Identification of the preparation and of the company

SAFETY DATA SHEET

WaterFine Zn Primer - Comp. B
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
1.
Emergency telephone
number
Supplier/Manufacturer
:
:
Product use Coatings: Hardener :
Label No. : 787
Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
[email protected]
WaterFine Zn Primer - Comp. B Product name and/or code :
Contact National Poison Centre via Hospital or Registered Medical Practitioner
Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Dangerous for the
environment

2.
Composition/information on ingredients
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
CAS
number
% by
weight
EC
number
Classification Chemical name*
zinc powder - dust (stabilised) - 7440-66-6 231-175-3 50 - 100 N; R50/53
zinc oxide - 1314-13-2 215-222-5 2.5 - 10 N; R50/53
See section 16 for the full text of the R-phrases
declared above
Occupational exposure limits, if available, are listed in section 8.
3.
Notes
If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.
Skin contact
Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
4.
First-aid measures
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Ingestion
Inhalation
Eye contact
:
:
:
:
First-aid measures
General In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
:
Date of issue : Page: 1/5 29.06.2010.
WaterFine Zn Primer - Comp. B
Fire-fighting measures 5.
Recommended: alcohol-resistant foam, CO2 blanket, water spray or mist. Extinguishing media :
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required.
Cool closed containers exposed to fire with water. Do not release runoff from fire to
drains or watercourses.
Extinguishing media not to
be used
: Do not use water jet.
Personal precautions Exclude sources of ignition and ventilate the area. Avoid breathing dust. Refer to
protective measures listed in sections 7 and 8.
6. Accidental release measures
:
: Spill Contain and collect spillage with an electrically protected vacuum cleaner or by wet-
brushing and place in container for disposal according to local regulations (see
section 13). Do not use a dry brush as dust clouds or static can be created.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.
Handling
Handling and storage
Storage
7.
Precautions should be taken to prevent the formation of dusts in concentrations
above flammable, explosive or occupational exposure limits.
Electrical equipment and lighting should be protected to appropriate standards to
prevent dust coming into contact with hot surfaces, sparks or other ignition sources.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Keep container tightly closed. Keep away from heat, sparks and flame.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Comply with the health and safety at work laws.
Always keep in containers made from the same material as the original one.
Put on appropriate personal protective equipment (see section 8).
Store in accordance with local regulations. Observe label precautions. Store in a dry,
cool and well-ventilated area. Keep away from heat and direct sunlight.
No smoking. Prevent unauthorised access. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage.
:
:
Persons suffering from respiratory problems or allergic responses should not be exposed to or handle powder
coatings.
Engineering measures Avoid breathing dust. Where reasonably practicable, this should be achieved by the
use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain exposure to dusts below the OEL, suitable respiratory
protection must be worn.
8. Exposure controls/personal protection
Skin and body
Personal protective equipment
If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. If dust is generated and ventilation is inadequate,
use respirator that will protect against dust/mist. (FFP2 / N95).
Personnel should wear protective clothing. Care should be taken in the selection of
protective clothing to ensure that inflammation and irritation of the skin at the neck
and wrists through contact with the powder are avoided.
Respiratory system
:
:
:
Occupational exposure limits
zinc powder - dust (stabilised) EH40-MEL (United Kingdom (UK), 2002).
STEL: 10 mg/m 15 minute(s).
TWA: 5 mg/m 8 hour(s).
Ingredient name
Dust Limit : 10 mg/m (TWA of total inhalable dust) and 4 mg/m (TWA of respirable) Occupational exposure
limits
:
Date of issue : Page: 2/5 29.06.2010.
WaterFine Zn Primer - Comp. B
Safety eyewear should be used when there is a likelihood of exposure. Eyes
:
:
Wear suitable gloves.
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber
Hands
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Physical and chemical properties 9.
Physical state
Solubility
Solid. [Powder.]
Insoluble in the following materials: cold water and hot water.
Characteristic. Odour
Various colours. Colour
Flash point Closed cup: Not applicable.
:
:
:
:
:
Density : 6.8 g/cm
3
Stability and reactivity
Stable under recommended storage and handling conditions (see section 7).
Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.
10.
Toxicological information 11.
There is no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 2 and 15 for details.
Coating powders can cause localised skin irritation in folds of the skin or under tight clothing. Handling and/or
processing of this material may generate a dust which can cause mechanical irritation of the eyes, skin, nose and
throat. Repeated inhalation of dust can produce varying degrees of respiratory irritation or lung damage. Swallowing
may cause nausea, diarrhoea, vomiting and gastro-intestinal irritation.
Inhalation of zinc fumes may induce influenza (zinc fever), which usually may last for two days.
Ecological information 12.
There is no data available on the preparation itself.
Coating powder residues should not be allowed to enter drains or watercourses or be deposited where they could affect
ground or surface waters.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.
Aquatic ecotoxicity
zinc powder - dust (stabilised) Mortality Acute LC50 0,24 mg/L
Fresh water
Fish -
Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss - 70
mm
96 hours
Mortality Acute LC50 68 ug/L
Fresh water
Daphnia -
Water flea -
Daphnia
magna - <24
hours
48 hours
zinc oxide Intoxication Acute EC50 >1000 ppm
Fresh water
Daphnia -
Water flea -
Daphnia
magna - <24
hours
48 hours
Mortality Acute LC50 1,1 to 2,5 Fish - 96 hours
Product/ingredient name Test Species Result Exposure
Date of issue : Page: 3/5 29.06.2010.
WaterFine Zn Primer - Comp. B
Ecological information
Product/ingredient name Aquatic half-life Photolysis Biodegradability
zinc powder - dust (stabilised) - - Not readily
zinc oxide - - Not readily
ppm Fresh water Rainbow
trout,donaldson
trout -
Oncorhynchus
mykiss
Biodegradability
Disposal considerations 13.
Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
08 01 11* waste paint and varnish containing organic solvents or other dangerous
substances. If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.
European waste catalogue
(EWC)
:
14.
International transport regulations
Environmentally hazardous substance, solid, n.o.s. (zinc, zinc oxide) Proper shipping name
Packing group III
Label

:
:
:
Transport information
3077 UN Number :
Class 9 :
Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
Additional information
ADR / RID : Tunnel restriction code: (E)
Hazard identification number: 90
Special provisions: 274
Emergency schedules (EmS): F-A, S-F
Marine pollutant: Yes.
: IMDG
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
These zinc types have been tested according to the criteria for classes 4.1, 4.2 and 4.3. The testresults shows that
these types do not meet the criterias for classifying in class 4.1, 4.2, 4.3 : BAM, 2005 Report II.2-916/04.
Marine pollutant
substances
zinc, zinc oxide :
Marking : The environmental hazardous / marine pollutant mark is only applicable
for packages containing more than 5 litres for liquids and 5 kg for
solids.
Regulatory information
Dangerous for the
environment

15.
Safety phrases S7/8- Keep container tightly closed and dry.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Hazard symbol or symbols
Risk phrases
EU regulations
:
:
:
: The product is classified and labelled for supply in accordance with the Directive
1999/45/EC as follows:
Date of issue : Page: 4/5 29.06.2010.
WaterFine Zn Primer - Comp. B
Industrial use : The information contained in this safety data sheet does not constitute the users
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.
Other information 16.
Date of issue 29.06.2010.
Version
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.
Notice to reader
3
:
CEPE Classification : 3
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: Full text of R-phrases
referred to in sections 2 and
3 - United Kingdom (UK)
This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.
:

Indicates information that has changed from previously issued version.
Date of issue : Page: 5/5 29.06.2010.