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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Advanced Subsidiary Level and Advanced Level 9701/11
May/June 2010 1 hour Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended) Data Booklet

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CHEMISTRY Paper 1 Multiple Choice

*9264472640*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet.

This document consists of 14 printed pages and 2 blank pages.

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2 Section A For each question there are four possible answers, A, B, C, and D. Choose the one you consider to be correct. 1 Use of the Data Booklet is relevant to this question. What could be the proton number of an element that has three unpaired electrons in each of its atoms? A 2 5 B 13 C 15 D 21

Use of the Data Booklet is relevant to this question. The elements radon (Rn), francium (Fr) and radium (Ra) have consecutive proton numbers in the Periodic Table. What is the order of their first ionisation energies? least endothermic A B C D Fr Fr Ra Rn Ra Rn Fr Ra most endothermic Rn Ra Rn Fr

Which gas closely approaches ideal behaviour at room temperature and pressure? A B C D ammonia carbon dioxide helium oxygen

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3 4 Some bond energy values are listed below. bond CH CCl ClCl BrBr bond energy / kJ mol1 410 340 244 193

These bond energy values relate to the following four reactions. P Q R S Br2 2Br 2Cl Cl2 CH3 + Cl CH3Cl CH4 CH3 + H

What is the order of enthalpy changes of these reactions from most negative to most positive? A B C D 5 PQRS QRSP RQPS SPQR

Given the following enthalpy changes, I2(g) + 3Cl2(g) 2ICl3(s) I2(s) I2(g) Ho = 214 kJ mol1 Ho = +38 kJ mol1

What is the standard enthalpy change of formation of iodine trichloride, ICl3(s)? A B C D 6 +176 kJ mol1 88 kJ mol1 176 kJ mol1 214 kJ mol1

Ammonium nitrate, NH4NO3, can decompose explosively when heated. NH4NO3 N2O + 2H2O What are the changes in the oxidation numbers of the two nitrogen atoms in NH4NO3 when this reaction proceeds? A 2, 4 B +2, +6 C +4, 6 D +4, 4

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4 7 The Haber process for the manufacture of ammonia is represented by the following equation. N2(g) + 3H2(g) 2NH3(g) H = 92 kJ mol1

Which statement is correct about this reaction when the temperature is increased? A B C D 8 Both forward and backward rates increase. The backward rate only increases. The forward rate only increases. There is no effect on the backward or forward rate.

Use of the Data Booklet is relevant to this question. 2.920 g of a Group II metal, X, reacts with an excess of chlorine to form 5.287 g of a compound with formula XCl2. What is metal X? A B C D barium calcium magnesium strontium

Which mass of gas would occupy a volume of 3 dm3 at 25 C and 1 atmosphere pressure? [1 mol of gas occupies 24 dm3 at 25 C and 1 atmosphere pressure.] A B C D 3.2 g O2 gas 5.6 g N2 gas 8.0 g SO2 gas 11.0 g CO2 gas

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5 10 The table gives the concentrations and pH values of the aqueous solutions of two compounds, X and Y. Either compound could be an acid or a base. X concentration pH Student P concluded that X is a strong acid. Student Q concluded that the extent of dissociation is lower in X(aq) than in Y(aq). Which of the students are correct? A B C D both P and Q neither P nor Q P only Q only 2 mol dm3 6 Y 2 mol dm3 9

11 Swimming pool water can be kept free of harmful bacteria by adding aqueous sodium chlorate(I), NaOCl. This reacts with water to produce HOCl molecules which kill bacteria. OCl (aq) + H2O OH(aq) + HOCl (aq)

In bright sunshine, the OCl ion is broken down by ultra-violet light. OCl (aq) + uv light Cl (aq) + O2(g) Which method would maintain the highest concentration of HOCl (aq)? A B C D acidify the pool water add a solution of chloride ions add a solution of hydroxide ions bubble air through the water

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6 12 Na2S2O3 reacts with dilute HCl to give a pale yellow precipitate. If 1 cm3 of 0.1 mol dm3 HCl is added to 10 cm3 of 0.02 mol dm3 Na2S2O3 the precipitate forms slowly. If the experiment is repeated with 1 cm3 of 0.1 mol dm3 HCl and 10 cm3 of 0.05 mol dm3 Na2S2O3 the precipitate forms more quickly. Why is this? A B C D The activation energy of the reaction is lower when 0.05 mol dm3 Na2S2O3 is used. The reaction proceeds by a different pathway when 0.05 mol dm3 Na2S2O3 is used. The collisions between reactant particles are more violent when 0.05 mol dm3 Na2S2O3 is used. The reactant particles collide more frequently when 0.05 mol dm3 Na2S2O3 is used.

13 How does concentrated sulfuric acid behave when it reacts with sodium chloride? A B C D as an acid only as an acid and oxidising agent as an oxidising agent only as a reducing agent only

14 X is a salt of one of the halogens chlorine, bromine, iodine, or astatine (proton number 85). The reaction scheme shows a series of reactions using a solution of X as the starting reagent.
X HNO3(aq) AgNO3(aq) a precipitate an excess of dilute NH3(aq) a colourless solution an excess of HNO3(aq) a precipitate

What could X be? A B C D sodium chloride sodium bromide potassium iodide potassium astatide

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7 15 The percentage of ammonia obtainable, if equilibrium were established during the Haber process, is plotted against the operating pressure for two temperatures, 400 C and 500 C. Which diagram correctly represents the two graphs?

A 40 % NH3 at 20 equilibrium 400 C 500 C 40 % NH3 at 20 equilibrium

B 500 C 400 C

0 0 10 20 pressure / 103 kPa

0 0 10 20 pressure / 103 kPa

C 40 % NH3 at 20 equilibrium 500 C 0 0 10 20 pressure / 103 kPa 400 C 40 % NH3 at 20 equilibrium

D 500 C

400 C 0 0 10 20 pressure / 103 kPa

16 Consecutive elements X, Y, Z are in the third period of the Periodic Table. Element Y has the highest first ionisation energy and the lowest melting point. What could be the identities of X, Y and Z? A B C D aluminium, silicon, phosphorus magnesium, aluminium, silicon silicon, phosphorus, sulfur sodium, magnesium, aluminium

17 Which property of Group II elements (beryllium to barium) decreases with increasing atomic number? A B C D reactivity with water second ionisation energy solubility of hydroxides stability of the carbonates

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8 18 Which element of the third period requires the least number of moles of oxygen for the complete combustion of 1 mol of the element? A B C D aluminium magnesium phosphorus sodium

19 Two properties of non-metallic elements and their atoms are as follows. property 1 property 2 has an oxide that can form a strong acid in water has no paired 3p electrons

Which properties do phosphorus and sulfur have? phosphorus A B C D 1 and 2 1 only 1 and 2 2 only sulfur 1 only 1 and 2 1 and 2 1 only

20 When gaseous chemicals are transported by road or by rail they are classified as follows. flammable non-flammable poisonous

Which commonly transported gas is non-flammable? A B C D butane hydrogen oxygen propene

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9 21 When heated with chlorine, the hydrocarbon 2,2-dimethylbutane undergoes free radical substitution. In a propagation step the free radical X is formed.
CH3 CH3CH2 C CH3 CH3 + Cl X + HCl

How many different forms of X are possible? A 1 B 2 with C the 3 two D isomeric 4 alcohols, (CH3)3CCH2OH and

22 What will react differently (CH3)2CHCH2CH2OH? A B C D

acidified aqueous potassium manganate(VII) concentrated sulfuric acid phosphorus pentachloride sodium

23 Which reagent will give similar results with both butanone and butanal? A B C D acidified aqueous potassium dichromate(VI) an alkaline solution containing complexed Cu2+ ions (Fehlings solution) an aqueous solution containing [Ag(NH3)2]+ (Tollens reagent) 2,4-dinitrophenylhydrazine reagent

24 What is formed when propanone is refluxed with a solution of NaBH4? A B C D propanal propan-1-ol propan-2-ol propane

25 Which compound is a product of the hydrolysis of CH3CO2C3H7 by boiling aqueous sodium hydroxide? A CH3OH B C3H7OH C C3H7CO2H D
C3H7CO 2 Na +

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10 26 In many countries plastic waste is collected separately and sorted. Some of this is incinerated to provide heat for power stations. Why is pvc, polyvinylchloride, removed from any waste that is to be incinerated? A B C D It destroys the ozone layer. It does not burn easily. It is easily biodegradable. Its combustion products are harmful.

27 Polymerisation of 1,1-dichloroethene produces a dense, high melting point substance that does not allow gases to pass through. It is used as cling wrapping. Which sequence appears in a short length of the polymer chain?
A B C D [ CH2CCl2CH2CCl2CH2CCl2 ] [ CHClCHClCHClCHClCHClCHCl ] [ CCl2CCl2CCl2CCl2CCl2CCl2 ] [ CH2CCl2CHClCHClCH2CCl2 ]

28 When an isomer Y of molecular formula C4H9Br undergoes hydrolysis in aqueous alkali to form an alcohol C4H9OH, the rate of reaction is found to be unaffected by changes in the concentration of OH ions present. Which is the most likely molecular structure of Y? A B C D CH3CH2CH2CH2Br CH3CH2CHBrCH3 (CH3)2CHCH2Br (CH3)3CBr

29 Which isomer of C4H10O forms three alkenes on dehydration? A B C D butan-1-ol butan-2-ol 2-methylpropan-1-ol 2-methylpropan-2-ol

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11 30 Which compound exhibits both cis-trans and optical isomerism? A B C D CH3CH=CHCH2CH3 CH3CHBrCH=CH2 CH3CBr=CBrCH3 CH3CH2CHBrCH=CHBr

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12 Section B For each of the questions in this section, one or more of the three numbered statements 1 to 3 may be correct. Decide whether each of the statements is or is not correct (you may find it helpful to put a tick against the statements that you consider to be correct). The responses A to D should be selected on the basis of A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response. 31 Which diagrams represent part of a giant molecular structure?
1 =C 2 =C 3 = Na = Cl

32 Which reactions are redox reactions? 1 2 3 CaBr2 + 2H2SO4 CaSO4 + Br2 + SO2 + 2H2O CaBr2 + 2H3PO4 Ca(H2PO4)2 + 2HBr CaBr2 + 2AgNO3 Ca(NO3)2 + 2AgBr

33 Sodium hydrogensulfide, NaSH, is used to remove hair from animal hides. Which statements about the SH ion are correct? 1 2 3 It contains 18 electrons. Three lone pairs of electrons surround the sulfur atom. Sulfur has an oxidation state of +2.

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13 34 When organic refuse decomposes in water carboxylic acids are formed. The water becomes acidic and aquatic life is destroyed. Which additives are suitable to remove this acid pollution? 1 2 3 calcium carbonate calcium hydroxide potassium nitrate

35 In a car engine, non-metallic element X forms a pollutant oxide Y. Further oxidation of Y to Z occurs in the atmosphere. In this further oxidation, 1 mol of Y reacts with mol of gaseous oxygen. What can X be? 1 2 3 carbon nitrogen sulfur

36 Sulfur dioxide and sulfites are used in food preservation. Why are they used for this purpose? 1 2 3 They are reducing agents so retard the oxidation of food. They inhibit the growth of aerobic bacteria. They react with NO2(g) converting it to NO(g).

37 Propanoic acid occurs naturally as a result of the bacterial fermentation of milk, and is partly responsible for the flavour of Swiss cheese.
O OH propanoic acid

Which starting materials could be used to synthesise propanoic acid? 1 2 3 CH3CH2CH2OH CH3CH2CN CH3CH2CHO

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14 The responses A to D should be selected on the basis of A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response. 38 Which structural formulae represent 2,2-dimethylpentane? 1 2 3 (CH3)2CHCH2CH(CH3)2 (CH3)3CCH2CH2CH3 CH3CH2CH2C(CH3)3

39 Which reactions are examples of nucleophilic substitution? 1 2 3 CH3CH2Br + OH CH3CH2OH + Br

H+ CH3OH + HI CH3I + H2O

40 The diagram shows some laboratory apparatus.

water

heat

Which preparations could this apparatus be used for? 1 2 3 bromoethane, from ethanol, sodium bromide and concentrated sulfuric acid ethanal, from ethanol, sodium dichromate(VI) and sulfuric acid 1,2-dibromoethane, from bromine and ethene

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Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

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