWV
technology company, has been licensed by Jennmar and will be used to produce
new types of roof bolt products used to reinforce coal and other shaft mines.
Pittsburgh-basedJennmaristheworld’sleadingsupplierofroofcontrolproducts
fortheminingandtunnelingindustries.Jennmarhassixmanufacturingfacilitiesin
theUS,twoinAustralia,andanewplantunderconstructioninChina.Thenewbolt
willeliminatethetwo-stepsystempreviouslyusedtoinstalltheboltintothemine
roof,byapplyingapolyester-basedcompounddirectlyontothebolt.Thenewprod-
uctiscalledthe‘BuddyBar’tohighlightthebuddysystemthatisusedinthemines
duringtheinstallationofthereinforcingsystem.
Napcor (National Association for PET Container Resources) provided the
expertise in identifying, developing, and sourcing appropriate post-consumer
materials.TheassistanceprovidedbyNapcorwaspartoftheTOPBottleProject
initiated by Napcor to eliminate the barriers that prevent all PET bottles from
beingrecycledirrespectiveofcolororconstruction.Jennmarexpectstohavethe
irstofiveprojectedretroitsoperationalbythefourthquarter2004.Demandfor
thepost-consumermaterialsisanticipatedtobeasmuchas15millionlbbythe
end of 2005.
CarpetrecyclingconsortiumCARE(CarpetAmericaRecoveryEffort)hasestab-
lished an economic way to pelletize unwashed, recycled nylon carpet. CARE, a
7.3 OtherApplications 95
jointly sponsored industry and government initiative, was established to increase
therecycle/reuseofpost-consumercarpetandreducethedisposalofwastecarpetin
landills. More than 2.5 million tons of carpet are discarded each year and with
landillcapacitydeclining,thereisanenvironmentalneedtorecycle/reusecarpet.
Asusedcarpetisheavyandbulkytohandle,itisdificultandexpensivetomanage
posingaburdenonwasteprocessorsandoftenresultsintheillegaldisposalofcar-
petbythegeneralpublic.
CAREworkedontheproblemofusedcarpetdisposalfor3yearswithtwoengi-
neering irms, Project Consultants & Associates Inc. of Florida, and Superior
PolymerSystemsInc.ofON,Canada.Themeltcompoundinganddensiicationof
shreddedcarpetprovedtooexpensive.CAREfoundthatamoreviablesolutionwas
to‘cold’pressthecarpetwasteinapelletmill.Thecompressedpellets,0.25–0.50in.
indiameterand0.50–0.75in.long,contain46%nyloniber,35%calciumcarbonate,
10% polypropylene, and 9% styrene-butadiene rubber. The pellets are reused by
meltblendingat10–50%levelswithapolyolein.Thenylonibers,whichdonot
meltinthepolyoleinmatrix,provide85%ofthepropertiesofacomparablequan-
tityofglassiberofsimilarlength.Carpetpelletshavebeentestedasstiffenersfor
polyoleinrailroadties,marinepilings,anddecking.Pellettestquantitiesareavail-
ablefromCARE.
DuPontCompositeRecycleTechnology,aclosed-loopnylonrecyclingprocess,can
convert parts made of glass or mineral illed nylon 6 or 66 into irst-use quality
materialinawaythatiseconomicallyviableandenvironmentallyresponsible.The
newDuPontCompositeRecycleTechnologymarksagiantstepforwardinhelping
automakers meet the European Union’s mandates for end-of-life vehicle (ELV)
closed-looprecycling.TheEUdirectiverequiresthat85%byweightofavehiclebe
capableofrecoveryandreusebytheendof2005(versus75%currently).Resultsof
‘in-use’ testing of recycle content material generated by a development program
withDensoCorp.(www.globaldenso.com)showCompositeRecycleTechnology
(CRT)canbeoneofthemosteffectivetechnologies.
Thefeedstockforthestudyconsistedof500radiatorendtankscollectedfrom
scrappedend-of-lifevehiclesinJapan.Allofthetanksweremadeofglassrein-
forcednylon66.Thetanksweredirty,andthematerialhadbeendegradedbyyears
ofcontactwithhotenginecoolant.CRTdissolvestheusedpolyamide,thenilters
awaycontaminantsandillers.Themolecularweightoftherecoveredpolyamideis
increasedtowhateverlevelisthedesiredfortheinalapplication.Theprocessgen-
eratesresinequivalenttovirginnylon.Thestudiesconirmedtheprocess’scapabil-
itytoconvertnylonautopartsfromscrappedvehiclesintoglassreinforcednylon
resinsandpartswithpropertiesequivalenttothoseofvirginnylonsforaworkable,
cradle-to-cradlesolutionofradiatorendtanks.Theprocesscanlikelybeadaptedto
recycleairintakemanifoldsandothernylonparts.
96 7 Medical,Emerging,andOtherEndUseApplications
AstudyrecentlyreleasedbyPlasticsEurope(formerlytheAssociationofPlastics
Manufacturers in Europe – APME) showed that mechanical recycling of plastic
partsfromcarsisfavorablefromaneco-eficiencypoint-of-viewonlywherelarge,
easily accessible, monomaterial parts are concerned. Feedstock recycling and
energyrecoveryarethemosteffectivemethodsforrecoveringplasticsinend-of-life
carsinthemajorityofcases.Thereportprovidedtheirstquantitativedataforthe
comparisonofrecyclingandenergyrecoveryoptionsforplasticspartsinend-of-life
vehicles(ELV)andwillbeanimportantconsiderationindeterminingthefateof
8millioncarsreachingtheendoftheirusefulliveseachyearinEurope.Theuseof
plasticsincarsissteadilygrowingandby2015itisexpectedthat1.3milliontonnes
ofplasticswastewillcomefrom12millionend-of-lifevehicles.
Six plastics waste management options (mechanical recycling, blast furnace,
cementkiln,syngasproduction,wastecombustion,landill)wereanalyzedinthe
studywithafocusonsevenvehiclecomponents(bumper,seatcushion,intakemani-
fold,washliquidtank,airduct,headlamplens,mirrorhousing).Keyindingsofthe
studywere(1)mechanicalrecyclingisthemethodofchoicemainlyforlarge,easily
accessible,monomaterialparts.(2)Formostparts,feedstockrecyclingoptionsand
energyrecoveryarethemethodsofchoice.(3)Wholelife-cycleanalysisshowsthat
theusephaseofplasticspartsincarsthathavethelargestcontributiontotheenvi-
ronmental impacts. (4) Landill shows the worst eco-eficiency of all the options
studied.
Polyethyleneirrigationtubingisaninexpensivewaytoirrigatecrops,butitiseasily
contaminatedwithsoilandvegetationduringthegrowingseasonandisdificultto
reuse.Thetubing,whichcanwindthroughmilesoffarmland,istypicallyusedfor
onlyoneseasonbeforeitisreplacedandcreatesamajorwastestreamforfarms.
Polyethyleneirrigationtubingmanufacturer,DeltaPlastics,hascreatedarecy-
clingsystemtocollecttheusedmaterialforrecycle.DoubleGFarmofArkansasis
oneoperationthatrecyclesitspipetoridthefarmofawastestream.The4,600acre
farmuses120rolls,or30milesofpipeayear.ThePEtubingiseasiertoinstall,
easier to pick back up, and is less expensive to handle than aluminum irrigation
systems. Delta Plastics operates 104 collection sites traveling up to 300 miles at
leasttwiceayeartoeachsitetopickupusedpipe.Farmerswhoutilizethecom-
pany’srecyclingservicemustbuytheirnewpipefromDelta.Thepipeisreturnedto
the Delta Plastics plant in Stuttgart, AK, where it is cut, washed, and pelletized.
Becauseofweathering’snegativeeffectontheplastic’sproperties,theusedmaterial
isnotrecycledintonewirrigationpipe.Makersoftrashbagsandparkingstopsare
themainconsumersofthepellets.From1998throughtheendof2002,DeltaPlastics
recycled70millionlboftheirrigationtubing.
Chapter 8
Plastics End Use Applications
Company Source Guide
Keywords Plastics•Metal•Rubber•Paper•Wood•Glass•Ceramic•Endusers
•Fabricators•Suppliers
Thissourcematerialcoverstheiveprimarycompetitivematerialareasandtheirinter-
acting20majorplasticendusemarketsegments.Featuredare250keymarketleader
corporatesources,and375othermajorcompanysources.Fororganizationalpurposes
the25majorareasarearrangedintoivegroupsofiverelatedsegments,consistingof
onegroupofcompetitivematerialsandfourgroupsofendusemarkets.
Withineachofthe25segmentstherearetwosubdivisionswhichconsistoften
keymarketleadingcorporationsand15othermajorcompanies,organizedalpha-
beticallyineachcategory,foratotalof625entities.
Theirstsubdivision,Primary,coversthetoptenglobalstartingpointsforcom-
panyinformationinagivenareaofinterest.Thesecondsubdivision,Other,paral-
lelstheprecedingkeydatabasesourceapproachfromanidenticallypatternedbut
moreconcisemanner.Withineachofthesubdivisions,companiesarequaliiedon
thebasisofspeciicsegmentSalessize,technicalmarketingproductlinebreadth,
globaldiversiication,specialtynichepositioning,andoverallnetSales.
Tofacilitatecrosscomparisonandreviewofcompanysources,theivetables(one
foreachoftheivegroupsofivesegments)summarizeprimarykeymarketleading
and other major companies across the twenty-ive critical areas (ive competitive
materials,followedbytwentylargesttosmallestendusemarkets).Alsointhetables,
companiesareidentiiedassuppliers(“S”),fabricators(“F”),Endusers(“E”),orcom-
binationsthereof.Salesdollariguresarein$USforeaseofcomparison(B=billion).
Companycountryoforiginisindicatedbytwolettercodesinparenthesis.
8.1.2 Plastic, Metal, Paper & Wood, Rubber, Glass & Ceramic
Companies
BASFAG(DE);S DSMN.V.(NL);S/F
www.basf.com www.dsm.com
Sales:$7.2billion
FerroCorporation(US);S
BayerAG(DE);S www.ferro.com
www.bayer.com
Sales:$11.6billion MannesmannPlasticsM(DE);S
www.mannesmann-plastics.com
DowChemicalCo.(US);S/F MilicronInc.(US);S
www.dow.com www.milacron.com
Sales:$13.57billion
PolyoneCorporation(US);S
DupontCompany(US);S/F www.polyone.com
www.dupont.com
Sales:$18.4billion Rohm&HaasCo.(US);S
www.rohmhaas.com
EastmanChemicalCo(US);S SinochemCorporation(CN);S
www.eastman.com www.sinochem.com
Sales:$2.6billion
SMSPlasticsTech.(DE);S
EquistarChem.LP(US);S www.sms-k.com
www.equistarchem.com
Sales:$5.54billion SolvayS.A.(BE);S
www.solvay.com
ExxonMobilChemical(US);S TiconaInc.(US);S
www.exxonmobil.com/chemical www.ticona-us.com
Sales:$20.3billion
TotalFinaElf-Atoina(FR);S/F
G.E.Plastics(US);S/F www.atoina.com
www.geplastics.com
WellmanInc.(US);S/F
Sales:$5.3billion
www.wellmaninc.com
8.1 PlasticandRelatedMaterialsSegments 99
Metal Paperandwood
Primary Other Primary
AlcanInc.(US);S/F AKSteelCorporation(US);S/F GeorgiaPaciic(US);S/F
www.alcan.com. www.aksteel.com www.gp.com.
Sales:$11.72billion Sales:$18.95billion
ASARCOInc.(MX);S/F
AlcoaInc.(US);S/F www.asarco.com InternationalPaper(US);S/F
www.alcoa.com www.internationalpaper.com
Sales:$17.5billion BethlehemSteel(US);S/F Sales:$16.70billion
www.bethsteel.com
Arcelor(ES,LU,FR);S CommercialMetals(US);F Kimberly-Clark(US);F
www.arcelor.com www.commercialmetals.com www.kimberly-clark.com
Sales:28.6billion Sales:$14.5billion
INCOLtd.(CA);S
CorusGroupplc(UK);S/F www.inco.com MeadWestvacoCorp.(US);F
www.corusgroup.com www.meadwestvaco.com
Sales:$11.4billion InternationalSteelGrp.(US);S/F Salesest.:$6.86billion
www.ltvsteel.com
KobeSteel,Ltd.(JP);S/F ISPATInt’lN.V.(NL);S/F NipponPaperInd.Co.(JP);F
www.kobelco.co.jp www.ispat.com www.npaper.co.jp
Sales:$6.28billion Sales:$9.14billion
KawasakiSteelCorp.(JP);S/F
NipponSteelCorp.(JP);S/F www.kawasaki-steel.co.jp OJIPaperCo.Ltd.(JP);S/F
www.nsc.co.jp www.ojipaper.co.jp
Sales:$13.88billion MaxxamInc.(US);S/F Sales:$7.90billion
www.kaiseral.com
NKKCorporation(JP);S/F NucorCorporation(US);S/F SAPPILtd.,(ZA);S/F
www.nkk.co.jp www.nucor.com www.sappi.com
Sales:$9.73billion Sales:$3.73billion
PhelpsDodgeCorp.(US);S/F
POSCOLtd.(KR);S/F www.phelpsdodge.com StoraEnsoOYJ(FI);S/F.
www.posco.co.kr www.storaenso.com
Sales:$9.45billion RyersonTull,Inc.(US);S/F Sales:$13.76billion
www.ryersontull.com
RioTintoplc(UK);S SandvikAB(SE);S/F UPM-Kymmmene.(FI);F
www.riotinto.com www.sandvik.com www.upm-kymmene.com
Sales:$10.83billion Sales:$8.0billion
TeckComincoLtd.(CA);S
USSteelCorporation(US);S/F www.teckcominco.com WeyerhaeuserCo.(US);S/F.
www.ussteel.com www.weyerhaeuser.com
ThyssenKrupp(DE);S/F
Sales:$6.95billion Sales:$15.1billion
www.thyssenkrupp.com
(continued)
100 8 PlasticsEndUseApplicationsCompanySourceGuide
Glassandceramic
Primary Other
AsahiGlassCompany(JP);S/F Cemex,S.A.deC.V.(MX);S
www.agc.co.jp. www.cemex.com
Sales:$10.34billion
CooksonGroupplc.(UK);S
Carl-Zess-Stiftung(DE);F www.cooksongroup.co.uk
www.zeiss.com
Sales:$2.43billion DonnellyCorporation(US);F
www.donnelly.com
CorningInc.(US);S/F EngelhardCorporation(US);S
www.corning.com www.engelhard.com
Sales:$3.16billion
FisherScientiicInt’lInc.(US);F
ElkemASA(NO);S www.isherscientiic.com
www.elkem.com
Sales:$0.70billion GuardianInd.Corp.(US);F
www.guardian.com
KyoceraCorporation(JP);S/F Harbison-WalkerRefract.(US)S
www.kyocera.co.jp www.hwr.com
Sales:$8.76billion
JohnsManvilleCorp.(US);F
LaFargeS.A.(FR);S www.jm.com
www.lafarge.fr
Sales:$15.73billion LancasterColonyCorp.(US);F
www.glassonline.com
OwensCorning(US);S/F MorganCrucibleCo.(UK);S
www.owenscorning.com www.morgancrucible.com
Sales:$4.87billion
N.A.RefractoriesCo.(US);S/F
Pilkingtonplc(UK);F www.hwr.com
www.pilkington.com
Sales:$4.56billion SeikoEpsonCorporation(JP);F
www.epson.co.jp
PPGIndustries,Inc(US);S/F TaiheiyoCementCorp.(JP);S
www.ppg.com www.taiheiyo-cement.co.jp
Sales:$2.67billion
TosohCorporation(JP);F
SaintGobainGroup(FR);S/F www.tosoh.com
www.saint-gobain.fr
Sales:$20.48billion WaterfordWedgewood(IE);F
tel: +353-147-8155
102 8 PlasticsEndUseApplicationsCompanySourceGuide
GroupoVitro(MX);F GerresheimerGroup(DE);F
www.vto.com www.gerresheimer.com
Sales:$0.95billion
GreifBrothersCorp.(US);F
Owens-Illinois,Inc.(US);F www.greif.com
www.o-i.com
Sales:$5.64billion HuhtamakiOYJ(FI);S/F
www.huhtamaki.com
PactivCorporation(US);F MenashaCorp.(US);S/F
www.pactiv.com www.menasha.com
Sales:$2.88billion
PackagingCorp.(US);F
PechineyS.A.(FR);S/F www.packagingcorp.com
www.pechiney.com
Sales:$2.52billion PlastipakPackagingInc.(US);F
www.plastipak.com
Smurit-StoneContainer(US);F Printpack,Inc.(US);F
www.smurit-stone.com www.printpack.com
Sales:$7.48billion
Rexamplc(UK);F
SonocoProductsCo(US);S/F www.rexam.co.uk
www.sonoco.com
Sales:$2.81billion SealedAirCorp.(US);F
www.sealedaircorp.com
TempleInlandInc.(US);S/F SilganHoldings,Inc.(US);F
www.temple-inland.com www.silgan.com
Sales:$2.59billion
SoloCupCompany(US);F
ToyoSeikanKaisha(JP);S/F www.solocup.com
www.toyo-seikan.co.jp
SweetheartCupCo.(US);F
Sales:$3.49billion
www.sweetheart.com
8.2 MajorandIntermediatePlasticEndUseMarketSegments 103
Appliance
Primary Other
Bosch-Siemens(DE);F/E ApplicaInc.(US);F/E
www.bsh-group.com www.applicainc.com
Sales:$5.4billion
ElcoBrandtS.A.(FR);F/E
CarrierCorporation(US);F/E www.elcopourbrandt.com
www.global.carrier.com
Sales:$8.77billion FeddersCorporation(US);F/E
www.fedders.com
Electrolux,AB(SE);F/E GoodmanMfg.Co.(US);F/E
www.electrolux.com www.goodmanmfg.com
Sales:$13.04billion
GroupeSEB(FR);F/E
G.E.ConsumerProd.(US);F/E www.groupeseb.com
www.geappliances.com
Sales:$6.07billion NACCOHousewares,(US);F/E
www.hambeach.com
MaytagCorporation(US);F/E JukiCorporation(JP);F/E
www.maytagcorp.com www.juki.co.jp
Sales:$4.66billion
LennoxInternational(US);F/E
Miele&CIE,GmbH.(DE);F/E www.lennoxinternational.com
www.miele.de
Sales:$2.42billion Melitta(DE);F/E
www.melitta.de
SunbeamCorp.(US);F/E MerloniElettrodomestici(IT);F/E
www.sunbeam.com www.merloni.com
Sales:$1.7billion
NortekHoldingsInc.(US);F/E
TheTraneCompany(US);F/E www.nortek-inc.com
www.trane.com
Sales:$4.74billion TheRivalCompany(US);F/E
www.rivco.com
WhirlpoolCorporation(US);F/E SaltonInc.(US);F/E
www.whirlpoolcorp.com www.saltoninc.com
Sales:$11.02billion
SingerNV(CN);F/E
YorkInt’lCorporation(US);F/E www.singerco.com
www.york.com
Sales:$3.84billion VorwerkandCompany(DE);F/E
www.vorwerk.de
106 8 PlasticsEndUseApplicationsCompanySourceGuide
BectonDickinson(US);F/E C.R.Bard,Inc.(US);F/E
www.bd.com www.crbard.com
Sales:$2.15billion
GambroAB(SE);F/E
BostonScientiic(US);F/E www.gambro.com
www.bsci.com
Sales:$2.92billion Hill-RomCo.(US);F/E
www.hillenbrand.com
GEMedicalSystems(US);F/E KendallCompany,The(US);F/E
www.gemedicalsystems.com www.kendallhq.com
Sales:$8.96billion
MedlineIndustries(US);F/E
GuidantCorporation(US);F/E www.medline.com
www.guidant.com
Sales:$3.24billion OmronCorporation(JP);F/E
www.omronhealthcare.com
Hoffmann-LaRoche(CH);F/E StJudeMedical(US);F/E
www.roche.com www.sjm.com
Sales:$5.31billion
Smith&Nephewplc(UK);F/E
Johnson&Johnson(US);F/E www.smith-nephew.com
www.jnj.com
Sales:$19.15billion StrykerCorporation(US);F/E
www.strykercorp.com
Medtronic,Inc.(US);F/E SybronDental(US);F/E
www.medtronic.com www.sybrondental.com
Sales:$6.41billion
Wyeth(US);F/E
SiemensMedical(DE);F/E www.wyeth.com
www.siemensmedical.com
Sales:$8.20billion ZimmerHoldings,Inc.(US);F/E
www.zimmer.com
8.2 MajorandIntermediatePlasticEndUseMarketSegments 107
Consumerproducts Toy
Primary Other Primary
EastmanKodakCo.(US);F/E BoseCorporation(US);F/E BandaiCo.,Ltd.(JP);F/E
www.kodak.com www.bose.com www.bandai.com
Sales:$6.52billion Sales:$1.65billion
CarrefourSA(FR);E
GilletteCo.,The(US);F/E www.carrefour.com Hasbro,Inc.(US);F/E
www.gillette.com www.hasbro.com
Sales:$8.453billion ConairCorporation(US);F/E Sales:$2.86billion
www.conair.com/corporate
LGElectronics(KR);F/E DaewooElectronics(KR);F/E K-BToys(US);E
www.lge.co.kr www.dwe.co.kr www.kbtoys.com
Sales:$6.88billion Sales:$2.0billion
FujiPhotoFilmCo.(JP);F/E
MatsushitaElectric(JP);F/E www.fujiilm.co.jp LegoCompany(DK);F/E
www.panasonic.co.jp/global www.lego.com
Sales:$11.88billion Ito-YokadoCo.,Ltd.(JP);E Sales:$1.1billion
www.itoyokado.iyg.co.jp
NewellRubbermaid(US);F/E LuxotticaGroup.SpA(IT);F/E LittleTikesCo.,The(US);F/E
www.newell-rubbermaid.com www.luxottica.it/english www.littletikes.com
Sales:$5.52billion Sales:$0.45billion
PolaroidCorporation(US);F/E
PioneerCorporation(JP);F/E www.polaroid.com Mattel,Inc.(US);F/E
www.pioneer.co.jp www.mattel.com
Sales:$3.53billion SamsungElectronics(KR);F/E Sales:$4.8billion
www.samsungelectronics.com
SanyoElectricCo.(JP);F/E SeikoCorporation(JP);F/E NintendoCo.Ltd.(JP);F/E
www.sanyo.co.jp www.seiko-corp.co.jp www.nintendo.com
Sales:$6.33billion Sales:$3.5billion
Snap-OnInc.(US);F/E
SonyCorporation(JP);F/E www.snapon.com SEGACorporation.(JP);F/E
www.sony.co.jp/en/sonyInfo www.sega.co.jp
Sales:$17.16billion TDKCorporation(JP);F/E Sales:$1.82billion
www.tdk.com
StanleyWorks,The(US);F/E TupperwareCorp.(US);F/E Toys“R”Us,Inc.(US);E
www.stanleyworks.com www.tupperware.com www.tru.com
Sales:$1.955billion Sales:$9.2billion
Wal-MartStoresInc.(US);E
3MCompany(US);F/E www.walmartstores.com TyInc.(US);F/E
www.mmm.com www.ty.com
Sales:$2.792billion YKKGroup(JP);F/E Sales:$0.85billion
www.ykk.co.jp
(continued)
108 8 PlasticsEndUseApplicationsCompanySourceGuide
Furniture
Primary Other
FurnitureBrandsInt’l(US);F/E AshleyFurniture(US);F/E
www.furniturebrands.com. www.ashleyfurniture.com
Sales:$2.398billion
BassettFurnitureInd.(US);F/E
HaworthInc.(US);F/E www.bassettfurniture.com
www.haworth.com
Sales:$1.66billion BushIndustriesInc.(US);F/E
www.bushfurniture.com
HermanMillerInc.(US);F/E ChromcraftRevington(US);F/E
www.hermanmiller.com Tel:(765)564-3500
Sales:$1.469billion
CraftmaticInd.(US);F/E
HONIndustriesInc(US);F/E Tel:(215)639-1310
www.honi.com
Sales:$1.692billion DorelIndustries,Inc.(CA);F/E
www.dorel.com
IKEAInternationalA/S(DK);E EthanAllenInc.(US);F/E
www.ikea.com www.ethanallen.com
Sales:$11.779billion
HunterDouglasNV(NL);F/E
KimballInt’l,Inc.(US);F/E www.hunterdouglas.com
www.kimball.com
Sales:$0.736billion KlaussnerFurniture(US);F/E
www.klaussner.com
Knoll,Inc.(US);F/E Leggett&Platt,Inc.(US);F/E
www.knoll.com www.leggett.com
Sales:$0.964billion
O’SullivanIndustries(US);F/E
LA-Z-BoyInc.(US);F/E www.osullivan.com
www.lazboy.com
Sales:$2.154billion PillowtexCorporation(US);F/E
www.pillowtex.com
MFIFurnitureGroup(UK);F/E SauderWoodworking(US);F/E
www.migroup.co.uk www.sauder.com
Sales:$2.065billion
SertaInc.(US);F/E
SteelcaseInc.(US);F/E www.serta.com
www.steelcase.com
Sales:$2.600billion Silentnight(UK);F/E
www.silentnight-holdings.co.uk
110 8 PlasticsEndUseApplicationsCompanySourceGuide
8.3.1 Specialty Office Products, Lawn & Garden, Marine & Boat,
Aerospace, and Industrial Companies
LexmarkInt’lGrp.(US);F/E DatacardCorporation(US)F/E
www.lexmark.com www.datacard.com
Sales:$4.356billion
A.B.DickCompany(US);F/E
MinoltaCo.,Ltd(JP);F/E www.abdick.com
www.minolta.com
Sales:$2.88billion Diebold,Inc.(US);F/E
www.dibold.com
NCRCorporation.(US);F/E EsselteAB(SE);F/E
www.ncr.com www.esselte.com
Sales:$2.963billion
FellowesManuf.Co(US);F/E
PitneyBowesInc.(US);F/E www.fellowes.com
www.pitneybowes.com
Sales:$2.32billion IKONOficeSol’ns(US);E
www.ikon.com
RicohCompanyLtd.(JP);F/E KonicaCorporation(JP);F/E
www.ricoh.com www.konica.co.jp
Sales:$11.168billion
MooreCorporationLtd.(CA);F/E
SharpieGroup(US);F/E www.moore.com
www.sanfordcorp.com
Sales:$1.8billion OcéN.V.(NL);F/E
www.oce.com
StaplesInc.(US);E PalmInc.(US);F/E
www.staples.com www.palm.com
Sales:$11.596billion
SocieteBICS.A.(FR);F/E
XeroxCorporation(US);F/E www.bic.fr
www.xerox.com
Sales:$7.95billion UnitedStationersInc.(US);E
www.unitedstationers.com
8.3 SpecialtyandNichePlasticEnduseMarketSegments 111
Lawnandgarden Marineandboat
Primary Other Primary
AmesTrueTemper(US);F/E AcornProducts(US);F/E AlstomS.A.(FR);F/E
www.ames-truetemper.com www.uniontools.com www.alstom.com
Sales:$0.58billion Sales:$1.081billiom
AgriumInc.(CA);F/E
Black/DeckerCorp.(US);F/E www.agrium.com BrunswickCorporation(US);F/E
www.bdk.com www.brunswickcorp.com
Sales:$0.98billion BlountInt’l,Inc.(US);F/E Sales:$3.111billion
www.blount.com
TheHomeDepot,(US);E CentralGarden&Pet(US);E DCN(FR);F/E
www.homedepot.com www.centralgardenandpet.com www.dcnintl.com
Sales:$4.41billion Sales:$1.61billion
DaveyTreeExpert,The(US);E
HusqvarnaAB(SE);F/E www.davey.com GeneralDynamics(US);F/E
www.international.husqvarna.com www.generaldynamics.com
Sales:$1.98billion GilmourManuf.Co(US);F/E Sales:$3.650billion
www.gilmour.com
LESCO,Ltd(US);F/E HomebaseLtd.(UK);E GenmarHoldingsInc.(US);F/E
www.lesco.com www.homebase.co.uk www.genmar.com
Sales:$0.511billion Sales:$1.00billion
HondaPowerEquip.(JP);F/E
MTDProducts,Inc.(US);F/E www.hondapowerequipment.com HyundaiHeavyInd.(KR);F/E
www.mtdproducts.com www.hhi.co.kr
Sales:$0.810billion LawnwareProducts(US);F/E Sales:$3.208billion
tel:(847)966-3400
MurrayInc.(US);F/E MakitaCorporation(JP);F/E MitsubishiHeavyInd.(JP);F/E
www.murrayinc.com www.makita.co.jp www.mhi.co.jp
Sales:$0.52billion Sales:$2.177billion
SakataSeedCorp.(JP);F/E
OrkinExterminatingCo.(US);E www..sakataseed.co.jp MitsuiEng.&Shipbuild.(JP);F/E
www.orkin.com www.mes.co.jp
Sales:$0.665billion SnapperPowerEquip.(US);F/E Sales:$1.008billion
www.snapper.com
ScottsCompany,The(US);F/E TextronGolfandTurf(US);F/E NorthropGrumman(US);F/E
www.scottscompany.com www.ttcsp.com www.nns.com
Sales:$1.76billion Sales:$4.74billion
USHome&GardenInc.(US);F
ToroCompany,The(US);F/E www.ushg.com SamsungHeavyInd.(KR);F/E
www.toro.com www.shi.samsung.co.kr
Sales:$1.399billion WoodstreamCorporation(US);F Sales:$1.54billion
www.woodstreamcorp.com
(continued)
112 8 PlasticsEndUseApplicationsCompanySourceGuide
Industrial
Primary Other
ABBLtd.(CH);F/E Briggs&StrattonCorp.(US);F/E
www.abb.com. www.briggsandstratton.com
Sales:$21.7billion
EatonCorporation(US);F/E
Caterpillar,Inc.(US);F/E www.eaton.com
www.cat.com
Sales:$18.602billion FanucLtd.(JP);F/E
www.fanuc.com
G.E.Industrial(US);F/E HalliburtonCo.(US);F/E
www.ge.com www.halliburton.com
Sales:$35.00billion
ITTIndustries,Inc.(US);F/E
IllinoisToolWorks(US);F/E www.ittind.com
www.itwinc.com
Sales:$9.22billion KawasakiHeavy.Ind.(JP);F/E
www.khi.co.jp
Ingersoll-RandCo.(US);F/E KomatsuLtd.(JP);F/E
www.irco.com www.komatsu.com
Sales:$9.51billion
NACCOMaterialsHd(US);F/E
KubotaCorporation(JP);F/E www.nacco.com
www.kubota.co.jp
Sales:$6.51billion NSKLtd.(JP);F/E
www.nsk.com
ManAG(DE);F/E ParkerHanniinCorp.(US);F/E
www.man.de www.parker.com
Sales:$6.85billion
Pentair,Inc.(US);F/E
MitsubishiElectric(JP);F/E www.pentair.com
www.mitsubishielectric.com
Sales:$17.74billion RockwellAutomation.(US);F/E
www.rockwellautomation.com
MitsubishiHeavy.Ind.(JP);F/E SchlumbergerLtd.(FR);F/E
www.mhi.co.jp www.slb.com
Sales:$15.21billion
SulzerLtd.(CH);F/E
SchneiderElectricS.A(FR);F/E www.sulzer.com
www.schneiderelectric.com
Sales:$9.754billion TimkenCompany,The(US);F/E
www.timken.com
114 8 PlasticsEndUseApplicationsCompanySourceGuide
Conagra,Inc.(US);E ChiquitaBrandsInt’l(US);E
www.conagra.com www.chiquita.com
Sales:$27.63billion
CNHGlobalN.V.(US);F/E
DanoneGroup(FR);E www.cnh.com
www.danonegroup.com
Sales:$14.237billion Deere&Company.(US);F/E
www.deere.com
GeneralMills,Inc.(US);E DoleFoodCompany(US);E
www.generalmills.com www.dole.com
Sales:$7.949billion
FarmlandIndustries.(US);E
KraftFoods,Inc.(US);E www.farmland.com
www.kraft.com
Sales:$29.723billion Frito-LayCompany.(US);E
www.fritolay.com
McDonald’sCorp.(US);E H.J.HeinzCompany(US);E
www.mcdonalds.com/corporate www.heinz.com
Sales:$15.406billion
HormelFoodsCorp.(US);E
NestléS.A.(CH);E www.hormel.com
www.nestle.com
Sales:$60.559billion KelloggCompany(US);E
www.kelloggs.com
SyscoCorporation(US);E McCormick&Company(US);E
www.sysco.com www.mccormick.com
Sales:$19.163billion
SaraLeeCorporation(US);E
Unileverplc(UK);E www.saralee.com
www.unilever.com
Sales:$28.48billion TysonFoods,Inc.(US);E
www.tyson.com
8.3 SpecialtyandNichePlasticEnduseMarketSegments 115
Wastemanagement Government
Primary Other Primary
AlliedWasteInd.(US);E BramblesIndustriesLtd.(AU);E BAESystemsplc(UK);F/E
www.alliedwaste.com www.brambles.com www.baesystems.com
Sales:$5.517billion Sales:$14.861billion
CalgonCarbonCorp.(US);F/E
DanaherCorporation(US);F/E www.calgoncarbon.com BechtelGroup,Inc(US);F/E
www.danaher.com www.bechtel.com
Sales:$3.385billion CasellaWasteSystems(US);E Sales:$8.52billion
www.casella.com
DoverIndustries(US);F/E CleanHarbors,Inc.(US);E BoeingInteg.Defense(US);F/E
www.dovercorporation.com www.cleanharbors.com www.boeing.com/ids
Sales:$1.124billion Sales:$19.97billion
CompactionAmerica(US);F/E
EbaraCorporation(JP);F/E www.uniteddominion.com BouyguesSA(FR);F/E
www.ebara.co.jp www.bouygues.fr
Sales:$2.21billion CraneEnvironmental(US);F/E Sales:$15.186billion
www.cranenv.com
PhilipServicesCorp.(CA);E ELGHanielGmbH(DE);E FluorCorporation(US);F/E
www.contactpsc.com www.haniel.de, www.elg.de www.luor.com
Sales:$1.119billion Sales:$8.30billion
GEOsmonics,Inc.(US);F/E
RepublicServices(US);E www.osmonics.com GeneralDynamics(US);F/E
www.republicservices.com www.generaldynamics.com
Sales:$2.365billion IonicsInc.(US);F/E Sales:$12.45billion
www.ionics.com
Safety-KleenCorp.(US);E KeldaGroupplc(UK);E KajimaCorporation(JP);F/E
www.safety-kleen.com www.keldagroup.com www.kajima.com
Sales:$1.515billion Sales:$11.14billion
NorcalWasteSystems(US);E
SuezSA(FR);F/E www.norcalwaste.com LockheedMartinCorp.(US);F/E
www.suez.fr www.lockheedmartin.com
Sales:$4.64billion ShawE&IInc.(US);E Sales:$23.92billion
www.shaw.grp.com
VeoliaEnvironment(FR);F/E SumitomoHeavyInd.(JP);F/E NorthropGrumman(US);F/E
www.vivendienvironnement.com www.shi.co.jp www.northgrum.com
Sales:$6.60billion Sales:$16.0billion
TetraTech,Inc.(US);E
WasteManagement(US);E www.tetratech.com RaytheonCompany(US);F/E.
www.wm.com www.raytheon.com
Sales:$11.142billion WasteIndustriesInc.(US);E Sales:$11.73billion
www.waste-ind.com
(continued)
116 8 PlasticsEndUseApplicationsCompanySourceGuide
Otherandemerging
Primary Other
ArmorHoldings,Inc.(US);F/E CaliperTechnologies(US);F/E
www.armorholdings.com www.calipertech.com
Sales:$0.305billion
Cree,Inc.(US);F/E
FriedeGoldmanH.(US);F/E www.cree.com
www.fgh.com
Sales:$0.246billion DigitalLightwaveInc.(US);F/E
www.lightwave.com
HainCelestialGrp.,The(US);E FiskarsCorporation(FI);F/E
www.hain-celestial.com www.iskars.i
Sales:$0.396billion
Hi-RiseRecyclingInc.(US);F/E
IndustrialDistribution(US);E www.hiriserecycling.com
www.idglink.com
Sales:$0.493billion Interiors,Inc.(US);F/E
www.interiors.com
KellstromIndustries(US);F/E JakksPaciic,Inc.(US);F/E
www.kellstrom.com www.jakkspaciic.com
Sales:$0.354billion
K-SwissInc.US);F/E
NCIBuildingSystems(US);F/E www.kswiss.com
www.ncilp.com
Sales:$0.953billion LandecCorporation(US);F/E
www.landec.com
SaltonInc.(US);F/E MatrixxInitiativesInc.,(US);F/E
www.saltoninc.com www.gum-tech.com
Sales:$0.923billion
PolymedicaCorp.(US);E
Scansource,Inc.(US);E www.polymedica.com
www.scansource.com
Sales:$0.842billion StandardAuto.Corp.(US);F/E
www.standardauto.com
SLI,Inc.(US);F/E SummaIndustries(US);F/E
www.sli-lighting.com www.summaindustries.com
Sales:$0.851billion
ThermoviewIndustries(US);F/E
Solectron,Inc.(US);F/E www.thermoviewinc.com
www.solectron.com
Sales:$12.27billion USPlasticLumber(US);F/E
www.usplasticlumber.com
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