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Joint Entrance Exam/IITJEE-2016

Paper Code - F
3rd April 2016 | 9.30 AM 12.30 PM
CHMISTRY, MATHEMATICS & PHYSICS

Important Instructions:
1. Immediately fill in the particulars on this page of Test Booklet with only Blue / Black Ball Point Pen
provided by the Board.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out
the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C, consisting of Chemistry, Mathematics and Physics
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct
response.
6. Candidates will be awarded ,marks as stated above in instruction No. 5 for correct response of each
question. (one fourth) marks will be deducted for indicating incorrect response for each question. No
deduction from the total score will be made if no response is indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling up more than one response in each question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6
above.
8. For writing particulars/marking responses on Side -1 and Side-2 of the Answer Sheet use only Blue / Black
Ball Point Pen provided by the Board.
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any electronic device, etc. except the Admit Card inside the examination room/hall.
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Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
12. The CODE for this booklet is F. Make sure that the CODE printed on Side 2 of the Answer Sheet and
also tally the serial number of the Test Booklet and Answer Sheet are the same as that on this booklet. In case of
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Test Booklet and the Answer Sheet.
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PART-A
1.

CHEMISTRY

A stream of electrons from a heated filament was passed between two charged plates kept at a potential
difference V esu. If e and m are charge and mass of an electron, respectively, then the value of

h
(where is

wavelength associated with electron wave) is given by :

(1)

2 meV

(2)
h

(3)

meV
h

and eV

1 P2

(4)

2meV

meV

1.(3)

de-Broglie wavelength,

2.

2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields :

CH3
|
C2 H5 CH 2 C CH 2
C2 H5 CH C CH3
(a)
C2 H5 CH 2 C OCH3
(b)
(c)
|
|
|
CH3
CH3
CH 3

2 m

P 2meV

(1)

2.(4)

(a) and (c)

(2)
(c) only
(3)
(a) and (b)
(4)
All of these
CH3
CH3
CH3
|
|
|
CH3 O Na

CH3 C CH 2 CH 2 CH3 CH3 C CH CH 2 CH3

CH3 C CH 2 CH 2 CH3
CH 3OH
|
|
Cl
OCH3 (SN 1 product)
(E1 and E2 product)
CH3
|
CH 2 C CH 2 CH 2 CH3

3.
3.(1)

Which of the following compounds is metallic and ferromagnetic ?

(1)
CrO2
(2)
VO2
(3)
MnO2
CrO2 is metallic and ferromagnetic substance (fact).

(4)

TiO2

Read NCERT (XIIth) - Chapter-1/The Solid State-Page-28

4.

4.(3)

5.

5.(2)

6.

Which of the following statements about low density polythene is FALSE ?

(1)
It is a poor conductor of electricity
(2)
Its synthesis requires dioxygen or a peroxide initiator as a catalyst
(3)
It is used in the manufacture of buckets, dust-bins etc
(4)
Its synthesis requires high pressure
Low density polythene is chemically inert and tough but flexible and a poor conductor of electricity. Hence, it is
used in the insulation of electricity carrying wires and manufacture of squeeze bottles, toys and flexible pipes.
For a linear plot of log (x/m) versus log p in Freundlich adsorption isotherm, which of the following statements is
correct ? (k and n are constants)
(1)
1/n appears as the intercept
(2)
Only 1/n appears as the slope
(3)
log (1/n) appears as the intercept
(4)
Both k and 1/n appear in the slope term
x
1
log log k log P (NCERT (XIIth-Chapter-5/Surface Chemistry-Page-125)
m
n
The heats of combustion of carbon and carbon monoxide are 393.5 and 283.5 kJ mol1 , respectively. The
heat of formation (in kJ) of carbon monoxide per mole is :
(1)
676.5
(2)
(3)
676.5

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110.5

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6.(3)

C O2 CO2 [i]
1

1
C O2 CO f H CO (H (i) H (ii) ) 393.5 (283.5) 110.0
CO O 2 CO2 [ii]
2
2

7.

The hottest region of Bunsen flame shown in the figure below is :

(1)

region 2

(2)

region 3

(3)

region 4

(4)

region 1

(2)
(4)

Cetyltrimethyl ammonium bromide

Sodium stearate

7.(1)

8.

8.(1)

Which of the following is an anionic detergent?

(1)
Sodium lauryl sulphate
(3)
Glyceryl oleate

NaOH aq

H SO

2 4
CH3 CH 2 10 CH 2 OH
CH3 CH 2 10 CH 2OSO3H
CH3 CH 2 10 CH 2OSO3 Na

Sodium lauryl sulphate (Anionic detergent)

(Read NCERT-XIIth-Chapter 16-Chemistry in Every day life/Page-452)

C6 H12O6

9.

18 g glucose

9.(2)

solution is:
(1)
76.0
(2)
752.4
(3)
759.0
(4)
7.6
18
178.2
nC H O
0.1, n n 20
9.9
6 12 6
180
18
0.1
0.1
p
p

C6 H12 O6

0.01, Now B
0.01 P 7.6 torr
0.1 9.9 10
760
PA

is added to 178.2 g water. The vapor pressure of water (in torr) for this aqueous

soln

10.

10.(3)

Pwater
P 760 7.6 752.4 torr

The distillation technique most suited for separating glycerol from spent-lye in the soap industry is:
(1)
Fractional distillation
(2)
Steam distillation
(3)
Distillation under reduced pressure
(4)
Simple distillation
Steam distillation is preferred for separation of substances which are steam volatile and are immiscible with
water.
Fractional distillation is used if the difference in boiling points of two liquids is not much. This technique is used
to separate different fractions of crude oil in petroleum industry.
Distillation under reduced pressure is used to purify liquids having very high boiling points and those, which
decompose at or below their boiling points. Glycerol can be separated from spent-lye in soap industry by using
this technique

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Simple distillation This technique is used to separate volatile liquids from nonvolatile impurities or liquids
having sufficient difference in their boiling points.
11.

The species in which the N atom is in a state of sp hybridization is :

(1)

NO2

(2)

NO3

(3)

(4)

NO2

NO2

11.(4)

12.

Decomposition of H 2 O2 follows a first order reaction. In fifty minutes the concentration of H 2 O2 decreases
from 0.5 to 0.125 M in one such decomposition. When the concentration of H 2 O2 reaches 0.05 M, the rate of
formation of O2 will be:

12.(1)

(1)

6.93 10 4 mol min 1

(2)

2.66 L min 1 at STP

(3)

1.34 102 mol min 1

(4)

6.93 10 2 mol min 1

In fifty minutes the concentration of H2O2 decreases from 0.5 to 0.125 M.

It means two half lives must have passed

2t1/ 2 50 minutes
t1/ 2 25 minutes

0.693
1
k
min
25

d[H 2 O2 ]
0.693
k[H 2 O2 ]
(0.05)mol min 1
dt
25
As per reaction

Also

2H 2O 2
2H 2 O O2

d[O 2 ]
1 d[H 2 O2 ] 1 0.693
4
1
1

2 25 0.05 mol min 6.93 10 mol min
dt
2
dt

13.

The pair having the same magnetic moment is : At. No. : Cr 24, Mn 25, Fe 26, Co 27
(1)

Cr H 2 O
6

(3)

CoCl4 2

and Fe H 2 O 6

and Fe H 2 O 6

(2)

Mn H 2 O
6

(4)

Cr H 2 O
6

and Cr H 2 O 6

and CoCl 4

13.(1) [Cr(H 2 O) 6 ]2 Cr 2 , [Ar] 3d 4

[Fe(H 2O) 6 ]2 Fe2 , [Ar]3d 6

[Mn(H 2 O) 6 ]2 Mn 2 , [Ar]3d5

[CoCl4 ]2 Co 2 , [Ar]3d 7

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14.

The absolute configuration of

14.(1)

(1)
(2S, 3R)
(2)
(2S, 3S)
(3)
(2R, 3R)
Order of priority of substituent of C-2 is OH > CH(Cl)(CH3) > COOH
(Z)

(4)

(2R, 3S)

Order of priority is in anti-clockwise direction hence, its configuration is S.

Order of priority of substituent of C-3 is Cl > CH(OH)COOH > CH3
(Z)

Order of priority is in clockwise direction hence, its configuration is R.

15.

C D is 100. If the initial concentration of all the

The equilibrium constant at 298 K for a reaction A B
four species were 1M each, then equilibrium concentration of D (in mol L1 ) will be :

15.(2)

(1)
0.818
Initially at equilibrium
A

1
1
(1 x) (1 x)

K eq

(2)

1.818

1
1 x

(3)

1.182

(4)

0.182

D K eq 100
1
1 x

Q 1

[C][D] (1 x)(1 x) (1 x) 2

[A][B] (1 x)(1 x) (1 x)2

1 x
1 x
9
On solving x
11
[D] 1.818
10

16.
16.(2)

17.

Which one of the following ores is best concentrated by froth floatation method ?
(1)
Siderite
(2)
Galena
(3)
Malachite
(4)
Magnetite
Sulphide ores are concentrated by forth floatation process
Galena PbS Siderite FeCO3
Malachite CuCO3 . Cu(OH)2 Magnetite Fe3 O4
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for
complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid
form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is :

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(1)
17.(None)

C3H8

(2)

C4H8

(3)

C4H10

(4)

C3H6

y
y

xCO 2 (g) H 2O(l)

Cx H y (g) x O2 (g)
4
2

15 ml

15 x ml
4

15 x ml

O2 used = 20% of 375 = 75 ml

Inert part of air = 80% of 375 = 300 ml
Total volume of gases = CO2 + Inert part of air = 330 ml
Vol of CO2 = 30 ml
Two equations are x = 2, y = 12
None of the option matches.
18.

18.(4)

The pair in which phosphorous atoms have a formal oxidation state of +3 is :

(1)
Pyrophosphorous and hypophosphoric acids (2)
Orthophosphorous and hypophosphoric acids
(3)
Pyrophosphorous and pyrophosphoric acids
(4) Orthophosphorous and pyrophosphorous acids
O
||
H 3 PO3 is orthophosphorous acid : HO P OH
|
H
O
O
||
||
H 4 P2 O5 is pyrophosphorous acid : HO P O P OH
|
|
H
H
Read NCERT (XIIth)-Chapter-7/p-Block Elements-Page-179

19.

Which one of the following complexes shows optical isomerism ?

(1)
cis [Co(en)2Cl2 ]Cl
(2)
trans [Co(en)2Cl2]Cl
(3)
[Co(NH3)4Cl2]Cl
(4)
[Co(NH3)3Cl3]
(en = ethylenediamine)

19.(1)

[Co(NH3 )4 Cl2 ]Cl can exist in both cis and trans form and both are optically inactive.
Read NCERT (XIIth)-Chapter-9/Co-ordination Compounds-Page-259

trans
cis
[Co(NH3 )3 Cl3 ] exist in fac and Mer forms and both are optically inactive.

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20.

20.(4)

The reaction of zinc with dilute and concentrated nitric acid, respectively, produces:
(1)
NO 2 and NO
(2)
NO and N2 O
(3)
NO2 and N 2 O (4)

N 2 O and NO 2

Zn 4HNO3
Zn(NO3 )2 2H 2 O 2NO 2
conc.

4Zn(NO3 )2 N 2 O 5 H 2 O
4Zn 10 HNO3
dil

21.

21.(2)
22.

22.(2)

23.

Which one of the following statements about water is FALSE?

(1)
Water can act both as an acid and as a base
(2)
There is extensive intramolecular hydrogen bonding in the condensed phase
(3)
Ice formed by heavy water sinks in normal water
(4)
Water is oxidized to oxygen during photosynthesis
Water shows only intermolecular H-bond in the condensed phase
The concentration of fluoride, lead, nitrate and iron in a water sample from an underground lake was found to be
1000 ppb, 40 ppb, 100 ppm and 0.2 ppm, respectively. This water is unsuitable for drinking due to high
concentration of :
(1)
Lead
(2)
Nitrate
(3)
Iron
(4)
Fluoride
In drinking water maximum permissible concentration of
Lead about 50 ppb
Nitrate about 50 ppm
Iron about 0.2 ppm
Fluoride about < 1 ppm
High concentration of nitrate in drinking water can cause disease such as methemoglobinemia.
Read NCERT (XIth)-Chapter-14/Environmental Chemistry-Page-412
The main oxides formed on combustion of Li, Na and K in excess of air are, respectively:
(1)
LiO2 , Na 2 O 2 and K 2 O
(2)
Li2O2, Na2O2 and KO2
(3)

23.(3)

Li mainly forms Li2 O

24.

Thiol group is present in:

(1)
Cystine
(2)

24.(2)

25.

(4)

Li2 O, Na 2 O2 and KO2

Na mainly forms Na 2 O 2
Cysteine

Li 2 O, Na 2 O and KO2

K mainly forms KO 2
(3)

Cysteine is amino acid having thiol group

HS CH 2 CH COOH
|
NH 2
Read NCERT (XIIth)-Chapter-14/Biomolecules-Page-413
Galvanization is applying a coating of:
(1)
Cr
(2)
Cu
(3)

Methionine

(4)

Cytosine

Zn

(4)

Pb

(4)

Rb

25. (3) Galvanization means applying a coating of zinc metal to prevent corrosion.
26.
Which of the following atoms has the highest first ionization energy?
(1)
Na
(2)
K
(3)
Sc
26.(3)

IE Na 496 kJ / mol ; IESc 633 kJ / mol

It is relatively difficult to remove on e from 4s orbital of Sc as compared to 3S of Na due to poor shielding of

d-orbital.

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27.

In the Hofmann bromamide degradation reaction, the number of moles of NaOH and Br2 used per mole of
amine produced are:
(1)
Four moles of NaOH and two moles of Br2 (2)
Four moles of NaOH and one mole of Br2

(3)

27.(3)
28.

Two moles of NaOH and two moles of Br2

One mole of NaOH and one mole of Br2

(4)

RCONH 2 4NaOH Br2

RNH 2 Na 2 CO3 2NaBr 2H 2 O
Read NCERT (XIIth)-Chapter-13/Amines-Page-386
Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pi and temperature T1 are

connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of
the bulbs is then raised to T2 . The final pressure p f is:

T1
2 pi

T1 T2

(1)

(2)

T2
2 pi

T1 T2

TT
2 pi 1 2
T1 T2

(3)

(4)

TT
pi 1 2
T1 T2

28.(2)
Number of mol of gases in each container
Total mol of gases in both containers 2

In left chamber n1

pf V
RT1

piV
RT1

and In right chamber, n2

Total moles of gases should remain constant

29.

piV
RT1

pf V
RT2

pf V pf V
T2
2 pi V

p f 2 pi

RT1
RT1
RT2
T1 T2

The reaction of propene with HOCl (Cl2 H2 O) proceeds through the intermediate:
(1)

CH3 CH CH 2 Cl

(2)

CH3 CH(OH) CH 2

(3)

CH3 CHCl CH 2

(4)

CH3 CH CH 2 OH

HO Cl

OH

29.(1)

CH3 CH CH 2
CH3 C H CH 2 Cl CH3 CH CH 2 Cl
Electrophilic addition
|
Intermediate
OH

30.

The product of the reaction given below is:

(1)

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(2)

(3)

(4)

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30.(1)

PART-C
31.

MATHEMATICS

Two sides of a rhombus are along the lines, x y 1 0 and 7 x y 5 0 . If its diagonals intersect at

1, 2 , then which one of the following is a vertex of this rhombus ?

3, 8

(1)
31.(2)

1 8
,
3 3

(2)

7
10
,
3
3

(4)

3, 9

1 8
C ,
3 3

3, 6 D
7 x y 15 0

(3)

P
7x y 5 0

x y 1 0

B(1, 2)

32.

If the 2nd, 5th and 9th terms of a non-constant A.P. are in G.P., then the common ratio of this G.P. is :
4
7
8
(1)
(2)
1
(3)
(4)
3
4
5

32.(1)

a d , a 4d , a 8d

a 4d 2 a d a 8d
a 2 16d 2 8ad a 2 9ad 8d 2

8d 2 ad
a 8d , d 0
r

33.

a 4d 12d 4

a d
9d
3

Let P be the point on the parabola, y 2 8 x which is at a minimum distance from the centre C of the
2

circle, x 2 y 6 1 . Then the equation of the circle, passing through C and having its centre at P is:

33.(4)

x
2 y 24 0
4

(1)

x 2 y 2 x 4 y 12 0

(2)

x2 y 2

(3)

x 2 y 2 4 x 9 y 18 0

(4)

x 2 y 2 4 x 8 y 12 0

2t

, 4t

0, 6

F t 4t 4 4t 6

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= 4 t

12t 9

= 4 t 4 4t 2 9 12t
4

4t 2

F ' t 4 4t 3 8t 12 0

t 1

t 2t 3 0

x 2 y 2 4 x 8 y 12 0

34.

The system of linear equations

x y z 0

x y z 0
x y z 0

34.(3)

has a non-trivial solution for :

(1)
exactly one value of

(2)

(3)

(4)

exactly three values of

exactly two values of

infinitely many values of

1 1
1 1 0
1 1

1 2 1 1 0
1 1
1 or

35.

0 or 1

1
If f x 2 f 3 x, x 0 and S x R : f x f x ; then S :
x

(1)
(3)
35.(2)

contains exactly one element

contains more than two elements (4)

(2)
contains exactly two elements
is an empty set

1
f x 2 f 3 x, x 0
x
3
1
f 2 f x
x
x
6
3 f x 3x
x
2
f x x
x
2
2
f x f x
x
x
x
x
4
2x
x

x2 2 x 2

36.

1 1 0

Let p lim 1 tan 2 x

x 0

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1
2x

then log p is equal to :

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(1)
36.(2)

37.

x 0

1
4

(3)

(4)

(4)

tan 2 x e 12

1
2

2 3i sin
is purely imaginary, is :
1 2i sin

3
sin 1

(2)

1
sin 1

(3)

Re 2 3i sin 1 2i sin 2 6 sin 2 0

sin 2

1
3

The eccentricity of the hyperbola whose length of the latus rectum is equal to 8 and the length of its
conjugate axis is equal to half of the distance between its foci, is :
4
3

(1)
38.(2)

lim e 2 x
x 0

38.

1
2x

A value of for which

(1)

37.(3)

p lim 1 tan 2 x

log e p

1
2

(2)

2
3

(2)

(3)

(4)

4
3

2b 2
8
a
2b ae
4b 2 a 2 e 2

4 a 2 e2 1 a 2 e2

3e2 4
e

39.

39.(1)

2
3

If the standard deviation of the numbers 2, 3, a and 11 is 3.5, then which of the following is true :
(1)

3a 2 32a 84 0

(2)

3a 2 34a 91 0

(3)

3a 2 23a 44 0

(4)

3a 2 26 a 55 0

xi2 xi
Variance
n

4 9 a 2 121 16 a

4
4

4 134 a 2 256 a 2 32a

16
2

7
3a 2 32a 280 16 4 49
2
3a 2 32 a 84 0

40.

The integral

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2 x12 5 x9

x5 x3 1

dx is equal to :

11

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(Where C is an arbitrary constant)
x10
(1)
C
2
2 x5 x3 1

x5

(2)

10

(3)

2 x5 x3 1
40. (1)

2 x12 5 x9

x5 x3 1

2 x5 x3 1

(4)

x3 1

dx

2 x12 5 x9

x15 1 x2 x5 3 dx

2 x 3 5 x 6

x 5 x 2 1

dx

x 5 x 2 1 t

5x6 2 x3 dx dt

41.

t 2

dt

x10

t3 2 C 2t 2 C 2

x5 x3 1

x 3 y2 z 4

lies in the plane, lx my z 9 , then l 2 m 2 is equal to:

2
1
3
18
(2)
5
(3)
2
(4)
26

If the line,
(1)

3 2m 5

(i)

2 m 3 0

2 m 3

(ii)

4 2 m 6

(iii)

(iii) (i)
1
2 m 2 2

m 1

42.

If 0 x 2 , then the number of real values of x, which satisfy the equation cosx + cos2x + cos3x +
cos4x = 0, is :
(1)
5
(2)
7
(3)
9
(4)
3

2 cos

5x
3x
5x
x
cos 2 cos cos 0
2
2
2
2

2 cos

5x
3x
x
cos cos 0

2
2
2

2 cos

5x
x
2 cos x cos 0
2
2
3
,
2 2

cos x 0

cos

x
0
2

cos

5x
0
2

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5 is repeated

3 7 9
,
,
,
5 5 5 5

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43.

The area (in sq. units) of the region

x, y : y

8
3
2 2

2
3

(1)
(3)

2 x and x 2 y 2 4 x, x 0, y 0 is :

(2)
(4)

4 2
3
4

3

x2 y 2 4 x 0

43.(1)

y2 2x
x2 2 x 4 x 0

x2 2 x 0

x x 2 0

x 0, x 2
2

Area

4 x x 2 2 x dx

2 2 x 2 2 x dx

2
x2
2 2
4
x2
2 3

8

2 x 2
2 2 2
4 x x 2 sin 1
2
2
2
3

3
2
3

44.

44.(3)

3
Let a , b and c be three unit vectors such that a b c
b c . If b is not parallel to c , then
2

the angle between a and b is:

2
(1)
(2)
2
3
5
3
(4)
(3)
6
4

a bc

3
b c
2

3
3
b
c
2
2
3
ab
2

ac

Angle between a & c 30

. c b a b c

3
2

and

5
6

A wire of length 2 units is cut into two parts which are bent respectively to form a square of side = x
units and a circle of radius = r units. If the sum of the areas of the square and the circle so formed is
minimum, then:
(1)
(2)
x 2r
4 x r
(3)

45.(2)

a & b 150

45.

2x = r

4 x 2 r 2

(4)

2 x 4 r

2x r 1
r

1 2x

f x x2 r 2

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= x2

1 2x2
2

1 2x 2

f x x2

2 1 2 x 2

f ' x 2x

2 1 2x
x

x 2 4x

1 r
x 2 4

2
x 2 2 1 r
x 2 2 2 r
x 2 r .

46.

46.(1)

The distance of the point 1, 5 , 9 from the plane x y z 5 measured along the line x = y = z is :
(1)

10 3

(2)

10
3

(3)

20
3

(4)

3 10

x 1 y 5 z 9

1
1
1
Any point is 1, 5 , 9

Equation of line:

It lies on plane

1 5 9 5

1 5 9 5

10 0

10
Point is 9, 15, 1 , another is 1, 5, 9

Distance =

47.

100 100 100 10 3

If a curve y = f (x) passes through the point

1
y (1 + xy) dx = xdy, then f is equal to :
2
4
2
(1)
(2)

5
5

1, 1

(3)

and satisfies the differential equation,

4
5

(4)

2
5

y 1 xy dx xdy

47.(3)

dy y
y2
dx x

dy y
y2
dx x

Bernaullis DE
n2
I.F

1 2 x dx x dx x ,
e

Solution y1 2 x

1 2 x 1 dx

x
x

C
y
2

Given

f 1 1

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1
1
C
1
2

equation

1
2

x
x2 1

2 2
y

1
1
1
1
When x , we have

2
2y
42 2

1
5

y
4

4
5
n

48.

48.(3)

4
2
If the number of terms in the expansion of 1 2 , x 0 , is 28, then the sum of the coefficients
x x

of the terms in this expansion, is :

(1)
2187
(2)
243
(3)
729
(4)
64
2 4
1 2
x x

Assuming all dissimilar terms

n 2

C2 28
n6

Sum of all coefficients 36 729

49.

49.(1)

1 sin x

. A normal to y f x at
also passes through the
Consider f x tan 1
1 sin x , x 0 , 2
6

point :
2


(2)
(3)
(4)
(0, 0)
(1)
0,

, 0
, 0
3
6

4
1 sin x

f x tan 1
; x 0,

2
1 sin x
f x

At x

1 sin x cos x 1 sin x cos x

1
1

2
1 sin x
1 sin x
x
1
sin

2
1 sin x
1 sin x

f
6

1
1
2
1
1
1
2
1

3
/
2
1
1
3
1
1

4 3

2
4 2 3
2
1 1 1 3 2 3 1
1
2
4
2

2
1
1
2
1

Slope of normal 2

Point at x
6

1
1

1
2 tan 1 3
f tan
1
3
6
1
2

equation y

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2 x
3
6

15

2x
3
3

y 2x

2
3

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50.

For x R , f x | log 2 sin x | and g x f f x , then :

(1)

g' 0 cos log 2

(2)

g' 0 cos log 2

(3)

g is differentiable at x = 0 and g' 0 sin log 2

(4)

g is not differentiable at x = 0

g 0 f f 0 f 0

For

x 0, log 2 sin x

f x log 2 sin x

f x cos x

Also,

x log 2, log 2 sin x

f x log 2 sin x

f x cos x

51.

f 0 1

f log 2 cos log 2

g 0 cos log 2 1 cos log 2

Let two fair six-faced dice A and B be thrown simultaneously. If E1 is the event that die A shows up four,

E2 is the event that die B shows up two and E3 is the event that the sum of numbers on both dice is odd,

51.(3)

then which of the following statements is NOT true ?

(1)
E2 and E3 are independent
(2)

E1 and E3 are independent

(3)

E1 , E2 and E3 are independent

E1 and E2 are independent

P E1

1
6

P E2

1
6

P E3

24642 1

36
2

P E2 E3

1 1
P E2 P E3
6 2

P E1 E3

1 1
P E1 P E3
6 2

(4)

P E1 E2 E3 0 P E1 P E2 P E3

52.

5a b
T
If A
and A adj A AA , then 5a b is equal to :
3
2

(1)
52.(1)

(2)
T

A adj A A I n AA

(3)

13

(4)

[Given]

A 10a 3b
5a 3
AT

b 2
0
5a b 5a 3 10a 3b
AAT
b 2 0
3
2
10
a
3b

25a 2 b 2 15a 2b 10a 3b

0

10a 3b
13 0
15a 2b

15a 2b 0

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2b
& 10a 3b 13
15

16

13 3b
10

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53.

2b 13 3b

15
10

5a b 2 3 5

2
6
2
3

15
15 5

4b 39 9b

13b 39

b3

5a 2

The Boolean Expression p q q p q is equivalent to :

(1)

53.(2)

pq

(2)

p q

p q

(3)

(4)

pq

p q q p q
p q q q p q

p q t p q
p q p q
p q p p q q
t q p q t p q p q

54.

The sum of all real values of x satisfying the equation x 2 5 x 5

(1)

54.(4)

x2 5 x 5

(2)

(3)

x 2 4 x 60

1 is :

(4)

x 4 x 60

Case I
x 2 4 x 60 0
x 10
x6

Case II
x2 5 x 5 1

x2 5 x 4 0
x 1
x4

Case III
x2 5 x 5 1

x2 5 x 6 0
x 2 or 3

For

x2
x 2 4 x 60 48

For

x3

x 2 4 x 60 39

x2

Sum of all real value 3

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55.

The centres of those circles which touch the circle, x 2 y 2 8 x 8 y 4 0 , externally and also touch
the x-axis, lie on :
(1)
an ellipse which is not a circle.
(3)
a parabola

55.(3)

(2)
(4)

a hyperbola
a circle

x2 y2 8x 8 y 4 0
C 4, 4

r6

Let centre be (x1, y1)

Radius = |y1|

x1 4 2 y1 4 2

6 | y1 |

x1 4 2 y1

x12 8 x1 8 y1 4 12| y1 |

y1 0

y1 < 0

C1 C2 = r 1 + r2

4 36 y12 12| y1 |

x12 8 x1 8 y1 4 12 y1

x12 8 x1 4 20 y1

x1 4 2

20 20 y1

x1 4

x12 8 x1 8 y1 4 12 y1

x12 8 x1 4 4 y1

20 y1 1

x1 4 2

Parabola

20 4 y1 x1 4 4 y 5 parabola

56.

If all the words (with or without meaning) having five letters, formed using the letters of the word
SMALL and arranged as in a dictionary ; then the position of the word SMALL is :
(1)
59th
(2)
52nd
(3)
58th
(4)
46th

56.(3)

4
12
2

4 24

4
12
2

SA

3
3
2

SL

36

Total
57
Next word is SMALL.
1/ n

57.

n 1 n 2 .........3n
is equal to :
lim

n
n2n

27
9
(1)
(2)
(3)
2
e
e2

3 log 3 2

(4)

18
e4

1/ n

57.(1)

n 1 n 2 n 3
n 2n

.
.
. .........

n
n
n
n

1 n 1
n 2
n 2n
log log
log
........ log

n n
n
n

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2

log log 1 x dx

1+x=t

0
3

log

log t

dt

1
log t log t . t dt
t
log t log t 1

log 3 log 3 1 1 log 1 1

= 3 log 3 2
= log 27 log e2
= log log

27
e2

27
e2
2

58.

58.(1)

16
3 2 1
4
If the sum of the first ten terms of the series 1 2 3 4 2 4 ..., is m , then
5
5 5 5
5
m is equal to :
(1)
101
(2)
100
(3)
99
(4)
102
8
Sn
5
1 2
Sn
8
25
10

Sn

12
16

5
5

10
n 1

10

n 1

n 1

20

5

122 16 2 202 ......

25 4n 4

16
n 12

25

16 2
n 2n 1

25

35.11

16 10 .11 . 21 10 .11

10
25
6
2

16
=
385 110 10
25
16
16
=
505
101
m 101
25
5

59.

If one of the diameters of the circle, given by the equation, x 2 y 2 4 x 6 y 12 0 is a chord of a

circle S, whose centre is at 3,2 , then the radius of S is :
(1)

(2)

5 3

(3)

10

(4)

5 2

59.(1)

3, 2
5 3

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60.

A man is walking towards a vertical pillar in a straight path, at a uniform speed. At a certain point A on
the path, he observes that the angle of elevation of the top of the pillar is 30 . After walking for 10
minutes from A in the same direction, at a point B, he observes that the angle of elevation of the top of the
pillar is 60 . Then the time taken (in minutes) by him, from B to reach the pillar, is :
(1)
10
(2)
20
(3)
5
(4)
6
C

60.(3)

Let speed be v
b
30
x

60
y

tan 60

b
3
y

b 3y

(i)

tan 30

1
3

b
x y

b
x y

x yb 3

(ii)

10v vt1 3 y . 3

10v vt1 3 y
10v vt1 3v t1
10 t1 3t1
2t1 10
t1 = 5.

PART-A
61.

A uniform string of length 20 m is suspended from a rigid support. A short wave pulse is introduced at its lowest
end. It starts moving up the string. The time taken to reach the support is: (Take g = 10 ms2)
(1)

61.(2)

PHYSICS

2s

(2)

(3)

2 2s

2s

(4)

2 2 s

Mgx
L

T
V

Mgx
L gx
M
L

dx
gx
dt
L

dx
gt
x

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20

2 x 10t

2 20 10t

62.

t 2 2s
A person trying to lose weight by burning fat lifts a mass of 10 kg upto a height of 1 m 1000 times. Assume that
the potential energy lost each time he lowers the mass is dissipated. How much fat will he use up considering the
work done only when the weight is lifted up? Fat supplies 3.8107 J of energy per kg which is converted to
mechanical energy with a 20 % efficiency rate. Take g = 9.8 ms2 .

(1)
62.(3)

6.45 10 3 kg

(2)

9.89 103 kg

(3)

12.89 103 kg

(4)

2.45 103 kg

PE = mgh 1000 10 9.8 1 1000

PE 10 4 9.8 J

If mass lost is m, then

2
Energy = m
3.8 107 J
10
1
So, 9.8 104 m . 3.8 107
5

63.

5
103 9.8 1.289 102 kg
3.8

A point particle of mass m, moves along the uniformly rough track PQR as shown in the figure. The coefficient
of friction, between the particle and the rough track equals . The particle is released, from rest, from the point
P and it comes to rest at a point R. The energies, lost by the ball, over the parts, PQ and QR, of the track, are
equal to each other, and no energy is lost when particle changes direction from PQ to QR. The values of the
coefficient of friction and the distance x (=QR) , are, respectively close to :

(1)
63.(2)

0.2 and 3.5 m

WPQ mg cos .

(2)

0.29 and 3.5 m

(3)

0.29 and 6.5 m

(4)

0.2 and 6.5 m

2
2mg

2mg 3
sin
tan

WQR mg .x

x 2 3 3.5m

P.E. lost = mgh 2mg

2 mg 4mg 3
1
2 3

64.

0.29

Two identical wires A and B, each of length l carry the same current I. Wire A is bent into a circle of radius R
and wire B is bent to form a square of side a. If BA and BB are the values of magnetic field at the centres of the
circle and square respectively, then the ratio
(1)

2
16 2

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(2)

BA
is:
BB

2
16

(3)

2
8 2

21

(4)

2
8

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64.(3)

2 R

I I
Ba 0 0
2R

BB 4

BB

0 I
sin 45 sin 45
a
4
2

8 2 0 I

BA
2

BB 8 2

65.

A galvanometer having a coil resistance of 100 gives a full scale deflection, when a current of 1 mA is passed
through it. The value of the resistance, which can convert this galvanometer into ammeter giving a full scale
deflection for a current of 10 A, is :
(2)
(3)
(4)
(1)
2
0.1
3
0.01

65.(4)

1mA100 10 1mA .x
101 10x
x

1
0.01
100

66.

An observer looks at a distant tree of height 10 m with a telescope of magnifying power of 20. To the observer
the tree appears:
(1)
10 times nearer (2)
20 times taller (3)
20 times nearer (4)
10 times taller.

66.(2)

20 times taller as the angular magnification is 20 and we observe angular magnification.

Option (3) would not be very correct as the telescope can be adjusted to form image anywhere between infinity
and least distance for distinct vision. Suppose that the image is formed at infinity. Then the observer will have to
focus the eyes at infinity to observe the image. Hence it is incorrect to say that the image will appear nearer to
the observer.

67.

The temperature dependence of resistances of Cu and undoped Si in the temperature range 300-400K, is best
described by:
(1)
Linear increase for Cu, exponential increase for Si
(2)
Linear increase for Cu, exponential decrease for Si
(3)
Linear decrease for Cu, linear decrease for Si
(4)
Linear increase for Cu, linear increase for Si

67.(2)
68.

Resistance of conductor increases and resistance of a semiconductor decreases with increase in temperature
Choose the correct statement:

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(1)

In amplitude modulation the frequency of the high frequency carrier wave is made to vary in
to the amplitude of the audio signal
In frequency modulation the amplitude of the high frequency carrier wave is made to vary in
to the amplitude of the audio signal
In frequency modulation the amplitude of the high frequency carrier wave is made to vary in
to the frequency of the audio signal
In amplitude modulation the amplitude of the high frequency carrier wave is made to vary in
to the amplitude of the audio signal

(2)
(3)
(4)

proportion
proportion
proportion
proportion

68.(4)

Fact

69.

Half lives of two radioactive elements A and B are 20 minutes and 40 minutes, respectively. Initially the
samples have equal number of nuclei. After 80 minutes, the ratio of decayed numbers of A and B nuclei will be :
(1)
4:1
(2)
1:4
(3)
5:4
(4)
1 : 16

69.(3)

For A: Number of half lives = 80/20 = 4

x0
24

1 15

A x0 1
x0
16 16

For B : Number of half lives = 80/40 = 2

x0
22

A
B

70.

3 x0
4

15 /16
5: 4
3/ 4

n mole of an ideal gas undergoes a process A B as shown in the figure.

The maximum temperature of the gas during the process will be :

70.(4)

(1)

3P0V0
2 nR

(2)

9 P0V0
2nR

(3)

9P0V0
nR

(4)

9 P0V0
4nR

P0
V 3P0
V0

PV nRT
T

1 P0 2
V 3P0V

nR V0

For Tmax ,

dT
0
dV

P0
2V 3 P0 0
V0

I max

3
V V0
2

1 P0 9 2
3 9 P0V0
V0 3P0 V0

nR V0 4
2 4 nR

Alternate :
Directly by using isotherms we can see that highest temperature will occur at the midpoint.

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71.

An arc lamp requires a direct current of 10 A at 80 V to function. If it is connected to a 220 V (rms), 50 Hz AC

supply, the series inductor needed for it to work is close to :
(1)
0.08 H
(2)
0.044 H
(3)
0.065 H
(4)
80 H

71.(3)

80
8
10
Vrms

irms 10 A

64 X L2

222 64 X L2

2 50 L 420
L

420
100

42 6.5

72.

X L 420

2 10

L 0.065 H

A pipe open at both ends has a fundamental frequency f in air. The pipe is dipped vertically in water so that half
of it is in water. The fundamental frequency of the air column in now :
(1)

3f
4

(2)

(3)

2f

f
2

(4)

72.(3)

Fundamental freq remains same

73.

The box of a pin hole camera, of length L, has a hole of radius a, It is assumed that when the hole is illuminated
by a parallel beam of light of wavelength the spread of the spot (obtained on the opposite wall of the camera)
is the sum of its geometrical spread and the spread due to diffraction. The spot would then have its minimum size

say bmin

when :

(1)

(3)

73.(None)

2 2
L and bmin
L

(2)

2
and bmin 4 L
L

(4)

L and bmin

2 2
2
and bmin
L
L

4 L

Geometrical spread = a

Diffraction spread = L
L
2a
2a
L
Sum (b) = a
2a
For b to be minimum
db
L
L
0 1 2 0 a
da
2
2a

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L
L

2 L
2
2
No answer is correct.

and

74.

bmin

A combination of capacitor is set up as shown in the figure. The magnitude

of the electric field, due to a point charge Q (having a charge equal to the
sum of the sum of the charges on the 4 F and 9 F capacitors), at a
point distant 30 m from it, would equal :
(1)
360 N/C
(2)
420 N/C
(3)
480 N/C
(4)
240 N/C

74.(2)

Q = 3 8
Q = 24 C

The charges on 4 F and 9 F capacitors are 24 C and 18 C respectively.

Hence, E

9 109 24 18
30 30

420 N / C

75.

Arrange the following electromagnetic radiations per quantum in the order of increasing energy :
A : Blue light
B : Yellow light
C : X-ray
D : Radiowave
(1)
A, B, D, C
(2)
C, A B, D
(3)
B, A, D, C
(4)
D, B, A, C

75.(4)

Energy of one quantum = hv

C A B D D B A C

76.

Hysteresis loops for two magnetic materials A and B are given below:

These materials are used to make magnets for electric generators, transformer core and electromagnet core. Then
it is proper to use:
(1)
A for electromagnets and B for electric generators.
(2)
A for transformers and B for electric generators.
(3)
B for electromagnets and transformers.
(4)
A for electric generators and transformers.
76.(3)

For electromagnets and transformers, energy loss should be low.

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Also,
77.

Thin hysteris curves.

B 0 when H = 0 and H should be small when B 0.

So option fulfills.
A pendulum clock loses 12 s a day if the temperature is 40C and gains 4 s a day if the temperature is 20C. The
temperature at which the clock will show correct time, and the co-efficient of linear expansion ( ) of the metal
of the pendulum shaft are respectively:

77.(4)

(1)

60C ; 1.85 104 / C

(2)

30C; 1.85 103 / C

(3)

55C ; 1.85 102 / C

(4)

25C ; 1.85 10 5 / C

Time loss per day =

86400
2

1
40 86400 12
2
1
20 86400 4
2
40
3
20

25C , 1.85 105 / C

78.

The region between two concentric spheres of radii 'a' and 'b',
A
, where A is
r
a constant and r is the distance from the centre. At the centre of the
spheres is a point charge Q. The value of A such that the electric field in
the region between the spheres will be constant, is: .
Q
2Q
2Q
(1)
(2)
(3)
2
2
2
2
a 2
2 b a
b a

respectively (see figure), has volume charge density

78.(4)

Q
2a 2

Charge in the region between a and r is calculated as follows :

r

Q1 4 r 2 dr .

E( r )

A
and Q1 2 A r 2 a 2
r

Q Q1
2

K
KQ 2 Aa 2
Q 2 A r 2 a 2 K 2 A

r 2
r2
r2

r
For uniform E1 last two terms should cancel

79.

(4)

KQ 2 A .a 2 K

Q
A

2 a 2

In an experiment for determination of refractive index of glass of a prism by i , plot, it was found that a ray
incident at angle 35, suffers a deviation of 40 and that it emerges at angle 79. In that case which of the
following is closest to the maximum possible value of the refractive index? .
(1)
1.6
(2)
1.7
(3)
1.8
(4)
1.5

79.(4)

i e A

40 35 79 A

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A 74

Let us put 1.5 and check.

A min
sin

1.5
sin A
2

74 min
sin

1.5
sin 37

0.9 sin 37 m
2

Using calculator, 37

m
64
2

m 54

This angle is greater than the 40 deviation angle already given. For greater , deviation will be even higher.
Hence of the given prism should be less than 1.5. Hence the closest option will be 1.5.
Upon solving the given case we get 1.31 .
Note :
80.

80.(4)

Upon solving with calculator the exact equations for the given case we get 1.31 .

A student measures the time period of 100 oscillations of a simple pendulum four times. The data set is 90s, 91s,
95 s and 92 s. If the minimum division in the measuring clock is 1 s, then the reported mean time should be :
(1)
92 5.0 s
(2)
92 1.8 s
(3)
92 3s
(4)
92 2 s

X i = 92
N

Xi X

1 4 9 0
= 1.8
4
N
But since LC of clock is 1s, rounding off to the correct sign : Time : 92 2s
2

(Standard dev ) =

81.

Identify the semiconductor devices whose characteristics are given below, in the order (1), (2), (3), (4):

(1)
(2)
(3)
(4)
81.(4)
82.

Zener diode, Simple diode, Light dependent resistance, Solar cell

Solar cell, Light dependent resistance, Zener diode, Simple diode
Zener diode, solar cell, Simple diode, Light dependent resistance
Simple diode, Zener diode, Solar cell, Light dependent resistance

Fact based question (From NCERT)

Radiation of wavelength , is incident on a photocell. The fastest emitted electron has speed . If the
wavelength is changed to

(1)

3
, the speed of the fastest emitted electron will be:
4

4 2

3

4 2

3

3 2

4

3 2

4

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(2)

(3)

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(4)

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82.(4)

V0

2 hc

2 4hc

m 3

4 hc 3

3
4
hc

4 hc

3

hc

hc

We can see that

hc

3
4

1 V V

4
3

83.

A particle performs simple harmonic motion with amplitude A. Its speed is trebled at the instant that it is at a
2A
distance
from equilibrium position. The new amplitude of the motion is: .
3
7A
A
(1)
3A
(2)
A 3
(3)
(4)
41
3
3

83.(3)

V A2 x 2

1/ 2

1/ 2

At

2A
4
, V1 A2 A2
3
9

V1

5 A2

A
5
3

Vnew 3V1 A 5
1/ 2

Now

2
x2
Vnew Anew

An2 x 2 5 A2

An2 5 A2

An

84.

A 5

4 A2
9

7A
3

A particle of mass m is moving along the side of square of side 'a', with a uniform speed in the x-y plane as
shown in the figure:

Which of the following statements is false for the angular momentum L about the origin?

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L m
a k when the particle is moving from C to D.
2

(1)

L m
a k when the particle is moving from B to C.
2

m
(3)
L
R k when the particle is moving from D to A.
2

m
(4)
L
R k when the particle is moving from A to B.
2

84.(1, 3) Angular momentum of a particle moving in a straight line is L m r v

(2)

85.

Hence, 1 and 3 are false.

An ideal gas undergoes a quasi static, reversible process in which its molar heat capacity C remains constant. If
during this process the relation of pressure P and volume V is given by PV n constant, then n is given by (Here
CP and CV are molar specific heat at constant pressure and constant volume, respectively):
n

(1)
85.(1)

C Cv

C Cv
1 n

C CP
C CV

(2)

CP C
C CV

(3)

C CV
C CP

(4)

CP
CV

R
1 n
C p Cv

1 n
C p Cv
C Cv

C p Cv C Cv C p Cv C C p
n 1

C Cv
C Cv
C Cv

86.

86.(1)

A screw gauge with a pitch of 0.5 mm and a circular scale with 50 divisions is used to measure the thickness of a
thin sheet of Aluminium. Before starting the measurement, it is found that when the two jaws of the screw gauge
are brought in contact, the 45th division coincides with the main scale line and that the zero of the main scale is
barely visible. What is the thickness of the sheet if the main scale reading is 0.5 mm and the 25th division
coincides with the main scale line?
(1)
0.80 mm
(2)
0.70 mm
(3)
0.50 mm
(4)
0.75 mm
0.5
0.01 mm
50
Zero error 0.5 45 0.01 0.05 mm

L.C. =

Measured reading = 0.5 25 0.01 0.75 mm

Actual reading = Measured reading - Z,E.
0.75mm 0.05 0.80 mm

87.

A roller is made by joining, together two cones at their vertices O. It is kept on

two rails AB and CD which are placed asymmetrically (see figure), with its axis
perpendicular to CD and its centre O at the centre of line joining AB and CD (see
figure). It is given a light push so that it starts rolling with its centre O moving
parallel to CD in the direction shown. As it moves, the roller will tend to:
(1)
turn right.
(2)
go straight.
(3)
turn left and right alternately.
(4)
turn left.

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87.(4)
88.

As the wheel rolls forward the radius of the wheel decreases along AB hence for the same number of rotations it
moves less distance along AB, hence it turns left.
If a, b, c, d are inputs to a gate and x is its output, then, as per the following time graph, the gate is:

(1)
88.(2)

89.

AND

(2)

OR

(3)

NAND

(4)

NOT

Since x 1 if either
a, b, c or d = 1
x a bc d
The gate is OR
For a common emitter configuration, if and have their usual meanings, the incorrect relationship between
and

(1)

89.(1,3) We know that

So
90.

(3)

(4)

1 2

1 1
1

1 1

1 and
are correct
1

A satellite is revolving in a circular orbit at a height h from the earths surface (radius or earth R; h<<R). The
minimum increase in its orbital velocity required, so that the satellite could escape from the earths gravitational
field, is close to : (Neglect the effect of atmosphere)
(1)

90.(3)

(2)

gR

V0

GM
Rh

Ve

2GM
Rh

(2)

Increase required = Ve V0

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GM
2 1

Rh

gR

(3)

gR / 2

30

2 1

2 1

(4)

2gR

gR

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