Safety Data Sheet: Identification of The Substance/preparation and of The Company/undertaking
Safety Data Sheet: Identification of The Substance/preparation and of The Company/undertaking
Safety Data Sheet: Identification of The Substance/preparation and of The Company/undertaking
1.
: Jotamastic 87 - Comp. A
Supplier/Manufacturer
Product Use
2.
Composition/information on ingredients
Chemical name*
CAS no.
EC Number
25068-38-6
500-033-5
10-25
Xylene
1330-20-7
215-535-7
2.5-10
2-Methylpropan-1-ol
78-83-1
201-148-0
2.5-10
Benzyl alcohol
Ethylbenzene
100-51-6
100-41-4
202-859-9
202-849-4
1-2.5
1-2.5
Classification
Xi; R36/38
R43
N; R51/53
R10
Xn; R20/21
Xi; R38
R10
Xi; R37/38, 41
R67
Xn; R20/22
F; R11
Xn; R20
See Section 16 for the full text of the R Phrases declared above.
* Occupational Exposure Limit(s), if available, are listed in Section 8.
3.
Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Flammable.
Irritating to eyes and skin.
May cause sensitization by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Irritant
The preparation may be a skin sensitiser. It may also be a skin irritant and repeated contact may increase this effect.
4.
First-aid measures
First-Aid measures
General
Inhalation
Skin contact
Eye Contact
Ingestion
Date of issue
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious place
in recovery position and seek medical advice.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin
cleanser. Do NOT use solvents or thinners.
: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
keeping eyelids open.
: If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest.
Do not induce vomiting.
: 03.03.2003.
Page: 1/5
Jotamastic 87 - Comp. A
5.
Fire-fighting measures
Extinguishing Media
Recommendations
6.
Personal Precautions
Spill
: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist. Refer to protective measures
listed in sections 7 and 8.
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13). Do not
allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product
contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.
7.
Handling
: Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air.
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap.
Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates and spray mist arising from the
application of this preparation. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty : container is not a pressure vessel. Always keep in containers of same material as
the original one.
Comply with the health and safety at work laws.
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be
sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a
compressed air-fed respirator during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.
: Store in accordance with local regulations. Observe label precautions. Store in a cool, well-ventilated area away
from incompatible materials and ignition sources.
Storage
8.
Engineering measures
Ingredient Name
: Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and
solvent vapour below the OEL, suitable respiratory protection must be worn.
Occupational Exposure Limits
2-Methylpropan-1-ol
Benzyl alcohol
Ethylbenzene
Date of issue
: 03.03.2003.
Not available.
EH40-OES (United Kingdom (UK), 2002). Skin Notes: OES
STEL: 441 mg/m3 15 minute(s).
STEL: 100 ppm 15 minute(s).
TWA: 220 mg/m3 8 hour(s).
TWA: 50 ppm 8 hour(s).
EH40-OES (United Kingdom (UK), 2002). Notes: OES
STEL: 231 mg/m3 15 minute(s).
STEL: 75 ppm 15 minute(s).
TWA: 154 mg/m3 8 hour(s).
TWA: 50 ppm 8 hour(s).
Not available.
EH40-OES (United Kingdom (UK), 2002). Skin Notes: OES
STEL: 552 mg/m3 15 minute(s).
STEL: 125 ppm 15 minute(s).
TWA: 441 mg/m3 8 hour(s).
TWA: 100 ppm 8 hour(s).
Page: 2/5
Jotamastic 87 - Comp. A
Personal protective equipment
: If workers are exposed to concentrations above the exposure limit they must use appropriate, certified
respirators. Use respiratory mask with charcoal and dust filter when spraying this product (as filter combination
A2-P2). In confined spaces use compressed air or fresh air respiratory equipment. When use of roller or
brush, consider use of charcoalfilter (A2).
: Personnel should wear anti-static clothing made of natural fibre or of high temperature resistant synthetic fibre.
Hands
Eyes
Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once
exposure has occurred.
: Use safety eyewear designed to protect against splash of liquids.
Respiratory system
9.
Physical state
: Liquid.
Odour
: Characteristic.
Colour
: Various colours.
Flash point
pH
: Not applicable.
Density
: 1.4 g/cm3
Vapour density
: The highest known value is 3.72 (Air = 1) (Benzyl alcohol). Weighted average: 3.49 (Air = 1)
Solubility
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is not classified as
dangerous for the environment, but contains substance(s) dangerous for the environment. See section 2 for details.
Ecotoxicity Data
Ingredient Name
Species
Reaction product: bisphenol A-(epichlorhydrin) Trout (LC50)
Daphnia (EC50)
Xylene
Oncorhynchus mykiss (LC50)
Oncorhynchus mykiss (LC50)
Lepomis macrochirus (LC50)
Lepomis macrochirus (LC50)
Lepomis macrochirus (LC50)
Pimephales promelas (LC50)
2-Methylpropan-1-ol
Scenedesmus subspicatus (EC50)
Daphnia pulex (EC50)
Scenedesmus subspicatus (EC50)
Oncorhynchus mykiss (LC50)
Pimephales promelas (LC50)
Pimephales promelas (LC50)
Benzyl alcohol
Lepomis macrochirus (LC50)
Pimephales promelas (LC50)
Ethylbenzene
Daphnia magna (EC50)
Daphnia magna (EC50)
Date of issue
: 03.03.2003.
Period
96 hours
48 hours
96 hours
96 hours
96 hours
96 hours
96 hours
96 hours
48 hours
48 hours
48 hours
96 hours
96 hours
96 hours
96 hours
96 hours
48 hours
48 hours
Result
1.5 mg/l
3.6 mg/l
3.3 mg/l
8.2 mg/l
8.6 mg/l
12 mg/l
13.3 mg/l
13.4 mg/l
230 mg/l
1100 mg/l
1250 mg/l
1330 mg/l
1430 mg/l
1510 mg/l
10 mg/l
460 mg/l
2.93 mg/l
2.97 mg/l
Page: 3/5
Jotamastic 87 - Comp. A
Selenastrum capricornutum (EC50)
Oncorhynchus mykiss (LC50)
Pimephales promelas (LC50)
Poecilia reticulata (LC50)
7.2 mg/l
4.2 mg/l
9.09 mg/l
9.6 mg/l
48 hours
96 hours
96 hours
96 hours
Ecological information
Ingredient Name
Bioaccumulative potential
Persistence/degradability
BOD5
COD
ThOD
Aquatic Half-life
Photolysis
Reaction product:
bisphenol
A-(epichlorhydrin)
Biodegradability
LogPow
BCF
Potential
Not readily
: 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS
UN number
Class
Packing group
ADR/RID Class
1263
Paint.
III
Label
Additional Information
Hazard identification
number
30
3
IMDG Class
1263
Paint.
III
Emergency Schedules
(EmS)
F-E, S-E
3
Marine pollutant
No.
Paint.
III
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG: Viscous substance. Transport
in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity).
Irritant
Contains
Risk Phrases
: R10- Flammable.
R36/38- Irritating to eyes and skin.
R43- May cause sensitization by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
: S16- Keep away from sources of ignition - No smoking.
S23- Do not breathe vapor / spray.
S24- Avoid contact with skin.
S37- Wear suitable gloves.
S51- Use only in well-ventilated areas.
S61- Avoid release to the environment. Refer to special instructions/Safety data sheets.
: Contains epoxy constituents. See information supplied by the manufacturer. This information is provided by the
present Safety Data Sheet.
Safety Phrases
Date of issue
: 03.03.2003.
Page: 4/5
Jotamastic 87 - Comp. A
: 1
: R11- Highly flammable.
R10- Flammable.
R20- Harmful by inhalation.
R20/21- Harmful by inhalation and in contact with skin.
R20/22- Harmful by inhalation and if swallowed.
R36/38- Irritating to eyes and skin.
R37/38- Irritating to respiratory system and skin.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.
R43- May cause sensitization by skin contact.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
HISTORY
Date of printing
: 24.03.2003.
Date of issue
: 03.03.2003.
: No Previous Validation.
Version
: 1
Prepared by
Notice to Reader
The information of this SDS is based on the present state of our knowledge and on current EU and national laws. The product is not to be used for other
purposes than those specified under section 1 without first obtaining written handling instruction. It is always the responsibility of the user to take all
necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this SDS is meant as a description of the safety
requirements of our product : it is not to be considered as a guarantee of the products properties.
Indicates information that has changed from previously issued version.
Changes have been made in international and national regulations that influences the following information in the Safety datasheets: Environmental labelling, sensitizers,
carcinogenic effects and effects from solvents.
Version
1
Page: 5/5