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ANDERSON JUNIOR COLLEGE Preliminary Examination 2008

CHEMISTRY Higher 2 Paper 1 Multiple Choice Additional Materials: Multiple Choice Optical Answer Sheet Data Booklet

9746/01 15 Sep 2008 1 hour

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the Optical Answer Sheet. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet.

Optical Answer Sheet Write your name and PDG. Shade the last 5 digits of your NRIC / FIN number. DO NOT shade the reference letter.

This document consists of 14 printed pages.

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Section A For each question there are four possible answers, A, B, C and D. Choose the one you consider to be correct. 1 To determine the mass of arsenic present in a sample of pesticide, all the arsenic was first converted to arsenate ion, AsO43-. 1.25 10-3 moles of AgNO3 was then added to precipitate AsO43- as Ag3AsO4. The excess Ag+ ions needed 3.64 cm3 of 0.054 mol dm-3 KSCN to form silver thiocyanate, AgSCN. Calculate the mass of arsenic (Ar = 74.9) present in the sample of pesticide. A 2 0.015 g B 0.026 g C 0.079 g D 0.488 g

An aqueous solution contains 1 mole of S2O32- ions and this reduces 4 moles of Cl2 molecules. What is the sulphur-containing product of this reaction? A SO2 B SO32C SO42D S4O62-

Three identical flasks each contains the same mass of gases E, F and G respectively. The temperature and pressure of each flask are indicated below.

Gas E
Temperature / oC Pressure / atm t p

Gas F
t 2p

Gas G
2t p

Assuming ideal gas behaviour, which of the following is a correct representation of the relative molecular masses of the three gases? A B C D 4 Mr(G) > Mr(E) > Mr(F) Mr(G) > Mr(F) > Mr(E) Mr(E) > Mr(F) > Mr(G) Mr(E) > Mr(G) > Mr(F)

The ion X2+ has 54 electrons and 81 neutrons. Which of the following statements is true? A B C D Element X is isoelectronic with xenon. The first ionization energy of element X is higher than that of Mg. The oxide of X formed is expected to have a higher melting point than MgO. In an electric field, the ion X2+ will be deflected at a smaller angle than that of Mg2+.

Which of the following statements cannot be explained by hydrogen bonding? A B C D Ice has a density lower than water at 0 oC. The boiling point of 2-nitrophenol is lower than that of 4-nitrophenol. The boiling point of ethanal is higher than dimethyl ether, CH3OCH3. The relative molecular mass of ethanoic acid is 120 when dissolved in benzene.
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6 Which of the following pairs of substances does not include a giant structure and a simple molecular structure? A B C D 7 aluminum and silicon(IV) oxide aluminium oxide and aluminium chloride silicon and chlorine silicon and silicon(IV) chloride

Given the following enthalpy changes CH3CH3 CH3CH2 CH3CH2 + H CH2=CH2 + H H = +412 kJ mol-1 H = +168 kJ mol-1

What is the enthalpy change of the following reaction? 2 CH3CH2 A 8 +412 kJ mol-1 CH3CH3 + CH2=CH2 B +244 kJ mol-1 C 244 kJ mol-1 D 412 kJ mol-1

A simple rechargeable battery is constructed by dipping two lead electrodes into aqueous lead(II) nitrate and passing current through it for a few minutes. When it is fully charged, lead(IV) oxide is deposited on one of the electrodes. During normal usage, a voltage of +1.60V is produced and the following reactions occur: Anode: Cathode: Pb Pb2+ + 2e Pb2+ + 2H2O

PbO2 + 4H+ + 2e

Which of the following changes can be made to the cell to increase the e.m.f.? A B C D 9 Increasing the size of the lead electrodes Using a higher current during charging of the battery Using a higher concentration of lead(II) nitrate Replacing the electrolyte with dilute sulphuric acid

The circuit shown in the diagram was set up.

an alloy of copper and tin dilute sulphuric acid Which reactions will occur at the electrodes? anode reaction Oxygen gas is evolved. Tin dissolves preferentially. Copper dissolves preferentially. Copper and tin both dissolve.

platinum

A B C D

cathode reaction Hydrogen gas is evolved. Hydrogen gas is evolved. Copper is deposited. Sulphur dioxide gas is evolved.
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10 The following reaction is used industrially to produce a combustible gas from coal. H2O(g) + C(s) H2(g) + CO(g)

At equilibrium, the partial pressure of each gaseous species is p atm at 500oC. When the total pressure of the system was increased at the same temperature, the partial pressure of the H2O(g) increased to 4p atm at the new equilibrium. What would be the partial pressure of CO(g) at the new equilibrium? A B C D 11 0.5p atm p atm 2p atm 4p atm

J and L can react together to reach equilibrium in the reaction below. J(g) + L(g) M(g) + N(g)

In an experiment, 1.0 mole each of J and L were reacted at constant pressure P and temperature 350 oC. The amount of N present in the mixture was recorded at regular intervals of time. The experiment was repeated at the same pressure P, but at a temperature of 700 oC. The results for both experiments are shown below.
1.0

number of moles of N 0.6

0.8

350 oC

700 oC

time

Which of the following information cannot be deduced from the graph? A B C D 12 The activation energy of the forward reaction is high. The forward reaction is exothermic. The value of Kp at 350 oC is 5.44. The time taken for the equilibrium to be achieved is shorter at higher temperatures.

A solution, saturated with Ca(OH)2 and CaSO4, has a pH of 12.3. What is the concentration, in mol dm-3, of SO42- ions in the solution? (Ksp value of Ca(OH)2 = 4.0 x 10-5, Ksp value of CaSO4 = 2.5 x 10-5) A B C D 1.25 x 10-4 2.50 x 10-4 1.25 x 102 2.50 x 102

AJC/H2 Chemistry/Prelims2008

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13 The pH change when 0.100 mol dm-3 CH3COOH is added dropwise to 10.0 cm3 of 0.100 mol dm-3 NaOH(aq) is shown below. At which point on the graph does pH = pKa, where Ka is the acid dissociation constant of the weak acid?
14

A
12 10 8 pH 6 4 2 0 0 2 4 6 8 10
-3

B C

12

14

16
3

18

20

volume of 0.100 mol dm CH3COOH added/cm

14

For the reaction P + 2Q

R + S, the rate equation is found experimentally to be: rate = k[P]

If the reaction is carried out using excess P, which of the following graphs most correctly represents the change in concentration of Q with time? A B

[Q]

[Q]

time

time

[Q]

[Q]

time

time

AJC/H2 Chemistry/Prelims2008

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15 Beryllium resembles aluminium in its chemical properties. Which property of beryllium compounds is unlikely to be correct? A B C D 16 Beryllium oxide can undergo reaction with acids. Beryllium oxide can undergo reaction with alkali. Beryllium chloride can form a dimer. Beryllium chloride is an ionic compound.

Which graph correctly shows the variation of the radii of the species shown? A B

17

Magnesium oxide is insoluble in water whereas barium oxide dissolves to give an alkaline solution. Which factor accounts for the difference in the behaviour of magnesium oxide and barium oxide in water? A B C D The magnitude of the lattice energy of magnesium oxide is larger than that of barium oxide. The first and second ionisation energies of magnesium are larger than that of barium. Magnesium is less electropositive than barium. The enthalpy change of hydration of magnesium ion is less exothermic than that of barium ion.

AJC/H2 Chemistry/Prelims2008

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18 Consider the following reaction route. T (aq) hot aqueous KOH AgNO3 (aq) precipitate dilute NH3 (aq) What could solutions T, U and V be? T Cl2 Cl2 I2 I2 U KCl KCl KI KI V KClO KClO3 KIO KIO3 colourless solution U (aq) + V (aq)

A B C D 19

Letters written on paper using aqueous ammonium thiocyanate are invisible until turned blood red by brushing the paper with aqueous iron(III) chloride. If the ammonium thiocyanate is first made alkaline, the letters are orange and less clear. Which of the following substances, when formed on the paper in these reactions, best explains these observations? with aqueous ammonium thiocyanate [Fe(SCN)(H2O)5]2+ [Fe(SCN)(H2O)5]2+ [Fe(SCN)(NH3)5]2+ [Fe(SCN)(NH3)5]2+ with alkaline aqueous ammonium thiocyanate [Fe(SCN)(OH)(H2O)4]+ Fe(OH)3 Fe(OH)3 [Fe(NH3)6]3+

A B C D 20

How many alkenes (both structural isomers and stereoisomers) can be obtained from the molecular formula C5H10? A 4 B 5 C 6 D 7

21

Chlorofluorocarbons (CFCs) are commonly used as aerosols, propellants and refrigerants. However in the stratosphere, CFCs can damage the ozone layer through a radical chain reaction. In which sequence are the following compounds listed in increasing order of their ability to destroy ozone? A B C D CHClFCClF2 CCl2FCCl2F CHClF2 CHClF2 < < < < CCl2FCCl2F CHClF2 CCl2FCCl2F CHClFCClF2 < < < < CHClF2 CHClFCClF2 CHClFCClF2 CCl2FCCl2F

AJC/H2 Chemistry/Prelims2008

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The reaction between boiling methylbenzene and chlorine takes place in a number of steps to give several products. Which of the following could be one of the steps?
CH3 CH3 + Cl CH3
+

22

+
CH3

H Cl

Cl

+
H Cl CHCl 2 + CH2Cl Cl

CHCl

+ CH2

Cl 2

HCl

23

When ethene reacts with bromine in the presence of concentrated aqueous sodium nitrate, the product contains the following compound.

H H C

H C H

ONO2 Br
What is the intermediate formed in this reaction? A
H H C H C H Br

H H C ONO2

H C H

H H C ONO2

H C H

H H C

H C H Br

AJC/H2 Chemistry/Prelims2008

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A halogen compound, W, is heated in a sealed tube with ammonia while a nitrile, X, is reacted with lithium aluminium hydride in dry ether. Which of the following pairs of W and X give the same product? W BrCH2CO2H CH3OCH2CH2F (CH3)2CHCl C6H5CHICH2CH3 X HO2CCH2CN CH3OCH2CN (CH3)2CHCN C6H5CH(CN)CH2CH3

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A B C D 25

Salbutamol is used as a temporary relief of bronchospasm in asthmatic patients.

Salbutamol Which deduction about salbutamol can be made from this structure? A B C D 26 1 mole of salbutamol reacts with 4 moles of dilute HNO3. The product of oxidation with acidified potassium manganate(VII) gives a red brown precipitate with Fehlings solution. It undergoes dehydration with hot Al2O3 to form an alkene. It turns reddish brown bromine solution colourless.

A compound Y, C8H10O, gives compound Z, C8H8O, on oxidation. Both Y and Z give a yellow precipitate on warming with aqueous alkaline iodine. Which of the following could be Y? A B C D 2,4-dimethylphenol 3-ethylphenol 1-phenylethanol 2-phenylethanol

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Why does hydrogen cyanide add to propanone but not to propene? A B C D Propanone is more susceptible to CN attack than propene. The addition product formed with propene would not be stable. Propanone is more susceptible to H+ attack than propene. The two methyl groups in propanone exert a stronger electron-donating effect than the single methyl group in propene.

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28

Which sequence shows the organic compounds in decreasing order of acid strength? strongest A B C D
CH2OH

weakest
Cl COOH
OH

CH2OH

OH

Cl

COOH

Cl
Cl

COOH
COOH

CH2OH
OH

OH

CH2OH

29

The structure of a tripeptide, tyrosylglycylalanine, is shown below.

HO

+ CH2CH(NH3)CONHCH2CONHCH(CH3)CO2

Which compound could be obtained when the tripeptide reacts with hot dilute NaOH? A B C D NH2CH2CO2H O2CNHCH2CO2
HO CH2CH2NH2

CH2CH(NH2)CONHCH2CO2

30

Which pair of amino-acid residue has an interaction which is likely to be broken during denaturation of protein due to a change in pH?
A B

NH O CH2

NH

CH2 H2C CH2

+ CH and H3N (CH2)4 CH CO CO

CH and O2C CH2 CO

NH CH CO

NH HS CH2 CH and HS CH2 CO

NH CH CO
HO CH2

NH CH and CO HS CH2

NH CH CO

AJC/H2 Chemistry/Prelims2008

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Section B

For each of the questions in this section, one or more of the three numbered statements 1 to 3 may be correct. Decide whether each of these statements is or is not correct (you may find it helpful to put a tick against the statements that you consider to be correct). The responses A to D should be selected on the basis of
A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response.

For which of the following pairs does species I have a smaller bond angle than species II?
I NO2H2S PH4+ II NO2+ SO2 ICl4-

1 2 3 32

The radius and charge of six ions are given below. Ion Radius / nm
J+ L+ M2+ XYZ2-

0.14

0.18

0.15

0.14

0.18

0.15

The ionic solids MZ, JX and LY are of the same lattice type. Which of the following statements are correct?
1 2 3 33

The melting point of JX is higher than that of LY. The numerical value of the lattice energy of MZ is greater than that of JX. The numerical value of the hydration energy of J+ is smaller than that of M2+.

The value of the ionic product of water, Kw, varies with temperature. temperature / C 25 62 Which of the following statements are correct?
1 2 3 Kw / mol2 dm-6

1.00 x 10-14 1.00 x 10-13

The concentration of H+(aq) is greater than the concentration of OH-(aq) at 62 C. The pH of pure water at 62 C is smaller than 7. The ionic dissociation of water is an endothermic process.

AJC/H2 Chemistry/Prelims2008

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The responses A to D should be selected on the basis of
A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response.

The activation energy of a reaction is usually

different for the forward and reverse reactions in an endothermic process. high for a reaction that takes place slowly. unaffected by a change in temperature.

35

Which statements concerning the element astatine (proton number 85) are consistent with its position in Group VII?
1 2 3

The element is a solid at room temperature and pressure. Hydrogen astatide is more acidic than hydrogen chloride. Astatine and aqueous potassium chloride react to form aqueous potassium astatide and chlorine.

36

The Cl in [CoCl(NH3)5]2+ acts as a good bridging ligand to [Cr(H2O)6]2+ to produce a bridged complex intermediate as shown below.
NH3
NH3

OH2
OH2

m+ OH2

H3N

Co NH3

Cl

Cr OH2

H3N

H2O

Which of the following deduction can be made from the structure of this complex intermediate?
1 2 3

The chromium ion has been reduced. The complex intermediate is an ion with a charge of 4+. Cl is a good bridging ligand since it contains more than one lone pair of electrons.

AJC/H2 Chemistry/Prelims2008

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The responses A to D should be selected on the basis of
A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response.

Three halogen compounds P, Q and R were heated separately with aqueous sodium hydroxide followed by the addition of aqueous silver nitrate to the resultant mixture. The following observations were recorded. Compound CH3CH2Cl CH3CH2I
Observations white precipitate

P Q R

yellow precipitate no precipitate

Br

Which of the following statements are correct?

The reaction of NaOH(aq) with P and Q is an example of nucleophilic substitution. The yellow precipitate takes a longer time to appear than the white precipitate.
R gives HO

Br after reacting with NaOH(aq).

38

Reversatrol is an insect repellent which is emitted by damaged plants.

Which statements about reversatrol are correct?

Its aqueous solution is acidic. It exists as a pair of stereoisomers. It reacts with 3 moles of ethanol in the presence of concentrated sulphuric acid to give an ester.

39

Which reaction yields a carbon compound containing deuterium, D? [D = 2H]

CH3COCH3
CH3COCI3

LiAlD4
NaOD D2O

CH3CD(OD)CO2H

acidified KMnO4 heat

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The responses A to D should be selected on the basis of
A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct

No other combination of statements is used as a correct response.

Prednisone is a steroid used to reduce unwanted swelling by decreasing the bodys ability to fight infections. OH O CH2 CH3 C OH O
CH3

Predisone

Which of the following statements about prednisone is not correct?

A yellow precipitate is formed on warming with aqueous, alkaline iodine. 2 moles of H2O molecules are obtained on heating with excess concentrated sulphuric acid. Prednisone forms an orange precipitate with 2,4-dinitrophenylhydrazine.

AJC/H2 Chemistry/Prelims2008

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