9701 w04 QP 1 PDF
9701 w04 QP 1 PDF
9701 w04 QP 1 PDF
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9701/01
CHEMISTRY
Paper 1 Multiple Choice
October/November 2004
1 hour
Additional Materials:
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2
Section A
For each question there are four possible answers, A, B, C, and D. Choose the one you consider to
be correct.
1
Granular urea, CON2H4, can be used to remove NO2 from the flue gases of power stations,
converting it into harmless nitrogen.
2CON2H4 + x NO2 2CO2 + y H2O + z N2
What are the values of x, y and z in a balanced equation?
The diagram shows the mass spectrum of a sample of zinc. Use the data to calculate the relative
atomic mass of the sample.
100
80
60
relative
abundance / %
40
20
0
64
66
65
67
Ar
65
65.25
65.5
65.66
The foul smell that skunks spray is due to a number of thiols, one of which is methanethiol,
CH3SH, which burns as follows.
CH3SH + 3O2 CO2 + SO2 + 2H2O
A sample of 10 cm3 of methanethiol was exploded with 60 cm3 of oxygen.
What would be the final volume of the resultant mixture of gases when cooled to room
temperature?
A
20 cm3
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30 cm3
50 cm3
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70 cm3
3
4
209
Bi
208
Pb
210
Po
208
Tl
The gecko, a small lizard, can climb up a smooth glass window. The gecko has millions of
microscopic hairs on its toes and each hair has thousands of pads at its tip. The result is that the
molecules in the pads are extremely close to the glass surface on which the gecko is climbing.
What is the attraction between the geckos toe pads and the glass surface?
co-ordinate bonds
covalent bonds
ionic bonds
What are the bond angles in the PH3 molecule likely to be?
A
90 o
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104 o
109 o
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120 o
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8
Pa
Pa
Pa
Pa
Which of these compounds, on complete combustion of one mole, will release the greatest
amount of energy?
A
CH3CH2CH2OH
CH3CH2CH3
CH3CH2CO2H
CH3COCH3
10 At high temperatures, steam decomposes into its elements according to the following equation.
2H2O(g)
2H2(g) + O2(g)
In one experiment at 1 atm pressure, it was found that 20 % of the steam had been converted into
hydrogen and oxygen.
What are the values of the equilibrium partial pressures, in atm, of the components of this
equilibrium?
partial pressure
of steam
partial pressure
of hydrogen
partial pressure
of oxygen
0.80 x 1
1.0
0.10 x 1
1.0
0.10 x 1
1.0
0.80 x 1
1.0
0.133 x 1
1.0
0.067 x 1
1.0
0.80 x 1
1.0
0.20 x 1
1.0
0.10 x 1
1.0
0.80 x 1
1.1
0.20 x 1
1.1
0.10 x 1
1.1
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11 Which statement concerning the equilibrium reaction below is true?
_
The addition of a catalyst will result in an increase in the concentration of Cr2 O 72 (aq) .
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12 The diagram shows the Boltzmann distribution for air at room temperature.
fraction of
molecules
energy
Air inside a car engine can reach a temperature of about 500 C, enabling nitrogen to react with
oxygen to form nitrogen oxides.
What would be the Boltzmann distribution for the air inside this car engine?
fraction of
molecules
fraction of
molecules
energy
fraction of
molecules
fraction of
molecules
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energy
energy
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energy
7
13
burette
conical flask
Which of these acid-base (neutralisation) reactions could be titrated using the apparatus shown
above to give a sharp end-point?
A
14 The species Ar, K+ and Ca2+ are isoelectronic (have the same number of electrons).
largest
Ar
Ca2+
K+
Ar
K+
Ca2+
Ca2+
K+
Ar
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Ar
Ca
2+
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15 Strontium metal can be obtained by the electrolysis of molten strontium bromide, SrBr2, using the
apparatus shown in the diagram.
steel cathode
atmosphere of
argon
graphite anode
molten strontium
molten
strontium
bromide
heat
Why is an atmosphere of argon used around the cathode?
A
The argon stops the molten strontium rising too high in the tube.
A thin film of a compound of strontium and argon forms on the surface protecting the freshly
formed metal.
heat
2NaCl + NaCl O3
weedkiller
+5
+1
+5
+1
+7
+2
+1
+7
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17 The following report appeared in a newspaper.
Drums of bromine broke open after a vehicle crash on the motorway. Traffic was diverted as
purple gaseous bromine drifted over the road (it is denser than air), causing irritation to
drivers eyes. Firemen sprayed water over the scene of the accident, dissolving the bromine
and washing it away.
What is wrong with the report?
A
18 Which reaction of ammonia does not involve the non-bonding pair of electrons on the nitrogen
atom?
A
19 Ammonium sulphate in nitrogenous fertilisers in the soil can be slowly oxidised by air producing
sulphuric acid, nitric acid and water.
How many moles of oxygen are needed to oxidise completely one mole of ammonium sulphate?
A
Br2
Na
NH3
CN
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21 Which molecule does not have a chiral centre?
CO2H
CO2H
OH
OH
HO
OH
CO2H
CH3
D
OH
OH
OH
OH
C
C
HO
HO
CH3
CO2C2H5
22 Instead of obtaining buta-1,3-diene from fossil fuel sources, it is proposed to obtain it from
ethanol, which can be obtained from nonfood agricultural crops. The sequence of reactions is as
follows.
step I
step II
CH3CH2OH
CH3CHO
step III
CH3CH(OH)CH2CHO
CH2=CHCH=CH2
buta-1,3-diene
condensation
dehydration
dehydrogenation
hydrogenation
23 How many different substitution products are possible, in principle, when a mixture of bromine
and ethane is allowed to react?
A
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24 This molecule is responsible for the flavour of spearmint chewing gum.
CH3
C
X
H
C H
H C
H
H
C
H
C
H
C
H
H
catalytic hydrogenation
polymerisation
thermal cracking
26 The reaction of chlorine with methane is carried out in the presence of light.
What is the function of the light?
A
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27 Use of the Data Booklet is relevant to this question.
Which of the bonds in the structure below has the lowest bond energy?
H
A
H
C
H
C
C
Cl
28 Which isomer of C5H11OH gives, on dehydration, the greatest number of different alkenes?
A
CH3
CH2
CH
CH2OH
CH3
B
CH3
CH2
CH2 CH
CH3
OH
C
CH3
CH2
CH
CH2 CH3
OH
D
CH3
CH
CH2 CH2OH
CH3
H
H
H
H
Br2(aq)
2,4-dinitrophenylhydrazine
NaBH4
Tollens reagent
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30 Acarol is sold as an insecticide for use on fruit and vegetables.
CH3
OH O
Br
CH
CH3
Br
Acarol
di(4-bromophenyl)methanol
methanol
propan-1-ol
propan-2-ol
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Section B
For each of the questions in this section, one or more of the three numbered statements 1 to 3 may
be correct.
Decide whether each of the statements is or is not correct (you may find it helpful to put a tick against
the statements that you consider to be correct).
The responses A to D should be selected on the basis of
A
1, 2 and 3
are
correct
1 and 2
only are
correct
2 and 3
only are
correct
1 only
is
correct
H = +92 J mol
H = _75 kJ mol
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32 Ammonia is produced commercially by the Haber process in which nitrogen and hydrogen react
as shown.
2NH3(g) ; H = 92 kJ mol1
N2(g) + 3H2(g)
33 What factors can affect the value of the activation energy of a reaction?
1
changes in temperature
34 The first ionisation energies of successive elements in the Periodic Table are represented in the
graph.
2500
2000
1500
first ionisation
_
energy / kJ mol 1
1000
500
A B C D E F G H
L M N O P Q R S
element
Which of these statements about this graph are correct?
1
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The responses A to D should be selected on the basis of
A
1, 2 and 3
are
correct
1 and 2
only are
correct
2 and 3
only are
correct
1 only
is
correct
36 Which properties in the sequence hydrogen chloride, hydrogen bromide and hydrogen iodide
steadily increase?
1
thermal stability
bond length
ease of oxidation
37 Which compounds may result from mixing ethane and chlorine in the presence of sunlight?
1
CH3CH2Cl
CH3CH2CH2CH3
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38 When halogenoalkanes, RX, are hydrolysed with NaOH, the corresponding sodium halide, NaX,
is produced.
RX + NaOH ROH + NaX
A student investigated the amount of NaX produced by hydrolysing CH3CH2Cl and another
halogenoalkane, Y. In a given time the amount of sodium halide formed was greater with Y than
with CH3CH2Cl.
number of
moles of
NaX formed
CH3CH2Cl
time
Cl CH2CH2Cl
CH3CH2Br
CH3CH2I
CH2OH
CH2OH
pentaerythritol
Which of the following statements about pentaerythritol are correct?
1
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The responses A to D should be selected on the basis of
A
1, 2 and 3
are
correct
1 and 2
only are
correct
2 and 3
only are
correct
1 only
is
correct
pyruvic acid
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lactic acid
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BLANK PAGE
University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES) which is itself a department of
the University of Cambridge.
9701/01/O/N/04