Eastman 25 MSDS

Download as pdf or txt
Download as pdf or txt
You are on page 1of 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

SECTION 1. IDENTIFICATION
Product name

Product code

Eastman(TM) Turbo Oil 25


: P3435602

Manufacturer or supplier's details


Company name of supplier
: Eastman Chemical Company
Address

200 South Wilcox Drive


Kingsport TN 37660-5280

Telephone

(423) 229-2000

Emergency telephone number

: CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321


For emergency transportation information, in the United States:
call CHEMTREC at 800-424-9300 or call 423-229-2000.

Recommended use of the chemical and restrictions on use


Recommended use
: Lubricant
Restrictions on use

None known.

SECTION 2. HAZARDS IDENTIFICATION


GHS Classification
Skin sensitisation

: Category 1

GHS label elements


Hazard pictograms

Signal word

: Warning

Hazard statements

: H317 May cause an allergic skin reaction.

Precautionary statements

: Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
1 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Chemical name
N-Phenylbenzenamine reaction products with
2,4,4-trimethylpentene
Phenothiazine
Tricresyl phosphate
1,4-dihydroxy-9,10-anthracenedione

CAS-No.
68411-46-1
92-84-2
1330-78-5
81-64-1

Concentration (% w/w)
<5
<1
<1
< 0.1

SECTION 4. FIRST AID MEASURES


If inhaled

: If breathed in, move person into fresh air.


If breathing is difficult, give oxygen.
Consult a physician if necessary.
Persons who have inhaled vapours or smoke fumes have to
be put under medical observation for at least 48 hours, due to
the delayed appearance of poisoning.

In case of skin contact

: Wash off immediately with soap and plenty of water while


removing all contaminated clothes and shoes.
Wash contaminated clothing before reuse.
If symptoms persist, call a physician.

In case of eye contact

: In case of contact, immediately flush eyes with plenty of water


for at least 15 minutes.
Get medical attention if symptoms occur.

If swallowed

: Rinse mouth.
Call a physician or poison control centre immediately.
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.

Most important symptoms


and effects, both acute and
delayed

: Prolonged skin contact may defat the skin and produce dermatitis.
Contact with hot product will cause thermal burns.
Inhalation of thermal decomposition products may lead to
adverse effects including pulmonary edema.
May cause an allergic skin reaction.

Notes to physician

: Treat symptomatically.

2 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

SECTION 5. FIREFIGHTING MEASURES


Suitable extinguishing media

: Water spray
Foam
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing
media

: Do not use a solid water stream as it may scatter and spread


fire.

Specific hazards during firefighting

: Hazardous combustion products


carbon dioxide, carbon monoxide
oxides of phosphorus

Further information

: In case of fire and/or explosion do not breathe fumes.


Use water spray to cool unopened containers.
Prevent fire extinguishing water from contaminating surface
water or the ground water system.

Special protective equipment


for firefighters

: Wear an approved positive pressure self-contained breathing


apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures

: Ventilate the area.


Material can create slippery conditions.
Use personal protective equipment.
Local authorities should be advised if significant spillages
cannot be contained.

Environmental precautions

: Avoid release to the environment.

Methods and materials for


containment and cleaning up

: Contain spillage, soak up with non-combustible absorbent


material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE


Advice on safe handling

: Handle in accordance with good industrial hygiene and safety


practice.
Wear protective gloves/ protective clothing/ eye protection/
face protection.
Do not get in eyes.
Do not get on skin or clothing.
Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the
workplace.
Do not breathe vapours or spray mist.
Use only in area provided with appropriate exhaust ventilation.
Drain or remove substance from equipment prior to break-in
3 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

or maintenance.
Conditions for safe storage

: Keep containers tightly closed in a cool, well-ventilated place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Components with workplace control parameters
Components

CAS-No.

Phenothiazine

92-84-2

Value type
(Form of
exposure)
TWA
TWA
TWA

Control parameters / Permissible


concentration
5 mg/m3
5 mg/m3
5 mg/m3

Basis

ACGIH
NIOSH REL
OSHA P0

Hazardous components without workplace control parameters


Components
N-Phenylbenzenamine reaction products with 2,4,4trimethylpentene
Tricresyl phosphate
Engineering measures

CAS-No.
68411-46-1

1330-78-5
: Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust
ventilation, or other engineering controls to maintain airborne
levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level.

Personal protective equipment


Respiratory protection
: Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Hand protection
Material

: Recommended gloves:

Material

: Nitrile rubber

Remarks

: Wear suitable gloves.

Eye protection

: Safety glasses with side-shields


Safety goggles

Protective measures

: Ensure that eye flushing systems and safety showers are


located close to the working place.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

4 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Appearance

: liquid

Colour

: amber

Odour

: No data available

Odour Threshold

: not determined

Melting point/freezing point

: -60 C

Flash point

: 246 C
Method: Cleveland open cup

Evaporation rate

: not determined

Vapour pressure

: not determined

Relative density

: 0.995

Solubility(ies)
Water solubility

: insoluble

Viscosity
Viscosity, kinematic

: 23 - 30 mm2/s (40 C)
4.9 - 5.4 mm2/s (100 C)

Explosive properties

: Classification Code: Not classified

Oxidizing properties

: Not classified

SECTION 10. STABILITY AND REACTIVITY


Reactivity

: None reasonably foreseeable.

Chemical stability

: Stable under normal conditions.

Conditions to avoid

: Keep away from sources of ignition - No smoking.

Incompatible materials

: Strong oxidizing agents

Hazardous decomposition
products

: Emits acrid smoke and fumes when heated to decomposition.

SECTION 11. TOXICOLOGICAL INFORMATION


Acute toxicity
Not classified based on available information.
Product
Acute oral toxicity

: LD50 Oral (Rat): > 10,000 mg/kg

5 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Acute dermal toxicity

: LD50 Dermal (Rabbit): > 3,160 mg/kg


Assessment: The substance or mixture has no acute dermal
toxicity

N-Phenylbenzenamine reaction products with 2,4,4-trimethylpentene:


Acute oral toxicity
: LD50 Oral (Rat): > 5,000 mg/kg
Acute dermal toxicity

: LD50 Dermal (Rabbit): > 2,000 mg/kg

Tricresyl phosphate:
Acute oral toxicity

: LD50 Oral (Rat): > 5,000 mg/kg

Acute inhalation toxicity

: LC50 (Rat): > 5.2 mg/l


Exposure time: 4 h

Acute dermal toxicity

: LD50 Dermal (Rabbit): > 10,000 mg/kg

Phenothiazine:
Acute oral toxicity

: Assessment: Harmful if swallowed.

Skin corrosion/irritation
Not classified based on available information.
Product
Species: Rabbit
Assessment: Not classified as hazardous.
Result: slight

N-Phenylbenzenamine reaction products with 2,4,4-trimethylpentene:


Species: Rabbit
Assessment: Not classified
Result: slight
Tricresyl phosphate:
Species: Rabbit
Exposure time: 24 h
Assessment: Not classified as hazardous.
Result: Non-irritating to the skin.
Serious eye damage/eye irritation
Not classified based on available information.
Product
Species: Rabbit
Result: slight
Assessment: Not classified

N-Phenylbenzenamine reaction products with 2,4,4-trimethylpentene:


6 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Species: Rabbit
Result: slight
Assessment: Not classified
Tricresyl phosphate:
Species: Rabbit
Assessment: Not classified
Respiratory or skin sensitisation
Skin sensitisation: May cause an allergic skin reaction.
Respiratory sensitisation: Not classified based on available information.
Product
Test Type: OECD 429: LLNA
Species: Mouse
Assessment: May cause sensitisation by skin contact.
Result: sensitizing

Tricresyl phosphate:
Test Type: Skin Sensitization
Assessment: Not classified
Phenothiazine:
Test Type: Skin sensitisation
Assessment: May cause sensitisation by skin contact.
Germ cell mutagenicity
Not classified based on available information.
Product
Genotoxicity in vitro

Genotoxicity in vivo

Tricresyl phosphate:
Genotoxicity in vitro

Genotoxicity in vivo

: Test Type: Mutagenicity


Result: Based on available data, the classification criteria are
not met.
: Test Type: Mutagenicity
Result: Based on available data, the classification criteria are
not met.

: Test Type: various


Result: Based on available data, the classification criteria are
not met.
Remarks: Not classified
: Test Type: various
Result: Based on available data, the classification criteria are
not met.

7 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Carcinogenicity
Not classified based on available information.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA

No component of this product present at levels greater than or


equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP

No component of this product present at levels greater than or


equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.
Product
Effects on foetal development
Reproductive toxicity - Assessment

Tricresyl phosphate:
Effects on fertility

: Remarks: No known significant effects or critical hazards.


Read-across from a similar material
: No toxicity to reproduction

:
Species: Rat
Remarks: Suspected of damaging fertility.

Effects on foetal development

: Species: Rat
Remarks: Suspected of damaging the unborn child.

Reproductive toxicity - Assessment

: May damage the unborn child. Suspected of damaging fertility.

STOT - single exposure


Not classified based on available information.
Product
Assessment: Based on available data, the classification criteria are not met.

Tricresyl phosphate:
Assessment: Based on available data, the classification criteria are not met.
STOT - repeated exposure
Not classified based on available information.
Product
8 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure.

N-Phenylbenzenamine reaction products with 2,4,4-trimethylpentene:


Assessment: Not classified
Tricresyl phosphate:
Assessment: Based on available data, the classification criteria are not met.
Repeated dose toxicity

Tricresyl phosphate:
Species: Rat
NOEL: 300 mg/l
Phenothiazine:
Assessment: The substance or mixture is classified as specific target organ toxicant, repeated
exposure, category 2.
Aspiration toxicity
Not classified based on available information.
Product
Not classified

Tricresyl phosphate:
Not classified
Experience with human exposure
Product
Inhalation

: Remarks: None known.

Skin contact

: Remarks: May cause an allergic skin reaction.


Prolonged skin contact may defat the skin and produce dermatitis.

Eye contact

: Remarks: None known.

Ingestion

: Remarks: None known.

SECTION 12. ECOLOGICAL INFORMATION


Ecotoxicity
Product:
9 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Toxicity to fish

: LC50 (Fish):
Exposure time: 96 h
Remarks: Not classified as hazardous.
(limit of solubility in fresh water)
Read-across from a similar material

Toxicity to daphnia and other


aquatic invertebrates

: EC50 (Daphnia magna (Water flea)):


Exposure time: 48 h
Remarks: Not classified as hazardous.
(limit of solubility in fresh water)
Read-across from a similar material

Toxicity to algae

: NOEC (Pseudokirchneriella subcapitata (algae)):


Exposure time: 72 h
Remarks: Not classified as hazardous.
(limit of solubility in fresh water)
Read-across from a similar material

Toxicity to fish (Chronic toxicity)

: NOEC (Fish):
Remarks: Not classified as hazardous.
(limit of solubility in fresh water)
Read-across from a similar material

Toxicity to daphnia and other


aquatic invertebrates (Chronic toxicity)

: NOEC:
Remarks: Not classified as hazardous.
(limit of solubility in fresh water)
Read-across from a similar material

Ecotoxicology Assessment
Acute aquatic toxicity

: This product has no known ecotoxicological effects.

Chronic aquatic toxicity

: This product has no known ecotoxicological effects.

Components:
Tricresyl phosphate:
Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 0.6 mg/l


Exposure time: 96 h

Toxicity to daphnia and other


aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 0.146 mg/l


Exposure time: 48 h

M-Factor (Acute aquatic toxicity)

: 1

Phenothiazine:
M-Factor (Acute aquatic toxicity)
M-Factor (Chronic aquatic
toxicity)
Ecotoxicology Assessment
Acute aquatic toxicity

: 1

: 1

: Very toxic to aquatic life.


10 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Chronic aquatic toxicity

: Very toxic to aquatic life with long lasting effects.

Persistence and degradability


Product:
Biodegradability

: Remarks: Expected to be biodegradable

Biochemical Oxygen Demand (BOD)

: Remarks: No data available

Chemical Oxygen Demand


(COD)

: Remarks: No data available

Bioaccumulative potential
Product:
Bioaccumulation

Components:
Tricresyl phosphate:
Bioaccumulation
Partition coefficient: noctanol/water

: Remarks: Mixture
Not applicable

: Bioconcentration factor (BCF): 2,000


Remarks: No information available.
: Pow: 860,000
log Pow: 5.93

Mobility in soil
Components:
Tricresyl phosphate:
Distribution among environmental compartments

: log Koc: 4.31

Other adverse effects


Product:
Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

SECTION 13. DISPOSAL CONSIDERATIONS


Disposal methods
Waste from residues

: Dispose of in accordance with local regulations.


11 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

SECTION 14. TRANSPORT INFORMATION


International Regulation
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
SARA 311/312 Hazards

: Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

: This material does not contain any chemical components with


known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act


This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
The components of this product are reported in the following inventories:
12 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

TSCA

: On TSCA Inventory

DSL

: On the inventory, or in compliance with the inventory

AICS

: On the inventory, or in compliance with the inventory

ENCS

: On the inventory, or in compliance with the inventory

KECI

: On the inventory, or in compliance with the inventory

PICCS

: Not listed

IECSC

: On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION


Full text of other abbreviations
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and
of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan
13 / 14

SAFETY DATA SHEET

Eastman(TM) Turbo Oil 25


Version
5.2

Revision Date:
07/28/2016

SDS Number:
150000094084

Date of last issue: 07/27/2016


Date of first issue: 02/28/2014

SDSUS / PRD / 0001

Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative
Further information
NFPA:

HMIS III:
Flammability

Health

Instability

FLAMMABILITY

PHYSICAL HAZARD

0 = not significant, 1 =Slight,


2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Special hazard.

Sources of key data used to


compile the Safety Data
Sheet
Revision Date

HEALTH

: www.EastmanAviationSolutions.com

: 07/28/2016

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
US / EN

14 / 14

You might also like