Acetylene Gas C2H2 Safety Data Sheet SDS P4559
Acetylene Gas C2H2 Safety Data Sheet SDS P4559
Acetylene Gas C2H2 Safety Data Sheet SDS P4559
Supersedes: 07/01/2014
Product identifier
Product form
: Substance
Name
: Acetylene, dissolved
CAS No
: 74-86-2
Formula
: C2H2
1.2.
Relevant identified uses of the substance or mixture and uses advised against
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1.4.
Emergency number
Classification (GHS-US)
Flam. Gas 1 H220
Dissolved gas H280
Full text of H-phrases: see section 16
2.2.
Label elements
GHS-US labeling
Hazard pictograms (GHS-US)
: Danger
: P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, Open flames, sparks, hot surfaces. - No smoking
P271+P403 - Use and store only outdoors or in a well-ventilated place.
P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 - Eliminate all ignition sources if safe to do so
P501 - Dispose of contents/container in accordance with container supplier/owner instructions
CGA-PG05 - Use a back flow preventive device in the piping.
CGA-PG13 - Fusible plugs in the top, bottom, or valve melt at 98C to 107C (208F to 224F).
Do not discharge at pressures above 15 psig (103 kPa).
CGA-PG06 - Close valve after each use and when empty.
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SDS ID: P-4559
GHS02
EN (English US)
GHS04
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Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Supersedes: 07/01/2014
Other hazards
2.4.
: For safety reasons, the acetylene is dissolved in acetone (CAS # 67-64-1; Flam. Liq. 2, Eye
Irrit. 2, STOT SE 3) in the gas container. Vapor of the solvent is carried away as impurity when
the acetylene is extracted from the gas container. The concentration of the solvent vapor in the
gas is lower than the concentration limits to change the classification of the acetylene.
Substance
Name
Product identifier
Acetylene, dissolved
100
(Main constituent)
3.2.
Mixture
Not applicable
: Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
: For exposure to liquid, immediately warm frostbite area with warm water not to exceed 105F
(41C). Water temperature should be tolerable to normal skin. Maintain skin warming for at
least 15 minutes or until normal coloring and sensation have returned to the affected area. In
case of massive exposure, remove clothing while showering with warm water. Seek medical
evaluation and treatment as soon as possible.
: Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Get immediate
medical attention.
4.2.
4.3.
Extinguishing media
: See below. See CGA Pamphlet SB-4, Handling Acetylene Cylinders in Fire Situations, for
further information.
Fire hazard
: EXTREMELY FLAMMABLE GAS. If venting or leaking gas catches fire, do not extinguish
flames. Flammable vapors may spread from leak, creating an explosive reignition hazard.
Vapors can be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical
equipment, static discharge, or other ignition sources at locations distant from product handling
point. Explosive atmospheres may linger. Before entering an area, especially a confined area,
check the atmosphere with an appropriate device.
Explosion hazard
: EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and oxidizing agents.
Reactivity
EN (English US)
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2/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
5.3.
Supersedes: 07/01/2014
Firefighting instructions
: Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
LFire Protection.
: Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters.
Specific methods
: Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas containers to rupture. Cool endangered containers with water spray jet
from a protected position. Prevent water used in emergency cases from entering sewers and
drainage systems. Stop flow of product if safe to do so. Use water spray or fog to knock down
fire fumes if possible. Continue water spray from protected position until container stays cool.
Other information
: Acetylene containers are provided with pressure relief devices designed to vent contents when
exposed to elevated temperature.
General measures
6.1.1.
: Wear self-contained breathing apparatus when entering area unless atmosphere is proven to
be safe. Evacuate area. Ensure adequate ventilation. Stop leak if safe to do so.
6.1.2.
6.2.
Environmental precautions
Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Contact supplier for any special requirements.
6.3.
6.4.
: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use only non-sparking tools. Use only explosion-proof equipment.
Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g., wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
EN (English US)
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3/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
7.2.
Supersedes: 07/01/2014
Storage conditions
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in
the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use
with adequate ventilation. If a leak occurs, close the container valve and blow down the system
in a safe and environmentally correct manner in compliance with all international,
federal/national, state/provincial, and local laws; then repair the leak. Never place a container
where it may become part of an electrical circuit.
Storage area
7.3.
: Acetylene trailers are designed and intended for outdoor use. Acetylene storage in excess of
2.500 cu ft (70.79 cubic meters) is prohibited in buildings and other occupancies.
Control parameters
Not established
Exposure controls
Eye protection
: As needed for welding, wear hand, head, and body protection to help prevent injury from
radiation and sparks. (See ANSI Z49.1.) At a minimum, this includes welders gloves and
protective goggles, and may include arm protectors, aprons, hats, and shoulder protection as
well as substantial clothing.
Respiratory protection
: When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an
organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a
self-contained breathing apparatus (SCBA).
: Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
specific methods for waste gas treatment.
Other information
: Consider the use of flame resistant anti-static safety clothing. Wear leather safety gloves and
safety shoes when handling cylinders.
Physical state
EN (English US)
: Gas
SDS ID: P-4559
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4/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Appearance
Molecular mass
: 26 g/mol
Color
: Colorless.
Odor
: Garlic like.
Odor threshold
: No data available
pH
: Not applicable.
: No data available
: Not applicable.
Melting point
: -80.8 C
Freezing point
: No data available
Boiling point
: -84 C
Flash point
: No data available
Critical temperature
: 36 C
Auto-ignition temperature
: 305 C
Decomposition temperature
: 635 C
Vapor pressure
: 4400 kPa
Critical pressure
: 6138 kPa
: No data available
Relative density
: Not applicable.
: 0.9
Solubility
Log Pow
: 0.37
Log Kow
: Not applicable.
Viscosity, kinematic
: Not applicable.
Viscosity, dynamic
: Not applicable.
Explosive properties
: Not applicable.
Oxidizing properties
: None.
Explosive limits
: No data available
9.2.
Supersedes: 07/01/2014
Other information
Sublimation point
: -83.3 C
Gas group
: Dissolved gas
Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.
Chemical stability
Dissolved in a solvent supported in a porous mass. Stable under recommended handling and
storage conditions (see section 7).
10.3.
10.4.
Conditions to avoid
High temperature. High pressure. Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
10.5.
Incompatible materials
EN (English US)
Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than
65% copper. Air, Oxidizer. Do not use alloys containing more than 43% silver.
SDS ID: P-4559
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Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
10.6.
Supersedes: 07/01/2014
Acute toxicity
: Not classified
Skin corrosion/irritation
: Not classified
: Not classified
: Not classified
: Not classified
Carcinogenicity
: Not classified
Reproductive toxicity
: Not classified
: Not classified
: Not classified
Aspiration hazard
: Not classified
Not applicable.
Toxicity
Ecology - general
12.2.
Will rapidly degrade by indirect photolysis in air. Will not undergo hydrolysis.
Bioaccumulative potential
0.37
Not applicable.
Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9.
Mobility in soil
No data available.
Because of its high volatility, the product is unlikely to cause ground or water pollution.
EN (English US)
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6/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Supersedes: 07/01/2014
UN-No.(DOT)
: UN1001
: Acetylene, dissolved
Additional information
Emergency Response Guide (ERG) Number
: 116 (UN1001)
Other information
: Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
UN-No. (IMDG)
: 1001
: Acetylene, dissolved
Class (IMDG)
: 2 - Gases
MFAG-No
: 116
Air transport
UN-No.(IATA)
: 1001
: Acetylene, dissolved
Class (IATA)
: 2
EN (English US)
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7/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Supersedes: 07/01/2014
EU-Regulations
Acetylene, dissolved (74-86-2)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Gas 1 H220
Dissolved gas H280
Full text of H-phrases: see section 16
15.2.2. National regulations
Acetylene, dissolved (74-86-2)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
15.3. US State regulations
Acetylene, dissolved(74-86-2)
U.S. - California - Proposition 65 - Carcinogens List
No
No
No
No
EN (English US)
: 1/12/2015 12:00:00 AM
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8/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Other information
Supersedes: 07/01/2014
: When using this product in welding and cutting, read and understand the manufacturers
instructions and the precautionary label on the product. Ask your welding products supplier for
a copy of Praxairs free safety booklet, P-2035, Precautions and Safe Practices for Gas
Welding, Cutting, and Heating, and for other manufacturers safety publications. For a detailed
treatment, get ANSI Z49.1, Safety in Welding, Cutting, and Allied Processes, published by the
American Welding Society (AWS), www.aws.org. Order AWS documents from Global
Engineering Documents, global.ihs.com. Arcs and sparks can ignite combustible materials.
Prevent fires. Refer to NFPA 51B, Standard for Fire Prevention During Welding, Cutting, and
Other Hotwork. Do not strike an arc on the container. The defect produced by an arc burn may
lead to container rupture.
Fumes and gases produced during welding and cutting processes can be dangerous to your
health and may cause serious lung disease. KEEP YOUR HEAD OUT OF FUMES. DO NOT
BREATHE FUMES AND GASES. Use enough ventilation, local exhaust, or both to keep fumes
and gases from your breathing zone and the general area. Short-term overexposure to fumes
may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes; or may
cause other similar discomfort. Contaminants in the air may add to the hazard of fumes and
gases.
When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product.
Praxair asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information.
The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe
that the information contained herein is current as of the date of this Safety Data Sheet. Since
the use of this information and the conditions of use are not within the control of Praxair, Inc., it
is the user's obligation to determine the conditions of safe use of the product.
Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your Praxair sales representative, local distributor, or supplier, or download from
www.praxair.com. If you have questions regarding Praxair SDSs, would like the document
number and date of the latest SDS, or would like the names of the Praxair suppliers in your
area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247;
Address: Praxair Call Center, Praxair, Inc., P.O. Box 44, Tonawanda, NY 14151-0044).
PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair
Technology, Inc. in the United States and/or other countries.
NFPA reactivity
EN (English US)
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9/10
Acetylene, dissolved
Safety Data Sheet P-4559
according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1979
Supersedes: 07/01/2014
Flammability
: 4 Severe Hazard
Physical
: 2 Moderate Hazard
EN (English US)
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