Designation: E 96 00

Standard Test Methods for

Water Vapor Transmission of Materials1
This standard is issued under the fixed designation E 96; the number immediately following the designation indicates the year of original
adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript
epsilon (e) indicates an editorial change since the last revision or reapproval.

This standard has been approved for use by agencies of the Department of Defense.

1. Scope TABLE 1 Metric Units and Conversion FactorsA,B

1.1 These test methods cover the determination of water To Obtain (for the
Multiply by
same test condition)
vapor transmission (WVT) of materials through which the
WVT
passage of water vapor may be of importance, such as paper, g/hm2 1.43 grains/hft2
plastic films, other sheet materials, fiberboards, gypsum and grains/hft2 0.697 g/hm2
plaster products, wood products, and plastics. The test methods Permeance
g/Pasm2 1.75 3 107 1 Perm (inch-pound)
are limited to specimens not over 114 in. (32 mm) in thickness 1 Perm (inch-pound) 5.72 3 108 g/Pasm2
except as provided in Section 9. Two basic methods, the Permeability
Desiccant Method and the Water Method, are provided for the g/Pasm 6.88 3 108 1 Perm inch
1 Perm inch 1.45 3 109 g/Pasm
measurement of permeance, and two variations include service
A
These units are used in the construction trade. Other units may be used in
conditions with one side wetted and service conditions with other standards.
low humidity on one side and high humidity on the other. B
All conversions of mm Hg to Pa are made at a temperature of 0C.
Agreement should not be expected between results obtained by
different methods. That method should be selected which more
nearly approaches the conditions of use. 3. Terminology
1.2 The values stated in inch-pound units are to be regarded 3.1 Definitions of terms used in this standard will be found
as the standard. Metric inch-pound conversion factors for in Terminology C 168, from which the following is quoted:
WVT, permeance, and permeability are stated in Table 1. All water vapor permeabilitythe time rate of water vapor
conversions of mm Hg to Pa are made at a temperature of 0C. transmission through unit area of flat material of unit thickness
1.3 This standard does not purport to address all of the induced by unit vapor pressure difference between two specific
safety problems, if any, associated with its use. It is the surfaces, under specified temperature and humidity conditions.
responsibility of the user of this standard to establish appro- 3.1.1 DiscussionPermeability is a property of a material,
priate safety and health practices and determine the applica- but the permeability of a body that performs like a material
bility of regulatory limitations prior to use. may be used. Permeability is the arithmetic product of per-
2. Referenced Documents meance and thickness.
water vapor permeancethe time rate of water vapor
2.1 ASTM Standards: transmission through unit area of flat material or construction
C 168 Terminology Relating to Thermal Insulating Materi- induced by unit vapor pressure difference between two specific
als2 surfaces, under specified temperature and humidity conditions.
D 449 Specification for Asphalt Used in Dampproofing and 3.1.2 DiscussionPermeance is a performance evaluation
Waterproofing3 and not a property of a material.
D 2301 Specification for Vinyl Chloride Plastic Pressure- 3.2 water vapor transmission ratethe steady water vapor
Sensitive Electrical Insulating Tape4 flow in unit time through unit area of a body, normal to specific
E 691 Practice for Conducting an Interlaboratory Study to parallel surfaces, under specific conditions of temperature and
Determine the Precision of a Test Method5 humidity at each surface.
4. Summary of Test Methods
1
These test methods are under the jurisdiction of ASTM Committee C-16 on 4.1 In the Desiccant Method the test specimen is sealed to
Thermal Insulation and are the direct responsibility of Subcommittee C16.33 on
Thermal Insulation Finishes and Vapor Transmission. the open mouth of a test dish containing a desiccant, and the
Current edition approved April 10, 2000. Published July 2000. Originally assembly placed in a controlled atmosphere. Periodic weigh-
published as E 96 53 T. Last previous edition E 96 94.
2
ings determine the rate of water vapor movement through the
Annual Book of ASTM Standards, Vol 04.06.
3 specimen into the desiccant.
Annual Book of ASTM Standards, Vol 04.04.
4
Annual Book of ASTM Standards, Vol 10.01. 4.2 In the Water Method, the dish contains distilled water,
5
Annual Book of ASTM Standards, Vol 14.02. and the weighings determine the rate of vapor movement

Copyright ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.

1
 E 96
through the specimen from the water to the controlled atmo- shall be between 21 and 32C (70 and 90F), and shall be
sphere. The vapor pressure difference is nominally the same in maintained constant within 61C (6 2F). A temperature of
both methods except in the variation, with extremes of humid- 32C (90F ) is recommended (Note 1). The relative humidity
ity on opposite sides. shall be maintained at 50 6 2 %, (When extremes of humidi-
ties are desired, the temperature shall be 38 6 1C (100 6
5. Significance and Use 1.8F ) The relative humidity shall be 90 6 2 %. Both
5.1 The purpose of these tests is to obtain, by means of temperature and relative humidity shall be measured fre-
simple apparatus, reliable values of water vapor transfer quently7, or preferably recorded continuously. Air shall be
through permeable and semipermeable materials, expressed in continuously circulated throughout the chamber, with a veloc-
suitable units. These values are for use in design, manufacture, ity sufficient to maintain uniform conditions at all test loca-
and marketing. A permeance value obtained under one set of tions. The air velocity over the specimen shall be between 0.02
test conditions may not indicate the value under a different set and 0.3 m-s-1(0.066 and 1ft/s). Suitable racks shall be provided
of conditions. For this reason, the test conditions should be on which to place the test dishes within the test chamber.
selected that most closely approach the conditions of use. NOTE 1Simple temperature control by heating alone is usually made
While any set of conditions may be used and those conditions possible at 32C (90F ). However, it is very desirable to enter the
reported, standard conditions that have been useful are shown controlled space, and a comfortable temperature is more satisfactory for
in Appendix X1. that arrangement. Temperatures of 23C (73.4F) and 26.7C (80F) are in
use and are satisfactory for this purpose. With cyclic control, the average
6. Apparatus test temperature may be obtained from a sensitive thermometer in a mass
of dry sand. The temperature of the chamber walls facing a specimen over
6.1 Test DishThe test dish shall be of any noncorroding water should not be cooler than the water to avoid condensation on the test
material, impermeable to water or water vapor. It may be of specimen.
any shape. Light weight is desirable. A large, shallow dish is
6.3 Balance and WeightsThe balance shall be sensitive to
preferred, but its size and weight are limited when an analytical
a change smaller than 1 % of the weight change during the
balance is chosen to detect small weight changes. The mouth of
period when a steady state is considered to exist. The weights
the dish shall be as large as practical and at least 4.65 in.2(3000
used shall be accurate to 1 % of the weight change during the
mm2x). The desiccant or water area shall be not less than the
steady-state period. For example: -perm
mouth area except if a grid is used, as provided in 12.1, its
(5.7 3 1011kgPa1s1m2) specimen 10 in. (254 mm) square
effective area shall not exceed 10 % of the mouth area. An
at 80F (26.7C) passes 8.6 grains or 0.56 g/day. In 18 days of
external flange or ledge around the mouth, to which the
steady state, the transfer is 10 g. For this usage, the balance
specimen may be attached, is useful when shrinking or warping
must have a sensitivity of 1 % of 10 g or 0.1 g and the weights
occurs. When the specimen area is larger than the mouth area,
must be accurate to 0.1 g. If, however, the balance has a
this overlay upon the ledge is a source of error, particularly for
sensitivity of 0.2 g or the weights are no better than 0.2 g, the
thick specimens. This overlay material should be masked as
requirements of this paragraph can be met by continuing the
described in 10.1 so that the mouth area defines the test area.
steady state for 36 days. An analytical balance that is much
The overlay material results in a positive error, indicating
more sensitive will permit more rapid results on specimens
excessive water vapor transmission. The magnitude of the error
below 1 perm (5.7 3 1011kgPa1s1m2) when the as-
is a complex function of the thickness, ledge width, mouth
sembled dish is not excessively heavy. A light wire sling may
area, and possibly the permeability. This error is discussed by
be substituted for the usual pan to accommodate a larger and
Joy and Wilson.6 This type of error should be limited to about
heavier load.
10 to 12 %. For a thick specimen the ledge should not exceed
34 in. (19 mm) for a 10-in. (254-mm) or larger mouth (square
7. Materials
or circular) or 18in. (3 mm) for a 5-in. (127-mm) mouth (square
7.1 Desiccant and Water:
or circular). For a 3-in. (76-mm) mouth (square or circular) the
7.1.1 For the Desiccant Method, anhydrous calcium chlo-
ledge should not exceed 0.11 in. (2.8 mm) wide. An allowable
ride in the form of small lumps that will pass a No. 8
ledge may be interpolated for intermediate sizes or calculated
(2.36-mm) sieve, and free of fines that will pass a No. 30
according to Joy and Wilson.6 A rim around the ledge (Fig.
(600-m) sieve, shall be used (Note 2). It shall be dried at
X1.1) may be useful. If a rim is provided, it shall be not more
400F (200C) before use.
than 14in. (6 mm) higher than the specimen as attached.
Different depths may be used for the Desiccant Method and NOTE 2If CaCl2 will react chemically on the specimen, an adsorbing
Water Method, but a 34-in. (19-mm) depth (below the mouth) desiccant such as silica gel, activated at 400F (200C), may be used; but
is satisfactory for either method. the moisture gain by this desiccant during the test must be limited to 4 %.
6.2 Test ChamberThe room or cabinet where the as- 7.1.2 For the Water Method, distilled water shall be used in
sembled test dishes are to be placed shall have a controlled the test dish.
temperature and relative humidity. The temperature chosen 7.2 SealantThe sealant used for attaching the specimen to
the dish, in order to be suitable for this purpose, must be highly

6
Joy, F. A., and Wilson, H. G., Standardization of the Dish Method for
7
Measuring Water Vapor Transmissions, National Research Council of Canada, The minimum acceptable is to preform this measurement each time the sample
Research Paper 279, January 1966, p. 263. is weighed.

2
 E 96
resistant to the passage of water vapor (and water). It must not reach equilibrium conditions.
lose weight to, or gain weight from, the atmosphere in an 10. Attachment of Specimen to Test Dish
amount, over the required period of time, that would affect the
test result by more than 2 %. It must not affect the vapor 10.1 Attach the specimen to the dish by sealing (and
pressure in a water-filled dish. Molten asphalt or wax is clamping if desired) in such a manner that the dish mouth
required for permeance tests below 4 perms defines the area of the specimen exposed to the vapor pressure
(2.3 3 1010kgPa1s1m2). Sealing methods are discussed in the dish. If necessary, mask the specimen top surface,
in Appendix X2. exposed to conditioned air so that its exposure duplicates the
mouth shape and size and is directly above it. A template is
8. Sampling recommended for locating the mask. Thoroughly seal the edges
8.1 The material shall be sampled in accordance with of the specimen to prevent the passage of vapor into, or out of,
standard methods of sampling applicable to the material under or around the specimen edges or any portion thereof. The same
test. The sample shall be of uniform thickness. If the material assurance must apply to any part of the specimen faces outside
is of nonsymmetrical construction, the two faces shall be their defined areas. Suggested methods of attachment are
designated by distinguishing marks (for example, on a one- described in Appendix X2.
side-coated sample, I for the coated side and II for the NOTE 3In order to minimize the risk of condensation on the interior
uncoated side). surface of the sample when it is placed in the chamber, the temperature of
the water prior to preparation of the test specimen should be within 62F
9. Test Specimens (61.1C) of the test condition.
9.1 Test specimens shall be representative of the material
11. Procedure for Desiccant Method
tested. When a product is designed for use in only one position,
three specimens shall be tested by the same method with the 11.1 Fill the test dish with desiccant within 14 in. (6 mm) of
vapor flow in the designated direction. When the sides of a the specimen. Leave enough space so that shaking of the dish,
product are indistinguishable, three specimens shall be tested which must be done at each weighing, will mix the desiccant.
by the same method. When the sides of a product are different 11.2 Attach the specimen to the dish (see 10.1) and place it
and either side may face the vapor source, four specimens shall in the controlled chamber, specimen up, weighing it at once.
be tested by the same method, two being tested with the vapor (This weight may be helpful to an understanding of the initial
flow in each direction and so reported. moisture in the specimen.)
9.2 A slab, produced and used as a laminate (such as a 11.3 Weigh the dish assembly periodically, often enough to
foamed plastic with natural skins) may be tested in the provide eight or ten data points during the test. A data point is
thickness of use. Alternatively, it may be sliced into two or the weight at a particular time. The time that the weight is made
more sheets, each being separately tested and so reported as should be recorded to a precision of approximately 1 % of the
provided in 9.4, provided also, that the overlay upon the cup time span between successive weighing. Thus, if weighings are
ledge (6.1) of any laminate shall not exceed 18 in. (3 mm). made every hour, record the time to the nearest 30 s; if
9.3 When the material as used has a pitted or textured recordings are made every day, a time to the nearest 15 min
surface, the tested thickness shall be that of use. When it is would be allowed. At first the weight may change rapidly; later
homogeneous, however, a thinner slice of the slab may be a steady state will be reached where the rate of change is
tested as provided in 9.4. substantially constant. Weighings should be accomplished
9.4 In either case (9.2 or 9.3), the tested overall thickness, if without removal of the test dishes from the controlled atmo-
less than that of use, shall be at least five times the sum of the sphere, but if removal is prescribed necessary, the time the
maximum pit depths in both its faces, and its tested permeance specimens are kept at different conditions, temperature or
shall be not greater than 5 perms (3.3 metric perms). relative humidity, or both, should be kept to a minimum. When
9.5 The overall thickness of each specimen shall be mea- results of water vapor transmission are expected to be less than
sured at the center of each quadrant and the results averaged. .05 perm, a dummy specimen is strongly recommended. Such
Measurement of specimens of 0.125 in. or less in thickness a dummy specimen should be attached to an empty cup in the
shall be made to the nearest 0.0001 in. Measurement of normal manner. The environmental effects of temperature
specimens greater than 0.125 in. in thickness shall be made to variation and buoyancy variability due to barometric pressure
the nearest 0.001 in. fluctuation can be arithmetically tared out of the weighing
9.6 When testing any material with a permeance less than values. This precaution permits earlier and more reliable
0.05 perms or when testing a low permeance material that may achievement of equilibrium conditions. Analyze the results as
be expected to lose or gain weight throughout the test (because prescribed in 13.1.
of evaporation or oxidation), it is strongly recommended that 11.4 Terminate the test or change the desiccant before the
an additional specimen, or dummy, be tested exactly like the water added to the desiccant exceeds 10 % of its starting
others, except that no desiccant or water is put in the dish. weight (Note 1 and Note 3). This limit cannot be exactly
Failure to use this dummy specimen to establish modified dish determined and judgement is required. The desiccant gain may
weights may significantly increase the time required to com- be more or less than the dish weight-gain when the moisture
plete the test. Because time to reach equilibrium of water content of the specimen has changed.
permeance increases as the square of thickness, thick, particu- NOTE 4The WVT of some materials (especially wood) may depend
larly hygroscopic, materials may take as long as 60 days to on the ambient relative humidity immediately before the test. An apparent

3
 E 96
hysteresis results in higher WVT if the prior relative humidity was above 13. Calculation and Analysis of Results
the test condition and vice versa. It is therefore recommended that
specimens of wood and paper products be conditioned to constant weight
13.1 The results of the rate of water vapor transmission may
in a 50 % relative humidity atmosphere before they are tested. Some be determined either graphically or numerically.
specimens may be advantageously preconditioned to minimize the mois- 13.1.1 Dummy SpecimenIf a dummy specimen has been
ture that the specimen will give up to the desiccant. This applies when the used to compensate for variability in test conditions, due to
specimen is likely to have high moisture content or when it is coated on temperature or barometric pressure, or both, the daily recorded
the top (vapor source) side. weights can be adjusted by calculating the weight change from
initial to time of weighing. This adjustment is made by
12. Procedure for Water Method reversing the direction of the dummys weight change, relative
12.1 Fill the test dish with distilled water to a level 34 6 14 to its initial weight, and modifying all the appropriate specimen
in. (19 6 6 mm) from the specimen. The air space thus allowed weight(s) recorded at this time. This permits earlier achieve-
has a small vapor resistance, but it is necessary in order to ment of equilibrium conditions. An alternate procedure, par-
reduce the risk of water touching the specimen when the dish ticulary for tests of long duration and more than six weighings,
is handled. Such contact invalidates a test on some materials is to subtract the arithmetic mean slope of the rate of weight
such as paper, wood, or other hygroscopic materials. The water change of the dummy specimen from the arithmetic mean slope
depth shall be not less than 18 in. (3 mm) to ensure coverage of of each similar specimen to get an effective rate of weight
the dish bottom throughout the test. However, if the dish is of change. These procedures are also desirable if the specimen is
glass, its bottom must be visibly covered at all times but no changing weight due to a curing process while under test.
specific depth is required. Water surges may be reduced in 13.1.2 Graphic AnalysisPlot the weight, modified by the
placing a grid of light noncorroding material in the dish to dummy specimen when used, against elapsed time, and in-
break the water surface. This grid shall be at least 14 in. (6 mm) scribe a curve which tends to become straight. Judgment here
below the specimen, and it shall not reduce the water surface is required and numerous points are helpful. When a straight
by more than 10 % (Note 4). line adequately fits the plot of at least six properly spaced
points (periodic weight changes matching, or exceeding 20 %
NOTE 5For the Water Method, baking the empty dish and promptly of the multiple of 100 times the scale sensitivity), a nominally
coating its mouth with sealant before assembly is recommended. The steady state is assumed, and the slope of the straight line is the
water may be added most conveniently after the specimen is attached,
through a small sealable hole in the dish above the water line.
rate of water vapor transmission.
13.1.3 Numerical AnalysisA mathematical least squares
12.2 Attach the specimen to the dish (see 10.1). Some regression analysis of the weight, modified by the dummy
specimens are likely to warp and break the seal during the test. specimen when used, as a function of time will give the rate of
The risk is reduced by preconditioning the specimen, and by water vapor transmission. An uncertainty, or standard deviation
clamping it to the dish ledge (if one is provided). of this rate, can also be calculated to define the confidence
12.3 Weigh the dish assembly and place it in the controlled band. For very low permeability materials, this method can be
chamber on a true horizontal surface. Follow the procedure used to determine the results after 30 to 60 days when using an
given in 11.3. If the test specimen cannot tolerate condensation analytical balance, with a sensitivity of 61 mg, even if the
on the surface, the dish assembly shall not be exposed to a weight change does not meet the 100 times the sensitivity
temperature that differs by more than 5F (2.8C) from the requirement of 6.3. Specimens analyzed in this manner must be
control atmosphere to minimize the risk of condensation on the clearly identified in the report.
specimen. When results of water vapor transmission are 13.2 Calculate the water vapor transmission, WVT, and
expected to be less than .05 perm, a dummy specimen is permeance as follows:
strongly recommended. Such a dummy specimen should be 13.2.1 Water Vapor Transmission:
attached to an empty cup in the normal manner. The environ- WVT 5 G/tA 5 ~G/t!/A (1)
ment effects of temperature variation and buoyancy variability
due to barometric pressure fluctuation can be arithmetically where:
tared out of the weighing values. This precaution permits In inch-pound units:
earlier and more reliable achievement of equilibrium condi- G = weight change, grains (from the straight line),
tions. Analyze the results as prescribed in 13.1. t = time during which G occurred, h,
G/t = slope of the straight line, grains/h,
12.4 Where water is expected to be in contact with the A = test area (cup mouth area), ft2, and
barrier in service, proceed as in 11.3 except place the dish in an WVT = rate of water vapor transmission, grains/hft2.
inverted position. The dish must be sufficiently level so that
water covers the inner surface of the specimen despite any In metric units:
distortion of the specimen due to the weight of the water. With G = weight change (from the straight line), g,
highly permeable specimens it is especially important to locate t = time, h,
the test dish so that air circulates over the exposed surface at G/t = slope of the straight line, g/h,
the specified velocity. The test dishes may be placed on the A = test area (cup mouth area), m2, and
balance in the upright position for weighing, but the period WVT = rate of water vapor transmission, g/hm2.
during which the wetted surface of the specimen is not covered 13.2.2 Permeance:
with water must be kept to a minimum. Permeance 5 WVT/Dp 5 WVT/S~R1 2 R2! (2)

4
 E 96

where: R1 =
49 % (in chamber),
In inch-pound units: R2 =
0 % (vapor sink), and
Dp = vapor pressure difference, in. Hg, WVT 0.05 g/h 4 0.0645 m2 = 0.775 g/hm2.
=
S = saturation vapor pressure at test temperature, in. Hg, Permeance WVT/DP WVT/S (R1 R2)
=
R1 = relative humidity at the source expressed as a fraction 0.775 g/hm2 3 1 h/3600s 4 46.66 3 102
=
(the test chamber for desiccant method; in the dish for Pa 3 (0.49 0)
water method), and = 9.42 3 108 g/Pasm2
R2 = relative humidity at the vapor sink expressed as a 13.4 Metric units and conversion factor are given in Table 1.
fraction
14. Report
In metric units:
Dp = vapor pressure difference, mm Hg (1.333 3 102 Pa), 14.1 The report shall include the following:
S = saturation vapor pressure at test temperature, mm Hg 14.1.1 Identification of the material tested, including its
(1.333 3 102 Pa), thickness.
R1 = relative humidity at the source expressed as a fraction 14.1.2 Test method used (desiccant or water).
(the test chamber for desiccant method; in the dish for 14.1.3 Test temperature.
water method), and
14.1.4 Relative humidity in the test chamber.
R2 = relative humidity at the vapor sink expressed as a
fraction. 14.1.5 Permeance of each specimen in perms (to two
significant figures).
13.2.3 In the controlled chamber the relative humidity and
temperature are the average values actually measured during 14.1.6 The side of each specimen on which the higher vapor
the test and (unless continuously recorded) these measurements pressure was applied. (The sides shall be distinguished as side
shall be made as frequently as the weight measurements. In the A and side B when there is no obvious difference between
dish the relative humidity is nominally 0 % for the desiccant them. When there is an obvious difference, this difference shall
and 100 % for the water. These values are usually within 3 % also be stated, such as side A waxed and side B unwaxed.).
relative humidity of the actual relative humidity for specimens 14.1.7 The average permeance of all specimens tested in
below 4 perms (2.3 3 107gPa1s1m2) when the required each position.
conditions are maintained (no more than 10 % moisture in 14.1.8 The permeability of each specimen (as limited by
CaCl2 and no more than 1 in. (25 mm) air space above water). 13.3), and the average permeability of all specimens tested.
13.3 Only when the test specimen is homogeneous (not 14.1.9 Include a portion of the plot indicating the section of
laminated) and not less than 12in. (12.5 mm) thick, calculate its the curve used to calculate permeability.
average permeability (perm in.) (metric perm-cm) as follows: 14.1.10 State design of cup and type or composition of
Average permeability 5 permeance 3 thickness (3) sealant.

NOTE 6Example: In a desiccant test that ran 288 h (12 days) on an 15. Precision and Bias 8
exposed area of 100 in.2 (0.0645 m2), it was found that the rate of gain was
substantially constant after 48 h and during the subsequent 240 h, the 15.1 PrecisionTable 2 is based on an interlaboratory tests
weight gain was 12 g. The controlled chamber conditions were measured conducted in 1988 and 1991.8, 9 In 1988 four materials (A, B,
at 89.0F (31.7C) and 49 % relative humidity. C, D) were tested using the dessicant method and the water
method in triplicate. Fifteen laboratories contributed data, with
Required: WVT and permeance
full results secured from four laboratories. In 1991 ten labora-
Calculation (inch-pound units):
tories contributed data for material E, using triplicate speci-
G/t = 12 g 3 15.43 grainsg 4 240 h
= 0.771 grains/h, mens, again using both the dessicant method and the water
A = 100 in.2 3 1 ft2144 in.2 = 0.695 ft2, method.
S = 1.378 in. Hg (from standard references 15.1.1 Test results were analyzed using Practice E 691.
tables), 15.2 BiasThis test method has no bias because water
R1 = 49 % (in chamber), vapor transmission of materials is defined in terms of this test
R2 = 0 % (vapor sink), and method.
WVT = 0.771 grains/h 4 0.694 ft2 = 1.11 grains/
ft2h. 16. Keywords
Permeance = WVT/DP = WVT/S (R1 R2)
= 1.11 grains/ft2h4 1.378 in. Hg (0.49 0) 16.1 permeability; plastics (general); plastic sheet and film;
= 1.64 grains/ft2hin. Hg = 1.64 perms sheet material; thermal-insulating materials; thermal insulation
permeability films; water vapor transmission (WVT)
Calculation (metric units):
G/t = 12 g/240 h = 0.05 g/h,
A = 0.0645 m2,
S = 35 mm Hg (from reference tables), 8
Supporting data have been filed at ASTM Headquarters. Request RR: C-16-
= 35 mm Hg 3 1.333 3 10 2 Pa/mm 1014.
9
Available from E. I. DuPont de Nemours & Co., Inc., Polymer Products Dept.,
Hg = 46.66 3 102 Pa,
Wilmington, DE 19898.

5
 E 96
TABLE 2 Precision Results from Interlaboratory Testing
For Desiccant Method at 73.4F:
WVT (mean), RepeatabilityA ReproducibilityA
Material Thickness, in.
perm S CV % LSD S CV % LSD
A 0.001 0.606 0.0166 2.70 0.047 0.098 15.0 0.278
B 0.0055 0.0129 0.0028 22.1 0.008 0.0055 42.6 0.016
C 0.5 0.0613 0.0044 7.22 0.012 0.0185 30.6 0.052
D 1.0 0.783 0.0259 3.30 0.073 0.0613 7.8 0.174
E 0.014 0.0461 0.0023 4.99 0.007 0.0054 11.7 0.015
For Water Method at 73.4F:
WVT (mean), RepeatabilityA ReproducibilityA
Material Thickness, in.
perm S CV % LSD S CV % LSD
A 0.001 0.715 0.0134 1.95 0.039 0.156 21.9 0.44
B 0.0055 0.0157 0.0022 13.8 0.0062 0.0021 19.4 0.006
C 0.5 0.097 0.0055 5.7 0.016 0.0195 20.9 0.055
D 1.0 1.04 0.0192 1.8 0.054 0.217 20.9 0.62
E 0.014 0.0594 0.0034 5.7 0.010 0.0082 13.8 0.023
A
For this data,

S = standard deviation,
CV = percent coefficient of variation (S 3 100/mean), and
LSD = least significant difference between two individual test results based on a 95 % confidence level = 2 =2S .
B
Material B was Teflon9 PTFE fluorocarbon resin brand of tetrafluoroethylene. It was extremely difficult to provide a seal to this sample, which accounts for the poor
repeatability.

APPENDIX

(Nonmandatory Information)

X1. STANDARD TEST CONDITIONS

X1.1 Standard test conditons that have been useful are: X1.1.4 Procedure CDesiccant Method at 90F (32.2C).
X1.1.1 Procedure ADesiccant Method at 73.4F (23C). X1.1.5 Procedure DWater Method at 90F (32.2C).
X1.1.2 Procedure BWater Method at 73.4F (23C). X1.1.6 Procedure EDesiccant Method at 100F (37.8C).
X1.1.3 Procedure BWInverted Water Method at 73.4F
(23C).

X2. CUP DESIGN AND SEALING METHODS

X1.2 An ideal sealing material has the following properties: are met (Note A2). Molten asphalt or wax is required for
X1.2.1 Impermeability to water in either vapor or liquid permeance tests below 4 perms (2.6 metric perms). Tests to
form. determine sealant behavior should include:
X1.2.2 No gain or loss of weight from or to the test chamber X1.2.8.1 An impervious specimen (metal) normally sealed
(evaporation, oxidation, hygroscopicity, and water solubility to the dish and so tested, and
being undersirable). X1.2.8.2 The seal normally assembled to an empty dish
X1.2.3 Good adhesion to any specimen and to the dish with no specimen and so tested.
(even when wet).
X1.2.4 Complete conformity to a rough surface. X1.3 The following materials are recommended for general
X1.2.5 Compatibility with the specimen and no excessive use when the test specimen will not be affected by the
penetration into it. temperature of the sealant:
X1.2.6 Strength or pliability (or both).
X1.2.7 Easy handleability (including desirable viscosity and X1.3.1 Asphalt, 180 to 200F (82 to 93C) softening point,
thermal of molten sealant). meeting the requirements of Specification D 449, Type C.
X1.2.8 Satisfactory sealants possess these properties in Apply by pouring.
varying degrees and the choice is a compromise, with more X1.3.2 Beeswax and rosin (equal weights). A temperature of
tolerance in items at the beginning of this list for the sake of 275F (135C) is desirable for brush application. Pour at lower
those at the latter part of the list when the requirements of 7.2 temperature.

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X1.3.3 Microcrystalline wax10 (60 %), mixed with refined X1.5.1.2 SealantAsphalt (see X1.3.1 used at the proper
crystalline paraffin wax (40 %). pouring consistency of 375 to 450F (179 to 232C).
X1.5.1.3 Melting Pot for the asphalt, electrically heated,
X1.4 The materials listed in X1.4.1 are recommended for with one dimension greater than 1138 in. (289 mm).
particular uses such as those shown in Fig. X1.1. The suggested X1.5.1.4 Small Ladle for pouring.
procedure described in X1.4.2 applies to an 11-38-in. (289- X1.5.2 ProcedureMark the 1138-in. (289-mm) square
mm) square specimen if its permeance exceeds 4 perms (2.6 specimen with a line at an equal distance from each edge, so
metric perms) (limited by evaporation of sealants). that the area enclosed by the lines is as nearly as possible a
X1.4.1 Materials: 10-in. (254-mm) square. The template may be used for
X1.4.1.1 Aluminum foil, 0.005 in. (0.125 mm) minimum marking. Dip each edge of the specimen in molten asphalt up
thickness. to the line, so that the test area is defined and all edges are
X1.4.1.2 Tape, meeting the requirements of Specification coated with a heavy layer of asphalt. Place the specimen over
D 2301, vinyl chloride plastic pressure-sensitive, electrical the pan containing water or desiccant. Lightly oil the template
insulating tape. or coat with petroleum jelly on its outer side, and place on the
X1.4.1.3 Cement, contact bond, preferably rubber base. specimen. Pour molten asphalt into the space between the
X1.4.2 Procedure: template and the rim of the pan. After the asphalt has cooled for
X1.4.2.1 Step 1Seal aluminum foil around edges of speci- a few minutes, the template should be easily removable.
men, leaving a 100-in.2(0.0654-m2) exposed test area on each
side. Use contact bond cement as directed by the manufacturer. X1.6 Hot wax may be applied like asphalt. It may also be
X1.4.2.2 Step 2Spread sealant on inside of rim and ledge. applied (freely) with a small brush. Its lower working tempera-
Place desiccant (dry), or water and surge control material (wet) ture may be advantageous when a specimen contains moisture.
in pan. Press specimen in place. Avoid squeezing compound X1.7 Several designs for dishes with supporting rings and
into the test area. flanges are shown in Fig. X1.2. Various modifications of these
X1.4.2.3 Step 3Coat outside of rim and bottom of ledge designs may be made provided that the principle of prevention
with contact bond cement, and place foil strips from edge of of edge leakage by means of a complete seal is retained. The
template, around rim, and bottom of ledge. dishes may be constructed of any rigid, impermeable,
X1.5 A method of using hot asphalt, as applied to a 10-in. corrosion-resistant material, provided that they can be accom-
(254-mm) square-mouth dish with ledge and rim, is as follows: modated on the available analytical balance. A lightweight
metal, such as aluminum or one of its alloys, is generally used
X1.5.1 Apparatus: for larger-size dishes. In some cases when an aluminum dish is
X1.5.1.1 TemplateA square frame of brass or steel, 316in. employed and moisture is allowed to condense on its surface,
(5 mm) thick and 34 in. (19 mm) deep. The 316-in. (5-mm) there may be appreciable oxidation of the aluminum with a
thickness is tapered to zero at the bottom of the frame where it resulting gain in weight. Any gain in weight will ordinarily
will touch the test specimen and maintain a 10-in. (254-mm) depend on the previous history of the dish and the cleanness of
square test area. the surface. An empty dish carried through the test procedure
as a control will help to determine whether any error may be
10
Grade Nos. 2305 or 2310 of the Mobil Oil Corp., or their equivalent, have been expected from this cause. When aluminum dishes are used for
found satisfactory for this purpose. the water methods, a pressure may develop inside the assembly

FIG. X1.1 Apparatus for Water Vapor Transmission Tests of Large Thick Specimens

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FIG. X1.3 Template Suitable for Use in Making the Wax Seals on
Test Dishes

FIG. X1.2 Several Types of Dishes for Water Vapor Transmission

Tests of Materials in Sheet Form template to admit air, and petrolatum applied to the beveled
edge of the template facilitate its removal after sealing the test
specimen to the dish. In use, the template is placed over the test
during a test due to corrosion. This can cause seal failure or specimen and when it is carefully centered with the dish
otherwise affect the result. Where this is a problem, it can be opening, molten wax is flowed into the annular space surround-
overcome by providing inside the dish a protective coating of ing the beveled edge of the template. As soon as the wax has
baked-on epoxy resin or similar material. Dishes with flanges solidified, the template is removed from the sheet with a
or rings that project from the inner walls of the dish are to be twisting motion. The outside flange of the dish should be high
avoided, as such projections influence the diffusion of the enough to extend over the top of the specimen, thus allowing
water vapor. The depth of the dish for the water procedures is the wax to completely envelop the edge.
such that there is a 0.80 6 0.20 in. (20 6 5-mm) distance X1.7.4 Gasketed types of seals are also in use on appropri-
between the water surface and the under surface of the ately designed dishes. These simplify the mounting of the
specimen, with a water depth of about 0.20 in. (5 mm). specimen, but must be used with caution, since the possibility
X1.7.1 For the desiccant-in-dish procedures, the dishes need of edge leakage is greater with gasketed seals than with wax
not be as deep as those required for the water-in-dish proce- seals. Gasketed seals are not permitted for the measurement of
dures. The desiccant is within 14 in. (6 mm) of the under permeance less than 44 perms (2.3 3 107 gPa1s1m2). As a
surface, and a minimum depth of only 12 in. (12 mm) of further precaution when gasketed seals are used instead of
desiccant is required. preferred sealants, a blank test run is suggested using glass or
X1.7.2 The dishes shown in Fig. X1.2 require a molten seal. metal as a dummy specimen.
X1.7.3 A template such as is shown in Fig. X1.3 is usually X1.7.5 A suitable weighing cover consists of a circular disk
used for defining the test area and effecting the wax seal. It of aluminum 132 to 332 in. (0.8 to 2.4 mm) in thickness
consists of a circular metal dish 18in. (3.18 mm) or more in provided with a suitable knob in the center for lifting. The
thickness with the edge beveled to an angle of about 45. The cover fits over the test specimen when assembled and makes
diameter of the bottom (smaller) face of the template is contact with the inside beveled surface of the wax seal at, or
approximately equal to, but not greater than, the diameter of just above, the plane of the specimen. The cover is free of sharp
the effective opening of the dish in contact with the specimen. edges which might remove the wax and is numbered or
Small guides may be attached to the template to center it otherwise identified to facilitate its exclusive use with the same
automatically on the test specimen. A small hole through the dish.

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