SAFETY DATA SHEET

According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)

________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

1. Identification of the substance & the company

Chemical name Phenol, isobutylenated, phosphate (3:1)

Synonym(s) tert-butylphenyl diphenyl phosphate

Chemical family Aryl phosphate

Type of product and use Lubricant Additive

Supplier ICL-IP America Inc.

622 Emerson Road - Suite 500St Louis, Missouri 63141, USA
Tel:(314)983-7884 Fax:(314)983-7607
e-mail:[email protected]

Emergency Telephone Chemtrec (800)424-9300

Medical: PROSAR 1-888-875-1685 (24HRS)

2. Hazards identification
OSHA HAZARDS No OSHA hazards

Labels and other form of warning

Symbol(s)

NFPA Ratings (Scale 0-4) Health = 1, Fire = 1, Reactivity = 0.

HMIS Ratings (Scale 0-4) Health = 1, Fire =1, Reactivity = 0.

3. Composition / information on ingredients

Components CAS No. Weight %
t-Butylphenyl diphenyl phosphate 56803-37-3 40 - 46
Bis(t-butylphenyl)phenyl phosphate 65652-41-7 12 - 18
Tri(t-butylphenyl) phosphate 78-33-1 1-3
Triphenyl phosphate 115-86-6 42 - 48

Butylated triphenyl phosphate is multi constituent substance can also be described as: (CAS No. 68937-40-6)
Phenol, isobutylated, phosphate (3:1)

4. First-aid measures

{ Page 1 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

Eye contact Holding the eyelids apart, flush eyes promptly with copious flowing water for at
least 20 minutes. Get medical attention immediately.

Skin contact Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of
water for at least 15 minutes. Wash clothing before reuse. Get medical attention if
irritation persists.

Inhalation In case of inhalation, remove person to fresh air. Keep him quiet and warm. Apply
artificial respiration if necessary and get medical attention immediately.

Ingestion If swallowed, wash mouth thoroughly with plenty of water. Get medical attention
immediately.
-------------------------------------------------------------------------------------
NOTE: Never give an unconscious person anything to drink
--------------------------------------------------------------------------------------

Most important symptoms and effects, acute or delayed

None known

Notes to the physician Treat symptomatically and supportively.

No specific antidote.

5. Fire - fighting measures

Suitable extinguishing media Material is not combustible. Use extinguishing media appropriate to surrounding
fire conditions.

Unusual fire and explosion

hazards When heated to decomposition, may release poisonous and corrosive fumes of
carbon dioxide, carbon monoxide and phosphorus oxides. The material is not
sensitive to ignition from static discharge.

Fire fighting procedure Fire fighters should wear full protective clothing and self-contained breathing
apparatus (SCBA). Contain runoff to prevent entry into water or drainage systems.

6. Accidental release measures

Personal precautions Wear appropriate safety clothing and eye/face protection (see Section 8).

Methods for cleaning up Soak up with sand or other suitable absorbant and dispose of as solid waste.
Collect in suitable and properly labeled containers. Ventilate area and wash spill
site after material pickup is complete.

Environmental precautions Prevent product from entering drains, ditches and rivers.

{ Page 2 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

7. Handling and storage

Handling Avoid bodily contact. Keep containers tightly closed.

Storage Store in a dry, cool, well-ventilated area away from incompatible materials (see
"materials to avoid"). Maximum recommended storage temperature of 65C
(149F) Crystallizes at temperatures below 4.4C (40F).

8. Exposure controls / personal protection

Exposure Limits :

Components ACGIH-TLV Data OSHA (PEL) Data

t-Butylphenyl diphenyl phosphate Not determined Not determined
56803-37-3
Bis(t-butylphenyl)phenyl phosphate Not determined Not determined
65652-41-7
Tri(t-butylphenyl) phosphate Not determined Not determined
78-33-1
Triphenyl phosphate 3 mg/m3 3 mg/m3
115-86-6

Ventilation requirements Ventilation must be sufficient to maintain atmospheric concentration below

recommended exposure limit.

Personal protective equipment:

- Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.
- Hand protection Chemical safety gloves
- Eye protection Chemical splash goggles and/or face shield if splash hazard exists
- Skin and body protection Body covering clothes and boots.

Hygiene measures Do not eat, smoke or drink where material is handled, processed or stored. Wash
hands thoroughly after handling and before eating or smoking. Safety shower and
eye bath should be provided.

9. Physical and chemical properties

Appearance Clear, transparent liquid
Odor None
Melting point/range -21C
Boiling point/range >400C (762mmHg)
Pour point -26.11C (-15 F)
Flash point >80C (closed cup)

{ Page 3 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

Flammable/Explosion limits Not flammable/Not explosive

Vapor pressure 1.08x10(-3)Pa (20C)
Density 1.176 g/mL (25C)
- Solubility in water 3.2 mg/l at 20C
Auto-ignition temperature Not self-ignitable
Decomposition temperature >234C
Viscosity 63.6 cP (25C)
Explosive properties There are no chemical groups associated with explosive properties present in the
molecule
Oxidising properties The structure indicates non oxidizing properties

10. Stability and reactivity

Stability Stable under normal conditions
Conditions to avoid Exposure to moisture.
Materials to avoid Strong oxidizers, strong acids and strong alkalis.
It hydrolyzes slowly at normal temperatures in acidic or alkaline aqueous
solutions.
Hazardous decomposition Carbon dioxide and carbon monoxide
products Phosphorus oxides,

11. Toxicological information

Acute toxicity:

- Rat oral LD50 > 5000 mg/kg

- Rabbit dermal LD50 > 2000 mg/kg

- Rat inhalation LC50 > 0.4 mg/l

- Eye irritation (rabbit) Not irritant

- Dermal irritation (rabbit) Not irritant

Dermal sensitization Sensitiser (Local lymph node assay in the mouse)

Based on the favourable outcome of the Human Patch test and the epidimiological
information that no incidences of sensitization are known at the production facility
for many years related to the use and production of the substance, it was decided
not to classify for sensitization

Sub-chronic toxicity:
- NOEL 100 ppm (13 weeks oral rat)

Chronic toxicity No data available

{ Page 4 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

Mutagenicity No evidence of genotoxic or mutagenic activity was noted in Ames tests, the
mouse lymphoma and chromosome aberration tests.

Carcinogenicity Not classified by IARC

Not included in NTP 12th Report on Carcinogens
Not classified as a carcinogen by USA OSHA

Reproductive toxicity Butylated triphenyl phosphate did not demonstrate reproductive toxicity.
In a rat reproduction study, male and female animals received either 50, 250 or
1000 mg/kg/day for several weeks after which they mated. There was no
reproductive toxicity observed at any dose level. Diagnostic pathology confirmed
no alterations to the reproductive organs. There was no effect on mating index,
litter size, survival of the offspring or on any other measured parameter.

Teratogenicity Not teratogenic when administered orally up to 1000 mg/kg

Neurotoxicity No signs of acute delayed neurotoxicity when administered orally to hens at 23

g/kg

12. Ecological information

Aquatic toxicity :

- 96 Hour-LC50, Fish 0.8 mg/l (Ictalurus punctatus)

- 48 Hour-EC50, Daphnia magna 202 g/L

Biodegradation Readily biodegradable

Bioaccumulative potential The wholefish BCF was found to be 1850.

Note: Not considered to be PBT or vPvB

13. Disposal considerations

Waste disposal Observe all federal, state and local environmental regulations when disposing of
this material

14. Transportation information

UN No. 3082

{ Page 5 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

DOT Proper shipping name: Environmentally hazardous substances, liquid , n.o.s

(triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10%
to 48% triphenyl phosphates)
Class: 9 - Miscellaneous Hazardous Material
Label: 9
Packing Group: III

Not regulated for surface and air transport in non-bulk (<119 gallons) packagings.
(contains triphenyl phosphate which is a Marine Pollutant per 49CFR 172.101
Appendix B)

IMDG Proper shipping name: Environmentally hazardous substance, liquid, n.o.s

(triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10%
to 48% triphenyl phosphates)
Class: 9 - Miscellaneous Dangerous Substances and Articles
Label: 9
Mark: MARINE POLLUTANT
Packing Group: III

ICAO/IATA Proper shipping name: Environmentally hazardous substance, liquid , n.o.s

(triphenyl phosphate, tert-butylated triphenyl phosphate mixtures containing 10%
to 48% triphenyl phosphates)
Class: 9
Hazard label(s): Miscellaneous
Packing group: III
Marking: Environmentally hazardous substance

15. Regulatory information

USA Reported in the EPA TSCA Inventory.

- SARA 313 This product does not contain a chemical listed at or above de minimis
concentrations

- Massachusetts Right-to-Know Listed (Triphenyl phosphate)

Hazardous Substances list
- New Jersey Right-to-Know Listed (Triphenyl phosphate)
Hazardous Substances list
- Pennsylvania Right-to-Know Listed (Triphenyl phosphate)
Hazardous Substances list

- Rhode Island Right-to-Know Listed (Triphenyl phosphate)

Hazardous Substances list

{ Page 6 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

- California-Prop 65 This product does not contain any ingredient known to the State of California to
cause cancer or reproductive toxicity as listed under the State drinking Water and
Toxic Enforcement Act of 1986.

- Waste Classifications This material does not meet RCRA`s characteristic definition of ignitability,
corrosivity, or reactivity, and is not listed in 40CFR 261.33.

- Workplace Classification This product is considered hazardous under the OSHA Hazard Communication
Standard (29CFR 1910.1200)

Canada Listed in DSL

-WHMIS hazard class Non-controlled

EU Reported in EINECS

Japan Listed in ENCS

Australia Listed in AICS

New Zealand Inventory Listed in NZIoC

China
- China inventory Listed in IECSC

Korea Listed in ECL

Taiwan Listed

Philippines Listed in PICCS

16. Other information

This data sheet contains changes from the previous version in section(s)
1, 2 (US), 8 (REACH)

Health, Safety & Environment Policy

We will strive to ensure that our operations and products meet the needs of the present global community without
compromising the ability of future generations to meet their needs We accept that the success of our business is
dependent on the supply of products and services that will benefit society whilst ensuring human safety and protection
of the environment and natural resources Within the framework of our commitment to the Responsible Care program,
we will provide a healthy and safe work environment for employees and will responsibly manage our products at all
stages of their life cycle in order to protect human health and the environment whilst maintaining high production
standards of operation

{ Page 7 of 8 }
 SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29 CFR 1910.1200 (GHS)
________________________________________________________________________________________

Product name SYN-O-AD 8485

Product id 7064
Revision date 11/09/2014 Revision: 4
Supersedes 08/12/2013
________________________________________________________________________________________

TO MEET THIS COMMITMENT WE WILL: Comply with or exceed applicable national and international regulatory
requirements and other requirements to which we subscribe Communicate openly and actively encourage dialogue
with employees, customers and community concerning our products and operations Implement documented
management systems consistent with and for promotion of the Responsible Care ethics

Develop and supply products that can be manufactured, transported, used and disposed of safely whilst best meeting
the needs of our customers Regularly assess, continually improve and responsibly manage health, safety and
environmental risks associated with products and processes throughout their life-cycles Share knowledge and
expertise with others and seek to learn from and incorporate improved practices into our own operations

Educate and train employees, contractors and customers to improve their HSE performance Communicate up-to-date
information to enable our workers, customers and other interested parties to handle our products in a safe and
environmentally responsible manner Endeavor to work with customers, suppliers, distributors and contractors to foster
the safe use, transport and disposal of our chemicals Support Product Stewardship programs in cooperation with
customers, distributors and transporters

Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith
and believed to be correct as of the date hereof, ICL-IP America Inc. makes no representations as to the
completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will
make their own determination as to its safety and suitability for their purposes prior to use. In no event will ICL-IP
America Inc. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon
information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE
HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.

In an event of discrepancy between the contents of this SDS and the English version of it, the English version shall
prevail.

Prepared by HERA Division in ISRAEL

telephone: +/972-8-6297835
telefax: +/972-8-6297832
www.icl-ip.com
e-mail:[email protected]

End of safety data sheet

{ Page 8 of 8 }