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    SET13 Chemical Science II (C)

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    sudipta88
    This document appears to be part of a chemistry exam containing multiple choice questions about various topics in chemical science. It provides instructions for candidates taking the exam, including writing their roll number and filling in responses on an attached OMR sheet. The exam consists of 75 questions across various subfields of chemistry.

    Copyright:

    © All Rights Reserved
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    SET13 Chemical Science II (C)

    Uploaded by

    sudipta88
    26 views11 pages
    This document appears to be part of a chemistry exam containing multiple choice questions about various topics in chemical science. It provides instructions for candidates taking the exam, including writing their roll number and filling in responses on an attached OMR sheet. The exam consists of 75 questions across various subfields of chemistry.

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    SET13 Chemical Science II(C)

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    This document appears to be part of a chemistry exam containing multiple choice questions about various topics in chemical science. It provides instructions for candidates taking the exam, including writing their roll number and filling in responses on an attached OMR sheet. The exam consists of 75 questions across various subfields of chemistry.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    26 views11 pages

    SET13 Chemical Science II (C)

    Uploaded by

    sudipta88
    This document appears to be part of a chemistry exam containing multiple choice questions about various topics in chemical science. It provides instructions for candidates taking the exam, including writing their roll number and filling in responses on an attached OMR sheet. The exam consists of 75 questions across various subfields of chemistry.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 11

    SET13CHEMICAL SCIENCE-II(C)-C

    Signature of Invigilators

    Roll No.

    1. _______________________________

    (Write Roll Number from left side


    exactly as in Admit Card)

    2. _______________________________

    Test Booklet Series


    PAPERII

    1312

    Test Booklet No.


    OMR Sheet No.

    CHEMICAL SCIENCES
    Time : 1 Hour 15 minutes

    Maximum Marks: 100


    Instructions for the Candidates

    1. Write your roll number in the space provided on the top of this page and roll number with subject
    code on the OMR Sheet attached with this booklet. Also write your OMR Sheet number in the space
    provided above.
    2. This paper consists of seventy-five multiple choice type questions. Answer all the questions. Each
    question carries two marks.
    3. Each question has four alternative responses marked (A), (B), (C) and (D). You have to select only
    one correct response and mark it in the OMR Sheet with blue/black ball pen.
    Example:

    Here (C) is the correct response.


    4. Your responses to the questions are to be indicated only in the top page of the duplicate OMR Sheet
    provided with this booklet. If the marking is put at any other place than in the top page of the duplicate
    OMR Sheet, it will not be evaluated.
    5. Sheets are attached at the end of the booklet for rough work.
    6. If you write your name or put any special mark on any part of the test booklet or the top page of
    the duplicate OMR Sheet which may disclose in any way your identity, you will render yourself
    liable to disqualification.
    7. Do not tamper or fold the OMR Sheet in any way. If you do so, your OMR Sheet will not be evaluated.
    8. You should return the top page of the duplicate OMR Sheet along with this test booklet to the
    invigilator at the end of the examination. You are allowed to carry the second page of the OMR
    Sheet back with you for your future reference.
    9. If the top page of the duplicate OMR Sheet is not returned along with the test booklet, you will
    be disqualified.
    10. No candidate shall be allowed to leave his/her seat or the examination hall/room till the end of the
    examination without the permission of the invigilator.
    [Please Turn Over

    C-3

    1312II

    Chemical Sciences
    PAPER II
    1. The dissociation constant of benzoic acid is equal
    to 6.6 105. The pH of 0.022 mol L1 bonzoic acid
    solution will be nearly equal to (considering
    [H+] > > [OH] and concentration of acid > > [H+])
    (A) 3
    (B) 4
    (C) 5
    (D) 6
    2. Molar translational partition function (Qt) is
    calculated from the molecular translational partition
    function (qt) by using the relation (NA is Avogadro
    Number),
    (A) Qt = qt NA!
    NA
    t

    (B) Qt = q

    5. The entropy of mixing per mole of a mixture


    containing 1 mole of O2 and 1 mole of N2 at temperature
    T is equal to
    (A) RT ln 0.5
    (B) 2 RT ln 2
    (C) R ln 0.5
    (D) RT ln 0.5
    dq

    rev
    6. The value of the cyclic integral of
    (q is heat)

    (A) > 0
    (B) < 0
    (C) = 0

    NA!

    NA

    (C) Qt = qt

    (D) Qt = qtNA NA

    (D) = 1
    7. The absorbance of a solution having 50%
    trasmittance is
    (A) 0.301

    3. Adsorption of a soap at the air-water surface


    follows Langmuir isotherm. Then the plot of soap
    adsorbed per unit surface area () versus soap
    concentration (C) will appear like
    (A)
    C

    (B)

    is

    (B) 0.699
    (C) 1.301
    (D) 1.699
    8. Two monodispersed polymers with
    M = 62 Kg mol1 and M = 78 Kg mol1 are mixed in
    equal amounts. The number average molar mass of the
    mixture is

    (A) 81 Kg mol1

    (C)

    (B) 71 Kg mol1
    C

    (C) 68 Kg mol1

    (D)

    (D) 70 Kg mol1
    C

    4. The expression for first law of thermodynamics


    for water surface ( is surface tension and is the surface
    area) is
    (A) dU = TdS + PdV + d
    (B) dU = TdS + PdV + d
    (C) dU = TdS + PdV d
    (D) dU = TdS + d

    is

    9. The pH of an aqueous solution of 0.010 M KNO3


    (A)
    (B)
    (C)
    (D)

    5.60
    7.38
    7.00
    6.98
    [Please Turn Over

    SET13CHEMICAL SCIENCE-II(C)-C

    1312II

    C-4

    10. The IUPAC name of the spiro-compound


    CH3

    13. Match the information in column I with those


    in column II
    I
    II
    Cl

    (i)
    (A) 2-methyl spiro [5, 4] deca1, 6diene

    (ii)
    (iii)

    (D) 3-methyl spiro [5, 4] deca3, 7diene

    11. Match the following IR data in column II to the


    compounds in column I:
    I
    i.
    ii.
    iii.
    iv.

    acetone
    ethylacetale
    acetylchloride
    acetamide

    1770
    1655
    1730
    1700
    1540

    Me

    o
    N

    CO2H

    CO2H

    o
    N

    NO2
    CO 2H

    B. enantiomers
    C. diastereomers

    NO2
    CO 2H

    D. homomers
    E. atrop isomers

    (A) i : C; ii : A; iii : B; iv : D
    (B) i : B; ii : C; iii : A; iv : E
    (C) i : D; ii : E; iii : C; iv : B

    II
    m.
    n.
    o.
    p.
    q.

    NO 2 NO2

    (iv)

    Me

    Cl

    Me

    (B) 2-methyl spiro [4, 5] deca1, 6diene


    (C) 8-methyl spiro [4, 5] deca1, 7diene

    A. rotamers

    Me

    cm1
    cm1
    cm1
    cm1
    cm1

    (A) i : m; ii : n; iii : o; iv : p
    (B) i : p; ii : o; iii : m; iv : n
    (C) i : o; ii : p; iii : n; iv : m
    (D) i : o; ii : p; iii : n; iv : q

    (D) i : A; ii : B; iii : C; iv : E
    14. Gammexane is
    (A) DDT
    (B) Benzene hexachloride
    (C) Chloral
    (D) Hexachloroethane
    d is
    15. The hermitian conjugate of the operator
    dx
    given by
    d
    ( ) =
    dx
    d
    d
    (
    ) =
    dx
    dx
    d
    d
    (
    ) =i
    dx
    dx
    d
    (
    ) = dx
    dx

    d
    (A)
    dx

    (B)
    (C)
    12. Fore some 1-electron atom, an approximate
    ground-state wave function is given as
    0 ~ exp [Zr2/a0].
    The most probable value of r (the radius) will be
    (A) a0/2Z
    (B)

    a0/2Z

    (D)

    16. An enolate ion is a reactive intermediate in


    (A) Reimer-Tiemann reaction
    (B) Grignard reaction

    (C) 2Z/a0

    (C) Aldol reaction

    (D)

    (D) Fries rearrangement

    2Z/a0

    SET13CHEMICAL SCIENCE-II(C)-C

    C-5
    17. Barbiturates, which are derivatives of barbituric
    acid, are generally used as:
    (A) anthelmintics
    (B) analgesics
    (C) antipyrelics
    (D) tranquillizers
    18. The total energy of a H-atom in its first excited
    state is 3.4 eV. The average kinetic and potential
    energies are denoted respectively by < T > and < V >.
    These values satisfy
    (A) < T > = 3.4 eV, < V > = 6.8 eV
    (B) < T > = 1.7 eV, < V > = 5.1 eV
    (C) < T > = 6.8 eV, < V > = 10.2 eV
    (D) < T > = 1.7 eV, < V > = 1.7 eV
    19. Which of the following is non-aromatic?
    (A)
    (B)
    (C)
    (D)

    20. Which of the following is not a green house gas?


    (A) CO2

    1312II
    o

    22.

    (C) 3P1
    (D) 1D2

    III

    H3C

    24. Packing efficiency of a simple cubic crystal


    structure is
    1
    2
    3
    (B)
    2
    (C)
    9
    (D)
    6

    (A)

    (D) Water Vapour

    (B) 3P0

    23. The electronic configuration of an atom X is


    1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p4. The chemistry of X is,
    therefore, likely to be similar to that of
    (A) Boron
    (B) Oxygen
    (C) Nitrogen
    (D) Chlorine

    (C) O2

    (A) 3P2

    II

    Which of the following statement is true for the


    above sequence of reactions?
    (A) II is (2Z, 4E) 2, 4-hexadiene and the
    conversion II III is an endo-selective
    Diels-Alder reaction
    (B) II is (2Z, 4E) 2, 4-hexadiene and the
    conversion II III is an exo-selective DielsAlder reaction
    (C) II is (2E, 4E) 2, 4-hexadiene and the
    conversion II III is an endo-selective
    Diels-Alder reaction
    (D) II is (2E, 4E) 2, 4-hexadiene and the
    conversion II III is an exo-selective DielsAlder reaction

    (B) CH4

    21. The ground state of carbon atom has the electron


    configuration 1S22S22P2. The term symbol for the lowest
    energy state will be

    CH 3

    o
    Me

    Me

    25.

    + CO + HCl

    AlCl3

    CHO

    Cu2Cl 2

    The above transformation is known as


    (A) HallerBauer reaction
    (B) Hajos-Wiechert reaction
    (C) Gattermann-Koch reaction
    (D) Heck reaction
    [Please Turn Over

    SET13CHEMICAL SCIENCE-II(C)-C

    1312II

    C-6

    26. In the crystal structure of CuF2, the Cu+2 ion is

    hexa coordinated with four F at a distance of 1.93 and

    two F at 2.27 . The reasons for this is


    (A) Jahn-Teller distortion
    (B) Asymmetric vibration and stretching of bond
    lengths
    (C) Axial and equitorial bonds are always
    different
    (D) Such asymmetry of structure is the law of
    nature

    27. Maxwells speed distribution yields

    C2 = 3RT
    M
    8RT
    M

    and C =

    The value of C4 would then satisfy the inequatity


    (A)

    C4

    (B)

    C4

    8RT

    is

    C 4 3RT

    (C) M
    (D)

    8RT
    M
    3RT
    M
    M

    3RT
    M

    C
    4

    i. KH
    ii.

    iii. H

    (A)
    0

    (B)
    O

    (C)
    O

    (D)
    O

    30. A non-polar liquid like cyclohexane boils at


    87C at 1 atm. pressure. The expected molar enthalpy of
    vaporization will be
    (A) 7000 Cal
    (B) 700 Cal
    (C) 350 Cal
    (D) 3500 Cal
    31. Which of the following statement is correct for
    the following transformation?
    hv

    6
    H

    28. The major product of the following transformation

    OH

    29. According to Enrico Fermi, the emission of ,


    and radiation from a radioactive element is
    materialization of energy.
    (A) The statement is absolutely wrong
    (B) The statement is true because large quantity
    of energy is equivalent to small quantity of
    mass
    (C) The statement is wrong because radioactivity
    is spontaneous disintegration of larger body
    to a smaller body by eliminating some
    fragments
    (D) The statment is true because Enrico Fermi
    said it

    (A) It is an electrocyclic reaction, its HOMO is


    2, and the motion is conrotatory
    (B) It is an electrocyclic reaction, its HOMO is
    2, and the motion is disrotatory
    (C) It is an electrocyclic reaction, its HOMO is
    3, and the motion is conrotatory
    (D) It is an electrocyclic reaction, its HOMO is
    3, and the motion is disrotatory
    32. Ortho and para hydrogen have different physical
    properties, e.g., boiling points, specific heats and thermal
    conductivities, because
    (A) they are structural isomers
    (B) they are nuclear spin isomers
    (C) their molecular weights are different
    (D) the nature of their bonding is different

    SET13CHEMICAL SCIENCE-II(C)-C

    C-7
    33. The bond length r of a diatomic molecule is
    related to its reduced mass and rotational constant B by
    (A) r B
    1
    (B) r (B) 2

    34. The major product of the following reaction is


    o

    OEt

    OEt

    (B)
    (C)

    1. n-BuLi (2 eqv.)
    2.

    (A)

    Br

    3. H3O

    (A) planer, pyramidal and tetrahedral


    (B) pyramidal, planer and tetrahedral

    39. The symmetric stretch of a linear AB2 type of


    molecule is
    (A) IR active but Raman inactive
    (B) IR inactive but Raman active
    (C) Both IR and Raman active
    (D) Both IR and Raman inactive

    CO2Et

    o o C3H7

    40. Which of the following reagents will react with


    pyrrole to form 2-formyl pyrrole?

    OEt

    o o

    (D)

    (D) pyramidal, pyramidal and tetrahedral

    (D) r (B)1

    38. The species CO3 , H3O and BH4 are, respectively,

    (C) planer, pyramidal and planer

    (C) r (B) 2

    1312II

    OEt

    35. The ionization potentials of atoms C, N and O


    follow the order
    (A) C < N < O
    (B) O < N < C
    (C) C < O < N
    (D) N < O < C
    36. The molecule CO has
    (A) bond order equal to 3, and the molecule is
    paramagnetic
    (B) bond order equal to 3, and the molecule is
    diamagnetic
    (C) bond order equal to 1, and the molecule is
    paramagnetic
    (D) bond order equal to 1, and the molecule is
    diamagnetic
    37. The reagents used in Oppenauer Oxidation are
    (A) KMnO4 & CH3COCH3
    (B) CrO3 & CH3COCH3
    (C) Isoprophl alcohol and Aluminium
    isopropoxide
    (D) Aluminium isopropoxide and Acetone

    (A) HCOOH MeOH


    (B) CHCl3KOH
    (C) H2O2NaOH
    (D) AC2OSnCl4
    41. A diatomic molecule A B has a dipole moment
    of 2D and the internuclear distance is 108 cm. The ionic
    character of A B bond is approximately
    (A) 30%
    (B) 40%
    (C) 50%
    (D) 60%
    42. Identify the point group symmetry of the following
    form of cyclohexane molecule:

    (A) C6v
    (B) D3d
    (C) D6d
    (D) D2d
    [Please Turn Over

    SET13CHEMICAL SCIENCE-II(C)-C

    1312II

    C-8

    43. The important pain killer morphine, the chief


    alkaloid of opium, contains
    (A) Phenanthrene nucleus
    (B) Isoquinoline nucleus
    (C) Pyrrolidine nucleus
    (D) Indole nucleus
    44. The complex [ Ni (CN)4]2 is
    (A) planer and diamagnetic
    (B) planer and paramagnetic
    (C) tetrahedral and diamagnetic
    (D) tetrahedral and paramagnetic

    47. The chemical and physical properties of elements


    are periodic function of
    (A) atomic density
    (B) atomic weight
    (C) atomic volume
    (D) atomic number
    48. The activated complex [AB] is formed repidly
    from A and B as shown below:
    A+B

    (A)
    (B)
    (C)
    (D)

    2/3
    1/3
    (A) Ca
    ++ Ce

    (B) Ca++ Ce2

    49.

    (C) Ca++ Ce
    2
    (D) Ca
    ++ Ce

    OH

    OH
    III

    OH
    II

    Appropriate reagents for the selective preparation


    of II and III from I are
    (A) II : H2, Pd | BaSO4; III : Na, Liq .NH3
    (B) II : Na, Liq .NH3; III : H2, Pd | BaSO4
    (C) II : H2 | Pd(OH)2; III : Sn | HCl
    (D) II : Sn | HCl; III : H2 | Pd(OH)2

    [AB]

    kb

    (Fast)

    If Kf is equal to ZeE/RT (Z being the frequency


    factor), the value of kb is

    45. The mean activity co-efficient () of the ions in


    a solution of CaCl2 in terms of the activity co-efficient
    of individual ions is given by

    46.

    kf

    Ze+ E/RT
    Z
    Z1eE/RT
    eE/RT
    NO2

    1.

    MgBr

    2. H3O

    N
    H

    The above transformation is an example of


    (A) Fischer Indole Synthesis
    (B) Bartoli Indole Synthesis
    (C) Reissert Synthesis
    (D) Madelung Synthesis
    50. The CFSE of d0, d5 (high spin) and d10 ions are
    (A) all zero
    (B) all non-zero
    (C) zero only for the first two cases
    (D) zero only for the last two cases

    SET13CHEMICAL SCIENCE-II(C)-C

    C-9
    ROUGH WORK

    1312II

    SET13CHEMICAL SCIENCE-II(C)-C

    1312II

    C-10
    ROUGH WORK

    SET13CHEMICAL SCIENCE-II(C)-C

    C-11
    ROUGH WORK

    1312II

    SET13CHEMICAL SCIENCE-II(C)-C

    1312II

    C-12
    ROUGH WORK

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