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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

International General Certificate of Secondary Education

MARK SCHEME for the May/June 2007 question paper

0620 CHEMISTRY
0620/03 Paper 3 (Extended Theory), maximum raw mark 80

This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.

All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.

Mark schemes must be read in conjunction with the question papers and the report on the
examination.

CIE will not enter into discussions or correspondence in connection with these mark schemes.

CIE is publishing the mark schemes for the May/June 2007 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
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Page 2 Mark Scheme Syllabus Paper
IGCSE May/June 2007 0620 3

An incorrectly written symbol, e.g. NA or CL, should be penalised once in the paper.

1 (a) (i) coal or coke or peat [1]

NOT wood or charcoal

(ii) natural gas or methane or propane or butane or petroleum gases or calor gas or
refinery gas [1]

(b) (i) petrol or gasoline

paraffin or kerosene
diesel
aviation fuel or jet fuel
fuel oil
heavy fuel oil
heating oil
Any TWO [2]
NOT a named alkane e.g. octane

(ii) waxes or grease or lubricants or polishes or bitumen (tar, asphalt) or naphtha [2]
Any TWO from the primary or secondary distillation of petroleum

(iii) (liquid) air or ethanol and water or alkenes (made by cracking) or Noble Gases
[1]

[Total: 7]

2 good [1]
named example e.g. sodium chloride [1]
ACCEPT correct formula

silica or silicon(IV) oxide or sand or silicon oxide

named polymer only TWO elements [1]

electrons [1] and positive ions [1] [2]

good [1]

[Total: 6]

3 (i) method C [1]

sulphuric acid (allow if given in equation) [1]
zinc oxide + sulphuric acid = zinc sulphate + water [1]

(ii) method A [1]

hydrochloric acid [1]
KOH + HCl = KCl + H2O [1]

(iii) method B [1]

potassium iodide or any soluble iodide [1]
Pb2+ + 2I- = PbI2 accept a correct equation even if soluble iodide is wrong [2]
Not balanced - Pb2+ + I- = PbI2 ONLY [1]

[Total: 10]

UCLES 2007
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Page 3 Mark Scheme Syllabus Paper
IGCSE May/June 2007 0620 3

4 (a) (i) BaO [1]

(ii) B2O3 [1]

(b) (i) S2- [1]

(ii) Ga3+ [1]

(c) NCl3 [1]

COND 8e (1bp and 3nbp) around each chlorine [1]
8e (3bp and 1nbp) around nitrogen [1]

(d) (i) ignore a correct chemical property in (i)

vanadium harder
vanadium higher melting point or boiling point
vanadium higher density
ANY TWO [2]
OR corresponding statements for potassium
NB has to be comparison

(ii) ignore a correct physical property in (ii)

potassium more reactive or example of different reactivities-
potassium reacts with cold water, vanadium does not.
potassium one oxidation state, vanadium more than one
vanadium coloured compounds, potassium white or colourless
vanadium and its compounds catalysts, not potassium
ANY TWO [2]
NB has to be comment about both elements

(e) (i) fluorine gas [1]

astatine solid [1]

(ii) both have valency of one

both can react with other elements to form halides
both are oxidants
or any correct Chemistry they both form acidic hydrides
both have diatomic molecules
both accept one electron or form ion X-
both have seven valency electrons
both react with non-metals to form covalent compounds
both react with metals to form ionic compounds
both form acidic oxides
NOT have a valency of 7
ANY TWO [2]

[Total: 15]

UCLES 2007
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Page 4 Mark Scheme Syllabus Paper
IGCSE May/June 2007 0620 3

5 (a) (i) air would react (with the magnesium or titanium)

OR argon would not react (with the metals) [1]
NOT argon is inert

(ii) any metal higher than magnesium in reactivity series [1]

(iii) add water (to dissolve salt) [1]

filter or centrifuge [1]

(b) (i) electron loss [1]

(ii) hydrogen [1]

(iii) oxygen [1]

chlorine [1]

(iv) it cannot lose electrons (because) [1]

it receives electrons (from the battery) [1]

OR reduction occurs at the cathode [1]

oxidation at the anode (not cathode) [1]

OR electrons are pushed to rig [1]

preventing it from being oxidised [1]

for comments of the type rusting needs oxygen, it is formed on titanium not iron ONLY
[1]
NOT the idea that titanium is more reactive etc

(v) SET 1
sacrificial protection is a cell
does not need electricity
cathodic protection is electrolysis
cathodic protection needs electricity

SET 2
sacrificial protection needs a more reactive metal (in contact with iron or steel)
this metal corrodes instead of steel
cathodic protection needs an inert electrode accept unreactive or less reactive metal as
an electrode
has to be ONE comment from each set [2]
all comments about oxide layers and coating are neutral

[Total: 12]

UCLES 2007
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Page 5 Mark Scheme Syllabus Paper
IGCSE May/June 2007 0620 3

6 (a) alumina or aluminium oxide [1]

sodium aluminate [1]
iron(III) oxide [1]
filtration or centrifuge NOT conditional [1]

(b) from left to right:

carbon cathode or carbon negative electrode [1]
900 to 1000oC [1]
aluminium [1]
cryolite [1]

(c) (i) Al3+ + 3e = Al [2]

not balanced [1]
Al3+(aq) = 0

(ii) oxygen is formed NOT oxide [1]

reacts with carbon anode [1]

(d) (i) low density or light or resistant to corrosion

accept strength/weight ratio or alloys are strong [1]
strong on its own is neutral

(ii) not attacked or corroded or unreactive

oxide layer
easily shaped or malleable or ductile
any TWO [2]

(iii) for strength or so it does not break or does not sag or can have pylons further apart
[1]
NOT steel is a better conductor
NOT aluminium protects steel from rusting

[Total: 16]

UCLES 2007
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Page 6 Mark Scheme Syllabus Paper
IGCSE May/June 2007 0620 3

7 (a) butanol [1]

no number needed but if one is given it has to be 1

structural formula (all bonds shown) [1]

accept OH NOT HO

ethanoic acid [1]

structural formula (all bonds shown) [1]
accept OH NOT HO
no conseq marking
if all bonds are not shown ( CH3CH2), penalise once

(b) (i) must have correct ester linkage [1]

COND continuation and a group on either side of the ester group [1]

Accept COO

(ii) accept any sensible suggestion

ropes, clothing, bottles, packaging, bags [1]

(c) (i) 8 [1]

(ii) double bond becomes single and 4 bonds per carbon atom [1]
COND a bromine atom on each carbon [1]
C2H4Br2 ONLY [1]
accept a structural formula with hydrogen atoms

(iii) corn oil [1]

(d) 100g of fat react with 86.2g of iodine

884g of fat react with 762 g of iodine [1]
limit 762 x 2
one mole of fat reacts with 762/254 moles of iodine molecules
one mole of fat reacts with 3 moles of iodine molecules [1]

number of double bonds in one molecule of fat is 3 [1]

limit 6
consequential marking allowed provided the number of double bonds is an integer.

[Total: 14]

UCLES 2007