Sodium Hydroxide: 1 Properties
Sodium Hydroxide: 1 Properties
Sodium Hydroxide: 1 Properties
1
1.1
Properties
Glass reacts slowly with aqueous sodium hydroxide solutions at ambient temperatures to form soluble silicates.
Because of this, glass joints and stopcocks exposed to
sodium hydroxide have a tendency to freeze. Flasks
and glass-lined chemical reactors are damaged by long
exposure to hot sodium hydroxide, which also frosts the
glass. Sodium hydroxide does not attack iron since iron
does not have amphoteric properties (i.e., it only dissolves
in acid, not base). A few transition metals, however, may
react vigorously with sodium hydroxide.
Physical properties
1.2.1
1.2
In 1986, an aluminium road tanker in the UK was mistakenly used to transport 25% sodium hydroxide solution,[13]
causing pressurization of the contents and damage to the
tanker. The pressurization was due to the hydrogen gas
which is produced in the reaction between sodium hydroxide and aluminium:
Chemical properties
2 Al + 2 NaOH + 6 H2 O 2 NaAl(OH)4 + 3
H2
Saponication
USES
3 Uses
Production
Sodium hydroxide is industrially produced as a 50% solution by variations of the electrolytic chloralkali process. Chlorine gas is also produced in this process. Solid
sodium hydroxide is obtained from this solution by the
evaporation of water. Solid sodium hydroxide is most
commonly sold as akes, prills, and cast blocks.[12]
In 2004, world production was estimated at 60 million
dry metric tonnes of sodium hydroxide, and demand was
estimated at 51 million tonnes.[12] In 1998, total world
production was around 45 million tonnes. North America and Asia each contributed around 14 million tonnes,
while Europe produced around 10 million tonnes. In the
United States, the major producer of sodium hydroxide
is the Dow Chemical Company, which has annual production around 3.7 million tonnes from sites at Freeport,
Texas, and Plaquemine, Louisiana. Other major US producers include Oxychem, PPG, Olin, Pioneer Companies, Inc. (PIONA, which was purchased by Olin), and
Formosa. All of these companies use the chloralkali process.[14]
Sodium hydroxide is a popular strong base used in industry. Around 56% of sodium hydroxide produced is used
by industry, 25% of which is used in the paper industry. Sodium hydroxide is also used in the manufacture of
sodium salts and detergents, pH regulation, and organic
synthesis. It is used in the Bayer process of aluminium
production.[12] In bulk, it is most often handled as an
aqueous solution,[16] since solutions are cheaper and easier to handle.
3.3
3.1
Chemical pulping
3.2
Tissue digestion
USES
3.6
Cleaning agent
Chemical burns caused by sodium hydroxide solution photographed 44 hours after exposure.
3.7
Historical uses
Sodium hydroxide has been used for detection of carbon Sodium hydroxide is corrosive to several metals, like
monoxide poisoning, with blood samples of such patients aluminium which reacts with the alkali to produce
turning to a vermilion color upon the addition of a few ammable hydrogen gas on contact:[31]
drops of sodium hydroxide.[30] Today, carbon monoxide
poisoning can be detected by CO oximetry.
2 Al + 2 NaOH + 2 H2 O 3 H2 + 2 NaAlO
3.8
Experimental
Safety
5 Commercial brands
Red Devil Lye
Lewis Lye
6 See also
HAZMAT Class 8 Corrosive Substances
8 BIBLIOGRAPHY
Common chemicals
List of cleaning agents
References
[19] Ayres, Chris (27 February 2010) Clean green nish that
sends a loved one down the drain Times Online. Retrieved
2013-02-20.
[20] Thacker, H. Leon; Kastner, Justin (August 2004). Carcass
Disposal: A Comprehensive Review. Chapter 6. National
Agricultural Biosecurity Center, Kansas State University,
2004. Retrieved 2010-03-08
[21] Roach, Mary (2004). Sti: The Curious Lives of Human
Cadavers, New York: W.W. Norton & Company. ISBN
0-393-32482-6.
[22] Sodium: Getting rid of dirt and murder victims. BBC
News. 3 May 2014.
[23] William Booth (January 27, 2009). "'Stewmaker' Stirs
Horror in Mexico. Washington Post.
[24] http://www.atsdr.cdc.gov/MMG/MMG.asp?id=246&
tid=45
[25] Mort, Campbell (1856). A treatise on chemistry applied
to the manufacture of soap and candles. Parry and McMillan.
[26] Andrew Hough (18 October 2012). British engineers
produce amazing 'petrol from air' technology. The Telegraph. Retrieved 21 October 2012.
[27] Sodium Hydroxide. rsc.org. 2014. Retrieved November 9, 2014.
[28] Hominy without Lye. National Center for Home Food
Preservation.
[29] Olives: Safe Methods for Home Pickling (application/pdf Object)" (PDF). ucanr.org. 2010. Retrieved January 22, 2012.
[30] Page 168 in: The Detection of poisons and strong drugs.
Author: Wilhelm Autenrieth. Publisher: P. Blakistons
son & Company, 1909.
[31] aluminium_water_hydrogen.pdf (application/pdf Object)" (PDF). www1.eere.energy.gov. 2008. Retrieved
January 15, 2013.
8 Bibliography
Euro Chlor-How is chlorine made? Chlorine Online
Greenwood, Norman N.; Earnshaw, Alan (1997).
Chemistry of the Elements (2nd ed.). ButterworthHeinemann. ISBN 0-08-037941-9.
Heaton, A. (1996) An Introduction to Industrial
Chemistry, 3rd edition, New York:Blackie. ISBN
0-7514-0272-9.
External links
International Chemical Safety Card 0360
NIOSH Pocket Guide to Chemical Hazards
CDC Sodium Hydroxide NIOSH Workplace
Safety and Health Topic
European Union Risk Assessment Report
Production by brine electrolysis
Sodium Hydroxide Safety Data Sheet (SDS)
Sodium hydroxide Safety Summary (BASF)
Titration of acids with sodium hydroxide; freeware
for data analysis, simulation of curves and pH calculation
Caustic soda production in continuous causticising
plant by lime soda process
10
10
10.1
10.2
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