Vectrabr e

Vectra ®
liquid crystal polymer (LCP)
• high melt flow,

easily fills long,
thin, complicated flow
paths with minimal
warpage
• heat resistant up to +340°C
• very good mechanical
strength, toughness
• excellent dimensional
stability
• fast cycling
• inherently flame retardant
• excellent organic solvent
resistance
• wide processing window
• flash-free manufacturing
Vectra® liquid crystal polymer (LCP)
Vectra®
Contents
1. Introduction and overview 9
2. Vectra product line 12

2.1 Grade descriptions 12
2.1.1 Glass fiber reinforced grades 12
2.1.2 Carbon fiber reinforced grades 12
2.1.3 Filler/fiber combinations 12
2.1.4 Mineral filled grades 12
2.1.5 Graphite filled grades 12
2.1.6 Specialty grades 12
2.1.7 Medical technology grades 13
2.2 Colors 14
2.3 Packaging 14
3. Physical Properties 15
3.1 Mechanical properties 16
3.1.1 Anisotropy and wall thickness 16
3.1.2 Behavior under short-term mechanical stress 18
3.1.3 Behavior under long-term mechanical stress 19
3.1.4 Behavior under impact stress 19
3.1.5 Behavior under cyclic stress 19
3.1.6 Tribological properties 20
3.1.7 Damping 21
3.2 Thermal properties 21
3.2.1 Dynamic mechanical analysis (DMA) 21
3.2.2 Deflection temperature under load 22
3.2.3 Coefficient of linear thermal expansion 23
3.2.4 Soldering resistance 24
3.2.5 Thermodynamics, heat of fusion 25
3.2.6 Outgassing behavior 26
3.3 Behavior on exposure to flame 26
3.4 Electrical properties 27
3.5 Rheological properties 30
3.6 Regulatory approvals and standards 30
3.6.1 Food contact / materials and articles 30
3.6.2 Drinking water applications 31
3.6.3 Medical / pharmaceutical applications 31
3.6.4 Underwriters Laboratories (UL) flame
classification 32
3.6.5 Canadian Standards Association (CSA)
flammability classification 32
3.6.6 Industry standards 32
3.6.7 Recycling 32
4. Behavior in relation to environmental effects 33

4.1 Hydrolysis 33
4.2 Chemicals and solvent resistance 34
4.3 Permeability to gases and vapors 36
4.4 Radiation resistance 36
4.5 Ultraviolet and weathering resistance 36
2
Vectra®
Introduction
5. Processing 38 and overview 1
5.1 Safety recommendations 38
5.1.1 Startup and shutdown procedures 38
5.1.2 Fire precautions 39
5.2 Drying 39
Vectra product line 2
6. Injection molding 41
6.1 Machine requirements 41
6.1.1 General 41
6.1.2 Screw design 41 Physical properties 3
6.1.3 Check ring 41
6.1.4 Nozzle 42
6.1.5 Hot runner systems 42
6.2 Processing conditions 43 Behavior in relation
6.2.1 Melt temperature 43 to environmental effects 4
6.2.2 Injection rate 43
6.2.3 Mold temperature 43
6.2.4 Screw speed 43
6.2.5 Back pressure 44
6.2.6 Screw decompression 44 Processing 5
6.2.7 Injection pressure 44
6.2.8 Holding pressure 44
6.2.9 Cycle time 44
6.3 Regrind 44
6.3.1 General recommendations 44 Injection molding 6
6.3.2 Equipment 45
6.3.3 Using regrind 45
6.4 Troubleshooting 46
6.4.1 Brittleness 46
6.4.2 Burn marks 46 Extrusion 7
6.4.3 Dimensional variation 46
6.4.4 Discoloration 47
6.4.5 Flashing 47
6.4.6 Jetting 47
6.4.7 Leaking check ring 47
Design 8
6.4.8 Nozzle problems 47
6.4.9 Short shots 48
6.4.10 Sinks and voids 48
6.4.11 Sticking 48
Secondary operations 9
6.4.12 Surface marks and streaks 48
6.4.13 Warpage and part distortion 49
6.4.14 Weld lines 49
7. Extrusion 50
Conversion Tables 10
7.1 Machine requirements 50
7.1.1 General 50
7.1.2 Screw design 50
7.1.3 Screen pack 50
7.1.4 Head and die 50 11
Subject index
7.1.5 Melt pump 51
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Vectra®
7.2 Processing 51
7.2.1 Film and sheet 51
7.2.2 Profiles 51
7.2.3 Pipe and tubing 52
7.2.4 Coating 52
7.3 Troubleshooting 53
7.3.1 General extrusion 53
7.3.2 Pipe and tubing 53
7.3.3 Profiles 53
7.3.4 Film and sheet 54
7.3.5 Coating 54
8. Design 55
8.1 Part design 55
8.1.1 Wall thickness 55
8.1.2 Flow length 56
8.1.3 Shrinkage 56
8.1.4 Draft angle 56
8.1.5 Warpage 56
8.1.6 Weld lines 57
8.1.7 Ribs, corners, radii 57
8.1.8 Holes and depressions 58
8.1.9 Snap-fits and press-fits 58
8.2 Mold design 58
8.2.1 Mold material 59
8.2.2 Mold finish 60
8.2.3 Runner systems 60
8.2.4 Gate location 61
8.2.5 Gate design 61
8.2.6 Gate types 62
8.2.6.1 Submarine (tunnel) gates 62
8.2.6.2 Pin gates 62
8.2.6.3 Film (fan) gates 62
8.2.6.4 Ring and diaphragm gates 63
8.2.6.5 Overflow gates 63
8.2.7 Venting 63
8.2.8 Ejection 63
9. Secondary Operations 65
9.1 Annealing 65
9.2 Assembly 65
9.2.1 Welding 65
9.2.1.1 Ultrasonic welding 65
9.2.1.2 Rotational (spin) welding 66
9.2.1.3 Hot plate welding 66
9.2.1.4 Vibration welding 67
9.2.1.5 Electromagnetic welding 67
9.2.2 Hot stamping 67
9.2.3 Adhesive bonding 67
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Vectra®
Introduction
9.2.4 Fasteners 68 and overview 1
9.2.4.1 Screws 68
9.2.4.2 Ultrasonic inserts 69
9.3 Decoration 71
9.3.1 Printing 71
9.3.2 Painting 72 Vectra product line 2
9.3.3 Laser marking 72
9.4 Plating and molded interconnect devices (MID) 72
9.4.1 Plating Vectra 72
9.4.2 MID 74
9.5 Machining 74 Physical properties 3
9.5.1 Tooling 75
9.5.2 Turning 75
9.5.3 Milling and drilling 75
9.5.4 Threading and tapping 75 Behavior in relation
9.5.5 Sawing 76 to environmental effects 4
10. Conversion Tables 77

10.1 Unit conversion factors 77
10.2 Stress conversion 77 Processing 5
10.3 Length conversion 77
10.4 Temperature conversion 77
11. Subject index 78 Injection molding 6
Extrusion 7
Design 8
Secondary operations 9
Conversion Tables 10
Subject index 11
5
Vectra®
List of tables
Table 1.1 Comparison of amorphous, semi-crystalline
and liquid crystalline polymers 9
Table 1.2 Key performance characteristics by market
segment 10
Table 2.1 Available color masterbatches 14
Table 3.1.1 Anisotropy of properties – 2 mm thick 16
Table 3.1.2 Anisotropy of properties – 1 mm thick 16
Table 3.1.3 Dynamic friction coefficient µ of Vectra® 20
Table 3.2.1 Dynamic mechanical analysis (DMA) 22
Table 3.2.2 Coefficient of linear thermal expansion
(– 50 to 200°C) 23
Table 3.2.3 Vapor phase soldering stability of Vectra® 24
Table 3.2.4 Soldering compatibility of Vectra® 24
Table 3.3.1 Smoke density of Vectra® A950 27
Table 3.3.2 Combustion products of Vectra® A950 27
Table 3.3.3 Heat release of Vectra® A950 27
Table 3.4.1 Vectra® LCP conductive grades 28
Table 3.4.2 Electrical properties of As-molded/
un-plated Vectra® LCP 28
Table 3.4.3 Electrical properties of gold plated
Vectra® LCP 28
Table 4.2.1 Chemical resistance 34
Table 4.3.1 Permeability of various polymer films 37
Table 4.3.2 Hydrogen permeability 37
Table 4.4.1 Cobalt 60 radiation Vectra® A950 37
Table 4.5.1 Results of artificial weathering for
2000 hours 37
Table 5.2.1 Drying conditions 40
Table 8.2 Partial listing of potential mold steels 59
Table 9.2.1 Electromagnetic weld strengths 67
Table 9.2.2 Lap shear strength 68
Table 9.2.3 Typical adhesives for Vectra® LCP 69
Table 9.2.4 Adhesives compliant with US regulations 69
Table 9.2.5 Lap shear strengths 69
Table 9.2.6 Typical boss dimensions 69
Table 9.2.7 EJOT PT ® K screw 70
Table 9.2.8 Performance of molded-in inserts 70
Table 9.5.1 Tool speeds for drilling and milling 75
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Vectra®
List of figures
Fig. 1.1 Representation of the structural differences 1
between liquid crystal polymers and conventional
semi-crystalline polymers 9
Fig. 1.2 Price performance comparison of engineering
and high performance plastics 11
Fig. 2.1 Vectra product line 13 2
Fig. 3.0 Fracture surface of unfilled Vectra® LCP 15
Fig. 3.1.1 Comparison of anisotropy of Vectra® LCP
versus PBT 16
Fig. 3.1.2 Micrograph of fiber structure showing orientation
of outer layers 16 3
Fig. 3.1.3 Tensile modulus versus wall thickness Vectra® LCP 17
Fig. 3.1.4 Tensile strength versus wall thickness Vectra® LCP 17
Fig. 3.1.5 Flexural modulus versus wall thickness Vectra® LCP 17
Fig. 3.1.6 Flexural strength versus wall thickness Vectra® LCP 17
Fig. 3.1.7 Stress-strain curves, tensile test at 23°C 18 4
Fig. 3.1.8 a) Influence of temperature on stress-strain
behavior, tensile test, Vectra® B230 18
Fig. 3.1.8 b) Influence of temperature on stress-strain
behavior, tensile test, Vectra® E130i 18
Fig. 3.1.9 Tensile modulus versus temperature, Vectra® LCP 19 5
Fig. 3.1.10 Tensile strength versus temperature, Vectra® LCP 19
Fig. 3.1.11 Tensile creep modulus, Vectra® E130i 19
Fig. 3.1.12 Tensile creep modulus, Vectra® A130 19
Fig. 3.1.13 Stress ranges in the fatigue test 20
Fig. 3.1.14 Wöhler curves for Vectra®, longitudinal direction 6
determined in the alternating flexural stress range 20
Fig. 3.1.15 Friction and wear 20
Fig. 3.1.16 Damping properties 21
Fig. 3.1.17 Vibration characteristics 21
Fig. 3.2.1 Dynamic mechanical analysis, Vectra® A130 22 7
Fig. 3.2.2 Dynamic mechanical analysis, Vectra® A530 22
Fig. 3.2.3 Dynamic mechanical analysis, Vectra® E130i 22
Fig. 3.2.4 Coefficients of linear thermal expansion of
selected engineering materials 23
Fig. 3.2.5 Sample geometry for CLTE measurements 24
8
Fig. 3.2.6 Specific heat 25
Fig. 3.2.7 Relative phase transition energy 25
Fig. 3.2.8 Enthalpy 25
Fig. 3.2.9 Thermal conductivity 26
9
Fig. 3.2.10 Outgessing* of Vectra® LC 26
Fig. 3.4.1 Relative permittivity/dielectric loss tangent versus
temperature, Vectra® E820iPd, gold plated 29
Fig. 3.4.2 Relative permittivity/dielectric loss tangent versus
frequency for Vectra® gold plated 29
10
11
7
Vectra®
List of figures
Fig. 3.5.1 Melt viscosity comparison Vectra® LCP versus
a semi-crystalline polymer 30
Fig. 3.5.2 Melt viscosity versus temperature (glass-filled) 30
Fig. 3.5.3 Melt viscosity versus temperature (unfilled) 30
Fig. 4.1.1 Tensile strength versus immersion time in hot water 33
Fig. 4.1.2 Tensile modulus versus immersion time in hot water 33
Fig. 4.1.3 Tensile strength versus immersion time in steam 33
Fig. 4.1.4 Tensile modulus versus immersion time in steam 33
Fig. 4.3.1 Permeability of various polymer films 37
Fig. 6.1.1 Metering type screws recommended for
processing Vectra® LCP 41
Fig. 6.1.2 Check ring non-return valve used on
reciprocoating screw injection molding machine 41
Fig. 6.1.3 Hot runner system for small parts 42
Fig. 6.1.4 Hot runner distributor 42
Fig. 6.2.1 Typical injection molding conditions 43
Fig. 8.1.1 Spiral flow lengths 55
Fig. 8.1.2 Weld lines 57
Fig. 8.2.1 Typical runner design for Vectra® LCP 60
Fig. 8.2.2 Submarine gate 62
Fig. 8.2.3 Sprue puller 64
Fig. 9.2.1 Ultrasonic welding joint design 65
Fig. 9.2.2 Ultrasonic weld strengths 66
Fig. 9.2.3 Spin welding joint design 66
Fig. 9.2.4 Spin weld strengths for Vectra® A130 66
Fig. 9.2.5 Vibration welding 67
Fig. 9.2.6 Electromagnetic welding 67
Fig. 9.2.7 Boss for EJOT PT ® K screw 70
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Vectra®
1. Introduction and overview Fig. 1.1 · Representation of Structural Differences

Between Liquid Crystal Polymers and
Conventional Semi-Crystalline Polymers
Vectra liquid crystal polymers are a family of high- 1
performance plastics based on patented Ticona tech-
nology. They are distinguished from semi-crystalline Liquid Semi-Crystalline Polymer
LiquidCrystal
CrystalPolymer
Polymer Semi Crystalline Polymer
plastics by their special molecular structure, which
consists of rigid, rod-like macromolecules that are
ordered in the melt phase to form liquid crystal
Melt
structures (Fig. 1.1). Melt
The characteristic property profile and behavior of

Nematic Structure Random Coil
liquid crystal polymers are so different from those of Nematic Structure Random Coil
other resins, that LCPs are treated as a separate class

of polymer (Table 1.1). Even so, they can be pro- Solid State
Solid
cessed by all conventional methods used for thermo- State
plastics, including injection molding, extrusion,
coextrusion, blow molding, etc.
Extended Chain Structure

Extended
• High Chain Structure
Chain Continuity Lamellar
LamellarStructure
Structure
• Highest Mechanical Properties • Low Chain Continuity
• High Chain Continuity • Low Chain Continuity
• Good Mechanical Properties
• Highest Mechanical Properties • Good Mechanical Properties
Table 1.1· Comparison of Amorphous, Semi-Crystalline and Liquid Crystalline Polymers

Amorphous Polymers Semi-Crystalline Polymers Liquid Crystal Polymers
No sharp melting point/soften gradually Relatively sharp melting point Melt over a range of temperatures;
low heat of fusion
Random chain orientation in both solid and Ordered arrangement of chains of molecules High chain continuity; extremely ordered
melt phase and regular recurrence of crystalline structure molecular structure in both melt phase and
only in solid phase solid phase
Do not flow as easily as semi-crystalline Flow easily above melting point Flow extremely well under shear within
polymers in molding process melting range
Fiberglass and/or mineral reinforcement only Reinforcement increases load bearing Reinforcement reduces anisotropy and
slightly improves Deflection Temperature under capabilities and DTUL considerably, particularly increases load bearing capability and DTUL
Load (DTUL) with highly crystalline polymers
Can give a transparent part Part is usually opaque due to the crystal struc- Part is always opaque due to the crystal
ture of semi-crystalline resin structure of liquid crystal resin
Examples: cyclic olefinic copolymer, Examples: polyester (Impet® and Celanex® Examples: Vectra® LCP
acrylonitrile-butadiene-styrene thermoplastic polyesters,
(ABS), Duranex™ PBT),
polystyrene (PS), polyphenylene sulfide (Fortron® PPS),
polycarbonate (PC), polyamide (Celanese® nylon),
polysulfone (PSU), and polyacetal copolymer (Celcon® POM,
polyetherimide (PEI) Hostaform® POM, Duracon™ POM)
9
Vectra®
Vectra liquid crystal polymers offer a balance of Vectra LCPs can be processed into thin films and
properties unmatched by most other resins. They are multi-layer products by conventional methods,
generally selected for a specific application or market although some process adjustments may be required.
sector based on a few key characteristics such as those Films and sheets produced from Vectra have excellent
shown in Table 1.2 below. For instance, in molding dimensional stability and exceptional barrier pro-
electrical connectors, high flow in thin sections, perties. Liquid crystal polymers are used in many
excellent resistance to heat deflection under load, different sectors, from electronics and medical
dimensional accuracy and inherent flame retardancy technology to industrial applications.
are the primary reasons for choosing an LCP. Key
properties, such as high flow, stiffness and resistance In addition to the above-mentioned advantages
to sterilizing radiation and sterilizing gases make offered by Vectra, other properties such as its low
LCPs extremely suitable for use in surgical instru- coefficient of linear thermal expansion (CLTE), high
ments. A number of Vectra grades are USP Class VI- chemical resistance, good stiffness, and toughness are
compliant and meet parts of the ISO 10993 standard observed in many applications.
(see section 3.5).
The performance of the latest Vectra grades goes
The family of Vectra resins are very easy to process beyond the requirements for thin-walled precision
in injection molding machines, providing fast cycles, parts. Attributes such as an attractive surface finish
high flow in thin sections and exceptional dimensional with wide color versatility, good non-stick effect and
stability. Molded parts exhibit very low shrinkage and resistance to cleaning agents make the materials in the
warpage and have outstanding high-temperature Vectra portfolio good candidates for applications that
resistance up to 340°C. have traditionally been the preserve of metal, such as
cookware and bakeware.
Table 1.2 · Key Performance Characteristics by Market Segment
Electrical / electronics Packaging Cookware and bakeware

Good flowability in molding Excellent barrier properties Good non-stick effect
thin-walled parts Stiffness Service temperatures from
Dimensional accuracy Strength –196 °C to +280 °C
Heat resistance Stiffness
Flame retardancy Automotive industry Low warpage
Good flowability in molding Dishwasher-safe
Technical fibers thin-walled parts
High tenacity fibers with good Fuel resistance Medical technology
damping properties Good resistance to low and high Good flowability in molding
Very good puncture and cut temperatures thin-walled parts
resistance of fibers Low outgassing Chemical resistance
Low abrasion Sterilizability
Low moisture absorption Lighting industry Stiffness, strength
Good flowability in molding
Telecommunications thin-walled parts
Good flowability in molding Good resistance to low and high
thin-walled parts temperatures
Dimensional accuracy Low outgassing
Strength, stiffness
10
Vectra®
The high strength-to-weight ratio of Vectra LCPs for use in regrind ratios up to 50% without loss of 1
makes them exceptional candidates for metal replace- properties, enabling the processor to improve cost
ment applications. A maker of needleless medical competitiveness even further. Although on a per
syringes estimated that injection molded Vectra com- pound or kilogram basis, Vectra may seem expensive,
ponents were 75% lighter and 50% less costly than in an overall cost comparison, it proves to be more
machined metal parts. Compared with less costly cost-effective than other materials (Fig. 1.2). For
resins, easy flowing Vectra LCPs speeds up molding many applications exposed to high service stresses,
cycles and eliminates the need for many secondary Vectra LCPs are the preferred alternative to metal
operations, so reducing the cost per part. In addition, alloys, thermosets and many other thermoplastics.
many Vectra grades are listed by UL as being suitable
Fig. 1.2 · Price Performance Comparison of Engineering and High Performance Plastics*
PEEK
FP
PAS/PES LCP
PEI Vectra
PSU
AMORPHOUS
PPS-GF
Fortron
PA 4,6
PPA
Performance
HTN
COC PCT
•
PC
PPS-MF
Fortron CRYSTALLINE
SPS
PA 6,6
PBT
Celanex
POM Duranex
Celcon
PPO PA6 Duracon
Hostaform
Kemetal
ABS PET
Impet Products available through Ticona
Price
* High Performance Plastics Acronyms
ABS = acrylonitrile-butadiene-styrene HTN = high temperature polyamide (nylon)

COC = cyclic olefin copolymer LCP = liquid crystal polymer
FP = fluoropolymers PA6,6 = polyamide 6,6 (nylon)
PA6 = polyamide 6 (nylon) PAS = polyaryl sulfone
PA4,6 = polyamide 4,6 (nylon) PCT = polycyclohexylenedimethylene terephthalate
PBT = polybutylene terephthalate PEI = polyether imide
PEEK = polyether ether ketone PET = polyethylene terephthalate
PES = polyether sulfone PPO = modified polyphenylene oxide
POM = polyoxymethylene (polyacetal) PPS-G = polyphenylene sulfide (glass filled)
PPS-MF = polyphenylene sulfide (mineral filled) PSU = polysulfone
PPA = polyphthalamide PC = polycarbonate
SPS = syndiotactic polystyrene
11
Vectra®
2. Vectra product line

Examples:
The Vectra product line is built around a number of Vectra A230D-3 (30% carbon fibers)
base polymers with different monomer composition. Vectra B230 (30% carbon fibers)
The base polymers differ in their high-temperature
resistance, stiffness, toughness and flow properties. 2.1.3 Filler/fiber combinations
Ticona is continually developing new polymers with
properties tailored to the different requirements of Products with various filler/fiber combinations are
specific applications. another important group in the Vectra portfolio.
The PTFE and glass modified grades are used for
Each of these Vectra grades can be used without low-friction and wear-resistant applications, while
modification for extrusion or injection molding appli- glass/mineral filled products are selected for com-
cations. Care should be taken when using unfilled ponents requiring both an attractive finish and
polymers for injection molding since fibrillation of improved stiffness.
the oriented surface can occur. As a rule, the base
polymers are compounded with various fillers and Examples:
reinforcing materials to provide the necessary combi- Vectra A430 (PTFE)
nation of thermal, mechanical, tribological or electrical Vectra A435 FDA (glass fibers, PTFE)
properties for the specific application or market need.
2.1.4 Mineral filled grades
Figure 2.1 surveys the Vectra grades currently avail-
able The mineral filled grades typically have high impact
strength and elongation at break relative to the glass
2.1 Grade descriptions fiber reinforced grades. In addition, they provide
an attractive surface finish and good flow properties.
2.1.1 Glass fiber reinforced grades Mineral filled Vectra products are available with 40%
filler content.
Reinforcement with glass fibers increases stiffness,
mechanical strength and heat resistance. At the same Examples:
time, the degree of anisotropy is reduced. Vectra is Vectra E540i (40% mineral)
available with 15%, 30%, 40% or 50% glass fiber Vectra S540 (40% mineral)
content.
2.1.5 Graphite filled grades
Examples:
Vectra A130 (30% glass fibers) Graphite flake provides some added lubricity and
Vectra E130i (30% glass fibers) exceptionally good hydrolytic stability and chemical
Vectra E480i (40% glass fibers) resistance.
Vectra S135 (35% glass fibers)
Vectra S150 (50% glass fibers) Examples:
Vectra A625 (25% graphite)
2.1.2 Carbon fiber reinforced grades Vectra S625 (25% graphite)
Reinforcement with carbon fibers gives even higher 2.1.6 Specialty grades
stiffness than with glass fibers. At the same time,
carbon fiber reinforced compounds have a lower Modification with electrically conductive carbon
density than glass fiber grades with the same filler black makes the following products particularly
content. Carbon fiber reinforced polymers are used suitable for antistatic applications.
where the highest possible stiffness is required.
Examples:
It should also be noted that carbon fiber reinforced Vectra A230D-3 (carbon fibers, conductive carbon
grades are to a certain extent electrically conductive. black)
Vectra A700 (glass fibers, conductive carbon black)
Vectra A725 (graphite, PTFE, conductive carbon black)
12
Vectra®
Fig. 2.1 · Vectra® product line
Glass fiber reinforced A115

A130 E130i S135
E480i
E150i S150 2
Carbon fiber reinforced A230D-3 B230
Fiber/filler A430 E440i

modified A435 FDA E471i S471
E473i S475
Mineral filled E540i S540
Graphite filled A625 S625
Electrically conductive A700

A725
Electroplatable E820i
E820i Pd
E840i LDS
Alloy V140 V143XL
Extrudable (unfilled) A950 V400P
Vectra base polymers

A polymers – standard polymers Ei polymers – standard polymers
best all-round properties very good flowability
SMT solderability
B polymers – highest stiffness
S polymers – highest heat resistance
very good flowability
SMT solderability
The following grades have been specially developed 2.1.7 Medical technology grades
for electroless plating, EMI/RFI shielding, printed
circuit boards and MID components with integrated Another product group in the Vectra portfolio com-
circuits. prises medical technology grades tested according to
the current standards specified by the medical device
Examples: and pharmaceutical industries. They are available with
Vectra E820i (mineral) different fillers to meet varying application require-
Vectra E820i Pd (mineral, catalyst) ments.
Vectra E840i LDS (mineral, catalyst)
Examples:
MT1300 (unfilled)
MT4310 (30% glass fibers)
MT4350 (40% mineral)
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Vectra®
2.2 Colors The last two digits at the end of the masterbatch code
denote the recommended mix ratio of natural pellets
The natural color of Vectra is beige or ivory. to color masterbatch, e.g.:
Graphite, carbon black and carbon fiber filled grades
are correspondingly black or anthracite in color. VJ3040K10 = 10:1 (9 parts pellets: 1 part master-
batch)
Vectra’s high-quality surface finish also provides an
opportunity to produce visible parts in attractive VA3031K20 = 20:1 (19 parts pellets: 1 part master-
colors. The good coloration properties of the material batch)
can also be used advantageously to identify or label
different components. However, Vectra is not suitable Lower concentrations are possible if necessary to
for exact color matching with other materials. achieve the required color effect. Higher concentra-
tions of masterbatch are not recommended because
Color masterbatches (or concentrates) with a high of a potential decrease in material properties and/or
pigment loading are available in a wide range of flowability at higher loading.
colors (Table 2.1). These masterbatches are supplied
as pellets and are added during processing. Color As an alternative to in-house coloration with color
masterbatches based on Vectra “A”, “Ei” and S poly- masterbatches, it is also possible to obtain Vectra
mers are available and are all cadmium-free. products in melt-colored form, if required. Further
information on this can be obtained from the Vectra
Table 2.1 · Available color masterbatches Businessline or Technical Service.
A9500 / E9500i 2.3 Packaging

Color number Standard Color
letdown The standard package is a 20/25 kg bag, although
VD3003K20 20:1 black other types of packaging, such as gaylords, are avail-
VA3031K20 20:1 white able on request.
VG3010K20 20:1 blue
VJ3040K10 10:1 emerald green
VL3021K10 (A9500) 10:1
yellow
VL3043K10 (E9500i) 10:1
VS3033K10 10:1 pink
VS3035K10 10:1 red
For Vectra “A” and “B” grades, color masterbatch

Vectra A9500 should be used and for “Ei” grades,
color masterbatch E9500i. For Vectra grades based on
“S” polymers, only one standard color (S9500 black)
is presently available. The Vectra Businessline or
Technical Service will be pleased to handle special
requests.
14
Vectra®
3. Physical Properties
The physical property values of the individual Vectra Vectra LCPs belong to the Ticona family of high
grades are shown in the enclosed table. performance engineering plastics. It is a stiff, tough
material with very good flow properties and excellent
The properties of Vectra® LCP are influenced to a heat resistance.
high degree by its liquid crystal structure. The rod
shaped molecules are oriented in the flow direction A summary of short-term physical properties for the 2
during injection molding or extrusion and are rod- majority of commercially available Vectra grades can
shaped, even in the melt phase. Due to the highly be found in the enclosed table. Since the Vectra port-
ordered nature of liquid crystal polymers, mechanical folio is being continually developed, please contact
properties, shrinkage and other part characteristics your local customer service for information on the
depend on the flow pattern in the part. During mold availability of additional grades. 3
filling, the molecules are oriented in the flow direction.
In the finished part, these molecules are ultimately All properties given in the enclosed table were
aligned on the surface where they form a skin that is measured on standard injection molded test speci-
highly oriented in the flow direction. The skin makes mens and can be used for grade comparison. Their
up 15-30% of the part's total thickness (Fig. 3.0). applicability to finished parts is limited because the
This molecular orientation causes a self-reinforce- strength of a component depends to a large extent on
ment effect giving exceptional flexural and impact its design. Most physical properties of LCPs depend
strength as well as good tensile performance. Relative on processing conditions, so that comparison with
strength values increase as a direct correlation with data from other sources must always be viewed
decrease in wall thickness (see Figures 3.1.3 – 3.1.6). critically.
The level of properties depends primarily on the type

Fig. 3.0 · Fracture Surface of Unfilled Vectra® LCP of filler or reinforcement used. Glass fibers impart
increased stiffness, tensile strength and heat deflection
temperature. Carbon fibers give the highest stiffness.
The addition of mineral fillers improves stiffness and
provides increased toughness and a smoother surface
compared with glass fiber reinforcement. Graphite
improves elongation at break and provides added
lubricity. PTFE modified grades have excellent sliding
and wear properties. The impact strength of unfilled
Vectra polymers is reduced by the addition of fillers
and reinforcing materials but is still high.
15
Vectra®
3.1 Mechanical properties

Table 3.1.1 · Anisotropy of Properties – 2 mm thick
Unfilled 30% glass 30% mineral
3.1.1 Anisotropy and wall thickness
filled filled
Liquid crystal polymers are well known to have Flex strength Ratio FD/TD* 2.7 2.1 2.4
anisotropic properties when molded into parts. Flex modulus Ratio FD/TD* 3.6 2.9 3.9
Unlike other engineering polymers, liquid crystal
polymers become significantly less anisotropic if Tensile strength Ratio FD/TD* 2.3 1.9 2.5
formulated with mineral fillers or, to a lesser extent, Tensile modulus Ratio FD/TD* 3.3 2.2 2.7
with glass fiber reinforcement. An example comparing
*FD/TD = anisotropy ratio – flow direction/transverse direction
the anisotropy of a Vectra test specimen with that
of a test specimen produced from a conventional
engineering plastic, PBT, is shown in Figure 3.1.1,
Table 3.1.2 · Anisotropy of Properties – 1 mm thick
both with and without glass fiber reinforcement.
The anisotropy of 30% glass fiber reinforced Vectra Unfilled 30% glass 30% mineral
and 30% glass fiber reinforced PBT is nearly the same. filled filled
In grades with a high mineral filler loading, the ani- Flex strength Ratio FD/TD* 3.9 3.1 2.9
sotropy ratio can even be reduced to 1 (isotropic).
Flex modulus Ratio FD/TD* 6.7 4.4 4.8
It therefore follows that in designing parts molded
from glass fiber reinforced Vectra, there is no need to Tensile strength Ratio FD/TD* 3.6 2.6 3.1
take into account anisotropy-induced changes as Tensile modulus Ratio FD/TD* 3.0 2.5 2.8
compared with the use of other glass fiber plastics.
*FD/TD = anisotropy ratio – flow direction/transverse direction
Anisotropic properties can be adequately managed by
suitable gate location and wall thickness adjustment.
Fig 3.1.2 · Micrograph of Fiber Structure
Table 3.1.1 compares the anisotropy in the flexural showing Orientation of Outer Layers
and tensile properties of various Vectra grades in
sheet form (80 mm x 80 mm x 2 mm). Table 3.1.2
shows the effect of decreasing wall thickness (80 mm
x 80 mm x 1 mm) on the anisotropy ratio.
As the wall, film or sheet thickness decreases, the

highly oriented outer layer accounts for a higher
proportion of the total wall thickness (Fig. 3.1.2).
This higher percentage of highly oriented surface
layer, in general, results in greater strength and
Fig. 3.1.1 · Comparison of Anisotropy* of Strand LCP extrudate shows the higher orientation in the outer ”skin”
layer but not in the core;
Vectra® LCP versus PBT (ISO universal test specimen)
3.0
2.5
Anisotropy Ratio (FD/TD*)
2.0
1.5
1.0
0.5
0
PBT 30%GF PBT LCP 30%GF LCP 40%MF LCP
Extruded LCP fiber is highly oriented with all ”skin” observed.
* Tensile strength in flow direction/tensile strength in transverse direction
16
Vectra®
Fig. 3.1.3 · Tensile Modulus versus Wall Thickness Vectra® LCP

45
40 1.0 mm
35 1.6 mm
Tensile Modulus, MPa
30 3.2 mm
25
4.0 mm
20
15
10
5
0
A130 B230 E130i E540i S135 S475
3
Fig. 3.1.4 · Tensile Strength versus Wall Thickness Vectra® LCP
350
1.0 mm
300
1.6 mm
Tensile Strength, MPa
250
3.2 mm
200
4.0 mm
150
100
50
0
A130 B230 E130i E540i S135 S475
Fig. 3.1.5 · Flexural Modulus versus Wall Thickness Vectra® LCP

35
1.0 mm
30
1.6 mm
Flexural Modulus, MPa
25
3.2 mm
20
4.0 mm
15
10
0
A130 B230 E130i E540i S135 S475
Fig. 3.1.6 · Flexural Strength versus Wall Thickness Vectra® LCP

450
1.0 mm
400
350 1.6 mm
Rlexural Strength, MPa
300 3.2 mm
250
4.0 mm
200
150
100
50
0
A130 B230 E130i E540i S135 S475
17
Vectra®
modulus in thinner sections (Figs 3.1.3, 3.1.4, 3.1.5

Fig. 3.1.8a · Influence of Temperature on
and 3.1.6).
Stress Strain Behavior, Tensile Test, Vectra® B230
The excellent flow properties of Vectra make it possible 250
to fill extremely fine structures and so produce very
thin-walled parts. 200
-40 °C 23 °C
Stress (MPa)
150
3.1.2 Behavior under short-term mechanical stress 80 °C
100
The tensile stress-strain curves shown in Figure 3.1.7
120 °C
are representative of the Vectra product line. Vectra
50
A130 and E130i are 30% glass filled resin, S135 is a 200 °C
35% glass fiber reinforced resins, Vectra A230D-3 and 0

B230 are 30% carbon fiber reinforced resins, Vectra 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
Strain (%)
Fig. 3.1.7 · Stress Strain Curves, Tensile Test at 23°C
250 Fig. 3.1.8b · Influence of Temperature on

Stress Strain Behavior, Tensile Test, Vectra® E130i
200
B230 A230D-3 A130 250
-40 °C
E130i
Stress (MPa)
150 200
S135 A430 23 °C
S471 S540
Stress (MPa)
100 150
E540i 80 °C
50 100
0 50 120 °C
0 1 2 3 4 5 6 7
Strain (%) 200 °C
0
0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8
Strain (%)
A430 is a 25% PTFE filled resin, Vectra E540i and
S540 are 40% mineral filled resins, and Vectra S471i
is a 45% glass/mineral filled resin.
Fig. 3.1.9 · Tensile Modulus versus Temperature,
Vectra® LCP
These products essentially cover the stress-strain
range for most filled or reinforced Vectra grades. 45.000
As with any thermoplastic, the stiffness and strength 40.000
-40 °C
of the Vectra decreases with increasing temperature. 23 °C
35.000
Figs 3.1.8a and b show the influence of temperature 80 °C
Tensile Modulus (MPa)
on the stress strain curves of Vectra B230 and Vectra 30.000

120 °C
E130i. The influence of temperature on tensile 25.000 200 °C
properties is given for a number of Vectra grades in
Figs 3.1.9 and 3.1.10. 20.000
15.000
10.000
5.000
0
B230 E130i
18
Vectra®
Fig. 3.1.10 · Tensile Strength versus Temperature, Fig. 3.1.12 · Flexural Creep Modulus, Vectra® A130
Vectra® LCP
20,000
250 15,000
23 °C
-40 °C
Flexural Creep Modulus (MPa)

10,000
200 23 °C
8,000
80 °C 80 °C
Tensile Strength (MPa)
6,000
120 °C
150
200 °C 4,000
120 °C
100
3
2,000
50 Maximum Stress = 50 MPa
1,000
0 10-2 10-1 1 10 102 103
B230 E130i Time (hours)
3.1.3 Behavior under long term mechanical stress 3.1.4 Behavior under impact stress
Vectra has good creep resistance. Figure 3.1.11 shows Vectra grades have very high notched and unnotched
the tensile creep modulus of Vectra E130i at 23°C Charpy and Izod impact strength because of their
and 120°C for various stress levels. The maximum wood-like fibrous structure. If this fibrous structure
exposure time was 1000 hours for E130i. The stress is cut by notching, as in a notched Izod or Charpy
levels were chosen to be 30% of the short-term failure specimen, the energy to break is high compared with
stress and none of the samples failed testing. No sign other glass reinforced plastics.
of creep rupture – a common form of failure – was
observed at stress levels below 30%. The values for notched and unnotched impact
strength are reported in the enclosed table.
Fig. 3.1.13 shows the flexural creep modulus of
Vectra A130 – a 30% glass fiber reinforced grade. 3.1.5 Behavior under cyclic stress
Fig. 3.1.11 · Tensile Creep Modulus, Vectra® E130i Components subject to periodic stress must be
designed on the basis of fatigue strength, i.e. the
16,000
cyclic stress amplitude σa determined in the fatigue
23 °C/40 MPa
14,000 test – at a given mean stress σm – which a test speci-
men withstands without failure over a given number
Tensile Creep Modulus (MPa)
12,000
of stress cycles, e.g. 107 (Wöhler curve). The various
23 °C/30 MPa
10,000 stress ranges in which tests of this nature are con-
ducted are shown in Fig. 3.1.16
8,000 120 °C/20 MPa
120 °C/30 MPa For most plastics, the fatigue strength after 107 stress
6,000
cycles is about 20 to 30% of the ultimate tensile
4,000 strength determined in the tensile test. It decreases
120 °C/40 MPa
with increasing temperature, stress cycle frequency
2,000
and the presence of stress concentration peaks in
0 notched components.
1 10 102 10 3
Time (hours)
19
Vectra®
Fig. 3.1.13 · Stress Ranges in Fatigue Tests Fig. 3.1.15 compares the dynamic coefficient of
friction µ of a number of Vectra grades with that of
POM. The test specimens were in unlubricated
m < a
m = 0
+ tension
sliding contact with a rotating steel shaft under low
m < a
u = 0
m > a
m = a
+ load.
Vectra has moderate surface hardness. Rockwell
m > a
time
m = a
pression –
u = 0
com-
– hardness M values of up to 100 are attained (see the

m ≥ a m < a m ≥ a enclosed product information).
range for range for range for
fluctuating stresses fluctuating stresses fluctuating stresses
(under compression) (under tension
Table 3.1.3 · Coefficient of Friction, µ, of
Vectra® LCP (ASTM D1894)
Description Vectra LCP Coefficient of Friction –
Fig. 3.1.14 · Wöhler Curves for Vectra, longitudinal Grade Flow Direction
direction determined in the alternating flexural Static Dynamic
stress range A115 0.11 0.11

Glass Fiber Reinforced
120 A130 0.14 0.14
test temperature 23 °C Carbon Fiber Reinforced A230D-3 0.19 0.12

100 stress cycle frequency 10 Hz
Stress amplitude ± a (MPa)
mean stress m = 0 A430 0.11 0.11

PTFE Modified
80 A435 FDA 0.16 0.18
A130
Graphite A625 0.21 0.15
60
B230 Glass Fiber Reinforced B230 0.14 0.14
40
Fig. 3.1.15 · Friction and Wear

20
0 A430
103 104 105 106 107 POM
Number of stress cycles N
A435 FDA
A625
The Wöhler flexural fatigue stress curves for various B230
Vectra LCP grades are shown in Fig. 3.1.17. The A230D-3
flexural fatigue strength of Vectra A130 after 107 A130
stress cycles is σ bw = 50 N/mm2. 0.4 0.3 0.2 0.1 0 5 10 15

Dynamic coefficient Wear* (mm3)
of friction μ*
3.1.6 Tribological properties * average from longitudinal and transverse to flow direction
Friction: steel ball diameter 13 mm,

The friction and wear characteristics of Vectra are load (FN = 6 N, sliding speed v = 60 cm/min.
Wear: roughness height = 0,1 μm,
very specific to the application. In general, Vectra
peripheral speed of the shaft v = 136 m/min,
resins have good friction and wear properties under load (FN = 3 N, duration of test 60 hr
low loads. Typical Vectra wear grades contain PTFE,
carbon fibers, graphite, or a combination of these
with other fillers and reinforcing materials. Dynamic
coefficients of friction typically range from 0.1 to 0.2.
More specific data can be obtained from standardized
tests (Table 3.1.3). However, because friction/slip
behavior is dependent on orientation, we recommend
testing the finished component under the specific
bearing, friction and wear conditions of the applica-
tion.
20
Vectra®
3.1.7 Damping
Fig. 3.1.17 · Vibration Characteristics
The unique structural characteristics of Vectra have 14

A950
an extremely favorable effect on its damping charac-
Damping Factor (1/sec)

teristics. Generally speaking, materials with high 12
A430 A130 A230D-3
modulus, such as metals, have low damping (internal
10
loss) characteristics and low modulus materials, such
B230
as rubbers, have high damping characteristics. 8
Vectra, however, exhibits high damping characteristics
despite its high modulus. This is due to the unique 6
0 10,000 20,000 30,000
morphology of liquid crystal polymers. The relation- 3
Flexural Modulus (MPa)
ship between internal loss, η, and damping factor, l,
is as follows:
λT/π = η 3.2 Thermal properties
where T = cycle and π = 3.14. 3.2.1 Dynamic mechanical analysis (DMA)
Fig. 3.1.16 shows the damping properties of various A snapshot of the thermomechanical behavior of
materials. plastic materials is provided by dynamic mechanical
analysis (DMA). This technique is used to determine
Figure 3.1.17 compares the vibration characteristics of the storage modulus or stiffness (E’), loss modulus
different Vectra grades. (E′′) and damping or energy dissipation (tan δ)
behavior of a material over a wide temperature range.
The stiffness or modulus (E′) corresponds to and
Fig. 3.1.16 · Damping Properties has nearly the same value as the conventional tensile
modulus (E) at temperatures with low loss or damping
x 103
100 factor. This modulus represents the recoverable elastic
80
Aluminium energy stored in a viscoelastic material during defor-
60
mation. The damping factor (tan δ) represents the
40
energy losses occurring during deformation due to
Vectra A230D-3
internal molecular friction that occurs in a viscoelastic
Tensile Modulus (GPa)
20
material.
10 Vectra A950
8 With this method, the absolute level of the test values
6 depends on the particular test used. Since Vectra®
4 LCP is an anisotropic material, the orientation of the
PBT POM test specimen and direction of mechanical stress have
2 a significant influence on the test values. The results
PE Rubber presented here were obtained using the torsion
1 pendulum test. In this method, the test specimen is
0 0.02 0.04 0.06 0.08 0.10 0.20
subjected to a load that is not exactly oriented in the
Internal loss
direction of the fiber axes. As a result of the torsional
movement, a significant component of the load is
applied at an angle to the fiber axes. This reduces the
level of the test values and the moduli shown differ
from the values obtained in the tensile test.
21
Vectra®
Table 3.2.1 Fig. 3.2.3 · Dynamic Mechanical Analysis

Dynamic Mechanical Analysis Vectra® S135
Sample ID transition transition Modulus E Half Modulus
(Tg) (°C) (°C) at 23°C Temperature 104 1.00
(MPa) T1/2G (°C)
Vectra A130 97 18 2400 88
Vectra A230D-3 103 21 3200 95

103
Moduli (MPa)
Vectra A430 99 11 1400 83 tan
tan
Vectra A625 98 22 3000 83 0.10
G’
Vectra E130i 113 59 2300 119
102
Vectra E471i 115 57 2500 119
Vectra E540i 117 61 3200 113

G’’
Vectra S135 128 35 2400 121
1
10 0.01
Vectra S471 131 39 3600 119 -50 0 50 100 150 200 250 300 350
Temperature (ºC)
Fig. 3.2.1 · Dynamic Mechanical Analysis

By comparing DMA curves of two or more Vectra
Vectra® A130
polymers (Figs. 3.2.1-3.2.3), retention of stiffness as
104 1.00 temperatures are raised is easily compared. Generally
speaking, the higher the stiffness at any temperature,
the more creep resistant the Vectra grade will be at
that temperature. In Table 3.2.1 the temperature at
103 tan which the modulus falls to 50% of the ambient tem-
Moduli (MPa)
tan
perature modulus value is listed for a number of

0.10
Vectra grades. In general, the higher this temperature,
G’ the more creep-resistant the grade will be at elevated
102
temperatures. For example, Vectra A130 (T1/2G =
88ºC) will be more creep-resistant than Vectra A625
G’’
(T1/2G = 83ºC) in the temperature range between
1
10 0.01 about 23 to 90ºC. Likewise, Vectra E130i (T1/2G =
-50 0 50 100 150 200 250 300 350
Temperature (ºC) 119ºC) will be more creep-resistant than Vectra A130
(T1/2G = 88ºC) in the 80 to 120ºC temperature
range.
Fig. 3.2.2 · Dynamic Mechanical Analysis
Vectra® E130i Similarly, peaks in the damping factor curve indicate
transitions and temperature ranges where the poly-
104 1.00
mer will be more energy-dissipating (note that the
tan
measurement frequencies are very low, of the order of
103 one hertz [cycle/second]. This frequency is well
below the audible sound range of 20-20,000 Hz).
Moduli (MPa)
Typically, Vectra polymers have two strong damping

tan
102 0.10 peaks at the glass transition point, α, and the low
G’ temperature transition point, β. These are listed in
G’’ Table 3.2.1. Typically, the damping peaks for all
101
Vectra grades fall over a wide range of temperature.
Glass transitions are usually in the 120 to 155ºC
10 0 0.01 range with the low temperature secondary loss peaks
-50 0 50 100 150 200 250 300 350
at 10 to 80ºC. In general, the damping peak tempera-
Temperature (ºC)
tures just above ambient make Vectra a good sound
22
Vectra®
absorber. When struck, they do not “ring”, but they 3.2.3 Coefficient of linear thermal expansion
“clunck” or sound “dead”.
One of the advantages of Vectra is its exceptionally
3.2.2 Deflection temperature under load low coefficient of linear thermal expansion (CLTE) in
comparison with other thermoplastics. The expansion
The deflection temperature under load (DTUL/HDT) coefficient change only slightly and almost linearly.
measured at 1.8 MPa (HDT/A) for Vectra grades The coefficient of expansion, like most properties of
ranges from 120°C for an unreinforced, low-tempera- Vectra, displays marked anisotropy. It is much lower
ture product to 340°C for the glass fiber reinforced in the flow direction than the cross-flow direction.
high heat products. The DTUL values at loads of With very high orientation in the flow direction, the
8 MPa (HDT/C) and 0.45 MPa (HDT/B) differ con- expansion coefficient may even be negative, especially 3
siderably from the HDT/A values and are given in for carbon fiber reinforced grades.
the enclosed table.
The expansion coefficient of Vectra can be varied
within certain limits and matched to the expansion
coefficient of glass, steel, ceramic, or glass fiber/
epoxy substrates. Fig. 3.2.4 compares the expansion
coefficients of various engineering materials. When
Fig. 3.2.4 · Coefficients of Linear Thermal composite structures of Vectra and other materials are
Expansion of Selected Engineering Materials heated, no thermally induced stresses occur because
the thermal expansion coefficients are similar.
Electrical components for surface mounting (SMD
Glass
or surface mounted devices) should have expansion
Steel
min. coefficients closely in line with those of the circuit
max. board substrate (usually FR 4 epoxy plastic/glass
Ceramic fiber) to avoid mechanical stresses at the soldering
points as a result of thermal loading. Vectra is there-
FR4 epoxy/
glass fibre
fore a good material for composite structures, partic-
ularly for surface mount technology (SMT).
Vectra GF30
(Flow)
Vectra GF30 The expansion coefficient depends on the flow
(Cross Flow) pattern and therefore on fiber orientation in the part.
Vectra MF40
(Flow) Table 3.2.2 · Coefficient of
Vectra MF40 Linear Thermal Expansion (–50°C to 200°C)
(Cross Flow)
Coefficient of Linear Thermal Expansion ( x 10 -6/°C)
Copper 30 x 10 x 4 mm
cut out from ISO Test Specimens
Vectra Flow Cross Flow
Aluminium
A130 5 20
PPS
B230 1 8
PBT
(Flow) E130i 5 19
PA E540i 11 12
(Flow)
E471i 4 15
0 20 40 60 80 100
CLTE (x 10 –6/°C) S135 4 22
23
Vectra®
Fig. 3.2.5 · Sample Geometry for Table 3.2.3 · Vapor Phase Soldering Stability
CLTE Measurements of Vectra® LCP
Change in Dimensions after Immersion
60 mm x 60 mm x 4 mm Plates
in Fluorinert FC70 at 215°C (%)
45 s immersion 120 s immersion
Vectra A130 (30% GF) L 0.05 0.05

W 0.05 0.05
D 0.05 0.05
Cross
Gate
Flow
PBT (30% GF) L 0.2 0.22
W 0.3 0.5
D 0.2 0.32
PPS (40% GF) L 0.15 0.16

W 0.53 0.55
D 0.55 0.57
170 mm x 10 mm x 4 mm ISO-bar GF = fiber glass reinforced
L = change in length dimension (%)
W = change in width dimension (%)
Gate D = change in depth dimension (%)
Flow direction
Table 3.2.4 · Soldering Compatibility of Vectra® LCP

Solder Bath Dipping Time Vectra Vectra Vectra
The more uniform the filling pattern in injection
Temperature (°C) (s) A130 E130i S135
molding a given section of the part, the lower the
anisotropy of the thermal expansion coefficient in the 240 10
60
various spatial directions. The higher flow-induced
orientation in the ISO test specimen is reflected in the 260 15
20
higher anisotropy of the linear expansion coefficient. 45
With the more balanced flow and orientation proper- 60
ties of the 60 x 60 x 4 mm test plaque, the expansion 280 10 --
values are also more balanced (see Figure 3.2.10). The 30 --
45 --
two values measured on this test plaque effectively 60 --
represent the achievable spectrum of the thermal ex- 90 -- --
pansion coefficient. The thermal expansion coefficients 290 60 -- --
of selected grades are compared in Table 3.2.3 and 300 30 -- --
further data can be obtained from the enclosed table
310 10 -- --
and the technical data sheets. 15 -- --
= no change in appearance -- = not tested
3.2.4 Soldering resistance = change in appearance
Parts molded from Vectra LCPs are suitable for Table 3.2.3 shows dimensional changes in a 56 mm
applications requiring vapor phase (wave) and long connector with 40 contacts after immersion in
infrared (reflow / SMD / through-hole) soldering. Fluorinert FC70, which is used in Vapor Phase
They are dimensionally stable and have extremely Soldering.
low thermal expansion coefficients at soldering
temperatures. Vectra LCPs exceptionally low mois- Resistance to soldering temperatures of a number of
ture absorption has a positive effect on dimensional Vectra grades is given in Table 3.2.4. Experience has
stability, minimizing dimensional changes and shown that Vectra A130 is resistant to soldering tem-
warpage. peratures up to 240°C. Above this temperature, parts
can soften or distort due to the proximity of the
melting point (280°C). Vectra E130i, with its much
24
Vectra®
higher melting point (335°C), is able to withstand Fig. 3.2.6 · Specific Heat
short-term soldering temperatures of up to 300°C.
6
The introduction of high-temperature grades such as
Vectra S135 (melting point 350°C) significantly
)
5
kg · K
Celanex PBT
kJ
extends the possible processing window.
4
(
Specific heat cp
The melting point is, however, only one criterion for Fortron PPS
3
assessing the suitability of Vectra grades for exposure
to soldering operations. Another important consider- 2
ation is heat deflection temperature under load. It is
necessary to decide on a case by case basis whether 1
Vectra A130
3
to use HDT/A or resistance to other loads such as
0
HDT/B or C as the basis. In making this decision, 0 50 100 150 200 250 300 350
loads due to internal pressure in the component (e.g. Temperature (°C)
from trapped inert gas) or other mechanical effects,
such as clamps, must be taken into account.
Fig. 3.2.7 · Relative Phase Transition Energy
As a result of the increased use of lead-free soldering,
temperature peaks in the soldering operation have Nylon 66
risen to 270°C. It should be noted that Vectra Ei and
S grades are suitable for such soldering operations, PET
provided that they have been correctly processed.
PBT
Frequent faults include insufficient drying of the
material before processing or excessive shearing of PPS
the material. Mineral filled grades may in some cases
require more careful drying than glass fiber rein- Vectra A130
forced grades. Shear is introduced by the screw on
0 5 10 15 20 25 30 35 40 45 50
the injection molding machine and in the mold
Heat of Fusion (J/g)
during the injection phase. Poor processing is usually
indicated by blistering on the component surface
during the soldering operation. Here we would refer Fig. 3.2.8 · Enthalpy
you to the troubleshooting recommendations in
section 6.4. 500
Celanex PBT
3.2.5 Thermodynamics, heat of fusion 400

Vectra A130
Enthalpy ( kJ )
kg
300
Figure 3.2.6 shows the specific heat Cp of Vectra
LCPs as a function of temperature compared to PPS Fortron PPS
200
and PBT. Vectra LCPs have a significantly lower spe-
cific heat than semi-crystalline thermoplastics. The
100
curves are more like those for amorphous thermo-
plastics. This is attributed to the liquid crystalline
0
structure of Vectra. With LCPs, the transition from 0 50 100 150 200 250 300 350
the solid to the melt phase is associated with a rela- Temperature (°C)
tively small change in the state of order since the melt

maintains the high orientation of the solid.
Because of the high order of the melt state and the

ability to solidify with minimal change in structure,
the transition energy during melting or freezing of
25
Vectra®
Vectra is one to two orders of magnitude less than tics. Vectra moldings that are exposed to high temper-
that of semi-crystalline thermoplastics (Fig. 3.2.7). atures in either the short or long term leave little or
no deposits on adjacent cooler surfaces.
Figure 3.2.8 shows the relative phase transition ener-
gies of Vectra A130, Celanex PBT and Fortron PPS Emissions are generated by low-molecular-weight
throughout the heating or cooling cycle. raw material residues or decomposition products.
However, the reaction process used in Vectra LCPs
In designing the optimum of injection molding manufacturing ensures reliable reaction of the raw
machinery and parts, it is essential to know how much materials, while the heat resistance of the polymer
heat must be supplied or removed during processing. minimizes thermal degradation. In addition, the small
With Vectra, less heat has to be removed and the melt fraction of low-molecular-weight residues has such a
freezes rapidly. This means that much faster cycles low boiling point that as a rule it does not cause
are possible than with semi-crystalline materials, so deposits on contacts, diffusors or lenses adjacent to
thus permitting lower-cost production of parts. The heat-stressed Vectra components.
thermal conductivity λ of unreinforced Vectra is in
the same range as that for semi-crystalline polymers. The emission level for standard grades is below 500
Thermal conductivity is dependent both on the base ppm at a temperature of 250°C over 5 hours (Fig.
polymer and the type as well as the use of fillers and 3.2.10). Through the use of high-temperature Vectra
reinforcements (Fig. 3.2.9). grades, this value can be reduced to below 50 ppm
under the same conditions.
3.2.6 Outgassing behavior
Vectra LCPs have very good outgassing behavior

compared with other high-temperature thermoplas-
Fig. 3.2.9 · Thermal Conductivity Fig. 3.2.10 · Outgassing* of Vectra® LCP

1 500
450
Thermal Conductivity (W/m*K)
0.8 400
E540i
350
A430 300
Emission
0.6
E480i E130i
250
200
0.4
E471i 150
S135 100
0.2
50
0
0 E540i E471i S135 S471 S475
0 50 100 150 200 250 300 350 400
* measured at 250°C / 20h
Temperature (ºC)
26
Vectra®
3.3 Behavior on exposure to flame

Table 3.3.1 · Smoke Density of Vectra® A950
(National Bureau of Standards Smoke Density
Vectra LCPs are inherently flame retardant and self-
Chamber, ASTM E-662)
extinguishing. On exposure to very high flame tem-
peratures, the fully aromatic Vectra polymers form Thickness
1.6 mm 3.2 mm
a carbon char layer, which retards the development of Flaming Smoldering Flaming Smoldering
flammable gases.
Specific smoke density – – – –
after 1.5 minutes
Vectra LCPs have a self ignition temperature of over
>540°C. The onset of thermal degradation in air is Specific smoke density 7 – 3 –
after 4.0 minutes
not significant until temperatures of over 380°C are 3
exceeded. Maximum value for 95 2 94 1
specific smoke density
The Limiting Oxygen Index (LOI) according to Time to smoke density of 17 20 17 19

90% of maximum value
ASTM D 2863-77 represents the minimum amount of (minutes)
oxygen as a percentage in air at which the combustion
of the polymer will continue after ignition without an
additional source of energy. The LOI of Vectra Table 3.3.2 · Products of Combustion (in ppm) of
ranges from 40% to 50% depending on the base Vectra® A950 (National Bureau of Standards Smoke
polymer. Density Chamber, ASTM E-662,
Generated on 3.2 x 76.2 x 76.2 mm plaques)
Smoke density measurements and combustion Thickness
products for a representative grade, Vectra A950, are 1.6 mm 3.2 mm
Flaming Smoldering Flaming Smoldering
given in Tables 3.3.1 and 3.3.2. The main combustion
products are carbon dioxide, carbon monoxide and Chlorine – – – –
water. Vectra LCPs also achieved very good results Phosgene – – – –
in the Ohio State University (OSU) heat release test
Hydrogen chloride – – – –
(Table 3.3.3).
Hydrogen fluoride – – – –
Vectra conforms to Underwriters Laboratories UL 94 Formaldehyde – – – –

V-0 at thicknesses as low as 0.2 mm with some Ammonia – – – –
grades. The UL listings can be reviewed at Under-
Carbon monoxide 320 <10 300 <10
writers Laboratories under file number E83005.
Carbon dioxide 8000 600 7000 600
Please note that Ticona is continually developing Nitrogen oxides 5 – 12 –

new grades of Vectra or adding to the data already Hydrogen cyanide – – – –
available for current grades. Please contact the Ticona
Sulfur dioxide – – – –
technical service team or log on to www.Ticona-
us.com (Product Information/Agency Compliance) Hydrocarbons as n-octane 250 – 300 –
for the most up-to-date UL information.
Table 3.3.3 · Heat Release of Vectra® A950
3.4 Electrical properties (Ohio State University)
Thickness of Accumulative heat release Maximum rate of
Vectra LCPs exhibit good electrical properties
test plaque after 2 minutes (kW min/m2) heat release (kW/m2)
(see enclosed product information). The electrical
characteristics combined with easy processing, 1.6 mm 16.8 57.8 (after 177 seconds)
dimensional stability, heat reisstance and mechanical 3.2 mm 2.4 59.2 (after 293 seconds)
integrity make Vectra LCPs a good choice for Specification (FAR) <65 <65
electronic components, especially surface mounted
Meets U.S. Federal Air Regulation, FAR25.853 (A-1), part IV, appendix F
devices (SMD). Vectra grades are also available with
governing materials used in aircraft
low to moderate electrical conductivity (Table 3.4.1).
27
Vectra®
These products are good candidates for antistatic

Tab. 3.4.1 · Vectra® LCP Conductive Grades
applications and electromagnetic shielding (EMI).
Vectra A230D-3 Vectra A700 Vectra A725
Carbon fiber Carbon black Graphite/
carbon black There has so far been no common industry standard
Volume Resistivity* 100 103 101
for determining the dielectric properties of materials.
(Ω · m) Several test methods were therefore evaluated. In the
Surface Resistivity 101 105 104
method finally selected (IEC 250), round test speci-
(Ω) mens with a diameter of 10 mm were punched out
* Measured on molded plaques painted with conductive silver of 0.4 mm thick injection molded plaques and then
metallized on both sides by gold vapor deposition.
The plating helps eliminate possible fault sources
Tab. 3.4.2 · Electrical Properties of such as surface unevennesses. A rough surface tends
As-Molded/Un-Plated Vectra® LCP to lead to lower relative permittivity (DC) values and
1 MHz 10 MHz 100 MHz 1 GHz 2 GHz higher dissipation factors (tan δ) due to poor contact.
Relative Permittivity
The relative permittivity values determined by the
A130 3.7 3.2 3.5 3.2 – method used here therefore tend to be relatively higher
A430 3.1 2.8 – – – and the tan δ values lower than values measured on
E130i 3.3 3.2 3.2 3.1 –
unplated specimens (see enclosed table). On the other
hand, they are more realistic, since antennae or parts
E471i 3.8 3.7 – – –
for shielding applications are normally also metallized.
E820i 3.6 – – – – When selecting materials on the basis of relative per-
S135 3.5 3.4 – – – mittivity (DC) and tan δ values, it is therefore essen-
Dielectric Loss Tangent
tial to take into account the specific test method used
to determine the dielectric characteristics.
A130 0.018 0.008 0.007 0.006 –
A430 0.016 0.008 – – – Tables 3.4.2 and 3.4.3 give the relative permittivity
E130i 0.025 0.02 0.01 0.008 – values and dissipation factors at various frequencies
for some selected Vectra grades used in antennae and
E471i 0.031 0.007 – – –
shielding applications.
E820i 0.03 – – – –
S135 0.009 0.023 – – – Figure 3.4.2 shows the relativity permittivity and
dissipation factors of some characteristic Vectra
grades as a function of frequency. The temperature
Tab. 3.4.3 · Electrical Properties of dependency of these values can be seen in Figure
Gold Plated Vectra® LCP 3.4.1 for the E820i Pd grade specially developed for
1 MHz 10 MHz 100 MHz 1 GHz 1,8 GHz plating.
Relative Permittivity
A130 5.18 5.05 5.00 5.01 5.00 The tests were carried out by COMTECH Labor für
A430 4.34 4.25 4.20 4.19 4.23 Kunststoffe GmbH Munich on a Hewlett Packard
HP 4291A RF impedance analyzer in the 1 MHz to
E130i 6.77 6.49 6.33 6.26 6.29
1.8 GHz range.
E820i 7.19 6.92 6.79 6.74 6.79
E820i Pd 6.79 6.54 6.42 6.39 6.43 Underwriters Laboratories (UL) has evaluated the
Dielectric Loss Tangent majority of Vectra grades. They report measurements
of flammability, arc resistance, hot wire ignition, high
A130 0.014 0.009 0.006 0.006 0.006
current arc ignition, high voltage tracking rates and
A430 0.009 0.006 0.003 0.004 0.005 comparative tracking index. The data is reported on
E130i 0.019 0.015 0.010 0.004 0.004 the UL “yellow card”. Many Vectra products allow
E820i 0.016 0.014 0.009 0.004 0.006
the use of 50% regrind while continuing to maintain
the UL rating.
E820i Pd 0.016 0.013 0.008 0.003 0.005
28
Vectra®
Fig. 3.4.1 · Relative Permittivity/Dielectric Loss Fig. 3.4.2 · Relative Permittivity/Dielectric Loss
Tangent vs Temperature, Vectra® E820iPd, Tangent vs Frequency for Vectra®,
Gold Plated Gold Plated
0.05 0.025
0.0424
Dielectric Loss Tangent, tan δ
0.04
Dielectric Loss Tangent, tan δ

0.020
0.03
1.8 GHz E130i
0.015
0.02 0.0163
1 MHz
E820i Pd
0.01 0.010 3
0.007
0.0055 0.0085
0 A430
0.0012 0.005
–0,01
–20 20 60 100 140 0.000
Temperature (°C) 106 107 108 109
Frequency (Hz)
8 7.00
7.84 E820i Pd
7.8
6.50 E130i
7.6
Relative Permittivity, DC
6.00
Relative Permittivity, DC
7.4
1 MHz
7.2
5.50
7
6.8 5.00
6.8
6.61
6.6 4.50
6.4 6.59 1.8 GHz A430
6.43 4.00
6.2 106 107 108 109
6.12 Frequency (Hz)
0
–20 20 60 100 140
Temperature (°C)
In addition, the UL tests also establishes the RTI tensile strength (mechanical strength without impact)
(= relative thermal index). Based on thermal aging and tensile impact strength. Vectra products are
measurements, the RTI for a given formulation gives assigned a generic RTI rating of 130°C based on their
a guideline temperature for the long-term retention of chemistry and historic performance, before testing is
characteristic properties such as dielectric strength, complete.
29
Vectra®
3.5 Rheological properties

Fig. 3.5.2 · Melt Viscosity versus Temperature
(Glass filled grades at shear rate = 1.000/s)
Vectra® LCPs have a nematic liquid crystal structure.
The melt viscosity decreases continually with in- 300
creasing deformation (shear) rate. At the shear rates Molding Range
that normally occur during injection molding, the 250
melt viscosity of Vectra is lower than that of conven-
Viscosity (Pa . s)
200
tional filled or reinforced polymers (Fig. 3.5.1). E130i
150
100
Fig. 3.5.1 · Melt Viscosity Comparison A130
Vectra® LCP versus Semi-Crystalline Polymer 50
0
1000 280 300 320 340 360
Temperature (°C)
Liquid Crystal Polymer
Viscosity (Pa . s)
Conventional Polymer
100
Fig. 3.5.3 · Melt Viscosity versus Temperature
(Unfilled grades at shear rate = 1.000/s)
600
10
0.1 1 10 100 1000 10000 500
–1
B950
Shear Rate (s )
Viscosity (Pa . s)
400
300
The melt viscosity values of some important glass
200
filled grades as a function of temperature are com- E950i
pared in Fig. 3.5.2. 100
A950
0
The melt viscosity values for selected unfilled Vectra 280 300 320 340 360
polymers frequently processed by extrusion are Temperature (°C)
shown in Fig. 3.5.3.
With Vectra LCPs, it is possible to fill very thin walls 3.6 Regulatory approvals and standards
down to less than 0.2 mm. The injection pressures are
lower than with amorphous or semi crystalline resins. 3.6.1 Food contact / materials and articles
Vectra can be used to produce thin-walled miniature
parts and complicated parts with long flow paths, such EU:
as long, narrow connectors or small coil bobbins. For plastics to obtain food contact approval, the raw
Despite good melt flow at the high shear rates, which materials used must be listed under the German
normally occur in injection molding, Vectra does not Regulations for Materials and Articles Coming into
form any flash. It is therefore possible to mold thin- Contact with Food (BG-VO) or other national regu-
walled articles and parts with movable cores without lations, such as the Recommendations of the German
any flash. In the case of connectors and relays, for Federal Institute for Risk Assessment (Bundesinstitut
example, this can sometimes bring a considerable für Risikobewertung – BfR, previously the BgVV
reduction in manufacturing cost because, the costly and, before that, the BGA). The BG-VO regulations
deflashing step is unnecessary. transpose into German national law the EU Directive
2002/72/EC (“Plastics Directive”) and its 4 amend-
ments 2004/1/EC, 2004/19/EC, 2005/79/EC, and
2007/19/EC.
30
Vectra®
If limits are specified for the listed substances, then UK – WRAS:

the finished parts must be tested by the manufacturer In the UK, all materials must be listed at WRAS
or seller to ensure compliance. If the plastic consists (= Water Regulations Advisory Scheme), before a test
of listed substances that are not subject to any indi- can be carried out. Various Vectra grades are listed
vidual limit, then the finished part must be tested for and have been “pretested” for use in contact with
global migration. drinking water up to a temperature of 85°C – these
can be viewed on the WRAS website.
Most of the raw materials used to produce our Vectra (http://www.wras.co.uk)
grades are listed in EU Directive 2002/72/EC (and the
BG-VO), i.e. the relevant Vectra grades are generally Germany – KTW
suitable for food contact use in the EU. In Germany, a few representative Vectra grades have 3
passed the so-called KTW tests (KTW = plastics in
USA: contact with drinking water), which were carried out
Many Vectra grades are compliant for food contact on test plaques. The plaques were subjected to both
with the FDA (Food and Drug Administration). the cold and hot (90°C) water tests. We can supply
They are approved for for food contact use under the KTW certificate awarded for the tests on request.
the system of premarket notifications through the
following Food Contact Notifications (FCN): The microbiological test as per Worksheet W270 of
FCN no. 103 and FCN no. 423. These FCNs can be the German Technical Association for Gas and Water
viewed in detail on the FDA website. (DVGW Arbeitsblatt W270) has also been carried out
(http://www.cfsan.fda.gov) on a representative Vectra grade.
3.6.2 Drinking water applications USA – NSF

Regarding drinking-water applications in the USA
Vectra grades are generally suitable for use in contact there is an exemplary test of a Vectra grade according
with drinking water. Various countries operate differ- to NSF standard 61 in process (NSF = National
ent approval application procedures but all are based Sanitary Foundation). On the basis of several existing
on the same principle. The final customer sends his approvals in other countries we expect a positive
product to the testing institute, which then – on result of the tests and the corresponding listing at
request – obtains the relevant formulation from the NSF in approx. 4–6 months.
material manufacturer (= Ticona) and carries out
the test. The final customer is then informed of the FR – ACS
test result and, if the product has passed, is given So far no tests have been carried out in accordance
a corresponding test certificate from the testing with the French ACS (Attestation Conformite
institute. Sanitaire) requirements.
In some countries, Ticona has performed the relevant Important information: The German drinking water
tests on test specimens produced from standard grades (KTW) regulations apply to products used in the
to give final customers the best possible guarantee drinking water system from the public reservoir via
that their products will also pass this test. However, the pipeline distribution system and domestic instal-
possession of such a manufacturer’s material test cer- lations to the end of the faucet. Once the water has
tificate does not exempt final customers from testing left the faucet, materials and articles coming into
the end product. contact with drinking water are covered exclusively
by the German Regulations for Materials and Articles
The most important approval application procedures Coming into Contact with Food (Lebensmittel-
within the EU (those of the UK, France and Ger- Bedarfsgegenstände-Regularien) (see also section
many) and the US procedure differ in a number of 3.5.1).
details, which have already been or will be taken into
account in the manufacturer’s material approval tests:
31
Vectra®
3.6.3 Medical / pharmaceutical applications 3.6.5 Canadian Standards Association (CSA)

flammability classification
Vectra MT products have been specially formulated
for use in the medical and pharmaceutical sectors. The Canadian Standards Association (CSA) has
As a result, they fulfil additional criteria besides con- approved most commercially available Vectra prod-
formity with food contact requirements: ucts. To obtain information on individual grades,
please contact Ticona’s Technical Customer Service
– formulation consistency team.
– freedom from additives of animal origin
(BSE freedom) 3.6.6. Industry standards
– listing in the FDA Drug Master File (DMF)
– listing in the FDA Device Master File (MAF) Vectra products comply with many electrical/elec-
– biocompatibility test as per the USP (United States tronics and automotive industry standards on the
Pharmacopeia) class VI and /or ISO 10993 absence of harmful substances, including the Joint
(ISO 10993-5; -10; -11) Industrial Guide (JIG) list for the electrical/elec-
tronics industry and the Global Automotive
In addition, cytotoxicity and pyrogenicity tests have Declarable Substance List (GADSL). In addition,
been carried out for some grades. some products have an IMDS (International Material
Data System) entry.
3.6.4 Underwriters Laboratories (UL) flame
classification 3.6.7. Recycling
Vectra is inherently flame-retardant. Most commer- In terms of hazardous substances, Vectra grades meet
cially available Vectra products are listed with UL the requirements of the EU Waste Electrical and
flame class V-0. Details of the properties and classi- Electronic Equipment (WEEE) Directive, the Restric-
fication of the materials are given on the relevant tion of Hazardous Substances (RoHS) Directive and
Yellow Cards and can be viewed on the UL website the End-of-Life Vehicle (ELV) Directive.
(http://www.ul.com)
For information about other approvals or questions
Further information can be obtained from Ticona’s of conformity relating to individual products, please
Technical Customer Service team. contact Ticona’s Technical Customer Service team.
32
Vectra®
4. Behavior in relation to
environmental effects
4.1 Hydrolysis Prolonged exposure at high temperatures leads to
gradual hydrolytic degradation.
Vectra has exceptional resistance to hydrolysis, com-
pared with other polyesters. Figs 4.1.1 to 4.1.4 show Vectra has exceptionally low equilibrium moisture
the results of immersion tests in hot water and steam. content (see enclosed product information).
Fig. 4.1.1 · Tensile Strength versus Fig. 4.1.3 · Tensile Strength versus
Immersion Time in Hot Water (120°C, 2 bar) Immersion Time in Steam 3
100 100
80 80 4
A130 A130
Retention (%)
Retention (%)
60 60
E130i
40 40
E130i
20 20
0 0
0 500 1000 0 500 1000
Immersion Time (hours) Immersion Time (hours)
Fig. 4.1.2 · Tensile Modulus versus Fig. 4.1.4 · Tensile Strength versus
Immersion Time in Hot Water (120°C, 2 bar) Immersion Time in Steam
100 100
E130i
E130i
80 80
A130
Retention (%)
Retention (%)
60 60
A130
40 40
20 20
0 0
0 500 1000 0 500 1000
Immersion Time (hours) Immersion Time (hours)
33
Vectra®
4.2 Chemical and solvent resistance

Table 4.2.1 · Chemical Resistance
Vectra has very good resistance to chemicals, partic- Rating: + Resistant – less than 2% change in weight and dimension,
less than 5% change in mechanical properties.
ularly to organic solvents (even at high temperatures)
o Limited resistance
and to the cleaning agents normally used in the – Not resistant
electronics industry. Its resistance to concentrated
mineral acids and alkaline (both inorganic and organic)
at elevated temperature is problematic.
Medium Conditions Vectra® LCP Rating
(time/temperature) grade
The resistance of Vectra to methanol and methanol-
Acetic acid (100%) 30 days/118°C A950 +
containing fuels depends very much on the tempera- 20 days/23°C A625 +
ture and degree of contact. In applications involving
Acetone 180 days/56°C A950 +
constant contact with methanol-containing fuels, the
A130 +
temperature should not exceed 70°C. The results of A625 +
testing in various chemicals, solvents and fuels are
Acetonitrile 120 days/23°C A625 +
given in Table 4.2.1. The results were determined on
injection molded test specimens without any exter- Brake fluids:
nally induced stress. The additional effect of mechan-
Castrol® TLX 988C 30 days/121°C A130 o
ical stresses can alter chemical resistance. The data are A950 +
therefore intended for initial guidance only. Before B950 +
90 days/121°C A130 –
commercial use, moldings or test specimens produced NAPA® brand DOT-3 90 days/121°C A130 o
from Vectra should be tested under actual service
Chlorine gas 180 days/23°C A950 +
conditions. Changes in concentration, temperature or
A130 +
the particular formulation can significantly affect A625 +
chemical resistance.
Chlorine/water 180 days/23°C A950 +
(saturated solution) A130 +
Five test bars (127 mm x 12.7 mm x 3.2 mm) were A625 +
immersed in the medium for a given perod of time
Chromic acid (50%) 90 days/50°C A625 +
without any externally induced stress. Changes in 180 days/50°C A950 +
weight, dimensions, flexural strength, flexural modulus A130 o
A625 o
and hardness were measured. 30 days/70°C A950 +
A130 +
60 days/70°C A950 +
A130 o
Chromic acid (70%) 30 days/88°C A950 +
A130 o
A625 o
Dimethyl formamide (DMF) 180 days/66°C A950 +

A130 +
A625 +
Diphenylamine 180 days/66°C A950 +

A130 +
A625 +
Diphenyl carbonate 10 days/250°C A950 –
Ethanol 30 days/52°C A950 +
Ethyl acetate 180 days/77°C A950 +

A130 +
A625 +
Ethylene diamine 30 days/100°C A950 –

180 days/23°C A950 +
A130 o
A625 +
34
Vectra®
Table 4.2.1 · Chemical Resistance (Continued) Table 4.2.1 · Chemical Resistance (Continued)
Medium Conditions Vectra® LCP Rating Medium Conditions Vectra® LCP Rating
(time/temperature) grade (time/temperature) grade
Ethylene glycol 30 days/50°C A950 + Methylene chloride 180 days/40°C A950 +

(Antifreeze/water) 30 days/121°C A950 o A130 o
(50/50) B950 o A625 +
A150 –
Monochloroacetic acid 180 days/50°C A950 +
Fluorinert® A130 +
FC-70 1 day/215°C A950 +
A625 +
A130 +
Morpholine 10 days/132°C A130 +
Formic acid (80%) 30 days/104°C A950 +
(200ppm/steam)
A625 + (tetrahydrooxazine)
270 days/104°C A950 o
A625 o Nitric acid (50%) 120 days/23°C A625 +
455 days/104°C A950 – 60 days/70°C A950 +
A130 +
Fuels:
180 days/70°C
A625
A950
+
+
4
Fuel C (ASTM D471) 30 days/121°C A950 + A130 o
50/50 iso-octane/toluene B950 + A625 +
90 days/121°C A130 o Nitric acid (70%) 30 days/88°C A950 o
Fuel C + 20% methanol 125 days/60°C A130 + A130 –
A230D-3 o A625 o
Fuel C + 20% ethanol 125 days/60°C A130 +
A230D-3 o Nitrobenzene 30 days/66°C A950 +
M-85 fuel 20 days/121°C A130 –
Nitroglycerine 30 days/66°C A950 +
Lead free gasoline (petrol) 30 days/121°C A950 +
B950 +
Oils:
90 days/121°C A130 +
Lead free gasoline 30 days/121°C A950 o Engine Oil, 10W-30 30 days/121°C A950 +
(petrol) + 10% methanol B950 o B950 +
90 days/121°C A130 – A130 +
90 days/93°C A130 o Shock absorber-Oil 40 days/150°C A130 +
A625 + (Shell® GHD 15)
Gasoline (petrol) 30 days/121°C A950 + Silicone-Oil 30 days/200°C A950 +
w/70/30 heptane/toluene, B950 + Hydraulic-Oil 30 days/71°C A950 +
copper ion, t-butyl-hydro- (Skydrol®) B950 +
peroxide Transmission-Oil 30 days/149°C A625 +
(Dexron® II) 90 days/149°C A625 +
Hexafluoro-isopropanol 10 days/25°C A950 –
Pentafluorophenol 10 days/60°C A950 –
Hexane 10 days/23°C A625 +
Phenol 100 days/100°C A950 +
A130 o
Hydrochloric acid (37%) 30 days/88°C A950 + A625 +
A130 o
A625 o Refrigerants:
120 days/88°C A950 o
A130 o Refrigerant R-22 30 days/80°C A950 +
A625 o A625 +
Refrigerant R-12 60 days/100°C A625 +
Hydrofluoric acid 30 days/23°C A950 – + 5% refrigerator oil
(anhydrous) Refrigerant 113 180 days/47°C A950 +
A130 +
A625 +
Hydrogen chloride 30 days/23°C A950 –
Refrigerant R134A 60 days/100°C A625 +
(anhydrous)
+ 5% refrigerator oil
H-FCKW 123 10 days/50°C A130 +(1)
Iso-octane 14 days/60°C A625 +
120 days/23°C A625 + Sodium Hydroxide (5%) 90 days/23°C A950 +
A130 +
Methanol 30 days/64°C A950 + A625 +
B950 + 180 days/23°C A950 +
90 days/64°C A130 + A130 o
45 days/110°C A130 – A625 o
35
Vectra®
4.3 Permeability to gases and vapors

Table 4.2.1 · Chemical Resistance (Continued)
Medium Conditions Vectra® LCP Vectra has extremely low permeability to gases and
Rating (time/temperature) grade
water vapor. Figure 4.3.1 shows the superior perfor-
30 days/70°C A950 + mance of unfilled Vectra polymers compared with
A130 o conventional barrier materials such as ethylene vinyl
60 days/70°C A950 o
A130 o alcohol copolymer (EVOH), polyvinylidene chloride
180 days/70°C A950 o (PVDC), MXD6 (a copolyamide of meta-xylenedi-
A130 –
A625 –
amine and adipic acid), and PCTFE (polychloro-
Sodium Hydroxide (10%) 90 days/23°C A950 + trifluoroethylene). The greater impermeability of
A130 + Vectra makes it possible to use thinner barrier layers
180 days/23°C A950 +
A130 + in coextruded structures. In the production of liquid
A625 o crystalline monolayer film, the problem of fibrillation
30 days/88°C A950 o
A130 –
must be addressed. This anisotropy can be overcome
Sodium Hydroxide (30%) 30 days/88°C A950 – by post-extrusion techniques such as biaxial orienta-
A130 – tion (see section 7, Extrusion). The water permeability
A625 –
of Vectra is shown in Table 4.3.1.
Sodium hypochlorite 28 days/23°C A130 o
(12.5%) 28 days/70°C A130 –
4.4 Radiation resistance
Sulphuric acid (50%) 180 days/88°C A950 +
A130 + Vectra has excellent resistance to gamma radiation.
A625 +
Sulphuric acid (70%) 5 days/190°C A950 – Table 4.4.1 shows the effect of Cobalt 60 radiation on
A130 – the mechanical properties of Vectra A950.
A625 –
Sulphuric acid (93%) 8 days/23°C A950 o
A625 o 4.5 Ultraviolet and weathering resistance
B950 –
30 days/121°C A950 –
A130 – On exposure to weathering, Vectra, like other
A625 – plastics, shows a surface change over time. The main
A950 –
reason for this is UV radiation. It causes a white
Tetrahydrofuran (THF) 120 days/23°C A625 + deposit of degraded material to form on the surface
(“chalking”) with consequent loss of gloss, color
Toluene 180 days/111°C A950 +
A130 + change and deterioration in mechanical properties.
A625 +
Trichlorethane 90 days/66°C A950 +

After artificial weathering for 2000 hours, samples
molded from Vectra retained over 90% of their initial
Urea (46%) 60 days/88°C A950 o mechanical property values (Table 4.5.1). After one
A130 –
A625 o year’s outdoor weathering, a slight white deposit was
detected.
Water 10 days/121°C A950 +
40 days/121°C A950 o
A625 +
60 days/121°C A950 o
A130 o
Water vapor 70 days/121°C A950 o

A130 o
A625 + (1) Weight change in 60 x 60 x 4 mm plaques only
Castrol ® TLX is a registered trademark of Castrol Limited.

NAPA® is a registered trademark of National Automotive
Parts Association.
SKYDROL ® is a registered trademark of Monsanto Co.
DEXRON ® is a registered trademark of General Motor Corp.
Fluorinert ® is a registered trademark of Minnesota Mining and
Manufacturing Co.
Shell ® is a registered trademark of Shell Oil Co.
36
Vectra®
Fig. 4.3.1 · Permeability of Various Polymer Films (Thickness 25 µm)

1000
O-Nylon 6 Nylon 6
100
at 38°C, 90% RH (g/m2 day bar)
PAN
Water Vapor Permeability
32 mole % C2 EVOH-F, 100% RH
44 mole % C 2 EVOH-E, 100% RH O-PET LDPE

10
MXD6 Nylon, 90% RH
HDPE & PP-O
PVDC COC
1
PCTFE
Vectra LCP
0-100% RH
0.1
4
0.1 1 10 100 1000 10000 100000
O2 Permeability
at 23°C, 0% RH (cm3/m2 day bar)
Table 4.3.1 · Permeability of Various Polymer Films Table 4.4.1 · Cobalt 60 Radiation
(Thickness 25µm) Vectra® A950 (Percent retention of properties)
Material O2 Permeability Water Vapor Radiation Dose 25 100 250 500
Permeability Mrads Mrads Mrads Mrads
23° C, 0% RH 38°C, 90% RH
cm3/m2 day bar g/m2 day bar Tensile strength(1) 97 95 95 95
Vectra LCP 0.9 0.3 Tensile modulus(1) 100 100 106 106
COC 1515.4 1.1 Break elongation(1) 81 81 79 79
EVOH-E 100%RH 9.1 21.4 Flexural strength(2) 101 102 102 102
EVOH-F 100%RH 12.0 57.9 Flexural modulus(2) 108 108 116 125
PVDC 1.4 3.9 HDT @ 1.82 MPa(3) 100 100 100 94
MXD6 11.7 15.3 (1) ASTM D638 (2) ASTM D790 (3) ASTM D648
MXD6 + Co 0.3 15.3
PAN 17.5 98.4 Table 4.5.1 · Results of Artificial Weathering

Nylon 6-oriented 27.2 158.1 for 2,000 hours
Nylon 6 77.3 307.1 (ASTM D2565 – xenon arc lamp,
PET-oriented 35.2 18.6 air temperature 125°C,
water spray for 18 minutes every 202 minutes)
PCTFE 221.5 0.6
(Percent retention of properties)
PP-oriented 2067.1 5.9
HDPE 2137.0 5.9 Vectra A950 Vectra A130
Tensile strength(1) 95 95
Tensile modulus(1) 90 98
Table 4.3.2 · Hydrogen Permeability Flexural strength(2) 95 95
Material Test Conditions H2 Permeability Film Flexural modulus(2) 95 95

cm3/m2·d·bar Thickness
HDT @ 1.82 MPa(3) 90 92
Vectra A950 40°C, 0% RH 78 50 µm
Notched Izod(4) 90 95
Vectra A950 150°C, 0% RH 98 2.5 mm
(1) ASTM D638 (2) ASTM D790 (3) ASTM D648 (4) ASTM D256
Vectra E130i 150°C, 0% RH 104 2.5 mm
37
Vectra®
5. Processing
Vectra is very suitable for conventional processing 5.1.1 Startup and shutdown procedures
methods such as injection molding and extrusion.
The most commonly used processing method for Startup
Vectra is injection molding. Fast cycles, good pro-
cessability and the possibility of blending with (sorted) The barrel temperatures are set to the level required
regrind increase cost efficiency. for processing. When the set values have been reached,
it is advisable to wait for 5 minutes before filling the
Because of the material’s good flow properties and plasticizing barrel. When the barrel has been filled,
low tendency to form flash, very long, thin-walled several shots are ejected into the open (air shot).
parts can be produced. Special attention should be given to the nozzle tem-
perature because if it is too cold the melt will freeze
5.1 Safety recommendations and block the nozzle. When the temperature of the
melt ejected into the open has been checked with a
Processing of Vectra poses no particular safety risk, needle pyrometer and the melt is flowing perfectly,
provided standard industry safety practices are processing can start.
observed. However, like most polymers, Vectra
decomposes when heated to excessively high tempe- Short and long interruptions
ratures. If insufficient ventilation is available, decom-
position products can build up that then may be For interruptions of less than 10 minutes no special
harmful to health. A suitable ventilation system is measures are required. For longer interruptions
therefore required. thorough evacuation of the barrel followed by a
100°C temperature reduction is recommended.
To prevent thermal decomposition, off-gassing and
pressure build-up in the barrel, melt temperatures Changing from another thermoplastic to Vectra
should not exceed 330°C for A polymers, 360°C for
Ei polymers and 380°C for S polymers. These tem- Since many other plastics are less thermally stable at
peratures are well above the normal processing range. the processing temperatures used for Vectra, it is
For more extended shutdowns (> 10 min), run the advisable to purge them from the machine before-
screw dry and lower the barrel temperatures by at hand as thoroughly as possible. A suitable purging
least 100°C. See section 6.2 for recommended pro- material is polypropylene (glass fiber reinforced
cessing conditions. grades have a better cleaning effect).
Other important precautions: The purging material is purged into the open at the
relevant melt temperature until it runs clean. Before
– Sufficient time should be allowed to heat up the increasing the barrel temperatures to the values
machine. The barrel should have reached the recommended for Vectra, the injection unit must be
required processing temperature settings 5 minutes run until empty. When the set temperatures are
before feeding in the pellets and turning the screw. reached, run Vectra with the unit retracted from the
– When handling hot material and molds, gloves, mold until the melt is free of all traces of the purge
protective clothing and goggles should be worn. material. Once this has happened, injection molding
– When switching off the machine, the injection unit can begin.
should be retracted.
Changing from one Vectra grade to another
Material Safety Data Sheets (MSDS) are available for
all Vectra grades. Always consult the MSDS before It is possible to process different Vectra grades using
working with any Vectra grade. one grade to remove another without purging with
38
Vectra®
another polymer in between. For this purpose, the 5.2 Drying

first material is completely pumped out and then
displaced by the second material. In case of a color Vectra resins are well known for their low water
change (particularly from black to natural), it is absorption. In order to ensure optimum molded part
important to ensure that the color of the previous properties, the resin and any regrind should be dried
material has been completely removed from the correctly prior to processing. If the resin is not
machine. properly dried, residual moisture can cause voids,
outgassing (so-called blisters) and in extreme cases
Shutting down the machine polymer degradation. These effects can result in poor
part quality. It is therefore important for the material
If Vectra is to be processed again after the machine to be dried under the recommended conditions and
has been shut down, the injection unit must simply appropriate equipment.
be run until empty. Then the nozzle and barrel
heaters can be switched off. If a change to another In order to ensure the quality of molded parts, a
thermoplastic is planned, the Vectra must first be dessicant air dryer with two or more desiccant beds is
purged with polypropylene. The temperatures should strongly recommended. Such dryers allow drier air
remain set at Vectra processing temperatures because than single bed dryers to be delivered to the plastic,
if they are reduced prematurely traces of Vectra can so reducing both moisture content and the necessary
no longer be purged out. drying time. The material should also be allowed to
reach the recommended drying temperature before
5.1.2 Fire precautions the drying time is started. When resin is placed in a 5
hopper at room temperature, it may take 2 to 6 hours
Vectra is inherently flame retardant. Nevertheless, for the material to reach the necessary drying temper-
is advisable when storing or processing the plastic ature. This time will vary according to the thermal
to take the necessary fire precaution measures. properties of the plastic, the mass of material being
Particular care should be taken to observe the specific dried, and the design of the hopper. In addition, it is
regulations applicable in the processing or storage important to note the location of the thermocouple
location. Certain end products and fields of applica- that measures the temperature of the air being deliv-
tion may impose special requirements from the fire ered to the hopper. Dryer systems that do not mea-
prevention standpoint. It is the responsibility of the sure the air temperature at the inlet of the hopper
raw material converter to ascertain and observe such might not accurately represent the delivery air tem-
requirements. perature. This is because significant heat loss can
occur between the exit of the dryer unit and the inlet
of the hopper. Heat loss, even through insulated
tubes, can result in up to a 50°C lower drying tem-
perature.
39
Vectra®
Summary of drying recommendations
1. The resin inside the hopper should be allowed to

reach the drying temperature, before the minimum
drying time is started.
2. A desicant dryer with two or more desiccant beds

capable of reaching -40°C dew point or below is
recommended.
3. Vectra resin should be dried in accordance with the

information in the following table. To ensure effec-
tive drying, the residual moisture content of the
dried material should be less than 0.01% (100 ppm).
Table. 5.2.1 · Drying conditions

Vectra® LCP A series B series Ei & S series V400P
V140 V143XL
Temp. (°C) 150 150 150 / 170 90
Time (hours) 4–24 6–24 6–24 / 4–16 8–24
4. Ensure the delivery air temperature readout

represents the actual temperature of the air being
delivered to the hopper.
Regrind should be dried for 2 hours longer than the

drying conditions recommended for virgin material,
because of its porosity and greater surface area.
40
Vectra®
6. Injection Molding
6.1 Machine requirements Fig. 6.1.1 · Metering Type Screws
Recommended for Processing Vectra® LCP
Vectra can be processed much like any other thermo-
plastics using common injection molding machines. Overall Length
Shank
Flight Length
Length
6.1.1 General Metering Feed Outside
Valve Depth Depth Diameter
Abrasive wear, particularly by glass, can occur on the
lands and edges of injection screws. In time, the root
diameter will wear in the feed, compression and Tran-
Metering Feed
metering zones. The highest level of wear and location Zone
sition
Zone Zone
of wear on the screw will depend on the type of mate-
rial and barrel utilization. The screw should there-
fore be made of a heat-treated alloy steel with a hard 6.1.3 Check ring
surface.
Because Vectra plastics have such low viscosity,
The barrel should be fitted with all heating zones it is essential for the check ring non-return valve to
independently controlled to ensure precise tempera- function correctly (Fig. 6.1.2). The check ring is
ture control. This is especially critical for the higher working properly if it holds a constant melt cushion.
temperature Vectra grades. Malfunctioning check rings result in inconsistent
parts, short shots and poorly formed weld lines. 5
Despite the thermal stability of the melt, it is impor-
tant to aim for the shortest possible melt residence time Fig. 6.1.2 · Check Ring Non-Return Valve Used on
(between 3 and 5 min) in the barrel, i.e. the capacity of Reciprocoating Screw Injection Molding Machine
the machine should be matched to the shot weight of
the injection molding. A. Plastication 6
Since Vectra is a fast-cycling material, the machine

should have a high plasticating capacity.
6.1.2 Screw design
The design of the screw is not crucial for processing

Vectra but some general rules should be observed:
(see Fig. 6.1.1). A three-zone screw divided into feed,
compression and metering zones is preferred. How- Check Ring Open
ever, a higher percentage of feed flights may be neces-

sary for smaller machines. B. Injection
Zone division:
– 1/2 feed
– 1/4 compression
– 1/4 metering
The screw length/diameter ratio (L/D) should be

between 16:1 and 24:1. 20:1 L/D is preferred and most
common for conventional molding.
Check Ring Closed
The preferred compression ratio ranges from 3:1 for
larger machines to as low as 2:1 for smaller machines
(see Fig. 6.1.1).
41
Vectra®
6.1.4 Nozzle Care should be taken to ensure that the molten mate-
rial is not retained for too long in the hot runner
Vectra can be processed with a free-flow or needle during processing. If possible, the total residence time
shut-off nozzle. In the case of free-flow nozzles, those in the melt should be less than 5 minutes to minimize
with a small aperture (1.5 to 2.5 mm) are recommended the thermal stress on the material. It is important to
to prevent drooling of the melt. Nozzles should be as ensure that uniform flow occurs right from the start
short as possible and have a heating band with its own of filling (swelling flow). This is achieved by correct
temperature control system. If drooling or stringing positioning of the gate, so that it injects against a core
occurs, the problem can normally be eliminated by or a wall. Jetting should be avoided. Flow to the part
reducing the nozzle temperature or the nozzle dia- can be achieved either directly from the hot runner
meter. or via a cold sub-runner. The recommendations for
Vectra runner geometry apply to sub-runners (Fig.
6.1.5 Hot runner systems 6.1.4). All cavities should be designed so that flow
resistance remains constant. Otherwise, the low vis-
Vectra can be processed successfully in hot runner cosity of Vectra can result in the melt moving ahead in
systems to conserve material and reduce the labor regions of low flow resistance, possibly leading to
input. Externally heated hot runner systems as well warpage problems.
as combinations of internally and externally heated
systems are preferable to internally heated (torpedo)
systems for processing Vectra. Externally heated hot Fig. 6.1.3 · Hot Runner System for small parts
runner systems achieve an even flow of material with
a constant melt temperature over the cross-section of Ø approx. 3–5 mm
the hot runner. The heat energy is evenly distributed
from outside to inside, so ensuring homogeneous Ø approx. 3–5 mm
temperature distribution in the melt. The choice of

the correct tool steel is important in the design of hot
runner tools for processing Vectra (HRc > 56).
Ø approx. 3 mm
The hot runner system designer should also consider
the shearing of the material and associated effect on
Ø 0.3– 0.6 mm
viscosity. The runner diameter in hot runner systems
should be designed according to shot weight in the
same way as for cold runner systems. Low shot
weights require runner diameters in the hot runner Fig. 6.1.4 · Hot Runner Distributor
nozzle of about 3 mm. In the hot runner manifold
block, runner diameters of 3-5 mm are usual. On the 2-cavities 4-cavities
other hand, with large shot weights (over 100 g),

the runner diameters normally used for processing
thermoplastics are recommended for the nozzle and
hot runner manifold block. For small components,
the hot runner gate diameter should be between 0.3
and 0.6 mm (see Fig. 6.1.3), while for large moldings,
gate diameters of about 0.8 to 2 mm are recommended. 8-cavities
Because of the required material shear, nozzles with
tips or torpedos are customary but needle shut-off
nozzles may also be used.
42
Vectra®
Parts manufactured from Vectra with hot runner 6.2.1 Melt temperature
systems are typically small, thin-walled parts for the
electrical/electronics industry, where good high-tem- Determine the melt temperature manually with a
perature resistance is required for soldering operations. needle pyrometer when the machine has been cycling
To maximize the heat resistance of the molded part, for several minutes. If there are any deviations from
the processing temperature profile should be kept as the set value, the barrel and nozzle heater settings must
low as possible within the recommended processing be adjusted accordingly. Melt temperature should
range. Residence times should also be minimized. generally be checked in this way, because the melt
A cold runner system that is properly designed is best thermocouples integrated into the injection molding
for inducing shear and may be preferred over a hot machine do not always show the true value.
manifold system. In addition, polymer stagnation in
a hot manifold system may be possible since Vectra If the molded parts are to be exposed to elevated
has a low heat of fusion. temperatures above 220°C, e.g. during a subsequent
soldering operation, then it is imperative that Vectra
6.2 Processing conditions is thoroughly predried and not overheated during
processing. Melt temperatures should, if possible, be
Vectra is notably easy to process. Typical processing maintained within the lower range of the temperatures
temperatures are shown in Fig. 6.2.1. Recommen- recommended in Fig. 6.2.1 and the melt residence time
dations for startup, shutdown and material changeovers in the barrel should be 3 to 5 min.
are given in section 5.1.1.
6.2.2 Injection rate
To improve weld line strength and flow, very fast

injection rates should be used for small moldings
Fig. 6.2.1 · Typical Injection Molding Conditions (0.2 to 0.3 sec fill time). With increasing shear, the
melt viscosity of Vectra rapidly decreases. For parts 6
TW1 TW2 TM
TD
that are difficult to fill, the injection rate can be
increased to improve flowability. Increasing the
injection rate and mold temperature may be more
effective than raising the melt temperature and pre-
serves the quality of the plastic at the same time.
6.2.3 Mold temperature
TN T4 T3 T2 T1 nS Vectra can be processed over a wide range of mold

temperatures, with temperatures between 65°C and
120°C being the most common. Higher mold temper-
Processing Temperatures (°C)
A and B series Ei series S series V400P
atures usually result in a smoother surface finish and
V140 V143XL achieve improved flow performance.
T1 270-280 315-325 330-350 185-195
T2 275-285 315-325 340-360 205-215 6.2.4 Screw speed

T3 280-290 325-335 345-365 205-215
The screw speed should be sufficiently high to achieve
T4 285-295 335-345 355-370 205-215
complete plastication of the melt before injection
TN 290-300 335-345 335-370 200-210
starts. Typical speeds are 100 to 200 rpm at a screw
TM 285-295 335-345 360-370 200-210
diameter of 15 to 25 mm.
TW1 80-120 80-120 80-120 –
TW2 80-120 80-120 80-120 –
nS – see screw speed, Section 6.2.4

TD – see drying instructions, Section 5.2
43
Vectra®
6.2.5 Back pressure changes approximately with the square of the thick-
ness. This also has an impact on the total cycle time.
Back pressure is not normally necessary during
plastication and should be set to a minimum (5 to 15 6.3 Regrind
bar spec.). With fiber reinforced grades, excessive back
pressure leads to fiber breakage as well as overheating The regrinding processes for Vectra are similar to
of material. those for other high-modulus thermoplastics. Liquid
crystal polymers are tough, fibrous materials that
6.2.6 Screw decompression require some care in handling to produce high regrind
quality.
Screw decompression is not generally recommended.
If screw decompression is necessary to prevent Several variables will affect regrind quality. These
drooling, it should be restricted to a minimum include the particular grade of Vectra being processed,
(2 to 4 mm). Excessive decompression can draw air the type of filler or reinforcement, the geometry of
or moisture into the nozzle and result in a cold slug the part and/or runner, the type of machine and the
or blistering on the surface of the molded part. reprocessing technology used.
6.2.7 Injection pressure The processor must determine the upper limit for
regrind addition on a case by case basis by evaluating
The optimum injection pressure depends on the part performance, regulatory limits and molding
specific Vectra grade as well on the design of the process stability.
molded part, the mold and machine conditions. All
Vectra grades have low melt viscosity and generally 6.3.1 General recommendations
require lower injection pressures than other thermo-
plastic materials. 1. Runners, sprues and reject parts will cut best when
fed to the granulator while still hot, i.e. just out of
6.2.8 Holding pressure the mold. Granulating while hot will produce the
smoothest chip edges and generate the least amount
The holding pressure can be equal to or less than of tails and fines. If this is not practical, the scrap
the injection pressure. The required holding pressure may be reheated in an oven to approximately 150°C
times are shorter than for semi-crystalline thermoplas- and then cut while hot. When grinding, take care to
tics since Vectra freezes very quickly. The required feed the parts into the granulator slowly. This will
holding pressure time can be determined by part minimize residence time in the granulator, so im-
weight consistency. proving cutting quality (otherwise the scrap tends
to be crushed rather than cut).
6.2.9 Cycle time
2. In order to avoid feeding and screw recovery issues
In addition to low viscosity, all Vectra grades have the particle size of regrind should be as close as
a very low heat of fusion (about 5 to 10% of the heat possible to the virgin pellets with smooth chip
of fusion of PET or PBT). This means that relatively edges.
little heat has to be removed from the molded part
through the walls of the mold to freeze the part. 3. Sharp blades improve regrind quality and will cut
Ejection can take place at high temperatures if the rather than shatter the scrap.
ejectors are designed not to make an indentation in
the molding. The extremely low internal stresses 4. Close tolerance gaps between blade and bed knife
occurring with Vectra make it possible to operate the improve regrind quality. Set to the closest gap
injection mold at relatively low temperatures. These recommended by the granulator manufacturer.
characteristics lead to exceptionally fast cycle times.
As the wall thickness is changed, the cooling time
44
Vectra®
If the above procedures are not successful, it may be In Europe, the machines can be purchased from
necessary to reduce the speed. Machines that operate
at or below 30 rpm tend to improve chip quality by Scholz Apparate & Anlagenbau GmbH
shear cutting the larger oversized granules during In der Hernau 5
regrinding rather than smashing or shredding them. D-90518 Altdorf
High speed granulators tend to shatter the scrap Germany
rather than shearing it – especially when it is cold (less Tel: ++49 (0) 9187-4037
than 100°C). This results in rough-edged, fibrous
Vectra regrind with a high level of fines. 6.3.3 Using regrind
The following table indicates the approximate per- Four factors have the potential to cause loss of
centage by weight of fines and chip quality obtained properties in regrind material: contamination, thermal
in a test. Naturally, results will vary according to the decomposition, hydrolysis (reaction with water) and
equipment used and processing parameters. Fines are damage to reinforcing material, especially glass fibers.
particles that pass through a 10-mesh screen (10 aper- Vectra plastics have excellent thermal and hydrolytic
tures/inch2). Excessive fines and poor chip quality stability when molded and dried under the recom-
may cause difficulty in feeding regrind into an injec- mended conditions. Glass fiber reinforced products
tion molding machine. may exhibit some loss of notched Izod impact strength
due to breakup of the glass fibers.
Cut Hot Cut Cold
To maintain color uniformity and optimum mechani-
Low Speed Granulator Fines, weight % 5 13
Chip Quality Good Fair
cal properties, limit regrind addition to 25%. Under-
writers Laboratories accepts up to 25% regrind for
High Speed Granulator Fines, weight % 5 17 UL listed applications without further testing.
Chip Quality Fair Poor
In certain cases, 50% regrind addition is possible. 6

6.3.2 Equipment Some of these grades are listed by UL as being
approved for use with a 50% regrind ratio (and even
A number of users have reported success using an 75% in the case of Vectra E150i).
S-Cutter from Usni Tech LLC for regrinding Vectra
runners, sprues and reject parts. Whenever using regrind material, the end user must
test the finished parts to ensure satisfactory perfor-
Contact address of Usni Tech LLC: mance. Best practice for using regrind includes:
818 Terminal Rd
Lansing, MI 48906, USA 1. Adequately dry both the regrind and virgin plastic,
Tel: ++1/517-332-7400 preferably to less than 0.01% moisture. Refer to
or: www.usnitech.com section 5.2 for recommended drying procedures.
2. Regrind material must be free from contamination

and any foreign material, including other plastics,
metal, and even other liquid crystal polymers.
3. Avoid excessive melt temperatures.
4. The melt residence time in the barrel should be as

short as possible, preferably between 3 and 5 min.
45
Vectra®
5. Do not use screw decompression. Adjustments should be moderate and made a step at
a time, giving the machine time to stabilize before
6. Dust should be avoided as much as possible. further adjustments are made. Check that the machine
In addition, the material should preferably be is operating within the parameters recommended
reground immediately after injection molding, for the specific Vectra grade. For example, melt tem-
while still hot. perature should be checked on air shots collected at
specified intervals when the process is stabilized.
7. Refer to section 6.2 for recommended injection
molding conditions. 6.4.1 Brittleness
When molded using the recommended conditions, – Check for contamination

Vectra maintains about 80-100% of its strength and – Decrease amount of regrind in the feed
modulus. Glass fiber reinforced grades may exhibit a – Decrease back pressure
reduction in notched Izod impact due to fiber break- – Decrease melt temperature by
age during processing. After repeated molding of the • Decreasing screw speed
same material, a slight discoloration has been • Decreasing the barrel temperature
observed. – Dry the plastic and regrind before use
Whenever regrind is used, and especially with regrind 6.4.2 Burn marks
ratios higher than 25%, the following guidelines should
be observed: Vectra materials are highly oriented and may have a
slightly dark discoloration in the gate region.
1. Run parts for quality testing under steady state con-
ditions. Continue production with a constant feed – Check the material for contaminants
of regrind material at the desired ratio for several – Decrease injection rate
hours to establish the distribution of residence time. – Improve venting to minimize trapped gas
– If necessary, relocate gate to improve venting
2. Qualify the regrind-containing parts,by using the
same test methods as for parts produced from 6.4.3 Dimensional variation
virgin material.
– Confirm complete screw recovery in allotted time
3. Adhere to any applicable regulatory requirements. – Confirm that check ring seats uniformly
– Maintain a 3 to 5 mm melt cushion
6.4 Troubleshooting – Fill the mold as rapidly as possible
– Increase cooling time
Many processing problems are caused by easily cor- – Check the machine’s hydraulic and electrical
rected conditions such as inadequate drying, incorrect systems for erratic performance
temperatures or pressures, etc. Often solutions can be – Reduce the number of cavities in the mold
found by following the recommendations given – Balance the layout of runners, gates and cavity
below. – Improve venting
– Increase injection pressure
46
Vectra®
6.4.4 Discoloration 6.4.6 Jetting
– Check for contamination of plastic feed Vectra polymers are highly oriented, exhibit little or
– Purge heating barrel no die swell and tend to jet into large cavities.
– Decrease melt temperature by
• Decreasing the screw speed – Adjust gate location so melt impinges on core,
• Decreasing the barrel temperature pin or wall
– Minimize residence time and cycle time – Decrease injection rate
– Improve venting in the mold – Increase gate dimensions to 85 to 100% of wall
– Reduce residence time, if necessary by changing to a thickness
smaller injection molding machine
6.4.7 Leaking check ring
6.4.5 Flashing
– Ensure check ring is sealing properly
Although Vectra has very good flowability in molding – Ensure check ring retains constant melt cushion
thin-walled parts, the material has no tendency to of 3 to 5 mm
flash, provided that the venting recommendations are
correctly followed (see section 9.2.7). 6.4.8 Nozzle problems
The reason for this is Vectra’s low enthalpy, which A. Nozzle drool or stringing
guarantees immediate freezing of the polymer melt on – Decrease nozzle temperature
the mold wall or in venting channels. – Decrease melt temperature by
• Decreasing the screw speed
– Decrease injection pressure • Decreasing the barrel and or nozzle temperature
– Ensure that a 3 to 5 mm melt cushion is maintained – Add minimal decompression (too much can cause
– Reduce shot size blisters on reheating molded parts) 6
– Decrease injection rate – Dry the material thoroughly
– Decrease melt temperature by – Use a nozzle with a smaller orifice
• Decreasing the screw speed – Use a nozzle with a nylon type reverse taper
• Decreasing the barrel temperature – Use a nozzle with a positive shut-off
– Check mold closure for mismatch of parting line – Increase cure time
– Improve mold venting
– Check mold for parallelism B. Nozzle freeze-off
– Move mold to a larger clamp tonnage press – Increase nozzle temperature
– Decrease cycle time
– Increase mold temperature
– Add sprue break (carriage back) if necessary
– Use a nozzle with a larger orifice and beryllium tip
47
Vectra®
6.4.9 Short shots 6.4.11 Sticking
– Check hopper to confirm adequate feed A. Sticking in cavity

– Ensure check ring is seated – Decrease injection pressure
– Ensure melt cushion is consistent – Decrease injection rate
– Increase shot size – Reduce holding pressure
- Increase injection pressure moderately – Eliminate undercuts; increase draft
– Increase injection speed – Check part for drag marks or unbalanced ejection
– Increase mold temperature – Polish tool in ejection direction
– Increase barrel temperature – Improve effectiveness and balance of pullers and
– Check cavity vents for blockage sucker pins
– Decrease size of gate (possibly runner) to increase
shear B. Sticking on the core
– Measure core temperature, decrease temperature or
6.4.10 Sinks and voids improve cooling
– Eliminate undercuts
Vectra has very low shrinkage values and is therefore – Polish cores in the ejection direction
rarely prone to sinks or voids. If these occur, they are – Increase drafts
most often an indication of short shots.
C. Sticking in the sprue bushing
– Ensure check ring is properly seated – Check the alignment and orifice size of the nozzle
– Ensure screw recovery is consistent relative to the sprue bushing
– Ensure clearance between screw and barrel is not – Decrease holding pressure
excessive – Decrease injection pressure
– Increase shot size to ensure 3 to 5 mm melt cushion – Eliminate undercuts and polish surfaces of sprue
– Increase injection pressure bushing
– Increase mold temperature – Provide a more effective sprue puller
– Increase melt temperature
– Check cavity vents for blockage 6.4.12 Surface marks and streaks
– Relocate gates to thicker-walled sections
– Core out the part Vectra is highly oriented and often exhibits flow lines.
– Increase holding pressure time
– Increase holding pressure – Decrease melt temperature by
– Reduce gate size to increase shear and viscosity • Decreasing the screw speed
• Decreasing the barrel temperature
– Check for contamination
– Dry material before molding
– Reduce screw decompression
– Decrease melt residence time by
• Decreasing overall cycle time
• Moving tool to a smaller-capacity press
48
Vectra®
6.4.13 Warpage and part distortion 6.4.14 Weld lines
Vectra products are highly oriented and shrink much – Eliminate mold release agent
less in the flow direction than in the direction trans- – Increase injection rate
verse to flow. Consistent and uniform melt flow is – Increase injection pressure
required to control shrinkage as much as possible. – Increase mold temperature
Most warpage is due to the flow patterns, dictated – Increase melt temperature
by part and gate design. For this reason, the risk of – Vent cavity in weld line area
warpage is considerably greater in parts with sharp – Provide overflow well adjacent to weld line area
cross sectional transitions than in parts with uniform – Use single gate
wall thicknesses. Except for mold temperature, – Improve flow pattern by
processing conditions have little effect on shrinkage • Relocating gate
differential. • Ensuring wall thickness is uniform
• Adjusting wall thickness variations to direct the
– Relocate gate or adjust wall thickness to improve fill melt flow
pattern
– Confirm that the part ejects uniformly
– Check for proper handling and immediate degating
of parts after ejection
– Decrease mold temperature
– Increase post-cooling time
– Ensure that the part is properly packed by
• Increasing the injection pressure, injection rate
49
Vectra®
7. Extrusion
A number of unreinforced Vectra LCPs can be used 7.1 Machine requirements
for extrusion of rods, profiles, films, sheets, pipes and
fibers. In addition, one grade of unreinforced Vectra 7.1.1 General
permits coextrusion with standard packaging materials.
This offers packaging producers a cost-effective way Vectra should be extruded with a relatively cool feed
of exploiting the excellent gas barrier properties and zone. A barrel L/D ratio of 24:1 to 30:1 is recom-
chemical resistance of LCPs. As a result of their mended to ensure complete and uniform melting of
molecular structure, LCP extrudates generally have the polymer. A vacuum vented extruder barrel is
highly anisotropic properties. This can be improved helpful in eliminating volatiles in the extrudate.
by suitable processing techniques. For example,
blown film technology can be utililzed to reduce the 7.1.2 Screw design
anisotropy of LCP films. Unfilled Vectra grades must
normally be used for this purpose. With blown films The melt viscosity of Vectra is highly dependent on
up to about 100 µm thickness, similar physical prop- shear stress. Therefore select a metering screw with
erties in the machine and transverse directions can be deep flights in the feed zone and a uniform pitch.
obtained by adjusting the draw ratio in the machine A compression ratio of 2:1 to 5:1 for a single stage
direction and the blow-up ratio in the transverse screw or the first stage of a two-stage screw is
direction. The tensile modulus can range between preferred. For the second stage of a vented screw,
20,000 MPa/3,500 MPa (in the machine direction/ the compression ratio should be 2:1 to 3:1. The length
transverse direction) for an anisotropic cast film to of the feed section and the metering section should
7,000 MPa/7,000 MPa for a blown film. This capabil- be at least five times screw diameter with a gradual
ity could be important in, for example, the electronics transition between them.
industry, where precise dimensional characteristics,
including low shrinkage and a controllable linear 7.1.3 Screen pack
thermal expansion coefficient, are required.
Since Vectra is often processed close to the melt
Mineral and fiber reinforced Vectra grades can also be temperature, efficient screen pack heaters and good
used for extrusion as long as the die cross section is insulation are essential to prevent polymer freeze-up.
large enough to accommodate the filler. Filled resins A fine-mesh screen (down to 100 mesh apertures/
are recommended for thermoformed sheet and inch2) can be used for filtering the extrudate without
extruded products that are to be machined. Fillers can causing excessive pressure build up. A screen filter
also improve thermal and wear characteristics. should not be used when extruding filled polymer.
Be sure to follow the drying procedures outlined in 7.1.4 Head and die
section 5.2 before processing Vectra.
Standard dies are generally appropriate for Vectra
extrusion but, particularly in coextrusion, the low
viscosity of Vectra should be taken into account by
designing narrow flow channels. Uniform tempera-
ture distribution over the entire head and die area
must be ensured by a suitable temperature control
system. The melt pressure should also be as uniform
as possible, and the screen pack replaced when the
pressure starts to increase significantly.
50
Vectra®
7.1.5 Melt pump Film up to 0.25 mm thickness can be cast on a single

roll or extruded onto a three-roll stack. Thicker sheet
Because Vectra is a shear thinning material, it tends may require a straight through string up. Finishing
to flow back over the screw flights more than con- rolls should be heated, if possible, to provide a con-
ventional polymers. This can result in reduced screw trolled uniform cooling rate and to produce a high
pumping efficiency at high extruder discharge pres- quality film surface. Since Vectra films neck in less at
sure. A melt pump is therefore recommended for the edges that other plastics, the required width of
high extrusion rates or whenever a filter (cartridge or the finishing rolls for a given die size may be greater
screen changer) is used. The melt pump should be than expected based on previous experience. Film less
placed directly downstream of the extruder. than 0.25 mm thick may be wound on a spool, while
thicker film generally must be cut into lengths.
7.2 Processing
7.2.2 Profiles
Safety precautions and startup/shutdown procedures
for extrusion are very similar to those outlined for Monofilament strands, rods and other profiles can
injection molding in section 5.1. Drying and storage be extruded from unfilled Vectra plastics, preferably
of material are described in section 5.2. Vectra A950. High molecular orientation developed
during extrusion gives these products exceptional
7.2.1 Film and sheet tensile strength and stiffness in the machine direction.
Due to their high melt strength, both products can be
Extrusion of film and sheet can be carried out with extruded either horizontally or vertically. A die melt
either unfilled or filled Vectra polymers. Thermo- temperature of approximately 280°C to 285°C is
forming operations generally require a glass or mineral suggested for Vectra A950. Keep the die pressure
filled grade, which can be used to extrude thicker-gage above 0.7 MPa to maintain a consistent, densely
sheet. packed product.
Film and sheet are often extruded close to the melting Unlike many other engineering thermoplastics, Vectra
point so care should be taken to prevent polymer products exhibit very little die swell or distortion upon
freeze-up in the screen pack and die, especially at exiting the die. With the proper die design, minimal
startup. Thermally insulating these components is drawdown is required to achieve high mechanical
helpful. Extrusion temperatures can be carefully strength. A drawdown ratio of 4 to 7 (ratio of die 7
lowered from the recommended values for thicker orifice area to cross sectional area of extrudate)
sheet (greater than 0.25 mm) if necessary to maintain is recommended for best results.
melt strength.
The entry to the die orifice should be streamlined and
The distance from the die to the finishing roll nip free of stagnation points so that polymer does not
should generally be kept as short as possible to avoid hang up and degrade. Conical entry dies with a 30 to
premature freezing of the molten extrudate. A draw- 70° cone entry angle are recommended for extrusion
down ratio (ratio of the die gap to film thickness) of of circular cross sections. A die with no land length is
2.0 is recommended for thin film (less than 0.25 mm), preferred but a short land length is acceptable. Keep
and a drawdown ratio of 1.1 to 1.2 should be used for the die land length to no more than 4 times the orifice
thicker film and sheet. diameter. A longer length will cause excessive shear
deformation and reduction of tensile properties.
Standard center feed dies can be used to extrude film A conical die mandrel is generally used with its tip
and sheet. A large manifold is recommended to centered upstream from the orifice entry.
distribute the melt evenly across the die. The die gap
setting should be adjustable to help regulate the die
pressure and achieve the desired drawdown ratio.
51
Vectra®
Cooling and sizing of the extruded profile depends Sizing rings should be about 0.25 mm greater in
on the cross sectional area. Air-cooling is adequate diameter than the product. A protruding mandrel is
for thin strands up to 0.15 mm diameter. A sizing required for effective sizing of the inside tube dia-
guide should be used for any diameter greater than meter.
3 mm.
A drawdown ratio (the ratio of the die flow annulus
Larger diameters and shapes should generally be divided by the cross sectional area of the extruded
water-cooled. Water baths should be temperature tube) of 1.2 to 2.0 is recommended for tubing.
controlled and held at 45°C for small diameter pro-
files (for example, 2 mm diameter rod running at 7.2.4 Coating
30 m/minute line speed). A short (approximately
one meter) bath length is generally sufficient. The Vectra A950 is suitable for coating both conventional
distance between the die face and the water bath and fiber-optic cables. In fiber-optic cables, it protects
normally ranges from less than 1 meter to 3 meters and also strengthens the glass fibers. The coated pro-
and may be adjusted to achieve the most circular ducts have very low thermal conductivity, moisture
cross section possible for the extruded monofilament. and gas permeability, water absorption and thermal
expansion.
Due to the stiffness of the extrudate, there should be
no sharp bends in the line. Roll and take up spool Use a crosshead die with a converging nozzle for
diameters should be no less than 200 times the dia- extrusion. A convergence ratio (ratio of the flow area
meter of the extruded rod. cross section before and after convergence) of 10 to
20 is required to induce molecular orientation for
7.2.3 Pipe and tubing good mechanical properties. The die land length
should be about 6 mm or less to avoid excessive heat
A wide range of pipe and tubing diameters and thick- transfer to the glass fiber buffer coating.
nesses can be extruded using Vectra LCPs. A melt
pump between the extruder and the die provides a The cooling water trough should be maintained at
smoother, uniform extrudate and minimizes surging. between 25°C and 45°C to prevent over-rapid cooling
It is recommended that extrusion melt temperatures of the coated fiber. Keep a distance of 15 to 20 cm
be as low as possible to improve melt strength and between the die face and the cooling water. Rolls
increase production rates. need to be placed so that the coated fiber is never
bent around a radius less than 100 times the coated
Small diameter tubes (up to about 2 mm) can be fiber diameter.
extruded directly into a cooling trough, while sizing
is required for larger diameters. Where uniform con- The coated fiber can be further oriented by draw-
trol of diameter and roundness are critical, a vacuum down after exiting the die, which helps increase ten-
water-sizing bath is preferred. If a spider die design is sile properties. The recommended drawdown ratio is
used, the legs should be as far from the die outlet as defined as:
possible to allow a molten extrudate to rejoin and
form a homogenous melt. The spider should be care- Drawdown ratio = (A2-B2)/(C2-D2)
fully centered to maintain a uniform wall thickness.
A die land length of two or more times the tube dia- A = outside diameter of the die nozzle flow annulus
meter is ideal. Sizing rings may be used to control B = inside diameter of the die nozzle flow annulus
outside diameter uniformity and smooth the outside C = diameter of the coated product
surface of the pipe or tube. D = diameter of the wire or fiber
52
Vectra®
7.3 Troubleshooting 7.3.2 Pipe and tubing
As with the injection molding troubleshooting guide Bowing of pipe or tubing

(section 6.4), many processing problems are caused
by easily corrected conditions, such as inadequate – Uneven cooling; make sure extrudate is completely
resin drying, incorrect temperatures, etc. Try the submerged in cooling water
recommended solutions given below in the order in – Check for wall thickness variation
which they are listed under each problem category. – Check alignment of extrusion and sizing dies
7.3.1 General extrusion Poor surface only on inner wall
Extrudate cross section varies with time – Check for material buildup on die mandrel
– Adjust length of mandrel
– Check line speed uniformity
– Check for extruder surging; reduce feed zone Wall thickness variation
temperature to restore even flow
– Excessive drawdown; adjust die dimensions – Center the die mandrel
– Install melt pump to stabilize flow rate
7.3.3 Profiles
Extrudate has excessive voids
Extrudate has distorted cross section
– If gassing appears to be a problem, reduce melt
temperature or use vacuum vented extruder – Adjust melt temperature either higher or lower
– If melt pressure is less than 0.7 MPa, increase screw – Adjust die to water bath distance
rpm, adjust die size, or use finer filter in screen – Adjust drawdown ratio
pack (for unfilled plastics) to increase melt pressure – Sizing may be required
Poor surface appearance Strand breaks in extrudate
– Dry plastic more thoroughly – Dry resin more thoroughly

– If gassing appears to be a problem, reduce melt – Raise melt temperature incrementally 7
temperature or use vacuum vented extruder – Reduce drawdown ratio if there is a periodic
– If striations occur, raise melt temperature in 2°C to variation in cross section
3°C increments
7.3.4 Film and sheet
Striations on extrudate in machine direction
Large, uniformly spaced perforations in film
– Check die for nicks
– Check all equipment surfaces for contamination or – Reduce melt temperature
degraded resin – Decrease die gap to reduce drawdown
– Reduce die temperature
53
Vectra®
Sagging extrudate 7.3.5 Coating
– Lower melt temperature Breaks in optical fiber
Uneven or distorted edges – Make sure polymer and optical fiber are thoroughly
dried
– Polymer freezes up on die edges; clean die and raise – Check for contamination in fiber guide
melt temperature – Adjust tension at the unwind stand and die entrance
Out of round cross section
– Reduce melt temperature

– Center die tip nozzle
– Adjust die to water bath distance
– Adjust water bath temperature
54
Vectra®
8. Design
In most cases, designers and molders choose Vectra and deflection. If the stress or deflection is too high,
for its excellent dimensional stability, mechanical the following alternatives should be considered:
properties, very good flow in thin walls and wide
processing window. Part design is the key considera- a) Use ribs or other suitable contours to increase the
tion in optimizing both processing latitude and part moment of inertia
performance. In general, all the standard recommen- b) Use a Vectra grade with higher strength
dations for good design of plastic parts are applicable c) Increase the thickness of the wall section if it has
when designing Vectra components. For instance, not already reached the limit.
parts should be designed and molds constructed to
provide smooth, uniform flow of the polymer melt. Plastic parts are good insulators for electrical and
In addition, the part design must control the poly- heat energy. They can also serve as filters for sound,
mer’s anisotropic properties – a fact that presents vibrations and light. In general, insulating ability is
both opportunities and challenges. This is because, directly related to the thickness of the plastic. In the
with Vectra,the direction of material flow in the mold case of sound transmission, the wall thickness of a
influences the mechanical properties of the molded plastic housing may need to be changed to avoid the
parts more than with other thermoplastics. There is resonance frequency.
therefore a close link between part design, perfor-
mance and end use requirements. The impact resistance of a particular part is directly
related to its ability to absorb mechanical energy
8.1.1 Part design without fracture or plastic deformation. This in turn
depends on the properties of the plastic and the
8.1.1 Wall thickness geometry of the part. Increasing wall thickness gener-
ally improves the impact resistance of the molded
Of all the issues in plastic design, selecting the proper part. However, increased wall thickness could also
nominal wall thickness is probably the most impor- negatively affect impact resistance by making the part
tant. Choosing the proper wall sections sometimes overly stiff, unable to deflect and distribute the
determines the ultimate success or failure of a product. impact. Both types of impact energy absorption
While an inadequate wall section can lead to poor should be tested when deciding on nominal wall
performance or structural failure, a section that is thickness.
too thick, even just in certain regions, can make the
product unattractive, overweight or too expensive. 7
Although some problems can be corrected after the Fig. 8.1.1 · Spiral Flow Lengths
mold is built, such solutions are often expensive. (Injection pressure: 195 bar hydraulic/1000 bar
specific, Mold temperature: 100°C)
The vast majority of injection molded plastic parts
have wall thicknesses in the range of 1 mm to 5 mm.
800
8
2 mm Thickness
700
Because of the low viscosity and easy flow of Vectra, 0.8 mm Thickness
typical wall thicknesses are in the range of 0.3 mm to 600
1 mm. Thickness within this range is generally related
500
Length (mm)
to the part size. This does not mean that parts cannot
be molded thinner or thicker, or that a large part can- 400
not be thin or a small part thick.
300
However, these norms should act as a starting point 200
for the design. 100
If a part is subjected to any significant loading, the 0

B230 A130 A435 FDA E130i
load-bearing areas should be analyzed for stress
55
Vectra®
8.1.2 Flow length 8.1.4 Draft angle
The spiral flow length values for the melt are deter- Vectra LCPs exhibit very low shrinkage and unusually
mined in the spiral flow test, which very closely high stiffness. Consequently, they typically eject easily
simulates actual injection molding conditions. In Fig. from most cores. If necessary, parts can be ejected
9.1.1, the spiral flow lengths of selected Vectra grades from molds with well-polished cores without any
under typical injection molding conditions are shown draft. Even so, molding parts without a draft should
for two different wall thicknesses. The spiral flow be considered only when there are no alternate
lengths vary according to factors such as gate cross options. A draft angle of 0.1 to 0.25 degree per side is
section, mold or melt temperature and, especially, suggested. Larger draft angles provide easier ejection.
injection rate. So the quoted values provide only a Parts with undercuts cannot generally be ejected
relative indication of the flow lengths that can be because of Vectra’s high stiffness. However, slight
expected from the different polymers in the mold. undercuts or roughened surfaces can be used to assist
In planning the design of a part, therefore, the infor- adhesion to the desired mold half (= ejector half) and
mation given in Section 8 Rheology should also be so help control ejection.
taken into consideration.
8.1.5 Warpage
8.1.3 Shrinkage
Controlled, uniformly flowing melt fronts are crucial
The change in volume of Vectra on solidifying from to preventing warpage. Wall sections should be as
the melt is considerably less than that of conventional uniform as possible, since parts are subject to warping
thermoplastics on account of its liquid crystalline if there is, for example, a thick wall on one side and
structure. Shrinkage of Vectra depends mainly on a thin one opposite. Warpage can be restricted to a
orientation and therefore on the flow paths in the minimum, if parts are designed so that the polymer
mold determined by part design, wall thickness and melt can flow evenly and continuously in a longitudi-
gate location. Shrinkage in the flow direction can nal path from one end of the mold to the other with-
even be virtually zero (see enclosed product informa- out forming weld lines.
tion and data sheets). Shrinkage anisotropy is greatest
with unfilled polymers and – unlike with other ther- The difference between mold shrinkage in the flow
moplastics – can be reduced by the use of fillers. and transverse directions is roughly comparable to
The effects of melt and mold temperature, injection that for other 30% glass fiber reinforced semi-crys-
pressure and injection rate on shrinkage are negligible talline plastics such as PBT. The differential shrinkage
relative to other engineering plastics. can be eliminated or greatly reduced by relocating the
gate and by suitable design of the part. With com-
Because of the low shrinkage, polished molds are rec- plicated moldings, it is extremely difficult to predict
ommended to avoid ejection problems. If necessary, a shrinkage exactly since the flow behavior of the melt
suitable draft (see section 8.1.4) should be provided to and subsequent orientation is difficult to foresee.
assist removal from the mold. The low shrinkage of
Vectra coupled with its low coefficient of thermal ex-
pansion (section 3.2.3) offers the advantage of very high
manufacturing precision and very close tolerances
(tolerance class IT6). This makes it possible to achieve
high reproducibility of the part dimensions, which
can be a crucial advantage for automatic assembly of
components leading to a considerable reduction in
manufacturing costs.
56
Vectra®
8.1.6 Weld lines has formed. Strength increases correspondingly with

increasing distance from the obstacle. Because of the
Weld lines are weak points in any molding made higher melt temperature, weld lines that are formed at
from reinforced plastics. In injection molding liquid the beginning of the filling process are stronger than
crystal polymers, not only any fibrous reinforcing those at the end of the flow path. This factor should
materials present but also the molecular chains them- be taken into account in selecting the gate position.
selves are oriented largely parallel to the weld line.
The reinforcement is therefore interrupted in the A molding without weld lines has the highest design
region of the weld line. Hence, great attention must strength. If weld lines are unavoidable, they should
be given to the weld lines. be sited in regions of low stress through suitable
location of the gate. If possible, butt welds should be
Butt welds, in which the melt fronts meet and remain avoided. Long weld lines after an obstacle are prefer-
in a plane perpendicular to the flow direction, are able to short weld lines. It has proved an advantage to
often particularly critical (see Fig. 8.1.2 top). The create swirling in the weld line by providing a flow
strength of a test specimen produced in this way can obstacle such as a rib or coring.
be reduced by up to 90%. Such a weld line frequently
also leads to a visible surface mark. Another way to improve the strength of weld lines is
to create an overflow well or tab. The melt can then
Moldings with weld lines formed after the melt has flow from the end of the weld line into the overflow.
flowed around an obstacle (core) retain 50 to 60% of The overflow is then trimmed off the molded part.
the transverse strength of parts without a weld line
(see Figure 8.1.2 bottom). The melt stream is divided 8.1.7 Ribs, corners, radii
into two at the obstacle and when the two streams
reunite, welding is impaired by the rapid cooling of The provision of ribs on molding walls is one possible
the melt. When two melt streams meet directly behind means of increasing design strength and at the same
the core at an obtuse angle, similarly low strength time avoiding material accumulation due to excessive
results as with a butt weld line. With growing dis- wall thickness. However, ribs influence melt flow in
tance from the obstacle, the two melt streams meet at the mold and can cause undesirable weld lines or
an increasingly acute angle until a parallel flow front possibly warpage. If the flow direction of the melt
coincides with the longitudinal axis of the ribs, the
thickness of the ribs should be as near as possible to
Fig. 8.1.2 · Weld Lines the thickness of the adjacent wall (80 to 100%).
The melt then flows in the same direction through
butt weld line the rib and wall. If the rib is thinner, there is a ten-
dency for the melt to first rush through the wall and
then flow in the transverse direction into the rib. This
8
would set up different directions of orientation and
lead to warpage. Any bosses should have the same
wall thickness as the ribs.
Rib connections to adjacent walls should be radiused.

Radii of 0.1 to 0.2 times the thickness of the adjacent
wall are recommended to reduce notch effects. Larger
2 radii cause the melt to rush into the rib connection
strength
possibly resulting in undesirable weld lines or “back

weld line after filling” of the molded part.
1 the melt has
flowed round
an obstacle
and strength
curve
(qualitative)
57
Vectra®
Transitions, corners and molding edges should have maintaining retention. Other techniques such as the
generous radii, provided this does not result in dis- use of barbs or splines on metal pins that are inserted
advantages for uniform mold filling (rushing of the into the plastic can create interference and provide
melt, weld lines). For outside radii, 1.5 times the wall effective holding forces.
thickness is recommended; for inside radii 0.5 times
wall thickness. 8.2 Mold design
8.1.8 Holes and depressions The quality of a molded part is essentially determined
by the following factors:
Holes and depressions or thinner areas are particularly
critical design issues because of the need to carefully - Properties of the molding material
consider the impact of weld lines on the integrity of - Design of the molded part
the molded Vectra part. Typically, to optimize the - Processing of the material
strength of a molded-in hole the minimum distance
between the edge of the hole and the edge of the part By optimizing all these factors, a high quality molded
should be at least twice the hole diameter or at least part can be produced. The design of the mold and
twice the nominal part wall thickness. Generally molded part are particularly important in processing
speaking, the greater the distance, the stronger the LCP. Just the location and design of the gate have a
part. A weld line can be critical if a snap-fit or press- significant influence on the achievable quality of the
fit pin is to be inserted into the hole.The stress at the part. For this reason, close cooperation between the
hole may cause a weak weld line to fail. Similar rules raw material manufacturer, designer, processor and
hold for depressions, since they can also cause a customer right from the start of the project is very
downstream weld line. The design situation is less desirable.
critical, since there is generally no external stress
imposed on a depression. If the part design is con- Processing is determined both by the set injection
strained to smaller than recommended dimensions molding parameters and the design of the machine
between the hole and edge of the part, the weld line and mold. Modern simulation methods are available
may be strengthened by placing an asymmetrical to assist in the mechanical, thermal and rheological
“overflow” gate and well in the vicinity of the weld design of a mold.
line. This can dramatically strengthen a weld line.
It is often possible to assess whether a molded part
8.1.9 Snap-fits and press-fits will meet requirements, by applying the principles
of materials science. Trials under closely simulated
Snap-fit joints designed in Vectra should be tapered service conditions should be carried out to confirm
(typically a 2:1 taper) to provide a more uniform practical suitability for the application.
stress distribution along the length of the beam. This
design technique will limit the stress concentration at 8.2.1 Mold material
the base of the snap-fit. Additional deflection can also
be achieved using this tapered beam approach. The selection of steels for the mold can be critical to
its successful performance. Just as plastics are formu-
Press fits depend on the interference of the compo- lated to satisfy processing and performance require-
nents to hold the assembly together. With low elon- ments, steels are alloyed to meet the specific needs
gation, high modulus materials such as Vectra, if the for mold fabrication, processing and its intended use.
strain is too high, the material will fracture, losing There are many different parts to the mold, e.g. cavity,
the retention force designed to hold the components gates, vents, pins, cores, slides, etc., and these may
together. Except for very light press fits, this type of have different requirements. For example, some
assembly is not recommended due to the hoop stress applications may require a mold steel with high hard-
in the boss, which might already be weakened by ness to resist wear and abrasion at the parting line
a weld line. Designing an interference press fit by while another application may require toughness to
adding “crush ribs” to the inside diameter of the boss resist mechanical fatigue. Usually, steels with higher
or hole is a technique that can lower the stress while hardness and wear resistance properties tend to be
58
Vectra®
more brittle and steels with higher toughness will Table 8.2 lists some steels that could be considered
show less wear resistance. The selection process for for constructing injection molds.
the tool steels should include input from the tool To achieve satisfactory protection against wear, the
steel supplier, the mold designer and mold fabricator recommended hardness should be at least Rc ≥ 56,
in addition to the plastic supplier. Post-treatment of especially for processing highly filled grades.
the mold can be used to reduce the propensity for
wear. Inserts should be considered where wear may Recommended steels for Vectra LCPs are through
be a concern and long production runs are anticipated. hardening steels like S-7. As Vectra is not corrosive,
Table 8.2 · Partial Listing of Potential Mold Steels

Steel Type Hardness Properties Typical Applications Drawbacks
USA Germany
D-2 1.2379 60-62 Good hardness, good abrasion resistance Gate inserts and cavity areas of Brittle and somewhat difficult to
high wear from glass and fillers grind and assemble
A-8 56-58 Good adhesive wear resistance, Slides, lifters and cams Fair abrasion resistance
good toughness
A-6 56-58 Good heat treatment stability, General purpose, Moderate ductility
high hardness and compressive strength air hardened steel
A-2 1.2363 56-58 Air hardened steel, high abrasion Moderate ductility
resistance and good toughness
S-7 54-56 Very good mechanical fatigue resistance Fair adhesive and abrasive
and toughness wear resistance
O-1 1.2510 56-58 General purpose oil hardening steel Small inserts and cores Medium to low toughness
with moderate adhesive wear resistance
L-6 55-57 Very good toughness, oil hardening Medium hardness with medium
with good heat treatment stability to low wear resistance
P-5 55-57 Highly malleable Hobbing steel Case hardened. Low core hardness,
low durability and heat treatment
stability
P-6 55-57 Easily machined and welded Low heat treatment stability with
medium to low durability
P-20 1.2311 28-34 Pre-hardened steel, very tough, Large cavities Subject to galling and high wear
easy to machine Low hardness
H-13 1.2344 46-48 Air or vacuum hardened steel Low hardness

with very high toughness
SS 420 1.2083 46-50 Very good chemical resistance Low hardness, low mechanical fatigue
strength, low thermal conductivity
Specialty Steels 8
M-2 62-64 Extreme hardness, abrasive and adhesive Gate inserts, core pins, Difficult and costly to machine
wear resistance shut off and part lines and grind
Böhler "M 340” 56 Corrosion resistant
Böhler "K 190” 60-63 Corrosion resistant
Böhler "M 390” 56-62 Corrosion resistant and

highly dimensional stable
Zapp CPM T420V 57 Corrosion resistant, highly dimensional

stable and easily polishable
Zapp CPM 3V 53-63 Corrosion resistant, highly dimensional

stable and high toughness
Zapp CPM 9V 55-67 Highly dimensional stable Low corrosion resistance
WST “G25” 64-66 Corrosion resistant
Elmax1 56-58 Highly wear and corrosion resistant
Ferro-Titanit S2 66-70 Extremely high wear resistant and corrosion resistant
1 Trademark is registered by Bohler-Uddeholm Corp. 2 Trademark is registered by Thyssen Krupp Stahlunion GmbH
59
Vectra®
special corrosion-resistant steels are generally not When designing runner systems for Vectra, the high
required. If the melt is injected against a wall or core, impact of shear forces on melt viscosity has to be
this area will be subject to higher abrasion. In such taken into consideration. This applies to both hot and
areas, wear-resistant materials, such as hard metal cold runner systems. To create optimum filling condi-
alloys like D-2 or 1.2379, should be considered or tions, more shear has to be applied to Vectra than to
suitable surface treatment carried out. The mold other engineering plastics. Therefore, runners have to
surface should be smooth and polished to improve be generally smaller in diameter and should continu-
surface properties and facilitate ejection. The molds ously increase shear. This is best achieved by suitably
can be heated with water or oil. narrowing the runner cross section at each branch
point. The reductions in flow rate that result from
8.2.2 Mold finish
Fig. 8.2.1 · Typical Runner Design for Vectra® LCP
Mold finish plays an important role in determining
the ease of processing as well as molded part appear-
Ø 1.8-2.0 mm
ance. Vectra exhibits such low shrinkage that even
15-20 mm
modest undercuts can cause poor ejection. Even EDM
Ø 1.6-1.7 mm
(Electrical Discharge Machine) or erosion marks can
hold the part or imbalance the ejection stroke. There-
fore, the mold should be suitably polished. Deep or
poorly drafted pins, cores and cavities require special
attention. Fine polishing should occur in the axis of 15-20 mm
ejection (draw polishing).
Ø 1.6-1.7 mm
8.2.3 Runner systems
35-40 mm
All typical runner systems (hot runner, conventional Ø 0.9-1.0 mm
cold runner or hot-runner with cold sub-runner) can
be used for injection molding of Vectra . Both full 15 mm
round and full radius trapezoidal runners are accept-

able but full round runners are preferred. For multi-
cavity tools, the runner system must be balanced
and radiused carefully to avoid filling and ejection Ø 0.3-0.8 mm
problems.
Hot runner systems have proven especially suitable retaining the same runner diameter at branch points
for the production of small components because they have a negative impact on shear, viscosity and orien-
avoid a situation where the sprue and runners tation.
account for an excessively high proportion of shot
weight. There are now technically perfected hot run- Due to the liquid crystal structure of Vectra, melting
ner systems for processing LCP. It is important to and processing conditions have a great influence on
ensure that the amount of plastic in the hot runner flow behavior and orientation. A typical Vectra run-
is kept to a minimum. Since the residence time in the ner design is shown in Figure 8.2.1.
hot runner is additional to the residence time in the
machine, the volume of the hot runner should not ex-
ceed the equivalent of five shots. The total residence
time (machine plus hot runner) must be limited to
five up to a maximum of ten minutes.
60
Vectra®
8.2.4 Gate location 8.2.5 Gate design
Selecting the gate location requires consideration of Jetting is a phenomenon that results when plastic
polymer orientation, warpage, jetting and weld line flows through a gate and directly into a cavity with-
effects. As with all plastics, the gate location should out meeting an obstacle. It produces a rope-like melt
be chosen as far as possible to achieve unrestricted flow or “jet” which, in the case of LCP, immediately
and uniform mold filling. The gate location should freezes and is then surrounded by the subsequent
control the cavity flow pattern to provide optimum melt flow. Ideally, immediately at the gate, the poly-
mechanical properties in the axis of maximum stress. mer should form a swelling flow stream with a uni-
It should be noted that the viscosity of LCPs reacts form flow front that fills the cavity evenly. Vectra has
very sensitively to pressure gradients. The material very little die swell when exiting the gate and is there-
therefore always tries to fill moldings “from thick to fore more prone to jetting than many other thermo-
thin”, which can lead to uneven cavity filling if a gate plastics.
is positioned at a point of low wall thickness. It is
therefore advisable to position gates in the thickest With three-plate molds and submarine gates, a small-
part of the molding. However, gating directly into an er gate is more practical for a cleaner break. Because
open cavity can be problematic because it can lead to of the increased flow rate of Vectra in comparison
jetting. Jetting generally results in a weak point and with other thermoplastics, particular care must be
so reduces the quality of the molded part. To avoid taken in this case to direct the flow against a core or
jetting, gates should be positioned so that the melt cavity wall to prevent jetting and ensure that uniform
stream impacts directly on a rib, core or nearby wall. flow develops. Vectra moldings are stronger in the
flow direction and therefore gates should be located
Part shrinkage in the flow direction is smaller than on the ejector half of the mold to push rather than
in the transverse direction. The resultant shrinkage pull the sprues and runners from the mold. In three-
differential might cause warpage. When flatness is plate molds, sprue diameters should be between 20%
critical, locate the gate to minimize orientation and 50% of the wall thickness to ensure that the
(shrinkage) differences, i.e. balance them across the sprue breaks off easily. The corresponding gate diam-
part or relocate them to non-critical areas. Due to the eters should be between 0.3 and 0.8 mm. Experience
high flow of Vectra, single gates are generally suffi- with Vectra shows that narrower runners and gates
cient. Avoiding multiple gates minimizes weld lines. reduce viscosity because of the increased shear and
When multiple gates are unavoidable, locate the gate therefore enable the cavity to be filled more easily.
so that weld lines occur in areas with lower mecha-
nical loads and minimal strain. Note that knit weld 8.2.6 Gate types
lines are significantly stronger than butt weld lines
(Fig. 8.1.2). The gate should be located so that a knit As with gate location, it is important to select the gate
weld line is formed as early as possible during the type appropriate to the part geometry. Currently
8
filling process to ensure good welding of the flow used gate types are described below. For Vectra,
fronts. injection molders usually choose submarine gates.
Since these effects must be carefully balanced, it is

important to check the filling pattern when proofing
new or existing tools. Simply limit the shot size and
inspect a series of short shots taken throughout cavity
filling, i.e. from the moment the melt comes through
the gate to the point of final fill. In making new tools,
the gate area should be part of an insert to facilitate
changes or adjustments.
61
Vectra®
8.2.6.1 Submarine (tunnel) gates 8.2.6.2 Pin gates
Submarine gates (Figure 8.2.2) require careful sizing Pin gates are used for thin-walled moldings and easy
to balance the ejection difficulties of large gates with degating in most 3-plate tools. As with any small
jetting of small gates. gate, direct the polymer flow onto a core, rib or cavity
wall to control jetting. If this approach is impractical,
Furthermore, the drop from the runner must flex enlarge the gate to minimize jetting.
enough to clear the cutting edge as the tool opens.
Vectra is very stiff, so the gate design must maximize 8.2.6.3 Film (fan) gates
flexibility and minimize the deflection required
during ejection. The runner diameter should be small Film gates are recommended for flat parts. A suffi-
and the ejector placed close to the gate (see Fig. 8.2.2 ciently thick transverse runner in front of the film
length l1). ensures that the melt is distributed evenly across the
land before entering the cavity. This way a homo-
The converging angle of the cone should be relatively geneous filling process is guaranteed, orientations are
small (about 30°) and the drop angle from the runner in line and warpage minimized.
relatively steep (about 60°). Most importantly, the
submarine gate should extend into the ejector side of 8.2.6.4 Ring and diaphragm gates
the tool so the ejection stroke can positively separate
the runner from the part. For cylindrical parts, a uniform flow front is critical
to maintain concentricity, dimensional stability, part
The ejectors should be robust and close to the gate performance and appearance. A diaphragm or ring
because Vectra has very high tensile and shear gate provides the best gate designs to obtain the uni-
strength in the highly oriented gate drop. If the sub- form flow front. In both types, the gate land or mem-
marine gate extends into the stationary side, the run- brane should be significantly thinner in cross section
ner could split at the pullers rather than break at the (shallower) than the runner ring or central disk. This
gate. thickness differential forces the ring or disk to fill
completely before the melt fills the membrane.
Fig. 8.2.2 · Submarine Gate The choice of ring or diaphragm depends on part and
tooling features. With an internal ring or diaphragm
gate, the gate vestige is internal to the part. Depend-
ing on the tool layout, the core may not seat as solidly
as with an external ring. With an external ring gate,
the core can be solidly seated but the gate vestige is
l1
external.
Gating
d1 R 8.2.6.5 Overflow gates
d2
A very effective technique for strengthening welds is
to cut an overflow gate and well into the tool on the
weld line. Changing the flat weld line plane into a
d1 = 0.8 - 2 mm three-dimensional contour strengthens a normally
d2 = 0.3 - 0.8 mm
l1 = minimal very weak butt weld line considerably. This is done

= 30 - 35° by first filling the mold in the normal way. Then
= 30°
R = >2 mm during the packing step, a small amount of melt flows
No sharp corners through the weld line plane into the overflow well.
To create a successful overflow design, the mold must
62
Vectra®
be completed, the part dimensions correct and the 8.2.8 Ejection

mold ready for final polishing. In other words, there
must be no further changes in the metal contours. Molded parts are generally ejected by ejector pins or
ejector blades. These are round or rectangular shaped
The key to a successful design is to position the over- pins located in suitable areas of the mold for part
flow gate just slightly off the weld line and vent as ejection.The main purpose of the blade ejector is for
deeply as possible. Weld lines are located on the part the ejection of very slender parts, such as ribs and
and the overflow gate can then be positioned about other projections, which cannot satisfactorily be
1.5 to 2.5 nominal wall thicknesses away from the ejected by standard types of ejector pins. The loca-
weld line location. A submarine or tab gate can be tion and number of the ejector pin/blade elements are
used; however, it must have a small enough area to dependent on the component’s size and shape. The
ensure that flow only occurs after the part starts to mold should preferably be fitted with ejectors at weld
pack out. This will ensure complete filling of the lines and where shrinkage of the plastic is expected
mold and proper formation of the weak weld line (i.e. corners).
before the plane of the weld line is altered by the
overflow. If the location is too near or too far from The ejector pins should be located so that the molded
the weld line, there will be no flow through the weld part is pushed off evenly from the core. Once the size
line plane and so no strengthening of the weld line. A of the ejector pins is decided, then the greater the
removable insert at the approximate location of the number of ejector pins incorporated the greater will
weld line can facilitate experimenting with the over- be the effective ejection force and the less the likeli-
flow location to improve weld line strength. hood of distortion occurring. For this reason it is bet-
ter to err by having too many ejector pins than by
8.2.7 Venting having too few.
The already low melt viscosity of Vectra is decreased Experienced mold makers are usually able to predict
significantly again with increasing injection rate. In knockout problems. Sometimes esthetic considera-
addition, high injection rates can improve weld line tions or shortage of space prevent use of the required
strength. For this reason – and to achieve fast cycles – number of pins. It is poor practice to build a mold
Vectra is normally run at high injection rates so that under these conditions. If a satisfactory ejection sys-
the tool should generally be well vented. Since Vectra tem cannot be designed initially on paper, it will be
has extremely low melt viscosity, there must be a suf- difficult, if not impossible, to instal it in the complet-
ficient number of vents, which should if possible be ed mold.
polished and no larger than 0.025 mm. Vents in the
runner system and parting line have proven particu- Unless a molded part can be ejected consistently, an
larly successful. Other vents should be located in sec- even cycle cannot be maintained and the part cannot
tions of the cavity where air could be trapped during be produced on a commercial basis.
8
filling, e.g. in the area of weld lines or bosses. Vents at
several locations in the tool avoid forcing all of the air
through one opening.
63
Vectra®
Experience has shown that Z-shaped sprue pullers are

very suitable for use in processing Vectra because of
the material’s unique characteristics. Figure 8.2.3
shows a diagram of a typical sprue puller used in pro-
cessing Vectra.
Fig. 8.2.3 · Sprue Puller
5°
R = 0.5
64
Vectra®
9. Secondary operations
9.1 Annealing imitations of the actual part, because most of the
characteristics of Vectra are developed by flow during
The high heat deflection temperature of Vectra can be the injection molding process.
further raised 30 to 50°C by thermal aftertreatment
(annealing) of the molded parts. This process can be 9.2.1 Welding
carried out in air or nitrogen in a circulating air oven
under the following conditions: With the current trend towards rationalization and
integration of plastic components, joining technology
Vectra A series is becoming increasingly important. For production
– Heat oven from room temperature to 220°C over and assembly reasons, it is often an advantage to join
2 hours molded parts after manufacture.
– Gradually increase temperature from 220 to 240°C
over 1 hour 9.2.1.1 Ultrasonic welding
– Maintain at 240°C for 2 hours
– Gradually increase temperature from 240 to 250°C The most important requirement in ultrasonic welding
over 1 hour of Vectra parts is to create an adequate pinch-off
– Maintain at 250°C for 2 hours weld. In ultrasonic welding of Vectra, the joint
– Cool to room temperature strength depends largely on the shear length – a lon-
ger shear length yields higher strength. Other types
Vectra Ei series and Vectra S series of joint design, such as the use of energy directors,
– Heat oven from room temperature to 220°C over result in low strength. The pinch-off weld should be
2 hours designed in a conventional manner for a high modulus
– Gradually increase temperature from 220 to 250°C material, that is with about a 0.2 to 0.4 mm inter-
over 1 hour ference and a greater than 2 mm depth (Fig. 9.2.1).
– Maintain at 250°C for 2 hours The strength of the welded joint will be determined
– Gradually increase temperature from 250 to 290°C more by the depth of the joint than by the inter-
over 1 hour ference.
– Maintain at 290°C for 2 hours
– Cool to room temperature Fig. 9.2.1
Ultrasonic Welding Joint Design
During annealing, some color change may occur. This
has no adverse effect on quality.
9.2 Assembly
8
>2
The assembly and surface treatment of parts made

from Vectra is quite similar to the methods used for
conventional semi-crystalline plastics like nylon and 0.1
polyesters. A factor that must be considered in
designing joints and fastening techniques is the rela-
9
tively weak weld line strength of liquid crystal poly-
mer materials. Any joint produced by fusing parts
~0.1
together must have some shearing deformation over a

large enough area to form a strong joint. When using
30°
any fastener that causes a high stress on the weld line
either during assembly or service, the strength of the 0.2 - 0.4
weld lines must be considered. Although Vectra
LCPs have good chemical resistance, they can be
successfully joined with adhesives, both with and
without surface treatment. As with all injection
molded parts, Vectra machined prototypes are poor
65
Vectra®
All high-melting-point plastics require high energy Fig. 9.2.3

inputs to weld and Vectra is no exception. For most Spin Welding Joint Design
welding applications, a 20 kHz machine should be
100%
adequate. For very small parts (less than 13 to 19 mm
diameter), a 40 kHz machine should be considered. 66%
Horn amplitudes will generally be between 0.05 and

0.08 mm for 20 kHz frequency and about half that
for 40 kHz .
The expected weld strength will depend on both the
5 mm
2 mm
actual welding conditions and the grade of Vectra
used. Joint shear strength of about 30% to 50% of
the bulk material strength should be expected when
the above guidelines are followed. Fig. 9.2.2 shows
the relative weld strengths for various Vectra grades.
Fig. 9.2.4
Fig. 9.2.2 · Ultrasonic Weld Strengths
Spin Weld Strengths for Vectra® A130
Relative Shear Strength
A130 B230 A435 FDA E130i
0 1000 2000 3000

Carrying capacity of the weld line (N)
During ultrasonic welding tests, horn wear was
Processing Parameters: Speed = 0,84 m/s
observed. This can be avoided by using a hard metal Trigger pressure = 0.1 MPa
Weld pressure = 0.3 MPa
material or a polyethylene film layer as a buffer. Weld length = 1.29 mm
Owing to the stiffness of Vectra, the ultrasonic Rotation impulse x 360° = 2
welding process can be noisy. A silicon rubber layer

underneath the parts helps diminish the noise. 9.2.1.3 Hot plate welding
9.2.1.2 Rotational (spin) welding Hot plate welding is not recommended for Vectra
moldings. The strength of the weld is 12-15% of the
Joint design is critical for maximizing weld line bulk material strength. There is no significant differ-
strength. With the optimum design (Fig. 9.2.3), weld ence between the values in the flow and transverse
strength up to 50% of bulk material strength can be directions. The part should not have direct contact
achieved. Owing to the compressive behavior, it is with the hot plate due to the tendency of Vectra to
difficult to establish the most suitable jointing area in bond onto the plate. Radiant heat transfer alone sup-
the part. Fig. 9.2.4 gives representative values for plies enough heat energy for the process.
weld strength as a function of design.
66
Vectra®
9.2.1.4 Vibration welding ment manufacturer. For efficiency reasons, the

longer welding times can be offset by use of a multi-
With vibration welding, the specific polymer structure ple welding system. During welding trials (Fig. 9.2.6),
of Vectra causes either long welding times with low parts made from Vectra A130 and Vectra A625
pressure or short welding times with high pressure withstood a breaking load of 1300 to 1650 newtons
(Fig. 9.2.5). Low welding pressure is recommended. (Table 9.2.1).
With low welding pressure, a weld strength of about
16% of bulk material strength can be achieved. Table 9.2.1 · Electromagnetic Welding Strengths
Welding parallel to the flow direction is not recom-
Variant Pressure (bar) Depth Gastight Load to break
mended. Trigger Welding (mm) 10 min./2.5 bar (N)
Vectra 0.5 1.0 3.2 – 3.4 Yes 1664 ± 57

A130 1.0 2.0 3.4 – 3.5 Yes 1542 ± 162
Fig. 9.2.5 · Vibration Welding
1.0 3.0 3.4 – 3.5 Yes 1550 ± 119
Vectra A130
Vectra 0.5 1.0 2.3 – 2.6 Yes 1302 ± 288
With increasing
Elongation
force A625 1.0 2.0 2.8 – 3.2 Yes 1752 ± 445

Strength
the elongation 1.0 3.0 3.2 – 3.3 Yes 1665 ± 108

will be better
but the
Pressure strength will
be reduced.
Processing Parameters: Frequency = 240 Hz 9.2.2 Hot stamping
Amplitude = 1.4 mm
Weld pressure = <1 MPa
(for Vectra A130 Weld pressure = 3 MPa) Hot stamping is the preferred way to form a “head”
on a boss or rivet made from Vectra. Typically, a very
hard surface is recommended for the shaping tool to
9.2.1.5 Electromagnetic welding reduce wear when heading bosses in parts molded
from the frequently used glass fiber reinforced Vectra
Electromagnetic welding is suitable for Vectra. The grades. Heating rates and temperatures are similar to
welding quality depends on process parameters, those used with other semi-crystalline or amorphous
which have to be defined together with the equip- thermoplastics like polyesters, nylons and polycarbo-
nates. Dwell times, temperatures, pressures and cycle
Fig. 9.2.6 · Electromagnetic Welding times should be established experimentally on molded
prototype parts to make sure the parameters for a
pressure
lid robust production process are known.
9.2.3 Adhesive bonding
Parts made from Vectra can be effectively bonded

metal ring
using readily available commercial adhesives. In most
cases, the bond strengths obtained with unmodified
surfaces are more than adequate for product assembly.
can 9
Adhesive bond strengths can be further enhanced by
electro bobbin
surface treatments which improve wetting, such as
plasma treatment, corona treatment, light sanding,
Processing Parameters:
grit blasting, and chemical etching.
Testing model: can and lid with diameter = 30 mm
and thickness = 3 mm
Cross section of ring: 2,25 mm (Steel C45)
Welding equipment: KVT, Type 010
Generator UTG 20/3000
Welding time: 45 sec
Holding time: 20 sec
Power of generator: 2700 Watt (scale 90%)
67
Vectra®
Table 9.2.2 · Lap Shear Strength

a) Testing Performed at 22°C
Adhesive Type Range of Values, N/mm2 Average Values, N/mm2

As Molded Surface Treated* As Molded Surface Treated*
2 Part Epoxy 3.1 – 6.9 5.5 – 14.5 4.8 9.0

1 Part Epoxy 4.1 – 9.0 5.5 – 9.7 6.2 10.7
Cyanoacrylate 2.1 – 4.8 3.4 – 6.9 3.4 5.5
2 Part Acrylate 1.7 – 5.5 3.4 – 5.5 3.1 4.8
b) Testing Performed at 100°C

2 Part Epoxy 1.0 – 2.1 1.0 – 2.8 1.4 2.1

1 Part Epoxy 1.4 – 4.8 1.7 – 5.5 3.4 4.1
Cyanoacrylate 2.1 2.1 – 3.4 2.1 2.8
2 Part Acrylic 0.7 – 1.4 1.4 – 2.1 1.0 1.7
c) Testing Performed at 150°C

2 Part Epoxy 0.7 – 1.4 0.7 – 1.4 0.7 1.0

1 Part Epoxy 0.7 – 2.1 0.7 – 2.1 1.4 1.4
Cyanoacrylate 0.2 – 0.3 0.3 – 0.7 0.2 0.7
2 Part Acrylic 0.3 0.7 0.3 0.7
* Light sanding or grit blasting and solvent wash
Most importantly, when bonding any molded plastic tion. Please note, these data are a general screening of
part, optimum adhesion will be obtained only when classes of adhesives, not a specific recommendation.
the parts are clean, the adhesive is fresh and the Table 9.2.3 presents commercial examples of the
procedure supplied by the adhesive manufacturer is adhesives represented in Table 9.2.2. Table 9.2.4
followed precisely. It is nearly impossible to com- includes examples of adhesives that comply with
pletely clean mold release from a molded part and either FDA regulations or United States Pharma-
mold release will prevent good adhesion. So, do not copeia (USP) Class VI requirements.
use mold release. Surfaces to be bonded should not
be touched after cleaning, because an oil film may be Adhesion will be improved by proper surface pre-
deposited which could interfere with adhesion. paration. Gas plasma technology has been successfully
used to improve the adhesive bond strength between
Certain Vectra grades provide greater bond strength Vectra and epoxy and urethane adhesives. Table 9.2.5
than others. Generally, filled or reinforced grades of shows the effectiveness of plasma treatment.
Vectra provide greater bond strengths than unfilled
grades. Table 9.2.2 a, b and c shows typical shear 9.2.4 Fasteners
strengths (ASTM D 3163) obtained with a variety of
adhesives tested at 22°C, 100°C and 150°C, respec- 9.2.4.1 Screws
tively. Before specifying these or any other adhesives,
the end user should make certain that all mechanical, Vectra can be used for producing parts that will be
thermal, electrical, chemical and other properties of joined together by screw fastening. Trials were con-
the adhesive are suitable for the application in ques- ducted to develop the design and determine the best
68
Vectra®
Table 9.2.3 · Typical Adhesives for Vectra® LCP

Supplier Grade Family Cure Temp Range (°C)
Lord Corporation Fusor ® 310 2 Part Epoxy 15 minutes at 105°C -40 to 205
3M Adhesives Scotch-Weld ®1838 A/B 2 Part Epoxy 30 min at 95°C -55 to 175
Cole-Parmer Co. 5- Minute Epoxy 2 Part Epoxy 1 hour at 20°C -30 to 95
3M Adhesives Scotch-Weld ® 2214 Hi-Temp 1 Part Epoxy 10 minutes at 150°C -55 to 175
3M Adhesives Scotch-Weld ® 1 Part Epoxy 15 minutes at 150°C -55 to 230

2214 Hi-Temp, New Formula
Epoxy Technology, Inc. EPO-TEK® H35-175MP 1 Part Epoxy 1.5 hours at 175°C -50 to 160
(Electrically Conductive)
Delo Industrie Klebstoffe Monopox 6093 1 Part Epoxy 1 hour at 100°C -40 to 240
Duopox AD 895 2 Part Epoxy 30 minutes at 80°C -40 to 180
Permabond International Permabond® 102 2) 1 Part Cyanoacrylate 30 seconds at 23°C -60 to 80
Permabond International 610/612 2) 2 Part Epoxy 25 seconds at 23°C -80 to 150
1) REN is the registered trademark of REN Plastics Co.

2) Permabond is the registered trademark of National Starch an Chemical Corp.
Table 9.2.4 · Adhesives Compliant with US Regulations

Supplier Grade Family Cure Temp Range (°C) In Compliance
Tra-Con Tra-Bond FDA-8 2 Part Epoxy 4 hours at 65°C -51 to 150 FDA*
Epoxy Technology Epo-Tek 301 2 Part Epoxy 1 hour at 65°C USP Class VI
Loctite Medical Adhesive 4013 Cyanoacrylate 30 seconds at 20°C -40 to 105 USP Class VI
* In compliance with FDA Title 21, US Code of Federal Regulations, Food and Drug Administration (FDA) Chapter 1, Sub Part B, Sections 175.105 and 175.300.
ratio of screw to hole dimensions. The screw hole dia-

Table 9.2.5 · Lap Shear Strengths
meter must be designed with very narrow tolerances.
Vectra A130 Vectra A625
Epoxy Urethan Epoxy Urethan Table 9.2.6 gives typical dimensions for a screw.
No treatment 7.2 MPa 0.9 MPa 6.5 MPa 1.3 MPa
Figure 9.2.7 shows a diagram of a screw hole boss.
Oxygen plasma 11.4 MPa 9.3 MPa 11.0 MPa 6.7 MPa Design recommendations and dimensions are given in
Ammonia plasma 8.8 MPa 10.5 MPa 8.6 MPa 7.2 MPa
Table 9.2.7.
9
9.2.4.2 Ultrasonic inserts
Table 9.2.6 · Typical Boss Dimensions
Material Screw-type Hole Boss Screwing Brass inserts are used to provide metal threads in
(EJOT) Diameter db Diameter D Depth te
thermoplastics. The inserts are installed using ultra-
Vectra A130 PT 0.84 x d 1.90 x d 1.80 x d sonic or heat equipment that develops heat between
the insert and the plastic. The heat remelts the narrow
Vectra E130i PT 0.86 x d 1.90 x d 1.80 x d
zone around the insert which, once resolidified,
Vectra B230 PT 0.90 x d 2.00 x d 1.90 x d provides a high strength anchorage for the insert.
The Ultrasert II insert from Heli-Coil has stepped
inclined ribs that continually present new metal
69
Vectra®
Fig. 9.2.7 Table 9.2.8 · Performance of Molded-in Inserts

Boss for EJOT PT ® K Screw (Dodge Ultrasert II inserts*)
D
Thread Size Part number Tensile Rotational Jack-out
de strength torque
(N) (Nm) (Nm)
#2-56 6035-02BR115 420.5 0.9 0.3

6035-02BR188 987.9 1.1 0.4
0.3 - 0.5 x d
#4-40 6035-04BR135 842.4 2.8 1.0

6035-04BR219 1764.4 2.9 1.7
db
#6-32 6035-06BR150 1067.1 3.2 0.8
te
6035-06BR250 2182.2 3.4 1.9
#8-32 6035-2BR185 1359.5 3.8 2.0

6035-2BR312 2247.3 5.7 2.9
#10-32 6041-3BR225 1659.0 6.3 3.7
*Emhart Heli-Coil, Shelter Rock Lane, Danbury, CT 06810

Phone (203) 743-7651, Fax (203) 798-2540
d = nominal screw diameter
D = boss diameter = 2 x d
de = d + 0.2 mm Ultrasonic insertion conditions
t e = screw depth (Branson Ultrasonic welder, model 8700)
d b = screw note diameter
Thread size Booster Weld time Hold time Air pressure
(s) (s) ( MPa )
surfaces to the plastic, so forming a continuous zone
of melting and solidifying during installation. #2 Black 0.4 0.5 0.10
#4 Black 0.5 0.5 0.10

This creates a homogenous polymer structure around
#6 Black 0.6 0.5 0.14
the insert. The Ultrasert II has a unique knurled flange,
which provides positive downward compressive force #8 Black 0.6 0.5 0.14
to the molten plastic that assures complete filling of #10 Black 0.7 1.0 0.14
the grooves for torque resistance. Table 9.2.8 shows
the performance of these inserts in Vectra moldings in
relation to three important criteria.
Table 9.2.7 · EJOT PT® K Screw

EJOT PT® K thread nominal screw hole diameter, Penetration driving stripping pull out
forming screw diameter, d db depth, te torque torque strength
(mm) (mm) (mm) (Nm) (Nm) (N)
Vectra A130 PT K 50 X 12 5 4.2 9.5 0.84 4.21 4170

PT K 30 X 10 3 2.5 9.5 0.43 1.36 1640
Vectra E130i PT K 50 X 12 5 4.4 9.5 0.54 2.38 2680

PT K 30 X 10 3 2.5 6 0.37 1.09 1340
Vectra B230 PT K 50 X 12 5 4.4 9.5 0.79 2.6 3050

PT K 30 X 10 3 2.7 6 0.4 1.09
70
Vectra®
Supplier Information IPN

151 Essex Street
Europe Haverhill, MA 01832, USA
Tel: ++1 (508) 372-2016
DELO Industrie Klebstoffe Fax: ++1 (508) 374-6955
GmbH & Co. KG
Ohmstraße 3 Emerson & Cumming
D-86899 Landsberg Polymers
Tel: ++49 8191 3204-0 55 Hayden Avenue
Fax: ++49 8191 3204-144 Lexington, MA 02173 USA
Tel: ++1 (800) 832-4929
Poly Tec GmbH Fax: ++1 (617) 861-9590
Poly-Tec-Platz 1-7
D-76337 Waldbronn Henkel Corporation
Germany 1001 Trout brook Crossing
Tel: ++49-7243-6040 Rocky Hill, CT 06067, USA
Fax: ++49-7243-69944 Tel: ++1 (860) 571-5100
Fax: ++1 (860) 571-5465
3M Deutschland GmbH
Carl-Schurz-Straße 1 9.3 Decoration
41453 Neuss
Germany 9.3.1 Printing
Tel: ++49-2131-140
Printing on untreated, freshly molded parts made
Huntsman from Vectra has been successfully demonstrated using
Klybeckstrasse 200 one- and two-component inks. Pretreatment such
CH-4057 Basel as corona or plasma surface treatment may not be
Tel.: ++41-61966 4120 necessary. Ink suppliers are willing to assist with the
selection of appropriate inks to match a customer’s
USA specific application. In most cases, they have the
experience to guide the customer through the com-
Huntsman Advanced Materials plete process. If necessary, they can modify the inks
10003 Woodloch Forest Drive and even test trial parts.
The Woodlands, Texas 77380
Tel: ++1 (888)-564-9318 Markem Corporation
150 Congress Street
Cole-Parmer Co. Keene, New Hampshire 03431, USA
7425 North Oak Park Avenue Tel.: ++1 (603) 352-1130
Chicago, IL 60648 USA Fax: ++1 (603) 357 1835
Tel: ++1 (847) 549-7600
9
Fax: ++1 (847) 247-2983 Colorcon
A Division of Berwind Pharmaceutical
Epoxy Technology, Inc. 415 Moyer Boulevard
14 Fortune Drive Billerica, West Point, Pennsylvania 19486-0024, USA
MA 01821 USA Tel.: ++1 (215) 699-7733
Tel: ++1 (800) 227-2201 Fax: ++1 (215) 661 2605
Fax: ++1 (508) 667-4446
71
Vectra®
Tampoprint International Corp. Laser marking conditions:

1400, 26th Street
Vero Beach, Florida 32960, USA Energy – 18 amperes
Tel.: ++1 (561) 772 8896 Frequency – 5,000 Hz
Fax. ++1 (561) 772 8289 Minimum writing size – 1 to 2 mm
Tampoprint AG Nd/YAG lasers produce anthracite-colored markings

Lingwiesenstrasse 1 on natural Vectra surfaces and pale gray markings on
D-70825 Korntal-Münchingen black Vectra surfaces.
Germany
Tel.: ++49 (0) 7150-928-0 9.4 Plating and molded interconnect devices (MID)
Fax: ++49 (0) 7150-928-400
9.4.1 Plating Vectra
9.3.2 Painting
In recent years, Vectra has increasingly been used
Vectra LCPs can be painted but strict conditions for applications in which not only its characteristic
must be observed. Because the plastic substrate is properties but also suitability for plating are required.
chemically inert, it is very difficult to improve the
adhesion of paints to Vectra by chemical etching. The Vectra 800 series, for example Vectra E820i, has
Pretreatment with a primer is therefore recommended. been specially developed for plating. These products
Pretreatment with Ditzler polypropylene primer, allow micro-roughness to be generated on the surface
code no. DPX801 has been used successfully in trials. of the part by an alkaline etching process, so that the
metal layer is provided adequate facility for adhesion.
Ditzler/PPG Industries Processing chemicals can be supplied by companies
One PPG Place such as ROHM and HAAS, ENTHONE or
North Pittsburgh, Pennsylvania 15272, USA ATOTECH.
Tel.: ++1 (412) 434-3131
Customer Service: ++1 (888) 774-1010 The adhesive strength of the metal layer depends on
the injection molding parameters (drying, injection
Schramm Coatings GmbH rate, barrel temperature and mold temperature),
Kettelerstrasse 100 the etching process and the test equipment. If the
Postfach 10 17 63 recommendations give here are followed, adhesion
D-63017 Offenbach/Main, Germany strengths from 0.9 to 1.5 N/mm2 can be achieved.
Tel.: ++49 (0) 69 8603-0 The plating process is shown schematically below.
Fax: ++49 (0) 69 8603-229
Molding
Berlac AG
Allmendweg 39
CH-4450 Sissach, Switzerland Etching
Tel.: ++41 (61) 976 9010
Fax: ++41 (61) 976 9620
Activating surface
9.3.3 Laser marking
Non-contact permanent marking of texts, patterns Applying copper chemically

and serial codes on Vectra surfaces is possible using a
laser beam. Two suitable laser-marking methods can
be used:
Applying copper electrolytically
– Nd:YAG laser
Finishing the surface (gold, tin/lead)
– Excimer or CO2 laser
72
Vectra®
The chemically deposited layer of copper is generally Lüberg Elektronik GmbH & Co. KG
2 – 3 µm thick. The individual process parameters Hans-Striegel-Straße 3
depend on the applications that have been developed D-92637 Weiden
by the various firms. After the etching and the depo- Germany
sition of copper over the whole surface, copper is Tel.: ++49 (0) 961-38159-30
then electrolytically applied until the desired layer Fax: ++49 (0) 961-62109
thickness is achieved (approximately 20 – 30 µm).
A barrier layer of nickel is then applied, and the Collini-Flühmann AG
surface is finished with tin/lead or with gold. Vectra Ringstraße 9
E820i is suitable for the plating process described. CH-8600 Dübendorf
Because of its special modification, Vectra E820i Pd Switzerland
does not require surface activation. This advantage Tel.: ++41 (0) 44 824 11 11
makes it an excellent material for the production of Fax: ++41 (0) 44 824 11 12
3D MID components (see MID).
AHC – Oberflächentechnik GmbH
In sputtering, the metal that is to be used to coat Coswiger Straße 16
the component is subjected to ion bombardment to D-12681 Berlin
release ionized atoms into a surrounding vacuum. Germany
The atoms drift along the potential gradient from the Tel.: ++49 (0) 30-549904-0
metal source to the plastic part, where they accu- Fax: ++49 (0) 30-549904-20
mulate in a hard, even layer. The thickness of that
layer depends on the sputtering time. In practice, Molded Circuits LTD
thicknesses of up to 5 µm are achieved with Vectra. 1142 Melton Road,
Syston Leicester LE7 2HA
In aluminum vapor deposition, the components are UK
placed in an evacuated chamber that also contains Tel.: ++44 (0) 116- 260 9841
small aluminum blocks as the source of metal. Very Fax: ++44 (0) 116-269 8392
high temperatures cause the aluminum to vaporize,
and the aluminum cloud precipitates on the com- In the USA:
ponents. This method is used with Vectra to produce
screening elements and reflectors, among other uses. Molded Interconnect Devices LLC
250 Metro Park
The addresses of some companies that have acquired Rochester, NY 14623, USA
knowledge of Vectra plating are included here: Tel.: ++1 (716) 272-3100
In Europe: Circuit-Wise
400 Sackett Point Road
FUBA Printed Circuits GmbH North Haven, CT 06473, USA
Bahnhofstraße 3 Tel.: ++1 (203) 281-6511
D-37534 Gittelde/Harz
9
Germany Cybershield of Texas
Tel.: ++49 (0) 5327- 880-0 308 Ellen Trout
Fax: ++49 (0) 5327- 880-200 Lufkin, TX 75904
Tel.: ++1 (936) 633-6387
Siegfried Schaal Metallveredlung GmbH & Co.
Laucherthaler Straße 30 Metal Surfaces
D-72517 Sigmaringendorf 6060 Shull Street
Germany Bell Gardens, CA 90201, USA
Tel.: ++49 (0) 7571-72 09-0 Tel.: ++1 (310) 517-9285
Fax: ++49 (0) 7571-72 09-23 Fax: ++1 (310) 517-9265
73
Vectra®
Crown City Platers conductor tracks has to be changed, it is only neces-

4350 Temple City Blvd. sary to reprogram the laser. This is a patented process
El Monte, CA 91731, USA developed by the company LPKF (www.lpkf.de).
Tel.: ++1 (626) 444-9291 With this technology, conductor track widths of 0.15
mm and spacing of 0.2 mm can be achieved.
Providence Metallizing Company, Inc.
51 Fairlawn Avenue 9.5 Machining
Pawtucket, RI 02860-2591, USA
Tel: ++1 (401) 722-5300 Although the usual aim of an injection molding
Fax: ++1 (401) 724-3410 process is to produce plastic parts that are ready for
use as soon as they have been ejected from the mold,
9.4.2 MID there are times when machining is needed. The
properties of molded parts produced from Vectra are
The production of three-dimensional circuit boards largely determined by molecular orientation, which
or so-called MID technology (MID = molded inter- in turn is influenced by gate and mold design and
connect device) is one of the most important applica- injection molding conditions. In preparing test speci-
tion areas for the metallization of Vectra. With the aid mens by machining, special care is needed. A test
of MID technology, it is possible to manufacture 3D specimen will not, of course, necessarily have the
circuit structures with great freedom of design by in- same orientation structure as the finished molding,
jection molding. The special combination of properties which can lead to differences in mechanical, electrical
offered by Vectra makes it well qualified to produce or other properties. If possible, therefore, test speci-
molded interconnect devices. The following processes mens should be produced by injection molding rather
can be used for the manufacture of MID components: than being milled from blocks. In the case of Vectra,
the properties of the surface layer differ significantly
The PCK (printed circuit board Kollmorgen) process from those of the core. Where preparation of test
(2-component injection molding): specimens by machining is the only option, the mini-
mum possible surface material should be removed.
First of all a pre-molding is produced from the plat- Every intrusion in the surface destroys the sandwich-
able, catalytically modified Vectra grade E820i Pd. like structure and therefore crucially weakens the
Then this first shot is overmolded with a non-platable component. If the component design includes inte-
Vectra grade (e.g. E130i). The component is then grally molded holes, drilling such holes in the prepa-
etched and the molding surface selectively plated. ration of test specimens invalidates assessment of
With Vectra 2-shot technology, wall thicknesses of weld line effects in the end product.
0.25 mm can be achieved for the conductor track
width and spacing. This process enables considerable There are exceptional cases in which machining
cost savings to be made through miniaturization of can be necessary. Reasons for this may be to avoid
components, higher integration density of functional complex mold configurations or weld lines in critical
elements, reduction in the number of parts and a high areas. The following practical rules should be borne
degree of automation. in mind when machining Vectra:
LPKF LDS® process: – Use sharp tools

– Provide adequate cooling
The energy of a laser beam can also be used to – Allow enough chip clearance
produce three-dimensional circuit boards. In this – Support the work properly
process, the component is injection molded entirely
from Vectra E840i LDS, a grade specially developed Compared to other thermoplastics, the stiffness,
for laser direct structuring (LDS). The component is thermal conductivity and low coefficient of friction
structured (activated) with a laser in the places where of Vectra promotes good machinability. Vectra is a
the conductor tracks are later to be created. Finally, thermoplastic and so will melt if the machining
the component is selectively plated. The advantage of operation generates too much frictional heat.
this process is its great flexibility. If the layout of the
74
Vectra®
9.5.1 Tooling For drilling, standard high-speed twist drills are best.
Occasionally burring may occur. This can be elimi-
Dull tools tend to scrape rather than cut, yielding a nated by clamping dummy pieces of plastic above and
poor surface finish and generating excess frictional below the work. In any case, the work should be
heat in the process. The best surface finishes are firmly supported and securely held. For deep holes,
obtained with sharp tools, high speeds and slow feed the drill should be raised frequently (about every 6
rates. Both machining speed and the feed rate should mm of depth) to clear the drill and hole of chips. A
be uniform and uninterrupted. Cooling allows higher jet of compressed air helps to disperse chips and cool
cutting speeds. Vectra is resistant to all currently used the drill.
cutting fluids.
Table 9.5.1 · Tool Speeds for Drilling or Milling
In addition to having sharp cutting edges, there must
Tool diameter Tool speed
be adequate clearance for chips. When there is a (mm) (rpm)
choice in tool selection, the machinist should pick
Unfilled grades Reinforced grades
one offering the greatest chip clearance, for example,
drills with wide flute areas or saw blades with deep 1.6 2,300 2,000
gullets. Unlike some plastics containing abrasive 3.2 2,000 1,700
fillers such as minerals, glass or carbon fibers etc.,
5.6 1,800 1,500
Vectra can be machined with standard high speed
stainless steel tools, although carbide tools prolong 6.4 1,600 1,300
tooling life during extended production runs. 9.5 1,300 1,000
15.9 1,000 800

9.5.2 Turning
Vectra can be easily turned on a lathe. Tool bits must

be sharp and should provide a rake angle of 5 to 15° 9.5.4 Threading and tapping
with front and side clearance angles of 0 to 15°. A tip
radius of at least 1.5 mm should be used for smooth Threads may be readily cut on a lathe, using the tool
finish cuts. Feed rates and cutting speeds for turning and cutting conditions previously outlined. Conven-
depend primarily on the nature of the cut and the tional taps and dies may be used with good results.
desired finish. For most work, a peripheral part speed These may be threaded either by hand or by machine.
of 0.3 m/s is reasonable. A smooth cut finish calls for A speed of about 180 rpm is suggested for screw sizes
a somewhat higher turning speed and slower feed rate. from UNC 10-24 through 3/8-16. The international
As a guideline, a 12 mm diameter rod turned with a metric equivalent sizes would be 6-1.00 to 10-1.50.
1.5 mm tool tip radius at 100 rpm and a 0.04 mm/ A special tap for plastics, with two flutes, is available
revolution feed advance delivers a good surface finish. and offers some advantages in greater chip clearance
but it is not essential for satisfactory results.
9.5.3 Milling and drilling
Standard helical-type milling cutters are suitable for

9
Vectra. Two-flute end mills are preferred for greater
chip clearance. Using the suggested tool speeds in
Table 9.5.1, Vectra can be cut without a coolant. Feed
rates should be adjusted to obtain the desired finish.
75
Vectra®
9.5.5 Sawing cutting, while a finer blade gives a smoother edge.

In general, the blade should have at least two teeth in
Vectra may be sawn with almost any type of saw. contact with the part at all times. Bandsawing gives
To prevent binding of the blade, however, the saw a good finish cut without cooling, using a blade speed
teeth should have some degree of offset, at least 0.125 of approximately 17 m/s, when the part is less than
mm offset per side. Coarse teeth and extra wide 6 mm thick.
gullets for chip clearance are desirable for rapid
76
Vectra®
10. Conversion tables

10.1 Unit conversion factors 10.3 Length conversion
Multiply by
Inches Inches Mils cm mm
Divide by
Length 1 1 1000 2.54 25.4
meter (m) 2.54 x 10–2 inch (in) 1/2 0.5 500 1.27 12.7
meter (m) 3.05 x 10–1 foot (ft) 1/4 0.25 250 0.64 6.4
1/8 0.125 125 0.32 3.2
Area
square meter (m2) 6.45 x 10–4 square inch (in2) 1/16 0.0625 62.5 0.16 1.6
square meter (m2) 9.29 x 10–2 square feet (ft2) 1/32 0.0313 31.3 0.08 0.8
1/64 0.0156 15.6 0.04 0.4
Volume
cubic meter (m3) 1.64 x 10–5 cubic inch (in3)
cubic meter (m3) 2.83 x 10–2 cubic feet (ft3)
Mass 10.4 Temperature conversion

kilogram (kg) 4.54 x 10–1 pound (lb)
Force Degrees Celsius (°C) Degrees Fahrenheit (°F)

newton (N) 4.45 pound-force (lb f)
newton (N) 9.81 kilogram-force (kgf) 0 32
10 50
Pressure
20 68
pascal (Pa) = newton/meter 2 (N/m2)
pascal (Pa) 6.985 x 10–3 lb f /in2 (psi) 50 122
mega Pascal (MPa) 6.985 x 10–3 lb f /in2 (psi) 75 167
pascal (Pa) 9.807 x 10–4 kg f /cm2 100 212
pascal (Pa) 10 5 bar 125 257
150 302
Viscosity
pascal.sec. (Pa · s) 0.1 poise 175 347
200 392
Energy 225 437
joule (J) 4.19 calorie (cal) 250 482
kilojoule/kilogram (kJ/kg) 4.19 calories/gram (cal/g)
275 527
joule/kilogram (J/kg) 2.33 x 10 3 BTU/lb
300 572
Technical textiles 325 617

350 662
Linear mass density of filaments 375 707
tex 9 denier 400 752
dtex 10–1 mg/m
Conversion factor °F = 1.8 · °C + 32
Tenacity
cN/tex 1.132 x 10–1 gf/denier
10.2 Stress conversion
Strength Modulus
9
MPa psi MPa psi x 106
75 10 877 6 000 0.87
100 14 504 8 000 1.16
125 18 130 10 000 1.45
150 21 756 12 000 1.74 10
175 25 382 14 000 2.03
200 29 008 16 000 2.32
225 32 634 18 000 2.61
250 36 259 20 000 2.90
275 39 885 22 000 3.19
300 43 511 24 000 3.48
77
Vectra®
11. Subject index

Adhesive bonding 67–68 Heat deflection temperature under load 22, 24
Anisotropy 16, 50, 56 Heat release test 27
Annealing 65 Holding pressure 44
Approvals 30–32 Hot runner systems 42, 60
Arc resistance 28 Hydrolysis, resistance to 33
Assembly of molded parts 65
Impact strength 19, 29
Back pressure 44 Impact stress 19
BfR/BgVV approvals 30 Injection molding 41–49
Inserts 59, 69, 70
Chemical resistance 19
Coefficient of linear thermal expansion 23 Laser beam 72, 74
Color masterbatches 14
Coloration 14 Machining 74
Combustion products 27 Masterbatches 14
Conductivity, electrical 12, 13, 28 Mechanical properties 15
Creep 19, 21 Melt temperatures 43
Creep resistance 19–20 Melting point 9, 24
Cyclic stress 19 MID 74
Milling 75
Damping 21–22 Mold design 58
Decoration 71 Mold temperatures 43
Design 60–69
Die 50–53 Non-return valve 41
Dissipation factor 21, 28 Nozzle 42–43, 47
DMA 21–22
Drilling 75 Outgassing 26
Drug Master File 31, 32 Oxygen index, LOI 27
Drying conditions 40
Packaging 14
Elongation at break 15 Painting 71
Enthalpy 25, 26 Permeability to gases and vapors 36, 37
Extrusion 50–54 Physical properties 15
Plating 72–74
Fatigue strength 19, 20 Printing 71
FDA approvals 30–32 Product line 12, 13
Filler/fiber combinations 12 Properties, electrical 30
Flammability 32 Properties, mechanical 16
Flashing 47 Properties, physical 15
Flexural creep modulus 19 Properties, thermal 21–26
Flexural modulus 17, 34, 37 Properties, tribological 20
Flexural strength 17, 37
Flow behavior 56, 60 Radiation resistance 36
Friction 20, 21 Regrind addition 45
Relative permittivity 28, 29
Gas permeability 36, 37 Residual moisture content 40
Gates 61–63 Rheology 56
Grade descriptions 12–13 Rockwell hardness 20
78
Vectra®
Safety data sheets 38 UL listings 27

Safey recommendations 38 Ultrasonic welding 65–66
Sawing 76 Underwriters Laboratories 27, 28, 32, 45
Screw decompression 44, 46, 48
Screw fastening 68 Venting (molds) 47, 63
Screw speed 43, 47, 48
Self ignition temperature 27 Warpage 49, 56, 57, 61
Shear strengths 62, 66, 68, 69 Water absorption 39, 52
Shrinkage 56 Wear 20, 41, 58–60, 66, 67
Shutting down the machine 39 Weld lines 49, 56–58, 63
Smoke density 27 Welding 65–67
Snap-fits 58 Wöhler curves 20
Soldering resistance 24
Specific heat 25
Sprue puller 64
Standards 30–32
Startup and shutdown procedures 38
Streaks 48
Stress-strain behavior 18
Submarine gate 62
Surface properties 60
Tensile creep modulus 19

Tensile modulus 16–18, 21, 33
Tensile strength 15–17, 19, 33
Thermal conductivity 25, 26
Thermal expansion coefficient, linear 23
Thermal properties 21–26
Tribological properties 20
Troubleshooting, extrusion 53–54
Troubleshooting, injection molding 46–49
Turning 75
11
79
Hostaform®, Celcon® Notice to users:
polyoxymethylene copolymer (POM) To the best of our knowledge, the information con-tained in
this publication is accurate, however we do not assume any
Celanex® liability whatsoever for the accuracy and completeness of such

information. The information contained in this publication
thermoplastic polyester (PBT) should not be construed as a promise or guarantee of specific
properties of our products.
Impet ® Further, the analysis techniques included in this publication
thermoplastic polyester (PET) are often simplifications and, therefore, approximate in nature.
More vigorous analysis techniques and prototype testing are
Vandar ® strongly recommended to verify satisfactory part performance.
Anyone intending to rely on any recommendation or to use
thermoplastic polyester alloys any equipment, processing technique or material mentioned in
this publication should satisfy themselves that they can meet all
Riteflex® applicable safety and health standards.
thermoplastic polyester elastomer (TPC-ET) It is the sole responsibility of the users to investigate whether
any existing patents are infringed by the use of the materials
Vectra® mentioned in this publication.
liquid crystal polymer (LCP) Properties of molded parts can be influenced by a wide variety
of factors including, but not limited to, material selection, addi-
Fortron® tives, part design, processing conditions and environmental
exposure. Any determination of the suitability of a particular
polyphenyle sulphide (PPS)
Vectra® liquid crystal polymer (LCP)

material and part design for any use contemplated by the users
is the sole respon-sibility of the users. The user must verify that
Celstran®, Compel ® the material, as subsequently processed, meets the requirements
of the particular product or use. The user is encouraged to test
long fiber reinforced thermoplastics (LFRT)
prototypes or samples of the product under the harshest con-
ditions likely to be encountered to determine the suitability
GUR® of the materials.
ultra-high molecular weight
Material data and values included in this publication are either
polyethylene (UHMW-PE) based on testing of laboratory test specimens and represent data
that fall within the normal range of properties for natural mate-
rial or were extracted from various published sources. All are
believed to be representative. These values alone do not repre-
Americas sent a sufficient basis for any part design and are not intended
Ticona for use in establishing maximum, minimum, or ranges of values
Product Information Service for specification purposes. Colorants or other additives may
cause significant variations in data values.
Tel.: +1-800-833-4882
Tel.: +1-859-372-3244 We strongly recommended that users seek and adhere to the
email: [email protected] manufacturer’s current instructions for handling each material
they use, and to entrust the handling of such material to
Customer Service adequately trained personnel only. Please call the numbers listed
Tel.: +1-800-526-4960 on the back cover for additional technical information. Call
Customer Services at the number listed overleaf for the appro-
Tel.: +1-859-372-3214 priate Material Safety Data Sheets (MSDS) before attempting
Fax: +1-859-372-3125 to process these products. Moreover, there is a need to reduce
human exposure to many materials to the lowest practical
Europe limits in view of possible adverse effects. To the extent that
Ticona GmbH any hazards may have been mentioned in this publication,
we neither suggest nor guarantee that such hazards are the only
Information Service
ones that exist.
Tel. +49 (0) 180 - 5 84 26 62 (Germany)*
+49 (0) 69 - 3 05-1 62 99 (Europe) The products mentioned herein are not intended for use in
Fax +49 (0) 180 - 2 02 12 02** medical or dental implants.
e-Mail: [email protected]
B 241 E 10.2007
Internet: www.ticona.com
© Copyright by Ticona GmbH
* 0,14 A/min + local landline rates

** 0,06 A/Call + local landline rates Published in Oktober 2007

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What are the different grades of Vectra LCP mentioned?

What are the different grades of Vectra LCP mentioned?

What are some of the mechanical properties discussed for Vectra LCP?

What are some of the mechanical properties discussed for Vectra LCP?

Vectra ®

liquid crystal polymer (LCP)

• high melt flow,

2. Vectra product line 12

4. Behavior in relation to environmental effects 33

10. Conversion Tables 77

11. Subject index 78 Injection molding 6

1. Introduction and overview Fig. 1.1 · Representation of Structural Differences

The characteristic property profile and behavior of

other resins, that LCPs are treated as a separate class

Extended Chain Structure

Table 1.1· Comparison of Amorphous, Semi-Crystalline and Liquid Crystalline Polymers

Table 1.2 · Key Performance Characteristics by Market Segment

Electrical / electronics Packaging Cookware and bakeware

* High Performance Plastics Acronyms

ABS = acrylonitrile-butadiene-styrene HTN = high temperature polyamide (nylon)

2. Vectra product line

Fig. 2.1 · Vectra® product line

Glass fiber reinforced A115

Carbon fiber reinforced A230D-3 B230

Fiber/filler A430 E440i

Mineral filled E540i S540

Graphite filled A625 S625

Electrically conductive A700

Alloy V140 V143XL

Extrudable (unfilled) A950 V400P

Vectra base polymers

A9500 / E9500i 2.3 Packaging

For Vectra “A” and “B” grades, color masterbatch

The level of properties depends primarily on the type

3.1 Mechanical properties

As the wall, film or sheet thickness decreases, the

Fig. 3.1.3 · Tensile Modulus versus Wall Thickness Vectra® LCP

Fig. 3.1.5 · Flexural Modulus versus Wall Thickness Vectra® LCP

Fig. 3.1.6 · Flexural Strength versus Wall Thickness Vectra® LCP

modulus in thinner sections (Figs 3.1.3, 3.1.4, 3.1.5

35% glass fiber reinforced resins, Vectra A230D-3 and 0

Fig. 3.1.7 · Stress Strain Curves, Tensile Test at 23°C

250 Fig. 3.1.8b · Influence of Temperature on

on the stress strain curves of Vectra B230 and Vectra 30.000

Flexural Creep Modulus (MPa)

50 Maximum Stress = 50 MPa

Vectra has moderate surface hardness. Rockwell

– hardness M values of up to 100 are attained (see the

stress range A115 0.11 0.11

test temperature 23 °C Carbon Fiber Reinforced A230D-3 0.19 0.12

mean stress m = 0 A430 0.11 0.11

Fig. 3.1.15 · Friction and Wear

The Wöhler flexural fatigue stress curves for various B230

Vectra LCP grades are shown in Fig. 3.1.17. The A230D-3

flexural fatigue strength of Vectra A130 after 107 A130

stress cycles is σ bw = 50 N/mm2. 0.4 0.3 0.2 0.1 0 5 10 15

Friction: steel ball diameter 13 mm,

The unique structural characteristics of Vectra have 14

Damping Factor (1/sec)

Vectra A130 (30% GF) L 0.05 0.05

PPS (40% GF) L 0.15 0.16